Gallagher Polyurethane Guide
Gallagher Polyurethane Guide
Gallagher Polyurethane Guide
Table of Contents:
Section 1: Polyurethane 101
Introduction to Urethane Elastomers................................................................................. 2
Urethane vs. Metal, Plastics and Rubber
Section 2: Key Polyurethane Properties..................................................................................... 5
Load Bearing
Fatigue
Shear
Hardness
Bonding to Metals
Oil and Chemical Resistance
Abrasion Resistance
Case Study: Polyurethane Abrasion Testing Results
Section 3: Design Considerations & Calculations.................................................................... 12
Effect of Loading Conditions
Shape Factor
Impact Shock Force
Hysteresis in Urethane
Vibration Isolation
Coefficient of Friction
Stoichiometry
Molding Tolerances
Physical Constants
Section 4: The Design Process................................................................................................ 23
7 Steps to Successful Polyurethane Part Design
Case Study: Polyurethane Part Design
Urethane Compound Specifications
Section 5: Finishing & Secondary Processes........................................................................... 25
Machining
Cutting
Contouring
Milling
Turning & Facing
Parting
Knifing
Grinding
Drilling
Section 6: Glossary.................................................................................................................. 29
Typical Physcial Properties of Gallagher Cast Urethanes........................................................ 31
Copyright 2016, Gallagher Corporation
Working three shifts at our ISO-certified, 100,000-square-foot facility, the people of Gallagher process up to 40
different cast urethane compounds every day, molded into hundreds of different tough urethane products. But theres
a lot more than polyurethane processing going on.
OEMs count on our help with everything from material selection to part design to secondary operations comprehensive
expertise that helps solve even the most challenging manufacturing puzzles involving polyurethane.
Engineering
Solving complex problems by applying over 50 years of experience and insights in
feasibility, design and material selection to your challenging application.
Moldmaking
Designing and building precise production molds in house to save time and make sure
your part meets your needs right from the start.
ISO 9001:2008
POLYISOPRENE
NATURAL
STYRENE-BUTADIENE
NITRILE
BUTYL
CHLOROSULFONATED P.E.
ETHYLENE-PROPYLENE
SILICONE
NEOPRENE
POLYSULFIDE
POLYURETHANE
POLYACRYLIC
FLUOROELASTOMER
FLUOROSILICONE
-200
-100
400
100
200
300
400
500F
-100
0
100
200C
The general characteristics of rubber and thermoset polyurethane are:
Temperature
Can be highly deformed without breaking
Ability to recover rapidly and repeatedly from deformation
Deformation is large in proportion to the original dimensions
Large deformations produced at relatively low stress levels
Desired stress-strain properties can often be obtained by compounding
Stress-strain characteristics are non-linear, thus the material becomes stiffer with greater deflection and
velocity of impact
Affected by the environment and conditions under which they are employed
SELECTION GUIDE TO ELASTOMERS WHICH GENERALLY QUALIFY FOR USE FROM -40F TO 160F
(-40C TO 71C) BASED ON ENVIRONMENTAL AND MECHANICAL PROPERTIES
CAPABILITIES
RESILIENT
RESILIENT
RESILIENT
RESILIENT
RESILIENT
ELASTIC MEMORY
ELASTIC MEMORY
ELASTIC MEMORY
ELASTIC MEMORY
ELASTIC MEMORY
NITRILE
STYRENE-BUTADIENE
NATURAL
CHLOROSULFONATED P.E.
ETHYLENE-PROPYLENE
SILICONE
FLUOROSILICONE
FLUOROELASTOMER
POLYACRYLIC
NEOPRENE
POLYURETHANE
BUTYL
POLYSULFIDE
POLYISOPRENE
WEATHER, OZONE,
AGE RESISTANT
WEATHER, OZONE,
AGE RESISTANT
WEATHER, OZONE,
AGE RESISTANT
ABRASION
RESISTANT
ABRASION
RESISTANT
NITRILE
CHLOROSULFONATED P.E.
SILICONE
FLUOROSILICONE
FLUOROELASTOMER
POLYACRYLIC
NEOPRENE
POLYURETHANE
POLYSULFIDE
CHLOROSULFONATED P.E.
SILICONE
FLUOROSILICONE
FLUOROELASTOMER
POLYACRYLIC
NEOPRENE
POLYURETHANE
POLYSULFIDE
POLYURETHANE
QUALIFYING ELASTOMERS
1. Typically, polyurethane rubber should not be used in dynamic applications above 200F (93C). When
tested at 200F (93C) their properties are generally only half of those measured at 75F (25C). They heat
age well however, and the effect of high temperatures up to 250F (120C) for weeks on physical properties
is almost completely reversible when tested again at 75F (25C). We have some polyurethanes that
perform well up to 300F (150C).
2. In most dynamic applications we recommend staying at temperatures below 160F (70C). The normal,
high property working range is -40F to 160F (-40C to 70C). At 160F (70C) the properties of the
elastomer begin to show a decline. The bond between urethane and metal weakens considerably above
160F (70C).
3. Generally, polyurethanes exhibit high hysteresis and low thermal conductivity. They do not dissipate
heat built up by dynamic action quickly. Avoiding heat build-up in an elastomeric part is a paramount
consideration in design. In practice, this is usually done by controlling the amplitude of the deflection. For
instance, using urethane elements in series allow large deflections.
