NEET

Arjuna
Arjuna NEET
NEET 3.02025
2025
Practice Sheet
Physical Chemistry
Equilibrium

Q1 The solution of blue vitrol in water is acidic Q7 For the reaction

because: , at 250 ,
∘
PCl3 ( g) + Cl2 ( g) ⇌ PCl5 ( g) C

(A) CuSO4 reacts with water the value of Kc is 26 , then the value of KP at
(B) Cu 2+ reacts with water same temperature will be
(C) SO4 reacts with water
2−
(A) 0.61 (B) 0.47
(D) CuSO4 removes OH ions from water
−
(C) 0.92 (D) 0.26

Q2 The solubility in water of a sparingly soluble salt Q8 In which of the following cases, is the solution of
AB2 is 1.0 × 10
−5
molL
−1
. Its solubility AgCl unsaturated?
(A) [Ag
+ −
product will be ] [Cl ] < Ksp

(A) 4 × 10
−15
(B) [Ag+ ] [Cl− ] > Ksp

(B) 4 × 10 −10
(C) [Ag+ ] [Cl− ] = Ksp

(C) 1 × 10 (D) [Ag

−15 + −
] [Cl ] ≤ Ksp

(D) 1 × 10 −10

Q9 Ksp of AgCl is 1 × 10−10 . Its solubility in 0.1 M

Q3 What is the pH of a solution of 0.28 M acid and KNO3 will be:
0.84 M of its conjugate base if the ionization (A) 10−5 mol/L
constant of acid is 4 × 10−4 ? (B) > 10
−5
mol/L
(A) 3.88 (B) 3.34 (C) < 10
−5
mol/L
(C) 7 (D) 10.12 (D) None of these

Q4 An aqueous solution at room temperature Q10 The solubility product of different sparingly
contains 0.1 M NH4Cl and 0.01 M NH4OH (pKb = soluble salts are given as under:
5) the pH of the solution is:
(A) 7.5 (B) 6.8
(C) 6.5 (D) 8.0

Q5 In the neutralization process of H3 PO4 and

NaOH , the number of buffers formed will be: The correct increasing order of solubility is:
(A) 3 (B) 1 (A) 1, 3, 2 (B) 2, 1, 3
(C) 2 (D) 4 (C) 1, 2, 3 (D) 3, 1, 2

Q6 For the reaction A + B ⇌ 2C , at the Q11 The solubility of electrolytes MX1 , MX2 and
is 1 × 10 moles per litre. Hence, their
−3
equilibrium concentration of A and B each is MX3

0.20 mole/litre concentration C is observed as respective solubility products are:

0.60 mol/ litre. Equilibrium constant (Kc ) will (A) 10−6 , 4 × 10−9 , 27 × 10−12
be (B) 10−9 , 4 × 10−9 , 32 × 10−12
(A) 9 (B) 18 (C) 10−9 , 8 × 10−8 , 32 × 10−12
(C) 6 (D) 24 (D) None of these

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Q12 In a saturated solution of AgCl, NaCl is added

gradually. The concentration of Ag is plotted
+

against the concentration of Cl . The graph

−

appears as:
(A)
Q15 pK a of NH+
4
is 9.26. Hence, effective range for
NH4 OH −NH4 Cl buffer is about pH :
(A) 8.26 to 10.26 (B) 4.74 to 5.74
(C) 3.74 to 5.74 (D) 8.26 to 9.26
(B)
Q16 Assertion- Mixture of CH3 COOH and
CH3 COONH 4 is not a buffer solution.
Reason- Acidic buffer contains the mixture of
(C)
weak acid and its salt with strong base.
(A) Both assertion and reason are correct and
reason is a correct explanation for assertion
(B) Both assertion and reason are correct and
(D) reason is not a correct explanation for
assertion
(C) Assertion is incorrect, Reason is correct
(D) Both assertion and reason are incorrect

Q13 Solid BaCO3 is gradually dissolved in a Q17 Assertion- pH of blood does not change inspite
1.0 × 10
−4
M Na2 CO3 solution. At what of taking acidic foods.
concentration of Ba+2 will a precipitate begin to Reason- Blood behaves as buffer solution.
form? (Ksp for BaCO3 = 5.1 × 10
−9
) ; (A) Both assertion and reason are correct and

