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Phy-Chy-I-All20t9
 PLEASE ENSURE THAT THIS QUESTION BOOKLET CONTAINS I2O
QUESTTO|{S SERTALLY NUMBERED FROM I TO 120. PRII\TED PAGES 32.

1. The dimensions for pressure is

(A) MLT-2 1e) ML-'r2 (c) M-rL-lT-2
(D) Ml.-rrr (E) MLT
2. The magnitude of deceleration required for a body, moving at a speed of 10 m/s
to come to a complete halt at a distance of 100 m is
(A) 20 mls2 (B) 10 m/s2 (C) 2 m/s2
(D) 0.5 m/s2 (E) I m/s2
3. An accurate measurement implies that
(A) the spread of the readings are broad around the mean value
(B) the spread of the readings are niurow around the mean value
(C) the mean value of the readings is always lower than the true value
(D) the mean value of the readings is always higher than the true value
(E) the closeness ofthe mean ofthe readings to the true value

4. The following plot gives the variation of acceleration (m/s2) with time (s) for an
object that started from rest at time /: 0 s. The velocity at time / : 15 s (V15)
and at25 s (Y25), respectively are

l5
N
@

€to
o
'5
LJ
3!.)
,J
o-
<(,
5 10 15 20 25
Time (s)

(A) Vl5 : 50 m/s andY25: 0 m/s (B) V15 : 100 m/s andY2l: 150 m/s
(C) V15 : 50 m/s and V25 :25 mls (D) V15 : 100 m/s andY25 :25 m/s
(E) V15 : 75 mls and V25 : 50 m/s
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Phy-Chy-I-Arl2019 3 [P.r.o.
5. An object, moving with velocity 5 m/s, undergoes an acceleration of 1 m/s2 at
time / : 0. If the object has a mass of 1 kg, the kinetic energy (KE) of the object
at time /: 5 s is
(A) KE: 12.5 Joules (B) KE:20 Joules (C) KE:30 Joules
(D) KE:50 Joules (E) KE : 0 Joules
6. The variation of speed (in m/s) of an object with time (in seconds) is given by the
expression V(r): Yo- 5t + 5t2
(A) At time /: 0 s, the instantaneous acceleration is zero
(B) At time t: 0 s, there is a deceleration of the object
(C) At time / : 1 s, the object is at rest
(D) At time /: 1 s, the instantaneous acceleration is zero
(E) The distance travelled by the object at time /: 1 s is V6 m
7. A boat is moving from the east bank to the west bank on a south flowing river. If
the speed of the boat is 4 km/h and that of the river is 3 km/h. If the width of the
river is 2km, the distance travelled by the boat is
(A) 5 km (B) 4 km (C) 3 km
(D) 2.5 km (E) 2 km
8. A bead is tied on one end of a stiff rope of length I m. With the other end of the
rope as the center, the rope is rotated in such a wa\/ that the bead completes l0
revolutions per second. The centripetal acceleration of the bead is
(A) 400 n2 mls2 (B) 200 x2 mls2 (C) 400 m/s2
(D) 200 mtsz (E) 100 m/s2
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'1

Phy-Chy-I-Arl20I9 4
9. The electric field of an electromagnetic wave in free space is given by
- (l* \
E = 5 sinl ? z - oil li Y l*. Which of the following statements is correct?
[3 )'
(A) The wave propagates along y
(B) The wave vector is given E =42
3

(C) The wavelength of the electromagnetic wave i, I *

3

(D) The corresponding magnetic fietd is U = -rr)O t

i."r[+,
(E) The frequency of the wave is approximately 106 Hz

10. w bulb has the following property

The radiation produced by a 100
(A) The radiation is in the form of an electromagnetic wave which carries
energy but not momentum
(B) The radiation is in the form of an electromagnetic wave which carries
momentum but not energv
(C) The radiation is in the form of an electromagnetic wave which carries both
energy and momentum
(D) The radiation neither carries energy nor momentum
(E) The intensity of radiation is independent of the distance from source

11. A parallel plate capacitor (of capacitance C) with circular plates of radius 16

located at positions t o, is connected in series rvith a resistor R and is charged

by a batte4'of voltage \/. Consider a circular loop L of radius Oarutlel to the

I
capacitor plates is located at the center. Which of the following statements is
correct?
(A) The charge on the capacitor at time t is q(t)= CR (f - r-,,f.,i;
(B) The charge on the capacitor at time t is q(t)= CV(t - r-rrtcvl )
\/
(C) The flux through the loop L is independent of the area enclosed by it
(D) The magnetic field is directed orthogonal to the loop L
(E) The magnetic field is directed along the loop L
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t2. A monochromatic light of frequency ,=**1016 Hz is produced by a laser.
The power emitted is P = 10-2W. The average number of photons per second
emitted by the source is
I
(A) --a---x1016 (B) (6"$)211020 (c) (6.$)2*1016
(6.63)'
(D) ro2o G) 1016

