DAILY PRACTICE PROBLEMS

DPP Course : ABHIMANYU

Subject : Physical Chemistry Target: JEE (Main + Advanced) 2022

DPP No. : 1 (JEE-MAIN)

Total Marks : 60 Max. Time : 40 min.
Single choice Objective ('–1' negative marking) Q.1 to Q.20 (3 marks, 2 min.) [60, 40]

1. 1 mole by definition represents same number of particles as :

16
(A) Number of atoms present in exactly 8 g of 8O isotope.
(B) Number of molecules in exactly 2 g of H2 gas.
16
(C) Number of atoms present in exactly 16 g of 8O isotope.
12
(D) Number of atoms present in exactly 12 g of 6C isotope.

2. The weight of a molecule of the compound C6H12O6 is about :

-22 -23
(A) 180 g (B) 3 × 10 g (C) 22 × 10 g (D) 132 g

-28
3. The mass of half mole of electrons is about : (Given : Mass of electron = 9.1 × 10 g)
(A) 0.546 mg (B) 0.273 mg (C) 1.092 mg (D) 4.55 mg

4. 39.4 kg of gold was recovered from a smuggler. The number of atoms of gold recovered are :
25 25 26
(A) 200 (B) 1.2044 × 10 (C) 6.022 × 10 (D) 1.2044 × 10

3+
5. The charge on 1 gram of Al ions is : (e = magnitude of electronic charge)
1 1 1
(A) NAe coulomb (B) NAe coulomb (C) NAe coulomb (D) 3 NAe coulomb
27 3 9

6. The number of atoms present in 0.5 g atoms of nitrogen is same as the atoms in :
(A) 24g of Mg (B) 8g of Oxygen gas (C) 32g of S (D) 12g of C

7. In which of the following pairs, do 1 g of each have an equal number of molecules ?

(A) N2O and CO (B) N2 and CO (C) N2O and CO2 (D) Both (B) and (C)

8. The number of atoms in 4.25 g of NH3 is approximately :

23 23 23 23
(A) 1 × 10 (B) 2 × 10 (C) 4 × 10 (D ) 6 × 10

9. Total number of neutrons present in 4 g of heavy water (D2O) is : (Where NA represents Avogadro's
number)
(A) 2.4 NA (B) 4 NA (C) 1.2 NA (D) 2 NA

10. In which of the following options, the molecules are correctly matched with their atomicity ?

(A) (1 – s), (2 – r), (3 – p), (4 – q) (B) (1 – q), (2 – s), (3 – p), (4 – r)

(C) (1 – q), (2 – s), (3 – r), (4 – p) (D) (1 – s), (2 – r), (3 – q), (4 – p)
1
11. The atomic weight of an element is 'a'. If this element occurs in nature as a triatomic gas, then the
correct formula for the number of moles of gas in its 'w' g is :
3w 3a a
(A) (B) (C) 3wa (D)
a w 3w

12. 124 g of P4 will contain which of the following :

(1) 4 atoms of Phosphorus
(2) 4NA atoms of Phosphorus
(3) NA molecules of Phosphorus
(4) 1 molecule of Phosphorus
(A) 1 and 4 (B) 2 and 3 (C) 1 and 3 (D) 2 and 4

13. Among the following samples, select the sample which contains maximum number of atoms.
(A) 4 gm of oxygen (B) 32 gm of sulphur (C) 108 gm of silver (D) 2 gm atoms of
nitrogen

14. A gaseous mixture contains oxygen and sulphur dioxide in the ratio of 1 : 4 by mass. Therefore, the
ratio of their respective number of molecules is :
(A) 1 : 2 (B) 1 : 4 (C) 2 : 1 (D) 4 : 1

15. Sulphur exist in different allotropic forms like S2, S6 and S8 etc. If equal moles of these three forms are
taken in separate containers, then the ratio of number of atoms present in them respectively is :
(A) 1 : 3 : 4 (B) 1 : 1 : 1 (C) 12 : 4 : 3 (D) 4 : 3 : 1

16. Which of the following has least mass?

23
(A) 2 gram-atom of Nitrogen (B) 3 × 10 atoms of Carbon
(C) 1 mole of Sulphur atoms (D) 7 g of Silver

17. Which of the following has least mass?

(A) 2 gram-molecules of CO2
24
(B) 1.2044 × 10 molecules of CH3COOH
(C) 3 moles of NH2CONH2
(D) 80 g of CaCO3

18 Which of the following contains the greatest number of atoms?

(A) 1 g of butane (C4H10) (B) 1 g of nitrogen (N2)
(C) 1 g of silver (Ag) (D) 1 g of water (H2O)

19. Cinnabar (HgS) is a prominent ore of mercury. How many grams of mercury are present in 464g of pure
HgS.
(A) 200 g (B) 400 g (C) 160 g (D) None of these

– 23
20. The number of F ions in 2.1g AlF3 is (NA = 6 x 10 )
22 22 22 22
(A) 1.5 x 10 (B) 6 x 10 (C) 3 x 10 (D) 4.5 x 10

2
 DPP No. : 2 (JEE-MAIN)
Total Marks : 60 Max. Time : 40 min.
Single choice Objective ('–1' negative marking) Q.1 to Q.4 (3 marks, 2 min.) [12, 08]
Multiple choice objective ('–1' negative marking) Q.5 to Q.7 (4 marks, 2 min.) [12, 06]
Comprehension ('–1' negative marking) Q.8 to Q.11 (3 marks, 2 min.) [12, 08]
Integer type Questions ('–1' negative marking) Q.12 to Q.15 (4 marks, 3 min.) [16, 12]
Match the Following (no negative marking) Q.16 (8 marks, 6 min.) [08, 06]

1. A gaseous mixture contains SO2 & CO2, average molecular mass of mixture may be :
(A) 64 (B) 44 (C) 54 (D) 70

2. An element is found in nature in two isotopic forms with mass numbers (A–1) and (A+3). If the average
atomic mass of the element is found to be A, then the relative abundance of the heavier isotope in the
nature will be :
(A) 66.6% (B) 75% (C) 25% (D) 33.3%

65 67
3. A hypothetical element Z exists in nature as two isotopes Z and Z with their relative abundances
25% and 75% respectively. Then, the average atomic mass (in u) of element Z is :
(A) 65.5 (B) 66 (C) 66.25 (D) 66.5

4. What is the ratio of weights of O2 and SO2, the mixture of which contains equal number of molecules of
each gas?
(A) 1 : 8 (B) 8 : 1 (C) 1 : 2 (D) 2 : 1

5. 360 amu of Glucose (C6H12O6) contains :

(A) 2 moles of glucose molecules (B) 24 hydrogen atoms
(C) 12 moles of carbon atoms (D) 2 glucose molecules

6. Equal mass of O2 and O3 gases contain the same number of :

(A) atoms (B) molecules (C) protons (D) moles of given
species

7. If 42 g of an unknown gas X occupies a volume of 125 L at 0.3 bar pressure and 300 K temperature,
then the gas X could be :
(A) N2 (B) CO2 (C) CO (D) NO2

Comprehension # 1
Consider a sample containing (NH4)2Cr2O7

8. Mass of nitrogen present in sample if mass of oxygen present is 11.2 g.

(A) 1.4 g (B) 2.8 g (C) 28 g (D) 14 g

9. Number of gm molecules of (NH4)2Cr2O7 present in the sample if mass of hydrogen obtained from the
sample is 2g.
(A) 0.25 NA (B) 0.25 (C) 0.125 NA (D) 0.125

Comprehension # 2
In a container equal number of moles of ethene and sulphur dioxide gases are present at 760 mm Hg
pressure and 546K temperature.

