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    CHY 47 Assignment #3 Group No. 2: - Log (Ka) Ka Ka Ka Ka Ka Ka

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    1. This document contains a chemistry assignment with multiple questions about acids, bases, pH, and buffer solutions. 2. Question 1 involves calculating pH, [H+], and [OH-] values for various solutions given their pH. Question 2 calculates the pH of an acetic acid solution. 3. Question 3 adds NaOH to the acetic acid solution, calculates concentrations after reaction, and finds the new pH. 4. Question 4 prepares an ammonia/ammonium chloride buffer and calculates its pH. Additional parts add NaOH or HCl and recalculate pH. 5. Question 5 writes the chemical equations for the reactions in parts 4b and 4c.

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    CHY 47 Assignment #3 Group No. 2: - Log (Ka) Ka Ka Ka Ka Ka Ka

    Uploaded by

    Fengari Cresent
    34 views4 pages
    1. This document contains a chemistry assignment with multiple questions about acids, bases, pH, and buffer solutions. 2. Question 1 involves calculating pH, [H+], and [OH-] values for various solutions given their pH. Question 2 calculates the pH of an acetic acid solution. 3. Question 3 adds NaOH to the acetic acid solution, calculates concentrations after reaction, and finds the new pH. 4. Question 4 prepares an ammonia/ammonium chloride buffer and calculates its pH. Additional parts add NaOH or HCl and recalculate pH. 5. Question 5 writes the chemical equations for the reactions in parts 4b and 4c.

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    Buffers

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    1. This document contains a chemistry assignment with multiple questions about acids, bases, pH, and buffer solutions. 2. Question 1 involves calculating pH, [H+], and [OH-] values for various solutions given their pH. Question 2 calculates the pH of an acetic acid solution. 3. Question 3 adds NaOH to the acetic acid solution, calculates concentrations after reaction, and finds the new pH. 4. Question 4 prepares an ammonia/ammonium chloride buffer and calculates its pH. Additional parts add NaOH or HCl and recalculate pH. 5. Question 5 writes the chemical equations for the reactions in parts 4b and 4c.

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    © All Rights Reserved
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    Download as docx, pdf, or txt
    34 views4 pages

    CHY 47 Assignment #3 Group No. 2: - Log (Ka) Ka Ka Ka Ka Ka Ka

    Uploaded by

    Fengari Cresent
    1. This document contains a chemistry assignment with multiple questions about acids, bases, pH, and buffer solutions. 2. Question 1 involves calculating pH, [H+], and [OH-] values for various solutions given their pH. Question 2 calculates the pH of an acetic acid solution. 3. Question 3 adds NaOH to the acetic acid solution, calculates concentrations after reaction, and finds the new pH. 4. Question 4 prepares an ammonia/ammonium chloride buffer and calculates its pH. Additional parts add NaOH or HCl and recalculate pH. 5. Question 5 writes the chemical equations for the reactions in parts 4b and 4c.

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    CHY 47

    Assignment #3

    Group No. 2

    1. Given the values of the following substances, fill in the Table below: (15 pts.)
    Sample         pH                     [H+]                     [OH-]                   pOH

    a. blood plasma          7.40 3.98 x 10-8 2.51 x 10-7 6.6

    b. cow’s milk 6.6 2.51 x 10-7 3.98 x 10-8 7.40

    c. gastric juice 1.50 3.16 x 10-2 3.16 x 10-13 12.5

    d. tomato juice 4.30 5.01 x 10-5 1.99 x 10-10 9.70

    e. cola drink 2.8 1.58 x 10-3 6.31 x 10-12 11.20

    2. A solution was prepared by dissolving 0.02 moles of acetic acid (HOAc; pKa = 4.8) in water to give 1
    liter of solution. What is the pH of this solution? (5 pts.)

    HOAc(aq) + H2O(l) H3O+(aq) + OAc-(aq)

    Step 1. Define equilibrium concs. In ICE table

    HOAc H3O+
    OAc-
    Initial 0.02 M 0 0
    Change -x x x
    Equilibrium 0.02M - x x x
    Step 3. Solve Ka expression

    Step 2. Write Ka expression pKa= - log [ka]


    Ka= 10-pKa
    [H3O+] [OAc-] Ka= 10-4.8
    Ka =
    [HOAc] x2
    Ka= 1.58 x 10-5 M =
    0.02M - x
    (x)(x)
    Ka = 0.002
    0.02M - x Since = 1,265 > 100, so (-x) can be ignored in the denominator
    1.58 x 10-5
    x2
    Ka =
    0.02M - x Then,
    x2
    Ka = 1.58 x 10-5 M =
    0.02M
    Ka = (1.58 x 10-5 M) (0.02M) = x2
    Ka = √3.16 x 10-7M = √x2
    Ka = 5.62 x 10-4 M = x = [H+]
    Step 4. Find pH
    pH = - log [H+]
    pH = - log [5.62 x 10-4]
    pH = -3.25

    3. To this solution obtained in #2, it was then added with 0.008 moles of concentrated sodium hydroxide
    (NaOH).

    a. What is the amount (in number of moles) acetic acid that has reacted to the added NaOH? (3pts.)