(A) 4.1 × 10−5 M reason is a correct explanation for assertion

(B) 5.1 × 10 −5 (B) Both assertion and reason are correct and
M

(C) 8.1 × 10−8 M reason is not a correct explanation for

assertion
(D) 8.1 × 10
−7
M
(C) Assertion is incorrect, Reason is correct
Q14 Which one of the following curves represents the (D) Both assertion and reason are incorrect
graph of pH during the titration of NaOH and
HCl ? Q18 Assertion- Borax forms alkaline aqueous

(A) solution.
Reason- Borax is the salt of a weak acid
(H3 BO 3 ) and a strong base (NaOH).
(A) Both assertion and reason are correct and
reason is a correct explanation for assertion
(B)
(B) Both assertion and reason are correct and
reason is not a correct explanation for
assertion
(C) Assertion is incorrect, Reason is correct
(C)
(D) Both assertion and reason are incorrect

Q19 Assertion- The pKa of acetic acid is lower than

that of phenol.
(D)

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Reason- Phenoxide ion is more resonance

Column-I Column-II
stabilized.
(A) Both assertion and reason are correct and Degree of ionization of
reason is a correct explanation for assertion Common ion
(a) weak electrolytes (p)
(B) Both assertion and reason are correct and effect
increases
reason is not a correct explanation for
pH of water decreases
assertion (b) (q) pH = 4
on
(C) Assertion is correct , Reason is incorrect
The solution has
(D) Both assertion and reason are incorrect
hydronium ion
(c) (r) Heating
Q20 Assertion- Solubility of sparingly soluble salt concentration of
decreases due to common ion effect. 0.0001 mol/litre
Reason- Solubility product constant does not The addition of NaOH
depend on common ion effect. (d) to Ca(OH)2 solution (s) On dilution
(A) Both assertion and reason are correct and precipitates Ca(OH)2
reason is a correct explanation for assertion (A) a − s, b − r, c − p, d − q

(B) Both assertion and reason are correct and (B) a − r, b − s, c − q, d − p

reason is not a correct explanation for (C) a − s, b − r, c − q, d − p

assertion (D) a − s, b − q, c − r, d − p

(C) Assertion is incorrect, Reason is correct

(D) Both assertion and reason are incorrect Q23 Match the column I with column II :

Q21 Match the column I with column II : Column-I Column-II

Column-I Column-II
pKb of X– (Ka of HX = 10–
(a) 6
(p) 6.9
The limits of pH values of )
(a) (p) 5 × 10–12
buffer solution
(b) pH of 10–8 M HCl (q) 8

Concentration of [H3O]+ in pH of 10–2 M acetic

(b) (q) Equal
0.001 M Ba(OH)2 (c) solution (Take Ka of (r) 10.7
acetic acid = 1.6 × 10–5)

pOH of a solution
The buffer capacity of a obtained by mixing
solution is maximum when (d) equal volumes of (s) 3.4
(c) (r) 10–14
concentration of salt to solution with pH = 3 and
that of acid is 5
(A) a − p, b − r, c − s, d − q

(B) a − s, b − r, c − q, d − p

(d) Ionic product of water is (s) pKa±1 (C) a − q, b − p, c − s, d − r

(D) a − p, b − q, c − r, d − s
(A) a-s , b-q , c-p , d-r
(B) a-s , b-p , c-r , d-q Q24 For the reversible reaction,
(C) a-p, b-s , c-q , d-r N2 ( g) + 3H2 ( g) ⇌ 2NH3 ( g) + heat ,the
(D) a-s , b-p , c-q , d-r equilibrium shifts in forward direction :
(A) By increasing the concentration of NH3 ( g)
Q22 Match the column I with column II :
(B) By decreasing the pressure