13. The work function of three photosensitive materials used to build photoelectric
devices are given as: Sodium (2.15 eV), copper (,1.ti5 eV) and gold (5.1 eV).
Which of the following statements is correct. CIhe frequency of visible light lies
in the range 4xl}taiHz to 8 x l0t4iHz1?
(A) Devices built by copper and gold can operate with visible light
(B) Devices built using sodium can operate with ultraviolet light
(C) All the devices can operate with infrared tight
(D) All the devices can operate with visible light
(E) No device can operate with visible light

(A) The image is formed 36 cm behind the mirror

(B) The image is 36 cm in front of the mirror
(C) The image is magnified, virtual and erect
(D) The image is magnified, real and erect
(E) The image is magnified, real and inverted :

15. An optician prescribes a lens of power +2.5 D. The focal length of the lens in
water is (Refractive indices of the lens and water are respectively 1.5 and 1.33)
(A) 40 cm (B) 2660117 cm (C) 17 /266A cm
(D) 3000/17 cm (E) 17l300(-t cnr
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Phy-Chy-I-A112019 6
16. In a single slit diffraction (of width o) by a monochromatic source of wavelength
l" the first minimum of the intensity distribution occurs at an angle
T
(A) c (B)
* (c) #
(D) (E)
* ;
17. A monochromatic source of wavelength 600 nm was used in Young's double slit
experiment to produce interference pattern. Ir is the intensity of light at a point
on the screen where the path difference is 150 nm. The intensity of light at a
point where the path difference is 200 nm is given by
1i)
(A) 1r' (B)
i" (c) i t'
74
(D)
i r, (E) J I'

18. The Brewster's angle for air to water interface is

(A) tan-r1t.l3) (81 sin-r1r.:r; (C)

"or-111.33y
(D) tan-,t#) G) ,'",(*)
19. A TV transmitting antenna is 8I m tall. It has a half-power beam width of 10
degrees. If the receiving antema is at the ground level, the service area covered
by the transmitter is determjned by
(A) the half-power beam width, the height of the transmitter and the radius of
the earth
(B) the height of the transmitter and the radius of the earth
(C) the half-power beam width and the radius of the earth
(D) the height of the transminer and the half-power beam width
(E) the height of the transmiuer
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 2A. In the amplitude modulation mode of transmission, the normal speech si-snal is
with a maximum frequency of 5 kHz. If the carier frequency is l0(_r kHz, the
modulated signal will have the frequencies varying between
(A) 190 kHz to 210 kHz (B) 195 krtz to 205 kHz (c) 195 kHz to ' ,r kHz
(D) 200kHz to 205 kHz (E) 199.5 kHz to 200.5kHz
21. For signal transmission, modulation is necessary
(A) to reduce distortion of the signal
(B) to modifli the frequency content of the signal
(C) to mask the signal information from enemy
(D) to radiate the signal to a large distance using antennas
(E) to make it easy to arnplify the signal

22. A light emitting diode is

(A) a n-p-n type semiconductor rvith a forward bias
(B) a p-n-p semiconductor with a reverse bias
(C) a p-n-p semiconductor with a forward bias
(D) a p-n semiconductor with a reverse bias
(E) a p-n semiconductor with a forward bias

23. In the context of p-n junction, select the correct statement from the follou r- *
(A) The barrier potential remains constant under forrvard bias
(B) The width of the depletion region depends on the doping level in rhe :- ::
and n-type regions
(C) Under forward bias condition, the p-n junction behaves like a pure res. -. . : l
irrespective of bias voltage
(D) Under reverse bias condition, the p-n junction behaves like a pure res:s:
irespective of bias voltage
(E) The barrier potential decreases under reverse bias
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Phy-Chy-I-Al/2019 8
24. The radius of gyration about an axis through the center of a hollow sphere with
external radius a and internal radius & is

(A)
2 1u3 - b31
(B) F t* -t^l
s @s -hs) la 1,r-6,
|--:_---:_
(D) lz (ot - b5) (E)
5 (oa -b4)
!s;45 2 @2 -b2)
25. A ball of mass I kg and radius 0.5 m, starting from rest rolls dorvn on a 30o
inclined plane. The torque acting on the ball at the distance of the 7 m from the
starling point is close to
(Take acceleration due to gravity as l0 m/s2)
(A) 0.25 N-rn (B) 0.7 N-m (C) 0.5 N-m
(D) 0.4 N-m (E) 1.4 N-m
26. If the radius of the earth suddenly decreases by half of its present value. Then the
time duration of one dal' u'ill be
(A) 6 hours (B) 8 hours (C) 12 hours
(D) 24 hours (E) 48 hours
27. A hollorv sphere and a solid sphere, of equal mass and equal radii roll down
ri ithout slipping on an inclined plane. If the torque experienced by the hollow
sphere and solid sphere are r H and t, respectively, then
(A) rn lrs (B) TH )Ts (C) rH =rs
(D) rH:0 (E) T5' -0
28. A brick of mass 2 kg slides down an incline of height 5 rn and angle 30". If the
I
coefficient of friction of the incline is --;. the velocitv of the block at the
-la
z!)
bottom of the incline is
(Assume the acceleration due to gravity is 10 m/s2)
(A) 5 m/s (B) 50 m/s (C) 7 m/s
(D) 0 (E) 10 m/s
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 29. A spherically uniform planet of mass 8xi02a kg and of radius 6x106 :. r

orbiting around the Sun. The escape velocity for the planet is close to
(Take G : 6 x l0-rr N-m,/kgr;
(A) km/s
I 1 .2 (B) 16 km/s (C) 4 krn/s
(D) 12.6 km/s (E) 1.6 km/s

