Particle Physics: Non-Relativistic QM (Revision)

Particle Physics
Michaelmas Term 2009

Prof. Mark Thomson
P+ P+
e- e+ e- e+
P- P-
P+ P+
e- e+ e- e+
P- P-
Handout 2 : The Dirac Equation

Prof. M.A. Thomson Michaelmas 2009 44
Non-Relativistic QM (Revision)
• For particle physics need a relativistic formulation of quantum mechanics. But
first take a few moments to review the non-relativistic formulation QM
• Take as the starting point non-relativistic energy:
• In QM we identify the energy and momentum operators:
which gives the time dependent Schrödinger equation (take V=0 for simplicity)
(S1)
with plane wave solutions: where
•The SE is first order in the time derivatives and second order in spatial
derivatives – and is manifestly not Lorentz invariant.
•In what follows we will use probability density/current extensively. For
the non-relativistic case these are derived as follows
(S1)* (S2)
•Which by comparison with the continuity equation
leads to the following expressions for probability density and current:
•For a plane wave

and
The number of particles per unit volume is

For particles per unit volume moving at velocity , have passing
through a unit area per unit time (particle flux). Therefore is a vector in the
particle’s direction with magnitude equal to the flux.
The Klein-Gordon Equation

•Applying to the relativistic equation for energy:
(KG1)
gives the Klein-Gordon equation:
(KG2)
•Using
KG can be expressed compactly as (KG3)

•For plane wave solutions, , the KG equation gives:
Not surprisingly, the KG equation has negative energy solutions – this is

just what we started with in eq. KG1
Historically the –ve energy solutions were viewed as problematic. But for the KG
there is also a problem with the probability density…
•Proceeding as before to calculate the probability and current densities:
(KG2)* (KG4)
•Which, again, by comparison with the continuity equation allows us to identify
•For a plane wave

and
Particle densities are proportional to E. We might have anticipated this from the
previous discussion of Lorentz invariant phase space (i.e. density of 1/V in the
particles rest frame will appear as E/V in a frame where the particle has energy E
due to length contraction).
The Dirac Equation

Historically, it was thought that there were two main problems with the
Klein-Gordon equation:
Negative energy solutions
The negative particle densities associated with these solutions
We now know that in Quantum Field Theory these problems are
overcome and the KG equation is used to describe spin-0 particles.
Nevertheless:
These problems motivated Dirac (1928) to search for a
different formulation of relativistic quantum mechanics
in which all particle densities are positive.
The resulting wave equation had solutions which not only

solved this problem but also fully describe the
intrinsic spin and magnetic moment of the electron!

The Dirac Equation :
•Schrödinger eqn: 1st order in
2nd order in
• Klein-Gordon eqn: 2nd order throughout
• Dirac looked for an alternative which was 1st order throughout:
(D1)
where is the Hamiltonian operator and, as usual,
•Writing (D1) in full:
“squaring” this equation gives
• Which can be expanded in gory details as…
• For this to be a reasonable formulation of relativistic QM, a free particle

must also obey , i.e. it must satisfy the Klein-Gordon equation:
• Hence for the Dirac Equation to be consistent with the KG equation require:
(D2)
(D3)
(D4)
Immediately we see that the and cannot be numbers. Require 4
mutually anti-commuting matrices
Must be (at least) 4x4 matrices (see Appendix I)
•Consequently the wave-function must be a four-component Dirac Spinor
A consequence of introducing an equation
that is 1st order in time/space derivatives is that
the wave-function has new degrees of freedom !
• For the Hamiltonian to be Hermitian

requires
(D5)
i.e. the require four anti-commuting Hermitian 4x4 matrices.
• At this point it is convenient to introduce an explicit representation for .
It should be noted that physical results do not depend on the particular
representation – everything is in the commutation relations.
• A convenient choice is based on the Pauli spin matrices:
with
• The matrices are Hermitian and anti-commute with each other