ISO 9001:2008 info@gallaghercorp.com 847 249-3440 800 524-8597
8000
(55)
7000
(48)
6000
(41.4)
SHAPE FACTOR OF 1
10% DEFLECTION
5000
(34.5)
4000
(27.6)
3000
(20.7)
2000
(13.8)
1000
(6.9)
0
0 30A 40A 50A 60A 70A 80A 90A 50D 60D 70D
Durometer Hardness
Neoprene
Urethane
3. The elastomers remaining on your list G or E should be the viable candidates to investigate.
Primary Variables
VMQ Silicone
FKM Fluoroelastomers
ACM Polyacrylate
NBR Nitrile
Butadiene
SBR Styrene
Butadiene
NR
Natural Rubber`
AU Polyester
Urethane
EU Polyether
Urethane
CR Neoprene
E Excellent
G Good
U Unsatisfactory
NR
AU
EU
CR
Resilience
Bonding to Metal
Compresson Set
Electrical
Impact Resistance
Abrasion Resistance
Tear Resistance
Radiation Resistance
Weather Resistance
Oxidation Resistance
Ozone Resistance
Water Resistance
ISO 9001:2008
Vs. Metal
Vs. Plastics
Vs. Rubber
Lightweight
Noise Reduction
Elastic Memory
Abrasion Resistance
Abrasion Resistance
Corrosion Resistance
Noise Reduction
Resilience
Colorability
Impact Resistance
Resilience
Oil Resistance
Flexibility
Ozone Resistance
Easily Moldable
Radiation Resistance
Non-Conductive
Non-Sparking
Castable Nature
Radiation Resistance
4000
(27.6)
3000
(20.7)
2000
(13.8)
1000
(6.9)
0
100
200
300
400
600
700
Neoprene 65 Duro A
60A Urethane Elastomer
1500
(10.3)
Tensile Stress, psi (MPa)
500
In Torsion
1250
(8.6)
1000
(6.9)
750
(5.2)
500
(3.4)
250
(1.7)
0
10
15
In Tension
20
300
Neoprene 65 Duro A
60A Urethane Elastomer
The urethanes have an unusually high load-bearing capacity relative to all other elastomers. They have deflection and
recovery capabilities possessed by no other plastic or metal.
This is the most common application for the high-load and impact-resistant urethanes. We'll attempt to provide a
considerable amount of information within the constraints of this Guide. There is much more information available,
however just contact us with your questions.
Urethanes in Shear
Elastomers in shear are generally used in mounting and
suspension applications. Urethane elastomers deflect
more easily in shear than in compression. Shear is
essentially a combination of tensile and compressive
forces acting at right angles to each other.
DEFLECTION
THICKNESS
400
(2.8)
350
(2.4)
300
(2.0)
250
(1.7)
200
(1.3)
150
(1.0)
100
(0.7)
50
(0.3 )
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
Shear Strain (Deflection/Thickness)
GC 1560
GC 1095
GC 1090
0.8
0.9
1.0
GC 980
GC 970
GC 855
ISO 9001:2008
HARDNESS SCALES
SOFT
MEDIUM
HARD
Rubbers
Durometer D
Pencil
Eraser
Rubber
Band
AutoTire
Tread
Plastics
Polystyrenes
Nylons
Acrylics
Phenolics
20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95
Polypropylenes
Durometer A
Flourocarbons
Cast Urethanes
Shoe
Heel
30 35 40 45 50 55 60 65 70 75 80
Shopping Cart
Wheel
Rockwell R
Hard Hat
Hardness Scales. Note: the durometer "A" scale is used for the softer urethanes. The durometer "D" scale is used for
the harder urethane compounds (above 95 A durometer)
TDI POLYETHER
(Material A)
MDI POLYESTER
(Material B)
1,800 (12.4)
1,570 (10.8)
3,400 (23.4)
3,180 (21.4)
5,000 (34.5)
6,460 (44.5)
400
440
500 (87.7)
762 (134.0)
150 (26.3)
175 (30.7)
Elongation Break, %
It's obvious from the data that the two elastomers are not the same, even though the hardness is the same. We
have ways to identify (with spectrographic and chemical analysis) the structure of elastomers at the same hardness,
but the process is costly and time consuming. Actually, they are both excellent materials but with widely different
engineering properties. One will perform better in some applications and the other will perform well in different
applications.