30. Suppose two planets A and B revolve around a Sun in the galaxy. The sen..-
major axis of A and B are 1 and 5 AU (astronomical unit) respectively. If t:"
period of revolution of A is I year, the period of revolution of B is
(A) 1 year (B) 5 years (C) lt years
(D) 25 years (E) 125 years
31. Tlre half-life of a3Tc" is 6 hours. If 12 mgof a3Tcee is injected to a patient, after
24 hours how much Tc will be left in the patient's body?
(A) 0 *s (B) 0.75 mg (C) 3 ms
(D) 6 *s (E) 12 mg
32. For atoms, rvhich of the following statement is correct?
(A) Heavier nuclei have more neutrons than protons
(B) Heavier nuclei have equal number of protons and neutrons
(C) Lighter nuclei have more neutrons than protons
(D) Lighter nuclei have less number of neutrons than protons
(E) For heavier nuclei, atomic mass varies as square of atomic number
33. which of the following statements is not a properry of nuclear force?
(A) it is an attractive force
(B) it is independent of interacting nucleons
(C) it is a long range force
(D) it is non-central force
(E) it is a short range force
34. Which of the following elements you need to rernor.e to form an isotone family?
(A) *o'u 18) ,N,r (c) uc,o
(D) ,rAt" (E) nF"
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35. A magnetic field of I T applied at an angle nl3 to the vertical direction is
decreased to zero at a steady rate in one second. The magnitude of induced emf
'
in a horizontally placed circular loop of radius 5 cm is given by
(A) t.25,l1nmy (B) t2.s.,l-3nv (C) t.25nmy
(D) t25nY (E) 25nY
36. The dimension of mutual inductance is
(Denote dimension of current as A)
{A) ML2T2 A-2 (B) M L2 T-2 A4 (c) M L-2 T2 A4
(D) ML2 T -3 A-r (E) M L2 T -3 A-3
3?. A pne inductor of inductance 0.1 H is connected to ari AC source (of rms
ruluge) 220 Y and angular frequency of 300 Hz. The rms current is

rA) )x 1e) ld (c) {loe

*o
II
(E) lo
Jfi

-i
r' - . . LCR series circuit (of inductance L, capacitance C and resistance R), the
- :;:ance is mir-rimum when the angular frequency of the source is given by
t;-
LC (B) -L (C)
VLC \i;
tc
,_
Ir (E) .trcR
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 39. A Camot engine is operating between a hot body and coid body
maintained at
temperatures T1 and 12 respectively. Consider the following
three cases
Case-I : The temperature of the hot bod-v is changed to T, +
AT and cold bodr.
is at T2
Case-II: The temperature of the hot body is at T1 and cold body is changed
to
Tr+AT
Case-III: The temperature of the hot body is at T1 and cold body is chaneed
to
Tz- AT
(A) The efficiency of the carnor cycie is highest for case-I
(B) The efficiency of the camot cycle is highest for case-Il
(c) The efficiency of the camot cycle is highest for case-III
(D) The efficiency of case-Il is higirer than case_III
(E) The efficiency of the camot cycle is same for all three cases

