Emergency Response Guidebook

THIS DOCUMENT SHOULD NOT BE USED TO
2012
DETERMINE COMPLIANCE WITH THE
DANGEROUS GOODS REGULATIONS
OR
TO CREATE WORKER SAFETY DOCUMENTS
FOR SPECIFIC CHEMICALS
EMERGENCY
NOT FOR SALE RESPONSE
GUIDEBOOK
A Guidebook for First
Responders During
the Initial Phase of a
Dangerous Goods/
Hazardous Materials
Transportation Incident
Gujarat State Disaster Management Authority

Block No. 11, 5th Floor, Udyog Bhavan, Sector – 11,
Gandhinagar – 382011. Gujarat, India.
Tel: +91-79-23259283/23259246
Fax: +91-79-23259275/23259302
Email: info@gsdma.org Gujarat State Disaster Management Authority
HOW TO USE THIS GUIDEBOOK
SHIPPING DOCUMENTS (PAPERS) RESIST RUSHING IN !
Shipping Documents (Papers) are synonymous and can be found as follows: APPROACH INCIDENT FROM UPWIND, UPHILL OR UPSTREAM
STAY CLEAR OF ALL SPILLS, VAPOURS, FUMES, SMOKE AND SUSPICIOUS SOURCES
• Road – kept in the cab of a motor vehicle
• Rail – kept in possession of a crew member STEP ONE: IDENTIFY THE MATERIAL AND USE ANY OF THE FOLLOWING:
• Aviation – kept in possession of the aircraft pilot • IDENTIFICATION NUMBER (4-DIGIT ID AFTER UN) FROM A:
• Marine – kept in a holder on the bridge of a vessel - PLACARD
- ORANGE PANEL
Shipping Documents (Papers) provide vital information regarding the hazardous - SHIPPING PAPER OR PACKAGE
materials/dangerous goods to initiate protective actions* • NAME OF THE MATERIAL FROM A:
-SHIPPING DOCUMENT OR PACKAGE
Information provided:
STEP TWO: IDENTIFY 3-DIGIT GUIDE NUMBER, USE:
• 4-Digit Identification Number, UN (go to Yellow Pages)
• ID NUMBER INDEX in yellow-bordered pages or
• Proper Shipping name (go to Blue Pages)
. • NAME OF MATERIAL INDEX in blue-bordered pages
• Emergency Response Telephone Number
Guide number supplemented with the letter (P) indicates that the material may undergo
• Hazard Class or Division number of material violent polymerization if subjected to heat or contamination.
• Packing Group INDEX ENTRIES HIGHLIGHTED IN GREEN are a TIH (Toxic Inhalation Hazard) material, a
• Information describing the hazards of the material (entered on or attached to chemicalwarfare agent or a Dangerous Water Reactive Material (produces toxic gas upon
shipping document) contact with water).
IDENTIFY ID NUMBER AND NAME OF MATERIAL IN TABLE 1 – INITIAL ISOLATION AND
PROTECTIVE ACTION DISTANCES (the green-bordered pages).
EMERGENCY CONTACT EXAMPLE OF EMERGENCY
IF NECESSARY, BEGIN PROTECTIVE ACTIONS IMMEDIATELY (see ProtectiveActions page 288). If
1-000-000-0000 CONTACT TELEPHONE NUMBER
no protective action required, use the information jointly with the 3-digit guide.
IF A REFERENCE TO A GUIDE CANNOT BE FOUND AND THIS INCIDENT IS BELIEVED TO
HAZARD CLASS INVOLVE DANGEROUS GOODS:
OR DIVISION NO. • Use GUIDE 111, UNTIL ADDITIONAL INFORMATION BECOMES AVAILABLE
NO. & TYPE
QUANTITY • Use GUIDE 112, EXPLOSIVES (other than 1.4 and 1.6)
OF PACKAGES
• Use GUIDE 114, EXPLOSIVES (1.4 and 1.6)
1 TANKTRUCK UN1219 ISOPROPANOL 3 II 12 000 LITERS
STEP THREE: TURN TO THE NUMBERED GUIDE (the orange-bordered pages) READ CAREFULLY.
IF A PLACARD IS THE ONLY SOURCE OF INFORMATION, turn to pages 6-7 and use the 3-digit guide next to
ID NUMBER SHIPPING NAME PACKING GROUP the placard and Proceed to Numbered Guide in orange-bordered pages.
AS A LAST RESORT: IF ONLY THE CONTAINER CAN BE IDENTIFIED, CONSULT THE TABLE OF RAIL CAR AND
ROAD TRAILER IDENTIFICATION CHART (page 11). INFORMATION ASSOCIATED WITH THESE CONTAINERS IS
EXAMPLE OF PLACARD AND PANEL WITH ID NUMBER FOR WORST-CASE SCENARIOS.
The 4-digit ID Number may be shown on the diamond-shaped placard or on an adjacent
orange panel displayed on the ends and sides of a cargo tank, vehicle or rail.car. CALL THE EMERGENCY RESPONSE TELEPHONE NUMBER:
• Listed on the shipping paper, if available.
• If shipping paper is not available, IMMEDIATELY CALL the appropriate emergency response
A Numbered A Placard agency telephone number listed on the inside back cover of this guidebook.
OR
Placard and an • Provide as much information as possible, such as the name of the carrier (trucking company or
Orange Panel railroad) and vehicle number.
* BEFORE AN EMERGENCY – BECOME FAMILIAR WITH THIS GUIDEBOOK!

* For the purposes of this guidebook, the terms hazardous materials/dangerous good are synonymous.
First responders must be trained in the use of this guidebook.
Page 01
SAFETY PRECAUTIONS NOTIFICATION AND REQUEST FOR TECHNICAL INFORMATION
RESIST RUSHING IN!
Follow the steps outlined in your organization's standard operating procedures and/or
local emergency response plan for obtaining qualified assistance. Generally, the
APPROACH CAUTIOUSLY FROM UPWIND, UPHILL OR UPSTREAM:
notification sequence and requests for technical information beyond what is available
• Stay clear of Vapour, Fumes, Smoke and Spills
in this guidebook should occur in the following order:
• Keep vehicle at a safe distance from the scene
SECURE THE SCENE: 1. NOTIFY YOUR ORGANIZATION/AGENCY
• Isolate the area and protect yourself and others • Based on information provided, this will set in motion a series of events
• Actions may range from dispatching additional trained personnel to the scene,
IDENTIFY THE HAZARDS USING ANY OF THE FOLLOWING: to activating the local emergency response plan
• Placards • Ensure that local fire and police departments have been notified
• Container labels
• Shipping documents 2. CALL THE EMERGENCY RESPONSE TELEPHONE NUMBER ON THE SHIPPING
• Rail Car and Road Trailer Identification Chart DOCUMENT
• Material Safety Data Sheets (MSDS) • If shipping paper is not available, use guidance under next section “ASSISTANCE”
• Knowledge of persons on scene 3. ASSISTANCE
• Consult applicable guide page • Contact the appropriate emergency response agency listed on the inside back
ASSESS THE SITUATION: cover of this guidebook
• Is there a fire, a spill or a leak? • Provide as much information about the hazardous material and the nature of the
• What are the weather conditions? incident
• What is the terrain like? • The agency will provide immediate advice on handling the early stages of the
• Who/what is at risk: people, property or the environment? incident
• What actions should be taken – evacuation, shelter in-place or dike? • The agency will also contact the shipper or manufacturer of the material for
• What resources (human and equipment) are required? more detailed information if necessary
• What can be done immediately? • The agency will request on-scene assistance when necessary
OBTAIN HELP:
• Advise your headquarters to notify responsible agencies and call for 4. PROVIDE AS MUCH OF THE FOLLOWING INFORMATION AS POSSIBLE:
assistance from qualified personnel • Your name, call-back telephone number, FAX number
RESPOND: • Location and nature of problem (spill, fire, etc.)
• Enter only when wearing appropriate protective gear • Name and identification number of material(s) involved
• Rescue attempts and protecting property must be weighed against you • Shipper/consignee/point-of-origin
becoming part of the problem • Carrier name, rail car or truck number
• Establish a command post and lines of communication • Container type and size
• Continually reassess the situation and modify response accordingly • Quantity of material transported/released
• Consider safety of people in the immediate area first, including your own • Local conditions (weather, terrain)
safety • Proximity to schools, hospitals, waterways, etc.
ABOVE ALL: Do not assume that gases or vapours are harmless because of lack of a • Injuries and exposures
smell— odorless gases or vapours may be harmful. Use CAUTION when handling empty • Local emergency services that have been notified
containers because they may still present hazards until they are cleaned and purged of all
residues.
Page 02 Page 03
HAZARD CLASSIFICATION SYSTEM INTRODUCTION TO THE TABLE OF PLACARDS
The hazard class of dangerous goods is indicated either by its class (or division) number or name.
USE THE TABLE OF PLACARDS ONLY WHEN THE ID NUMBER OR PROPER SHIPPING
Placards are used to identify the class or division of a material. The hazard class or division
number must be displayed in the lower corner of a placard and is required for both primary and
NAME IS NOT AVAILABLE.
subsidiary hazard classes and divisions, if applicable. For other than Class 7 or the OXYGEN The next two pages display the placards used on transport vehicles carrying dangerous
placard, text indicating a hazard (for example, “CORROSIVE”) is not required. Text is shown only goods with the applicable reference GUIDE circled. Follow these steps:
in the U.S. The hazard class or division number and subsidiary hazard classes or division 1. Approach scene from upwind, uphill or upstream at a safe distance to safely
numbers placed in parentheses (when applicable), must appear on the shipping document after
identify and/or read the placard or orange panel. Use binoculars if available.
each proper shipping name.
2. Match the vehicle placard(s) with one of the placards displayed on the next two
Class 1- Explosives
pages.
Division 1.1 Explosives with a mass explosion hazard
Division 1.2 Explosives with a projection hazard 3. Consult the circled guide number associated with the placard. Use that guide
Division 1.3 Explosives with predominantly a fire hazard information for now. For example:
Division 1.4 Explosives with no significant blast hazard
Division 1.5 Very insensitive explosives with a mass explosion hazard • Use GUIDE 127 for a FLAMMABLE (Class 3) placard
Division 1.6 Extremely insensitive articles
Class 2- Gases • Use GUIDE 153 for a CORROSIVE (Class 8) placard
Division 2.1 Flammable gases
Division 2.2 Non-flammable, non-toxic* gases
Division 2.3 Toxic* gases • Use GUIDE 111 when the DANGER/DANGEROUS placard is displayed or the
Class 3- Flammable liquids (and Combustible liquids [U.S.]) nature of the spilled, leaking or burning material is not known. Also use this
Class 4- Flammable solids; Spontaneously combustible materials; and GUIDE when the presence of dangerous goods is suspected but no placards can
Dangerous when wet materials/Water-reactive substances be seen.
Division 4.1 Flammable solids If multiple placards point to more than one guide, initially use the most conservative
Division 4.2 Spontaneously combustible materials guide (i.e., the guide requiring the greatest degree of protective actions).
Division 4.3 Water-reactive substances/Dangerous when wet materials
4 Guides associated with the placards provide the most significant risk and/or
Class 5- Oxidizing substances and Organic peroxides hazard information.
Division 5.1 Oxidizing substances
5 When specific information, such as ID number or proper shipping name, becomes
Division5.2 Organic peroxides
available, the more specific Guide recommended for that material must be
Class 6- Toxic* substances and Infectious substances consulted.
Division 6.1 Toxic*substances
6 Asterisks (*) on orange placards represent explosives “Compatibility Group”
Division 6.2 Infectious substances
letters; refer to the Glossary (page 375).
Class 7 - Radioactive materials
7 Double asterisks (**) on orange placards represent the division of the explosive.
Class 8 - Corrosive substances
Class 9 - Miscellaneous hazardous materials/Products, Substances or Organisms
* The words “poison” or “poisonous” are synonymous with the word “toxic”
Page 04 Page 05
TABLE OF PLACARDS AND INITAL RESPONSE GUIDE TO USE ON-SCENE
USE THIS TABLE ONLY IF MATERIALS CANNOT BE SPECIFICALLY IDENTIFIED BY USING THE SHIPPING DOCUMENT, NUMBERED PLACARD, OR ORANGE PANEL NUMBER
Page 06 Page 07
EMERGENCY INFORMATION PANEL 800
In India, it is mandatory for the vehicles transporting hazardous chemicals to display Emergency Correct Technical Name (Class Labels)
Information Panel (EIP) with details and at places as specified under Rule 134 of the Central Motor (a)
135
Vehicles Rules, 1989 as shown in the next figure.
Every class label and emergency information panel (EIP) shall be marked on the goods carriage and
10 (c)
shall be kept free and clean from obstruction at all times. UN No.
One practical problem encountered with the use of EIP is the selection of the substance 120 (b)
15
identification number and the HAZCHEM code to be incorporated in the EIP when a tanker
transports different chemicals in different compartments. The solution in such case is to 5
HAZCHEM 600
incorporate the word "Multi-load" in the sections of EIP earmarked for "UN Number" and
"HAZCHEM" and to label each compartment separately with the UN number and HAZCHEM code 120 (Subsidiary
15 (e)
corresponding to the chemical in the compartment. Risk Labale)
10
The emergency information panel (EIP) should have dimensions as shown in the next figure. IN EMERGENCY DIAL SPECIALIST ADVICE
180
(d) (f)
30 15
800
10
10
380 390
Correct Technical Name (Class Label)
(a) 10 10 10
135
0
25
(Having Subsidiary hazard class label)

10
(e)
UN No. (All dimensions are expressed in millimeters)
120 (b)
15
5
HAZCHEM 600
120
15 (c)
PETROLEUM
10 PRODUCTS
IN EMERGENCY DIAL SPECIALIST ADVICE
1203
UN No.
FLAMMABLE
LIQUID
180
(d) (f)
3YE
HAZCHEM
30 15
10 IN EMERGENCY DIAL
Name
380 390 ooo, POLICE OR
Phone
FIRE BRIGADE
10 10 10
(Having only one UN hazard class label) (Sample Emergency Information Panel)
Page 08 Page 09
EMERGENCY ACTION CODES (EAC) ROAD TRAILER IDENTIFICATION CHART
The EAC provides information on:
• The fire extinguishing media to be used
• The level of PPE required
• Whether the spillage should be contained or may be diluted
• Whether there is a possibility of violent reaction
• Whether the substance poses a Public Safety Hazard
1 = Water Jet 2 = Fog 3 = Foam 4 = Dry Agent
P V
R Full
S V BA
S BA for FIRE only DILUTE
T BA
T BA for FIRE only
W V
X Full
Y V BA Every goods carriage used for transporting any dangerous or hazardous goods shall be legibly and
Y BA for FIRE only CONTAIN conspicuously marked with an emergency information panel in each of the three places as specified,
Z BA so that the emergency information panel faces to each side of the carriage and to its rear and such
panel shall contain the following information viz.,
Z BA for FIRE only · The correct technical name of the dangerous or hazardous goods in letters not less than 50 mm
high.
E CONSIDER EVACUATION · The United Nations class number for the dangerous goods in letters not less than 100 mm high (Rule
137).
K V Can be violently or even explosively reactive · The class label of the dangerous or hazardous goods in the size of not less than 250 mm square.
· The name and telephone number of the emergency services to be contacted in the event of fire or
E Full Full body protective clothing with B. A.
any other accident in letters and numerals that are not less than 50 mm high and the name and
Y BA Breathing apparatus plus protective gloves
telephone number of the consignor of the dangerous or hazardous goods or of some other person
DILUTE Spillages may be washed to drains with large quantities of water. from whom expert information and advice can be obtained concerning the measures that should
However, due care must be taken to avoid unnecessary pollution of be taken in the event of emergency.
watercourses.
CONTAIN Prevent the spillage from entering drains and watercourses using any CAUTION: This chart depicts only the most general shapes of road trailers. Emergency response
means available. personnel must be aware that there are many variations of road trailers, not illustrated above, that
DRY AGENT Water MUST NOT be allowed to come into contact with the substance. are used for shipping chemical products. The suggested guides are for the most hazardous products
E People should be warned to stay indoors with all doors and windows that may be transported in these trailer types.
closed but evacuation may need to be considered. Consult Control,
Police and product expert.
FOG In the absence of fog equipment a fire spray may be used.
Page 10 Page 11
HAZARD IDENTIFICATION NUMBERS HAZARD IDENTIFICATION NUMBERS
DISPLAYED ON SOME INTERMODAL CONTAINERS DISPLAYED ON SOME INTERMODAL CONTAINERS
Hazard identification numbers utilized under European and some South American regulations, The hazard identification numbers listed below have the following meanings:
may be found in the top half of an orange panel on some intermodal bulk containers. The United
Nations 4-digit identification number is in the bottom half of the orange panel. 20 Asphyxiant gas
22 Refrigerated liquefied gas, asphyxiant
223 Refrigerated liquefied gas, flammable
225 Refrigerated liquefied gas, oxidizing (fire-intensifying)
33 23
239
Flammable gas
Flammable gas which can spontaneously lead to violent reaction
1203 25
26
263
Oxidizing (fire-intensifying) gas
Toxic gas
Toxic gas, flammable
265 Toxic gas, oxidizing (fire-intensifying)
The hazard identification number in the top half of the orange panel consists of two or three 268 Toxic gas, corrosive
digits. In general, the digits indicate the following hazards: 30 Flammable liquid, or flammable liquid or solid in the molten state with a flash point
2 -Emission of gas due to pressure or chemical reaction above 60oC, heated to a temperature equal to or above its flash point, or self-heating
liquid
3 -Flammability of liquids (VAPOURS) and gases or self-heating liquid
323 Flammable liquid which reacts with water, emitting flammable gas
4 -Flammability of solids or self-heating solid X323 Flammable liquid which reacts dangerously with water, emitting flammable gas
5 -Oxidizing (fire-intensifying) effect 33 Highly flammable liquid
6 -Toxicity or risk of infection 333 Pyrophoric liquid
X333 Pyrophoric liquid which reacts dangerously with water
7 -Radioactivity 336 Highly flammable liquid, toxic
8 -Corrosivity 338 Highly flammable liquid, corrosive
9 -Risk of spontaneous violent reaction X338 Highly flammable liquid, corrosive, which reacts dangerously with water
339 Highly flammable liquid which can spontaneously lead to violent reaction
NOTE: The risk of spontaneous violent reaction within the meaning of digit 9 include the 36 Flammable liquid, toxic, or self-heating liquid, toxic
possibility, due to the nature of a substance, of a risk of explosion, disintegration 362 Flammable liquid, toxic, which reacts with water, emitting flammable gas
and polymerization reaction followed by the release of considerable heat or X362 Flammable liquid, toxic, which reacts dangerously with water, emitting flammable gas
flammable and/or toxic gases. 368 Flammable liquid, toxic, corrosive
38 Flammable liquid, corrosive or self-heating liquid, corrosive
382 Flammable liquid, corrosive, which reacts with water, emitting flammable gas
• Doubling of a digit indicates an intensification of that particular hazard (i.e., 33, 66,
X382 Flammable liquid, corrosive, which reacts dangerously with water, emitting flammable
88).
gas
• Where the hazard associated with a substance can be adequately indicated by a single 39 Flammable liquid which can spontaneously lead to violent reaction
digit, the digit is followed by a zero (i.e., 30, 40, 50).