Material A
1250
(8.6)
25
50
75
100
125
% Strain
150
175
200
225
75
100
125
% Strain
150
175
200
225
Material B
Stress, psi (MPa)
1250
(8.6)
ISO 9001:2008
25
50
First Cycle
Twentieth Cycle
B = Moderate Effect
C = Probably Unsatisfactory
D = Unsatisfactory
RATING
RATING
NUMBER 1 OIL
NUMBER 2 OIL
NUMBER 3 OIL
SPECIFICATION FLUID
RATING
SPECIFICATION FLUID
RATING
MIL-H-13862
MIL-H-13866A
MIL-H-13910B
MIL-H-13919A
MIL-H-15017
MIL-H-15018B
MIL-H-15719A
MIL-H-15019C
MIL-H-16958A
MIL-H-17331D
MIL-H-17353A
MIL-H-18486A
MIL-H-19701
MIL-H-21260
MIL-H-22396
MIL-H-23699A
MIL-H-25336B
MIL-H-26087A
MIL-H-27694A
MIL-H-3150A
FLUID
B = Moderate Effect
C = Probably Unsatisfactory
RATING
FLUID
D = Unsatisfactory
RATING
FLUID
RATING
ACETONE
AMMONIUM HYDROXIDE
AMMONIUM NITRATE
ANIMAL FATS
ASPHALT
BARIUM CHLORIDE
BARIUM SULFATE
BARIUM SULFIDE
BORIC ACID
BUTANE
BUTTER
BUNKER OIL
CALCIUM CHLORIDE
CALCIUM HYDROXIDE
CALCIUM NITRATE
CARBON DIOXIDE
CARBON MONOXIDE
CITRIC ACID
COCONUT OIL
COPPER CHLORIDE
COPPER CYANIDE
COPPER SULFATE
CORN OIL
CYCLO HEXANE
DIESEL OIL
DIETHYL ETHER
DOWTHERM OIL
ETHYL ALCOHOL
ETHYL CELLULOSE
ETHYL CHLORIDE
ETHYL ETHER
ETHYLENE GLYCOL
GLUCOSE
GLYCERINE
GLYCOLS
HYDRAULIC OIL
(PETROLEUM BASED)
HYDRAULIC FLUIDS
(SYNTHETIC)
HYDROGEN GAS
ISOOCTANE
KEROSENE
LARD
LINSEED OIL
LYE
MAGNESIUM CHLORIDE
METHANE
METHYL ALCOHOL
METHYLENE CHLORIDE
MINERAL OIL
NATURAL GAS
NITROGEN
OLEUM SPIRITS
OLIVE OIL
OXYGEN - 200F
PEANUT OIL
POTASSIUM CHLORIDE
POTASSIUM HYDROXIDE
POTASSIUM NITRATE
POTASSIUM SULFATE
PROPANE
RADIATION
SEWAGE
SILICATE ESTERS
SILICONE GREASES
SILICONE OILS
SOAP SOLUTIONS
SODIUM CHLORIDE
SODIUM HYDROXIDE
SODIUM PEROXIDE
SODIUM PHOSPHATE
SODIUM SULFATE
SOYBEAN OIL
STEARIC ACID
TANNIC ACID
TOLUENE
TUNG OIL
WATER, FRESH
WATER, SALT
WHISKEY, WINES
ISO 9001:2008
A
A,B
Soft, resilient compounds 60A to 85A last longest in particle impingement types of service.
Medium durometer, resilient compounds 85A to 95A last longest in abrasive slurry (e.g. pump impellers,
etc.).
90A to 5A durometer compounds work best in impact and sliding types of abrasion found in sand, gravel,
coal and ore mining applications.
The very hard compounds 65D to 75D durometer work best in bushing and bearing applications in wet or dry
environments often where sand, grit or mud are present.
Wear Loss Under Equal Test Conditions
0.05
End Of Useful Life Due To Tolerance
0.04
0.03
0.02
0.01
Gallagher Urethane
SBR: Most widely used
GC
485
conventional
rubber
forour
There is no substitute for a field test of 2 or 3 chosen
compounds.
With
components
experience and knowing your field performance,mechanical
we can help
you select test
candidates
10
200
Force:
30 lbf
Revolutions
6,000
Wheel Diameter:
9"
Wheel Material:
Chlorobutyl Rubber
Aggregate
Pivot
Weight
Rounded Quartz
(AFS 50/70)
Rubber Tire
Test Specimen
Test Description:
Laboratory test procedure ASTM G65 was chosen for this experiment, it was performed by an independent testing
facility experienced in this field. Per the ASTM testing procedure this test is used to, rank materials in their resistance
to scratching abrasion under a specified set of conditions. Test results are reported as volume loss in cubic millimeters,
per the ASTM standard. An illustration detailing the testing apparatus and equipment specifications are shown in
Figure 1. This test was conducted using Procedure A of ASTM G65. Test specimens were carefully weighed before
and immediately following the test procedure. Mass loss was converted to volume loss using the density of each
material.
300
Test Results:
Lower Volume Loss = Less Abrasive Wear
Three
polyurethane
compounds,
UHMW and D2 Tool Steel hardened to
250
HRC 58.5 - 60.5 were samples selected
for this experiment. GC 995 and GC
200
485 are high performance polyurethane
compounds specially forumlated for
highly abrasive applications. GC1560
150
is a widely used general purpose
polyether polyurethane compound.
100
Test results are provided in Figure 2,
abrasion resistance for UHMW was
used as the benchmark for comparing
50
the different polyurethane compounds.
Of all the samples included in this test,
0
GC995 produced the most favorable
D2 Tool Steel UHMW
GC 995
GC485
GC1560
results and also out-performed the
benchmark, UHMW.
Figure 2: Abrasion Test Results
ISO 9001:2008
Shape Factor
The compression-deflection relationship is modified by
the shape of the part. Shape has only a minor effect in
tension and shear.
For example, consider two blocks of urethane. One
is a cylinder, the other is a block of the same height
and the same cross-sectional area but is rectangular
rather than circular. Both blocks are made from the
same compound and the top and bottom surfaces are
bonded to metal. If the same weight is placed on each
block, the deflection will be greater for the rectangular
block than for the cylindrical block. Neither block loses
perceptible volume during deflection; they bulge at the
sides that were perpendicular to the top and bottom
surfaces. The area under the load is the same for each
block, but the area of the side walls (the total area free
to bulge) on the rectangular block is greater than the
side wall area of the cylinder thus increasing the area
free to bulge, making bulging easier and permitting
greater vertical displacement.
6000
(41.4)
5000
(44.5)
4000
(27.6)
3000
(20.7)
2000
(13.8)
1000
(6.9)
0
0
10
20
30
Compressive Strain, %
40
50
12
Example 1:
Example 2:
Example 3:
Design Recommendations:
Maximum Strain for Compressive Loading
Hardness
60A
75A
80A
85A
90A
95A
60D
75D
15%
15%
15%
15%
10%
10%
5%
2%
Dynamic Service
(0.32 Hz)
25%
20%
20%
15%
15%
10%
5%
5%
Dynamic Service
(0.16 Hz)
35%
35%
35%
25%
25%
20%
10%
5%
Impact Service
(Very Low Frequency)
50%
50%
50%
50%
50%
50%
50%
50%
These are approximations for "average" service conditions. Please check with us for specific application recommendations.
