Worksheet-2 Juniors Mole Concept

1. Chlorophyll contains 2.68% of magnesium by mass. Calculate the number of magnesium atoms in 3 grams of
chlorophyll. (Atomic mass of Mg = 24)

2. Each molecule of haemoglobin contains four iron atoms. (Atomic mass of iron = 56). If haemoglobin contains
0.32% of iron by weight, what will be the molecular weight of haemoglobin.

3. Find the ratio of number of molecules contained in 1gram of NH 3 and 1 gram of Nitrogen.

4. On an wedding day, bride and bridegroom exchanged diamond rings. The diamond is only made of carbon
atoms. The weight of diamond in their rings combinedly is 8g. Weight of diamond in bride’s ring is twice that of
bridegroom’s. Calculate the number of C atoms present in the diamond ring of bridegroom.

5. Calculate the number of moles of SO2Cl2 in 13.5 grams of it.

6. An ore contains 1.34 % of the mineral Argentite, Ag2S by weight. How many grams of this ore would have to
be processed in order to obtain 1g of pure solid silver, Ag?

7. (a) If the atomic weight of nitrogen is expressed as 14 amu, how many atoms would it represent?
(b) If the atomic weight of nitrogen is expressed as 14 grams, how many atoms would it represent?

35
8. Chlorine has two naturally occurring isotopes Cl17 with an abundance of 75.77% and an atomic weight of
37
34.969 amu, and Cl17 with an abundance of 24.23% and an atomic weight of 36.966 amu. What is the
average atomic weight of chlorine.
9. If you won 1 mol of Rupees in a lottery the day you were born and spent a billion rupees every second,
how much percentage still you will have the prize money the day when you will die at the age of ninety
years.
i) What is the mass of 3.01  10 molecules of ammonia?
23
10.
ii) How many molecules and atoms are present in 11.2 litre of chlorine at STP

11. 1 mole of Glucose (C6H12O6) consists of

(A) 6 gram molecules of H2 (B) 6 gram atoms of carbon
(C) 12 gram atoms of Hydrogen (D) All of these

12. Weight of a molecule of the compound C60 H22 is

-21 -21 23 23
(A) 1.09 x 10 g (B) 1.24 x 10 (C) 5.025 x 10 g (D) 16.02 x 10 g

13. The volume of one mole of a gas at standard temperature and pressure is
(A) 11.2 litres (B) 22.4 litres (C) 100 litres (D) 5.6 litres

14. How many years it would take to spend Avogadro’s number of rupees at the rate of 10 lac rupees per
second?

15. Calculate the no. of moles of water in 488 g BaCl2. 2H2O. (Ba = 137, Cl = 35.5, O = 16, H = 1)

16. If molecular mass and atomic mass of sulphur are 256 and 32 respectively, its atomicity is
(A) 2 (B) 4 (C) 8 (D) 16

17. Number of atoms in 22 g of CO2 is:-

(A) 3  6.023  10 (B) 21.5  6.023  10 (C) 1.5  6.023  10 (D) 2.5  6.023  10
23 23 23 23
18. The percentage of oxygen in NaOH is
(A) 40 (B) 16 (C) 8 (D) 1

19. Which of the following specimens has highest weight?

(A) One atom of silver (B) One mole of SO2
(C) One grams atoms of nitrogen (D) Two grams of sodium
20. Calculate the no. of molecules present in 350 CC of NH3 gas at 273 K and 1 atm pressure is
22 22 21 21
(A) 1.882 x 10 (B) 18.82 x 10 (C) 1.882 x 10 (D) 18.82 x 10

21. Number of neutrons present in 8g of methane gas, are

24 22 23 23
(A) 1.8066 x 10 (B) 18.82 x 10 (C) 1.8066 x 10 (D) 1.5 x 10

22. Number of atoms in 5.6 L of He gas at STP is

22 23 22 23
(A) 1.51 x 10 (B) 1.51 x 10 (C) 15.1 x 10 (D) 1.51 x 10

23. Which of the following expressions is correct (n = no. of moles of the gas, N A = Avogadro constant, m =mass
of one molecule of the gas, N = no. of molecules of the gas ) ?
(A) n = mNA (B) m = NA (C) N = nNA (D) m = mn/NA

