Wastewater Treatment Report
Wastewater Treatment Report
Wastewater Treatment Report
ON
Environment
Impact Assessment of DHDS
&
Effluent Treatment Plant (ETP)
OF
Ammara Haider
INTERNEE NO.
117
DEPARTMENT
Technical Services
SUBMITTED TO:
NAME
Zuhair Sadiq
DESIGNATION
Process Engineers
DEPARTMENT
TECHNICAL SERVICES
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IN THE NAME OF
ALLAH
The Most Gracious,
The Most Merciful.
Whose Help We Solicit
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DEDICATED TO
My loving Parents, their
un-returnable
patience,
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ACKNOWLEDGEMENT
All praise to ALMIGHTY ALLAH, who provided me with the
strength to accomplish this orientation report. All respects are
for His HOLY PROPHET (PBUH), whose teachings are true
source of knowledge & guidance for whole mankind.
Before anybody else I thank my Parents who have always
been a source of moral support, driving force behind
whatever I do. I am indebted to my trainers Zuhair Sadiq
(Process Engineer) and Syed Mahmood Mehdi
(Process Engineer) for their worthy discussions,
encouragement, technical discussions, inspiring guidance,
remarkable suggestions, keen interest, constructive criticism
& friendly discussions which enabled me to complete this
report. They spared a lot of precious time in advising &
helping me in writing this report.
I am also thankful to Mrs. Khalida Mudassir (In charge
Library) for her cooperation in search of material.
Internee
Ammara Haider
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PREFACE
Today faced with increased rivalry among the
major competitors, it is mandatory for an
organization to engage in quality practices,
primarily to maintain its existence in competitive
environment and secondary to gain competitive
advantage over its competitors. One could argue
that it is virtually impossible for organizations to
function effectively without quality practices. The
quality practices not only improve the corporate
value but also canalize the energy of the people
working there. In most of the contemporary
organizations, regardless of the strong financial
position, substantial growths are not achieved
due to poor quality practices.
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TABLE OF CONTENTS
1.
General Information 7
2.
Utilities Introduction.9
3.
4.
Additional Assignments..22
5.
6.
P&ID..36
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GENERAL INFORMATION
Introduction:
Pak Arab Refinery Limited:
(A national organization with an internal presence)
PARCO is a joint venture between Government of Pakistan and Abu Dhabi. The MCR
(Mid-Country Refinery) was established in 2000 but the organization is about thirty
years old. Before the MCR the organization only served to pump HSD to various part
of the country via pipelines from Karachi. To fulfill the needs of the country a refinery
needed to be established. Thus the MCR was established.
For the PARCO, MCR crude oil is being imported from Middle east i.e. Arabian Light,
Upper Zakum, and Murban. Local crude oil and local condensate are also used. The
crude is being transported through Karachi-Mahmood kot pipeline. In 2005, white oil
pipeline was commissioned from Karachi to Mahmood kot to transport diesel.
Process Units with their Design Capacities:
Capacity is the minimum rate of output for a facility
The Refinery complex includes 11 onsite units process units besides numerous off
site / utilities units and other permanent facilities with 51 tanks to store the Crude oil,
intermediate feeds stocks and finished products.
S. No.
Unit Code
Units
BPSD
1
2
3
4
5
100
110
130
200
284
300
Crude Distillation
Vacuum Distillation
Visbreaker
Naphtha Hydrotreater
Dieselmax *
CCR Platformer &
Cyclemax CCR
411
Gas Concentration
8
9
801
802
Kerosene Merox
LPG Merox
10
810
Amine Treating
11
820
Sulphur Recovery
100,000
42,800
15,560
25,400
22,450
16,350
1,000 lb/hr (454 kg/hr)
Liquid: 22,050
Gas: 12,548 Nm3/hr
20,000
4,500
F.G: 8,618 Nm3/hr
SWS: 76 SM3/hr
115 MTPD
* Dieselmax Process Unit (Mild Hydrocracking with Thermal Cracking) for maximizing
HSD production at Relatively Low cost.
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Utilities:
The utilities at MCR consist of the following units.
S. No.
Unit No.
Unit Name
900
910
915
Flare System
920
925
Water System
926
940
Steam System
930
ETP
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Plant and Instrument Air is supplied by the two equal size centrifugal
compressors, one operating and one spare. The compressor capacity is
determined in such a way that one compressor can supply the air demand at
normal operation. In the case of Diesel max Regeneration Operation, both
compressors will be run in parallel. One compressor is motor driven, and the
other one steam turbine driven.