ISO 9001:2008
6000
(41.4)
5000
(34.5)
5000
(34.5)
4000
(27.6)
4000
(27.6)
3000
(20.7)
3000
(20.7)
2000
(13.8)
2000
(13.8)
1000
(6.9)
1000
(6.9)
GC 965
6000
(41.4)
GC 1285
6000
(41.4)
A high percentage of all urethanes are related to the unique high load
bearing and impact resistance of urethanes, lets consider the load bearing
ability of typical compounds.
10
20
30
6000
(41.4)
40
50
GC 1090
6000
(41.4)
5000
(34.5)
5000
(34.5)
10000
(69)
4000
(27.6)
4000
(27.6)
4000
(27.6)
8000
(55)
3000
(20.7)
3000
(20.7)
3000
(20.7)
6000
(41)
2000
(13.8)
2000
(13.8)
2000
(13.8)
4000
(28)
1000
(6.9)
1000
(6.9)
1000
(6.9)
2000
(14)
10
20
30
40
50
10
20
30
40
50
10
20
30
40
50
Compression Strain, %
Shape Factor:
Ratio of the Area of
One Loaded Surface
to the Total Area of
Unloaded Surfaces
Free to Expand
6000
14
(41.4)
2"
2"
NO LOAD
1000 PSI
2"
4 IN2
16 IN2
0.25
SHAPE
FACTOR
2.26"
2"
SURACE AREA
4 IN2
AREA FREE TO BULGE 14.2 IN2
SHAPE FACTOR
0.28
1000 PSI
28%
36%
RECTANGLE
CYLINDER
GC 970
GC 980
GC 480
6000
6000
ISO 9001:2008 info@gallaghercorp.com
847 249-3440(41.4)
800 524-8597
(41.4)
12000
(83)
5000
(34.5)
.25
.5
1
2
3
55
30
40
5000
(34.5)
4000
(27.6)
4000
(27.6)
4000
(27.6)
3000
(20.7)
3000
(20.7)
3000
(20.7)
2000
(13.8)
2000
(13.8)
2000
(13.8)
1000
(6.9)
1000
(6.9)
1000
(6.9)
10
20
30
40
50
GC 1095
10
20
30
40
50
GC 1560
12000
(83)
10000
(69)
10000
(69)
8000
(55)
8000
(55)
8000
(55)
6000
(41)
6000
(41)
6000
(41)
4000
(28)
4000
(28)
4000
(28)
2000
(14)
2000
(14)
2000
(14)
10
15
20
25
10
15
10
20
20
25
30
40
50
20
25
GC 1575
12000
(83)
10000
(69)
50
GC 485
6000
(41.4)
5000
(34.5)
12000
(83)
40
GC 980
6000
(41.4)
5000
(34.5)
50
090
GC 970
6000
(41.4)
10
15
Compression Strain, %
Shape Factor:
Ratio of the Area of
One Loaded Surface
to the Total Area of
Unloaded Surfaces
Free to Expand
6000
(41.4)
GC 970
2"
2"
NO LOAD
1000 PSI
2"
4 IN2
16 IN2
0.25
SHAPE
FACTOR
2.26"
2"
SURACE AREA
4 IN2
AREA FREE TO BULGE 14.2 IN2
SHAPE FACTOR
0.28
1000 PSI
28%
36%
RECTANGLE
CYLINDER
.25
.5
1
2
3
GC 980
GC 480
6000
6000
ISO 9001:2008 info@gallaghercorp.com 847 249-3440 800 524-8597 15
(41.4)
(41.4)
Example:
An 800 pound (362.kg) transfer carrier travels at 10 ft/sec and hits a stop once per minute. Without a bumper to
decelerate the carrier, the impact force may exceed a million pounds. To protect the machine we should limit the
impact or transmitted force to 50,000 pounds by installing a urethane bumper. Due to limited space the bumper will be
6 inches in diameter by 3 inches long (15cm x 7.6cm), bonded between metal plates. Let's select the right urethane.
Taking the kinetic energy of the impact as equal to the
area under the load/deflection curve:
) (
KE = 1,242 ft lbs
KE = 14,904 in lbs
KE = 14,904 in lbs
KE = 1 Fd
2
14,904 in lbs = 1 50,000 d
2
d = 0.60 in
This is the minimum deflection that we need so that we don't exceed the 50,000 pounds of force maximum. The loaded
area of the bumper is 28.3 in, the bulge area is 56.5 in, therefore, the Shape Factor is .5. The maximum force of .60
inches is 20% of the 3 inch length. Therefore, the proper material will deflect at least 20% at 1,767 psi for a .5 shape
factor. Referring to the static strain curves, we see that GC 1095 at .5 Shape Factor will deflect approximately 33% at
1,767 psi (we are allowing for an approximate 1.5 dynamic to static spring rate ratio). A test should be conducted to
verify the actual deflection achieved in use.
1,000,000
900,000
800,000
Load, lbs.
700,000
600,000
These two equal impact loads have the same area under load-deflection
curves. The reaction force in one case is 1,000,000 pounds and in the other
only 50,000 pounds. This graphically illustrates the importance of deflection
in absorbing impact. The urethane in this case is 95A durometer (GC1095).
