1 2 3 4

P 10 1 0.1766474 1.7664744
V 600 600 300 300
T 4.9236 49.236 139.26044 13.926044

1 2 3 4
Q 11486.215 0 -5743.108 0 5743.1077
W 11486.215 3741.3 -5743.108 -3741.3 5743.1077 Cv 12.471
U 0 -3741.3 0 3741.3 0 Cp 20.785
H 0 -6235.5 0 6235.5 0
S 19.143692 0 -19.14369 0 0
n= Eficiencia

n= W total /Q(+)

n= 0.5
 Gas diátomico
Estado 1 Estado 2 Estado 3 Estado 4 n= 2

P (atm) 4.935 1.975 0.987 0.987 R= 0.08206

T (K) 7486.714 5762.843 5762.843 1497.34276 R= 8.3140

V (L) 249 479 958.330 249.000 Cv 5/2R
Cp 7/2R

Adiabatica Isotérmica Isobárica Isocórica Total

Q (J) 0.000 66453.474 -248243.565 248978.154 67188.063

H (J) -100325.85 0 -248243.565 348569.415 0
W (J) 71661.322 66453.474 -70936.456 0.000 67178.340
U (J) -71661.322 0 -177307.108 248978.154 9.7236336
S (J/K) 0.000 11.531371 -78.436 66.904334 0.000

-71661.322 0.000 -177307.108 248978.154

 mol
atmL/mol
K
J/molK
20.785
29.099
 R
(atmL/mol 0.082 0.082
K

T (K) V (L) P (atm) P vs. V

10 2.000 0.410 0.450
10 4.000 0.205
0.400
10 6.000 0.137
0.350
10 8.000 0.103
f(x) = − 0.037022976608187 x + 0.41198758
10 9.000 0.091 0.300 R² = 0.828709895432989
10 10.000 0.082 0.250
0.200
0.150
0.100
0.050
0.000
1.000 2.000 3.000 4.000 5.000 6.000 7.0

1. Gas ideal 2. Calculo de (dP/dV)T

Z= 1.0007317 -0.205
1.0007317 -0.05125
1.0007317 -0.022778
1.0007317 -0.012813
1.0007317 -0.010123
1.0007317 -0.0082
 P vs. V

22976608187 x + 0.411987588693957
895432989

.000 5.000 6.000 7.000 8.000 9.000 10.000 11.000

 Datos Helio Oxígeno
Tc (K) 5.195 154.580
Z(Helio)= Z(oxígeno) Pc (atm) 2.245 50.140

Vc (/Lmol) 0.058 0.080

8.2215664536585 7561.60117073171
a
(L^2atm/ 0.034 0.880
mol^2)
(dP/dV)T Oxigeno b(L/mol) 0.237 0.030
R
(atmL/mol 0.082 0.082
2a 1.76 K
(b-nb)^2 0.0009
0.0002910436 Oxígeno
0.002025 T (K) V (L) P (atm)
0.003025 10 0.060 -5946.113
0.0036 10 0.065 -37175.23
0.0049 10 0.075 -2092.264
10 0.085 -1327.468
RT 12.6848348 10 0.090 -1109.299
10 0.100 -828.7418
 Para calcular P (atm)

Condición
n=1

P vs. V
0
0.055 0.060f(x) =0.065 0.070 0.075
522967.321784708 0.080 0.085 0.090
x − 49481.4319390354 0.095 0.100 0.105
-5000 R² = 0.309775294530768

-10000

-15000

-20000

-25000

-30000

-35000

-40000
Para el agua a presion de una atmosfera y temperatura de 100 °C. Determine la linea de saturacion, volumen del liquido y el v
Teniendo a=5,40*10^6 atm*cm/mol^2 y b= 30,46 cm^3/mol
Gas
Agua
P (atm) 1 a 5.46 L/mol 4.8307896
Temperatur 373.15 b 0.030635 L^2*bar/mol^2
Volumen 30.620689

P= 1.0010015 - 0.0051521
P= 0.9958493
Volumen critico llevado

Liquido
2
Tc 647.126 K
Vc 0.05595 L/mol

P= 2097.6954 - 9.7862815
P= 2087.9091
olumen del liquido y el volumen de un gas a partir de Van der Waals.

