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SESSION 2024-25

CHEMISTRY PROJECT
WORK

Submitted By :
Name – Shubham Raj
Class – 12th
Subject –Chemistry
Acknowledgement
First and foremost, I would like to
thank the Director sir of the school or
having provided us with the essential
platform needed for Completion of this
project.
I extend my sincere gratitude to
Principal Mrs Simple Kumari sinha her
support and motivation during my
project work.
It gives me immense plesure in
expressing my gratitude towards Mr
Mantosh Kumar the academic
coordinator for assisting us in the
completion of this project.
Whole heartedly express my deep
sense indebtedness and appreciation
to Physics teacher Mr. Amardeep
Bhardwaj for his motivation, guidance
and content encouragement for the
successful completion of the project.
I also acknowledge to extend my
gratitude towards my parents, other
faculty members of the school to give
me in completing the project.

CERTIFICATE
This is to certify that the project
work on Study of the presence of
oxalate ions in guava fruit at
different stages of ripening based
on the curriculum of CBSE class
XII , Section Patna Doon Public
School, Patna,

The above-mentioned project work


has been completed under my
guidance during the academic year
2024-25.

Signature of Teacher

Date:
Place: Patna

INDEX
Table Of Contents
1. Introduction
2. Aim
3. Theory
4. Requirements
5. Chemical Equation
6. Procedure
7. Precaution
8. Observation
9. Calculations
10. Results
11. Conclusion
12. Bibliography

INTRODUCTION

Guava, (Psidium guajava), small


tropical tree or shrub of the
family Myrtaceae, cultivated for
its edible fruits. Guava trees are
native to tropical America and
are grown in tropical and
subtropical areas worldwide.
Guava fruits are processed into
jams, jellies, and preserves and
are common pastry fillings. Fresh
guavas are rich in vitamins A, B,
and C; they are commonly eaten
raw and may be sliced and
served with sugar and cream as
a dessert.

What Is Oxalate?
Oxalate (IUPAC: ethanedioate) is an
anion Represented by the chemical
formula, C2O4-2. This dianion is
colorless. It occurs naturally,
including in some foods. It forms a
variety of salts, for example
sodium oxalate and several esters
such as dimethyl oxalate. What
contains Oxalate are a dicarboxylic
acid dianion composition that goes
with the chemical formula of C2O4
Also known as Ethanedioate or
Oxalate lon or Oxalic Acid Dianion,
Oxalates are one of the most
abundant materials that exist on
the earth's surface, found in both
plants and animals. Interestingly,
the process of obtaining it through
the deprotonation of the given
carboxy groups of C2H2O4 (oxalic
acid). These specific carboxyl
groups are used as a source of
derivatives, similar to the likes of
salts that are present over oxalic
acid. Few examples over the same
suggestions are dimethyl oxalate or
sodium oxalate. Further, Oxalates
also form superior coordination
with a variety of compounds that
are sometimes also abbreviated as
an 'ox'.

AIM
To Study The Presence Of
Oxalate Ions In Guava Fruit At
Different Stages Of Ripening.

THEORY
Oxalate ions are extracted from
the fruits by boiling pulp with
dilute SO₄. The oxalate ions are
estimated volumetrically, by
titrating the solution with KMnO4
solution. A reagent called the
titrant of a known concentration
(a standard solution) and with

Volume is used to react with a


solution of the analyte or titrand,
whose concentration is
unknown. Using a calibrated
burette or chemistry pipetting
syringe to add the titrant, it is
possible to determine the exact
amount that has been consumed
when the endpoint is reached.
The endpoint is the point at
which the titration is complete,
as determined by an indicator.
This is ideally the same volume
as the equivalence point.

The volume of added titrant at


which the number of moles of
titrant is equal to the number of
moles of analyte, or some or
some multiple thereof (as in
polyprotic acids). In the classic
strong acid-strong base titration,
the endpoint of a titration is the
point at which the pH of the
reactant is just about equal to 7,
and often when the solution
takes on a persisting solid colour
as in the pink of phenolphthalein
indicator
Requirements
Apparatus-
Chemicals-

Guava fruits at
different stages of
ripening-

CHEMICAL
EQUATIONS
PROCEDURE
1) Weighed 50 g of fresh guava
and crushed it to a fine pulp
using a pestle and mortar.

(2) Transferred the crushed pulp


to a beaker and added about 50
ml dilute H₂SO₄ to it.
(3) Boiled the content for about
10 minutes. Cooled and filtered
the contents in a 100 ml
measuring flask.

(4) Made up the volume of 100


ml by adding an ample amount
of distilled water.
5) Took 20 ml of the solution
from the flask and added 20 ml
of dilute sulphuric acid to it.

(6) Heated the mixture to about


60° C and titrated it against
(n/10) KMnO4solution taken in a
burette till the end point had an
appearance of pink colour.

(7) Repeated the above


experiment with 50 g of 1-day,
2-day and 3-day-old guava fruits.
PRECAUTIONS
1. There should be no parallax
while taking measurements.

2. Spillage of chemicals should


be checked.

3. Avoid the use of a burette


having a rubber tap as KMnO4
attacks rubber.

4. In order to get some idea


about the temperature of the
solution touches the flask with
the back side of your hand.
When it becomes unbearable to
touch the required temperature
is reached.
5. Add about an equal volume of
dil. H₂SO₄ to the guava extract is
to be titrated (say a full test
tube) before adding KMnO4.
OBSERVATION
1. THE WEIGHT OF THE GUAVA
FRUIT FOR EACH TIME WAS 50 G.
2. VOLUME OF GUAVA EXTRACT
TAKEN FOR EACH TITRATION
WAS 20 ML.
3. NORMALITY OF THE KMNQ
SOLUTION WAS (1/10).
4. END POINT: COLOUR
CHANGES TO PINK.
CALCULATIONS
RESULTS
(a) The normality of oxalate ions of;

(i) Fresh guava solution is = 1.32


ml

(ii) Semi-ripen guava solution is =


1.37 ml

(iii) Ripened guava solution is =


1.39 ml
(b) The strength of oxalate ions of;

(i) Fresh guava solution is = 0.58


ml

(ii) Semi-ripened guava is = 0.6 ml

(iii) Ripened guava is = 0.61 ml


CONCLUSION
The content of oxalate ions in
guava was found to be 59.67 per
cent, which is close to the literature
value of 60 per cent.

It was also noticed that the content


of oxalic ions grows with the
ripening of guava.
BIBLIOGRAPHY
1. Search engines used:

www.google.com
www.wikipedia.com
www.reader.google.com
www.labs.google.com
www.britannica.com

2. Practical Chemistry by Laxmi


Publications.
3. The Family Encyclopedia by
Dorling Kindersley
4. NCERT Textbook

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