100,000
400,000
300,000
200,000
100,000
50,000
0
.1
0
.03
16
.2
.3
.4
.5
.6
.7
Deflection, Inches
Hysteresis in Urethane
Let's examine the compression-deflection curve for a given compound at a given shape factor and record the stressstrain relationship.
As the piece is loaded, we arrive at one reproducible curve after three or four cycles. Now, if we record the curve
generated during the unloading we see that not all the initial energy is returned. The area under the loading curve can
be called the input energy. The area under the return curve can be considered the return of stored energy and the area
between the two curves is the energy that is not returned but is converted to heat. This energy is converted to heat
by hysteresis. This phenomenon is characteristic of all types of rubber, because rubber compounds are viscoelastic
systems. See chart: stress-strain cycling of two 95A durometer urethanes.
The urethane elastomers consist of an elastic
portion that stores energy and returns it and a
viscous portion that captures energy and converts
it to heat. It might help to consider the spring and
dash pot experiments of Physics class. The spring
represents the elastic response and dash pot the
viscous response.
Due to the inherent low thermal conductivity of urethane and hysteretic heat build-up, part designers must address
ways to generate less heat under cyclic loading conditions. This is typically accomplished by reducing the deflection
(strain) per cycle, by increasing the compression modulus of the elastomer, or increasing the shape factor. Reducing
the stress per unit area is another possible approach. The selection of compounds and stoichiometry coupled with
design can alleviate many potential heat build-up problems.
ISO 9001:2008
Natural Frequency
It is usually expressed in Hertz (Hz) or cycles per second:
1
fn = 3.13
Static Deflection
Frequency Ratio
The Forcing Frequency, ff (sometimes called disturbing or driving frequency), divided by the Natural Frequency, fn, is
the ratio that indicates the effectiveness of a vibration isolator. The Forcing Frequency units are Hertz or cycles per
second.
Frequency Ratio = ff
fn
Damping
This is the hysteresis (viscous) component of a polyurethane isolator. It is this hysteresis characteristic that converts
mechanical energy into heat which is then dissipated. In free vibration a fair percentage of the input energy is dissipated
in the form of heat during each cycle causing the vibration to die out.
The Damping Ratio, C/Ccr is used to indicate the amount of damping in a system. C/Ccr is affected by temperature and
preload. Typically for most urethanes it can be varied from a low of .05 for highly resilient compounds to .15 for the
low resilience urethanes. Using the above information and the Transmissibility Curve shown on the next page we can
design urethane isolators.
Example
A rotary compressor weighing 5,000 lbs. is to be supported on four sandwich type mounts (urethane pad bonded
between metal plates). The motor operates at 1,800 rpm. At least 75% of the disturbing vibratory forces must be
isolated; that is, the transmissibility is to be less than 25%.
First, assume a Damping Ratio of .1, we need a starting point to get into the ballpark and we can always come back
and change it. Next, by examination of the Transmissibility Curve we see that to be at 25% Transmissibility with a
C/Ccr of .1 the Frequency Ratio (ff/fn) should be 2.5 or higher.
fn = 12 Hz
Now we know that each mount must deflect .068 inches under the total 65,000 lbs. or 1,250 lbs. per mount in order
to have a natural frequency of 12 Hz.
Next, we need to design an element with .068" deflection at 1,250 lbs. In consideration of the long term static load
plus the possible heat generation due to hysteresis let's use a free height of .75 inches of urethane. That means that
the .068" deflection is a 9% deflection. GC 1285 is a good material choice for this type application. By making a few
trial and error calculations at different pad cross sections and using the Stress-Strain Curves we arrive at a 2" x 2"
urethane pad, with a Shape Factor of .67, and a compressive stress of 313 psi produces a deflection of 10% of 0.75
inches. A test should be performed to verify the calculated results.
18
100
TRANSMISSIBILITY, Ftransmitted/Fforcing
10
0.1
0.01
1.0
2.0
3.0
FREQUENCY RATIO, ff/fn
4.0
5.0
ISO 9001:2008
The coefficient of friction between polyurethane elastomers and non-lubricated surfaces decreases with increasing
hardness. Since harder elastomers have the lowest coefficient of friction, these materials perform the best where
sliding abrasion resistance is necessary. The softer compounds are ideal where friction is required, such as a urethane
drive wheel.
1.0
.8
.6
.4
.2
0
0 80A
90A
95A
60D
70D
.8
.6
SMOOTH PLASTIC
.4
.2
0
80D
GC 1575 - UNLUBRICATED
LINEAR VELOCITY: 75 ft/min
TEST TEMPERATURE: 75F
CONTACT SURFACE AS SHOWN
1.0
10 RMS STEEL
1.0
20
.8
.4
75
50
25
.2
0
10
20
30
40
Normal Load, lbs
50
30
40
50
1.0
.6
20
10
.8
.6
.4
.2
0
50
100
150
200
Test Temperature, F
250
Polyurethane Stoichiometry
Stoichiometry is the chemical relationship of the amount of reactive elastomer polymer to the amount of curing agent
used.
Selection of proper stoichiometry is our responsibility, it plays an all important part in compression set resistance, cut
and tear resistance and flex fatigue resistance. When higher stoichiometry is used, flex fatigue resistance will be higher;
however, the part will build up heat faster due to hysteresis. When lower stoichiometry is used, the finished material
will have reduced compression set and will heat up slower due to hysteresis. The drawback to lower stoichiometry is
that the material will be less resistant to flex fatigue and cuts or tears.