40 Flammable solid, or self-reactive substance, or self-heating substance
• A hazard identification number prefixed by the letter “X” indicates that the substance 423 Solid which reacts with water, emitting flammable gas, or flammable solid which reacts
will react dangerously with water (i.e., X88). with water, emitting flammable gas, or self-heating solid which reacts with water,
emitting flammable gas
Page 12 Page 13
HAZARD IDENTIFICATION NUMBERS HAZARD IDENTIFICATION NUMBERS
DISPLAYED ON SOME INTERMODAL CONTAINERS DISPLAYED ON SOME INTERMODAL CONTAINERS
X423 Solid which reacts dangerously with water, emitting flammable gas, or flammable 665 Highly toxic substance, oxidizing (fire-intensifying)
solid which reacts dangerously with water, emitting flammable gas, or self-heating 668 Highly toxic substance, corrosive
solid which reacts dangerously with water, emitting flammable gas X668 Highly toxic substance, corrosive, which reacts dangerously with water
43 Spontaneously flammable (pyrophoric) solid 669 Highly toxic substance which can spontaneously lead to violent reaction
X432 Spontaneously flammable (pyrophoric) solid which reacts dangerously with water, 68 Toxic substance, corrosive
emitting flammable gas 69 Toxic substance which can spontaneously lead to violent reaction
44 Flammable solid, in the molten state at an elevated temperature 70 Radioactive material
446 Flammable solid, toxic, in the molten state at an elevated temperature 78 Radioactive material, corrosive
46 Flammable solid, toxic, or self-heating solid, toxic
462 Toxic solid which reacts with water, emitting flammable gas 80 Corrosive substance
X462 Solid which reacts dangerously with water, emitting toxic gas X80 Corrosive substance which reacts dangerously with water
48 Flammable or self-heating solid, corrosive 823 Corrosive liquid which reacts with water, emitting flammable gas
482 Corrosive solid which reacts with water, emitting flammable gas 83 Corrosive substance, flammable
X482 Solid which reacts dangerously with water, emitting corrosive gas X83 Corrosive substance, flammable, which reacts dangerously with water
839 Corrosive substance, flammable, which can spontaneously lead to violent reaction
50 Oxidizing (fire-intensifying) substance X839 Corrosive substance, flammable, which can spontaneously lead to violent reaction and
539 Flammable organic peroxide which reacts dangerously with water
55 Strongly oxidizing (fire-intensifying) substance 84 Corrosive solid, flammable or self-heating
556 Strongly oxidizing (fire-intensifying) substance, toxic 842 Corrosive solid which reacts with water, emitting flammable gas
558 Strongly oxidizing (fire-intensifying) substance, corrosive 85 Corrosive substance, oxidizing (fire-intensifying)
559 Strongly oxidizing (fire-intensifying) substance which can spontaneously lead to 856 Corrosive substance, oxidizing (fire-intensifying) and toxic
violent reaction 86 Corrosive substance, toxic
56 Oxidizing (fire-intensifying) substance, toxic 88 Highly corrosive substance
568 Oxidizing (fire-intensifying) substance, toxic, corrosive X88 Highly corrosive substance which reacts dangerously with water
58 Oxidizing (fire-intensifying) substance, corrosive 883 Highly corrosive substance, flammable
59 Oxidizing (fire intensifying) substance which can spontaneously lead to violent 884 Highly corrosive solid, flammable or self-heating
reaction 885 Highly corrosive substance, oxidizing (fire-intensifying)
60 Toxic substa.nce 886 Highly corrosive substance, toxic
606 Infectious substance X886 Highly corrosive substance, toxic, which reacts dangerously with water
623 Toxic liquid which reacts with water, emitting flammable gas 89 Corrosive substance which can spontaneously lead to violent reaction
63 Toxic substance, flammable 90 Miscellaneous dangerous substance; environmentally hazardous substance
638 Toxic substance, flammable, corrosive 99 Miscellaneous dangerous substance transported at an elevated temperature
639 Toxic substance, flammable, which can spontaneously lead to violent reaction
64 Toxic solid, flammable or self-heating
642 Toxic solid which reacts with water, emitting flammable gas
65 Toxic substance, oxidizing (fire-intensifying)
66 Highly toxic substance
663 Highly toxic substance, flammable
664 Highly toxic solid, flammable or self-heating
Page 14 Page 15
PIPELINE TRANSPORTATION Markers – Often appear at road, railroad, and
water crossings. Signs may be posted at
In Gujarat, hazardous materials are transported through thousands of Kilometers of
property boundaries. Signs include
underground pipelines and related structures that can contain crude oil, natural gas, other operator's POC and product transported.
refinery products and other commodities. Although pipelines are buried, there are above- Warning, Caution, or Danger will appear
ground structures and signs indicating the presence of underground transmission pipelines (see on signs.
page 19 for Gujarat pipeline location information). Note: Pipelines transporting natural gas
containing dangerous levels of H2S may
have signs that say: “Sour Gas” or “Poison
Gas Pipelines Gas”.
Natural Gas Transmission Pipelines

Large-diameter, steel pipelines transporting For Natural Gas Pipeline Incidents
flammable, toxic and non-toxic natural gas at very
high pressure. Two important things to remember:
Structures: Compressor Station Buildings, Valves, • Never attempt to extinguish a gas fire; this could prolong/worsen incident/cause
Metering Stations, and Aerial Patrol Markers. another leak in the pipeline.
Markers: “Warning, Caution, or Danger” appear
• Never attempt to operate pipeline valves; this could prolong/worsen
at road, railroad, and water crossings, or may be
posted at property boundaries and include incident/cause another leak in the pipeline.
operator's emergency Point-of-Contact (POC)
and product transported. SIGNS OF GAS PIPELINE RUPTURE:
Natural Gas Distribution Pipelines • Loud roaring or explosive sound; OR
Natural gas is delivered directly to customers via distribution pipelines--typically smaller- • Large flames and loud roaring noise.
diameter, lower-pressure pipelines, and can be steel, plastic, or cast iron.
Structures: Regulator stations, customer meters and regulators, and valve box covers are Follow these steps:
the only above-ground indicators of gas distribution pipelines.
• Immediately evacuate area;
Gas Gathering and Gas Well Production Pipelines • Move upwind, away from flames; prevent individuals from entering;
Gas gathering/gas well production pipelines collect “raw” natural gas from wellheads and • If no flames present, do not start/turn off vehicles/electrical equipment (ex: cell
transport product to gas-processing and/or gas-treating plants. These gathering pipelines phones, pagers, two-way radios, or lights) as this could cause spark/ignition;
carry natural gas mixed with some level of gas liquids, water and, in some areas,
• Abandon equipment used in/near area;
contaminants such as hydrogen sulfide (H2S).
Structures: Compressor Station Buildings, Valves, Metering Stations, and Aerial Patrol
• If flames present, driving away from area is acceptable;
Markers. • Move far enough from noise to allow normal conversation;
• From safe location, call 108 or contact the local fire/law enforcement; and
• Notify pipeline operator.
Page 16 Page 17
ANY ONE OF THESE COULD INDICATE A SUSPECTED GAS PIPELINE LEAK: Liquids Pipelines
• Whistling/hissing sound;
• Distinctive, strong odor, similar to rotten eggs; Petroleum and Hazardous Liquids Pipelines
• Dense fog, mist, or white cloud; Crude oil, refined petroleum products, and
• Bubbling in water, ponds, or creeks; hazardous liquids often are transported by
• Dust or dirt blowing up from ground; OR pipelines and include gasoline, jet fuels,
• Discolored/dead vegetation above pipeline right-of-way. diesel fuel, home heating oils, carbon dioxide
and anhydrous ammonia. Sometimes liquids
pipelines transport natural gas liquids, which,
Follow these steps: like carbon dioxide and anhydrous ammonia,
• Evacuate area to where you can no longer hear, see, or smell gas; rapidly change from liquid to gaseous state
• Do not start/turn off vehicles/electrical equipment (ex: cell phones, pagers, two- when released from a pressurized pipeline.
way radios or lights) as this could cause spark/ignition; Structures – Storage Tanks, Valves, Pump
• Abandon equipment used in/near the area; Stations, Aerial Patrol Markers
• Avoid open flames; Markers – Often appear at road, railroad and water crossings, and may be posted at
• Prevent individuals from entering area; property boundaries. Signs include operator emergency POCs and product transported.
Warning, Caution, or Danger appear on signs
• Call 108 or contact the local fire/law enforcement from a safe location; and
For Petroleum and Hazardous Liquids Pipeline Incidents
Considerations for Establishing Protective Action Distance: Two important things to remember:
• Type of product (eg. sour vs sweet); • Never attempt to extinguish flame before shutting off supply, as this can cause
• Pressure and diameter of pipe; formation of explosive mixtures, and
• Timing of valve closure by utility (quickly for automated valves/longer for • Never attempt to operate pipeline valves. This could prolong/worsen incident–or
manually operated valves); cause another pipeline leak.
• Dissipation time of gas in pipe once valves are closed; SIGNS OF LIQUIDS PIPELINE RUPTURE:
• Heat factor of natural gas; • Loud roaring, hissing, or explosive sound; OR
• Local variables such as climate/weather, wind direction, topography, population • Very large flames and loud roaring noise.
density, demographics, and fire suppression methods available;
Follow these steps:
• Nearby building construction material/density;
• Immediately evacuate area;
• Wild land/urban interface; and
• Move upwind, far from flames, prevent individuals from entering area;
• Natural and manmade barriers (highway).
• If no flames present, do not start/turn off vehicles/electrical equipment (ex: cell
If you know the material involved, identify the three-digit guide number by looking phones, pagers, two-way radios, or lights) as this could cause spark/ignition;
up the name in the alphabetical list (blue-bordered pages), then using the three-digit • Abandon equipment used in/near the area;
guide number, consult the recommendations in the assigned guide. • Keep traffic away; secure the area;
Page 18 Page 19
• If flames present, driving away from area is acceptable; • Nearby building construction material/density;
• Move far enough away from noise to allow normal conversation; • Wild land/urban interface; and
• From safe location, call 108 or contact the local fire/law enforcement; and • Natural and man-made barriers (highway).
• From a safe area, call toll-free emergency number on right-of-way marker to
notify pipeline operator. If you know the material involved, identify the three-digit guide number by looking up
the name in the alphabetical list (blue-bordered pages), then using the three-digit guide
ANY ONE OF THESE COULD INDICATE SUSPECTED LIQUIDS PIPELINE LEAK: number, consult the recommendations in the assigned guide.
• Liquids bubbling up from ground;
• “Oil slick” on flowing/standing water;
Gujarat Pipeline Location
• Flames appearing from ground;
• VAPOUR clouds; A Geo-Spatial Database prepared with data collated from all pipeline operators (private
and public sector) in digital format. It shows all principal pipelines carrying Crude Oil,
• Discolored vegetation or snow; and
Natural Gas and refinery products categorized by Company in different districts of
• Unusual petroleum, skunk or rotten-egg odor. Gujarat. Emergency Responders / Companies can access the database during fire /
other accidents (such as oil spillage) and respond effectively to ensure that it does not
Follow these steps: spread to nearby pipelines. Oil and Gas pipeline network link is available on GSDMA's
• Do not drive into VAPOUR cloud; Web Site: http://gsdma.org/
• Carefully evacuate the immediate area so you can no longer hear, see, smell odor;
• Avoid introducing sources of ignition--do not start/turn off vehicles/electrical
equipment (ex: cell phones, pagers, two-way radios, or lights); as this could cause
spark/ignition;
• Abandon equipment being used in/near area;
• Avoid open flames;
• Prevent individuals from entering area;
• Call 108 or contact the local fire/law enforcement from a safe location; and
Considerations For Establishing Protective Action Distance:

• Type of product (eg. sour vs sweet);
• Pressure/diameter of pipe;
• Timing of valve closure by utility (quickly for automated valves/longer for
manually operated valves);
• Dissipation time of material in pipe once valves closed;
• Heat factor of product;
• Local variables such as climate/weather, wind direction, topography, population
density, demographics and fire suppression methods available for use;
Page 20 Page 21
ID Guid Name of Material ID Guid Name of Material
No. No. No. No.
GREEN HIGHLIGHTED ENTRIES IN YELLOW PAGES —— 112 Ammonium nitrate-fuel oil 1014 122 Oxygen and Carbon dioxide
mixtures mixture, compressed
—— 158 Biological agents 1015 126 Carbon dioxide and Nitrous
For entries highlighted in green follow these steps: —— 112 Blasting agent, n.o.s. oxide mixture
—— 112 Explosives, division 1.1, 1.2, 1015 126 Nitrous oxide and Carbon
• IF THERE IS NO FIRE: dioxide mixture
1.3 or 1.5
-- Go directly to Table 1 (green bordered pages) —— 114 Explosives, division 1.4 or 1.6 1016 119 Carbon monoxide
—— 153 Toxins 1016 119 Carbon monoxide,
– Look up the ID number and name of material compressed
1001 116 Acetylene
-- Identify initial isolation and protective action distances 1017 124 Chlorine
1001 116 Acetylene, dissolved
• IF THERE IS A FIRE or A FIRE IS INVOLVED: 1018 126 Chlorodifluoromethane
1002 122 Air, compressed
1018 126 Refrigerant gas R-22
-- Also consult the assigned orange guide 1003 122 Air, refrigerated liquid
(cryogenic liquid) 1020 126 Chloropentafluoroethane
– If applicable, apply the evacuation information shown under 1003 122 Air, refrigerated liquid 1020 126 Refrigerant gas R-115
PUBLIC SAFETY (cryogenic liquid), non - 1021 126 1-Chloro-1,2,2,2

pressurized tetrafluoroethane
Note: If the name in Table 1 is shown with “When Spilled In Water”, these
materials produce large amounts of Toxic Inhalation Hazard (TIH) gases 1005 125 Ammonia, anhydrous 1021 126 Chlorotetrafluoroethane
when spilled in water. Some Water Reactive materials are also TIH 1005 125 Anhydrous ammonia 1021 126 Refrigerant gas R-124
materials themselves (e.g., Bromine trifluoride (1746), Thionyl chloride 1006 121 Argon 1022 126 Chlorotrifluoromethane
(1836), etc.). In these instances, two entries are provided in Table 1 for 1006 121 Argon, compressed 1022 126 Refrigerant gas R-13
land-based and water-based spills. If the Water Reactive material is NOT a 1008 125 Boron trifluoride 1023 119 Coal gas
TIH and this material is NOT spilled in water, Table 1 and Table 2 do not 1008 125 Boron trifluoride, compressed 1023 119 Coal gas, compressed
apply and safety distances will be found within the appropriate orange
1009 126 Bromotrifluoromethane 1026 119 Cyanogen
guide.
1009 126 Refrigerant gas R-13B1 1026 119 Cyanogen gas
1010 116P Butadienes, stabilized 1027 115 Cyclopropane
1010 116P Butadienes and hydrocarbon 1028 126 Dichlorodifluoromethane
mixture, stabilized 1028 126 Refrigerant gas R-12
1011 115 Butane 1029 126 Dichlorofluoromethane
1011 115 Butane mixture 1029 126 Refrigerant gas R-21
1012 115 Butylene 1030 115 1,1-Difluoroethane
1013 120 Carbon dioxide 1030 115 Difluoroethane
1013 120 Carbon dioxide, compressed 1030 115 Refrigerant gas R-152a
1014 122 Carbon dioxide and Oxygen 1032 118 Dimethylamine, anhydrous
mixture, compressed
1033 115 Dimethyl ether
Page 22 Page 23
ID Guid Name of Material ID Guid Name of Material ID Guid Name of Material ID Guid Name of Material
No. No. No. No. No. No. No. No.
