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Final Exam Review Key

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Page 1: Answers to select ( important) questions

1. | 7.89-8.92 | x 100 = 11.5%


8.92

2. A. 5.48 x 105
B. 7.70 x 10-5
C. 0.001200
D. 92500000
3. m = D x V = 22.57 x 56.2 = 1268 g
4. A. 65.2 mm x 1 m x 100 cm = 6.52 cm
1000 mm 1m

B. 2.3 kg x 1000g = 23000g


1 Kg

C. 65 L

D. 0.502 km x 1000m x 100 cm = 50200 cm


1km 1m

8. A. Carbon - 14 ; P = 6, E = 6 , N = 8 , Mass # = 14, Atomic # = 6


B. Chromium-53 ; P = 24, E = 24 , N = 29 , Mass # = 53, Atomic # = 24

9. Zn : A# = 30, Mass # = 65, P = 30, E = 30, N = 65-30 = 35


Ca: A# 20, Mass #: 20 + 21 = 41, P = 20, N = 21, E = 20
Se: A# 34; Mass # = 74; E = 34; N = 74-34 = 40

11. You can google these

12. When you heat an electron it becomes excited by jumping up the energy levels. When you come back to
the ground state it releases a photon.
13. Photon is a particle of light with fixed(discreet0 amount of energy called Quanta.
14. Wavelength is indirectly related to frequency.
15. IGNORE
16. S = 1 orbital (2e), P = 3 orbital(6 e), D = 5 orbital (10 e), F = 7 orbital (14 e)

17. Notes*
He has the highest ionization energy
F has the highest electronegativity
Fr has the largest atomic radius
Ca vs Ca2+ the neutral atom is bigger than the cation
S vs S2- the anion is bigger than the neutral atom
Page 2: Answers to select Questions

22. A. MgO = Ionic (M + NM) B. LiCl ( M + NM) = Ionic C. H2O ( 2NM) = Polar
D. Br2 (same atom) = Nonpolar Covalent

23. A. Metallic ; B. Ionic; C. Metallic; D. Covalent ; E. Ionic; F. Covalent

24. Show arrows when drawing the transfer of 2 electrons from Mg to O

25. the molecular geometry of water is bent and E.G is tetrahedral; Lone Pair = 2, BP = 2

26. Lower the potential energy more stable the molecule

27.
A. Ionic CaBr2 B. Fe2(SO4)3 C. Li3PO4 D. SiO2 E. N2O4 F. (NH4)2 CO3

28. A. Chromium (III) Chloride B. Copper ( I) Carbonate C. Arsenic Pentachloride

D. Magnesium Sulfate E. Tetraphosphorus Hexaoxide F. Sodium Chlorate

30. VSEPR stands for Valence Shell Electron Repulsion Theory, which means when atoms bond they are the
farthest away from each other to avoid repelling of the bonded or lone pair of electrons.

31. BeCl2 lone Pair : 0


Shared Pair: 2
MG: EG: Linear
NON POLAR

CF4 Lone Pair = 0 ; Bonded Pair: 4 ; EG = MG = Tetrahedral NON POLAR

H2O see # 25 POLAR


MOLE
34. 25g MgSO4 x 1 mol MgSO4 x 6.02 x 1023 molecules MgSO4 = 1.25 x 1023 molecules MgSO4
120.36 g 1 mol MgSO4

35. Copper (II) Chloride : CuCl2

Cu = 63.55 g
Cl2 = 35.45 x 2 = 70.9 g
134.45 g

% Cu = (63.55/ 134.34) x 100 = 47.3 %

% Cl = (70.9 /134.45) x 100 = 52.7 %

36. 40 g C x (1 mol / 12.01 g) = 3.33 mol / 3.33 = 1 CH2O is the Empirical Formula
6.7 g H x (1 mol / 1.01 g) = 6.6 mol / 3.33 = 2 MM = (12 + 2.02 + 16) = 30.02
53.7 g O x (1 mol / 16.00) = 3.36 / 3.33 = 1 180/30 = 6
6 (CH2O) = C6H12O6 is the molecular mass

37. 5 g H2SO4 x 1 mol H2SO4 = 0.051 moles


98.08 g

38. 34 L H2 x 1 mol H2 x 2.02 g H2 = 3.0 g H2


22.4 L 1 mol H

39. 170.4 g Ca(OH)2

40 3.4 mol x 22.4 L = 76.2 L O2


Page 3:
Chemical Reactions

41. 2NaClO3 (aq) —>2 NaCl (aq) + 3O2 (g) - Decomposition

42. A. 2 K + ZnCl2 → Zn + 2 KCl - SR


B. Cl2 + HF —> NR Cl is weaker than F
C. Fe + Na3 PO4 —> NR Fe is weaker

43. A. KI + AgNO3 —> AgI (s) + KNO3 (aq)

B. 3 (NH3)3PO4 (aq) + 3 Na2SO4 (aq) —> 2 Na3PO4 (aq) + 3 (NH4)2SO4 (s)

44. a) balanced : SR b) 1, 8, 5, 6 : Combustion c) 2, 4, 3 : Decomposition d) 1,1,1,2 : DR


e) 2, 1, 2 : Synthesis
Stoichiometry

* #50 I made a mistake.


Limiting R is Li and Theoretical Yield is O2 ; % yield is (12.5/13.88) x 100 = 90.1%
Gas Laws

51. A Boyle’s Law: Balloon pops because the air inside expands (V ) as the pressure drops when going up.

B. Charles Law: T and V are directly proportional. As Temperature increases the volume inside the balloon
expands.
C. Charles Law: T and V are directly proportional. As Temperature inside the can increases the volume of the
gas inside the aerosol can increase causing it to explode.

52.
T1 = 22 C + 273 = 295 K P1 = P2 ; P2 = (P1 x T2)/T1
P1 = 772 mmHg / 760 = 1.016 atm T1 T2
T2 = 178C + 273 = 451K
P2 =? P2 = ( 1.016 x 451) / 295 = 1.55 atm
Gay-Lussac’s Law or 1180 mmHg

53. V = ? PV = nRT ; V = nRT/ P


n = 5 mol
T = 50 + 273 = 323K V = (5 x 0.0821 x 323) / 1.2 = 110.5 L
P = 1.2 atm
R = 0.0821
IDEAL GAS LAW

54. PHe = 1.8 atm; PH2 = ?, Total P = 5.9 atm

Ptotal = PHe + PH2 ; PH2 = Ptotal - PHe = 5.9 - 1.8 = 4.1 atm
DALTON’s LAW OF PARTIAL PRESSURE

55. IGNORE AVOGADRO’s LAW

56. V1 = 3L ; P1 = 75 /101.325 = 0.74 atm , P1V1 = P2V2 ; P2 = (P1V1/V2)


V2 = 1.25L ; P2? (0.74 x 3)/1.25 = 1.78 atm
Boyle’s Law

57. V1 = 50L; T1 = 75C + 273 = 348K (V1/T1) = (V2/T2)


V2 = 110L ; T2 = ? T2 = (V2 x T1)/ V1
*I need my temperature in C at the end. T2 = (110 x 348)/50 = 765.6 K or

Charles’ Law 765.6 - 273 = 493 C

58. V1 = 325 L ; T1 = 25 + 273 = 298K ; P1= 98/101.325 = 0.96 atm.


V2 = ? ; T2 = 15 + 273 = 288K ; P2 = 70/101.325 = 0.69 atm

COMBINED GAS LAW P1V1 = P2V2 = (325 x 0.96) = (0.69 x V2) = 437 L
T1 T2 298 288

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