It's important to try to establish whether heat build-up or flex fatigue resistance is the more important property needed
for best application performance. Stoichiometry can be used to our advantage for problem solving specific applications
50
COMPRESSION SET, %
METHOD B 22 HRS. @ 70C
10,000,000
1,000,000
100,000
10,000
GC 1090
1,000
100
85
90
95
100
105
110
CURATIVE, % OF THEORY
40
30
20
GC 1090
10
0
85
100
90
95
105
CURATIVE, % OF THEORY
110
These graphs show the broad effect of stoichiometry on the physical properties of 90A durometer elastomer (GC 1090). (click to
enlarge)
.005 in ( .1mm)
1 - 36 in (25 - 915mm)
0.5%
0.7%
ISO 9001:2008
Thermal Conductivity
-32F to +32F
(-35C to 0C)
32F to 75F
(0C to 24C)
75F to 212F
(24C to 100C)
GC1285
1.08
.92
1.1 10-4
GC1090
1.11
.92
1.4 10
.95 10
.95 110-4
GC1095
1.13
.86
1.3 10-4
.89 10-4
.9 110-4
GC1260
1.16
.80
1.0 10-4
.87 10-4
.85 110-4
GC1275
1.19
.75
.8 10-4
.83 10-4
.8 110-4
GC855
1.22
.75
1.4 10-4
1.0 10-4
.9 110-4
GC970
1.25
.80
1.3 10
.93 10
-4
.9 110-4
GC485
1.24
.80
1.2 10-4
1.1 10-4
.8 110-4
GC980
1.25
.80
1.2 10-4
.91 10-4
.8 110-4
see note 1
see note 2
Compound
-4
-4
-4
see note 3
NOTES:
1. Specific Gravity can be interpreted in terms of grams per cubic centimeter.
2. Thermal Conductivity is the amount of heat in BTU per hour per square foot for a temperature gradient of one
BTU
degree Fahrenheit per inch thickness.
(hr)(ft2)(F/in)
3. T
he coefficient of linear thermal expansion is the change per length per degree F. The expansion of all
rubbers is about the same order of magnitude, approximately 10 times that of steel. Thermal contraction may
also be calculated using the coefficients to determine the shrinkage at low temperatures.
22
The following steps in order yield the best approach to design and problem solving. We encourage you to contact us
for help every step of the way.
1. Prioritize the properties that are necessary for performance in a given application.
2. Material characterization bring us in at this stage. The urethane elastomers can be tailored to an almost
infinite variety of material properties. We can assist in the selection. There is no perfect elastomer for all
applications, but there are usually one or two choices that are worthy of prototype testing.
3. Establish a prototype test program simulating the operating conditions. Acceleration of testing by increasing
cyclic rates or amplitudes beyond the application parameters always results in excessive heat build-up in
urethanes and unsatisfactory data.
4. Modify the compound or design to correct any deficiencies noted in testing.
5. Set up a limited field trial and monitor results.
6. Modify compound and design if required.
7, Write a material specification for inclusion with design drawings.
Given the list of parameters above, it is logical to select a compound that meets those requirements and proceed
through the design process. Let's select GC 1090 as our starting compound. GC 1090 has a limit of 10% for long
term static deflection.
By performing several iterations of different shapes at 10% deflection, we are able to arrive at an unbonded
stack of sixteen GC 1090 pads (each 9 3/4" diameter x 1 3/16" thick) separated by fifteen 1/4" thick steel plates. By
using the urethane pads in series we are able to use the load bearing capacity of one pad combined with the
total deflection of sixteen. A dynamic load of 84 kips would produce a deflection of approximately 4 inches. Drop
hammer tests confirmed that the calculated deflections were within the allowable tolerance and several hundred
assemblies are now in service.
ISO 9001:2008
D2240
Tensile Strength
D412
Elongation
D412
D412
D624
D470
Specific Gravity
D792
D1630
Where an application requires specific environmental performance, those requirements should also be listed. We're
always willing to help our customers write specifications. Comprehensive specifications should be on the drawings
before they go to the Purchasing Department for quotation requests.
Remember that the chemical structures we use are all premium performance compounds, with no fillers or extenders
unless they serve a technical purpose. We never use additives as a way to reduce compound cost. Any reduction
of physical and mechanical properties must be balanced with any cost advantages achieved. It is not possible to
maximize all properties in one compound. Intelligent compromise is always required.
We have urethane elastomers which can meet the following military specifications:
MIL-R 83397
MIL-P 3065 PLUS ASTM D 2000
MIL-R 45036 (AU/EU)
MIL-R 45036 D (MR)
MIL-M 24041
ASTM-D 2000
SAE-J 200
MIL-R 15624
MIL-M-I 46058
MIL-M 24041
MIL-C 24231
We also make urethane compounds which meet FDA and USDA requirements for contact with wet, dry, or oily foods.
In addition some compounds meet or exceed flame resistance requirements of mine safety (MSHA). We use MIL-I
45208 for quality assurance.
24
Cast polyurethanes can be readily turned, sawed, drilled, ground and milled. We offer many engineering shapes of
our compounds which can often be used to make prototypes or limited production quantities. It is important to note
that the material presented here is a starting point. The wide variety of urethane compounds and their respective
physical properties and characteristics creates a wide range of situations.
Harder urethanes 90A and up have a high degree of machinability. Lathe turning, fly-cutting, grinding, contouring
and more are easily accomplished on conventional metal working equipment by machinists who are familiar with
procedures for handling plastics.
Some different tools and techniques are required for compounds of 80A durometer and lower. The lower modulus
compounds are typically machined by knifing, grinding and sanding. In some cases, however, they can be worked like
higher modulus materials by "freezing" them with dry ice or liquid nitrogen.