    No. of moles HOAc = 0.008


    The number of moles HOAc reacted with NaOH is 0.008 since there should be a 1:1 ratio
    of the reactants in the reaction and which eventually gives a remaining 0.012 mol HOAC and 0
    mol NaOH after the reaction.

    b. Write is the chemical reaction that has taken place upon the addition of NaOH? (3 pts.)

    Chemical reaction:
    HOAc(aq) + NAOH(aq) NAOAc + H2O(l)
    HOAc(aq) + NA+(aq) + OH-(aq) NA+(aq) + OAc-(aq) + H2O(l)
    HOAc(aq) + OH-(aq) OAc+(aq) + H2O(l)

    c. Calculate the equilibrium concentrations of acetic acid (HOAc), H3O+, OAc- (acetate) as defined
    in Table 2 below after the addition of NaOH:

    Table 2. Equilibrium concentrations of the species after the addition of NaOH. (1 point each)

    HOAc OAc- H3O+


    Initial 0.02 0.008 0
    Change -x x x
    Equil 0.012 - x 0.008 + x x

    d. What is the new pH of the solution? (In this problem, you may ignore changes in volume due to
    the addition of NaOH). 5 pts.

    [OAc-]
    pH = pKa + log
    [HOAc]
    [0.008]
    pH = pKa + log
    [0.012]
    pH = 4.8 + log [0.67]
    pH = 4.8 + log [-0.17]
    pH = 4.63
    4. A buffer was prepared by mixing 1.00 mole of ammonia (NH3) and 1.00 mole of ammonium chloride
    (NH4Cl) to form an aqueous solution with a total volume of 1.00 liter.
    Kb (NH3) = 1.75 x 10-5

    a. What is the pH of the solution? Show your calculations. 5 pts.


    GIVEN: 1 mol NH3
    1 mol NH4
    V = 1L
    Kb (NH3) = 1.75 x 10-5
    Step 2. Find pKa Step 3. Find pH
    Step 1. Find pKb pKa + pKb = 14 conjugate
    pKb = - log [kb] pH = pKa + log
    pKa = 14 + pkb weak
    pKb = - log [1.75 x 10-5] pKa = 14 + 4.76 1 mol NH3
    pKb = 4.76 pH = 9.2 + log
    pKa = 9.24 1 mol NH4
    pH = 9.24 + 0
    pH = 9.24

    b. To 500 mL of the buffer solution in # 4 was added 30.0 mL of 1.00 M NaOH. What is the pH of this
    solution? Show your calculations. (5 pts.)

    GIVEN: 500 mL (0.5L)


    30.0 mL (0.03 L) of 1 M NaOH
    Step 1.
    mol NAOH = (1.00)(0.03L) = 0.03 Step 3. Step 4.
    4.76 + 0.887 M
    pOH =
    Step 2. log 1M pH + pOH = 14
    mol pOH = 4.76 + log (0.887)
    +¿=
    1 (L )
    ( 0.5 L ) −0.03
    =1 M ¿ pOH = 4.76 + (- 0.05) pH = 14 – pOH
    0.530 L
    NH 4 pOH = 4.71 pH = 14 – 4.71
    mol
    N H 3=
    1
    L ( )
    ( 0.5 L )+ 0.03
    =0.887 M
    pH = 9.30
    0.530 L

    c. To 500 mL of the buffer solution in # 4 was added 30.0 mL of 1.00 M HCl. What is the pH of this
    solution? Show your calculations. (5 pts.)
    GIVEN: 500 mL (0.5L)
    30.0 mL (0.03 L) of 1 M NaOH
    Step 1.
    Mol HCl = (1.00)(0.03L) = 0.03 Step 3. Step 4.
    4.76 + 1M
    pOH =
    Step 2. log 0.887 M pH + pOH = 14
    pOH = 4.76 + log (1.13)
    +¿=
    (1 molL )(0.5 L )−0.03 =1 M ¿ pOH = 4.76 + 0.05 pH = 14 – pOH
    0.530 L
    NH 4 pOH = 4.81 pH = 14 – 4.81
    mol
    N H 3=
    1
    L ( )
    ( 0.5 L )+ 0.03
    =0.887 M
    pH = 9.19
    0.530 L
    5. Write the chemical equation involved for each of the chemical reaction as follows: (5 pts.)

    a. Chemical reaction involved in #4b (addition of NaOH):

    NH4CL(aq) + NAOH(aq) NaCl(aq) + NH3(aq) + H2O(l)


    NH4+(aq) + Cl-(aq)+ Na+(aq) + OH-(aq) Na+(aq) + Cl-(aq) + NH3(aq) + H2O(l)
    NH4+(aq) + OH-(aq) NH3(aq) + H2O(l)
    acid + base conjugate acid + conjugate base

    b. Chemical reaction involved in #4c (addition of HCl):

    NH3(aq) + HCl-(aq) NH4(aq) + Cl(aq)


    base + acid conjugate acid + conjugate base

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