10. The ratio of carbon atoms to oxygen atoms present in container will be :
(A) 2 : 1 (B) 1 : 2 (C) 1 : 1 (D) 3 : 2

11. If all ethene molecules are replaced by same number of molecules of ethyne, then molar mass of the
gaseous mixture will be
(A) 46 g (B) 45 g (C) 60 g (D) 32 g

3
12. Calculate mass of carbon in 0.01 mole of K4[Fe(CN)6]. Report your answer after dividing by 0.08.

24
13. What is the number of gram atoms of oxygen in 6.023 ×10 CO-molecule.

14. A gaseous mixture contains SO3(g) and CH4(g) in 25 : 1 ratio by mass. What is ratio of total number of
atoms present in SO3(g) to total number of atoms present in CH4(g) in the mixture.

15. A gaseous mixture is composed of equal number of moles of CH4, C2H6 and C2H2. Determine the
average molecular mass of mixture (in amu).

16. Match the column :

DPP No. : 3 (JEE-MAIN)

Total Marks : 68 Max. Time : 40 min.
ChemINFO : 8 Questions ('–1' negative marking) Q.1 to Q.8 (4 marks, 2 min.) [32, 16]
Single choice Objective ('–1' negative marking) Q.9 to Q. 20 (3 marks, 2 min.) [36, 24]

ChemINFO Atomic Structure

Daily Self-Study Dosage for mastering Chemistry I. Cathode Rays-Discovery of Electron

In 1859, Julius Plucker started the study of conduction of electricity through gases at low pressure
-4
(10 atm) in a discharge tube. When a high voltage of the order of 10,000 volts or more was applied across the
electrodes, some sort of invisible rays moved from the negative electrode to the positive electrode. These rays
are called cathode rays.

Properties :
(i) Path of travelling is straight with a very high velocity as it produces shadow of an object placed in their
path.
(ii) Cathode rays produce mechanical effects. If small light paddle wheel is placed between the electrodes,
it rotates. This indicates that the cathode rays consist of material particles.
(iii) When electric and magnetic fields are applied, the rays are deflected thus establishing that they consist
of charged particles. The direction of deflection showed that cathode rays consist of negatively charged
particles called electrons. Electrons were discovered by J.J. Thomson.
(iv) They produce a green glow when strike the glass wall beyond the anode. Light is emitted when they
strike the zinc sulphide screen.
(v) Cathode rays penetrate through thin sheets of aluminium and other metals, affect the photographic
plates and produce heating effect when they collide with a metal objective.
11
(vii) Specific charge i.e. charge/mass is same (1.76 × 10 C/kg) for all cathode rays irrespective of the gas
used in the tube or the material of cathode. Thus, electrons were considered fundamental particles of
matter.
Read this unseen theory & Learn it. It is not expected that this will be covered in class. Read it,
understand it & then answer the following questions (1–4):

4
1. Which is not true with respect to cathode rays :
(A) Cathode rays consist of fast moving electrons.
(B) For production of Cathode rays in a discharge tube, the gas filled should be at a low pressure.
(C) For production of Cathode rays in a discharge tube, the voltage applied across the electrodes
should be high.
(D) None of these

2. Select the correct statement :

(A) Cathode rays have charge only, no mass.
(B) Cathode rays move with same speed as that of light.
11
(C) The magnitude of e/m ratio for Cathode rays is 1.76 × 10 C/g.
(D) Cathode rays are deflected by electric and magnetic field.

3. The e/m ratio for cathode rays :

(A) varies with the element forming the cathode in the discharge tube.
(B) varies with the gas in the discharge tube.
(C) is constant.
(D) has the smallest value when the discharge tube is filled with hydrogen.

4. Cathode rays _____ penetrate through thin metal sheets and produce _______ effect when they collide
with a metal object :
(A) can, cooling (B) can, heating (C) cannot, heating (D) cannot, cooling

ChemINFO Atomic Structure

Daily Self-Study Dosage for mastering Chemistry II. Anode Rays-Discovery of Proton

Goldstein (1886) repeated the cathode ray experiment with a discharge tube filled with a perforated cathode
and found that new type of rays came out through the hole in the cathode. When this experiment is conducted,
a faint red glow is observed on the wall behind the cathode. These rays are called anode rays.

Properties :
 Anode rays travel along straight paths and hence they cast shadows of object placed in their path.
 They rotate a light paddle wheel placed in their path. This shows that anode rays are made up of material
particles.
 They are deflected in magnetic field as well as towards the negative plate of an electric field. This shows
that these rays are positively charged.
 For different gases used in the discharge tube, the specific charge of the positive particles constituting the
positive rays is different. When hydrogen gas is taken in the discharge tube, the q/m value obtained for the
positive rays is found to be maximum. Since the value of charge (q) on the positive particle obtained from
different gases is the same, the value of m must be minimum for the positive particles obtained from
hydrogen gas. Thus, the positive particle obtained from hydrogen gas is the lightest among all the positive
particles obtained from different gases. This particle is called the proton (H+) and is also considered a
fundamental particle of matter.

Read this unseen theory & Learn it. It is not expected that this will be covered in class. Read it,
understand it & then answer the following questions (5–7):

5
5. Which of the following statements is/are INCORRECT regarding anode rays :
(A) Anode rays consist of fast moving protons.
(B) Anode rays are produced by the ejection of protons from the anode material.
(C) Both (A) & (B)
(D) None of these.

6. Select the correct statement(s) :

(A) Anode rays have charge as well as mass.
(B) Anode rays are deflected by electric and magnetic field.
(C) Anode rays are also known as Positive rays or Canal rays.
(D) All of these

7. The e/m ratio for Anode rays :

(A) varies with the element forming the anode in the discharge tube.
(B) varies with the gas in the discharge tube.
(C) is constant.
(D) Both (A) & (B).

8. The highest value for e/m for anode rays has been observed when the discharge tube is filled with
______ gas:
(A) nitrogen (B) oxygen (C) hydrogen (D) helium

9. Match the following :

(A) (1 - q, 2 - s, 3 - r, 4 - p) (B) (1 - p, 2 - p, 3 - q, 4 - s)
(C) (1 - r, 2 - s, 3 - p, 4 - q) (D) (1 - q, 2 - s, 3 - p, 4 - r)

10. Which of the following is an arrangement of increasing value of e/m (wrt magnitude only) :
(A) n <  < p < e (B) e < p <  < n (C) n < p < e <  (D) n < p <  < e

11. The ratio of the e/m values of a proton and an  -particle is.
(A) 2 : 1 (B) 1 : 1 (C) 1 : 2 (D) 1 : 4

12. Which has highest specific charge?

+ +2
(A) Na (mass no. = 23) (B) Mg (mass no. = 24)
+3 +4
(C) Al (mass no. = 27) (D) Si (mass no. = 28)

13. Rutherford’s experiment, which established the nuclear model of the atom, used a beam of :
(A)  -particles, which impinged on a metal foil & got absorbed.
(B)  -rays, which impinged on a metal foil & ejected electrons.
(C) helium atoms, which impinged on a metal foil & got scattered.
(D) helium nuclei, which impinged on a metal foil & got scattered.