40. Some smoke is trapped in a small glass container

and is viewed i::-_rn a
microscope. A number of very smalr smoke particles are seen in c-:.,.-,*,l,us
random motion as a result of their bombardment by air
molecules. If rhc : ..s :,i
the smoke particle is about 1012 times higher than that of an
air mc-;;- _ :le
average speed of a smoke particle is
(A) 106 times the average speed of an air molecule
(B) 10-r2 times the average speed of an air molecule
(C) 1012 times the average speed of an air molecule
(D) 10-6 times the average speed of an air molecule
(E) 10-r0 times the average speed of an air molecule
41. The standard of length is maintained by a l meter
long bar made up oi :.:::iar
having coefficient of rinear expansion o:0.0000r oc-r. "
If the rengtn :- : ; car
were to be preserved to an accuracy of I part per million,
what ,,, _ _": be
maximum allowed temperature variation?
(A) * 0. 01 oc (B) +0. 1oc (c) + 0. oot "c
(D) + 0.0001 "c (E) + 1.0 oc
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42, Inside the engine of an automobile, the cylinder compresses the air
from
approximately standard temperature and pressure to one-twentieth of the original
volume and a pressure of 50 atm. What is the temperature of the compressed air?
(A) s00 K (B) 682K (c) s50 K
(D) 1000 K (E) 200 K
43, A spring of natural length I and spring constant 50 N/m is kept on a horizontal
frictionless table with one end attached to a rigid supporl. First the spring was
compressed by l0 cm and then released to hit a ball of mass 20 g kept at a
disrance / from the rigid supporl. If after hitting the ball, the natural length of the
spring is restored, what is the speed with which the ball moved?
(.lgnore the air resistance)
(A) 5 m/s (B) 7 mls (C) 25 mls
(D) 50 m/s (E) 2500 m/s
44. In a water container, an aluminum piece of volume 0.5 m3 is lowered through an
external force, until it is completely submerged. In another identical 'water
container, a lead piece of same volume was similarly submerged using the same
amount of external force. The mass density of lead is 4 times larger than the
mass density of the aluminum. If Fa and F; are the buoyancy forces acting on
aluminum and lead respectively, then which of the following statements is
correct?
(A) FA>4FL (B) FL>4FA (c) FA>2FL
(D) FL>2FA (E) Fr: Fe
15. A boy formed a bubble and a liquid drop from the same soapy water. The
pressure difference between inside and outside of the soap bubble is measured to
:e 100 N/m2. If the radius of the droplet is half of the radius of the bubble, then
.:. pressure difference between the inside and outside of the droplet is
(B) 50 N/m2 (C) 100 N/rn2
n
(1J t '\ :ll (E) 400 N/m2
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 constant k,
46. A mass rn, suspended vertically by a massless ideal spring with spring
the kinetic
is at rest. The mass is displaced upward by a height ft. When released,
energy of the mass will be proportional to
(Neglecting air resistance)
(A) onlY h
(B) onlY h2
(c) m
(D) a linear combination of terms involvin gh and h2
(E) k

47. Instantaneous power delivered to a damped harmonic oscillator (natural

frequency is ro6) by an external periodic force (driving frequency ro) under
steady state conditions is
(A) positive alwaYs
(B) negative alwaYs
(C) positive and negative with power integrated over a period being zero
(D) positive and negative with power integrated over a period being positive
(E) positive and negative with power integrated over a period being negative
48. The Q factor for a damped oscillator is given by the
(A)Ratioofenergystoredpercycletotheinitialenerry
(B) Ratio of energy dissipated per cycle to the initial enersr
(C) Rptio of energy stored per cycle to the energy dissipated per cycle
(D) Ratio of energy dissipated per cycle to the energy stord per cycle
(E) Ratio of the damping coefficient to the natural frequency
49. A ball of mass m is projected upward with a speed vo . The speed at a height ft is
(Neglecting air resistance)
(A) independent of angle and direction of projection
(B) independent of mass, angle and the direction of projection
(C) dependent on the direction of projection
(D) dependent on the shape, size and mass of the ball and angle of projection
(E) dependent on mass of the ball but independent of the angle and direction of
projection
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Phy-Chy-I'All20r9 l4
50. An object having a velocity 5 m/s is accelerated at the rate 2 mls2 for 6 s. Find
the distance travelled during the period of acceleration
(A) 60 m (B) 25 m (C) 36 m
(D) 66 m (E) 45 m
51. .{ rehicle rnoving at36 km/hr is to be stopped by applying brakes in the next
5 m. If the vehicle weighs 2000 kg, determine the average force that rrust be
applied on it
(A) lo4 N (B) 2"104 N (C) 3x104 N
(D) 5*103 N (E) 103 N

A block of mass 20 kgis suspended through two spring

balances with negligible mass as shown in figure. What
will be the readings in the upper and lower balance
respectively?
(A) 0 kg, 20 kg
(B) l0 kg, 20kg
(C) 20kg,10 kg
(D) l0kg, l0kg 20ks
(E) 20kg,20 kg
Two masses connected in series ri'ith two massless strings are hanging from a
support 35 5hss'n in the figure. Find the tension in the upper string
(A) mE
(B) (mt - m)s
(c) mB
(D) (m1+ m2)g
(E) (mt * mz)g
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54. An electron, placed in an electric field, experiences a force F of 1 N. What are
the magnitude and direction of the electric field E at the point u here the electron
is located (e :1.6x10-re C;?

(A) :
I
N/C, F and E are along the same direction

I
(B) - N/C, F and E are against each other

(C) :
I
N/C, F and E are perpendicular

(D) e N/C, F and E are against each other

(E) e NlC, F and E are perpendicular

55. The distance between two charges Qt: +) pC and Qt: +8 prC is -: ::.
Calculate the distance from the charge Q1 to the points on the line sesi:-c::
joining the two charges where the electric field is zero
(A) 1 cm (B) 2 cm (C) 3 cm
(D) 4 cm (E) 5 cm
56. Four point charges (with equal magnitude of charge of 5 C; but with ..:.':-: :
signs) are placed at four corners of a square of side 10 m. Assumins .--- ..3
square is centered at the origin and the configuration of the chargeS ?ri :! _ in
in the figure, the potential and the magnitude of electric field at :: - - -.n,
respectively are

[no,.
't = l-]
L 47rr0
_l

(A) 0Vand0V/m
la
(B) 0 v and
\t vt^
(c) +rv and $o u,^
(D) 0Vand 5V/m
t;
(E) \n V and 0 V/m