Volumen critico llevado a L/mol

P/atm 0.75 0.5 0.25 T/V
Vm*(dm^3*mol^-1) 29.9649 44.809 89.6384 9.1156653
Densidad(g*dm^3) 1.07144 0.71411 0.357965 6.0958736
3.0472431

R= 0.0820053 0.0820264 0.0818179 0.0819499

P vs. T/
Gráfico P vs T/V 0.8

0.7 f(x) = 0.082393119823307 x − 0.001

R² = 0.999992472065274
0.6

0.5

0.4

0.3

0.2

0.1

0
2 3 4 5 6
 P
0.75
0.5
0.25

P vs. T/V

0.082393119823307 x − 0.001466006335916
999992472065274

4 5 6 7 8 9 10
T Benceno 72.3106 °C P= 594 mmHg
T Tolueno 102.16 °C

Benceno Tolueno
A 6.90565 6.95334 Rango 2.98
B 1211.033 1343.943
C 220.79 219.377

120
Temperatura PA ben PB tol Xa Xb Ya Yb
72.3106 594.08721 221.751269 0.99976578 0.0002342 0.99991256 8.7439E-05
100
75.2906 653.78665 246.866359 0.85307527 0.1469247 0.93893809 0.06106191
78.2706 718.11357 274.236143 0.72038774 0.2796123 0.87090945 0.12909055 80
81.2506 787.31038 304.00603 0.6000235 0.3999765 0.79529416 0.20470584
84.2306 861.62474 336.326499 0.49052801 0.509472 0.71153379 0.28846621 60
87.2106 941.30927 371.353037 0.3906387 0.6093613 0.61904349 0.38095651
90.1906 1026.6214 409.246062 0.2992571 0.7007429 0.51721166 0.48278834 40

93.1706 1117.8229 450.170851 0.21542531 0.7845747 0.40539957 0.59460043

20
96.1506 1215.1801 494.29744 0.13830623 0.8616938 0.28294104 0.71705896
99.1306 1318.963 541.800535 0.06716673 0.9328333 0.14914215 0.85085785 0
102.1106 1429.4457 592.859393 0.00136341 0.9986366 0.003281 0.996719 0 0.2

120

100

80

60

40

20

0
0 0.2
 T vs YA & XA
20

00

80

60

40

20

0
0 0.2 0.4 0.6 0.8 1 1.2

T vs YB & XB
20

00

80

60

40

20

0
0 0.2 0.4 0.6 0.8 1 1.2
 1 Benceno Diagramas a T=100°C A B
2 Tolueno 1 6.90565 1211.033
2 6.95334 1343.943
1 2 Temperatura
A 6.90565 6.95334 100 °C
B 1211.033 1343.943
C 220.79 219.377

XA XB P1=XA*PA° P2=XB*PA°Ptotal YA=P1/Pt YB=P2/Pt

0 1 0 556.32125 556.32125 0 1
0.1 0.9 135.04913188 500.68908 635.73821 0.2124288 0.7875712
0.2 0.8 270.09826376 445.05696 715.15522 0.3776778 0.6223222
0.3 0.7 405.14739564 389.42484 794.57224 0.5098937 0.4901063
0.4 0.6 540.19652753 333.79272 873.98925 0.6180814 0.3819186
0.5 0.5 675.24565941 278.1606 953.40626 0.7082455 0.2917545
0.6 0.4 810.29479129 222.52848 1032.8233 0.7845435 0.2154565
0.7 0.3 945.34392317 166.89636 1112.2403 0.8499458 0.1500542
0.8 0.2 1080.3930551 111.26424 1191.6573 0.9066307 0.0933693
0.9 0.1 1215.4421869 55.63212 1271.0743 0.9562322 0.0437678
1 0 1350.4913188 0 1350.4913 1 0