Dirac Equation: Probability Density and Current

•Now consider probability density/current – this is where the perceived
problems with the Klein-Gordon equation arose.
•Start with the Dirac equation
(D6)
and its Hermitian conjugate
(D7)
•Consider remembering are Hermitian
•Now using the identity:

gives the continuity equation (D8)
where
•The probability density and current can be identified as:
and
where
•Unlike the KG equation, the Dirac equation has probability densities which
are always positive.
• In addition, the solutions to the Dirac equation are the four component
Dirac Spinors. A great success of the Dirac equation is that these
components naturally give rise to the property of intrinsic spin.
• It can be shown that Dirac spinors represent spin-half particles (appendix II)
with an intrinsic magnetic moment of
(appendix III)
Covariant Notation: the Dirac J Matrices

•The Dirac equation can be written more elegantly by introducing the
four Dirac gamma matrices:
Premultiply the Dirac equation (D6) by
using this can be written compactly as:
(D9)
NOTE: it is important to realise that the Dirac gamma matrices are not
four-vectors - they are constant matrices which remain invariant under a
Lorentz transformation. However it can be shown that the Dirac equation
is itself Lorentz covariant (see Appendix IV)
Properties of the J matrices
•From the properties of the and matrices (D2)-(D4) immediately obtain:
and
•The full set of relations is
which can be expressed as:
• Are the gamma matrices Hermitian?

is Hermitian so is Hermitian.
The matrices are also Hermitian, giving
Hence are anti-Hermitian
Pauli-Dirac Representation
•From now on we will use the Pauli-Dirac representation of the gamma matrices:
which when written in full are
•Using the gamma matrices and can be written as:
where is the four-vector current.

(The proof that is indeed a four vector is given in Appendix V.)
•In terms of the four-vector current the continuity equation becomes
•Finally the expression for the four-vector current
can be simplified by introducing the adjoint spinor

The Adjoint Spinor
• The adjoint spinor is defined as
i.e.
•In terms the adjoint spinor the four vector current can be written:
We will use this expression in deriving the Feynman rules for the
Lorentz invariant matrix element for the fundamental interactions.
That’s enough notation, start to investigate the free particle solutions

of the Dirac equation...
Dirac Equation: Free Particle at Rest

•Look for free particle solutions to the Dirac equation of form:
where , which is a constant four-component spinor which must satisfy

the Dirac equation
•Consider the derivatives of the free particle solution
substituting these into the Dirac equation gives:
which can be written: (D10)

•This is the Dirac equation in “momentum” – note it contains no derivatives.
•For a particle at rest
and
eq. (D10)
(D11)
•This equation has four orthogonal solutions:
(D11) E=m (D11) E = -m

still have NEGATIVE ENERGY SOLUTIONS (Question 6)
• Including the time dependence from gives
Two spin states with E>0 Two spin states with E<0
In QM mechanics can’t just discard the E<0 solutions as unphysical

as we require a complete set of states - i.e. 4 SOLUTIONS
Dirac Equation: Plane Wave Solutions

•Now aim to find general plane wave solutions:
•Start from Dirac equation (D10):
and use
Note
Note in the above equation the 4x4 matrix is

written in terms of four 2x2 sub-matrices
•Writing the four component
spinor as
Giving two coupled

simultaneous equations (D12)
for
Expanding
•Therefore (D12)
gives
•Solutions can be obtained by making the arbitrary (but simplest) choices for
i.e. or
where N is the
giving and wave-function
normalisation
NOTE: For these correspond to the E>0 particle at rest solutions

The choice of is arbitrary, but this isn’t an issue since we can express any
other choice as a linear combination. It is analogous to choosing a basis for
spin which could be eigenfunctions of Sx, Sy or Sz
Repeating for and gives the solutions and
The four solutions are:
•If any of these solutions is put back into the Dirac equation, as expected, we obtain
which doesn’t in itself identify the negative energy solutions.