14. The mass of an electron in amu is :

–3 –28 –4 –31
(A) 5.48 × 10 amu (B) 9.109 × 10 amu (C) 5.48 × 10 amu (D) 9.109 × 10 amu

15. How many moles of protons will have total charge equal to about 4825 Coulombs :
(A) 0.02 mole (B) 0.5 mole (C) 0.05 mole (D) 0.2 mole
24
16. Which of the following samples does not contain a total of 1.8066 × 10 atoms :
(A) 0.375 mole of S8 (B) 45 g of NO
(C) 24 g of Oxygen (D) 0.5 gram-molecule of ethene (C2H4)

6
17. Total number of H2 molecules that can be obtained from all hydrogen atoms of 10 formula units of
CH3COONH4 is :
(A) 35 NA (B) 140 (C) 140 NA (D) 35

18. The number of neutrons present in 7 gm of phosphonium PH4 ion is : 

31 1
15 P,1 H :
(A) 8 NA (B) 3.2 NA (C) 4 NA (D) 5 NA
23
19. Total number of ions in 17.1 g Al2(SO4)3 is [NA = 6 × 10 ]
23 23 23 22
(A) 1.5 × 10 (B) 4.5 × 10 (C) 3 × 10 (D) 6 × 10

20. If 36 grams of ozone gas is replaced by an another unknown gas ‘X’ keeping all other parameters same
and the gas ‘X’ weighs 24 g, then the unknown gas may be :
(A) SO2 (B) O2 (C) CH4 (D) None of these

DPP No. : 4 (JEE-MAIN)

Total Marks : 64 Max. Time : 42 min.
Single choice Objective ('–1' negative marking) Q.1 to Q.2 (3 marks, 2 min.) [06, 04]
Multiple choice objective ('–1' negative marking) Q.3 to Q.7 (4 marks, 2 min.) [20, 10]
Comprehension ('–1' negative marking) Q.8 to Q.9 (3 marks, 2 min.) [06, 04]
Single Integer type Questions ('–1' negative marking) Q.10 to Q.13 (4 marks, 3 min.) [16, 12]
Double Integer type Questions ('–1' negative marking) Q.14 to Q.15 (4 marks, 3 min.) [08, 06]
Match the Following (no negative marking) Q.16 (8 marks, 6 min.) [08, 06]

2+
1. The potential energy of the electron present in the ground state of Li ion is represented by :
(r = Radius of ground state)
3e 2 3e 3e 2 3e 2
(A)  (B)  (C)  (D) 
4  0 r 4  0 r 4  0 r 2 4  0 r

2.  -particles are projected towards the following metals, with the same kinetic energy. Towards which
metal, the distance of closest approach is minimum ?
(A) Cu(Z = 29) (B) Ag(Z = 47) (C) Au(Z = 79) (D) Ca(Z = 20)

3. Which of the following pairs has different values of e/m :

(A) A proton and a neutron (B) A proton and a Deuterium nucleus
(C) A Deuterium nucleus and an  -particle (D) An electron and  -particle

4. As an electron (at rest) is brought towards a proton from infinity, its :

(A) Potential energy increases (B) Potential energy decreases
(C) Kinetic energy increases (D) Total energy remains constant

5. A wavelength of 400 nm of an electromagnetic radiation is corresponding to :

14 6 -1
(A) frequency = 7.5 × 10 Hz (B) wave number = 2.5 × 10 m .
8 -1
(C) velocity = 3 × 10 ms (D)  = 40 Å

6. Which of the following path of  –particle is/are possible in the  -particle scattering experiment ?

(A) I (B) II (C) III (D) IV

7
7. Three different containers contain three different gases with following parameter.
0
Container 1 of 67.2 L containing gas X at 0 C and 1.01325 bar
Container 2 of 44.8 L containing gas Y at 546 K & 760 mm of Hg
2 0
Container 3 of 89.6 L containing Z gas at 101325 N/m & 0 C.
Now they are mixed in single container. If gram molecular mass of X, Y & Z are 10 g/mol, 20 g/mol and
40 g/mol respectively. Then which of the following statements are correct
(A) Mole percent of gas Z in final mixture is 50%
(B) Average molecular mass of final mixture is 26.25 amu.
(C) Mole ratio of gas X and gas Z is 3 : 4
(D) Number of molecules present in final mixture is equal to number of atoms in 320 g Ca.

Comprehension #
Rutherford model :
The approximate size of the nucleus can be calculated by using energy conservation theorem in
Rutherford’s -scattering experiment. If an -particle is projected from infinity with speed v, towards the
nucleus having Z protons, then the -particle which is reflected back or which is deflected by 1800 must
have approached closest to the nucleus. It can be approximated that -particle collides with the nucleus
and gets back. Now, if we apply the energy conservation equation at initial point and collision point,
then :

(P.E.)i = 0, since P.E. of two charge system separated by infinite distance is zero. Finally the particle
stops and then starts coming back.

Thus the radius of nucleus can be calculated using above equation. The nucleus is so small a particle
that we can’t define a sharp boundary for it.

8. An  -particle with initial speed v is projected from infinity and it approaches up to r distance from a
0 0

nuclie. Then, the initial speed of  -particle, which approaches upto 2r distance from the nucleus, is:
0

v0 v0
(A) 2 v0 (B) (C) 2v 0 (D)
2 2
9. Radius of a particular nucleus is calculated by the projection of  -particle from infinity at a particular
speed. Let this radius is the true radius. If the radius calculation for the same nucleus is made by
another  -particle with half of the earlier speed, then the percentage error involved in the radius
calculation is :
(A) 75% (B) 100% (C) 300% (D) 400%

10. If the diameter of two different nuclei are in the ratio 2 : 1,then calculate the ratio of their mass number :

11. For a broadcasted electromagnetic wave having frequency of 1200 KHz, calculate number of waves
that will be formed in 2 km distance.

12. Calculate the ratio of the energy of a photon of wavelength 3000 Å to that of a photon of wavelength
6000Å respectively.

13. What volume (in mL) of liquid H2O2 has same number of molecules as there are number of molecules in
-3
22.4 ml H2O(g) at 2 atm and 546 K. [Given : Density of liquid H2O2 = 6.8 x 10 gm/ml]

8
14. If the atomic number (Z) and mass number (A) of an element X are related by the equation : A + Z = 46
and the total number of neutrons in one atom of X is 16, then the total number of protons and electrons
in one atom of element X = ‘a’. Find value of ‘a’.

14 -1 5
15. If the frequency of violet radiation is 7.5 × 10 Hz, then the value of wavenumber in m for it is p × 10 .
Give the value of p?

16. Match the column :

DPP No. : 5 (JEE-MAIN)

Total Marks : 63 Max. Time : 39 min.
Single choice Objective ('–1' negative marking) Q.1 to Q.3 (3 marks, 2 min.) [09, 06]
Multiple choice objective ('–1' negative marking) Q.4 to Q.6 (4 marks, 2 min.) [12, 06]
Comprehension ('–1' negative marking) Q.7 to Q.8 (3 marks, 2 min.) [06, 04]
Single Integer type Questions ('–1' negative marking) Q.9 to Q.11 (4 marks, 3 min.) [12, 09]
Match the Following (no negative marking) Q.12 (8 marks, 6 min.) [08, 06]
ChemINFO : 4 Questions ('–1' negative marking) Q.13 to Q.16 (4 marks, 2 min.) [16, 08]

1. Four different containers contain four different gases with following parameters :

now they are mixed in a single container, then which of following option is correct.
(A) Mole % of gas X and gas Z are same. (B) Average molar mass of final mixture is 25.
(C) Mole ratio of gas W and gas Z is 4 : 1 (D) All are correct.

2. One quantum is absorbed per gaseous molecule of Br2 for converting into Br atoms. If light absorbed
has wavelength 5000Å, then the bond energy of Br2 is about ..... KJ/mol (1eV/particle = 96 KJ/mol).
(A) 119 (B) 238 (C) 357 (D) 476

3. A photon of 300 nm is absorbed by a gas and then, it re-emits two photons and attains the same initial
energy level. One re-emitted photon has wavelength 500 nm. Calculate the wavelength of other photon
re-emitted out :
(A) 450 nm (B) 800 nm (C) 200 nm (D) 750 nm

4. Identify the correct statement(s) :

(A) Cathode rays produce heating effect when they collide with a metal object.
(B) Anode rays consist of fast moving protons.
(C) For production of Cathode rays in a discharge tube, the gas filled should be at a very high pressure.
11
(D) The magnitude of e/m ratio for Cathode rays is 1.76 × 10 C/Kg.