1035 115 Ethane 1050 125 Hydrogen chloride, anhydrous 1066 121 Nitrogen, compressed 1079 125 Sulfur dioxide
1035 115 Ethane, compressed 1051 117 AC 1067 124 Dinitrogen tetroxide 1079 125 Sulphur dioxide
1036 118 Ethylamine 1051 117 Hydrocyanic acid, aqueous 1067 124 Nitrogen dioxide 1080 126 Sulfur hexafluoride
1037 115 Ethyl chloride solutions, with more than
20% Hydrogen cyanide 1069 125 Nitrosyl chloride 1080 126 Sulphur hexafluoride
1038 115 Ethylene, refrigerated liquid
(cryogenic liquid) 1051 117 Hydrogen cyanide, anhydrous, 1070 122 Nitrous oxide 1081 116P Tetrafluoroethylene, stabilized
1039 115 Ethyl methyl ether stabilized 1070 122 Nitrous oxide, compressed 1082 119P Trifluorochloroethylene,
1051 117 Hydrogen cyanide, stabilized 1071 119 Oil gas stabilized
1039 115 Methyl ethyl ether
1040 119P Ethylene oxide 1052 125 Hydrogen fluoride, anhydrous 1083 118 Trimethylamine, anhydrous
1071 119 Oil gas, compressed
1040 119P Ethylene oxide with Nitrogen 1053 117 Hydrogen sulfide 1085 116P Vinyl bromide, stabilized
1072 122 Oxygen
1041 115 Carbon dioxide and Ethylene 1053 117 Hydrogen sulphide 1086 116P Vinyl chloride, stabilized
1072 122 Oxygen, compressed
oxide mixture, with more 1055 115 Isobutylene
1073 122 Oxygen, refrigerated liquid 1087 116P Vinyl methyl ether, stabilized
than 9% but not more than 1056 121 Krypton
87% Ethylene oxide (cryogenic liquid) 1088 127 Acetal
1056 121 Krypton, compressed
1041 115 Carbon dioxide and Ethylene 1057 115 Lighter refills (cigarettes) 1075 115 Butane 1089 129 Acetaldehyde
oxide mixtures, with more (flammable gas) 1075 115 Butane mixture 1090 127 Acetone
than 6% Ethylene oxide 1057 115 Lighters (cigarettes) 1075 115 Butylene 1091 127 Acetone oils
1041 115 Ethylene oxide and Carbon (flammable gas)
dioxide mixture, with more 1075 115 Isobutane 1092 131P Acrolein, stabilized
1058 120 Liquefied gases,
than 9% but not more than nonflammable,charged 1075 115 Isobutane mixture 1093 131P Acrylonitrile, stabilized
87% Ethylene oxide withNitrogen, Carbon dioxide 1075 115 Isobutylene 1098 131 Allyl alcohol
1041 115 Ethylene oxide and Carbon or Air 1075 115 Liquefied petroleum gas 1099 131 Allyl bromide
dioxide mixtures, with more 1060 116P Methylacetylene and
than 6 % Ethylene oxide 1075 115 LPG 1100 131 Allyl chloride
Propadiene mixture, stabilized
1043 125 Fertilizer, ammoniating 1060 116P Propadiene and 1075 115 Petroleum gases, liquefied 1104 129 Amyl acetates
solution, with free Ammonia Methylacetylene mixture, 1075 115 Propane 1105 129 Amyl alcohols
1044 126 Fire extinguishers with stabilized 1075 115 Propane mixture 1105 129 Pentanols
compressed gas 1061 118 Methylamine, anhydrous
1044 126 Fire extinguishers with 1075 115 Propylene 1106 132 Amylamines
1062 123 Methyl bromide
liquefied gas 1076 125 CG 1107 129 Amyl chloride
1063 115 Methyl chloride
1045 124 Fluorine 1076 125 Diphosgene 1108 128 n-Amylene
1063 115 Refrigerant gas R-40
1045 124 Fluorine, compressed 1076 125 DP 1108 128 1-Pentene
1064 117 Methyl mercaptan
1046 121 Helium
1065 121 Neon 1076 125 Phosgene 1109 129 Amyl formates
1046 121 Helium, compressed
1065 121 Neon, compressed 1077 115 Propylene 1110 127 n-Amyl methyl ketone
1048 125 Hydrogen bromide, anhydrous
1066 121 Nitrogen 1078 126 Dispersant gas, n.o.s. 1110 127 Amyl methyl ketone
1049 115 Hydrogen
1049 115 Hydrogen, compressed 1078 126 Refrigerant gas, n.o.s. 1110 127 Methyl amyl ketone
Page 24 Page 25
1111 130 Amyl mercaptan 1150 130P 1,2-Dichloroethylene 1173 129 Ethyl acetate 1199 132P Furfural
1112 140 Amyl nitrate 1150 130P Dichloroethylene 1175 130 Ethylbenzene 1199 132P Furfuraldehydes
1113 129 Amyl nitrite 1152 130 Dichloropentanes 1176 129 Ethyl borate 1201 127 Fusel oil
1114 130 Benzene 1153 127 Ethylene glycol diethyl ether 1177 130 2-Ethylbutyl acetate 1202 128 Diesel fuel
1120 129 Butanols 1154 132 Diethylamine 1177 130 Ethylbutyl acetate 1202 128 Fuel oil
1123 129 Butyl acetates 1155 127 Diethyl ether 1178 130 2-Ethylbutyraldehyde 1202 128 Fuel oil, no. 1,2,4,5,6
1125 132 n-Butylamine 1155 127 Ethyl ether 1179 127 Ethyl butyl ether 1202 128 Gas oil
1126 130 1-Bromobutane 1156 127 Diethyl ketone 1180 130 Ethyl butyrate 1202 128 Heating oil, light
1126 130 n-Butyl bromide 1157 128 Diisobutyl ketone 1181 155 Ethyl chloroacetate 1203 128 Gasohol
1127 130 Butyl chloride 1158 132 Diisopropylamine 1182 155 Ethyl chloroformate 1203 128 Gasoline
1127 130 Chlorobutanes 1159 127 Diisopropyl ether 1183 139 Ethyldichlorosilane 1203 128 Motor spirit
1128 129 n-Butyl formate 1160 132 Dimethylamine, aqueous 1184 131 Ethylene dichloride 1203 128 Petrol
1129 129 Butyraldehyde solution 1185 131P Ethyleneimine, stabilized 1204 127 Nitroglycerin, solution in
1160 132 Dimethylamine, solution 1188 127 Ethylene glycol monomethyl alcohol, with not more than
1130 128 Camphor oil 1% Nitroglycerin
1161 129 Dimethyl carbonate ether
1131 131 Carbon bisulfide 1206 128 Heptanes
1189 129 Ethylene glycol monomethyl
1131 131 Carbon bisulphide 1162 155 Dimethyldichlorosilane
ether acetate 1207 130 Hexaldehyde
1131 131 Carbon disulfide 1163 131 1,1-Dimethylhydrazine
1190 129 Ethyl formate 1208 128 Hexanes
1131 131 Carbon disulphide 1163 131 Dimethylhydrazine,
1191 129 Ethylhexaldehydes 1208 128 Neohexane
unsymmetrical
1133 128 Adhesives (flammable) 1191 129 Octyl aldehydes 1210 129 Ink, printer’s, flammable
1164 130 Dimethyl sulfide
1134 130 Chlorobenzene 1192 129 Ethyl lactate 1210 129 Printing ink, flammable
1164 130 Dimethyl sulphide
1135 131 Ethylene chlorohydrin 1193 127 Ethyl methyl ketone 1210 129 Printing ink related material
1165 127 Dioxane
1136 128 Coal tar distillates, flammable 1193 127 Methyl ethyl ketone 1212 129 Isobutanol
1166 127 Dioxolane
1139 127 Coating solution 1194 131 Ethyl nitrite, solution 1212 129 Isobutyl alcohol
1167 128P Divinyl ether, stabilized
1143 131P Crotonaldehyde 1195 129 Ethyl propionate 1213 129 Isobutyl acetate
1169 127 Extracts, aromatic, liquid
1143 131P Crotonaldehyde, stabilized 1196 155 Ethyltrichlorosilane 1214 132 Isobutylamine
1170 127 Ethanol
1144 128 Crotonylene 1197 127 Extracts, flavoring, liquid 1216 128 Isooctenes
1170 127 Ethanol, solution
1145 128 Cyclohexane 1197 127 Extracts, flavouring, liquid 1218 130P Isoprene, stabilized
1170 127 Ethyl alcohol
1146 128 Cyclopentane 1198 132 Formaldehyde, solution, 1219 129 Isopropanol
1170 127 Ethyl alcohol, solution flammable
1147 130 Decahydronaphthalene 1219 129 Isopropyl alcohol
1171 127 Ethylene glycol monoethyl 1198 132 Formaldehyde, solutions
1148 129 Diacetone alcohol 1220 129 Isopropyl acetate
ether (Formalin)
1149 128 Butyl ethers 1221 132 Isopropylamine
1172 129 Ethylene glycol monoethyl 1199 132P Furaldehydes
1149 128 Dibutyl ethers ether acetate 1222 130 Isopropyl nitrate
Page 26 Page 27
1223 128 Kerosene 1262 128 Isooctane 1287 127 Rubber solution 1318 133 Cobalt resinate, precipitated
1224 127 Ketones, liquid, n.o.s. 1262 128 Octanes 1288 128 Shale oil 1320 113 Dinitrophenol, wetted with
1228 131 Mercaptan mixture, liquid, 1263 128 Paint (flammable) 1289 132 Sodium methylate, solution in not less than 15% water
flammable, poisonous, n.o.s. 1263 128 Paint related material alcohol 1321 113 Dinitrophenolates, wetted
1228 131 Mercaptan mixture, liquid, (flammable) 1292 129 Ethyl silicate with not less than 15% water
flammable, toxic, n.o.s. 1264 129 Paraldehyde 1292 129 Tetraethyl silicate 1322 113 Dinitroresorcinol, wetted with
1228 131 Mercaptans, liquid, not less than 15% water
1265 128 Isopentane 1293 127 Tinctures, medicinal
flammable, poisonous, n.o.s. 1323 170 Ferrocerium
1265 128 n-Pentane 1294 130 Toluene
1228 131 Mercaptans, liquid, 1324 133 Films, nitrocellulose base
1265 128 Pentanes 1295 139 Trichlorosilane
flammable, toxic, n.o.s. 1325 133 Flammable solid, n.o.s.
1266 127 Perfumery products, with 1296 132 Triethylamine
1229 129 Mesityl oxide 1325 133 Flammable solid, organic, n.o.s.
flammable solvents 1297 132 Trimethylamine, aqueous
1230 131 Methanol solution 1325 133 Fusee (rail or highway)
1267 128 Petroleum crude oil
1230 131 Methyl alcohol 1298 155 Trimethylchlorosilane 1326 170 Hafnium powder, wetted with
1268 128 Petroleum distillates, n.o.s.
1231 129 Methyl acetate not less than 25% water
1268 128 Petroleum products, n.o.s. 1299 128 Turpentine
1233 130 Methylamyl acetate 1327 133 Bhusa, wet, damp or
1270 128 Oil, petroleum 1300 128 Turpentine substitute
1234 127 Methylal contaminated with oil
1270 128 Petroleum oil 1301 129P Vinyl acetate, stabilized
1235 132 Methylamine, aqueous 1327 133 Hay, wet, damp or
1272 129 Pine oil 1302 127P Vinyl ethyl ether, stabilized contaminated with oil
solution
1274 129 n-Propanol 1303 130P Vinylidene chloride, stabilized 1327 133 Straw, wet, damp or
1237 129 Methyl butyrate
1274 129 normal Propyl alcohol 1304 127P Vinyl isobutyl ether, stabilized contaminated with oil
1238 155 Methyl chloroformate
1274 129 Propyl alcohol, normal 1305 155P Vinyltrichlorosilane 1328 133 Hexamethylenetetramine
1239 131 Methyl chloromethyl ether
1275 129 Propionaldehyde 1305 155P Vinyltrichlorosilane, stabilized 1328 133 Hexamine
1242 139 Methyldichlorosilane
1276 129 n-Propyl acetate 1306 129 Wood preservatives, liquid 1330 133 Manganese resinate
1243 129 Methyl formate
1277 132 Monopropylamine 1307 130 Xylenes 1331 133 Matches, “strike anywhere”
1244 131 Methylhydrazine
1277 132 Propylamine 1308 170 Zirconium metal, liquid 1332 133 Metaldehyde
1245 127 Methyl isobutyl ketone suspension
1278 129 1-Chloropropane 1333 170 Cerium, slabs, ingots or rods
1246 127P Methyl isopropenyl ketone, 1308 170 Zirconium suspended in a
1278 129 Propyl chloride 1334 133 Naphthalene, crude
stabilized flammable liquid
1279 130 1,2-Dichloropropane 1334 133 Naphthalene, refined
1247 129P Methyl methacrylate 1308 170 Zirconium suspended in a
monomer, stabilized 1279 130 Dichloropropane 1336 113 Nitroguanidine (Picrite), wetted
liquid (flammable)
1279 130 Propylene dichloride with not less than 20% water
1248 129 Methyl propionate 1309 170 Aluminum powder, coated
1280 127P Propylene oxide 1336 113 Nitroguanidine, wetted with
1249 127 Methyl propyl ketone 1310 113 Ammonium picrate, wetted not less than 20% water
1250 155 Methyltrichlorosilane 1281 129 Propyl formates with not less than 10% water
1336 113 Picrite, wetted
1251 131P Methyl vinyl ketone, stabilized 1282 129 Pyridine 1312 133 Borneol
1337 113 Nitrostarch, wetted with not
1259 131 Nickel carbonyl 1286 127 Rosin oil 1313 133 Calcium resinate less than 20% water
1261 129 Nitromethane 1314 133 Calcium resinate, fused
Page 28 Page 29
1337 113 Nitrostarch, wetted with not less 1348 113 Sodium dinitro-o-cresolate, 1364 133 Cotton waste, oily 1382 135 Potassium sulfide, anhydrous
than 30% solvent wetted with not less than 15% 1365 133 Cotton 1382 135 Potassium sulfide, with less
1338 133 Phosphorus, amorphous water than 30% water of
1365 133 Cotton, wet
1338 133 Phosphorus, amorphous, red 1348 113 Sodium dinitro-ortho-cresolate, crystallization
wetted 1366 135 Diethylzinc
1338 133 Red phosphorus 1382 135 Potassium sulfide, with less
1349 113 Sodium picramate, wetted with 1369 135 p-Nitrosodimethylaniline
1338 133 Red phosphorus, amorphous than 30% water of hydration
not less than 20% water 1370 135 Dimethylzinc
1339 139 Phosphorus heptasulfide, free 1382 135 Potassium sulphide, anhydrous
from yellow and white 1350 133 Sulfur 1372 133 Fiber, animal or vegetable,
1382 135 Potassium sulphide, with less
Phosphorus 1350 133 Sulphur n.o.s., burnt, wet or damp
than 30% water of
1339 139 Phosphorus heptasulphide, free 1352 170 Titanium powder, wetted with 1372 133 Fibers, animal or vegetable, crystallization
from yellow and white not less than 25% water burnt, wet or damp
1382 135 Potassium sulphide, with less
Phosphorus 1353 133 Fabrics impregnated with weakly 1372 133 Fibres, animal or vegetable, than 30% water of hydration
1340 139 Phosphorus pentasulfide, free nitrated Nitrocellulose, n.o.s. burnt, wet or damp
1383 135 Aluminum powder,
from yellow and white 1353 133 Fibers impregnated with weakly 1373 133 Fabrics, animal or vegetable pyrophoric
Phosphorus nitrated Nitrocellulose, n.o.s. or synthetic, n.o.s. with oil
1383 135 Pyrophoric alloy, n.o.s.
1340 139 Phosphorus pentasulphide, free 1353 133 Fibres impregnated with weakly 1373 133 Fibers, animal or vegetable or
from yellow and white nitrated Nitrocellulose, n.o.s. 1383 135 Pyrophoric metal, n.o.s.
synthetic, n.o.s. with oil
Phosphorus 1353 133 Toe puffs, nitrocellulose base 1384 135 Sodium dithionite
1373 133 Fibres, animal or vegetable or
1341 139 Phosphorus sesquisulfide, free 1354 113 Trinitrobenzene, wetted with synthetic, n.o.s. with oil 1384 135 Sodium hydrosulfite
from yellow and white not less than 30% water 1384 135 Sodium hydrosulphite
1374 133 Fish meal, unstabilized
Phosphorus 1355 113 Trinitrobenzoic acid, wetted with
1374 133 Fish scrap, unstabilized 1385 135 Sodium sulfide, anhydrous
1341 139 Phosphorus sesquisulphide, free not less than 30% water
from yellow and white 1376 135 Iron oxide, spent 1385 135 Sodium sulfide, with less than
1356 113 TNT, wetted with not less than 30% water of crystallization
Phosphorus 30% water 1376 135 Iron sponge, spent
1343 139 Phosphorus trisulfide, free from 1385 135 Sodium sulphide, anhydrous
1356 113 Trinitrotoluene, wetted with not 1378 170 Metal catalyst, wetted
yellow and white Phosphorus less than 30% water 1385 135 Sodium sulphide, with less
1379 133 Paper, unsaturated oil treated
1343 139 Phosphorus trisulphide, free than 30% water of
1357 113 Urea nitrate, wetted with not 1380 135 Pentaborane
from yellow and white crystallization
less than 20% water
Phosphorus 1381 136 Phosphorus, white, dry or 1386 135 Seed cake, with more than
1358 170 Zirconium metal, powder, wet under water or in solution
1344 113 Picric acid, wetted with not less 1.5% oil and not more than
1358 170 Zirconium powder, wetted with 1381 136 Phosphorus, yellow, dry or 11% moisture
than 30% water
not less than 25% water under water or in solution
1344 113 Trinitrophenol, wetted with not 1387 133 Wool waste, wet
1360 139 Calcium phosphide
less than 30% water 1381 136 White phosphorus, dry 1389 138 Alkali metal amalgam
1361 133 Carbon, animal or vegetable
1345 133 Rubber scrap, powdered or 1381 136 White phosphorus, in solution 1389 138 Alkali metal amalgam, liquid
origin
granulated 1381 136 White phosphorus, under
1361 133 Charcoal 1389 138 Alkali metal amalgam, solid
1345 133 Rubber shoddy, powdered or water
granulated 1362 133 Carbon, activated 1390 139 Alkali metal amides
1381 136 Yellow phosphorus, dry
1346 170 Silicon powder, amorphous 1363 135 Copra 1391 138 Alkali metal dispersion
1381 136 Yellow phosphorus, in solution
1347 113 Silver picrate, wetted with not 1391 138 Alkaline earth metal dispersion
less than 30% water 1381 136 Yellow phosphorus, under water
1392 138 Alkaline earth metal amalga
Page 30 Page 31
1392 138 Alkaline earth metal 1420 138 Potassium, metal alloys, liquid 1448 141 Barium permanganate 1471 140 Lithium hypochlorite
amalgam, liquid 1421 138 Alkali metal alloy, liquid, n.o.s. 1449 141 Barium peroxide mixtures, dry
1393 138 Alkaline earth metal alloy, n.o.s. 1422 138 Potassium sodium alloys 1450 141 Bromates, inorganic, n.o.s. 1472 143 Lithium peroxide
1394 138 Aluminum carbide 1422 138 Potassium sodium alloys, 1473 140 Magnesium bromate
1451 140 Caesium nitrate
1395 139 Aluminum ferrosilicon powder liquid 1474 140 Magnesium nitrate
1451 140 Cesium nitrate
1396 138 Aluminum powder, uncoated 1422 138 Sodium potassium alloys 1475 140 Magnesium perchlorate
1452 140 Calcium chlorate
1397 139 Aluminum phosphide 1422 138 Sodium potassium alloys, 1476 140 Magnesium peroxide
1453 140 Calcium chlorite
1398 138 Aluminum silicon powder, liquid
1454 140 Calcium nitrate 1477 140 Nitrates, inorganic, n.o.s.
uncoated 1423 138 Rubidium
1455 140 Calcium perchlorate 1479 140 Oxidizing solid, n.o.s.
1400 138 Barium 1423 138 Rubidium metal
1456 140 Calcium permanganate 1481 140 Perchlorates, inorganic, n.o.s.
1401 138 Calcium 1426 138 Sodium borohydride
1457 140 Calcium peroxide 1482 140 Permanganates, inorganic, n.o.s.
1402 138 Calcium carbide 1427 138 Sodium hydride
1403 138 Calcium cyanamide, with 1428 138 Sodium 1458 140 Borate and Chlorate mixtures 1483 140 Peroxides, inorganic, n.o.s.
more than 0.1% Calcium 1431 138 Sodium methylate 1458 140 Chlorate and Borate mixtures 1484 140 Potassium bromate
carbide 1485 140 Potassium chlorate
1431 138 Sodium methylate, dry 1459 140 Chlorate and Magnesium
1404 138 Calcium hydride chloride mixture 1486 140 Potassium nitrate
1432 139 Sodium phosphide
1405 138 Calcium silicide 1459 140 Chlorate and Magnesium 1487 140 Potassium nitrate and Sodium
1433 139 Stannic phosphides
1407 138 Caesium chloride mixture, solid nitrite mixture
1435 138 Zinc ashes
1407 138 Cesium 1459 140 Magnesium chloride and 1487 140 Sodium nitrite and Potassium
1435 138 Zinc dross
1408 139 Ferrosilicon Chlorate mixture nitrate mixture
1435 138 Zinc residue
1409 138 Hydrides, metal, n.o.s. 1459 140 Magnesium chloride and 1488 140 Potassium nitrite
1435 138 Zinc skimmings
1409 138 Metal hydrides, water- Chlorate mixture, solid 1489 140 Potassium perchlorate
1436 138 Zinc dust
reactive, n.o.s. 1461 140 Chlorates, inorganic, n.o.s. 1490 140 Potassium permanganate
1436 138 Zinc powder
1410 138 Lithium aluminum hydride 1462 143 Chlorites, inorganic, n.o.s. 1491 144 Potassium peroxide
1437 138 Zirconium hydride
1411 138 Lithium aluminum hydride, 1463 141 Chromium trioxide, anhydrous
1438 140 Aluminum nitrate 1492 140 Potassium persulfate
ethereal
1465 140 Didymium nitrate 1492 140 Potassium persulphate
1413 138 Lithium borohydride 1439 141 Ammonium dichromate
1466 140 Ferric nitrate 1493 140 Silver nitrate
1414 138 Lithium hydride 1442 143 Ammonium perchlorate
1444 140 Ammonium persulfate 1467 143 Guanidine nitrate 1494 141 Sodium bromate
1415 138 Lithium
1444 140 Ammonium persulphate 1469 141 Lead nitrate 1495 140 Sodium chlorate
1417 138 Lithium silicon
1445 141 Barium chlorate 1470 141 Lead perchlorate 1496 143 Sodium chlorite
1418 138 Magnesium alloys powder
1445 141 Barium chlorate, solid 1470 141 Lead perchlorate, solid 1498 140 Sodium nitrate
1418 138 Magnesium powder
1446 141 Barium nitrate 1470 141 Lead perchlorate, solution 1499 140 Potassium nitrate and Sodium
1419 139 Magnesium aluminum
phosphide 1447 141 Barium perchlorate 1471 140 Lithium hypochlorite, dry nitrate mixture
1420 138 Potassium, metal alloys 1447 141 Barium perchlorate, solid 1471 140 Lithium hypochlorite mixture
Page 32 Page 33
1499 140 Sodium nitrate and Potassium 1549 157 Antimony compound, 1574 151 Calcium arsenate and Calcium 1590 153 Dichloroanilines, liquid
nitrate mixture inorganic, solid, n.o.s. arsenite mixture, solid 1590 153 Dichloroanilines, solid
1500 140 Sodium nitrite 1550 151 Antimony lactate 1574 151 Calcium arsenite and Calcium 1591 152 o-Dichlorobenzene
1502 140 Sodium perchlorate 1551 151 Antimony potassium tartrate arsenate mixture, solid
1593 160 Dichloromethane
1503 140 Sodium permanganate 1553 154 Arsenic acid, liquid 1575 157 Calcium cyanide
1593 160 Methylene chloride
1504 144 Sodium peroxide 1554 154 Arsenic acid, solid 1577 153 Chlorodinitrobenzenes
1594 152 Diethyl sulfate
1505 140 Sodium persulfate 1555 151 Arsenic bromide 1577 153 Chlorodinitrobenzenes, liquid
1594 152 Diethyl sulphate
1505 140 Sodium persulphate 1556 152 Arsenic compound, liquid, 1577 153 Chlorodinitrobenzenes, solid
1595 156 Dimethyl sulfate
1506 143 Strontium chlorate n.o.s. 1577 153 Dinitrochlorobenzenes
1595 156 Dimethyl sulphate
1506 143 Strontium chlorate, solid 1556 152 Arsenic compound, liquid, 1578 152 Chloronitrobenzenes
1596 153 Dinitroanilines
n.o.s., inorganic 1578 152 Chloronitrobenzenes, liquid
1506 143 Strontium chlorate, solution 1597 152 Dinitrobenzenes
1556 152 MD 1578 152 Chloronitrobenzenes, solid
1507 140 Strontium nitrate 1597 152 Dinitrobenzenes, liquid
1556 152 Methyldichloroarsine 1579 153 4-Chloro-o-toluidine
1508 140 Strontium perchlorate 1597 152 Dinitrobenzenes, solid
1556 152 PD hydrochloride
1509 143 Strontium peroxide 1598 153 Dinitro-o-cresol
1557 152 Arsenic compound, solid, n.o.s. 1579 153 4-Chloro-o-toluidine
1510 143 Tetranitromethane hydrochloride, solid 1599 153 Dinitrophenol, solution
1557 152 Arsenic compound, solid, n.o.s.,
1511 140 Urea hydrogen peroxide 1580 154 Chloropicrin 1600 152 Dinitrotoluenes, molten
inorganic
1512 140 Zinc ammonium nitrite 1581 123 Chloropicrin and Methyl 1601 151 Disinfectant, solid, poisonous,
1558 152 Arsenic
1513 140 Zinc chlorate bromide mixture n.o.s.