Plant and Instrument Air System will include adequate facilities to provide
required quantities of instrument air and plant air at uses.
3.
ii)
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4.
The fuel gas system is designed to collect process unit off gas, natural gas and
vaporized LPG. All sources of gas are routed to knockout drum which provides
liquid knockout and mixing.
One LPG vaporizer is provided to make fuel gas and to dispose of off- spec or
excess LPG. Off spec LPG is produced at start up of Gas Concentration Init,
LPG Merox Unit and CCR Plat forming Unit and sent to LPG Vaporizer.
The priority of fuel gas sources is as follows:
Normal Operation:
Primary Makeup :
Secondary Makeup:
5.
i)
Raw Water
Water is readily available in the area from shallow wells with a capacity
of about 100 m3/hr per well. A total of six wells are provided, although
four wells are sufficient to meet the normal raw water requirements.
Water from wells is pumped up normally to Raw Water Tank and for fire
water up to Fire Water Tank by well pumps .Raw Water Tanks serve as
a secondary source of fire water, raw water stored in the water tanks is
pumped to the following users by the raw water supply pumps.
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ii)
Plant Water
Raw water is pumped directly from the raw water supply pumps via back
flow preventer refinery plant users. At downstream of the back flow
preventer service changes its name as plant water. Plant water is mainly
used mainly of Boiler Make up Water Treating System feed, Cooling
Water Make up utility hose stations and other miscellaneous users.
iii)
Potable Water
Raw water is treated by the potable water filter system and potable
water chlorination system. The treated water is stored in a potable water
tank as potable water. Potable water is pumped to users by a refinery
potable water pump.
iv)
Cooling Water
Cooling water is supplied from an evaporative cooling tower circulation
system. Cooling water is pumped to the various users by the cooling
water circulation pumps and returned to the cooling tower from the
cooling water circulation system has side stream filter system. Chemical
feed System and Chlorination System.
6.
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7.
The main purpose of the unit is to generate and distribute steam to the plant
users. The system consists of three levels of HP Steam, MP Steam and LP
Steam, and each steam level condensate is recovered as much as possible.
This system will include all facilities to provide steam at the required
temperature and pressure, except the process steam generators.
8.
i)
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ii)
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Effluent first flows into first compartments where and or vase are
closed at sufficient rate using control pumps to maintain the pH
range between 6-9. pH sensors are installed to give control pH
process readings and base are present in day storage tanks for
continuous supply. After pH adjustment, effluent moves to the
second compartment. Both compartments are separated by baffles.
Coagulant ferric chloride is added to assist the formation of froes in
waste water before waste water enters DAF basins. Speed of
flocculator is adjusted. As effluent moves to the stilling chamber,
DAF polymer is added to promote the formation and settling of
flocks.
The effluent is then closed to Flash mixer basins having baffles which
equalizes and evenly distribute the flow across the width of both
chambers. It is also filled with flocculator having normally adjusted
speed. The effluent flows over and under baffles and enters DAF
Basins.
Now, after chemical close and formation of flocks, effluent in DAF
inlet baffle is injected with air saturated recycle water. It actually
works on dissolved air floatation principle. The compressed air is
supplied from refinery plant air system. Flow is introduced through
nozzles. Nozzles are positioned to ensure optimum contact occurs
between micro-bubbles of air and morning flock particles air bubbles
capture the flock particles and float on the surface.
A portion of treated water resulting from DAF process is pumped
back into DAF water pressure vessels. Water is vessels becomes
saturated with compressed air under control conditions and is
injected back to DAF basins.
DAF basins have simmer to remove the floating flocks forming a
blanket surface and a scraper at bottom for the removal of settled
sludge. Skimmers operate at adjustable speed to remove suspended
flocks from water surface while scraper scraps off the bottom sludge.
Skimmer scrape the flocks into DAF sludge troughs while scrapers
discharge into DAF sludge sump from here, oily sludge is pumped to
oily sludge setting tank and effluent flows to Biological Aeration
Basin.
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Clarifiers (930-Me27a/B)
Flocs formed on the surface of mixed Liquor are separated
by settling procedure in clarifier unit also known as
secondary settling tank. Activated sludge from aerobic
basins tends to flocculate under specific gravity near the
water. The ability to settle the flocs depend upon many
factors i.e. presence of industrial waste, DO content,
aeration mode, presence of micro-organisms, temperature
etc. the proper operation of clarifiers. Clarifiers are installed
for two important functions.