5. In which of the following conditions, the de-Broglie wavelength of a charged particle A will be less than
that of another charged particle B ? Given that particle A is heavier than particle B :
(A) Linear momentum of these particles is same.
(B) Both particles move with same speed.
(C) Both particles have same kinetic energy.
(D) Same potential difference has been applied across both the particles from rest.
9
6. Select the correct statement :
-
(A) Orthosilicate ion (SiO4 ) and Perchlorate ion (ClO4 ) are isoelectronic species.
4-

(B) According to Rutherford formula, volume of a nucleus is directly proportional to mass number of
nucleus.
(C) Isotopes have different number of nucleons in them.
(D) All atoms of Ar, K and Ca are isobars of each other.

Comprehension #
A chemist was performing an experiment to study the effect of varying voltage and de-Broglie
wavelength of the electron. In first experiment , the electron was accelerated through a potential
difference of 1 kV from rest and in second experiment , it was accelerated through a potential difference
of 2 kV from rest.
The wavelength of de-Broglie waves associated with electron is given by :
h

2qVm
where , V is the voltage through which an electron is accelerated.
Putting the values of h, m and q, we get
12.3
 Å
V
Answer the following questions

7. The wavelength of electron will be :

(A) 1.4 times in first case than in second case (B) 1.4 times in second case than in first case
(C) double in second case than in first case (D) double in first case than in second case

8. In order to get half velocity of electron than in second case, the applied potential difference from rest
will be :
(A) 0.25 kV (B) 2 kV (C) 0.5 kV (D) 0.75 Kv

9. What change in molar energy (in J) would be associated with an atomic transition giving rise to a
-34 10
radiation of 1 Hz frequency : (h = 6.6 × 10 Js). Report your answer after multiplying by 10

10. For a wave, frequency is 10 Hz and wavelength is 2.5 m. How much linear distance (in km) will it travel
in 40 seconds.

11. A certain dye absorbs 4000 Å and fluoresces at 8000 Å. These being wavelengths of maximum
absorption that under given conditions 50% of the absorbed energy is emitted. Calculate the ratio of the
no. of quanta emitted to the number absorbed.

12. Match the following : (Mass numbers : H = 1, C = 12, N = 14, O = 16)

ChemINFO Atomic Structure

Daily Self-Study Dosage for mastering Chemistry III. Rutherford Scattering formula
The scattering of alpha particles from nuclei can be modeled from the coulomb force and treated as an
orbit. The scattering process can be treated statistically in terms of the cross section for interaction with
a nucleus, which is considered to be a point charge Ze. For a detector at specific angle with respect to
the incident beam, the number of particles per unit area striking the detector N() is given by the
Rutherford formula:

10
 N int Z 2k 2 e 4
N( ) 
4r 2KE 2 sin 4  / 2

Ni = Number of incident alpha particles

n = Atoms per unit volume, in target
t = Thickness of target
Z = Atomic number of target
e = Electronic charge
K = Coulomb's constant
r = Target-to-detector distance
KE = Kinetic energy of alpha particle
 = Scattering angle
PE = Potential energy

1 
In general, N ()   cos ec 4
 2
sin 4
2
N( )  t
1
N( ) 
KE 2
Ex. In Rutherford formula, the number of -particles showing scattering is minimum when  is :
(A) 90º (B) 45º (C) 60º (D*) 180º
Sol.

13. Select the correct graph :

(A) (B) (C) (D)

14. In Rutherford experiment, minimum number of  -particles will be deflected on using the thin foil of
same thickness of which of the following metals?
(A) Ag (B) Au (C) Pt (D) Al

15. In Rutherford formula, maximum number of  -particles deflecting is for which among the following
angles  .
(A) 30º (B) 45º (C) 60º (D) 90º

16. Select the correct graph :

(A) (B) (C) (D)

11
 DPP No. : 6 (JEE-MAIN)

Total Marks : 60 Max. Time : 40 min.

Single choice Objective ('–1' negative marking) Q.1 to Q.20 (3 marks, 2 min.) [60, 40]

1. Which of the following is correct statement?

+ + + 2+
(A) The ratio of e/m value for H & He is 1 : 2. (B) The ratio of e/m value for He & Li is 7 : 8.
2+ 3+
(C) The ratio of e/m value for Li & Be is 9 : 8. (D) The ratio of e/m value for 11H & 12 H  is 1 : 2

2. If the volume of nucleus of an atom V is related to its mass number A as V  An according to

Rutherford's formula, find the value of n :
(A) n = –1 (B) n = 1 (C) n = 1/3 (D) n = –1/3

3. Photon of which light has minimum energy :

(A) green (B) blue (C) violet (D) red

4. Visible spectrum contains light of following colours "Violet - lndigo - Blue - Green - Yellow - Orange -
Red" (VIBGYOR).
14 14
Its frequency ranges from Violet (7.5 × 10 Hz) to Red (4 × 10 Hz). Find out the maximum wavelength
in this range :
(A) 400 Å (B) 750 Å (C) 4000 Å (D) 7500 Å

-17
5. Assume that 10 J of light energy is needed by the interior of the human eye to see an object. How
many minimum photons of green light (  = 310 nm) are needed to generate this energy:
(A) 14 (B) 15 (C) 16 (D) 17

6. The work function for a metal is 4 eV. To eject a photoelectron of zero velocity from the surface of the
metal, the wavelength of incident light should be below :
(A) 310 Å (B) 1550 Å (C) 155 Å (D) 3100 Å

7. The energies E1 and E2 of two electronic radiations are 25 eV per electron and 50 eV per electron
respectively. The relation between their de-broglie wavelengths i.e. 1 and 2 will be :
1
(A) 1 = 2 2 (B) 1 = 22 (C) 1 = 42 (D) 1  2
2
8. Which of the following statements is correct :
A) Observations like Photoelectric effect and Blackbody radiations could not be explained by particle
nature of electromagnetic radiations.
(B) UV rays and IR rays have the same frequency.
+
(C) Bohr's model is not valid for Li ion.
(D) None of these
-20
9. The energy required to remove an electron from a metal X is 3.31 × 10 J. Wavelength/s of light that
can photoeject an electron from metal X is/are
(A) 4  m (B) 6  m (C) 7  m (D) 5  m

10. The wavelength   of monochromatic light coming from some light sources is listed below. How many
of these sources will be able to exhibit photoelectric effect if incident upon surface of Li metal (work
function,  = 2.4 eV).

(A) 5 (B) 4 (C) 6 (D) 3

11. For which of the following species, Bohr model is not valid :
+ 2+ +
(A) He (B) H (C) Li (D) H

12
12. If radius of third stationary orbit (in Bohr's atom) is R. Then radius of fourth orbit will be
(A) R/5 (B) 9R (C) 9R/16 (D) 16R/9
2+
13. If the radius of the first Bohr orbit of the H atom is r, then for Li ion, it will be :
(A) 3r (B) 9r (C) r/3 (D) r/9
23
14. The number of Br¯ ions in 2.1 g CaBr2 is [NA = 6 × 10 ]
22 21 21 20
(A) 1.26 × 10 (B) 6.3 × 10 (C) 1.05 × 10 (D) 1.2 × 10
22
15. If the mass of 10 molecules of a hydorcarbon is about 1.2 g, then the gram molecular mass of
hydrocarbon is:
(A) 36 g (B) 72 g (C) 54 g (D) 90 g

16. The value of R will be maximum for which of the following gases :
(A) H2 (B) N2
(C) O2 (D) It has the same value for all gases.