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(C) By decreasing the concentrations of N2 ( g) (A) 0.818 (B) 1.818

and H2 ( g) (C) 1.182 (D) 0.182
(D) By increasing pressure and decreasing
Q30 For the reaction,
temperature
2SO 2 ( g) + O2 ( g) → 2SO 3 ( g) ,
Q25 For the reaction, ΔH = −57.2 kJ mol
−1
and
if Kp = Kc (RT)x .
1 16
SO 2 ( g) + O2 ( g) ⇌ SO 3 ( g) K1 = 1.7 × 10
2

where, the symbols have usual meaning, then the Which of the following statement is incorrect?
value of x is (assuming ideality). (A) The equilibrium constant decreases as the
temperature increases
(A) -1 (B) The addition of inert gas at constant volume
(B) − 12 will not affect the equilibrium constant
(C) 1
(C) The equilibrium will shift in the forward
2

(D) 1 direction as the pressure increases

(D) The equilibrium constant is large suggestive
Q26 For the reaction, A + B ⇌ C + D, Kc = 9 . If of reaction going to completion and so no
A and B are taken in equal amounts, then the catalyst is required.
amount of C at equilibrium is:
(A) 1 (B) 0.25 Q31 The standard Gibbs energy change at 300 K for
(C) 0.75 (D) None of these the reaction, 2 A ⇌ B + C is 2494.2 J. At a
given time, the composition of the reaction
Q27 Consider the following reversible chemical mixture is [A] =
1
, [B] = 2 and [C ] =
1
. The
2 2
reaction, reaction proceed in the
k1

A2 (g) + B 2 (g) ⇌ 2 AB(g) . . . . (i) (R = 8.314JK/mol, e = 2.718)

(A) forward direction because Q > Kc

K2

6 AB(g) ⇌ 3A2 (g) + 3B 2 (g) . . . . (ii) (B) reverse direction because Q > Kc

(C) forward direction because Q < Kc

The relation between K1 and K2 is
(D) reverse direction because Q < Kc
(A) K2 = K
3
1

(B) K1 K2 = 3 Q32 If the equilibrium constant for

(C) K2 = K
−3

1
N2 ( g) + O2 ( g) ⇌ 2NO(g) is K, the
(D) K1 K2 =
1
equilibrium constant for
3
1 1
N2 (g) + O 2 (g) ⇌ NO(g) will be,
Q28 For a given exothermic reaction, Kp and K′p are
2 2

(A) K 1/2

the equilibrium constants at temperatures T1 and

(B) 1
K
T2, respectively. Assuming that heat of reaction is 2

(C) K
constant in temperature range between T1 and
(D) K2
T2, it is readily observed that
(A) Kp > K
′
p
Q33 Ag
+
+ NH3 ⇌ [Ag (NH3 ) ]
2
+
; K1 = 3. 5

(B) Kp < K
′
p × 10
−3

(C) Kp
′ + +
= K [Ag(NH3 )] + NH3 ⇌ [Ag (NH3 ) ] ; K2
p 2

(D) Kp =
1
−3
Kp
′
= 1. 7 × 10

then, the formation constant of [Ag(NH3 )2 ] is

+

Q29 The equilibrium constant at 298 K for a reaction, (A) 6.08 × 10

−6

A + B ⇌ C + D is 100. If the initial (B) 6.08 × 106

concentration of all the four species were 1M (C) 6.08 × 10−9
each, then equilibrium concentration of D (in (D) None of these
molL
−1
) will be

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Q34 Using the Gibbs energy change, Both Assertion and Reason are false
for the following reaction, statements
o
ΔG = +63.3 kJ

the
+ 2−
Ag CO3 ( s) ⇌ 2Ag (aq) + CO (aq)
2 3
Q39 Assertion: For the reaction
of Ag2 CO3 ( in water at 25 is
∘
Ksp s) C
−1 −1 A(g) ⇌ B(g) + C(g), Kp = 1 atm . If we
(R = 8.314JK mol )
start with equal moles of all gases at 9 atm of
(A) 3.2 × 10
−26