24. 2 moles of N atoms at NTP occupy a volume of

(A) 11.2 L (B) 44.8 L (C) 22.4 L (D) 5.6 L

25. Which of the following contains the greatest number of atoms,

(A) 1g of butane (C4H10) (B) 1g of Nitrogen (N2)
(C) 1g of silver (Ag) (D) 1g of water (H2O)

26. In which of the following pairs do 1g of each have an equal number of molecules ?
(A) N2O and CO (B) N2 and C3O2 (C) N2 & CO (D) N2O and CO2

27. The atomic weights of two elements A and B are 40 and 80 respectively. If x g of A contains Y atoms, how
many atoms are present in 2xg of B.
Y Y
(A) (B) (C) Y (D) 2Y
2 4

28. Which of the following will contain same number of atoms as 20g of calcium.
(A) 24 g magnesium (B) 12 g carbon
(C) 8g of oxygen gas. (D) 16g of oxygen gas.

22
29. 4.6 x 10 atoms of an element weight 13.5 gm. The atomic mass of the element is
(A) 290 (B) 180 (C) 344 (D) 104

30. Which of the following contains the least no of molecules

(A) 1 gm CO2 (B) 1 gm N2 (C) 1 gm O2 (D) 1 gm H2

31. A polystyrene of formula Br3 C6 H2 (C8 H8)n was prepared by heating styrene with tribromobenzoyl peroxide in
the absence of air. If it was found to contain 10.46% Bromine by weight. Find the value of n.
(Atomic mass of Br = 80 g)

32. Which of the following contains the same no. of atoms as 20 gm of calcium
(A) 24 gm of Mg (B) 12 gm of Mg (C) 24 gm of C (D) 12 gm of C
33. Avogadro’s number is the no. of molecules present in
(A) One litre of the gas at N.T.P. (B) 22.4 litre of gas at N.T.P.
(C) 22.4 ml of the gas at N.T.P. (D) 44.8 litre of the gas at N.T.P.

34. One atomic mass unit is equivalent to

–27 –27 –27 –27
(A) 1.66 x 10 g (B) 1.66 x 10 kg (C) 1.66 x 10 mg (D) 1.66 x 10 cg

35. The atomic mass of an element is measured relative to the mass of (Now a days)
(A) hydrogen atom (B) oxygen atom
12 13 14
(C) carbon–12 (D) isotopic mixture of C, C and C.

36. Avogadro’s Number is the number of molecules present in:

(A) 22.4 litres of a gas at NTP (B) 1g – molecule of a substance
(C) 32 g of oxygen (D) 6gm of carbon

37. Which of the following is correct?

23
(A) g–mole wt. = mol. Wt. in g = wt. of 6.02 x 10 molecules
23
(B) Mole = N molecule = 6.02 x 10 molecules
(C) Mole = g – molecules (D) Mole = 1g. atom.

38. 8g of O2 has the same number of molecules as :

(A) 7g of CO (B) 14 g of CO (C) 28 g of CO (D) 11g of CO2

39. 11.2 litre of a gas at STP weighs 14g. The gas could not be :
(A) N2 (B) CO (C) B2H6 (D) N2O

40. The weight of Ca present in Ca(NO3)2 that contains 20g of nitrogen, is

20  28 28 40  28 40  20
(A) (B) (C) (D)
40 40  20 20 28

41. 0.44 g of an oxide of nitrogen occupies 224 ml at, STP, molecular formula is
(A) N2O (B) NO (C) N2O4 (D) N2O3

23 23
42. The weight of gaseous mixture containing 6.02 x 10 molecules of nitrogen and 3.01 x 10 molecules of SO2
(A) 46 (B) 92 (C) 60 (D) 30