17. Volume occupied by an ideal gas at one atmospheric pressure and 0°C is V ml. Its volume at 273 K will
bel:
(A) V ml (B) V/2 ml (C) 2V ml (D) None of these

18. Which of the following exert highest pressure at 300 K and 4 L volume (assume ideal behaviour)?
(A) 28 g CO + 40 g D2 (B) 88 g CO2 + 280 g N2 (C) 256 g O2 + 400 g SO3 (D) 24 g He + 128 g CH4

19. Match the List I with the appropriate List II and select the correct answer using the code given below
the lists:

(A) 4 3 2 1 (B) 1 2 3 4 (C) 1 3 2 4 (D) 4 1 3 2

20. Select the correct option:

(A) In Photoelectric effect, all the ejected electrons have maximum possible K.E.
(B) Work function is independent of the nature of the metal on which light falls.
(C) Thomson assumed the mass of the atom to be uniformly distributed throughout the atom.
(D) Rutherford’s model explained the line spectrum of H atom.

DPP No. : 7 (JEE-MAIN)

Total Marks : 60 Max. Time : 40 min.
Single choice Objective ('–1' negative marking) Q.1 to Q.20 (3 marks, 2 min.) [60, 40]

1. 11.2 litre of a gas at STP weighs 14 g. The gas could not be :

(A) N2 (B) CO (C) C2H4 (D) N2O

2. x g Urea (NH2CONH2) contains y total number of atoms. 4x g Acetic acid (CH3COOH) contains py total
number of atoms. Find the value of p.
(A) 8 (B) 4 (C) 2 (D) 6

3. Air in a room is separated in two regions in volume ratio of 4 : 1 by an imaginary boundary. Which
statement is correct :
(A) Mavg of air in bigger region is half of Mavg of air in smaller region.
(B) Mavg of air is bigger region is twice of Mavg of air in smaller region.
(C) Both regions will have same Mavg of air.
(D) Mavg of air in bigger region is thrice of Mavg of air in smaller region.

13
 23
4. Find the average molar mass of a gaseous mixture in g/mole, which contains 1.2046 × 10 atoms of an
unknown gas and 0.2 mole of H2 gas. The weight of mixture is 22g.
(A) 44 (B) 55 (C) 110 (D) 22

5. The triad of nuclei which is isotonic will be

(A) 6C14 7N15 , 9F17 12 14
(B) 6C , 7N , 9F
19
14 14 17 14 14 19
(C) 6C , 7N , 9F (D) 6C , 7N , 9F

+2
6. “A ” is isoelectronic with N2O and has (Z + 1) neutron (Z is atomic number of A) then mass number of
A is:
(A) 45 (B) 41 (C) 49 (D) 43

7. Select the correct statement :

(A) Cathode rays are electromagnetic waves, but anode rays are not.
(B) Electromagnetic waves need a material medium for their propagation.
(C) Electromagnetic waves may have different frequencies.
(D) Electromagnetic waves consist of some material particles travelling with the speed of light.

8. A wavelength of 400 nm of electromagnetic radiation corresponds to :

14
(A) frequency   = 7.5 × 10 Hz (B) wave number   = 2.5 × 106 m-1.
-27 -1
(C) momentum of photon = 1.66 × 10 kg ms (D) all are correct values.

9. The de-Broglie wavelength of a particle with mass 1 g and velocity 100 m/s is :
-33 -34 -35 -36
(A) 6.63 × 10 m (B) 6.63 × 10 m (C) 6.63 × 10 m (D) 6.65 × 10 m

10. If the kinetic energy of a particle is doubled , De-Broglie wavelength becomes :

1
(A) 2 times (B) 4 times (C) 2 times (D) times
2

11. Momentum of a photon of wavelength  is :

h h h
(A) (B) zero (C) 2
(D)
 c c

12. When an electron drops from a higher energy level to a low energy level, then :
(A) energy is absorbed (B) energy is emitted
(C) atomic number increases (D) atomic number decreases
13. In hydrogen atom, energy of second state is –3.4 eV. Then, KE of electron in same orbit of hydrogen
atom is :
(A) + 3.4 eV (B) + 6.8 eV (C) – 13.6 eV (D) + 13.6 eV

14. In a certain electronic transition in the Hydrogen atom from an initial state i to a final state f, the
difference in the orbit radius (ri - rf) is seven times the first Bohr radius. Identify the transition:
(A) 4  1 (B) 4  2 (C) 4  3 (D) 3  1

15. The energy of an excited H-atom is –1.51 eV. Angular momentum of e– in the given orbit will be
(A) 3h/ (B) 3h/2 (C) 2h/ (D) h/

+3
16 The radius of the an orbit of Be ion is 0.529Å. The velocity of electron in this orbit will be
6 6 6 6
(A) 0.545 × 10 m/s (B) 2.18 × 10 m/s (C) 4.36 × 10 m/s (D)1.09 × 10 m/s

17. The ratio of radius of two different orbits in a H-atom is 4 : 9. Then, the ratio of the frequency of
revolution of electron in these orbits is :
(A) 2 : 3 (B) 27 : 8 (C) 3 : 2 (D) 8 : 27

14
18. Kinetic energy of electron which is moving in the orbit that has its radius, four times the radius of
second Bohr orbit for H–atom will be
(A) 0.85 eV (B) -0.85 eV (C) 0.54 eV (D) –0.54 eV

+
19. What is the ratio of speeds of electrons in Ist orbit of H-atom to IVth orbit of He ion.
(A) 2 (B) 8 (C) 3 (D) 27

20. Statement-1: We can use two photons successively of 1240 Å and 2000 Å wavelength in order to
ionise a H atom from ground state.
Statement-2: Sum of the energies of both the photons is greater than IE of H atom.
(A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.
(B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1
(C) Statement-1 is True, Statement-2 is False
(D) Statement-1 is False, Statement-2 is True

DPP No. : 8 (JEE-MAIN)

Total Marks : 64 Max. Time : 43 min.
Single choice Objective ('–1' negative marking) Q.1 to Q.2 (3 marks, 2 min.) [06, 04]
Multiple choice objective ('–1' negative marking) Q.3 to Q.6 (4 marks, 2 min.) [16, 08]
Comprehension ('–1' negative marking) Q.7 to Q.8 (3 marks, 2 min.) [06, 04]
Single Integer type Questions ('–1' negative marking) Q.9 to Q.14 (4 marks, 3 min.) [24, 18]
Double Integer type Question ('–1' negative marking) Q.15 (4 marks, 3 min.) [04, 03]
Match the column (no negative marking) Q.16 (8 marks 6 min.) [08, 06]

1. In a gaseous mixture, if an alkane (CxH2x + 2) and an alkene (CyH2y) are taken in 2 : 1 mole ratio, the
average molecular weight of mixture is observed to be 20. If the same alkane and alkene are taken in
1 : 2 mole ratio, the average molecular weight of mixture is observed to be 24. Then, the value of ‘x’
and ‘y’ are respectively :
(A) 2, 1 (B) 1, 2 (C) 2, 3 (D) 3, 2

2. In I experiment, electromagnetic radiations of a certain frequency are irradiated on a metal surface

ejecting photoelectrons having a certain value of maximum kinetic energy. However, in II experiment,on
doubling the frequency of incident electromagnetic radiations, the maximum kinetic energy of ejected
photoelectrons becomes three times. What percentage of incident energy is converted into maximum
kinetic energy of photoelectrons in II experiment ?
(A) 75 % (B) 50 % (C) 12.5 % (D) 25 %
3. Which of the following charge(s) can exist on an oil drop (in Millikan's oil drop experiment)
-19 -19 -19 -19
(A) 3.2 × 10 C (B) 8.3 × 10 C (C) 4.8 × 10 C (D) 9.6 × 10 C