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57. A poinr dipole with dipole moment, F = psk, is kept at the origin. An external

elecrrc field given by, E :Eo(2i -3i *+[1, is applied on it. Which one of the
tt true?
,. - '.r rnc' statements is
, .r. . he force on the dipole is zero while torque rotates the dipoie on the
-plane
!, - :,eforce on the dipole moves it along the direction of electric field
- -:,e interaction energy between the dipole and electric field is zero
- -;re potential due to the dipole alone on the xy-plane with e: 0 depends on
tre value ofpo
fEl The application of the electric field orients the dipole along the
-f direction
: - - ...e total capacitance and total charge
- - .-apacitors
' j nF,9 nC
: -: ttF, 18 nC
,-r

. 5 nF,4.5 nC
, _: r-,\nF,9 nC
- -r,t.) riF, 4.5 nC

-. - :cr,rit is made using Rr, Rz, Ri, R+ and a battery as shown in the following
Find the equivalent resistance of the given circuit and the cument passing
=.-:i
R,:o'5 Q
:o,]a (B) ! a, zt e.
I

-i
I

il
C]

lo, lt (D)
I ",T"
l'. ?o
_1 J

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Phy-Chy-I-A1 1019 17 lP.r.o.

60. Find the voltage and current passing through the resistr-rr R.: shown in the
following circuit
(A) 3 V,3 mA l0 pF R2:2 ksJ
(B) 1V, I mA
(C) 3V, lmA
(D) i V,2 mA
(E) 2V, lmA
61. TheresistorRl :3 fl andR2:1 Oareconnected inparallel toa20 V banery.
Find the heat developed in the resistor R1 in one minute
(A) 600 J (B) 800 J (c) 6000 J
(D) 8000 J (E) 7000 J

62. The velocity and acceleration of a particle performing sirnple hannonic motion
have a steady phase relationship. The acceleration shows a phase lead over the
velocity in radians of
(A) *n (B) 0 (C) + nl2
(D) - nl2 (E) -n
63. Consider a driven damped mechanical oscillator is in resonance. \\Ihich of the
following statements is true?
(A) Driving frequency is trvice the natural frequency of the oscillator
(B) Power transfer from the driving source to system is minimum
(C) Driving frequency is the same as the natural frequency of the osciliator
(D) The force damping the oscillations are at a minimum value
(E) The driving force is in phase with the displacement
64. A body undergoing simple harmonic motion has a maximum acceleration of
8n m/s2 and maximum speed of 1.6 m/s. What is the time period T?
(A) 0.1 seconds (B) 0.2 seconds (C) 0.3 seconds
(D) 0.4 seconds (E) 0.5 seconds
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Phy-Chy-I-All20l9 18
65. A bat entits an ultrasonic sound wave at 33.0 kHz and receives an echo 0.1 s
\\
later, hat is the distance of the bat from the object-producing echo? (Speed of
sourd rr air is 330 m/s)
r.\ ',-r
m
,,) (B) 20.0 m (C) 33.0 m
rD r {in.l,i ni (E) 16.5 m

66. .\ u ar e alortg a string has the following equation y : 0.05 sin (28r - 2.0-r) m
(u here , is in seconds and x is in meters). What are the amplitude, frequency and
u ar e.;nqth of the wave?
t-{ amplitude : 0.05 m, frequency : 4.456P.2 and wavelength :3.518 m
3 , amplitude : 0.05 m, frequency :28 Hz and wavelength :2.0 m
r

L r amplitude:5.0 m, frequency:4.456 Hz and wavelength:3.518 m

D r amplitude : 0.05 m, frequency :2.0H2 and wavelength: 28 m
iE r amplitude:0.05 m, frequency:3.456H2 andwavelength:4.518 m

6:. \ ::ain sounds its whistle as it approaches an observer standingat a point near
:ne tr:ck. The observer measures a frequency of 216IH2 as the train approaches
and , ;iequency of 184 Hz as the train leaves. What is the frequency of its
u his:ie l
(A) I I i-r Hz (B) 190 Hz (C) 205 Hz
(D) 201 ilz (E) 200 Hz
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Phy-Chy-I-A112019 t9 [P,T.O.
 68.
of rosic gares rhe inputs are
;ff
rhe fll"J'l-"rffi:f one of the f"lb;;;;#;Hi[ff'.Lff1_?
output is c. which :::::Tl,:*on A and B.