initial pressure, then at equilibrium partial

(B) 8.0 × 10−12
pressure of A increases.
(C) 2.9 × 10−3
(D) 7.9 × 10−12
Reason: Reaction quotient Qp > Kp hence
Q35 Consider the following equilibrium in a closed equilibrium shifts in the backward direction.
container N2 O4 ( g) ⇌ 2NO2 ( g) (A) Both Assertion and Reason are true and the
At a fixed temperature, the volume of the Reason is the correct explanation of the
reaction container is halved. For this change, Assertion
which of the following statements hold true (B) Both Assertion and Reason are true but the
regarding the equilibrium constant (Kp ) and Reason is not the correct explanation of the
degree of dissociation (α) ? Assertion
(A) Neither Kp nor α changes (C) Assertion is false statement but Reason is true
(B) Both Kp and α change (D) Both Assertion and Reason are false
(C) Kp changes but α not change statements
(D) Kp not change but α changes
Q40 Assertion: The active mass of pure solid and pure
Q36 If the concentration of OH ions in the reaction,
−
liquid is taken unity.
Fe(OH)3 ( s) ⇌ Fe
3+
(aq) + 3OH
−
(aq) is Reason: The active mass of pure solids and
decreased by 1/4 times, then equilibrium liquids depends on density and molecular mass.
concentration of Fe
3+
will increase by The density and molecular mass of pure liquids
(A) 8 times (B) 16 times and solids are constant.
(C) 64 times (D) 4 times (A) Both Assertion and Reason are true and the
Reason is the correct explanation of the
Q37 The incorrect match in the following is
Assertion
(A) ΔGo < 0, K > 1
(B) Both Assertion and Reason are true but the
(B) ΔGo = 0, K = 1
Reason is not the correct explanation of the
(C) ΔGo > 0, K < 1
Assertion
(D) ΔGo < 0, K < 1
(C) Assertion is true statement but Reason is false
Q38 Assertion: The equilibrium of (D) Both Assertion and Reason are false
A(g) ⇌ B(g) + C(g) is not affected by statements
changing the volume.
Q41 Assertion: For the reaction
Reason: Kc for the reaction does not depend on
H2 ( g) + I2 ( g) ⇌ 2HI(g) , if the volume of
volume of the container.
vessel is reduced to half of its original volume,
(A) Both Assertion and Reason are true and the
the equilibrium concentration of all gases will be
Reason is the correct explanation of the
doubled.
Assertion
Reason: According to Le Chateliers principle, the
(B) Both Assertion and Reason are true but the
reaction shifts in a direction that tends to
Reason is not the correct explanation of the
minimize the effect of the stress.
Assertion
(A) Both Assertion and Reason are true and the
(C) Assertion is true statement but Reason is false
Reason is the correct explanation of the
(D)

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Assertion List – I List – II

(B) Both Assertion and Reason are true but the ΔG > 0, K
(A) Equilibrium (I)
Reason is not the correct explanation of the < 1

Assertion Spontaneous
(B) (II) ΔG = 0
(C) Assertion is true statement but Reason is false reaction
(D) Both Assertion and Reason are false Non-
statements (C) spontaneous (III)
ΔG < 0, K

> 1
reaction
Q42 Assertion: The catalyst does not alter the
equilibrium constant. Choose the correct answer from the options

Reason: For the catalysed reaction and given below:

uncatalyzed reaction, ΔH remains the same and (A) A-II , B-III , C-I
the equilibrium constant depends on ΔH. (B) A-I , B-II , C-III

(A) Both Assertion and Reason are true and the (C) A-II , B-I , C-III
Reason is the correct explanation of the (D) A-III , B-I , C-II
Assertion
Q45 Match the column I (equilibria) with the column II
(B) Both Assertion and Reason are true but the
(condition).
Reason is not the correct explanation of the
Column – I Column –II
Assertion
(C) Assertion is true statement but Reason is false
(a) Liquid ⇌ Vapour (p) Saturated solution
(D) Both Assertion and Reason are false
statements (b) (q) Boiling point
Solid ⇌ Liquid
Q43 Match the column I ( Condition) with column II (
(c) Solid ⇌ Vapour (r) Sublimation point
Effect ) :

Solute (s) ⇌ Solute

Column – I Column –II (d) (s) Melting point
(solution)