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ADDITIONAL ASSIGNMENTS
Assignment No 1:
1.
2.
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The capital cost and operational cost of aerobic digestion is less compared to
anaerobic digestion. Aerobic digestion process is an important practice of
managing sludge and stabilizing sludge in the treatment of waste water plants.
The micro organisms are fed in to aerobic digesters over the organic compound
to reduce the biochemical oxygen demand of sewage and suspended solids in
the wastewater. The organic compounds are converted to carbon dioxide.
The aerobic treatment helps in easy decomposition of organic matter present in
the sludge that comes out from anaerobic digestion treatment system. The left
out organic compound in aerobic digestion system can be either land filled or
disposed off on agricultural field. In some cases sludges from aerobic digestion
are incinerated before disposal on to land fill or onto agricultural land. The
treated sludge can be recycled in to anaerobic digester to convert the organic
compounds into biogas, carbon dioxide and water.
When the sewage sludge is placed in aerobic environment, then the volatile
solids are reduced in no time with the optimal supply of oxygen. This mechanism
is related to microbial protoplasm oxidation where energy helps in balancing the
function of cell. The initial process of aerobic sludge digestion is similar to
endogenous respiration of cellular material. Aerobic digesters are generally used
as adequately mixed reactor. The optimal configuration of aerobic digesters
helps in easy disposal of sludge.
Anaerobic treatment process:
Anaerobic wastewater treatment uses biological agents in an oxygen-free
environment to remove impurities from wastewater. After undergoing such a
treatment, water can be safely released back into the environment. The
biological agents used in the process are microorganisms that consume or break
down biodegradable materials in sludge, or the solid portion of wastewater
following its filtration from polluted water.
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BOD at 5 days:
Biochemical oxygen demand or B.O.D. is a chemical procedure for determining
the amount of dissolved oxygen needed by aerobic biological organisms in a
body of water to break down organic material present in a given water sample at
certain temperature over a specific time period. It is not a precise quantitative
test, although it is widely used as an indication of the organic quality of water. It
is most commonly expressed in milligrams of oxygen consumed per liter of
sample during 5 days of incubation at 20 C and is often used as a robust
surrogate of the degree of organic pollution of water.
Legend has it that the 5-day BOD (Biological Oxygen Demand) test was
developed in England. Sewage was dumped in a river and it took five days for it
to reach the ocean, hence the five-day incubation requirement in the BOD
method.
BOD at 7 days:
BOD is a measure of the content of biologically degradable substances
sewage. The substances are broken down by microorganisms in the presence
(and with the consumption of) oxygen. Oxygen demand is measured in terms
the oxygen consumed by microorganisms over a period of 5 days (BOD5)
seven days (BOD7).
in
of
of
or
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sample. Unlike for the BOD test, toxic compounds (such as heavy metals and
cyanides) in the samples to be analyzed do not have an effect on the oxidants
used in the COD test. Therefore, the COD test can be used to measure the
strength of wastes that are too toxic for the BOD test. Some organic molecules
(e.g., benzene, pyridine) are relatively resistant to dichromate oxidation and may
give a falsely low COD.
Effect of SVI on water quality:
The Sludge Volume Index (SVI) represents the volume occupied by the
concentrated sludge that is obtained after the sludge is allowed to settle for a
period of half an hour. Only the volume occupied by 1gm of the sludge is
considered when calculating the index. This index is also used primarily to asses
the settling ability of the particles in the activated sludge, as well as the settling
capacity of other types of suspensions in wastewater.
A calculation that indicates the tendency of activated sludge solids (aerated
solids)
to
thicken
or
to
become
concentrated
during
the
sedimentation/thickening process.
Sludge Volume Index (SVI) is a very important indicator that determines your
control or rate of de sludging on how much sludge is to be returned to the
aeration basin and how much to take it out from the system. It actually serves
as a very important empirical measurement that can be used as a guide to
maintain sufficient concentration of activated sludge in the aeration basin
whereby too much or too little can be considered detrimental to the systems
overall health. To put it in a lay mans term, de sludging or sometimes referred
to as recycling sludge process, actually plays a very important role because the
whole operation is needed to somehow strike a balance between removing dead
or aged bacteria out of the systems or to determine how much goes back to the
aeration pond.