•One rather subtle point: One could ask the question whether we can interpret
all four solutions as positive energy solutions. The answer is no. If we take
all solutions to have the same value of E, i.e. E = +|E|, only two of the solutions
are found to be independent.
•There are only four independent solutions when the two are taken to have E<0.
To identify which solutions have E<0 energy refer back to particle at rest (eq. D11 ).
• For : correspond to the E>0 particle at rest solutions
correspond to the E<0 particle at rest solutions
So are the +ve energy solutions and are the -ve energy solutions
Interpretation of –ve Energy Solutions
The Dirac equation has negative energy solutions. Unlike the KG equation
these have positive probability densities. But how should –ve energy
solutions be interpreted? Why don’t all +ve energy electrons fall into
to the lower energy –ve energy states?
Dirac Interpretation: the vacuum corresponds to all –ve energy states
being full with the Pauli exclusion principle preventing electrons falling into
-ve energy states. Holes in the –ve energy states correspond to +ve energy
anti-particles with opposite charge. Provides a picture for pair-production
and annihilation.
.. .. ..
.. .. ..
mc2 mc2 mc2

J J
-mc2 -mc2 -mc2
.. .. ..
.. .. ..
Discovery of the Positron

Cosmic ray track in cloud chamber: C.D.Anderson, Phys Rev 43 (1933) 491
B
e 23 MeV 6 mm
Lead
Plate
e 63 MeV
• e+ enters at bottom, slows down in the

lead plate – know direction
• Curvature in B-field shows that it is a
positive particle
• Can’t be a proton as would have stopped in the lead
Provided Verification of Predictions of Dirac Equation
Anti-particle solutions exist ! But the picture of the vacuum corresponding to

the state where all –ve energy states are occupied is rather unsatisfactory, what
about bosons (no exclusion principle),….
Feynman-Stückelberg Interpretation
There are many problems with the Dirac interpretation of anti-particles
and it is best viewed as of historical interest – don’t take it too seriously.
Feynman-Stückelberg Interpretation:
Interpret a negative energy solution as a negative energy particle which
propagates backwards in time or equivalently a positive energy anti-particle
which propagates forwards in time
e– (E<0) e+ (E>0)
J J
time
e+ e-
E>0 E<0
e– (E>0) e– (E>0)
NOTE: in the Feynman diagram the arrow on the
anti-particle remains in the backwards in time
direction to label it an anti-particle solution.
At this point it become more convenient to work with anti-particle
wave-functions with motivated by this interpretation
Anti-Particle Spinors
•Want to redefine our –ve energy solutions such that:
i.e. the energy of the physical anti-particle.
We can look at this in two ways:

n Start from the negative energy solutions
Where E is understood to
be negative
•Can simply “define” anti-particle wave-function by flipping the sign

of and following the Feynman-Stückelburg interpretation:
where E is now understood to be positive,

Anti-Particle Spinors
o Find negative energy plane wave solutions to the Dirac equation of
the form: where
•Note that although these are still negative energy solutions
in the sense that
•Solving the Dirac equation
(D13)
Í The Dirac equation in terms of momentum for ANTI-PARTICLES (c.f. D10)
•Proceeding as before:
etc., …
•The same wave-functions that were written down on the previous page.
Particle and anti-particle Spinors

Four solutions of form:
Four solutions of form
Since we have a four component spinor, only four are linearly independent
Could choose to work with or or …
Natural to use choose +ve energy solutions

Wave-Function Normalisation
•From handout 1 want to normalise wave-functions
to particles per unit volume
•Consider
Probability density
which for the desired 2E particles per unit volume, requires that
•Obtain same value of N for
Charge Conjugation
• In the part II Relativity and Electrodynamics course it was shown that
the motion of a charged particle in an electromagnetic field
can be obtained by making the minimal substitution
with
this can be written
and the Dirac equation becomes:
•Taking the complex conjugate and pre-multiplying by
But and
(D14)
•Define the charge conjugation operator:

D14 becomes:
•Comparing to the original equation
we see that the spinor describes a particle of the same mass but with
opposite charge, i.e. an anti-particle !
particle spinor anti-particle spinor
•Now consider the action of on the free particle wave-function:
hence
similarly
Under the charge conjugation operator the particle spinors and
transform to the anti-particle spinors and
Using the anti-particle solutions

•There is a subtle but important point about the anti-particle solutions written as
Applying normal QM operators for momentum and energy

gives and
But have defined solutions to have E>0
Hence the quantum mechanical operators giving the physical energy and
momenta of the anti-particle solutions are:
and
•Under the transformation :
Conservation of total angular momentum
The physical spin of the anti-particle solutions is given by
0
A spin-up hole leaves the
In the hole picture: -mc2 negative energy sea in a spin
down state
.
Summary of Solutions To Dirac Equation
•The normalised free PARTICLE solutions to the Dirac equation:
satisfy
with
•The ANTI-PARTICLE solutions in terms of the physical energy and momentum:

satisfy
with
For these states the spin is given by

•For both particle and anti-particle solutions:
(Now try question 7 – mainly about 4 vector current )
Spin States
•In general the spinors are not Eigenstates of
(Appendix II)
•However particles/anti-particles travelling in the z-direction:
are Eigenstates of
Note the change of sign
of when dealing with
antiparticle spinors
z z
Spinors are only eigenstates of for

Pause for Breath…
•Have found solutions to the Dirac equation which are also eigenstates but
only for particles travelling along the z axis.
•Not a particularly useful basis
•More generally, want to label our states in terms of “good quantum numbers”,
i.e. a set of commuting observables.
•Can’t use z component of spin: (Appendix II)
•Introduce a new concept “HELICITY”
Helicity plays an important role in much that follows
Helicity
The component of a particles spin along its direction of flight is a good quantum
number:
Define the component of a particles spin along its direction of flight as HELICITY:
•If we make a measurement of the component of spin of a spin-half particle

along any axis it can take two values , consequently the eigenvalues
of the helicity operator for a spin-half particle are:
Often termed: “right-handed” “left-handed”

NOTE: these are “RIGHT-HANDED” and LEFT-HANDED HELICITY eigenstates
In handout 4 we will discuss RH and LH CHIRAL eigenstates. Only in the limit
are the HELICITY eigenstates the same as the CHIRAL eigenstates

Helicity Eigenstates
Wish to find solutions of Dirac equation which are also eigenstates of Helicity:
where and are right and left handed helicity states and here is
the unit vector in the direction of the particle.
•The eigenvalue equation:
gives the coupled equations:

(D15)
•Consider a particle propagating in direction
•Writing either or then (D15) gives the relation
(For helicity )
So for the components of BOTH and
•For the right-handed helicity state, i.e. helicity +1:
•Putting in the constants of proportionality gives:

•From the Dirac Equation (D12) we also have
(D16)
Helicity
(D15) determines the relative normalisation of and , i.e. here
•The negative helicity particle state is obtained in the same way.

•The anti-particle states can also be obtained in the same manner although
it must be remembered that
i.e.
The particle and anti-particle helicity eigenstates states are:
particles anti-particles
For all four states, normalising to 2E particles/Volume again gives

The helicity eigenstates will be used extensively in the calculations that follow.
Intrinsic Parity of Dirac Particles
non-examinable
Before leaving the Dirac equation, consider parity
The parity operation is defined as spatial inversion through the origin:
•Consider a Dirac spinor, , which satisfies the Dirac equation
(D17)
•Under the parity transformation:
Try
so
(D17)
•Expressing derivatives in terms of the primed system:
Since anti-commutes with :
Pre-multiplying by
•Which is the Dirac equation in the new coordinates.

There for under parity transformations the form of the Dirac equation is
unchanged provided Dirac spinors transform as
(note the above algebra doesn’t depend on the choice of )

•For a particle/anti-particle at rest the solutions to the Dirac Equation are:
with
etc.
Hence an anti-particle at rest has opposite intrinsic parity to a particle at rest.