Reaction is nearer to Unsaturated

(a) Q=K (p) (t)
completion solution

(b) Q>K (q) Reaction at equilibrium (A) a-(q) , b-(s) , c-(r) , d-(p)
(B) a-(p) , b-(q) , c-(r) , d-(t)
Reaction will move in (C) a-(t) , b-(s) , c-(r) , d-(q)
(c) Q<K (r) backward direction to (D) a-(s) , b-(t) , c-(r) , d-(p)
achieve equilibrium
Q46 For the reaction:
Reaction will move in
N2 ( g) + 3H2 ( g) → 2 NH3 ( g)
(d) K >>> 1 (s) forward direction to
2
[NH3 ]
achieve equilibrium Equilibrium constant Kc =
3
[ N 2][H2 ]

Some reactions are written below in column I and

(A) a-q , b-s , c-r , d-p their equilibrium constants in terms of Kc in
(B) a-p , b-q , c-r , d-s column II. Match the following reactions with the
(C) a-p , b-r , c-s , d-q corresponding equilibrium constant.
(D) a-q , b-r , c-s , d-p Column – I Column –II

Q44 Match the column I ( Type of reaction ) with (Reaction) (Equilibrium

column II ( Effect on ΔG and K ) : constant)

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(C) Statement I is incorrect but statement II is

2N2(g) + 6H2(g) ⇌
(a) (p) 2Kc correct
4 NH3(g)
(D) Both statement I and II are incorrect.
2NH3(g) ⇌ N2(g) +
(b) (q) 1/2

3H2(g)
Kc
Q50 Statement-I : For the reaction,

1
CH3COOH(l) + C2H5OH(l) ⇌ CH3COOC2H5 (l) +
N2 (g)
2 H2O (l),
1
(c) +
3
H2 (g) (r) Kc 1 mole each of acid and alcohol were taken
2

⇌ NH3 (g)
initially. At equilibrium, 2

3
mole of ester will be
formed if Kc = 4.
(s) Kc
2
Statement-II : Concentration terms of solids and
pure liquids are included in the expression of
(A) a-p , b-q , c-r
equilibrium constant.
(B) a-s , b-p , c-r
(A) Both statement I and II are correct
(C) a-s , b-r , c-q
(B) Statement I is correct but statement II is
(D) a-p , b-q , c-s
incorrect
Q47 Statement-I: The active mass of 64 gm of HI in a (C) Statement I is incorrect but statement II is
two litre flask would be 0.25. correct
Statement-II: The active mass is always equal to (D) Both statement I and II are incorrect.
molar concentration.
Q51 Statement-I : If Q = Keq then, ΔGo = 0 for any
(A) Both statement I and II are correct.
reversible reaction.
(B) Statement I is correct but statement II is
Statement-II : ΔGo = 0 is essential condition for a
incorrect
reversible reaction at equilibrium.
(C) Statement I is incorrect but statement II is
(A) Both statement I and II are correct
correct
(B) Statement I is correct but statement II is
(D) Both statement I and II are incorrect.
incorrect
Q48 Statement-I : If value of reaction quotient is (C) Statement I is incorrect but statement II is
greater than KC , it means reaction is proceeding correct
in backward direction. (D) Both statement I and II are incorrect.
Statement-II : KC value is definite for any
Q52 Statement-I : At constant pressure, addition of
reaction at particular temperature while reaction
an inert gas in aqueous solution of reversible
quotient may be variable.
reaction does not disturb the equilibrium.
(A) Both statement I and II are correct
Statement-II : Concentration change and
(B) Statement I is correct but statement II is
temperature change does affect the equilibrium
incorrect
of aqueous solution of reversible reaction.
(C) Statement I is incorrect but statement II is
(A) Both statement I and II are correct
correct
(B) Statement I is correct but statement II is
(D) Both statement I and II are incorrect.
incorrect
Q49 Statement-I : If HI(g) is 30% dissociated at 2 atm, (C) Statement I is incorrect but statement II is
its degree of dissociation at 5 atm would be 0.3. correct
Statement-II : Degree of dissociation of HI would (D) Both statement I and II are incorrect.
be independent of pressure.
Q53 Statement-I : HI is more acidic than HBr.
(A) Both statement I and II are correct
Statement-II : Stronger acid has weaker
(B) Statement I is correct but statement II is
conjugate base.
incorrect
(A) Both statement I and II are correct

