Grade 11 Chem Atomic Structure 3

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GRADE 11

UNIT 2 ATOMIC STRUCTURE


Discovery of Electron
• In mid 1850s many scientists mainly Faraday
began to study electrical discharge in partially
evacuated tubes, known as cathode ray
discharge tubes
Cathode ray discharge tube
CATHODE RAYS
• When sufficiently high voltage is applied
across the electrodes, current starts flowing
through a stream of particles moving in the
tube from the negative electrode (cathode) to
the positive electrode (anode).
• These were called cathode rays or cathode ray
particles.
A cathode ray discharge tube with
perforated anode
CATHODE RAYS
• The flow of current from cathode to anode
was further checked by making a hole in the
anode and coating the tube behind anode
with phosphorescent material zinc sulphide.
• When these rays, after passing through anode,
strike the zinc sulphide coating, a bright spot is
developed on the coating.
PROPERTIES OF CATHODE RAYS

The cathode rays start from cathode and


move towards the anode.
(ii) These rays themselves are not visible but
their behaviour can be observed with the
help of certain kind of materials
(fluorescent or phosphorescent) which
glow when hit by them. Television picture
tubes are cathode ray tubes and
television pictures result due to
fluorescence on the television screen
coated with certain fluorescent or
phosphorescent materials.
PROPERTIES OF CATHODE RAYS

In the absence of electrical or magnetic


field, these rays travel in straight lines
.
(iv) In the presence of electrical or magnetic
field, the behaviour of cathode rays are
similar to that expected from negatively
charged particles, suggesting that the
cathode rays consist of negatively
charged particles, called electrons.
ELECTRON
• The characteristics of cathode rays (electrons)
do not depend upon the material of
electrodes and the nature of the gas present
in the cathode ray tube.
• Thus, we can conclude that electrons are basic
constituent of all the atoms.
The charge to the mass ratio of electron
DEVIATIONS
• The magnitude of the • The mass of the particle —
negative charge on the lighter the particle, greater
the deflection.
particle, greater the
• The strength of the electrical
magnitude of the or magnetic field — the
charge on the particle, deflection of electrons from
greater is the its original path increases
interaction with the with the increase in the
electric or magnetic voltage across the
field and thus greater is electrodes, or the strength
of the magnetic field.
the deflection.
The charge to the mass ratio of electron
• Where me is the mass
othe electron in kg and
e is the magnitude of
the charge on the
electron in coulomb (C).
• Since electrons are
negatively charged, the
charge on electron is -e.
MASS OF ELECTRON
• R.A. Millikan (1868-1953) devised a
method known as oil drop
experiment (1906-14), to
determine the charge on the
electrons.
• He found the charge on the
electron to be – 1.6 × 10–19 C.
• The present accepted value of
electrical charge is – 1.602176 ×
10–19 C.
• The mass of the electron (me ) was
determined by combining these
results with Thomson’s value of
e/me ratio.
PROTONS
• Electrical discharge • Unlike cathode rays, mass of
carried out in the positively charged particles
modified cathode ray depends upon the nature of
gas present in the cathode
tube led to the discovery ray tube.
of canal rays carrying • These are simply the
positively charged positively charged gaseous
particles. ions.
• The characteristics of • (ii) The charge to mass ratio
these positively charged of the particles depends on
particles are listed below. the gas from which these
originate.
PROTONS
• (iii) Some of the positively • The smallest and
charged particles carry a lightest positive ion was
multiple of the obtained from hydrogen
fundamental unit of and was called proton.
electrical charge.
• This positively charged
• (iv) The behaviour of
particle was
these particles in the
magnetic or electrical field characterised in 1919
is opposite to that
observed for electron or
cathode rays
Neutrons
• Particles were discovered • He named these
by Chadwick (1932) by particles as neutrons
bombarding a thin sheet
of beryllium by α-particles.
• When electrically neutral
particles having a mass
slightly greater than that
of protons were emitted.
He named these
• particles as neutrons
SUB ATOMIC PARTICLES
ATOM
• Indivisible particle of matter.
• It contains Protons (+) charge , Electrons (-)
charge, Neutrons of no charge
• Atomic number Z = No of protons (or) No of
electrons of the atom
• Mass number A= No of Protons + No of
Neutrons
ATOM
DALTON’S MODEL OF AN ATOM
THOMSON’S MODEL
RUTHERFORD’S α PARTICLES EXPERIMENT
RUTHERFORD’S MODEL
BHOR’S MODEL
LIMITATIONS OF BHOR'S MODEL
DEVELOPMENT OF BHOR'S MODEL
ELECTROMAGNETIC RADIATION
WAVE MOTION
MOTION OF ELECTROMAGENTIC WAVE
SPECTRUM OF RADIATION
SPECTRUM
PARTICLE NATURE OF ELECTROMAGNETIC
RADIATION
CHANGE OF RADIATION
CHANGE OF RADIATION
CHANGE OF RADIATION
QUANTA
QUANTA
WAVE NATURE
PHOTOELECTRIC EFFECT
PHOTOELECTRIC EFFECT
PARTICLE NATURE
PARTICLE NATURE
SPECTRUM
SPECTRUM
EMISSION SPECTRUM
SPECTROSCOPY
SPECTRUM
SPECTRUM
HYDROGEN SPECTRUM
SPECTRAL LINES OF ATOMIC HYDROGEN
LINE SPECTRUM
DEVELOPMENT OF ATOMIC MODEL
RELATION BETWEEN TWO NATURE
UNCERTANITY PRINCIPLE
ADVANTAE OF UNCERTANITY PRINCIPLE
ADVANTAGE OF UNCERTANITY PRICIPLE
INTRODUCTION OF QUANTUM MECHANICS
QUANTUM MECHANICS
ORBITAL
• Orbital is a three dimentional space around
the nuclues where the probability of finding
the electron is maximum
• Orbit =Orbital= Shell
ORBITALS
PRINCIPAL QUANTUM NUMBER
AZIMUTHAL QUANTUM NUMBER
AZIMUTHAL QUANTUM NUMBER

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