1559 151 Arsenic pentoxide
1514 140 Zinc nitrate 1581 123 Methyl bromide and 1601 151 Disinfectant, solid, toxic, n.o.s.
1560 157 Arsenic chloride
1515 140 Zinc permanganate Chloropicrin mixture 1601 151 Disinfectants, solid, n.o.s.
1560 157 Arsenic trichloride (poisonous)
1516 143 Zinc peroxide 1582 119 Chloropicrin and Methyl
1561 151 Arsenic trioxide chloride mixture 1602 151 Dye, liquid, poisonous, n.o.s.
1517 113 Zirconium picramate, wetted
1562 152 Arsenical dust 1582 119 Methyl chloride and 1602 151 Dye, liquid, toxic, n.o.s.
with not less than 20% water
1564 154 Barium compound, n.o.s. Chloropicrin mixture 1602 151 Dye intermediate, liquid,
1541 155 Acetone cyanohydrin, stabilized
1565 157 Barium cyanide 1583 154 Chloropicrin mixture, n.o.s. poisonous, n.o.s.
1544 151 Alkaloids, solid, n.o.s.
(poisonous) 1566 154 Beryllium compound, n.o.s. 1585 151 Copper acetoarsenite 1602 151 Dye intermediate, liquid,
1567 134 Beryllium powder 1586 151 Copper arsenite toxic, n.o.s.
1544 151 Alkaloid salts, solid, n.o.s.
(poisonous) 1569 131 Bromoacetone 1587 151 Copper cyanide 1603 155 Ethyl bromoacetate
1545 155 Allyl isothiocyanate, stabilized 1570 152 Brucine 1588 157 Cyanides, inorganic, n.o.s. 1604 132 Ethylenediamine
1546 151 Ammonium arsenate 1571 113 Barium azide, wetted with not 1588 157 Cyanides, inorganic, solid, n.o.s. 1605 154 Ethylene dibromide
1547 153 Aniline less than 50% water 1589 125 CK 1606 151 Ferric arsenate
1548 153 Aniline hydrochloride 1572 151 Cacodylic acid 1589 125 Cyanogen chloride, stabilized 1607 151 Ferric arsenite
1549 157 Antimony compound, 1573 151 Calcium arsenate 1590 153 Dichloroanilines 1608 151 Ferrous arsenate
inorganic, n.o.s.
Page 34 Page 35
1611 151 Hexaethyl tetraphosphate 1636 154 Mercury cyanide 1655 151 Nicotine preparation, solid, 1680 157 Potassium cyanide
1611 151 Hexaethyl tetraphosphate, 1637 151 Mercury gluconate n.o.s. 1680 157 Potassium cyanide, solid
liquid 1638 151 Mercury iodide 1656 151 Nicotine hydrochloride 1683 151 Silver arsenite
1611 151 Hexaethyl tetraphosphate, solid 1639 151 Mercury nucleate 1656 151 Nicotine hydrochloride, liquid 1684 151 Silver cyanide
1612 123 Hexaethyl tetraphosphate and 1640 151 Mercury oleate 1656 151 Nicotine hydrochloride, solid 1685 151 Sodium arsenate
compressed gas mixture 1656 151 Nicotine hydrochloride,
1641 151 Mercury oxide 1686 154 Sodium arsenite, aqueous
1613 154 Hydrocyanic acid, aqueous solution solution
1642 151 Mercuric oxycyanide
solution, with less than 5% 1657 151 Nicotine salicylate
1642 151 Mercury oxycyanide, 1687 153 Sodium azide
Hydrogen cyanide
desensitized 1658 151 Nicotine sulfate, solid 1688 152 Sodium cacodylate
1613 154 Hydrocyanic acid, aqueous
1643 151 Mercury potassium iodide 1658 151 Nicotine sulfate, solution 1689 157 Sodium cyanide
solution, with not more than
20% Hydrogen cyanide 1644 151 Mercury salicylate 1658 151 Nicotine sulphate, solid 1689 157 Sodium cyanide, solid
1613 154 Hydrogen cyanide, aqueous 1645 151 Mercuric sulfate 1658 151 Nicotine sulphate, solution 1690 154 Sodium fluoride
solution, with not more than 1645 151 Mercuric sulphate 1659 151 Nicotine tartrate 1690 154 Sodium fluoride, solid
20% Hydrogen cyanide 1660 124 Nitric oxide
1645 151 Mercury sulfate 1691 151 Strontium arsenite
1614 152 Hydrogen cyanide, stabilized 1660 124 Nitric oxide, compressed
1645 151 Mercury sulphate 1692 151 Strychnine
(absorbed)
1646 151 Mercury thiocyanate 1661 153 Nitroanilines 1692 151 Strychnine salts
1616 151 Lead acetate
1647 151 Ethylene dibromide and 1662 152 Nitrobenzene 1693 159 Tear gas devices
1617 151 Lead arsenates
Methyl bromide mixture, 1663 153 Nitrophenols 1693 159 Tear gas substance, liquid,
1618 151 Lead arsenites liquid 1664 152 Nitrotoluenes n.o.s.
1620 151 Lead cyanide 1647 151 Methyl bromide and Ethylene 1664 152 Nitrotoluenes, liquid 1693 159 Tear gas substance, solid,
1621 151 London purple dibromide mixture, liquid n.o.s.
1664 152 Nitrotoluenes, solid
1622 151 Magnesium arsenate 1648 127 Acetonitrile 1694 159 Bromobenzyl cyanides
1665 152 Nitroxylenes
1623 151 Mercuric arsenate 1648 127 Methyl cyanide 1694 159 Bromobenzyl cyanides, liquid
1665 152 Nitroxylenes, liquid
1624 154 Mercuric chloride 1649 131 Motor fuel anti-knock mixture 1694 159 Bromobenzyl cyanides, solid
1665 152 Nitroxylenes, solid
1625 141 Mercuric nitrate 1650 153 beta-Naphthylamine 1694 159 CA
1669 151 Pentachloroethane
1626 157 Mercuric potassium cyanide 1650 153 beta-Naphthylamine, solid 1695 131 Chloroacetone, stabilized
1670 157 Perchloromethyl mercaptan
1627 141 Mercurous nitrate 1650 153 Naphthylamine (beta) 1697 153 Chloroacetophenone
1671 153 Phenol, solid
1629 151 Mercury acetate 1650 153 Naphthylamine (beta), solid 1697 153 Chloroacetophenone, liquid
1672 151 Phenylcarbylamine chloride
1630 151 Mercury ammonium chloride 1651 153 Naphthylthiourea 1697 153 Chloroacetophenone, solid
1673 153 Phenylenediamines
1631 154 Mercury benzoate 1652 153 Naphthylurea 1697 153 CN
1674 151 Phenylmercuric acetate
1634 154 Mercuric bromide 1653 151 Nickel cyanide 1698 154 Adamsite
1677 151 Potassium arsenate
1634 154 Mercurous bromide 1654 151 Nicotine 1698 154 Diphenylamine chloroarsine
1678 154 Potassium arsenite
1634 154 Mercury bromides 1655 151 Nicotine compound, solid,
1679 157 Potassium cuprocyanide
1636 154 Mercuric cyanide n.o.s.
Page 36 Page 37
1698 154 DM 1715 137 Acetic anhydride 1740 154 Hydrogendifluorides, solid, 1754 137 Chlorosulphonic acid and
1699 151 DA 1716 156 Acetyl bromide n.o.s. Sulphur trioxide mixture
1699 151 Diphenylchloroarsine 1717 155 Acetyl chloride 1741 125 Boron trichloride 1754 137 Sulfur trioxide and
1742 157 Boron trifluoride acetic acid Chlorosulfonic acid mixture
1699 151 Diphenylchloroarsine, liquid 1718 153 Acid butyl phosphate
complex 1754 137 Sulphur trioxide and
1699 151 Diphenylchloroarsine, solid 1718 153 Butyl acid phosphate
1742 157 Boron trifluoride acetic acid Chlorosulphonic acid mixture
1700 159 Tear gas candles 1719 154 Caustic alkali liquid, n.o.s. complex, liquid 1755 154 Chromic acid, solution
1700 159 Tear gas grenades 1722 155 Allyl chlorocarbonate 1743 157 Boron trifluoride propionic 1756 154 Chromic fluoride, solid
1701 152 Xylyl bromide 1722 155 Allyl chloroformate acid complex 1757 154 Chromic fluoride, solution
1701 152 Xylyl bromide, liquid 1723 132 Allyl iodide 1743 157 Boron trifluoride propionic 1758 137 Chromium oxychloride
1702 151 1,1,2,2-Tetrachloroethane 1724 155 Allyltrichlorosilane, stabilized acid complex, liquid
1759 154 Corrosive solid, n.o.s.
1702 151 Tetrachloroethane 1725 137 Aluminum bromide, anhydrous 1744 154 Bromine
1759 154 Ferrous chloride, solid
1704 153 Tetraethyl dithiopyrophosphate 1726 137 Aluminum chloride, anhydrous 1744 154 Bromine, solution
1760 154 Chemical kit
1704 153 Tetraethyl dithiopyrophosphate, 1727 154 Ammonium bifluoride, solid 1744 154 Bromine, solution (Inhalation
1760 154 Compound, cleaning liquid
mixture, dry or liquid Hazard Zone A)
1727 154 Ammonium (corrosive)
1707 151 Thallium compound, n.o.s. hydrogendifluoride, solid 1744 154 Bromine, solution (Inhalation
1760 154 Compound, tree or weed
Hazard Zone B)
1708 153 Toluidines 1727 154 Ammonium hydrogen fluoride, killing, liquid (corrosive)
solid 1745 144 Bromine pentafluoride
1708 153 Toluidines, liquid 1760 154 Corrosive liquid, n.o.s.
1728 155 Amyltrichlorosilane 1746 144 Bromine trifluoride
1708 153 Toluidines, solid 1760 154 Ferrous chloride, solution
1729 156 Anisoyl chloride 1747 155 Butyltrichlorosilane
1709 151 2,4-Toluenediamine 1761 154 Cupriethylenediamine,
1730 157 Antimony pentachloride, liquid 1748 140 Calcium hypochlorite, dry solution
1709 151 2,4-Toluylenediamine
1731 157 Antimony pentachloride, 1748 140 Calcium hypochlorite mixture, 1762 156 Cyclohexenyltrichlorosilane
1709 151 2,4-Toluylenediamine, solid dry, with more than 39%
solution 1763 156 Cyclohexyltrichlorosilane
1710 160 Trichloroethylene available Chlorine (8.8%
1732 157 Antimony pentafluoride available Oxygen) 1764 153 Dichloroacetic acid
1711 153 Xylidines
1733 157 Antimony trichloride 1749 124 Chlorine trifluoride 1765 156 Dichloroacetyl chloride
1711 153 Xylidines, liquid
1733 157 Antimony trichloride, liquid 1750 153 Chloroacetic acid, liquid 1766 156 Dichlorophenyltrichlorosilane
1711 153 Xylidines, solid
1733 157 Antimony trichloride, solid 1750 153 Chloroacetic acid, solution 1767 155 Diethyldichlorosilane
1712 151 Zinc arsenate
1733 157 Antimony trichloride, solution 1751 153 Chloroacetic acid, solid 1768 154 Difluorophosphoric acid,
1712 151 Zinc arsenate and Zinc arsenite
1736 137 Benzoyl chloride anhydrous
mixture 1752 156 Chloroacetyl chloride
1737 156 Benzyl bromide 1769 156 Diphenyldichlorosilane
1712 151 Zinc arsenite 1753 156 Chlorophenyltrichlorosilane
1738 156 Benzyl chloride 1770 153 Diphenylmethyl bromide
1712 151 Zinc arsenite and Zinc arsenate 1754 137 Chlorosulfonic acid
mixture 1739 137 Benzyl chloroformate 1771 156 Dodecyltrichlorosilane
1754 137 Chlorosulfonic acid and Sulfur
1713 151 Zinc cyanide 1740 154 Hydrogendifluorides, n.o.s. trioxide mixture 1773 157 Ferric chloride
1714 139 Zinc phosphide 1754 137 Chlorosulphonic acid 1773 157 Ferric chloride, anhydrous
Page 38 Page 39
1774 154 Fire extinguisher charges, 1790 157 Hydrofluoric acid 1810 137 Phosphorus oxychloride 1826 157 Nitrating acid mixture, spent,
corrosive liquid 1790 157 Hydrofluoric acid, solution 1811 154 Potassium hydrogendifluoride with more than 50% nitric acid
1775 154 Fluoboric acid 1791 154 Hypochlorite solution 1811 154 Potassium hydrogen 1826 157 Nitrating acid mixture, spent, with
1775 154 Fluoroboric acid difluoride, solid not more than 50% nitric acid
1791 154 Hypochlorite solution, with
1776 154 Fluorophosphoric acid, more than 5% available 1812 154 Potassium fluoride 1827 137 Stannic chloride, anhydrous
anhydrous Chlorine 1827 137 Tin tetrachloride
1812 154 Potassium fluoride, solid
1777 137 Fluorosulfonic acid 1792 157 Iodine monochloride, solid 1828 137 Sulfur chlorides
1813 154 Caustic potash, dry, solid
1777 137 Fluorosulphonic acid 1793 153 Isopropyl acid phosphate 1828 137 Sulphur chlorides
1813 154 Potassium hydroxide, dry,
1778 154 Fluorosilicic acid 1794 154 Lead sulfate, with more than solid 1829 137 Sulfur trioxide, stabilized
1778 154 Fluosilicic acid 3% free acid
1813 154 Potassium hydroxide, flake 1829 137 Sulphur trioxide, stabilized
1778 154 Hydrofluorosilicic acid 1794 154 Lead sulphate, with more
than 3% free acid 1813 154 Potassium hydroxide, solid 1830 137 Sulfuric acid
1779 153 Formic acid
1796 157 Nitrating acid mixture with 1814 154 Caustic potash, liquid 1830 137 Sulfuric acid, with more than
1779 153 Formic acid, with more than 51% acid
more than 50% nitric acid 1814 154 Caustic potash, solution
85% acid
1796 157 Ni t rat ing acid mi x ture wi th 1814 154 Potassium hydroxide, solution 1830 137 Sulphuric acid
1780 156 Fumaryl chloride
not more than 50% nitric acid 1815 132 Propionyl chloride 1830 137 Sulphuric acid, with more
1781 156 Hexadecyltrichlorosilane than 51% acid
1798 157 Aqua regia 1816 155 Propyltrichlorosilane
1782 154 Hexafluorophosphoric acid 1831 137 Sulfuric acid, fuming
1798 157 Nitrohydrochloric acid
1783 153 Hexamethylenediamine, 1817 137 Pyrosulfuryl chloride
1799 156 Nonyltrichlorosilane 1831 137 Sulfuric acid, fuming, with less
solution 1817 137 Pyrosulphuryl chloride than 30% free Sulfur trioxide
1800 156 Octadecyltrichlorosilane
1784 156 Hexyltrichlorosilane 1818 157 Silicon tetrachloride
1801 156 Octyltrichlorosilane 1831 137 Sulfuric acid, fuming, with not
1786 157 Hydrofluoric acid and Sulfuric 1819 154 Sodium aluminate, solution less than 30% free Sulfur trioxide
acid mixture 1802 140 Perchloric acid, with not more
than 50% acid 1823 154 Caustic soda, bead 1831 137 Sulphuric acid, fuming
1786 157 Hydrofluoric acid and
1803 153 Phenolsulfonic acid, liquid 1823 154 Caustic soda, flake 1831 137 Sulphuric acid, fuming, with
Sulphuric acid mixture
1823 154 Caustic soda, granular less than 30% free Sulphur
1786 157 Sulfuric acid and Hydrofluoric 1803 153 Phenolsulphonic acid, liquid
trioxide
acid mixture 1804 156 Phenyltrichlorosilane 1823 154 Caustic soda, solid
1831 137 Sulphuric acid, fuming, with
1786 157 Sulphuric acid and 1805 154 Phosphoric acid 1823 154 Sodium hydroxide, bead
not less than 30% free
Hydrofluoric acid mixture 1805 154 Phosphoric acid, liquid 1823 154 Sodium hydroxide, dry Sulphur trioxide
1787 154 Hydriodic acid 1805 154 Phosphoric acid, solid 1823 154 Sodium hydroxide, flake 1832 137 Sulfuric acid, spent
1787 154 Hydriodic acid, solution 1805 154 Phosphoric acid, solution 1823 154 Sodium hydroxide, granular 1832 137 Sulphuric acid, spent
1788 154 Hydrobromic acid 1806 137 Phosphorus pentachloride 1823 154 Sodium hydroxide, solid 1833 154 Sulfurous acid
1788 154 Hydrobromic acid, solution 1807 137 Phosphorus pentoxide 1824 154 Caustic soda, solution 1833 154 Sulphurous acid
1789 157 Hydrochloric acid 1808 137 Phosphorus tribromide 1824 154 Sodium hydroxide, solution 1834 137 Sulfuryl chloride
1789 157 Hydrochloric acid, solution 1809 137 Phosphorus trichloride 1825 157 Sodium monoxide 1834 137 Sulphuryl chloride
1789 157 Muriatic acid
Page 40 Page 41
1835 153 Tetramethylammonium 1851 151 Medicine, liquid, toxic, n.o.s. 1886 156 Benzylidene chloride 1912 115 Methylene chloride and
hydroxide 1854 135 Barium alloys, pyrophoric 1887 160 Bromochloromethane Methyl chloride mixture
1835 153 Tetramethylammonium 1855 135 Calcium, metal and alloys, 1888 151 Chloroform 1913 120 Neon, refrigerated liquid
hydroxide, solution pyrophoric (cryogenic liquid)
1889 157 Cyanogen bromide
1836 137 Thionyl chloride 1855 135 Calcium, pyrophoric 1914 130 Butyl propionates
1891 131 Ethyl bromide
1837 157 Thiophosphoryl chloride 1855 135 Calcium alloys, pyrophoric 1915 127 Cyclohexanone
1892 151 ED
1838 137 Titanium tetrachloride 1856 133 Rags, oily 1916 152 2,2'-Dichlorodiethyl ether
1892 151 Ethyldichloroarsine
1839 153 Trichloroacetic acid 1857 133 Textile waste, wet 1916 152 Dichloroethyl ether
1894 151 Phenylmercuric hydroxide
1840 154 Zinc chloride, solution 1858 126 Hexafluoropropylene 1917 129P Ethyl acrylate, stabilized
1895 151 Phenylmercuric nitrate
1841 171 Acetaldehyde ammonia 1858 126 Hexafluoropropylene, 1918 130 Cumene
1897 160 Perchloroethylene
1843 141 Ammonium dinitro-o-cresolate compressed 1918 130 Isopropylbenzene
1843 141 Ammonium dinitro-o-cresolate, 1858 126 Refrigerant gas R-1216 1897 160 Tetrachloroethylene
1919 129P Methyl acrylate, stabilized
solid 1859 125 Silicon tetrafluoride 1898 156 Acetyl iodide
1920 128 Nonanes
1845 120 Carbon dioxide, solid 1859 125 Silicon tetrafluoride, compressed 1902 153 Diisooctyl acid phosphate
1921 131P Propyleneimine, stabilized
1845 120 Dry ice 1860 116P Vinyl fluoride, stabilized 1903 153 Disinfectant, liquid, corrosive,
n.o.s. 1922 132 Pyrrolidine
1846 151 Carbon tetrachloride 1862 130 Ethyl crotonate
1903 153 Disinfectants, corrosive, 1923 135 Calcium dithionite
1847 153 Potassium sulfide, hydrated, 1863 128 Fuel, aviation, turbine engine
with not less than 30% water of liquid, n.o.s. 1923 135 Calcium hydrosulfite
1865 131 n-Propyl nitrate
crystallization 1905 154 Selenic acid 1923 135 Calcium hydrosulphite
1866 127 Resin solution
1847 153 Potassium sulfide, hydrated, 1906 153 Acid, sludge 1928 135 Methyl magnesium bromide
with not less than 30% water of 1868 134 Decaborane
1906 153 Sludge acid in Ethyl ether
hydration 1869 138 Magnesium
1907 154 Soda lime, with more than 4% 1929 135 Potassium dithionite
1847 153 Potassium sulphide, hydrated, 1869 138 Magnesium, in pellets, turnings
Sodium hydroxide 1929 135 Potassium hydrosulfite
with not less than 30% water of or ribbons
crystallization 1908 154 Chlorite solution 1929 135 Potassium hydrosulphite
1869 138 Magnesium alloys, with more
1847 153 Potassium sulphide, hydrated, than 50% Magnesium, in pellets, 1908 154 Chlorite solution, with more 1931 171 Zinc dithionite
with not less than 30% water of turnings or ribbons than 5% available Chlorine 1931 171 Zinc hydrosulfite
hydration 1870 138 Potassium borohydride 1908 154 Sodium chlorite, solution, 1931 171 Zinc hydrosulphite
1848 132 Propionic acid 1871 170 Titanium hydride with more than 5% available
1932 135 Zirconium scrap
Chlorine
1848 132 Propionic acid, with not less 1872 141 Lead dioxide 1935 157 Cyanide solution, n.o.s.