A B C A B C
0 0 I 0 0 1
(A) 0 I I 0 I
(B) 0
1 0 1
I
(c) t-i
0 1
I 1 1 I -
I I 0
i 1

A B C A B C
0 0 I
(D) 0 0 0
0 I I (E)
I
0 i 0
0 0
1 0 0
1 I 0 I 1 0

69' A particle of mass m andcharge

q withan initiar velocity il is su:.;,
uniform magnetic fierd E :_ ._ E
arong the verticar direction.
(A) follow a circular path if il is The p&rticle i.;
along the vertical direction
(B) make hericar motion if is f
arong the
(c) make helicar motion if il is neither horizontar direction
paralrel nor orthogonal
(D) always make circular motion to B
(E) always make helical motion
Space for rough work

Phy-Chy-I-At/2019
20
i0. Consider a circular loop of radius R on the xy-plane carrying a steady current
anticlockwise. The magnetic field at the center of the loop is given by

(A) #-,t (B) #,, (c) #,,

(D) Lt
R
Ii (E,
/tr\ fto r l'
R ^-,

71. Co:.,ier nvo parallel current carrying conductors separated by a distance. Which
following statements is true?
,--r3 r'rf the
.{r Currents flowing in same direction will lead to repulsion
rB ) Currents flowing in opposite directions will lead to attraction
(C) The conductors will always attract each other
(D) The conductors will always repel each other
(E) Currents flowing in same direction will lead to attraction and opposite
directions will lead to repulsion

7). . :: energy gap is much more in silicon than in germanium because

r f. ir has less number of electrons

iB l: has high atomic mass number

i tl -:s crystal has much stronger bonds called ionic bonds
I -:s .' alence electrons are more tightly bound to their parent nuclii
: -.s '. alence electrons are more loosely bound to their parent nuclii
Space for rough work

Phy-Chy-I-All20l9 2l [P.T.O.
73. NO* has bond order
(A) 2 (B) 2.s (c) 3
(D) 3.s (E) 4
74. Which hydride amongst the following has the least boiling point?
(A) NH: (B) PH: (C) AsH3
(D) SbH3 (E) BiH3
75. Which of the following sets has Lervis acid behaviour for all the components?
(A) BF: (B) BF3, SiFa, PF5 (C) SiF+, PF5
(D) BF3, PF5 (E) (A) and (B)

76. The carbon atoms in calcium carbide are held by

(A) Ionic bonds
(B) Two sigma bonds
(C) Two sigma and one coordinate bond
(D) One sigma and two n bonds
(E) One sigma and one n bond
77. According to the VSEPR theory, the shape of C1O3- would be
(A) Linear (B) Triangular planar (C) Pyramic:
(D) Square planar (E) Angular
78. Acetic acid in liquid ammonia behaves as
(A) Weaker acid than that in water
(B) Stronger acid than that in water
(C) Base acid
(D) Neutral acid
(E) (C) and (D)

79. The compound(s) that does(do) not exist is(are)

(A) BiF5 (B) PFs (C) AsF5
(D) SbFs ,) ' i (E) All the compounds exist
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Phy-Chy-I-Arl20l9 22
80. Rme gases are sparingly soluble in water because of
(A) Hydrogen bonding
(B) Dipole-dipole interaction
(C) Induced dipole-induced dipole interaction
(D) Dipole-induced dipole interaction
(E) (A) and (D)

81. An example of a non-stoichiometric oxide when heated is

(A) Beo (B) Zno (C) Meo
(D) Cao (E) LizO

82. The donor atom in EDTA are

(A) Two N and two O (B) Two N and four O (C) Four N and two O
(D) Three N and three O (E) Two N and three O
83. Hard acids prefer to combine with
(A) bases
Soft (B) Soft acids (C) Hard acids
(D) Hard bases (E) Salts

84. Among the following, which species represents a pseudohalide?

(A) CN- (B) Cao (C) 12

(D) K:HgI+ (E) BiOCI

85. PClj is stored in a well stoppered bottle since
(A) It decomposes in the presence of moisture
(B) It is decomposed by light
(C) It is highly volatile
(D) It reacts with air to form POCI3
(E) (A) and (C)

86. An orange solid (A) on heating gives a green residue (B), a colourless gas (C)
and water vapours. The dry gas (C) upon passing over heated Mg gave a white
solid (D) which upon subsequent reaction with water gave a gas (E) that gave
dense white fumes with HCl. Identify (D)
(A) Fe(NH3)Cl2 (B) CuN2 (C) MgrNz
(D) NII4CI (E) FeC12
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Phy-Chy-I-A1t2019 23 [P.r.o.
 87. On passing silent electric discharge through oxygen in an ozlr..z;:. ,< -i mol % of
oxygen is converted to ozone. How many moles of o1 an.,i_i :;:.... qhen 35
moles of 02 is originally present?
(A) 33.0 (B) 34.4 ll

(D) 31.8 (E) 31.0

88. Carnallite is a mineral containing
(A) K (B) Na (c) Mg
(D) Fe (E) (A) and (c)
89. Maximum number of photons emitted by a bulb eapable of producing
monochromatic light of wavelength 550 nm is_,ifl00VandlAis
supplied for one hour.
(A) 1 , 1024 (B) 5 x 1024 (C) 1 x 102i
(D) 5 x 1023 (E) 5
" 1022