4. Which of the following statement is(are) true in the context of photoelectric effect:
(A) The maximum possible kinetic energy of ejected electrons is independent of the intensity of
radiation at a given frequency.
(B) The threshold frequency is same for all metals.
(C) The number of photoelectrons ejected depends on the frequency of the incident radiation
(D) The maximum possible kinetic energy of the emitted electrons depends on the frequency of the
incident radiation

5. A single electron orbits around a stationary nucleus of charge +Ze where Z is atomic number and ‘e’ is
the magnitude of the electric charge. The hydrogen like species required 47.2 eV to excite the electron
from the second Bohr orbit to the third Bohr orbit. Which of the following is/are correct.
(A) Atomic number of species is 5
(B) The kinetic energy in first excited state is 85 eV
(C) the potential energy in second state is -170 eV
(D) First excitation potential of species is 255 V
15
6. Which one of the following relationships when graphed does not give a straight line for ideal gas?
I. K.E. and T at constant pressure and volume
II. P vs. V at constant temperature for a constant mass
III. V vs. 1/T at constant pressure for a constant mass
(A) I (B) II (C) III (D) I & III

Comprehension #
Niles Bohr a Danish physicist received his Ph.D from the University of Copenhagen in 1911. He then
spent a year with J.J. Thomson and Ernest Rutherford in England. In 1913, he returned to Copenhagen
whrere he remained for the rest of his life. In 1920 he was named Director of the Institute of theoritical
Physics. After first World War, Bohr worked energetiocally for peaceful uses of atomic energy. He
recieved the first Atoms for Peace award in 1957. Bohr was awarded the Nobel Prize in Physics in
1922.
(a) The Angular momentum of an electron in a given stationery state can be expressed as
h
mevr = n. where n = 1, 2, 3... Thus an electron can move only in those orbits for which its angular
2
momentum is intergal multiple of h/2 that is why only certain fixed orbits are alowed.
(b) The radii of the stationary states are expressed as rn  n 2 a0 where a0 = 52.9 pm. Thus the radius of
the first stationary state, called the Bohr radius, is 52.9 pm. Normally the electron in the hydrogen
atom is found in this orbit (that is n = 1). As n increases the value of r will increase.
(c) The most important property associated with the electron, is the energy of its stationary state. It is
 Z2 
given by the expression. En  2.18  10 –18  2  J n = 1,2,3
n 
 
(d) It is also possible to calculate the velocities of electrons moving in these orbits by using
Z
v n  2.18  10 6  m / sec . Qualitatively the magnitude of velocity of electron increases with increase
n
of positive charge on the nucleus and decreases with increase the value of n.
(e) Bohr’s theory can also be applied to the ions containing only one electron, similar to that present in
+ 2+ 3+
hydrogen atom. For example, He , Li , Be and so on.

7. Choose the correct statement:

(A) The order of velocity is v1 < v2 < v3 < v4 (vn : where n is orbit number for a given atom)
(B) The order of total energy is E1 > E2 > E3 > E4 (En : where n is orbit number for a given atom)
+ + 3+ 3+ +2 +
(C) The order of velocity of electron in H, He , Li , Be species in second Bohr orbit is Be < Li < He < H
(D) The order of Bohr radius is r1 < r2 < r3 < r4 (rn : where n is orbit number for a given atom)

8. Select the incorrect curve:

If v = velocity of electron in Bohr's orbit
r = Radius of electron in Bohr's orbit
P.E. = Potential energy of electron in Bohr's orbit
K.E. = Kinetic energy of electron in Bohr's orbit.

(A) (B) (C) (D)

9. Infrared lamps are used in restaurants to keep the food warm. The infrared radiation is strongly
absorbed by water, raising its temperature and that of the food. If the wavelength of infrared radiation is
assumed to be 1500 nm, then the number of photons per second of infrared radiation produced by an
19
infrared lamp that consumes energy at the rate of 100 W and is 12% efficient only is y x 10 . Find the
value of y.

16
10. The number of revolutions/sec made by an electron in IInd orbit is 8 times of the number of
th
revolutions/sec made by an electron in n orbit. Give the value of “n”.

11. In the Bohr's model, for unielectronic species following symbols are used
th
rn,z  Radius of n orbit with atomic number "z"
Un,z  Potential energy of electron in nth orbit with atomic number "z"
th
Kn,z  Kinetic energy of electron in n orbit with atomic number "z"
th
vn,z  Velocity of electron in n orbit with atomic number "z"
th
Tn,z  Time period of revolution of electron in n orbit with atomic number "z"
Calculate z in all in cases.
(i) U1, 2 : K1,z = – 8 : 9 (ii) r1,z : r2, 1 = 1 : 12 (iii) v1, z : v3, 1 = 15 : 1 (iv) T1, 2 : T2, z = 9 : 32
Report your answer as (2r-p-q-s) where p, q, r and s represents the value of "z" in parts (i), (ii) ,(iii) &
(iv).

12. What is the ratio of the wave lengths of last lines of Balmer and Lyman series.

13. Calculate maximum number of possible spectral lines which may be emitted in brackett series in H
th
atom, if electrons present in 9 excited level return upto ground level in a sample of H-like species.

14. What minimum number of atoms/ions should be present in a sample of H-like species, so that a
maximum of 6 spectral lines can be produced of electronic transition from fifth excited state upto n = 2?

+ +
15. In a mixture of sample of H-atoms and He ions, electrons in all the H-atoms and He ions are present
th
in n = 4 state. Then, find maximum number of different spectral lines obtained when all the electrons
make ransition from n = 4 upto ground state.

16. Match the following :

DPP No. : 9 (JEE-MAIN)

Total Marks : 60 Max. Time : 40 min.
Single choice Objective ('–1' negative marking) Q.1 to Q.20 (3 marks, 2 min.) [60, 40]

1. Fluoxymesterone, C20H29FO3, is an anabolic steroid. A solution is prepared by dissolving 10.0 mg of the

steroid in 500 mL of water. How many moles of Fluoxymesterone are present in 1 mL of solutions.
-10 -17 -8 -11
(A) 1.16 × 10 (B) 1.19 × 10 (C) 5.95 × 10 (D) 2.38 × 10

2. Volume at STP of 0.22 g of CO2 is same as that of :

(A) 0.01 g of hydrogen (B) 0.085 g of NH3
(C) 320 mg of gaseous SO2 (D) All the above

3. Which of the following is incorrect about a sample of 11.2L CH4 gas at STP :
23
(A) Number of molecules in the sample are 3.01 × 10
(B) Weight of 11.2L of CH4(g) at STP is 8 g.
22
(C) Number of atoms in the sample are 15.05 × 10
(D) None of these

17
4. Boron has two isotopes, B–10 and B–11. The average atomic mass of boron is found to be 10.80 u.
Predict the percentage of abundance of these elements respectively.
(A) B–10 = 80% ; B–11 = 20% (B) B–10 = 40% ; B–11 = 60%
(C) B–10 = 20% ; B–11 = 80% (D) B–10 = 70% ; B–11 = 30%

5. 0.2 moles of an unknown compound weigh 5.6 g. The unknown compound is :

(A) N2 (B) CO2 (C) CO (D) N2O

6. Which of the following statements about the electromagnetic radiation is incorrect.

(A) IR radiations have larger wavelength than X-rays
(B) The frequency of visible region is less than that of UV region
(C) Gamma rays have larger wave number than micro wave
(D) The velocity of  rays is more than that of IR radiations
3+
7. Li and a proton are accelerated by the same potential, their de-Broglie wavelengths have the ratio
(assume mass of proton = mass of neutron) :
(A) 1 : 2 (B) 1 : 4 (C) 1 : 21 (D) 1 : 3 3

8. If numerical value of mass and velocity are equal for a particle, then its de-Broglie wavelength in terms
of K.E. is :
mh h
(A) (B) (C) both are correct (D) none is correct.
2K.E. 2mK.E.