Convention: particles are chosen to have +ve parity; corresponds to choosing

Summary
The formulation of relativistic quantum mechanics starting from the
linear Dirac equation
New degrees of freedom : found to describe Spin ½ particles

In terms of 4x4 gamma matrices the Dirac Equation can be written:
Introduces the 4-vector current and adjoint spinor:
With the Dirac equation: forced to have two positive energy and two
negative energy solutions
Feynman-Stückelberg interpretation: -ve energy particle solutions
propagating backwards in time correspond to physical +ve energy
anti-particles propagating forwards in time
Most useful basis: particle and anti-particle helicity eigenstates
In terms of 4-component spinors, the charge conjugation and parity

operations are:
Now have all we need to know about a relativistic description of

particles… next discuss particle interactions and QED.

Appendix I : Dimensions of the Dirac Matrices
non-examinable
Starting from
For to be Hermitian for all requires
To recover the KG equation:
Consider
with
Therefore
(using commutation relation)
similarly
We can now show that the matrices are of even dimension by considering
the eigenvalue equation, e.g.
Eigenvalues of a Hermitian matrix are real so

but
Since the are trace zero Hermitian matrices with eigenvalues of
they must be of even dimension
For N=2 the 3 Pauli spin matrices satisfy
But we require 4 anti-commuting matrices. Consequently the of the

Dirac equation must be of dimension 4, 6, 8,….. The simplest choice for
is to assume that the are of dimension 4.

Appendix II : Spin
non-examinable
•For a Dirac spinor is orbital angular momentum a good quantum number?
i.e. does commute with the Hamiltonian?
Consider the x component of L:
The only non-zero contributions come from:
Therefore (A.1)
Hence the angular momentum does not commute with the Hamiltonian
and is not a constant of motion
Introduce a new 4x4 operator:
where are the Pauli spin matrices: i.e.
Now consider the commutator
here
and hence
Consider the x comp:

Taking each of the commutators in turn:
Hence
•Hence the observable corresponding to the operator is also not

a constant of motion. However, referring back to (A.1)
Therefore:
•Because
the commutation relationships for are the same as for the , e.g.
. Furthermore both S and Sz are diagonal
2
•Consequently and for a particle travelling along

the z direction
S has all the properties of spin in quantum mechanics and therefore the
Dirac equation provides a natural account of the intrinsic angular
momentum of fermions
Appendix III : Magnetic Moment
non-examinable
• In the part II Relativity and Electrodynamics course it was shown that
the motion of a charged particle in an electromagnetic field
can be obtained by making the minimal substitution
• Applying this to equations (D12)

(A.2)
Multiplying (A.2) by
(A.3)
where kinetic energy
•In the non-relativistic limit (A.3) becomes
(A.4)
•Now
which leads to
and
•The operator on the LHS of (A.4):
Substituting back into (A.4) gives the Schrödinger-Pauli equation for

the motion of a non-relativisitic spin ½ particle in an EM field

Since the energy of a magnetic moment in a field is we can
identify the intrinsic magnetic moment of a spin ½ particle to be:
In terms of the spin:
Classically, for a charged particle current loop
The intrinsic magnetic moment of a spin half Dirac particle is twice

that expected from classical physics. This is often expressed in terms
of the gyromagnetic ratio is g=2.
Appendix IV : Covariance of Dirac Equation

non-examinable
•For a Lorentz transformation we wish to demonstrate that the Dirac
Equation is covariant i.e.
(A.5)
transforms to (A.6)
where
and is the transformed spinor.