90. Which of the following is the correct unit of angular momentum of an - r- . r. in

an orbital of an atom?
(A) Js
r
(B) J/s (C) Wi s:
(D) Ws (E) J s2

91. Consider afcc lattice made of a metal cation (M6*) and three oxic,' -- -.s per
unit cell. The resultant structure lvould have
(A) 3D netr.vork of edge shared octahedra
(B) 3D network of corner shared octahedra
(C) 2D network of edge shared octahedra
(D) 2D network of corner shared octahedra
(E) 3D network of face shared octahedra
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Phy-Chy-I-Al/2019 24
92. The e Jge ie:-sth of a soiid possessing cubic unit cell is 2Jir (structure I), based

ol :.':i sphere model, which upon subjecting to a phase transition, a new cubic

-..:*.iure (structure II) having an edge length of ) rvhere r is the

VJ "obtained,
:;orus of the hard sphere. Which of the follor,ving statements is true?
{A) Density of the structure II is lower than structure I
(B) Density of structure II is higher than structure I
(C) The pore volume in structure I is 1.2 times higher than that of structure II
(D) The pore volume of both the structures are equal
(E) The octahedral voids in structure I is transformed into tetrahedral voids in
structure II
oC is kept in a container having
93. An ideal gas "A" having volume of 1 L at 2l
mor,able piston and adiabatic walls in ambient condition. If 1.33 L atm of
eners\/ is supplied inside the s1'stem. find out the final temperature of the
system?
(A) 3ee K (B) 4ee K (c) see K
(D) 2ee K (E) 4s0 K
A 5.2 L closed container contains some water and N2(g) at 29 'C. The total
pressure of the system and water tension are 1 atm and 0.04 atm, respectively.
Upon electrolysing the liquid water inside completely, the final pressure of
system ri'as at 2 atm. What is number of moles of water that was present inside
the container?

(A)
3.46
RT
0.208
(B)
5.2
RT
8.0
(c) #
(D) (E)
RT RT
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Phy-Chy-I-All20t9 25 [P.r.o.
95. A solution of methanol in water is 20 % by volume. If the solution and pure
methanol have densities of 0.964 kg L-r and 0.793 kg L-', reqpectively, find the
per cent of methanol by weight?
(A) 1s.8 (B) 16.4s (C r:
(D) 14.8 (E) 17.6
96. The Henry's law constant for 02 dissolved in water is 4.34 x 10r arn-. at certain
temperature. If the partial pressure of 02 in a gas mixture that is in eq'-.ilibrium
with water is 0.434 atm, what is the mole fraction of 02 in the solution?
(A) I x 10-s
(B) 1 x 104
(C) 2 x l}-s
(D) 1 x 10{
(E) 2 * l}a
97. The standard heat of formation of CHa, Co2and H2o (l) are -16.2, -394.8 and
-285.82 kJ mol-r, respectively. Heat of vaporizatron of \\'ater is 44 kJ mol-l.
Calculate the amount of heat evolved when 22.4 L of CH-,. kept under normal
conditions, is oxidized into its gaseous products
(A) 802 kJ (B) 878.4 kJ rC - : ..'"'
(D) 788.4 kJ (E) 500 kJ
Acetic acid dimerizes when dissolved in benzene. As a res*,: : - ..::s point of the
solution rises by 0.36oc, rvhen 100 g of benzene is mire: ,'.,::. "-\" g of acetic
acid. In this solution, if experimentally measured moi::....: ',reisht of acetic
acid is,117.8 and molar elevation constant of benzene is I :- K kg mol-r, rvhat
is the weight Yo and degree of dissociation (in %) of acei1. ,:.; in benzene?
(A) 1.62 and 98.3 (B) 0.81 and 98.3 : t-).5 and 86
(D) 1 and 98.3 (E) 1.4 and 99
99. At a certain temperature, 2 moles of CO and 4 moles of C"; _i:s;-i ,.,. ere reacted to
form COC12 in a 10 L vessel. At equilibrium if one mole ;- rli,*r ;s tresenr then
equilibrium constant for the reaction is
(A) 4 (B) 3.3 rCr .

(D) 2.s (E) 4.s

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Phy-Chy-I-All20l9 26
1r.rt-t. The equiiibrium constant for the reaction, Nz(g) +3Hr;=:2NH3(S) and
lN: (g) + 6Hr 3 +NH3 (s) are K1 and Kz, respectively. The relationship
between Kr and Kz is
(A) Kz: Kr2 (B) K:: Kr-2 (C) Kr : Kz2

(D) Kr: J( (E) Kr = JKz

oC, the volume of "A" left in the
101. For a first order reaction, A(g) --- B(g) at 35
reaction r,essel at r arious times are given below. [Given data: log(514):0.09691
I / minutes 0 10 20 30 40

VimL 25 20 15.7 t2.s 9.6

\\'hat is the value of rate constant?

(A) 0.02231 min I (B) 0.04231 min I
(C) 0.06231 min-l
(D) 0.08231 minr (E) 0.1231 minr
t02. E..x of the following cell is
Pt(s) lHz(s), 1 bar lH- (1 M) ll H- (0.1 M) 1H:(-e), 1 bar lPt(s)

(A) -2.303RT
F
(B) rsll (c) -2.303RT
2F

(D)
2.303RT
2F
(E) #
103. In a lead-acid battery, if 1 A current
is passed to charge the battery for t h, what
is the amount of PbSO+ converted to PbO2? (Given data: 1 F :96500 C mol-r)
(A) 0.0373 moles (B) 0.0186 moles (C) 0.0093 moles
(D) 0.0268 moles (E) 0.0400 moles
Space for rough work

Phr -Ch', - -- r- : . " 27 lP.r.o.