Activated sludge pond is designed to allow adjustments on the amount of
sludge return and also the take off rate. Regular de sludging must be carried out
to remove the aged sludge so that the new bacteria can regenerate and allowed
to grow. As an experienced operator or engineers that operate the wastewater
treatment plant, a tight control must be put in place to adjust the MLSS value to
the desired concentration based on the set limit SVI to be used as a guide.
5.
Current standards
pH
Oil and grease (ppm)
Suspended solids (ppm)
Sulphates (ppm)
COD (ppm)
BOD (ppm)
6 -10
10
30
600
150
80
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Assignment No 2:
1.
Typically, a belt filter press receives a slurry ranging from 1-4% feed solids and
produces a final product of 12-35% cake solids. Performance depends on the
nature of the solids being processed.
2.
3.
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treatment process removes the grit and other solids through a screening
process followed by a period of settlement. The RBC process involves allowing
the wastewater to come in contact with a biological medium in order to
remove pollutants in the wastewater before discharge of the treated
wastewater to the environment, usually a body of water (river, lake or ocean).
A rotating biological contactor is a type of secondary treatment process. It
consists of a series of closely spaced, parallel discs mounted on a rotating shaft
which is supported just above the surface of the waste water. Microorganisms
grow on the surface of the discs where biological degradation of the
wastewater pollutants takes place.
P&IDs
Please see attachments on Page No. 36.
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construction and operation. Here, EIA formed an integral part of project design
process.
The EIA report was gathered by identifying the issues and impacts, establishing an
environmentally sound preferred option for achieving all the objectives, identifying
and predicting the environmental effects of the proposed project while determining
its relative importance and then clearly document all the impacts of the proposal.
Environmental impact assessment is essential as it gives complete understanding of
nature of existing environment, prior to its interaction with the proposed activity. This
can be achieved through the detailed review of all project specified monitoring
studies to collect the data in the following area i.e.
Terrestrial ecology
Water quality characteristics
Archaeology
Flora and fauna
Traffic
Ambient air and noise conditions
Local socio-economic conditions
The approach adopted in the EIA study of DHDS unit is to assess the impact of
proposed project of existing environment and define the potential impacts avoided
through the careful choice of location, technology and materials.
Role of Policy and Legal Administration In The EIA Of DHDS Unit:
Two organizations, the Pakistan Environmental Protection Council (PEPC) and the
Pakistan Environmental Protection Agency (Pak-EPA) are responsible for
administering the provision of the Pakistan Environmental Protection Act, 1997. The
Pak-EPA ensures compliance with NEQS and establishes monitoring and evaluation
system and is responsible for identifying the need of legislation where ever
necessary. Its function is to review and approve the EIA reports of projects
undertaken in their respective jurisdictions.
EIA report analysis gave a thorough overview of client responsibilities and its
interaction with the other agencies. The client is responsible for the provision of
complete documents required by Pak-EPA; provide logistic support and meeting
Punjab Government criteria.
Environmental and Social Study:
It is highly important to describe the prevailing environmental and social conditions
present within the proposed project area and details the importance of these
resources in terms of local, national and international context which can be derived
by combination of desk study and field survey.
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Project site was located in Mehmood Kot, Muzaffarghar District lies between Chenab
and Indus river. It is the inner most zone of Thal desert where water can be brought
to land by means of inundation canals. Area is flat and soil studies indicate that the
sediment consist of fine to medium grained sand, silt, clay. The site is protected
against flooding by the river Indus. Topography of area is flat with no as such
noticeable variation in the elevation. Area is not thickly populated and surrounded by
agricultural lands having extreme hot, arid climate.
The rainfall data of the project area, temperature, humidity and wind direction are
also calculated. The ambient air quality is monitored for priority pollutants including
carbon dioxide, sulfur dioxide, nitrogen dioxide and particulate matter by using
portable automatic analyzer. There are also significant numbers of water resources
existing in and outside the PARCO industry in the form of groundwater and surface
streams whose characteristics determining parameters should be well within the limits
set by WHO drinking water criteria and NEQS quality standards. Noise measurements
are also made at a height of 1.5m above the ground level and LAeq is monitored for
24 hour at individual location which should be within acceptable NEQS standards. A
socio-economic survey should be carried out near project area with the help of semistructured open-ended questionnaires to identify the various stakeholders and their
opinion regarding the proposed project to find out their social, economical and health
profile. In this way, one can have the easy access to the problems faced by
employees regarding health care facilities, drinking water, availability of Sui gas,
provision of sewage system and recreational facilities etc.