43. The weight of a piece of copper is 0.635 g. The number of copper atoms present in it are (N = Avogadro’s no.)
(A) 0.05N (B) 0.1 N (C) 0.01 N (D) 1 N

44. Match the following:

Column – I Column – II

(A) 52g of He (P) 13 atoms

(B) 52 moles of He (Q) 44.8 L
23
(C) 34 g of NH3 (R) 313.196 x 10 atoms
23
(D) 52 u of He (S) 78.299 x 10 atoms
45. Match the following :
Column – I Column – II
23
(A) Volume in litre of 0.1 mole of CO2 at N.T.P (P) 12.046 x 10
(B) No. of oxygen atoms in 44g of CO2 (Q) 110
(C) Total number of molecules in 100 g of (R) 2.24
limestone
Total number of electrons in five azide  N3 
23
(D) (S) 6.023 x 10

ions

46. Molarity of 4% (w/v) NaOH solution is

(A) 1 M (B) 4 M (C) 0.1 M (D) 0.4 M

47. Molarity of 10.6% (w/v) Na2CO3 solution is

(A) 1 M (B) 10.6 M (C) 2 M (D) 0.1 M

3
48. Molarity of a solution containing 4.9 gm of H2SO4 in 100 cm of its solution is
(A) 1 M (B) 0.5 M (C) 5 M 4(D) 0.1 M

3
49. The amount of Na2CO3 present in 500 cm of decimolar of its solution is
(A) 5.3 gm (B) 0.005 mol (C) 5.3 mol (D) 0.05 gm

3
50. The weight of NaOH present in 100 cm of semimolar its solution is
(A) 2 gm (B) 4 gm (C) 40 gm (D) 8 gm

3
51. The number of millimoles present in 200 cm of 0.2 M of a solution is
(A) 4 (B) 0.4 (C) 40 (D) 400

3
52. The total particle concentration in 100 cm of 0.2 M Al2(SO4)3 solution is
(A) 1 Mole (B) 10 Mole (C) 0.1 Mole (D) 0.4 Mole

3
53. The number of molecules of NaOH present in 100 cm of decimolar its solution is
(A) N (B) N/10 (C) N/100 (D) N/1000

3
54. The molarity of a solution containing 0.4 gm mole of NaOH in 100 cm of its solution is
(A) 4 M (B) 0.4 M (C) 0.2 M (D) 1 M

55. A solution of glucose is 18% (w/v). What volume of this solution contains 1 gm mole of glucose
3 3 3 3
(A) 1 m (B) 1 dm (C) 1 cm (D) 10 dm

3 3
56. What volume of water must be added to prepare 75 cm of decimolar NaCl solution from 30 cm of 0.25 M of
NaCl solution
3 3 3 3
(A) 30 cm (B) 45 cm (C) 75 cm (D) 150 cm

57. A person adds 1.71 gram sugar (C12H22O11) in order to sweeten his tea. The number of carbon atoms added
are (mol. mass of sugar = 342)
22 21 22
(A) 3.6 x 10 (B) 7.2 x 10 (C) 0.05 (D) 6.6 x 10

–1
58. The total number of electrons present in 18 ml of water (density of water is 1 g ml ) is
22 23 24 25
(A) 6.02 x 10 (B) 6.02 x 10 (C) 6.02 x 10 (D) 6.02 x 10
 21
59. If 10 molecules are removed from 200 mg of CO2, then the number of moles of CO2 left are
–3 –3 –3 –2
(A) 2.88 x 10 (B) 28.8 x 10 (C) 0.288 x 10 (D) 1.66 x 10

22
60. The weight of 1 x 10 molecules of CuSO4. 5H2O is
(A) 41.59g (B) 415.9 g (C) 4.159g (D) none of three

61. How many g of KCl would have to be dissolved in 60g of H2O to give 20% by weight solution
(A) 15g (B) 1.5g (C) 11.5g (D) 31.5g