9. The wave motion of an electron in a Bohr's orbit of Hydrogen atom is as shown in diagram. The orbit
number is:

(A) 2 (B) 3 (C) 4 (D) 6

nd
10. If the de-Broglie wavelength of an electron revolving in 2 orbit of H-atom is x, then radius of that orbit
is given by :
x 2x x
(A) (B) (C) (D) Cannot be determined
  2
+
11. The most probable radius (in pm) for finding the electron in He is :
(A) 0.0 (B) 52.9 (C) 26.5 (D) 105.8

12. What is the ratio of minimum to maximum wavelength of radiation emitted by electron when it jumps
2+
from a higher state to ground state in Li ion :
1 8 3 1
(A) (B) (C) (D)
4 9 4 9

13. An electron jumps from nth level to the first level.

The correct statement is :
n(n - 1) n(n  1)
(A) Number of spectral lines = (B) Number of spectral lines =
2 2
(C) If n = 4 , number of spectral lines = 6 (D) Both (A) and (C)

14. Statement-1 : It is possible to measure simultaneously both the position and momentum of a moving
microscopic particle with absolute accuracy.
Statement-2 : In case of moving microscopic particle, if uncertainty in position is reduced, then
uncertainty in velocity is very high and vice versa.
(A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.
(B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1
(C) Statement-1 is True, Statement-2 is False
(D) Statement-1 is False, Statement-2 is True

18
15. According to Heisenberg's uncertainty principle, on increasing the wavelength of light used to locate a
microscopic particle, uncertainty in measurement of position of particle :
(A) Increases (B) Decreases (C) Remains unchanged (D) Cannot be

-5
16. The uncertainty in momentum of an electron is 1 × 10 kg.m/s. The uncertainty in its position will be (h
-34 2
= 6.62 × 10 kg m /s) :
-28 -26 -30 -28
(A) 1.05 × 10 m (B) 1.05 × 10 m (C) 5.27 × 10 m (D) 5.25 × 10 m

-31 -34
17. Given : The mass of electron is 9.11 x 10 kg, planck constant is 6.626 x 10 J s, the Uncertainity
involved in the measurement of velocity within a distance of 0.1 Å is :
8 -1 5 -1 6 -1 7 -1
(A) 5.79 x 10 m s (B) 5.79 x 10 m s (C) 5.79 x 10 m s (D) 5.79 x 10 m s

18 The uncertainties in measurement of position and momentum (in SI units) of an electron are equal.
h
Choose the correct statement : (Given  7.2  10 18
4
13
(A) The uncertainty in measurement of speed = 8 × 10 m/s.
(B) The uncertainty in measurement of kinetic energy = h/8  m .
(C) Increasing the wavelength of light used in the experiment will decrease the uncertainty in position
and increase the uncertainty in momentum.
(D) None of these

19. If uncertainty in momentum is twice the uncertainty in position of an electron, then uncertainty in
 h 
velocity of electron is :  
 2 
1 1 1 1
(A)  (B) (C) (D) 
2m 4 m 4m m

20. Which of the following statements is correct :

(A) Two charged particles having the same mass and accelerated through same potential difference
from rest will have same value of de-Broglie wavelength.
(B) Heisenberg’s uncertainty principle is more significant for microscopic particles than for macroscopic
particles.
(C) When electron jumps from lower energy level to higher energy level it emits energy.
(D) According to de-Broglie, wavelength associated with electron and proton are same. If both have
same velocity.

DPP No. : 10 (JEE-ADVANCED)

Total Marks : 62 Max. Time : 41 min.
Single choice Objective ('–1' negative marking) Q.1 to Q.4 (3 marks, 2 min.) [12, 08]
Multiple choice objective ('–1' negative marking) Q.5 to Q.8 (4 marks, 2 min.) [16, 08]
Comprehension ('–1' negative marking) Q.9 to Q.10 (3 marks, 2 min.) [06, 04]
Single Integer type Questions ('–1' negative marking) Q.11 to Q.13 (4 marks 3 min.) [12, 09]
Double Integer type Questions ('–1' negative marking) Q.14 to Q.15 (4 marks 3 min.) [08, 06]
Match the column (no negative marking) Q.16 (8 marks 6 min.) [08, 06]

1. A certain dye absorbs light of certain wavelength and then fluorescence light of wavelength 5000 Å.
Assuming that under given conditions, 50% of the absorbed energy is re-emitted out as fluorescence
and the ratio of number of quanta emitted out to the number of quanta absorbed is 5 : 8, find the
wavelength of absorbed light (in Å) : [hc = 12400 eVÅ ]
(A) 4000 Å (B) 3000 Å (C) 2000 Å (D) 1000 Å

19
 th
2. In a single isolated atom of hydrogen, electrons make transition from 4 excited state to ground state
nd
producing maximum possible number of wavelengths. If the 2 lowest energy photon is used to further
2+
excite an already excited sample of Li ion, then transition will be :
(A) 12  15 (B) 9  12 (C) 6  9 (D) 3  6

3. Two electrons A and B in an atom have the following set of quantum numbers; what is true for A and B:
1 1
For A; n = 3, = 2, m = –2, s =  ; For B; n = 3, = 0, m = 0, s = 
2 2
(A) A and B have same energy (B) A has more energy than B
(C) B has more energy than A (D) A and B represent the same electron

4. Which of the following pair of orbitals for mentioned species have equal energy :
+ + 2+
(A) 2s (He ) and 4p (H) (B) 8p (He ) and 6s (Li )
+ 3+ + 3+
(C) 6s (He ) and 18s (Be ) (D) 4p (He ) and 8d (Be )

5. When photons of energy 4.25 eV strike the surface of a metal A, the ejected photoelectrons have
maximum kinetic energy (K.E)A and de-Broglie wavelength is  A. The maximum kinetic energy of
photoelectrons liberated from another metal B by photons of energy 4.7 eV is (KE)B, where (KE)B =
(KE)A –1.5 eV. If the de-Broglie wavelength of these photoelectrons is B. (= 2  A. ), then :
(A) The work function of metal A is 2.25 eV (B) The work function of metal B is 4.20 eV
(C) (KE)A = 2 eV (D) (KE)B = 2.75 eV

4+
6. Which of the following statements is incorrect with respect to V ion :
(A) Maximum possible number of electrons with clockwise spin and m = 0 is 11.
(B) The quantum numbers for the unpaired electron is n = 4, = 0, m = 0.
(C) Total number of electrons in orbitals with one radial node and ms = 1/2 is 4.
(D) Total number of filled orbitals having = 0 is 6.

