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    lucas
    The document discusses calculating properties of naphthalene using the Clausius-Clapeyron equation. It then: (1) Calculates the enthalpy of vaporization of naphthalene as 49095 J/mol using vapor pressure and temperature data. (2) Calculates the normal boiling point of naphthalene as 488K. (3) Calculates the enthalpy of vaporization at the boiling point as 49072 J/mol. It also calculates the melting point of ice under 50 bar of pressure as 272.80K.

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    Presentation 2

    Uploaded by

    lucas
    493 views9 pages
    The document discusses calculating properties of naphthalene using the Clausius-Clapeyron equation. It then: (1) Calculates the enthalpy of vaporization of naphthalene as 49095 J/mol using vapor pressure and temperature data. (2) Calculates the normal boiling point of naphthalene as 488K. (3) Calculates the enthalpy of vaporization at the boiling point as 49072 J/mol. It also calculates the melting point of ice under 50 bar of pressure as 272.80K.

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    The document discusses calculating properties of naphthalene using the Clausius-Clapeyron equation. It then: (1) Calculates the enthalpy of vaporization of naphthalene as 49095 J/mol using vapor pressure and temperature data. (2) Calculates the normal boiling point of naphthalene as 488K. (3) Calculates the enthalpy of vaporization at the boiling point as 49072 J/mol. It also calculates the melting point of ice under 50 bar of pressure as 272.80K.

    Copyright:

    © All Rights Reserved
    Download as PPTX, PDF, TXT or read online from Scribd
    Download as pptx, pdf, or txt
    493 views9 pages

    Presentation 2

    Uploaded by

    lucas
    The document discusses calculating properties of naphthalene using the Clausius-Clapeyron equation. It then: (1) Calculates the enthalpy of vaporization of naphthalene as 49095 J/mol using vapor pressure and temperature data. (2) Calculates the normal boiling point of naphthalene as 488K. (3) Calculates the enthalpy of vaporization at the boiling point as 49072 J/mol. It also calculates the melting point of ice under 50 bar of pressure as 272.80K.

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    You are on page 1of 9

    Naphthalene, C10H8, melts at 80.2°C.

    If the vapour pressure of the


    liquid is 1.3 kPa at 85.8°C and 5.3 kPa at 119.3°C.
    Use the Clausius–Clapeyron equation to calculate :
    (a) The enthalpy of vaporization
    (b) The normal boiling point
    (c) The enthalpy of vaporization at the boiling point
    6.9 (A) Diketahui
    R : 8.3145 J/K Mol
    P-1 : 10 Torr = 1.3 × 103 Pa
    P-2 : 50 Torr = 5.3 × 103 Pa
    T-1 : 85.8°C = 358.8 K
    T-2 : 119.3°C = 392.3 K
    𝑑𝑃 ∆𝑆 𝑑𝑃 ∆𝐻
    = =
    𝑑𝑇 ∆𝑉 𝑑𝑇 𝑇∆𝑉
    𝑑𝑃 ∆𝐻𝑃
    =
    𝑑𝑇 𝑅𝑇 2
    𝑑𝑃 ∆𝐻
    CLASIUS = 2
    𝑑𝑇
    𝑃 𝑅𝑇
    CLAPEYRON 𝑃2 𝑇2
    𝑑𝑃 ∆𝐻
    න =න 2
    𝑑𝑇
    𝑃1 𝑃 𝑇1 𝑅𝑇

    𝑃2 ∆𝐻 1 1 𝑃2 ∆𝐻 1 1
    ln = − ×( − ቇ ln = ×( − ቇ
    𝑃1 𝑅 𝑇2 𝑇1 𝑃1 𝑅 𝑇1 𝑇2
    𝑃2 ∆𝐻 1 1
    ln = ×( − ቇ
    𝑃1 𝑅 𝑇1 𝑇2
    −1
    THE 𝑃2 1 1
    R × ln × − = ∆𝐻
    𝑃1 𝑇1 𝑇2
    ENTHALPY
    −1
    OF 8.3145 × ln
    5.3 𝑘𝑃𝑎
    ×
    1
    −
    1
    = ∆𝐻
    VAPORIZATI 1.3 𝑘𝑃𝑎 353.2 𝐾 392.3 𝐾

    ON 49095 JΤMol = ∆𝐻
    𝑃2 ∆𝐻 1 1
    ln = ×( − ቇ
    𝑃1 𝑅 𝑇1 𝑇2

    R 𝑃2 1 1
    ൬ × ln ) + =
    THE ∆𝐻 𝑃1 𝑇2 𝑇1
    NORMAL
    8.3145 5.3 𝑘𝑃𝑎 1 1
    BOILING ቆ
    49095 𝐽Τ𝑀𝑜𝑙
    × ln
    101.3 𝑘𝑃𝑎
    )+ =
    392.5 𝐾 𝑇1
    POINT
    1 1
    −3
    = 488 𝐾 = 𝑇1
    2.048 × 10 𝑇1
    𝑃2 ∆𝐻 1 1
    ln = ×( − ቇ
    𝑃1 𝑅 𝑇1 𝑇2
    THE 𝑃2 1 1
    −1
    R × ln × − = ∆𝐻
    ENTHALPY 𝑃1 𝑇1 𝑇2
    OF 5.3 𝑘𝑃𝑎 1 1
    −1

    VAPORIZATI 8.3145 × ln × − = ∆𝐻
    101.3 𝑘𝑃𝑎 488 𝐾 392.3 𝐾
    ON AT THE
    BOILING 49072 JΤMol = ∆𝐻
    POINT
    6.10 (A)
    Calculate the melting point of a cube of ice under a pressure of
    50 bar. Assume that the density of ice under these conditions is
    ca. 0.92 g cm−3 and that of liquid water is 1.00 g cm−3.

    Diketahui :
    P = 50 Bar = 50 X 106 Pa
    d-1 = 0.92 g cm−3
    d-2 = 1.00 g cm−3
    𝑑𝑃 ∆𝑆 𝑑𝑃 ∆𝐻
    = =
    𝑑𝑇 ∆𝑉 𝑑𝑇 𝑇∆𝑉
    𝑑𝑃 × ∆𝑉 𝑑𝑃 × ∆𝑉
    = 𝑑𝑇 න = න 𝑑𝑇
    ∆𝐻 ∆𝐻
    ∆𝑃 × ∆𝑉
    = ∆𝑇
    CLAPEYRON ∆𝐻
    ∆𝑃 × 𝑀 1 1
    × ( − ) = ∆𝑇
    ∆𝐻 𝑃2 𝑃1
    ∆𝑃 × 𝑀 × 𝑇 1 1
    × ( − ) = ∆𝑇
    ∆𝐻 𝑃2 𝑃1
    𝑔
    50 × 106 𝑃𝑎 × 18.02 × 273.15 𝐾 1 1
    𝑚𝑜𝑙 × ( − ) = ∆𝑇
    THE CHANGE 3
    6.01 × 10 𝐽/𝑚𝑜𝑙 1 𝑔/𝑐𝑚 3 0.92 𝑔/𝑐𝑚 3

    IN −0.35 𝐾 = ∆𝑇
    TEMPERATUR
    E
    𝑇 50 𝐵𝑎𝑟 = 273.15 − 0.35 𝐾 = 272.80 𝐾

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