4-1 PDV Work - Moving Boundary Work: W Fds P Ads PDV

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Work is the energy transfer

between system and surroundings


4-1 PdV WORK – MOVING BOUNDARY WORK during the process

A Work out is used for something outside:


rotate the shaft, overcome friction, etc.
pressure at the
force acting on
inner surface P F = PA
the moving boundary
of the boundary

 3 kN 3 
dS  kPa ⋅ m = m 2 ⋅ m = kN ⋅ m = kJ 
 
dV
 
dV = AdS δ W = F ⋅ dS = P ⋅ ( A ⋅ dS ) = PdV differential boundary work (4-1)

Boundary work done during the process Work done during a cycle

P P P
2
1
W = ∫ δW [ kJ ] 1−2 1−2
1

Wnet > 0 Wnet < 0


2 2
W = ∫ PdV (4-2)
W 1
V V V
V1 V2

total boundary work is equal to the area difference between the work done by the system
under the path (depends on path) ( 4-3 ) and the work done on the system

compression expansion
W <0 W >0
Direction of boundary work
work on system work by system

dV < 0 dV > 0

in out
P P

2 1

1
W <0 W >0 2
− +
V V
V2 V1 V1 V2

Constant pressure process P P


W = P ⋅ (V2 − V1 ) < 0 W = P ⋅ (V2 − V1 ) > 0
2 1 1 2
2
W = ∫ PdV = P ⋅ (V2 − V1 ) W <0
W
W <0
W
1
− in − out
V V
V2 V1 V1 V2
compression expansion

Boundary work assume the only work sign will be adjusted


Qnet ,in − Wboundary
in the 1st Law is the PdV work Wboundary automatically

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