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(B) Statement I is correct but statement II is Statement-II : Solutions of salt of strong acid and
incorrect strong base are neutral.
(C) Statement I is incorrect but statement II is (A) Both statement I and II are correct
correct (B) Statement I is correct but statement II is
(D) Both statement I and II are incorrect. incorrect
(C) Statement I is incorrect but statement II is
Q54 Statement-I : The degree of dissociation of pure
correct
water at 25˚C is 1.8×10-9.
(D) Both statement I and II are incorrect.
Statement-II : Auto-ionization of water is an
endothermic reaction. Q58 Statement-I : A solution of ammonium acetate is
(A) Both statement I and II are correct neutral buffer.
(B) Statement I is correct but statement II is Statement-II : pKb value of NH4OH is equal to
incorrect pKa value of CH3COOH.
(C) Statement I is incorrect but statement II is (A) Both statement I and II are correct
correct (B) Statement I is correct but statement II is
(D) Both statement I and II are incorrect. incorrect
(C) Statement I is incorrect but statement II is
Q55 Statement-I : NaOH base will apply common ion
correct
effect on the ionization of HCN in same solution.
(D) Both statement I and II are incorrect.
Statement-II : When strong base e.g. NaOH is
added to the weak acid e.g. acetic acid, Q59 Statement-I : Aqueous solution of CH3COONH4,
CH3COOH, then dissociation of acetic acid NaHS and NH4HS act as buffer solution.
increases; this effect is known as reverse ion Statement-II : pH of aqueous solution of
effect. CH3COONH4, NaHS and NH4HS do not depend
(A) Both statement I and II are correct upon concentration.
(B) Statement I is correct but statement II is (A) Both statement I and II are correct
incorrect (B) Statement I is correct but statement II is
(C) Statement I is incorrect but statement II is incorrect
correct (C) Statement I is incorrect but statement II is
(D) Both statement I and II are incorrect. correct
(D) Both statement I and II are incorrect.
Q56 Statement-I : HCl acid will apply common ion
effect on the ionization of HCN. Q60 Statement-I : Solubility of sparingly soluble salt
Statement-II : Degree of ionization of HCN is is decreased by adding common ion containing
increased in presence of HCl. salt of strong acid and strong base.
(A) Both statement I and II are correct Statement-II : Adding common ion in solution of
(B) Statement I is correct but statement II is sparingly soluble salt, equilibrium move towards
incorrect precipitation.
(C) Statement I is incorrect but statement II is (A) Both statement I and II are correct
correct (B) Statement I is correct but statement II is
(D) Both statement I and II are incorrect. incorrect
(C) Statement I is incorrect but statement II is
Q57 Statement-I : NaCl does not increase the degree
correct
of ionisation of water.
(D) Both statement I and II are incorrect.

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Answer Key
Q1 (B) Q31 (B)

Q2 (A) Q32 (A)

Q3 (A) Q33 (A)

Q4 (D) Q34 (B)

Q5 (A) Q35 (D)

Q6 (A) Q36 (C)

Q7 (A) Q37 (D)

Q8 (A) Q38 (D)

Q9 (A) Q39 (A)

Q10 (A) Q40 (A)

Q11 (A) Q41 (B)

Q12 (C) Q42 (A)

Q13 (B) Q43 (D)

Q14 (B) Q44 (A)

Q15 (A) Q45 (A)

Q16 (A) Q46 (C)

Q17 (A) Q47 (B)

Q18 (A) Q48 (A)

Q19 (C) Q49 (A)

Q20 (B) Q50 (B)

Q21 (D) Q51 (D)

Q22 (C) Q52 (A)

Q23 (C) Q53 (A)

Q24 (D) Q54 (A)

Q25 (B) Q55 (C)

Q26 (C) Q56 (B)

Q27 (C) Q57 (A)

Q28 (B) Q58 (A)

Q29 (B) Q59 (A)

Q30 (D) Q60 (A)

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