than 10% and less than 90% acid 1910 157 Calcium oxide
1873 143 Perchloric acid, with more than 1938 156 Bromoacetic acid
1849 153 Sodium sulfide, hydrated, with 50% but not more than 72% acid 1911 119 Diborane
not less than 30% water 1938 156 Bromoacetic acid, solution
1884 157 Barium oxide 1911 119 Diborane, compressed
1849 153 Sodium sulphide, hydrated, with 1939 137 Phosphorus oxybromide
1885 153 Benzidine 1911 119 Diborane mixtures
not less than 30% water 1939 137 Phosphorus oxybromide, solid
1912 115 Methyl chloride and
1851 151 Medicine, liquid, poisonous, n.o.s. Methylene chloride mixture
Page 42 Page 43
1940 153 Thioglycolic acid 1953 119 Compressed gas, flammable, toxic, 1955 123 Compressed gas, poisonous, 1961 115 Ethane-Propane mixture,
1941 171 Dibromodifluoromethane n.o.s. (Inhalation Hazard Zone C) n.o.s. refrigerated liquid
1942 140 Ammonium nitrate, with not 1953 119 Compressed gas, flammable, toxic, 1955 123 Compressed gas, poisonous, 1961 115 Propane-Ethane mixture,
more than 0.2% combustible n.o.s. (Inhalation Hazard Zone D) n.o.s. (Inhalation Hazard Zone A) refrigerated liquid
substances 1953 119 Compressed gas, poisonous, 1955 123 Compressed gas, poisonous, 1962 116P Ethylene
1944 133 Matches, safety flammable, n.o.s. n.o.s. (Inhalation Hazard Zone B) 1962 116P Ethylene, compressed
1945 133 Matches, wax “vesta” 1953 119 Compressed gas, poisonous, 1955 123 Compressed gas, poisonous, 1963 120 Helium, refrigerated liquid
1950 126 Aerosol dispensers flammable, n.o.s. (Inhalation n.o.s. (Inhalation Hazard Zone C) (cryogenic liquid)
Hazard Zone A)
1950 126 Aerosols 1955 123 Compressed gas, poisonous, 1964 115 Hydrocarbon gas,
1953 119 Compressed gas, poisonous, n.o.s. (Inhalation Hazard Zone D)
1951 120 Argon, refrigerated liquid compressed, n.o.s.
flammable, n.o.s. (Inhalation
(cryogenic liquid) 1955 123 Compressed gas, toxic, n.o.s. 1964 115 Hydrocarbon gas mixture,
Hazard Zone B)
1952 126 Carbon dioxide and Ethylene 1955 123 Compressed gas, toxic, n.o.s. compressed, n.o.s.
1953 119 Compressed gas, poisonous,
oxide mixtures, with not more (Inhalation Hazard Zone A) 1965 115 Hydrocarbon gas, liquefied,
flammable, n.o.s. (Inhalation
than 6% Ethylene oxide 1955 123 Compressed gas, toxic, n.o.s. n.o.s.
Hazard Zone C)
1952 126 Carbon dioxide and Ethylene (Inhalation Hazard Zone B)
1953 119 Compressed gas, poisonous, 1965 115 Hydrocarbon gas mixture,
oxide mixtures, with not more
flammable, n.o.s. (Inhalation 1955 123 Compressed gas, toxic, n.o.s. liquefied, n.o.s.
than 9% Ethylene oxide
Hazard Zone D) (Inhalation Hazard Zone C) 1966 115 Hydrogen, refrigerated liquid
1952 126 Ethylene oxide and Carbon
1953 119 Compressed gas, toxic, 1955 123 Compressed gas, toxic, n.o.s. (cryogenic liquid)
dioxide mixtures, with not more
flammable, n.o.s. (Inhalation Hazard Zone D) 1967 123 Insecticide gas, poisonous,
1953 119 Compressed gas, toxic, 1955 123 Organic phosphate compound n.o.s.
1952 126 Ethylene oxide and Carbon
flammable, n.o.s. (Inhalation mixed with compressed gas 1967 123 Insecticide gas, toxic, n.o.s.
dioxide mixtures, with not more
Hazard Zone A) 1955 123 Organic phosphate mixed
than 9% Ethylene oxide 1967 123 Parathion and compressed
1953 119 Compressed gas, toxic, with compressed gas gas mixture
1953 119 Compressed gas, flammable,
flammable, n.o.s. (Inhalation 1955 123 Organic phosphorus
poisonous, n.o.s. (Inhalation 1968 126 Insecticide gas, n.o.s.
Hazard Zone B) compound mixed with
Hazard Zone A) 1969 115 Isobutane
1953 119 Compressed gas, toxic, compressed gas
1953 119 Compressed gas, flammable, 1969 115 Isobutane mixture
flammable, n.o.s. (Inhalation 1956 126 Compressed gas, n.o.s.
poisonous, n.o.s. (Inhalation
Hazard Zone C) 1970 120 Krypton, refrigerated liquid
Hazard Zone B) 1957 115 Deuterium
1953 119 Compressed gas, toxic, (cryogenic liquid)
1953 119 Compressed gas, flammable, 1957 115 Deuterium, compressed
flammable, n.o.s. (Inhalation 1971 115 Methane
poisonous, n.o.s. (Inhalation
Hazard Zone D) 1958 126 1,2-Dichloro-1,1,2,2-
Hazard Zone C) 1971 115 Methane, compressed
1954 115 Compressed gas, flammable, n.o.s. tetrafluoroethane
1953 119 Compressed gas, flammable, 1971 115 Natural gas, compressed
1954 115 Dispersant gas, n.o.s. 1958 126 Dichlorotetrafluoroethane
poisonous, n.o.s. (Inhalation 1972 115 Liquefied natural gas
Hazard Zone D) (flammable) 1958 126 Refrigerant gas R-114
(cryogenic liquid)
1953 119 Compressed gas, flammable, toxic, 1954 115 Refrigerant gas, n.o.s. 1959 116P 1,1-Difluoroethylene
1972 115 LNG (cryogenic liquid)
n.o.s. (Inhalation Hazard Zone A) (flammable) 1959 116P Refrigerant gas R-1132a
1972 115 Methane, refrigerated liquid
1953 119 Compressed gas, flammable, toxic, 1961 115 Ethane, refrigerated liquid (cryogenic liquid)
n.o.s. (Inhalation Hazard Zone B)
Page 44 Page 45
1972 115 Natural gas, refrigerated liquid 1981 121 Rare gases and Nitrogen 1993 128 Compound, tree or weed 2015 143 Hydrogen peroxide, aqueous
(cryogenic liquid) mixture, compressed killing, liquid (flammable) solution, stabilized, with more
1973 126 Chlorodifluoromethane and 1982 126 Refrigerant gas R-14 1993 128 Diesel fuel than 60% Hydrogen peroxide
Chloropentafluoroethane 1982 126 Refrigerant gas R-14, 1993 128 Flammable liquid, n.o.s. 2015 143 Hydrogen peroxide, stabilized
mixture compressed 2016 151 Ammunition, poisonous, non-
1993 128 Fuel oil
1973 126 Chloropentafluoroethane and 1982 126 Tetrafluoromethane explosive
1994 131 Iron pentacarbonyl
Chlorodifluoromethane mixture 1982 126 Tetrafluoromethane, 2016 151 Ammunition, toxic, non-
1999 130 Asphalt
1973 126 Refrigerant gas R-502 compressed explosive
1999 130 Tars, liquid
1974 126 Bromochlorodifluoromethane 1983 126 1-Chloro-2,2,2-trifluoroethane 2017 159 Ammunition, tear-producing,
2000 133 Celluloid, in blocks, rods, non-explosive
1974 126 Chlorodifluorobromomethane 1983 126 Chlorotrifluoroethane rolls,sheets, tubes, etc.,
1974 126 Refrigerant gas R-12B1 1983 126 Refrigerant gas R-133a 2018 152 Chloroanilines, solid
except scrap
1975 124 Dinitrogen tetroxide and Nitric 1984 126 Refrigerant gas R-23 2019 152 Chloroanilines, liquid
2001 133 Cobalt naphthenates, powder
oxide mixture 1984 126 Trifluoromethane 2020 153 Chlorophenols, solid
2002 135 Celluloid, scrap
1975 124 Nitric oxide and Dinitrogen 1986 131 Alcohols, flammable, 2021 153 Chlorophenols, liquid
tetroxide mixture 2003 135 Metal alkyls, water-reactive,
poisonous, n.o.s. n.o.s. 2022 153 Cresylic acid
1975 124 Nitric oxide and Nitrogen 1986 131 Alcohols, flammable, toxic, 2023 131P 1-Chloro-2,3-epoxypropane
dioxide mixture 2003 135 Metal aryls, water-reactive,
n.o.s. n.o.s. 2023 131P Epichlorohydrin
1975 124 Nitric oxide and Nitrogen 1986 131 Alcohols, poisonous, n.o.s.
tetroxide mixture 2004 135 Magnesium diamide 2024 151 Mercury compound, liquid,
1986 131 Alcohols, toxic, n.o.s. 2005 135 Magnesium diphenyl n.o.s.
1975 124 Nitrogen dioxide and Nitric
oxide mixture 1987 127 Alcohols, n.o.s. 2006 135 Plastic, nitrocellulose-based, 2025 151 Mercury compound, solid, n.o.s.
1975 124 Nitrogen tetroxide and Nitric 1988 131 Aldehydes, flammable, spontaneously combustible, 2026 151 Phenylmercuric compound,
oxide mixture poisonous, n.o.s. n.o.s. n.o.s.
1976 126 Octafluorocyclobutane 1988 131 Aldehydes, flammable, toxic, 2006 135 Plastics, nitrocellulose-based, 2027 151 Sodium arsenite, solid
n.o.s. self-heating, n.o.s. 2028 153 Bombs, smoke, non-explosive,
1976 126 Refrigerant gas RC-318
1988 131 Aldehydes, poisonous, n.o.s. 2008 135 Zirconium powder, dry with corrosive liquid, without
1977 120 Nitrogen, refrigerated liquid
1988 131 Aldehydes, toxic, n.o.s. 2009 135 Zirconium, dry, finished initiating device
(cryogenic liquid)
1989 129 Aldehydes, n.o.s. sheets, strips or coiled wire 2029 132 Hydrazine, anhydrous
1978 115 Propane
1990 129 Benzaldehyde 2010 138 Magnesium hydride 2029 132 Hydrazine, aqueous solutions,
1978 115 Propane mixture
1991 131P Chloroprene, stabilized 2011 139 Magnesium phosphide with more than 64%
1979 121 Rare gases mixture, Hydrazine
compressed 1992 131 Flammable liquid, poisonous, 2012 139 Potassium phosphide
n.o.s. 2030 153 Hydrazine, aqueous solution,
1980 121 Oxygen and Rare gases mixture, 2013 139 Strontium phosphide
with more than 37% Hydrazine
compressed 1992 131 Flammable liquid, toxic, n.o.s. 2014 140 Hydrogen peroxide, aqueous
1993 128 Combustible liquid, n.o.s. 2030 153 Hydrazine, aqueous solution,
1980 121 Rare gases and Oxygen mixture, solution, with not less than
with not less than 37% but
compressed 1993 128 Compound, cleaning liquid 20% but not more than 60%
not more than 64% Hydrazine
1981 121 Nitrogen and Rare gases (flammable) Hydrogen peroxide (stabilized
as necessary) 2030 153 Hydrazine hydrate
mixture, compressed
Page 46 Page 47
2031 157 Nitric acid, other than red 2053 129 Methylamyl alcohol 2076 153 Cresols, liquid 2201 122 Nitrous oxide, refrigerated
fuming, with more than 70% 2053 129 Methyl isobutyl carbinol 2076 153 Cresols, solid liquid
nitric acid 2202 117 Hydrogen selenide, anhydrous
2053 129 M.I.B.C. 2077 153 alpha-Naphthylamine
2031 157 Nitric acid, other than red 2203 116 Silane
2054 132 Morpholine 2077 153 Naphthylamine (alpha)
fuming, with not more than 70%
2055 128P Styrene monomer, stabilized 2078 156 Toluene diisocyanate 2203 116 Silane, compressed
nitric acid
2056 127 Tetrahydrofuran 2079 154 Diethylenetriamine 2204 119 Carbonyl sulfide
2032 157 Nitric acid, fuming
2057 128 Tripropylene 2186 125 Hydrogen chloride, 2204 119 Carbonyl sulphide
2032 157 Nitric acid, red fuming
2033 154 Potassium monoxide 2058 129 Valeraldehyde refrigerated liquid 2205 153 Adiponitrile
2034 115 Hydrogen and Methane 2059 127 Nitrocellulose, solution, 2187 120 Carbon dioxide, refrigerated 2206 155 Isocyanate solution,
mixture, compressed flammable liquid poisonous, n.o.s.
2034 115 Methane and Hydrogen 2059 127 Nitrocellulose, solution, in a 2188 119 Arsine 2206 155 Isocyanate solution, toxic, n.o.s.
mixture, compressed flammable liquid 2188 119 SA 2206 155 Isocyanate solutions, n.o.s.
2035 115 Refrigerant gas R-143a 2067 140 Ammonium nitrate fertilizers 2189 119 Dichlorosilane 2206 155 Isocyanates, n.o.s.
2035 115 1,1,1-Trifluoroethane 2068 140 Ammonium nitrate fertilizers, 2190 124 Oxygen difluoride 2206 155 Isocyanates, poisonous, n.o.s.
with Calcium carbonate
2035 115 Trifluoroethane, compressed 2190 124 Oxygen difluoride, 2206 155 Isocyanates, toxic, n.o.s.