62. The volume occupied by one molecule of water (density = 1g /cc) is

(A) 18 cm3 (B) 22400 cm2 (C) 6.023  1023 cm3 (D) 3  1023 cm3

63. Equal weights of SO2 and SO3 are present in a flask. Mole fraction of SO2 in the mixture is
(A) greater than that of SO3 (B) smaller than that of SO3
(C) equal to that of SO3 (D) None of these

64. 2g mixture of H2 and He gases have mole fraction of H2 as 0.5. Hence mole fraction of He is
(A) 0.25 (B) 0.5 (C) 1.0 (D) 1.5

63
65. The atomic mass of copper is 63.546. There are only two naturally occurring isotopes of coper, Cu and
65 63
Cu . The natural abundance of the Cu isotope must be approximate.
(A) 10% (B) 30% (C) 50% (D) 73%

66. Molality of 40% (by mass) urea solution is

(A) 0.40 (B) 0.60 (C) 11.11 (D) 0.167

67. 224 ml of a triatomic gas weighs 1g at 273K and 1 atm. The mass of one atom of this gas is
(A) 8.30  1023 g (B) 2.08  1023 g (C) 5.53  1023 g (D) 6.24  1023 g

68. A compound posses 8% sulphur by mass. The least molecular mass is

(A) 200 (B) 400 (C) 155 (D) 355

69. Which of the following has the smallest number of molecules?

3
(A) 0.1 mol of CO2 gas (B) 11.2 L of CO2 gas (C) 22 gm of CO2 gas (D) 22.4 × 10 ml of CO2 gas

70. The volume of 1.0 g of hydrogen in litres at NTP is

(A) 2.24 (B) 22.4 (C) 1.12 (D) 11.2

71. The specific gravity of 36.5% by weight of HCl solution is 1.18, its molarity is
(A) 1.18 M (B) 11.8 M (C) 2 M (D) 9.2 M

3
72. The molarity of 500 cm of a solution containing 2 gm of 98% pure phosphoric acid is
(A) 4 M (B) 0.4 M (C) 0.04 M (D) 40 M

3
73. The molarity of 500 cm of a solution containing 5 gm of 80% pure NaOH is
(A) 0.1 M (B) 0.2 M (C) 0.4 M (D) 0.02 M
 3
74. The amount of 98% pure Na2CO3 required to prepare 500 cm of 0.5 M of its solution is
(A) 27 gm (B) 26.5 gm (C) 0.25 mol (D) 2.5 mol

3
75. The weight of 80% pure NaOH required to prepare 100 cm of decimolar its solution is
(A) 0.4 gm (B) 4 gm (C) 8 gm (D) 0.5 gm

76. A solution of glucose is 18% (w/v). What volume of this solution contains 1 gm mole of glucose
3 3 3 3
(A) 1 m (B) 1 dm (C) 1 cm (D) 10 dm

3
77. The molarity of a solution containing 0.01 weights of NaCl in 500 cm of its solution is
(A) 0.01 M (B) 0.02 M (C) 0.03 M (D) 0.1 M

3
78. Molarity of HCl solution is 12 M. What volume of water must be added to 200 cm of the acid to get 0.5 M HCl
solution
3 3 3 3
(A) 4.8 dm (B) 4.6 dm (C) 2.6 dm (D) 1 dm

79. The molarity of a solution is 2 M. It is diluted by four times. What is the final molarity
(A) 0.1 M (B) 0.5 M (C) 2 M (D) 1.5 M

3 3
80. 20 cm of 0.1 M H2SO4 is neutralized by 40 cm of NaOH solution. The molarity of NaOH solution is
(A) 0.1 M (B) 0.01 M (C) 0.2 M (D) 0.6 M

3
81. The volume of decimolar NaOH solution required to neutralize completely 20 cm of 0.05 M oxalic acid
solution is
3 3 3 3
(A) 200 cm (B) 10 cm (C) 40 cm (D) 20 cm

