Pressure Temperature Moles Grams

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Problem Set in Gas Laws

1. Use ideal gas law to complete the following table for propane (C 3H8) gas.

Pressure Volume Temperature Moles Grams


18.9 psi 0.886L 22oC
633 mmHg 1.993L 0.0844
1.876 atm 75oF 2.482
o
2244 mL 13 C 47.25
1.15L 39oF 0.166
2. Calculate the densities (g/L) of the following gases at 78 oF and 13.6 psi
a. Butane b. acetylene c. methane
3. Phosgene is a highly toxic gas made up of carbon, oxygen and chlorine atoms. Its density at 1.05
atm and 25oC is 4.24 g/L
a. What is the molar mass of phosgene?
b. Phosgene is made up of 12.1% C, 16.2% O, and 71.7% Cl. What is the molecular formula of
phosgene?
4. A 0.750 g sample of the gas PX3 is in a sealed 542 mL bulb at 26oC and 1.0 atm pressure.
Identify the element X and name the gas.
5. Nitrogen trifluoride gas reacts with steam to produce the gases HF, NO and NO 2.
a. Write a balanced equation for the reaction.
b. What volume of the nitrogen oxide is formed when 5.22 L of nitrogen fluoride are made to
react with 5.22 L of steam? Assume 100% yield and constant temperature and pressure
conditions throughout the reaction.
6. A certain laser uses a gas mixture consisting of 9.0 g HCl, 2.00g H 2, and 16.5 g of Ne. what
pressure is exerted by the mixture in a 75.0 L tank at 22 oC? which gas has the smallest partial
pressure?
7. Nitrogen gas can be obtained by decomposing ammonium nitrate at high temperatures. The
nitrogen gas is collected over water in a 500 mL flask in 19 oC. the ambient pressure is 745
mmHg. (vapor pressure of water at 19oC is 16.48 mmHg).
a. What is the partial pressure of nitrogen ?
b. How many moles of water are there in the wet gas?
c. How many moles of dry gas are collected?
d. If 0.128 g of Ne are added to the flask at the same temperature, what is the partial pressure
of neon in the flask?
e. What is the total pressure after Neon is added?
8. A gas effuses through an opening one-fifth as fast as helium gas effuses through the same
opening.
a. Is the gas heavier than helium?
b. What is the molar mass of the gas?
9. At a certain temperature it takes 11.2 seconds for 1.78x10 -3 mol of NH3 gas to effuse through a
pinhole. Under the same conditions, how long will it take for the same amount of phosphine
gas, PH3, to effuse through the same pinhole?
10. Calculate the average speed of a
a. chlorine molecule at -32oC
b. UF6 molecule at room temperature (25oC)

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