2069 140 Ammonium nitrate fertilizers, compressed
2036 121 Xenon 2208 140 Bleaching powder
with Ammonium sulfate
2036 121 Xenon, compressed 2191 123 Sulfuryl fluoride 2208 140 Calcium hypochlorite mixture,
2069 140 Ammonium nitrate fertilizers,
2037 115 Gas cartridges with Ammonium sulphate 2191 123 Sulphuryl fluoride dry, with more than 10% but
2037 115 Receptacles, small, containing gas 2192 119 Germane not more than 39% available
2069 140 Ammonium nitrate mixed
Chlorine
2038 152 Dinitrotoluenes fertilizers 2193 126 Hexafluoroethane
2209 132 Formaldehyde, solutions
2038 152 Dinitrotoluenes, liquid 2070 143 Ammonium nitrate fertilizers, 2193 126 Hexafluoroethane,
(Formalin) (corrosive)
2038 152 Dinitrotoluenes, solid with Phosphate or Potash compressed
2210 135 Maneb
2044 115 2,2-Dimethylpropane 2071 140 Ammonium nitrate fertilizer, 2193 126 Refrigerant gas R-116
with not more than 0.4% 2210 135 Maneb preparation, with not
2045 130 Isobutyl aldehyde 2193 126 Refrigerant gas R-116,
combustible material less than 60% Maneb
compressed
2045 130 Isobutyraldehyde 2211 133 Polymeric beads, expandable
2071 140 Ammonium nitrate fertilizers 2194 125 Selenium hexafluoride
2046 130 Cymenes 2211 133 Polystyrene beads, expandable
2072 140 Ammonium nitrate fertilizer, n.o.s. 2195 125 Tellurium hexafluoride
2047 129 Dichloropropenes 2212 171 Asbestos
2072 140 Ammonium nitrate fertilizers 2196 125 Tungsten hexafluoride
2048 130 Dicyclopentadiene
2073 125 Ammonia, solution, with more 2212 171 Asbestos, blue
2049 130 Diethylbenzene 2197 125 Hydrogen iodide, anhydrous
than 35% but not more than 2212 171 Asbestos, brown
2050 128 Diisobutylene, isomeric 50% Ammonia 2198 125 Phosphorus pentafluoride
2212 171 Blue asbestos
compounds 2074 153P Acrylamide 2198 125 Phosphorus pentafluoride,
compressed 2212 171 Brown asbestos
2051 132 2-Dimethylaminoethanol 2074 153P Acrylamide, solid
2199 119 Phosphine 2213 133 Paraformaldehyde
2051 132 Dimethylethanolamine 2075 153 Chloral, anhydrous, stabilized
2200 116P Propadiene, stabilized 2214 156 Phthalic anhydride
2052 128 Dipentene 2076 153 Cresols
Page 48 Page 49
2215 156 Maleic anhydride 2242 128 Cycloheptene 2269 153 3,3'-Iminodipropylamine 2297 128 Methylcyclohexanone
2215 156 Maleic anhydride, molten 2243 130 Cyclohexyl acetate 2270 132 Ethylamine, aqueous solution, 2298 128 Methylcyclopentane
2216 171 Fish meal, stabilized 2244 129 Cyclopentanol with not less than 50% but 2299 155 Methyl dichloroacetate
not more than 70%
2216 171 Fish scrap, stabilized 2245 128 Cyclopentanone 2300 153 2-Methyl-5-ethylpyridine
Ethylamine
2217 135 Seed cake, with not more 2246 128 Cyclopentene 2301 128 2-Methylfuran
2271 128 Ethyl amyl ketone
than 1.5% oil and not more 2247 128 n-Decane 2302 127 5-Methylhexan-2-one
than 11% moisture 2272 153 N-Ethylaniline
2248 132 Di-n-butylamine 2303 128 Isopropenylbenzene
2218 132P Acrylic acid, stabilized 2273 153 2-Ethylaniline
2249 131 Dichlorodimethyl ether, 2304 133 Naphthalene, molten
2219 129 Allyl glycidyl ether 2274 153 N-Ethyl-N-benzylaniline
symmetrical 2305 153 Nitrobenzenesulfonic acid
2275 129 2-Ethylbutanol
2222 128 Anisole 2250 156 Dichlorophenyl isocyanates 2305 153 Nitrobenzenesulphonic acid
2276 132 2-Ethylhexylamine
2224 152 Benzonitrile 2251 128P Bicyclo[2.2.1]hepta-2,5-diene, 2306 152 Nitrobenzotrifluorides
2277 130P Ethyl methacrylate
2225 156 Benzenesulfonyl chloride stabilized 2306 152 Nitrobenzotrifluorides, liquid
2277 130P Ethyl methacrylate, stabilized
2225 156 Benzenesulphonyl chloride 2251 128P 2,5-Norbornadiene, stabilized 2307 152 3-Nitro-4-
2278 128 n-Heptene
2226 156 Benzotrichloride 2252 127 1,2-Dimethoxyethane chlorobenzotrifluoride
2279 151 Hexachlorobutadiene
2227 130P n-Butyl methacrylate, 2253 153 N,N-Dimethylaniline 2308 157 Nitrosylsulfuric acid
stabilized 2280 153 Hexamethylenediamine, solid
2254 133 Matches, fusee 2308 157 Nitrosylsulfuric acid, liquid
2232 153 Chloroacetaldehyde 2281 156 Hexamethylene diisocyanate
2256 130 Cyclohexene 2308 157 Nitrosylsulfuric acid, solid
2282 129 Hexanols
2232 153 2-Chloroethanal 2257 138 Potassium 2308 157 Nitrosylsulphuric acid
2283 130P Isobutyl methacrylate,
2233 152 Chloroanisidines 2257 138 Potassium, metal 2308 157 Nitrosylsulphuric acid, liquid
stabilized
2234 130 Chlorobenzotrifluorides 2258 132 1,2-Propylenediamine 2308 157 Nitrosylsulphuric acid, solid
2284 131 Isobutyronitrile
2235 153 Chlorobenzyl chlorides 2258 132 1,3-Propylenediamine 2309 128P Octadiene
2285 156 Isocyanatobenzotrifluorides
2235 153 Chlorobenzyl chlorides, liquid 2259 153 Triethylenetetramine 2310 131 Pentan-2,4-dione
2286 128 Pentamethylheptane
2236 156 3-Chloro-4-methylphenyl 2260 132 Tripropylamine 2310 131 2,4-Pentanedione
2287 128 Isoheptenes
isocyanate 2310 131 Pentane-2,4-dione
2261 153 Xylenols 2288 128 Isohexenes
2236 156 3-Chloro-4-methylphenyl 2311 153 Phenetidines
2261 153 Xylenols, solid 2289 153 Isophoronediamine
isocyanate, liquid 2312 153 Phenol, molten
2262 156 Dimethylcarbamoyl chloride 2290 156 IPDI
2237 153 Chloronitroanilines 2313 129 Picolines
2263 128 Dimethylcyclohexanes 2290 156 Isophorone diisocyanate
2238 129 Chlorotoluenes 2315 171 Articles containing
2264 132 N,N-Dimethylcyclohexylamine 2291 151 Lead compound, soluble,
2239 153 Chlorotoluidines Polychlorinated biphenyls
2264 132 Dimethylcyclohexylamine n.o.s.
2239 153 Chlorotoluidines, liquid (PCB)
2265 129 N,N-Dimethylformamide 2293 128 4-Methoxy-4-methylpentan-
2239 153 Chlorotoluidines, solid 2315 171 PCB
2-one
2266 132 Dimethyl-N-propylamine 2315 171 Polychlorinated biphenyls
2240 154 Chromosulfuric acid 2294 153 N-Methylaniline
2267 156 Dimethyl thiophosphoryl 2315 171 Polychlorinated biphenyls,
2240 154 Chromosulphuric acid 2295 155 Methyl chloroacetate
chloride liquid
2241 128 Cycloheptane 2296 128 Methylcyclohexane
Page 50 Page 51
2315 171 Polychlorinated biphenyls, solid 2337 131 Phenyl mercaptan 2368 128 Pinene (alpha) 2396 131P Methacrylaldehyde, stabilized
2316 157 Sodium cuprocyanide, solid 2338 127 Benzotrifluoride 2370 128 1-Hexene 2397 127 3-Methylbutan-2-one
2317 157 Sodium cuprocyanide, solution 2339 130 2-Bromobutane 2371 128 Isopentenes 2398 127 Methyl tert-butyl ether
2318 135 Sodium hydrosulfide, solid, with 2340 130 2-Bromoethyl ethyl ether 2372 129 1,2-Di-(dimethylamino)ethane 2399 132 1-Methylpiperidine
less than 25% water of 2341 130 1-Bromo-3-methylbutane 2373 127 Diethoxymethane 2400 130 Methyl isovalerate
crystallization
2342 130 Bromomethylpropanes 2374 127 3,3-Diethoxypropene 2401 132 Piperidine
2318 135 Sodium hydrosulfide, with less
than 25% water of 2343 130 2-Bromopentane 2375 129 Diethyl sulfide 2402 130 Propanethiols
crystallization 2344 129 2-Bromopropane 2375 129 Diethyl sulphide 2403 129P Isopropenyl acetate
2318 135 Sodium hydrosulphide, solid, 2344 129 Bromopropanes 2376 127 2,3-Dihydropyran 2404 131 Propionitrile
with less than 25% water of 2345 130 3-Bromopropyne 2377 127 1,1-Dimethoxyethane 2405 129 Isopropyl butyrate
crystallization
2346 127 Butanedione 2378 131 2-Dimethylaminoacetonitrile 2406 127 Isopropyl isobutyrate
2318 135 Sodium hydrosulphide, with less
2346 127 Diacetyl 2379 132 1,3-Dimethylbutylamine 2407 155 Isopropyl chloroformate
than 25% water of
crystallization 2347 130 Butyl mercaptan 2380 127 Dimethyldiethoxysilane 2409 129 Isopropyl propionate
2319 128 Terpene hydrocarbons, n.o.s. 2348 129P Butyl acrylates, stabilized 2381 130 Dimethyl disulfide 2410 129 1,2,3,6-Tetrahydropyridine
2320 153 Tetraethylenepentamine 2350 127 Butyl methyl ether 2381 130 Dimethyl disulphide 2410 129 1,2,5,6-Tetrahydropyridine
2321 153 Trichlorobenzenes, liquid 2351 129 Butyl nitrites 2382 131 1,2-Dimethylhydrazine 2411 131 Butyronitrile
2322 152 Trichlorobutene 2352 127P Butyl vinyl ether, stabilized 2382 131 Dimethylhydrazine, 2412 130 Tetrahydrothiophene
2353 132 Butyryl chloride symmetrical 2413 128 Tetrapropyl orthotitanate
2323 130 Triethyl phosphite
2354 131 Chloromethyl ethyl ether 2383 132 Dipropylamine 2414 130 Thiophene
2324 128 Triisobutylene
2356 129 2-Chloropropane 2384 127 Di-n-propyl ether 2416 129 Trimethyl borate
2325 129 1,3,5-Trimethylbenzene
2357 132 Cyclohexylamine 2384 127 Dipropyl ether 2417 125 Carbonyl fluoride
2326 153 Trimethylcyclohexylamine
2358 128P Cyclooctatetraene 2385 129 Ethyl isobutyrate 2417 125 Carbonyl fluoride,
2327 153 Trimethylhexamethylenediaines
2359 132 Diallylamine 2386 132 1-Ethylpiperidine compressed
2328 156 Trimethylhexamethylene
diisocyanate 2360 131P Diallyl ether 2387 130 Fluorobenzene 2418 125 Sulfur tetrafluoride
2329 130 Trimethyl phosphite 2361 132 Diisobutylamine 2388 130 Fluorotoluenes 2418 125 Sulphur tetrafluoride
2330 128 Undecane 2362 130 1,1-Dichloroethane 2389 128 Furan 2419 116 Bromotrifluoroethylene
2331 154 Zinc chloride, anhydrous 2363 129 Ethyl mercaptan 2390 129 2-Iodobutane 2420 125 Hexafluoroacetone
2332 129 Acetaldehyde oxime 2364 128 n-Propyl benzene 2391 129 Iodomethylpropanes 2421 124 Nitrogen trioxide
2333 131 Allyl acetate 2366 128 Diethyl carbonate 2392 129 Iodopropanes 2422 126 Octafluorobut-2-ene
2334 131 Allylamine 2367 130 alpha-Methylvaleraldehyde 2393 129 Isobutyl formate 2422 126 Refrigerant gas R-1318
2335 131 Allyl ethyl ether 2367 130 Methyl valeraldehyde (alpha) 2394 129 Isobutyl propionate 2424 126 Octafluoropropane
2336 131 Allyl formate 2368 128 alpha-Pinene 2395 132 Isobutyryl chloride 2424 126 Refrigerant gas R-218
Page 52 Page 53
2426 140 Ammonium nitrate, liquid 2444 137 Vanadium tetrachloride 2469 140 Zinc bromate 2498 129 1,2,3,6-Tetrahydrobenzaldehyde
(hot concentrated solution) 2445 135 Lithium alkyls 2470 152 Phenylacetonitrile, liquid 2501 152 1-Aziridinyl phosphine oxide (Tris)
2427 140 Potassium chlorate, aqueous 2445 135 Lithium alkyls, liquid 2471 154 Osmium tetroxide 2501 152 Tri-(1-aziridinyl)phosphine
solution oxide, solution
2446 153 Nitrocresols 2473 154 Sodium arsanilate
2427 140 Potassium chlorate, solution 2501 152 Tris-(1-aziridinyl)phosphine
2446 153 Nitrocresols, solid 2474 157 Thiophosgene
2428 140 Sodium chlorate, aqueous oxide, solution
2447 136 Phosphorus, white, molten 2475 157 Vanadium trichloride
solution
2447 136 White phosphorus, molten 2502 132 Valeryl chloride
2429 140 Calcium chlorate, aqueous 2477 131 Methyl isothiocyanate
2447 136 Yellow phosphorus, molten 2503 137 Zirconium tetrachloride
solution 2478 155 Isocyanate solution,
2448 133 Sulfur, molten flammable, poisonous, n.o.s. 2504 159 Acetylene tetrabromide
2429 140 Calcium chlorate, solution
2448 133 Sulphur, molten 2478 155 Isocyanate solution, 2504 159 Tetrabromoethane
2430 153 Alkyl phenols, solid, n.o.s.
(including C2-C12 homologues) 2451 122 Nitrogen trifluoride flammable, toxic, n.o.s. 2505 154 Ammonium fluoride
2431 153 Anisidines 2451 122 Nitrogen trifluoride, 2478 155 Isocyanate solutions, n.o.s. 2506 154 Ammonium hydrogen sulfate
2431 153 Anisidines, liquid compressed 2478 155 Isocyanates, flammable, 2506 154 Ammonium hydrogen
2431 153 Anisidines, solid 2452 116P Ethylacetylene, stabilized poisonous, n.o.s. sulphate
2432 153 N,N-Diethylaniline 2453 115 Ethyl fluoride 2478 155 Isocyanates, flammable, toxic, 2507 154 Chloroplatinic acid, solid
2453 115 Refrigerant gas R-161 n.o.s. 2508 156 Molybdenum pentachloride
2433 152 Chloronitrotoluenes
2433 152 Chloronitrotoluenes, liquid 2454 115 Methyl fluoride 2478 155 Isocyanates, n.o.s. 2509 154 Potassium hydrogen sulfate
2433 152 Chloronitrotoluenes, solid 2454 115 Refrigerant gas R-41 2480 155 Methyl isocyanate 2509 154 Potassium hydrogen sulphate
2434 156 Dibenzyldichlorosilane 2455 116 Methyl nitrite 2481 155 Ethyl isocyanate 2511 153 2-Chloropropionic acid
2435 156 Ethylphenyldichlorosilane 2456 130P 2-Chloropropene 2482 155 n-Propyl isocyanate 2511 153 2-Chloropropionic acid, solid
2436 129 Thioacetic acid 2457 128 2,3-Dimethylbutane 2483 155 Isopropyl isocyanate 2511 153 2-Chloropropionic acid,
2437 156 Methylphenyldichlorosilane 2458 130 Hexadiene 2484 155 tert-Butyl isocyanate solution
2438 132 Trimethylacetyl chloride 2459 128 2-Methyl-1-butene 2485 155 n-Butyl isocyanate 2512 152 Aminophenols
2439 154 Sodium hydrogendifluoride 2460 128 2-Methyl-2-butene 2486 155 Isobutyl isocyanate 2513 156 Bromoacetyl bromide
2440 154 Stannic chloride, 2461 128 Methylpentadiene 2487 155 Phenyl isocyanate 2514 130 Bromobenzene
pentahydrate 2463 138 Aluminum hydride 2488 155 Cyclohexyl isocyanate 2515 159 Bromoform
2440 154 Tin tetrachloride, 2464 141 Beryllium nitrate
2490 153 Dichloroisopropyl ether 2516 151 Carbon tetrabromide
pentahydrate 2465 140 Dichloroisocyanuric acid, dry
2491 153 Ethanolamine 2517 115 1-Chloro-1,1-difluoroethane
2441 135 Titanium trichloride, 2465 140 Dichloroisocyanuric acid salts
pyrophoric 2491 153 Ethanolamine, solution 2517 115 Chlorodifluoroethanes
2465 140 Sodium dichloroisocyanurate
2441 135 Titanium trichloride mixture, 2491 153 Monoethanolamine 2517 115 Difluorochloroethanes
2465 140 Sodium dichloro-
pyrophoric striazinetrione 2493 132 Hexamethyleneimine 2517 115 Refrigerant gas R-142b
2442 156 Trichloroacetyl chloride 2466 143 Potassium superoxide 2495 144 Iodine pentafluoride 2518 153 1,5,9-Cyclododecatriene
2443 137 Vanadium oxytrichloride 2468 140 Trichloroisocyanuric acid, dry 2496 156 Propionic anhydride 2520 130P Cyclooctadienes
Page 54 Page 55
2521 131P Diketene, stabilized 2557 133 Nitrocellulose 2583 153 Alkyl sulfonic acids, solid, with 2586 153 Aryl sulfonic acids, liquid, with
2522 153P 2-Dimethylaminoethyl 2557 133 Nitrocellulose mixture, more than 5% free Sulfuric acid not more than 5% free
methacrylate without pigment 2583 153 Alkyl sulphonic acids, solid, Sulfuric acid
2522 153P Dimethylaminoethyl 2557 133 Nitrocellulose mixture, with more than 5% free 2586 153 Aryl sulphonic acids, liquid,
methacrylate without plasticizer Sulphuric acid with not more than 5% free
2583 153 Aryl sulfonic acids, solid, with Sulphuric acid
2524 129 Ethyl orthoformate 2557 133 Nitrocellulose mixture, with
more than 5% free Sulfuric acid 2587 153 Benzoquinone
2525 156 Ethyl oxalate pigment
2583 153 Aryl sulphonic acids, solid, 2588 151 Pesticide, solid, poisonous
2526 132 Furfurylamine 2557 133 Nitrocellulose mixture, with with more than 5% free 2588 151 Pesticide, solid, poisonous, n.o.s.
pigment and plasticizer Sulphuric acid
2527 129P Isobutyl acrylate, stabilized 2588 151 Pesticide, solid, toxic, n.o.s.