7. Which of the following set of orbitals are arranged in correct energy order ?
(A) 3px > 3s > 2pz (in He) (B) 3px = 3s = 2pz (in H)
+
(C) 4px = 4py = 4pz (in He ) (D) 4px = 4py = 4pz = 4s = 4dxy (in H)

Comprehension #
Azimuthal quantum number () :
It describes the shape of electron cloud and the number of subshells in a shell.
* It can have values from 0 to (n – 1)
* value of  0 1 2 3
subshell s p d f
* Number of orbitals in a subshell = 2+ 1
h  h 
* Orbital angular momentum L  (  1)   (  1)   2 
2  
Magnetic quantum number (m) :
It describes the orientations of the subshells. It can have values from –to + including zero, i.e., total
(2+ 1) values. Each value corresponds to an orbital. s-subshell has one orbital, p-subshell three
orbitals (px, py and pz), d-subshell five orbitals (d xy , d yz , d zx , d x 2  y 2 , d z 2 ) and f-subshell has seven
orbitals.
Spin quantum number (s) :
It describes the spin of the electron. It has values +1/2 and –1/2. Signifies clockwise spinning and
anticlockwise rotation of electron about its own axis.
h 1
Spin of the electron produces angular momentum equal to S  s(s  1) where s  
2 2

20
 n n
Total spin of an atom =  or  (where n is the number of unpaired electron)
2 2

The magnetic moment of an atom  s  n(n  2) B.M. n = number of unpaired electrons n(n 2)
B.M. (Bohr magneton)

8. A d-block element has total spin value of +3 or –3 then the magnetic moment of the element is
approximately:
(A) 2.83 B.M. (B) 3.87 B.M. (C) 5.9 B.M. (D) 6.93 B.M.

4+ 3+ 3+
9. The correct order of the maximum spin of [25Mn , 24Cr , 26Fe ] is :
3+ 3+ 4+ 3+ 3+ 4+ 3+ 4+ 3+ 3+ 4+ 3+
(A) Fe > Cr = Mn (B) Fe = Cr > Mn (C) Cr = Mn > Fe (D) Fe > Mn > Cr

h
10. Orbital angular momentum of an electron is 3 then the number of orientations of this orbital in

space are
(A) 3 (B) 5 (C) 7 (D) 9

11. In one experiment, a proton having initial kinetic energy of 1 eV is accelerated through a potential
difference of 3 V. In another experiment, an -particle having initial kinetic energy 20 eV is retarded by
a potential difference of 2 V. Calculate the ratio of de-Broglie wavelengths of proton and  -particle.

12. If the value of Azimuthal Quantum Number for an electron in a particular subshell is 3, then what will
be the minimum value of shell number associated with this electron.

nm
13. What is the value of   for all possible orbitals with number of radial nodes = 1 and where
 2 
n3.

st
14. In a sample of hydrogen atom containing 1 mole H atoms, electrons in 30% of H-atoms are in 1
nd
excited state and remaining are in 2 excited state and ground state. If the total energy emitted when
nd
all electrons return to ground state is 642.24 kJ, find % of electrons in 2 excited state.
Energy level in H atom = E1 = –13.6 eV, E2 = –3.4 eV, E3 = –1.5 eV and (1 eV / species=96 kJ/mole)

15. What is the maximum possible number of electrons in an atom with (n + = 7) :

16. Match the column

21
 DPP No. : 11 (JEE-ADVANCED)
Total Marks : 57 Max. Time : 35 min.
Single choice Objective ('–1' negative marking) Q.1 to Q.4 (3 marks, 2 min.) [12, 08]
Multiple choice objective ('–1' negative marking) Q.5 to Q.10 (4 marks, 2 min.) [24, 12]
Comprehension ('–1' negative marking) Q.11 to Q.13 (3 marks, 2 min.) [09, 06]
Single Integer type Questions ('–1' negative marking) Q.14 to Q.15 (4 marks 3 min.) [08, 06]
Double Integer type Question ('–1' negative marking) Q.16 (4 marks 3 min.) [04, 03]

st + nd 2+
1. In a sample, one H atom is in I excited state, two He ion are in II excited state and three Li ions are
rd
in III excited state. Then, find the maximum number of spectral lines which can be obtained, when all
possible transitions terminate at n = 1 :
(A) 9 (B) 10 (C) 11 (D) 8

3+ +
2. Among the following, which orbital in Be has same energy as that of electron in He in ground state
and also has 2 angular nodes?
(A) 2s (B) 2px (C) 3dxy (D) None of these

3. Bombardment by  -particle leads to artificial disintegration in three ways, (I), (II) and (III) as shown.
Products X, Y and Z respectively are :

(A)  -particle, proton, positron (B) positron, neutron, proton

(C)  -particle, neutron, proton (D) positron, proton, neutron

4. Which particle must have been produced in the following processes respectively:
14 4 17 198 198
(I) 7N + 2He  8O + .... (II) 79Au  80Hg + ....
24 4 27 23
(III) 12Mg + 2He  14Si + .... (IV) 11Na23  10Ne + ....
(A) Proton, Positron, Neutron,  -particle (B) Positron,  -particle, Neutron, Proton
(C) Proton,  -particle, Neutron, Positron (D) Positron, Neutron,  -particle, Proton

5. A neutral atom of an element has 2K, 8L, 9M and 2N electrons. Which of the following is/are correctly
matched :
(A) Total number of s electrons - 8 (B) Total number of p electrons - 12
(C) Total number of d electrons -1 (D) Number of unpaired electrons in element – 3

6. 4.0 g of caustic soda (NaOH) contains same number of sodium ions as are present in:
(A) 5.3 g of Na2CO3 (B) 0.05 mole of Na2SO4 (C) 5.85 g of NaCl (D) 0.1 mole of NaNO3

7. If the binding energy of 2nd excited state of a hypothetical H-like atom is 12 eV, then the CORRECT
option is/are :
(A) I excitation potential = 81 V (B) II Excitation energy = 96 eV
nd
(C) Ionisation potential = 192 V (D) Binding energy of 2 state = 27 eV

8. If the radius of first Bohr’s orbit of H-atom is x, which of the following is/are the CORRECT conclusion :
(A) The de-Broglie wavelength of electron in the third Bohr orbit of H-atom = 6  x
+
(B) The fourth Bohr’s radius of He ion = 8x
2+
(C) The de-Broglie wavelength of electron in third Bohr’s orbit of Li = 2  x
2+
(D) The second Bohr’s radius of Be = x

22
9. d z 2  orbital has: d
(A) A lobe along z-axis and a ring along xy-plane (B) A lobe along z-axis and a lobe along xy-plane
(C) It has two angular nodes (D) It has two radial nodes

10. Which of the following process lead to formation of isobars?

(A) 1  particle and 2  particles are emitted (B) Positron emission
(C) β particle  – 1e
0
 emission (D) K-electron capture

Comprehension # (11-13)
In the disintegration of a radioactive element ,  and  particles are evolved from the nucleus.

Then , emission of these particles changes the nuclear configuration and results into a daughter
nuclide. Emission of an -particle results into a daughter element having atomic number lowered by 2
and mass number by 4. On the other hand , emission of particle yields an element having atomic
number raised by one.

11. During beta decay, the mass number of atomic nucleus

(A) decreases by 1 unit (B) Increases by 1 unit (C) decreases by 2 unit (D) Remains unaffected

12. How many α and β particles should be emitted from a radioactive nuclide so that an isobar is formed
(A) 1α ,1β (B) 1α ,2β (C) 2α ,2β (D) nβ

13. Which of the following combinations give finally an isotope of the parent element?
(A) α, α, β (B) α,  , β (C) α, β, β (D) β,  , α

3+
14. The de-Broglie wavelength of electron in a certain orbit 'n' of Be ion is found to be 5.83 Å. Find the
value of 'n'. Take Ist Bohr radius for H-atom = 53 pm :

15. Find the value of x + 2y + z.

x = no. of radial nodes in 3px
y = no. of angular nodes in 6s
1
z = the maximum no. of electrons in 24Cr with n = 3 and s =  and orbital angular momentum 6 
2
16. 75 Re
162
 Z1 x A 1 + alpha particle
188 A2
74 W Z2 x + Beta particle
A 2  A1
Value of is
Z 2  Z1

23