ISO 9001:2008
10 - 20
Safe fixturing of parts when contouring is very important. When contouring urethanes softer than 95A, use a tool with
15 to 30 degrees of top rake. Lathe speed depends on the O.D. of the part. In general, high rpm works best. Feeds
should be slow until experience is achieved.
Note: When machining urethane, wear a full face mask.
1/32"
- 1/16" R
3/8"
10 - 15
1/8"
30
3/64"
20 - 30
26
3/8"
3/8"
3/8"
.09"
We use two types of knifing tools; high speed steel is used on medium to hard urethane (70A to 95A). This type of tool
must be very smooth and have a razor sharp point. All edges and surface behind the cutting point must be smooth
to prevent the cut-off material from being pulled between the work piece and the tool. High turning speeds of 600 to
1000 rpm with rapid hand feed will yield an excellent surface finish. Carbide works best for medium and softer grades.
/16"
10
30
Knifing tool for softer urethanes (carbide)
ISO 9001:2008
GallagherTips
Corporation
Design
& Application
Guide
Design
to Improve
Service
Life of Urethane
Components Bonded to Metal.
NOT RECOMMENDED
RECOMMENDED
COMPRESSION
WITH CORED HOLES
COMPRESSION
SHEAR
TORSION
TENSION
WHEELS
BUSHINGS
28
Section 6: Glossary
Urethane Design Glossary
Glossary of Terms
ASTM TEST METHODS
You will note that we refer to ASTM tests and test results frequently. We use ASTM tests to classify properties, but the
limitations on the usefulness of the standard tests are well stated in ASTM D 394 and D 1630: "No relation between
this test and service performance is given or implied..." As stated previously and repeated for emphasis: NEVER bypass the all-important prototype and field test steps. However, once performance has been proven, relevant ASTM
test data serves well in specification writing.
COMPRESSION
Stress on a material tending to cause deflection, since, in many instances, urethane elastomers can be considered
incompressible. Because very little volume change occurs, we prefer to use the term "deflection." Cellular products
such as urethane foam do compress because of the collapse of the air-filled cells.
ELASTOMER
The word is generally applied to the man-made rubbers. It's simply the contraction of the words "elastic polymer."
Each of the elastomer classes is characterized by its own set of characteristics which make it useful.
HEAT BUILD-UP
This term, peculiar to the rubber industry, means the temperature rise within an elastomer body due to hysteresis and
the low thermal conductivity of elastomers. Since the physical properties of urethanes are reduced as the temperature
rises above 160F (70C), heat build-up is to be avoided. The amount of heat liberated per deformation cycle is
proportional to the amplitude of the strain, the frequency of application and the duration of the condition. Designers
can avoid heat build-up by constructive use of shape factor.
HYSTERESIS
Refers to the percent energy lost per cycle of deformation or 100% minus the resilience percent. Hysteresis is the
result of inter-molecular friction and is manifested by conversion of mechanical energy to heat. See hysteresis page.
MODULUS OF ELASTICITY
In elastomers, as in steel, this term refers to the ratio of stress to the strain, produced by that stress. Within the region
of low strain (up to 15%), an elastomer's stress-strain curve is almost linear and design calculations which assume
stress proportional to strain may be made with tolerable error. Strains greater than 15% are far from proportional
to stress. Modulus of elasticity in this engineering sense should not be confused with "modulus" which is rubber
industry jargon for tensile stress and is applied when strains are much greater than 15%. Elastomers in general have
two moduli of elasticity; static and dynamic, in as much as they have the peculiar property of behaving stiffer when
vibrated or impacted. The term "modulus" when applied to steel is defined as the slope of the straight line portion of
the stress-strain curve. In the case of elastomers, modulus is defined as the stress required to produce a given strain
of say 300%, would be called the 300% modulus, and is not useful in calculations.
NATURAL FREQUENCY
The characteristic frequency of vibration for a particular spring-mass system after a force or displacement is applied
and removed.
POLYURETHANE
An alternative term for urethane.
RESILIENCE
The resilience of elastomers subjected to and relieved of stress has been defined by the ASTM as the ratio of energy
given up on recovery from deformation to the energy required to produce the deformation, expressed as a percent.
ISO 9001:2008
The term embraces a large group of materials which have the ability, under certain conditions, to undergo large
deformations and recover almost completely and instantaneously on release of the deforming force. This elasticity
is due to the repetition of long molecular chains and cross links of the base polymer. The "first" rubber came from
the tree "HEVEA BRASILIENSIS" and was called Indian or natural rubber. Its use can be traced to the Mayan Indian
culture. Since the 1930's, at least 16 different man-made rubbers with different, improved and controlled molecular
structures have been developed. Familiar types are neoprene, nitrile, butyl, silicone and urethane.
SHAPE FACTOR
The ratio of the load area of an elastomer body subjected to a compressive load to the sum of the areas which are free
to bulge. As the shape factor increases, the strain produced by given stress decreases. This is a critical consideration
in avoiding heat build-up in dynamic applications. It is also important in static load bearing applications such as
structural bearing pads where compressive stress relaxation versus time is to be avoided.
TANGENT DELTA
(TAN DELTA): A ratio of the loss modulus (viscous component of the elastomer) to the elastic modulus (storage
component of the elastomer). A low tan delta means higher resilience and less hysteresis.
TENSILE PROPERTIES
These properties in steel are basic. They affect almost every design calculation for steel products and have a direct
bearing on the product's serviceability. Tensile properties of elastomers, on the other hand, have much less, if any
bearing on serviceability and almost never affect a design calculation. They do have some influence in high impact
studies, however.