2557 133 Nitrocellulose mixture, with 2584 153 Alkyl sulfonic acids, liquid,
2528 130 Isobutyl isobutyrate 2589 155 Vinyl chloroacetate
plasticizer with more than 5% free
2529 132 Isobutyric acid 2590 171 Asbestos, white
2558 131 Epibromohydrin Sulfuric acid
2531 153P Methacrylic acid, stabilized 2590 171 White asbestos
2560 129 2-Methylpentan-2-ol 2584 153 Alkyl sulphonic acids, liquid,
2533 156 Methyl trichloroacetate 2591 120 Xenon, refrigerated liquid
2561 128 3-Methyl-1-butene with more than 5% free
(cryogenic liquid)
2534 119 Methylchlorosilane Sulphuric acid
2564 153 Trichloroacetic acid, solution 2599 126 Chlorotrifluoromethane and
2535 132 4-Methylmorpholine 2584 153 Aryl sulfonic acids, liquid, with
2565 153 Dicyclohexylamine Trifluoromethane azeotropic
more than 5% free Sulfuric acid
2535 132 N-Methylmorpholine mixture with approximately
2567 154 Sodium pentachlorophenate 2584 153 Aryl sulphonic acids, liquid,
2535 132 Methylmorpholine 60% Chlorotrifluoromethane
2570 154 Cadmium compound with more than 5% free
2536 127 Methyltetrahydrofuran 2599 126 Refrigerant gas R-13 and
2571 156 Alkylsulfuric acids Sulphuric acid
Refrigerant gas R-23
2538 133 Nitronaphthalene 2585 153 Alkyl sulfonic acids, solid, with
2571 156 Alkylsulphuric acids azeotropic mixture with 60%
2541 128 Terpinolene not more than 5% free Refrigerant gas R-13
2571 156 Ethylsulfuric acid Sulfuric acid
2542 153 Tributylamine 2599 126 Refrigerant gas R-23 and
2571 156 Ethylsulphuric acid 2585 153 Alkyl sulphonic acids, solid,
2545 135 Hafnium powder, dry Refrigerant gas R-13
2572 153 Phenylhydrazine with not more than 5% free azeotropic mixture with 60%
2546 135 Titanium powder, dry Sulphuric acid
2573 141 Thallium chlorate Refrigerant gas R-13
2547 143 Sodium superoxide 2585 153 Aryl sulfonic acids, solid, with
2574 151 Tricresyl phosphate 2599 126 Refrigerant gas R-503 (azeotropic
2548 124 Chlorine pentafluoride not more than 5% free mixture of Refrigerant gas R-13
2576 137 Phosphorus oxybromide, Sulfuric acid
2552 151 Hexafluoroacetone hydrate molten and Refrigerant gas R-23 with
2585 153 Aryl sulphonic acids, solid, approximately 60% Refrigerant
2552 151 Hexafluoroacetone hydrate, 2577 156 Phenylacetyl chloride with not more than 5% free gas R-13)
liquid
2578 157 Phosphorus trioxide Sulphuric acid 2599 126 Trifluoromethane and
2554 130P Methylallyl chloride 2586 153 Alkyl sulfonic acids, liquid,
2579 153 Piperazine Chlorotrifluoromethane
2555 113 Nitrocellulose with water, not with not more than 5% free azeotropic mixture with
2580 154 Aluminum bromide, solution
less than 25% water Sulfuric acid approximately 60%
2581 154 Aluminum chloride, solution
2556 113 Nitrocellulose with alcohol 2586 153 Alkyl sulphonic acids, liquid, Chlorotrifluoromethane
2582 154 Ferric chloride, solution with not more than 5% free
2556 113 Nitrocellulose with not less 2600 119 Carbon monoxide and
than 25% alcohol Sulphuric acid Hydrogen mixture, compressed
Page 56 Page 57
2600 119 Hydrogen and Carbon 2615 127 Ethyl propyl ether 2657 153 Selenium disulphide 2680 154 Lithium hydroxide, solid
monoxide mixture, compressed 2616 129 Triisopropyl borate 2659 151 Sodium chloroacetate 2681 154 Caesium hydroxide, solution
2601 115 Cyclobutane 2617 129 Methylcyclohexanols 2660 153 Mononitrotoluidines 2681 154 Cesium hydroxide, solution
2602 126 Dichlorodifluoromethane and 2618 130P Vinyltoluenes, stabilized 2660 153 Nitrotoluidines (mono) 2682 157 Caesium hydroxide
Difluoroethane azeotropic 2619 132 Benzyldimethylamine
mixture with approximately 2661 153 Hexachloroacetone 2682 157 Cesium hydroxide
74% Dichlorodifluoromethane 2620 130 Amyl butyrates 2662 153 Hydroquinone 2683 132 Ammonium sulfide, solution
2602 126 Difluoroethane and 2621 127 Acetyl methyl carbinol
2662 153 Hydroquinone, solid 2683 132 Ammonium sulphide, solution
Dichlorodifluoromethane 2622 131P Glycidaldehyde
2664 160 Dibromomethane 2684 132 3-Diethylaminopropylamine
azeotropic mixture with 2623 133 Firelighters, solid, with
approximately 74% flammable liquid 2667 152 Butyltoluenes 2684 132 Diethylaminopropylamine
Dichlorodifluoromethane 2624 138 Magnesium silicide 2668 131 Chloroacetonitrile 2685 132 N,N-Diethylethylenediamine
2602 126 Refrigerant gas R-12 and 2626 140 Chloric acid, aqueous 2669 152 Chlorocresols 2686 132 2-Diethylaminoethanol
Refrigerant gas R-152a solution, with not more than 2669 152 Chlorocresols, liquid 2686 132 Diethylaminoethanol
azeotropic mixture with 74% 10% Chloric acid 2669 152 Chlorocresols, solid 2687 133 Dicyclohexylammonium
Refrigerant gas R-12 2627 140 Nitrites, inorganic, n.o.s.
2669 152 Chlorocresols, solution nitrite
2602 126 Refrigerant gas R-152a and 2628 151 Potassium fluoroacetate
Refrigerant gas R-12 2670 157 Cyanuric chloride 2688 159 1-Bromo-3-chloropropane
azeotropic mixture with 74% 2629 151 Sodium fluoroacetate 2688 159 1-Chloro-3-bromopropane
2671 153 Aminopyridines
Refrigerant gas R-12 2630 151 Selenates 2689 153 Glycerol
2672 154 Ammonia, solution, with
2602 126 Refrigerant gas R-500 2630 151 Selenites alphamonochlorohydrin
morethan 10% but not more
(azeotropic mixture of 2642 154 Fluoroacetic acid than 35% Ammonia 2690 152 N,n-Butylimidazole
Refrigerant gas R-12 and 2643 155 Methyl bromoacetate 2672 154 Ammonium hydroxide 2691 137 Phosphorus pentabromide
Refrigerant gas R-152a with 2644 151 Methyl iodide
approximately 74% 2672 154 Ammonium hydroxide, with 2692 157 Boron tribromide
Refrigerant gas R-12) 2645 153 Phenacyl bromide more than 10% but not more 2693 154 Bisulfites, aqueous solution, n.o.s.
2603 131 Cycloheptatriene 2646 151 Hexachlorocyclopentadiene than 35% Ammonia
2693 154 Bisulfites, inorganic, aqueous
2604 132 Boron trifluoride diethyl 2647 153 Malononitrile 2673 151 2-Amino-4-chlorophenol solution, n.o.s.
etherate 2648 154 1,2-Dibromobutan-3-one 2674 154 Sodium fluorosilicate 2693 154 Bisulphites, aqueous solution, n.o.s.
2605 155 Methoxymethyl isocyanate 2649 153 1,3-Dichloroacetone 2674 154 Sodium silicofluoride 2693 154 Bisulphites, inorganic,
2606 155 Methyl orthosilicate 2650 153 1,1-Dichloro-1-nitroethane 2676 119 Stibine aqueous solution, n.o.s.
2607 129P Acrolein dimer, stabilized 2651 153 4,4'-Diaminodiphenylmethane
2677 154 Rubidium hydroxide, solution 2698 156 Tetrahydrophthalic anhydrides
2608 129 Nitropropanes 2653 156 Benzyl iodide
2678 154 Rubidium hydroxide 2699 154 Trifluoroacetic acid
2609 156 Triallyl borate 2655 151 Potassium fluorosilicate
2678 154 Rubidium hydroxide, solid 2705 153P 1-Pentol
2610 132 Triallylamine 2655 151 Potassium silicofluoride
2679 154 Lithium hydroxide, solution 2707 127 Dimethyldioxanes
2611 131 Propylene chlorohydrin 2656 154 Quinoline
2680 154 Lithium hydroxide 2709 128 Butylbenzenes
2612 127 Methyl propyl ether 2657 153 Selenium disulfide
2680 154 Lithium hydroxide, monohydrate 2710 128 Dipropyl ketone
2614 129 Methallyl alcohol
Page 58 Page 59
2713 153 Acridine 2734 132 Polyamines, liquid, corrosive, 2757 151 Carbamate pesticide, solid, 2772 131 Dithiocarbamate pesticide,
2714 133 Zinc resinate flammable, n.o.s. poisonous liquid, flammable, toxic
2715 133 Aluminum resinate 2735 153 Alkylamines, n.o.s. 2757 151 Carbamate pesticide, solid, toxic 2772 131 Thiocarbamate pesticide,
2735 153 Amines, liquid, corrosive, n.o.s. 2758 131 Carbamate pesticide, liquid, liquid, flammable, poisonous
2716 153 1,4-Butynediol
flammable, poisonous 2772 131 Thiocarbamate pesticide,
2717 133 Camphor 2735 153 Polyalkylamines, n.o.s.
2758 131 Carbamate pesticide, liquid, liquid, flammable, toxic
2717 133 Camphor, synthetic 2735 153 Polyamines, liquid, corrosive, flammable, toxic 2775 151 Copper based pesticide, solid,
n.o.s. poisonous
2719 141 Barium bromate 2759 151 Arsenical pesticide, solid,
2738 153 N-Butylaniline poisonous 2775 151 Copper based pesticide, solid,
2720 141 Chromium nitrate
2739 156 Butyric anhydride 2759 151 Arsenical pesticide, solid, toxic toxic
2721 141 Copper chlorate
2740 155 n-Propyl chloroformate 2760 131 Arsenical pesticide, liquid, 2776 131 Copper based pesticide,
2722 140 Lithium nitrate flammable, poisonous liquid, flammable, poisonous
2741 141 Barium hypochlorite, with more
2723 140 Magnesium chlorate 2760 131 Arsenical pesticide, liquid, 2776 131 Copper based pesticide,
than 22% available Chlorine
2724 140 Manganese nitrate flammable, toxic liquid, flammable, toxic
2742 155 sec-Butyl chloroformate
2725 140 Nickel nitrate 2761 151 Organochlorine pesticide, 2777 151 Mercury based pesticide,
2742 155 Chloroformates, n.o.s. solid, poisonous solid, poisonous
2726 140 Nickel nitrite
2742 155 Chloroformates, poisonous, 2761 151 Organochlorine pesticide, 2777 151 Mercury based pesticide,
2727 141 Thallium nitrate corrosive, flammable, n.o.s. solid, toxic
solid, toxic
2728 140 Zirconium nitrate 2742 155 Chloroformates, toxic, 2762 131 Organochlorine pesticide, 2778 131 Mercury based pesticide,
2729 152 Hexachlorobenzene corrosive, flammable, n.o.s. liquid, flammable, poisonous liquid, flammable, poisonous
2730 152 Nitroanisoles 2742 155 Isobutyl chloroformate 2762 131 Organochlorine pesticide, 2778 131 Mercury based pesticide,
liquid, flammable, toxic liquid, flammable, toxic
2730 152 Nitroanisoles, liquid 2743 155 n-Butyl chloroformate
2763 151 Triazine pesticide, solid, 2779 153 Substituted nitrophenol
2730 152 Nitroanisoles, solid 2744 155 Cyclobutyl chloroformate
poisonous pesticide, solid, poisonous
2732 152 Nitrobromobenzenes 2745 157 Chloromethyl chloroformate 2763 151 Triazine pesticide, solid, toxic 2779 153 Substituted nitrophenol
2732 152 Nitrobromobenzenes, liquid 2746 156 Phenyl chloroformate 2764 131 Triazine pesticide, liquid, pesticide, solid, toxic
2732 152 Nitrobromobenzenes, solid 2747 156 tert-Butylcyclohexyl flammable, poisonous 2780 131 Substituted nitrophenol
chloroformate 2764 131 Triazine pesticide, liquid, pesticide, liquid, flammable,
2733 132 Alkylamines, n.o.s.
2748 156 2-Ethylhexyl chloroformate flammable, toxic poisonous
2733 132 Amines, flammable, corrosive,
2771 151 Dithiocarbamate pesticide, 2780 131 Substituted nitrophenol
n.o.s. 2749 130 Tetramethylsilane
solid, poisonous pesticide, liquid, flammable,
2733 132 Polyalkylamines, n.o.s. 2750 153 1,3-Dichloropropanol-2 toxic
2771 151 Dithiocarbamate pesticide,
2733 132 Polyamines, flammable, 2751 155 Diethylthiophosphoryl chloride solid, toxic 2781 151 Bipyridilium pesticide, solid,
corrosive, n.o.s. 2752 127 1,2-Epoxy-3-ethoxypropane 2771 151 Thiocarbamate pesticide, poisonous
2734 132 Alkylamines, n.o.s. 2753 153 N-Ethylbenzyltoluidines solid, poisonous 2781 151 Bipyridilium pesticide, solid,
2734 132 Amines, liquid, corrosive, 2771 151 Thiocarbamate pesticide, toxic
2753 153 N-Ethylbenzyltoluidines, liquid
flammable, n.o.s. solid, toxic 2782 131 Bipyridilium pesticide, liquid,
2753 153 N-Ethylbenzyltoluidines, solid flammable, poisonous
2734 132 Polyalkylamines, n.o.s. 2772 131 Dithiocarbamate pesticide,
2754 153 N-Ethyltoluidines liquid, flammable, poisonous
Page 60 Page 61
2782 131 Bipyridilium pesticide, liquid, 2797 154 Battery fluid, alkali, with 2810 153 HN-1 2811 154 Poisonous solid, organic, n.o.s.
flammable, toxic electronic equipment or 2810 153 HN-2 2811 154 Toxic solid, organic, n.o.s.
2783 152 Organophosphorus pesticide, actuating device
2810 153 HN-3 2812 154 Sodium aluminate, solid
solid, poisonous 2798 137 Benzene phosphorus dichloride
2810 153 L (Lewisite) 2813 138 Water-reactive solid, n.o.s.
2783 152 Organophosphorus pesticide, 2798 137 Phenylphosphorus dichloride
solid, toxic 2810 153 Lewisite 2814 158 Infectious substance, affecting
2799 137 Benzene phosphorus
2810 153 Mustard humans
2784 131 Organophosphorus pesticide, thiodichloride
liquid, flammable, poisonous 2799 137 Phenylphosphorus 2810 153 Mustard Lewisite 2815 153 N-Aminoethylpiperazine
2784 131 Organophosphorus pesticide, thiodichloride 2810 153 Poisonous liquid, n.o.s. 2817 154 Ammonium bifluoride,
liquid, flammable, toxic 2800 154 Batteries, wet, non-spillable solution
2810 153 Poisonous liquid, n.o.s.
2785 152 4-Thiapentanal 2801 154 Dye, liquid, corrosive, n.o.s. (Inhalation Hazard Zone A) 2817 154 Ammonium
2785 152 Thia-4-pentanal hydrogendifluoride, solution
2801 154 Dye intermediate, liquid, 2810 153 Poisonous liquid, n.o.s.
2786 153 Organotin pesticide, solid, corrosive, n.o.s. (Inhalation Hazard Zone B) 2817 154 Ammonium hydrogen
poisonous 2802 154 Copper chloride fluoride, solution
2810 153 Poisonous liquid, organic, n.o.s.
2786 153 Organotin pesticide, solid, toxic 2803 172 Gallium 2818 154 Ammonium polysulfide,
2810 153 Poisonous liquid, organic, n.o.s. solution
2787 131 Organotin pesticide, liquid, 2805 138 Lithium hydride, fused solid (Inhalation Hazard Zone A)
flammable, poisonous 2818 154 Ammonium polysulphide,
2806 138 Lithium nitride 2810 153 Poisonous liquid, organic, n.o.s.
2787 131 Organotin pesticide, liquid, solution
2807 171 Magnetized material (Inhalation Hazard Zone B)
flammable, toxic 2819 153 Amyl acid phosphate
2809 172 Mercury 2810 153 Sarin
2788 153 Organotin compound, liquid, n.o.s. 2820 153 Butyric acid
2809 172 Mercury metal 2810 153 Soman
2789 132 Acetic acid, glacial 2821 153 Phenol solution
2810 153 Buzz 2810 153 Tabun
2789 132 Acetic acid, solution, more than 2822 153 2-Chloropyridine
80% acid 2810 153 BZ 2810 153 Thickened GD
2810 153 Compound, tree or weed 2823 153 Crotonic acid
2790 153 Acetic acid, solution, more than 2810 153 Toxic liquid, n.o.s.
10% but not more than 80% acid killing, liquid (toxic) 2823 153 Crotonic acid, liquid
2810 153 Toxic liquid, n.o.s. (Inhalation
2793 170 Ferrous metal borings, 2810 153 CS 2823 153 Crotonic acid, solid
Hazard Zone A)
shavings, turnings or cuttings 2810 153 DC 2826 155 Ethyl chlorothioformate
2810 153 Toxic liquid, n.o.s. (Inhalation
2794 154 Batteries, wet, filled with acid 2810 153 GA Hazard Zone B) 2829 153 Caproic acid
2795 154 Batteries, wet, filled with alkali 2810 153 GB 2810 153 Toxic liquid, organic, n.o.s. 2829 153 Hexanoic acid
2796 157 Battery fluid, acid 2810 153 GD
2810 153 Toxic liquid, organic, n.o.s. 2830 139 Lithium ferrosilicon
2796 157 Sulfuric acid, with not more 2810 153 GF (Inhalation Hazard Zone A) 2831 160 1,1,1-Trichloroethane
than 51% acid 2810 153 H 2810 153 Toxic liquid, organic, n.o.s. 2834 154 Phosphorous acid
2796 157 Sulphuric acid, with not more 2810 153 HD (Inhalation Hazard Zone B)
than 51% acid 2834 154 Phosphorous acid, ortho
2810 153 HL 2810 153 VX
2797 154 Battery fluid, alkali 2835 138 Sodium aluminum hydride
2811 154 CX
2797 154 Battery fluid, alkali, with battery 2837 154 Bisulfates, aqueous solution
Page 62 Page 63
2837 154 Bisulphates, aqueous solution 2856 151 Fluorosilicates, n.o.s. 2880 140 Calcium hypochlorite, hydrated, 2910 161 Radioactive material, excepted
2837 154 Sodium bisulfate, solution 2856 151 Silicofluorides, n.o.s. with not less than 5.5% but not package, empty packaging
more than 16% water 2910 161 Radioactive material,
2837 154 Sodium bisulphate, solution 2857 126 Refrigerating machines,
containing Ammonia solutions 2880 140 Calcium hypochlorite, excepted package,
2837 154 Sodium hydrogen sulfate,
(UN2672) hydrated mixture, with not instruments or articles
solution
less than 5.5% but not more 2910 161 Radioactive material,
2837 154 Sodium hydrogen sulphate, 2857 126 Refrigerating machines,
than 16% water excepted package, limited
solution containing non-flammable,
non-poisonous gases 2881 135 Metal catalyst, dry quantity of material
2838 129P Vinyl butyrate, stabilized
2857 126 Refrigerating machines, 2881 135 Nickel catalyst, dry 2911 161 Radioactive material,
2839 153 Aldol excepted package,
containing non-flammable, 2900 158 Infectious substance, affecting
2840 129 Butyraldoxime non-toxic gases animals only instruments or articles
2841 131 Di-n-amylamine 2858 170 Zirconium, dry, coiled wire, 2901 124 Bromine chloride 2912 162 Radioactive material, low
2842 129 Nitroethane finished metal sheets or strips specific activity (LSA), n.o.s.
2902 151 Pesticide, liquid, poisonous, n.o.s.
2844 138 Calcium manganese silicon 2859 154 Ammonium metavanadate 2912 162 Radioactive material, low
2902 151 Pesticide, liquid, toxic, n.o.s.
specific activity (LSA-I), non
2845 135 Ethyl phosphonous dichloride, 2861 151 Ammonium polyvanadate 2903 131 Pesticide, liquid, poisonous, fissile or fissile-excepted
anhydrous 2862 151 Vanadium pentoxide flammable, n.o.s.
2913 162 Radioactive material, surface
2845 135 Methyl phosphonous 2863 154 Sodium ammonium vanadate 2903 131 Pesticide, liquid, toxic, contaminated objects (SCO)
dichloride flammable, n.o.s.