3
82. The volume of 0.025 M phosphoric acid required to neutralize 25 cm of 0.05 M Ca(OH)2 solution is
3 3 3 3
(A) 75 cm (B) 25 cm (C) 33.34 cm (D) 150 cm

3
83. The volume of 2 M H2SO4 required to neutralize 100 cm of a solution containing 4 gm of NaOH is
3 3 3 3
(A) 250 cm (B) 25 cm (C) 500 cm (D) 50 cm

3
84. The volume of 1 M NaOH solution required to convert 100 cm containing 12 gm of NaH2PO4 completely to
Na3PO4 is
3 3 3 3
(A) 200 cm (B) 20 cm (C) 2 dm (D) 500 cm

3 3
85. 100 cm of 0.1 M KMnO4 solution oxidizes 200 cm of 'x' M FeSO4 solution. The value of 'x' is
(A) 2.5 M (B) 0.25 M (C) 0.5 M (D) 1 M

3 3
86. 100 cm of 0.2 M K2Cr2O7 solution oxidizes x cm of 0.1 M FeSO4 solution. The value of 'x' is
3 3 3 3
(A) 1.2 dm (B) 12 dm (C) 1 dm (D) 4 dm

87. To prepare 3 M solution from 2 M and 6 M solutions, in what volume ratio they must be mixed
(A) 3 : 1 (B) 6 : 1 (C) 4 : 1 (D) 1 : 2

3
88. The molarity of chloride ions in the resultant solution obtained by mixing 100 cm of 0.2 M NaCl solution and
3
200 cm of 0.1 M BaCl2 solution
(A) 1.2 M (B) 0.2 M (C) 2.0 M (D) 4 M
89.
3 3
100 cm of 0.1 M NaCl solution is mixed with 100 cm of 0.2 M AgNO3 solution. The concentration of NO3
ion in the resultant solution is
(A) 50 M (B) 5 M (C) 0.1 M (D) 0.05 M

90. There are four solutions A, B, C and D obtained by mixing acids in various proportions as mentioned below.
The correct order of their molarities
3 3
[A] : 100 cm of 0.1 M HCl + 200 cm of 0.2 M HNO3
3 3
[B] : 200 cm of 0.2 M H2SO4 + 100 cm of 0.4 M HNO3
3 3
[C] : 300 cm of 0.1 M HCl + 300 cm of 0.1 M H2SO4
3 3
[D] : 500 cm of 0.2 M HCl + 500 cm of 0.1 M H2SO4
(A) A > B > C > D (B) A < B < C < D (C) B > A > D > C (D) B > D > C > A

Answers
2  10 1  10
21 23
1. atoms 2. 70,000 3. 28 : 17 4. atoms
(a) one atom (b) 6.023  10
23
5. 0.1 6. 85.68 7. atoms
8. 35.45 amu 9. 99.99%
(i) 8.5 g (ii) 3.01  10 molecules and 6.022  10
23 -23
10. atom.
10
11. D 12. B 13. B 14. 1.9099 x 10 years.
15. 4 16. C 17. C 18. A 19. B
20. A 21. C 22. A 23. B 24. B
25. B 26. B 27. C 28. C 29. B
30. A 31. 19 32. B 33. B 34. B
35. C 36. A, B, C 37. A, B, C, D 38. A, D 39. D
40. D 41. A 42. C 43. C
44. A  s ; B  r; C  q ; D  p 45. Ar;Bp;Cs;Dq
46. A 47. A 48. B 49. A 50. A
51. C 52. C 53. C 54. A 55. B
56. B 57. A 58. C 59. A 60. C
61. A 62. D 63. A 64. B 65. D
66. C 67. C 68. C 69. B 70. A
71 B 72. C 73. B 74. C 75. D
76. B 77. B 78. B 79. B 80. A
81. D 82. C 83. B 84. A 85. B
86. A 87. A 88. B 89. C 90. C