Impact Prediction and Evaluation:
The analysis of environmental releases during construction and operation is also
necessary section of EIA report. The project interaction with environmental is
primarily by way of release of emissions, generation of waste materials, consumption
of resources and accidental releases and spills etc. it is important to qualify the
emissions regarding air, liquid effluents, solid waste, hazardous wastes, noise and
accidental releases.
The major pollutants in air include TSP, NOx, SOx, CO, un-burnt hydrocarbons and
VOC. Liquid effluents contain BOD, COD, and TSS from the machinery washings,
mobile equipment washing, vehicle washing and sewage from site offices and
construction camps. This effluent is sent to treatment plant at site and is discharged
after necessary treatment. Solid waste from construction debris, excavated soil, scrap
metal from construction and equipment fabrication is land filled onsite or recycled to
the extent possible. Solid and liquid wastes from spills/leaks and empty containers of
paints/solvents etc are safely handled and stored by ensuring proper practices.
There are also major releases during operational phase. The exhaust samples of
transport, standby generators, vehicles, valves and storage areas are monitored by
the C.E. Lab of PARCO, showing the concentration of these gases well under the
NEQS limits. Liquid effluent contains liquid effluent from various process units,
sanitary water and vessel/floor cleaning from utility areas. They are treated in
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effluent treatment plant. The solid waste during operation is stored at designated
waste storage area at the facility and finally disposes off through an approved
contractor or sold to potential buyers for recycling.
The assessment of potential impacts during construction and operation is carried out
utilizing both qualitative and quantitative assessment techniques and the impacts are
rated on the basis of severity and likelihood of impact.
There are certain beneficial impacts from the project in terms of generation of
employment opportunities, development of the project are and the nearby
communities. The objective of impact assessment is to assess the adverse impacts
and rate them to identify appropriate improvement measures.
Improvement Measures:
EIA analysis also presents the improvement or alleviation measures the project
should adopt to ensure the practical. Cost-effective and sufficient approach to the
environment it is deigned to ensure that the residual adverse impacts resulting from
work are reduced to an acceptable level, whilst maximizing the benefits of the
project. The operations equivalent procedures for local procurement, waste
management, spill prevention and noise lessening will be maintained. It includes fire
and safety management and wastewater management.
The following are the impacts of DHDS unit installed under study where measures
can be taken
Dust formation : use of water sprinkles, safe driving speed, controlled heavy
earth moving equipments, wetted stockpiles of fine material, dust masks and
safety goggles and good housekeeping
Exhaust emissions: use of new diesel generators, less probability of human
intervention, devices properly tuned, serviced and monitored, vent of exhaust at
specified height and use of low emission content fuel.
Noise: generators installed at isolated place, regularly
noise monitoring,
minimization of night time work activities, insulation, use earplugs and personal
protection equipment
Natural sources: no expected damage to ecology and resulting impacts are
insignificant
Ambient air quality: fixed roof on intermediate diesel tank for DHDS unit, double
sealing, low NOx burners, personal protection equipment, VOC emission control
and properly serviced and monitored vehicles and devices.
Soil conditions: storage and process units marked, drain of oil spills should not
contact with rainwater runoff, emergency response plans, cathodes protection and
incineration.
Ground water: effluent treatment plant, provision of dykes, avoiding the
infiltration of oil into groundwater, monitoring of ground water, incineration of oily
sludge, proper drainage and good housekeeping.
Solid waste: proper land filling, regulatory collection of municipal waste,
collection of hazardous waste in proper drums, indication of the type of waste,
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proper storage and recycle of waste, use of bio sludge as fertilizers, adequate
disposal techniques and staff training regarding sludge collection, handling and
storage.
Safety and occupational health: regularly inspection, emergency response
plans and protective personal equipments
Environment Management Plan (EMO):
The EIA report has identified several environmental impacts which can be managed
by EMP and monitoring plan which serves to mange environmental impacts and
focuses on implementation of improvement measures in its true sense against likely
environmental impacts.
Conclusion:
The comprehensive study of environmental impact assessment report of DHDS unit
installed enabled me to understand the fundamental need of this study and gave me
a keen insight to its practical approach that facilitated me to understand the
theoretical course I took in the university. The detailed EIA report considered all the
minor details and particulars the environment could face during its construction, its
improvement measures and implementation vision and the regulatory monitoring of
emissions, effluent and wastes generated during its operation. The surrounding
environment and community health and safety were considered. Tabulated
information and third party monitoring reports were given for the complete
understanding of the reader.
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