XA vs P1, P2, PT XB
1600
1600
1400
1400
1200 1200
1000 1000
800 800
600 600

400 400

200 200

0 0
0 0.2 0.4 0.6 0.8 1 1.2 0 0.2 0.4

YA vs PT, P2, P1 YB
1600 1600

1400 1400

1200 1200

1000 1000

800 800

600 600

400 400
1400 1400

1200 1200

1000 1000

800 800

600 600

400 400

200 200

0 0
0 0.2 0.4 0.6 0.8 1 1.2 0 0.2 0.4
 T+C logPA Pao
320.79 3.1304918 1350.4913
319.377 2.7453256 556.32125

10

556.3212

XB vs P1, P2, PT

0.2 0.4 0.6 0.8 1 1.2

YB vs PT, P2, P1
0.2 0.4 0.6 0.8 1 1.2
pxy
tolue + benz @ T=100 (C)
~ T=1,770995
1.770995 0 0 1.8

1.750282 0.02 0.0084021

1.729567 0.04 0.0170054
1.708854 0.06 0.0258173 1.6

1.688139 0.08 0.0348454

1.667426 0.1 0.0440979
1.646712 0.12 0.0535831
1.4
1.625998 0.14 0.06331
1.605284 0.16 0.0732879

Pressure (atm)
1.58457 0.18 0.0835266
1.563856 0.2 0.0940367 1.2

1.543142 0.22 0.104829

1.522428 0.24 0.115915
1.501714 0.26 0.127306 1.0

1.481001 0.28 0.139017

1.460286 0.3 0.151059
1.439573 0.32 0.163448
0.8
1.418858 0.34 0.176199
1.398145 0.36 0.189328
1.377431 0.38 0.202851 0.0 0.2 0.4 0.6

x tolue

1.356717 0.4 0.216788

1.336003 0.42 0.231156
1.315288 0.44 0.245978
1.294575 0.46 0.261273
1.273861 0.48 0.277066
1.253147 0.5 0.293381
1.232433 0.52 0.310244
1.21172 0.54 0.327684
1.191005 0.56 0.345731
1.170292 0.58 0.364416
1.149577 0.6 0.383775
1.128864 0.62 0.403845
1.10815 0.64 0.424664
1.087435 0.66 0.446277
1.066722 0.68 0.468729
1.046007 0.7 0.49207
1.025294 0.72 0.516355
1.00458 0.74 0.541641
0.983866 0.76 0.567991
0.963152 0.78 0.595475
0.942438 0.8 0.624167
0.921724 0.82 0.654149
0.90101 0.84 0.685509
0.880296 0.86 0.718346
0.859582 0.88 0.752764
0.838868 0.9 0.788883
0.818154 0.92 0.82683
0.79744 0.94 0.866749
0.776726 0.96 0.908797
0.756012 0.98 0.953149
0.735298 1 1
 X tolueno vs. Presion

0.6 0.8 1.0

x tolue
Txy
~ p=103,363 benz + tolu @ p=0.7815 (atm)

103.363 0 0
102.439 0.02 0.0459662
101.534 0.04 0.0898181
100.649 0.06 0.131676 100

99.78302 0.08 0.171651

98.935 0.1 0.20985
98.104 0.12 0.24637 95

97.29102 0.14 0.281303

96.49402 0.16 0.314735

Temperature (C)
95.71402 0.18 0.346748 90

94.94901 0.2 0.377417

94.19901 0.22 0.406813
93.46402 0.24 0.435003 85

92.74301 0.26 0.462048

92.03601 0.28 0.488009
91.34201 0.3 0.51294 80

90.66101 0.32 0.536892

89.99301 0.34 0.559916
89.33801 0.36 0.582056 75

88.694 0.38 0.603356

88.06201 0.4 0.623856 0.0 0.2 0.4 0.6

87.44101 0.42 0.643595 x benz

86.83099 0.44 0.662609

86.23199 0.46 0.680933
85.64301 0.48 0.698597
85.064 0.5 0.715634
84.495 0.52 0.732071
83.936 0.54 0.747935
83.38602 0.56 0.763253
82.84399 0.58 0.778048
82.31201 0.6 0.792343
81.78799 0.62 0.806161
81.27301 0.64 0.819521
80.76501 0.66 0.832444
80.26599 0.68 0.844948
79.77402 0.7 0.85705
79.29001 0.72 0.868767
78.81302 0.74 0.880115
78.34302 0.76 0.89111
77.88 0.78 0.901764
77.42401 0.8 0.912092
76.974 0.82 0.922107
76.53101 0.84 0.931822
 76.095 0.86 0.941247
75.664 0.88 0.950394
75.24002 0.9 0.959273
74.82101 0.92 0.967896
74.40802 0.94 0.976271
74.00101 0.96 0.984407
73.60001 0.98 0.992314
73.203 1 1
 Xbenceno vs Temperatura