104. A fuel cell operates at constant current, with H2 fuel (1 bar) and 02 oxidant
(1 bar). The electrolyte used is 0.001 M HCI and the product(s) of the reaction
are confined inside the fuel cell. Which of the following is true about the
electrolyte?
(A) Boiling point of the electrolyte decreases with increase in the duration of
fuel cell operation
(B) Boiling point of the electrolyte increases with increase in the duration of
fuel cell operation
(C) Open circuit voltage of the fuel cell remains constant with increase in
duration of operation
(D) Open circuit voltage of the fuel celI increases with increase in duration of
operation
(E) Both (A) and (C)
105. The correct IUPAC name for methylisopropylacetylene is
(A) 2-methyl-4-pentyne
(B) 4-methyl-2-pentyne
(C) isopropylmethylacetylene
(D) 3-methyl-4-pentyne
(E) 2-methyl-3-pentyne
106. Cyclohexylamine and aniline can be distinguished by
(A) Hinsberg's test (B) Carbylamine test (C) Br,-.rnrne test
(D) Beilstein's test (E) Lassaigne's test
107. The compounds pyridine and planar cyclooctatetraene are
respectively
(A) aromatic and non-aromatic
(B) aromatic and anti-aromatic
(C) aromatic and aromatic
(D) anti-aromatic andnon-aromatic
(E) anti-aromatic andanti-aromatic
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Phy-Chy-I-All20l9 28
108. Propvlene on treatment with HBr/FI2O2 provides
r{r 1-bromopropane (B) 2-bromopropane (c) I,2-dibromopropane
D, 1-bromopropan-2-ol (E) 2-bromopropan-1-ol
I {.rq. is a potent vasodilator.
-. :l:stamine (B) Serotonin (C) Codeine
lr r- :retidine (E) Aspirin
tr 1tl. :.- .:'. ;:: sugar is
..,:otatory (B) Levorotatory (C) Dextrorotatory
I -:,rca1ly inactive (E) Mutarotatory
11 1. :'. :.: :gest base among the following is
:. (B) oH- (C) CH:C-
".i-
: _-i.CH2- (E) OEr-
1 l: , -: :: -:enryl halide in ethanol yields alkenes by El mechanism due to
r. , "i, .oncentration of solvent
!' ::s;lce ofbase
- : ,s a primary halide
I ::::.c factor which prevents E2 mechanism
: . -.',:iion effect
1 13. -.- . :: . :rrdes are not good candidates for
i ',1.
-:iz-Fittig reaction
ts : .:.g reaction
rC f :r:del-Crafts reaction
(Dr Gr.nard reaction
(E) Ga:r:el-phthalimide synthesis

114. Sulfonation of benzene with excess sulfuric acid provides

(A) benzenesulfonicacid
(B) p-benzenedisulfonic acid
(C) o-benzenedisulfonic acid
(D) m-benzenedisulfonic acid
rE) decomposition of benzene
Space for rough rvork

Ph1-Chr -l-.{ 1 lr-r 1 9 29 [P.T.O.

115. The following reaction is named as

fl\cHo KoH
* 6\r-coox
U.ro '*"
U"r,o,
(A) Reimer-Tiemann
(B) Kolbe-Schmitt
(C) Cannizzaro
(D) Gattermann
(E) Aldol
116. When C6H5COCOC6H5 is reduced with LiAlH.. ile product formed has
stereoisomers.
(A) 2 (B) 3 (c) 4
(D) 6 (E) 8

117. The compound which does not lead to benzoic aci; : . -'...i:tion rvith KMnOa is
(A) toluene (B) benzyl alcohol 1l r rz-butylbenzene
(D) /-butylbenzene (E) styrene
118. In the Hofmann rearangement of primary amides har-:- .:. :'l.r'active group
with S-configuration, the product amine has
(A) R-configuration
(B) S-configuration
(C) Racemic mixture
(D) Meso form
(E) Achiral nature
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Phy-Chy-I-All20t9 30
lL9. Benzonitrile can be prepared from benzaldehyde on treatment with
(A) NH3
(B) NH3 followed by hydrogenation with Ni
(c) NH2OH
(D) NH2OH followed by dehydration with acetic anhydride
(E) Hydrogen cyanide
120. The product formed in the below reaction is

CH" O
lo" cr
H3C-N-CH3
H2SO4/HNO3
li,,\
\2 product

CH" O CHa O CH" O CH. O CH. O

lo" cr lo" cl lo" cl lo- cl lo" cr
H3C-N-CH3 HsC-T-CH, H'c-r[cH' H3C-N-CH3 H3C-N-CH3

(A)ry (B) O*o, (c)

v (D) ,\-*o,
V
(E)
?_".
Noz Noz

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Phy-Chy-I-Atl20l9 31
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Phy-Chy-I-A112019 32 \\J
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