•The covariance of the Dirac equation will be established if the 4x4 matrix
S exists.
•Consider a Lorentz transformation with the primed frame moving with
velocity v along the x axis
where

With this transformation equation (A.6)
which should be compared to the matrix S multiplying (A.5)
Therefore the covariance of the Dirac equation will be demonstrated if

we can find a matrix S such that
(A.7)
•Considering each value of
where
and
•It is easy (although tedious) to demonstrate that the matrix:
with
satisfies the above simultaneous equations
NOTE: For a transformation along in the –x direction
To summarise, under a Lorentz transformation a spinor transforms

to . This transformation preserves the mathematical
form of the Dirac equation

Appendix V : Transformation of Dirac Current
non-examinable
The Dirac current plays an important rôle in the description
of particle interactions. Here we consider its transformation properties.
•Under a Lorentz transformation we have
and for the adjoint spinor:
•First consider the transformation properties of
where
giving
hence
The product is therefore a Lorentz invariant. More generally, the
product is Lorentz covariant
Now consider
•To evaluate this wish to express in terms of

(A.7)
where we used
•Rearranging the labels and reordering gives:
Hence the Dirac current, , transforms as a four-vector


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Particle Physics

Michaelmas Term 2009

Handout 2 : The Dirac Equation

• In QM we identify the energy and momentum operators:

with plane wave solutions: where

leads to the following expressions for probability density and current:

•For a plane wave

The number of particles per unit volume is

The Klein-Gordon Equation

KG can be expressed compactly as (KG3)

 Not surprisingly, the KG equation has negative energy solutions – this is

•Which, again, by comparison with the continuity equation allows us to identify

•For a plane wave

The Dirac Equation

The resulting wave equation had solutions which not only

Prof. M.A. Thomson Michaelmas 2009 49

•Writing (D1) in full:

“squaring” this equation gives

• Which can be expanded in gory details as…

Prof. M.A. Thomson Michaelmas 2009 50

• For this to be a reasonable formulation of relativistic QM, a free particle

• For the Hamiltonian to be Hermitian

• The matrices are Hermitian and anti-commute with each other

Dirac Equation: Probability Density and Current

•Consider remembering are Hermitian

•Now using the identity:

Prof. M.A. Thomson Michaelmas 2009 53

Prof. M.A. Thomson Michaelmas 2009 54

Covariant Notation: the Dirac J Matrices

Premultiply the Dirac equation (D6) by

using this can be written compactly as:

which can be expressed as:

• Are the gamma matrices Hermitian?

 Hence are anti-Hermitian

Prof. M.A. Thomson Michaelmas 2009 56

which when written in full are

•Using the gamma matrices and can be written as:

where is the four-vector current.

•Finally the expression for the four-vector current

can be simplified by introducing the adjoint spinor

That’s enough notation, start to investigate the free particle solutions

Dirac Equation: Free Particle at Rest

where , which is a constant four-component spinor which must satisfy

•Consider the derivatives of the free particle solution

substituting these into the Dirac equation gives:

which can be written: (D10)

•This equation has four orthogonal solutions:

(D11) E=m (D11) E = -m

In QM mechanics can’t just discard the E<0 solutions as unphysical

Dirac Equation: Plane Wave Solutions

Note in the above equation the 4x4 matrix is

Giving two coupled

NOTE: For these correspond to the E>0 particle at rest solutions

Repeating for and gives the solutions and

 The four solutions are:

which doesn’t in itself identify the negative energy solutions.

mc2 mc2 mc2

Prof. M.A. Thomson Michaelmas 2009 64

Discovery of the Positron

The number of particles per unit volume is

Not surprisingly, the KG equation has negative energy solutions – this is

The resulting wave equation had solutions which not only

Hence are anti-Hermitian

That’s enough notation, start to investigate the free particle solutions

In QM mechanics can’t just discard the E<0 solutions as unphysical

The four solutions are:

Anti-particle solutions exist ! But the picture of the vacuum corresponding to

Four solutions of form

The physical spin of the anti-particle solutions is given by

(D15) determines the relative normalisation of and , i.e. here

The particle and anti-particle helicity eigenstates states are:

For all four states, normalising to 2E particles/Volume again gives

Hence an anti-particle at rest has opposite intrinsic parity to a particle at rest.

Introduces the 4-vector current and adjoint spinor:

Most useful basis: particle and anti-particle helicity eigenstates

In terms of 4-component spinors, the charge conjugation and parity

Now have all we need to know about a relativistic description of