0.6 0.8 1.0

x benz
Ecuación cúbica Funcion objetivo Solver
AX^3+BX^2+CX+ D

Valor X 1.392797 Valor X 0

Coeficientes
A B C D
1 -2 3 -3 0.0004878 -3
Xi (ac) Yi (ac) P (torr) gamai (ac)
gamai (clo) Pacetona Pcloroformo Σ acetona
0 0 293 0 1 0 293 0
0.0821 0.05 279.5 0.49410521 0.98728475 13.975 265.525 -0.263116
0.2003 0.1434 262 0.544477913 0.95782164 37.5708 224.4292 -0.443838
0.3365 0.3171 249 0.681116332 0.87467741 78.9579 170.0421 -0.495725
0.4188 0.4368 248 0.750824458 0.82020252 108.3264 139.6736 -0.484529
0.5061 0.5625 255 0.822691753 0.77092404 143.4375 111.5625 -0.443442
0.6034 0.6868 267 0.882159298 0.71963567 183.3756 83.6244 -0.380478
0.709 0.8062 286 0.944002981 0.65006861 230.5732 55.4268 -0.284682
0.8147 0.8961 307 0.98018468 0.58750408 275.1027 31.8973 -0.183266
0.9397 0.9715 332 0.996328229 0.53554752 322.538 9.462 -0.061901
1 1 344.5 1 0 344.5 0 0
(1-ac y clo)
P (clor pur 293
P (ac) puro 344.5

Xi vs Pi
400 1.2

350
1
300
0.8
250

200 0.6

150
0.4
100
0.2
50

0 0
0 0.2 0.4 0.6 0.8 1 1.2 0 0.2 0.

Xi vs GE
0 2
0 0.2 0.4 0.6 0.8 1 1.2
1.8
-100 1.6
1.4
-200
1.2
-300 1
0.8
-400
0.6
-500 0.4
0.2
-600
0
0 0.2 0.4
0 Column J Column M
 Σ cloroformo GE Σ acetona Σ clorofor GE normal SE SE normal HE HE normal
0 0 0 0 0 0 0 0 0
-0.0903797484 -216.9351 -0.205235 -0.078634 -174.2059 0.7023962 0.5640469 0 0
-0.2132098715 -403.2205 -0.32207 -0.178748 -307.3445 1.3055544 0.9951254 0 0
-0.3610279696 -525.7763 -0.366501 -0.272185 -391.9524 1.7023678 1.2690703 0 0
-0.4305903527 -561.5948 -0.364508 -0.315394 -417.2455 1.8183415 1.3509647 0 0
-0.4769037339 -564.8024 -0.344665 -0.348408 -425.3283 1.8287272 1.3771356 0 0
-0.4972718595 -538.6622 -0.304823 -0.366786 -412.1563 1.7440899 1.334487 0 0
-0.4845468289 -472.064 -0.243825 -0.35922 -370.0794 1.5284571 1.1982497 0 0
-0.4109307752 -364.6499 -0.166961 -0.312375 -294.1611 1.1806699 0.95244 0 0
-0.2070031966 -165.0224 -0.058444 -0.169348 -139.7926 0.5343126 0.4526231 0 0
0 0 0 0 0 0 0 0 0

Xi (ac) Yi (ac)

R= 1.987
Xi vs Gama T= 308.85
1.2 GE /n = RTΣXi. Ln ᵞi.xi
G de exceso
1

0.8

0.6

0.4

0.2

0
0 0.2 0.4 0.6 0.8 1 1.2

Xi vs SE
2
1.8
1.6
1.4
1.2
1
0.8
0.6
0.4
0.2
0
0 0.2 0.4 0.6 0.8 1 1.2
HE normal

Error ley de Raoult

HE

P (torr)
P total