How To Make Pure Gold

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The key takeaways are that the Miller and Wohlwill Processes are two popular techniques used to create pure gold samples for industrial use since pure gold is rarely found in nature. The Miller Process uses chlorine gas to remove impurities while the Wohlwill Process uses electrolysis.

The two main processes described for refining gold are the Miller Process and the Wohlwill Process. The Miller Process is cheaper but the Wohlwill Process can produce even purer gold samples.

The main steps of the Miller Process are to melt the impure gold sample, blow chlorine gas across it to form chlorides from the impurities that rise to the top, and then skim the chlorides off to leave 99.95% pure gold.

How to Make Pure Gold

The Miller and Wohlwill Processes

Manhattan Gold & Silver | 45 W 47th Street | New York, NY 10036 | 212-398-1454
Refining Pure Gold
• Many industries require samples of pure gold.
– However, pure gold is extremely rare in traditional mining.

• Pure gold must be created by professional metal


refiners.

• Two popular techniques for creating pure gold are


the Miller Process and the Wohlwill Process.

2013 © Manhattan Gold & Silver


www.mgsrefining.com | 212-398-1454
Miller Process Materials
• Dr. Francis Bowyer Miller rocked the world of gold
refining when he created a cheap and easy way to
purify gold – the Miller Process.

• The Miller Process requires these components:


– Sample of impure gold
– Induction furnace
– Graphite crucible
– Chlorine gas

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www.mgsrefining.com | 212-398-1454
How the Miller Process Works
• Gold is inert to a majority of chemicals. Its impurities
(such as zinc, copper and iron) are not.

• The first step in the Miller Process is to use an


induction furnace to melt the gold sample in a
crucible.

• Once the sample is liquefied pure chlorine gas is


blown across it.
– This causes the impurities to form chlorides which rise to
the top of the crucible.

2013 © Manhattan Gold & Silver


www.mgsrefining.com | 212-398-1454
How the Miller Process Works
• The final step is to skim the chlorides off the
surface of the melted gold.

• Once the chlorides have been removed the


gold that remains is about 99.95% pure gold…

• But for some applications that isn’t pure


enough.

2013 © Manhattan Gold & Silver


www.mgsrefining.com | 212-398-1454
Wohlwill Process Materials
• Hans Emil Wohlwill developed a method to create
even purer samples of gold – the Wohlwill Process.
– However, it’s much more expensive and complex than
the Miller Process.

• The Wohlwill Process requires:


– An anode – an electrode through which electric current
flows into a polarized electrical device.
– An cathode – an electrode through which electric current
flows out of a polarized electrical device.
– An electrolyte – an electrically conductive substance.

2013 © Manhattan Gold & Silver


www.mgsrefining.com | 212-398-1454
The Anode, Cathode,
and Electrolyte
• Each component is made of gold.

– The anode is made of somewhat impure gold,


about 95% purity or higher. (Lower purity will
reduce the efficiency of the Wohlwill Process).
– The cathode is made out of pure 24k gold sheets.
– The electrolyte is pure chloroauric acid which is
made by dissolving gold in aqua regia.

2013 © Manhattan Gold & Silver


www.mgsrefining.com | 212-398-1454
How the Wohlwill Process Works
• With the components properly arranged an electric
current is applied.

• Electricity travels from the anode through the


conductive electrolyte and into the cathode.
– When this occurs the gold in the impure anode dissolves
and its ions travel through the chloroauric acid then
electroplate or “stick” to the 24k gold cathode.

• This Wohlwill Process continues until the anode is


completely dissolved.
– The pure gold cathode is then melted down to be used.

2013 © Manhattan Gold & Silver


www.mgsrefining.com | 212-398-1454
Miller vs. Wohlwill
• To perform the Wohlwill Process a refiner
must have enough gold for anodes, cathodes
and chloroauric acid.
– It takes gold to make gold.

• Unless ultra-high purity gold is needed the


Miller Process is the preferred way to purify
gold.

2013 © Manhattan Gold & Silver


www.mgsrefining.com | 212-398-1454
About MGS
• Manhattan Gold & Silver (MGS) is a precious metals refiner that has been
based in Manhattan’s historic Diamond District since 1985. We are a B2B
company that buys and recycles precious metal scraps that accumulate in
other businesses.

• We serve:
– Jewelers
– Pawnbrokers
– Dentists
– The industrial sector
– Antique dealers
– Machinists
– And more!

• MGS also creates charts, calculators, and other online tools for our
customers to use.
– Try our Precious Metals Prices app, which lets you monitor the real-time precious metals
market situation from anywhere, right from your iPhone, iPad, or Android device.

Manhattan Gold & Silver | 45 W 47th Street | New York, NY 10036 | 212-398-1454
Recycle your Precious
Metals for Profit
• MGS accepts gold, silver, platinum, and palladium.

• Payouts are based on the London Fixing.

• Up to 99% payout (among the highest in the US)


– Up to 98.5% for gold brought in for hand testing.

• Not in NYC? Ship us your precious metals using our


Ship & Sell service which offers:
– Same day wired payment (once lot is received)
– Discounted, insured shipping
– Payout calculator

Manhattan Gold & Silver | 45 W 47th Street | New York, NY 10036 | 212-398-1454
Connect with MGS
• For amazing facts, history and news, read our gold and precious
metals blog.

• Join the conversation about precious metals on the MGS page on


Facebook.

• Follow gold, silver, and other precious metal trends at the MGS
Twitter account.

• Circle MGS on Google+ to hear our latest updates.

• If you do business with us, connect with us on the MGS LinkedIn


page.

• To see precious metal melting and refinement in action, visit the


MGS YouTube channel.

Manhattan Gold & Silver | 45 W 47th Street | New York, NY 10036 | 212-398-1454

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