TENSION
URETHANE
The name given to a class of NCO (isocyanate) terminated resins with cross linking or chain extension intermediates
called curing agents. Urethane is often used as an alternative term for Polyurethane. There are ten major groups of
urethanes:
1. MDI-Polyesters: produce FDA dry and wet food grade urethanes in the normal hardness range from 85
Durometer A to 45 Durometer D. They are tough, abrasion resistant and tear resistant.
2. TDI-Polyesters: produce urethanes from 50 Durometer A to 75 Durometer D which are tough, abrasion resistant,
and with excellent oil and aliphatic solvent resistance.
3. MDI-Polyethers: produce urethanes with higher resilience, better impingement type abrasion resistance, good
dynamic performance, improved hydrolysis resistance and excellent low temperature properties. Some are
adaptable to FDA and USDA application for wet and dry food contact.
4. TDI-Polyethers: have excellent low temperature and dynamic properties, microbial resistance and long term
water resistance.
5. TODI Polycaprolactone: Excellent heat resistance, hydrolysis resistance and superior mechanical properties.
6. PPDI: Terminated polyesters and polyethers offer superior performance at higher temperatures.
7. MDI: Diphenylmethane Diisocyanate
8. TDI: Toluene Diisocyante
9. PPDI: Paraphenylene Diisocyanate
10. TODI: Toluidine Diisocyanate
Taken together, urethanes possess:
Oil, water and weather resistance, ozone and oxidation resistance, and resistance to many chemicals. Some
are radiation, fungus and bacteria resistant.
High tensile and tear strength compared to other elastomers.
Outstanding abrasion resistance compared to metals, plastics and other elastomers.
Higher load bearing capacity than other elastomers. Higher impact resistance and resilience than plastics.
Excellent retention of properties at very low temperatures and at temperatures up to 220F (104C). (Bonded
to metal to 160F (71C).
YOUNG'S MODULUS
Alternative term for modulus of elasticity. It is the slope of the linear portion of the stress-strain curve of the elastomer
in tension or compression.
30
ISO 9001:2008
Coefficient of Thermal
Expansion, in./in./F
D 257
10x10-5
-34 (-37)
D 2137
D 792
Specific Gravity
100
D 1630
33
750 (5.2)
D 2632
Resilience (rebound), %
73
25
GC 970
80
30
GC 980
85
35
GC 485
85
35
GC 1285
90
40
GC 1090
530
3500
(24.2)
700
1.25
140
30
30
1.25
150
30
30
1.24
250
40
27
430 (75.3)
235 (41.1)
550
1.08
160
50
35
400 (70.0)
85 (14.9)
580
1.11
175
45
27
240 (42.0)
75 (13.1)
450
1.13
300
40
25
5.4
500 (87.5)
150 (26.3)
400
5000 (34.5)
900 (6.2)
1800 (12.4)
3400 (23.5)
95
50
GC 1095
1.16
370
42
4.8
465 (81.4)
135 (23.6)
320
8500 (58.7)
1200 (8.3)
2400 (16.6)
8000 (55.2)
60
GC 1560
1.19
500
50
1.8
1000 (175.0)
145 (25.4)
250
8500 (58.7
2000 (138)
4000 (27.6)
73
GC 1575
10x10-5
-70 (-57)
9.3x10-5
-42 (-41)
1.5x1010
9.0x10-5
-34 (-37)
2.0x1011
11.0x10-5
-31 (-35)
11.0x10-55
4.8x1011
9.5x10-5
3.7x1012
8.9x10-5
<-94 (<-70)
2.7x1013
8.7x10-5
-65 (-55)
2.0x1014
8.3x10-5
-65 (-55)
750 (5.2) 1800 (12.4) 4000 (27.6) 4700 (32.4) 4900 (33.8) 5100 (35.2) 10000 (69.0) 30000(207.0) 63000(434.7)
1.16
120
30
370 (64.8)
225 (39.4)
625
5000 (34.5) 6000 (41.4) 7500 (51.8) 4400 (30.4) 4500 (31.1)
65
GC 965
450
3800
(26.2)
125 (0.9)
270 (1.9)
520 (3.6)
55
D 395
D 395
Die C
Split Tear
D 624
D 470
D 412
Ultimate Elongation, %
D 412
D 412
D 412
D 412
D 2240
D 2240
ASTM Test
Method
GC 855
Ultimate Tensile
at 50% extension
at 100% extension
at 300% extension
Durometer A
Durometer D
Hardness
Compound
For over five decades, OEMs have turned to Gallagher Corporation because we consistently deliver the custom,
critical polyurethane parts they need to succeed. Not every molder can handle the complexities of polyurethane
molding, but our experienced engineers welcome every challenge.
Cast Urethane
Every day, we process up to 40 different cast urethane compounds, which can be molded into hundreds of different
products.
Our advanced machinery accurately maintains both
temperature and flow rate of the liquid components, ensuring
that the mixed compound is optimum and consistent.
Because the cast urethane is a liquid, we can gravityfill molds with little or no pressure. This type of tooling is
generally less expensive great for prototyping and shortto medium-production runs. We can also pressure fill
molds directly from the mixing machine, centrifugally mold,
compression mold and mold under vacuum.
Injection Molding
Gallagher offers a wide range of thermoplastic urethanes,
glass filled urethane, TPR, polycarbonate and nylon.
Processed via injection molding, thermoplastics combine
great physical properties and cost-effectiveness on mediumand high-volume production runs.
Insert Molding
Using either of the above processes, we can mold to
inserts such as bearings, wheel and roller hubs, threaded
fasteners, metal plates, and shafts. The insert can be made
from aluminum, steel, stainless steel or plastic.
32