2864 151 Potassium metavanadate 2913 162 Radioactive material, surface
2845 135 Pyrophoric liquid, n.o.s. 2904 154 Chlorophenates, liquid
2865 154 Hydroxylamine sulfate contaminated objects (SCO-I),
2845 135 Pyrophoric liquid, organic, n.o.s. 2904 154 Chlorophenolates, liquid non fissile or fissileexcepted
2865 154 Hydroxylamine sulphate
2846 135 Pyrophoric solid, n.o.s. 2904 154 Phenolates, liquid 2913 162 Radioactive material, surface
2869 157 Titanium trichloride mixture
2846 135 Pyrophoric solid, organic, n.o.s. 2905 154 Chlorophenates, solid contaminated objects (SCOII),
2870 135 Aluminum borohydride
2849 153 3-Chloropropanol-1 non fissile or fissileexcepted
2870 135 Aluminum borohydride in 2905 154 Chlorophenolates, solid
2850 128 Propylene tetramer 2915 163 Radioactive material, Type A
devices 2905 154 Phenolates, solid
package non-special form,
2851 157 Boron trifluoride, dihydrate 2871 170 Antimony powder 2907 133 Isosorbide dinitrate mixture non fissile or fissile-excepted
2852 113 Dipicryl sulfide, wetted with 2872 159 Dibromochloropropanes 2908 161 Radioactive material, excepted 2916 163 Radioactive material, Type
not less than 10% water package, empty packaging
2873 153 Dibutylaminoethanol B(U) package, non fissile or
2852 113 Dipicryl sulphide, wetted with 2909 161 Radioactive material, excepted fissile-excepted
2874 153 Furfuryl alcohol
not less than 10% water package, articles manufactured
2875 151 Hexachlorophene 2917 163 Radioactive material, Type
2853 151 Magnesium fluorosilicate from depleted Uranium B(M) package, non fissile or
2876 153 Resorcinol
2853 151 Magnesium silicofluoride 2909 161 Radioactive material, excepted fissile-excepted
2878 170 Titanium sponge granules package, articles manufactured
2854 151 Ammonium fluorosilicate 2918 165 Radioactive material, fissile, n.o.s.
2878 170 Titanium sponge powders from natural Thorium
2854 151 Ammonium silicofluoride 2919 163 Radioactive material,
2879 157 Selenium oxychloride 2909 161 Radioactive material, excepted transported under special
2855 151 Zinc fluorosilicate
package, articles manufactured arrangement, non fissile or
2855 151 Zinc silicofluoride from natural Uranium fissile-excepted
Page 64 Page 65
2920 132 Corrosive liquid, flammable, 2927 154 Poisonous liquid, corrosive, 2929 131 Toxic liquid, flammable, n.o.s. 2949 154 Sodium hydrosulfide, with not less
n.o.s. organic, n.o.s. (Inhalation (Inhalation Hazard Zone B) than 25% water of crystallization
2921 134 Corrosive solid, flammable, Hazard Zone B) 2929 131 Toxic liquid, flammable, 2949 154 Sodium hydrosulphide, with
n.o.s. 2927 154 Toxic liquid, corrosive, n.o.s. organic, n.o.s. not less than 25% water of
2922 154 Corrosive liquid, poisonous, 2927 154 Toxic liquid, corrosive, n.o.s. 2929 131 Toxic liquid, flammable, crystallization
n.o.s. (Inhalation Hazard Zone A) organic, n.o.s. (Inhalation 2950 138 Magnesium granules, coated
2922 154 Corrosive liquid, toxic, n.o.s. 2927 154 Toxic liquid, corrosive, n.o.s. Hazard Zone A) 2956 149 5-tert-Butyl-2,4,6-trinitrom-
2923 154 Corrosive solid, poisonous, (Inhalation Hazard Zone B) 2929 131 Toxic liquid, flammable, xylene
n.o.s. 2927 154 Toxic liquid, corrosive, organic, n.o.s. (Inhalation 2956 149 Musk xylene
organic, n.o.s. Hazard Zone B)
2923 154 Corrosive solid, toxic, n.o.s. 2965 139 Boron trifluoride dimethyl
2927 154 Toxic liquid, corrosive, 2930 134 Poisonous solid, flammable, n.o.s. etherate
2924 132 Flammable liquid, corrosive,
n.o.s organic, n.o.s. (Inhalation 2930 134 Poisonous solid, flammable, 2966 153 Thioglycol
Hazard Zone A) organic, n.o.s.
2925 134 Flammable solid, corrosive, 2967 154 Sulfamic acid
n.o.s. 2927 154 Toxic liquid, corrosive, 2930 134 Toxic solid, flammable, n.o.s.
2967 154 Sulphamic acid
organic, n.o.s. (Inhalation 2930 134 Toxic solid, flammable,
2925 134 Flammable solid, corrosive, 2968 135 Maneb, stabilized
Hazard Zone B) organic, n.o.s.
organic, n.o.s.
2928 154 Poisonous solid, corrosive, 2968 135 Maneb preparation, stabilized
2926 134 Flammable solid, poisonous, 2931 151 Vanadyl sulfate
n.o.s. 2969 171 Castor beans, meal, pomace
n.o.s. 2931 151 Vanadyl sulphate
2928 154 Toxic solid, corrosive, organic, or flake
2926 134 Flammable solid, poisonous, 2933 129 Methyl 2-chloropropionate
n.o.s. 2974 164 Radioactive material, special
organic, n.o.s. 2934 129 Isopropyl 2-chloropropionate
2929 131 Poisonous liquid, flammable, form, n.o.s.
2926 134 Flammable solid, toxic, 2935 129 Ethyl 2-chloropropionate
n.o.s. 2975 162 Thorium metal, pyrophoric
organic, n.o.s.
2929 131 Poisonous liquid, flammable, 2936 153 Thiolactic acid 2976 162 Thorium nitrate, solid
2927 154 Ethyl phosphonothioic
n.o.s. (Inhalation Hazard Zone A) 2937 153 alpha-Methylbenzyl alcohol 2977 166 Radioactive material, Uranium
dichloride, anhydrous
2929 131 Poisonous liquid, flammable, 2937 153 alpha-Methylbenzyl alcohol, liquid hexafluoride, fissile
2927 154 Ethyl phosphorodichloridate
n.o.s. (Inhalation Hazard Zone B) 2937 153 Methylbenzyl alcohol (alpha) 2977 166 Uranium hexafluoride, fissile
2927 154 Poisonous liquid, corrosive,
2929 131 Poisonous liquid, flammable, 2940 135 Cyclooctadiene phosphines containing more than 1%
n.o.s.
organic, n.o.s. Uranium-235
2927 154 Poisonous liquid, corrosive, 2940 135 9-Phosphabicyclononanes
2929 131 Poisonous liquid, flammable, 2978 166 Radioactive material, Uranium
n.o.s. (Inhalation Hazard Zone A) 2941 153 Fluoroanilines
organic, n.o.s. (Inhalation hexafluoride
2927 154 Poisonous liquid, corrosive, Hazard Zone A) 2942 153 2-Trifluoromethylaniline
2978 166 Uranium hexafluoride
n.o.s. (Inhalation Hazard Zone B) 2943 129 Tetrahydrofurfurylamine
2929 131 Poisonous liquid, flammable, 2978 166 Uranium hexafluoride, non
2927 154 Poisonous liquid, corrosive, organic, n.o.s. (Inhalation 2945 132 N-Methylbutylamine fissile or fissile-excepted
organic, n.o.s. Hazard Zone B) 2946 153 2-Amino-5- 2979 162 Uranium metal, pyrophoric
2927 154 Poisonous liquid, corrosive, 2929 131 Toxic liquid, flammable, n.o.s. diethylaminopentane
organic, n.o.s. (Inhalation 2980 162 Uranyl nitrate, hexahydrate,
2929 131 Toxic liquid, flammable, n.o.s. 2947 155 Isopropyl chloroacetate solution
Hazard Zone A)
(Inhalation Hazard Zone A) 2948 153 3-Trifluoromethylaniline
Page 66 Page 67
2981 162 Uranyl nitrate, solid 2994 151 Arsenical pesticide, liquid, poisonous 3009 131 Copper based pesticide, 3018 152 Organophosphorus pesticide,
2982 163 Radioactive material, n.o.s. 2994 151 Arsenical pesticide, liquid, toxic liquid, poisonous, flammable liquid, toxic
2983 129P Ethylene oxide and Propylene 2995 131 Organochlorine pesticide, 3009 131 Copper based pesticide, 3019 131 Organotin pesticide, liquid,
oxide mixture, with not more liquid, poisonous, flammable liquid, toxic, flammable poisonous, flammable
than 30% Ethylene oxide 2995 131 Organochlorine pesticide, 3010 151 Copper based pesticide, 3019 131 Organotin pesticide, liquid,
2983 129P Propylene oxide and Ethylene liquid, toxic, flammable liquid, poisonous toxic, flammable
oxide mixture, with not more 3010 151 Copper based pesticide, 3020 153 Organotin pesticide, liquid,
2996 151 Organochlorine pesticide,
than 30% Ethylene oxide liquid, toxic poisonous
liquid, poisonous
2984 140 Hydrogen peroxide, aqueous 3011 131 Mercury based pesticide, 3020 153 Organotin pesticide, liquid, toxic
2996 151 Organochlorine pesticide,
solution, with not less than 8% liquid, poisonous, flammable 3021 131 Pesticide, liquid, flammable,
liquid, toxic
but less than 20% Hydrogen 3011 131 Mercury based pesticide, poisonous, n.o.s.
2997 131 Triazine pesticide, liquid, liquid, toxic, flammable
peroxide 3021 131 Pesticide, liquid, flammable,
poisonous, flammable
2985 155 Chlorosilanes, flammable, 3012 151 Mercury based pesticide, toxic, n.o.s.
2997 131 Triazine pesticide, liquid, toxic, liquid, poisonous 3022 127P 1,2-Butylene oxide, stabilized
corrosive, n.o.s.
flammable 3012 151 Mercury based pesticide,
2985 155 Chlorosilanes, n.o.s. 3023 131 2-Methyl-2-heptanethiol
2998 151 Triazine pesticide, liquid, liquid, toxic
2986 155 Chlorosilanes, corrosive, 3023 131 tert-Octyl mercaptan
poisonous 3013 131 Substituted nitrophenol
flammable, n.o.s. 3024 131 Coumarin derivative pesticide,
2998 151 Triazine pesticide, liquid, toxic pesticide, liquid, poisonous, liquid, flammable, poisonous
2986 155 Chlorosilanes, n.o.s. flammable
3002 151 Phenyl urea pesticide, liquid, 3024 131 Coumarin derivative pesticide,
2987 156 Chlorosilanes, corrosive, n.o.s. poisonous 3013 131 Substituted nitrophenol liquid, flammable, toxic
2987 156 Chlorosilanes, n.o.s. 3002 151 Phenyl urea pesticide, liquid, toxic pesticide, liquid, toxic, 3025 131 Coumarin derivative pesticide,
2988 139 Chlorosilanes, n.o.s. flammable liquid, poisonous, flammable
2988 139 Chlorosilanes, water-reactive, liquid, poisonous, flammable 3014 153 Substituted nitrophenol 3025 131 Coumarin derivative pesticide,
flammable, corrosive, n.o.s. pesticide, liquid, poisonous liquid, toxic, flammable
3014 153 Substituted nitrophenol 3026 151 Coumarin derivative pesticide,
2989 133 Lead phosphite, dibasic liquid, toxic, flammable
pesticide, liquid, toxic liquid, poisonous
2990 171 Life-saving appliances, 3005 131 Thiocarbamate pesticide, liquid,
3015 131 Bipyridilium pesticide, liquid, 3026 151 Coumarin derivative pesticide,
selfinflating poisonous, flammable
poisonous, flammable liquid, toxic
2991 131 Carbamate pesticide, liquid, 3005 131 Thiocarbamate pesticide, liquid, 3015 131 Bipyridilium pesticide, liquid,
poisonous, flammable toxic, flammable 3027 151 Coumarin derivative pesticide,
toxic, flammable solid, poisonous
2991 131 Carbamate pesticide, liquid, 3006 151 Dithiocarbamate pesticide, 3016 151 Bipyridilium pesticide, liquid,
toxic, flammable liquid, poisonous 3027 151 Coumarin derivative pesticide,
poisonous solid, toxic
2992 151 Carbamate pesticide, liquid, 3006 151 Dithiocarbamate pesticide, 3016 151 Bipyridilium pesticide, liquid, toxic
poisonous liquid, toxic 3028 154 Batteries, dry, containing
3017 131 Organophosphorus pesticide, Potassium hydroxide solid
2992 151 Carbamate pesticide, liquid, toxic 3006 151 Thiocarbamate pesticide, liquid, liquid, poisonous, flammable 3048 157 Aluminum phosphide
2993 131 Arsenical pesticide, liquid, poisonous 3017 131 Organophosphorus pesticide, pesticide
poisonous, flammable 3006 151 Thiocarbamate pesticide, liquid, toxic liquid, toxic, flammable 3049 138 Metal alkyl halides,
2993 131 Arsenical pesticide, liquid, toxic, 3018 152 Organophosphorus pesticide, waterreactive, n.o.s.
flammable liquid, poisonous
Page 68 Page 69
3049 138 Metal aryl halides, 3071 131 Mercaptan mixture, liquid, 3082 171 Other regulated substances, 3094 138 Corrosive liquid, which in
waterreactive, n.o.s. poisonous, flammable, n.o.s. liquid, n.o.s. contact with water emits
3050 138 Metal alkyl hydrides, 3071 131 Mercaptan mixture, liquid, 3083 124 Perchloryl fluoride flammable gases, n.o.s.
waterreactive, n.o.s. toxic, flammable, n.o.s. 3095 136 Corrosive solid, self-heating,
3084 140 Corrosive solid, oxidizing, n.o.s.
3050 138 Metal aryl hydrides, 3071 131 Mercaptans, liquid, poisonous, n.o.s.
waterreactive, n.o.s. flammable, n.o.s. 3085 140 Oxidizing solid, corrosive, n.o.s.
3096 138 Corrosive solid, water-
3051 135 Aluminum alkyls 3071 131 Mercaptans, liquid, toxic, 3086 141 Poisonous solid, oxidizing, n.o.s. reactive, n.o.s.
3052 135 Aluminum alkyl halides flammable, n.o.s. 3086 141 Toxic solid, oxidizing, n.o.s. 3096 138 Corrosive solid, which in
3052 135 Aluminum alkyl halides, liquid 3072 171 Life-saving appliances, not 3087 141 Oxidizing solid, poisonous, n.o.s. contact with water emits
3052 135 Aluminum alkyl halides, solid self-inflating flammable gases, n.o.s.
3087 141 Oxidizing solid, toxic, n.o.s.
3053 135 Magnesium alkyls 3073 131P Vinylpyridines, stabilized 3097 140 Flammable solid, oxidizing, n.o.s.
3076 138 Aluminum alkyl hydrides 3088 135 Self-heating solid,
3054 129 Cyclohexanethiol organic,n.o.s. 3098 140 Oxidizing liquid, corrosive, n.o.s.
3054 129 Cyclohexyl mercaptan 3077 171 Environmentally hazardous
substances, solid, n.o.s. 3089 170 Metal powder, flammable, n.o.s. 3099 142 Oxidizing liquid, poisonous, n.o.s.
3055 154 2-(2-Aminoethoxy)ethanol
3077 171 Hazardous waste, solid, n.o.s. 3090 138 Lithium batteries 3099 142 Oxidizing liquid, toxic, n.o.s.
3056 129 n-Heptaldehyde
3077 171 Other regulated substances, 3090 138 Lithium batteries, liquid or 3100 135 Oxidizing solid, self-heating, n.o.s.
3057 125 Trifluoroacetyl chloride solid, n.o.s. solid cathode 3101 146 Organic peroxide type B, liquid
3064 127 Nitroglycerin, solution in alcohol, 3078 138 Cerium, turnings or gritty
with more than 1% but not more 3090 138 Lithium metal batteries 3102 146 Organic peroxide type B, solid
powder (including lithium alloy
than 5% Nitroglycerin 3103 146 Organic peroxide type C, liquid
3079 131P Methacrylonitrile, stabilized batteries)
3065 127 Alcoholic beverages 3104 146 Organic peroxide type C, solid
3080 155 Isocyanate solution, 3091 138 Lithium batteries contained in
3066 153 Paint (corrosive) poisonous, flammable, n.o.s. equipment 3105 145 Organic peroxide type D, liquid
3066 153 Paint related material (corrosive) 3080 155 Isocyanate solution, toxic, 3091 138 Lithium batteries packed with 3106 145 Organic peroxide type D, solid
3070 126 Dichlorodifluoromethane and flammable, n.o.s. equipment 3107 145 Organic peroxide type E, liquid
Ethylene oxide mixture, with 3080 155 Isocyanate solutions, n.o.s.
not more than 12.5% Ethylene 3091 138 Lithium metal batteries 3108 145 Organic peroxide type E, solid
oxide 3080 155 Isocyanates, n.o.s. contained in equipment
3080 155 Isocyanates, poisonous, (including lithium alloy 3109 145 Organic peroxide type F, liquid
3070 126 Dichlorodifluoromethane and
Ethylene oxide mixtures, with not flammable, n.o.s. batteries) 3110 145 Organic peroxide type F, solid
more than 12% Ethylene oxide 3080 155 Isocyanates, toxic, flammable, 3091 138 Lithium metal batteries 3111 148 Organic peroxide type B,
3070 126 Ethylene oxide and n.o.s. packed with equipment liquid, temperature controlled
Dichlorodifluoromethane 3082 171 Environmentally hazardous (including lithium alloy 3112 148 Organic peroxide type B, solid,
mixture, with not more than substances, liquid, n.o.s. batteries) temperature controlled
12.5% Ethylene oxide 3082 171 Hazardous waste, liquid, n.o.s. 3092 129 1-Methoxy-2-propanol 3113 148 Organic peroxide type C,
3070 126 Ethylene oxide and 3093 140 Corrosive liquid, oxidizing, n.o.s. liquid, temperature controlled
Dichlorodifluoromethane
mixtures, with not more than 3094 138 Corrosive liquid, 3114 148 Organic peroxide type C, solid,
12% Ethylene oxide waterreactive, n.o.s. temperature controlled
Page 70 Page 71
3115 148 Organic peroxide type D, liquid, 3123 139 Poisonous liquid, which in\ 3127 135 Self-heating solid, oxidizing, n.o.s. 3138 115 Propylene, Ethylene and
temperature controlled contact with water emits\ 3128 136 Self-heating solid, poisonous, Acetylene in mixture,
3116 148 Organic peroxide type D, solid, flammable gases, n.o.s. organic, n.o.s. refrigerated liquid containing
temperature controlled (Inhalation Hazard Zone B) 3128 136 Self-heating solid, toxic, at least 71.5% Ethylene with
3123 139 Toxic liquid, water-reactive, n.o.s. organic, n.o.s. not more than 22.5%
3117 148 Organic peroxide type E, liquid,
Acetylene and not more than
temperature controlled 3123 139 Toxic liquid, water-reactive, 3129 138 Water-reactive liquid,
6% Propylene
3118 148 Organic peroxide type E, solid, n.o.s. (Inhalation Hazard Zone A) corrosive, n.o.s.
3139 140 Oxidizing liquid, n.o.s.
temperature controlled 3123 139 Toxic liquid, water-reactive, 3130 139 Water-reactive liquid,
poisonous, n.o.s. 3140 151 Alkaloids, liquid, n.o.s.
3119 148 Organic peroxide type F, liquid, n.o.s. (Inhalation Hazard Zone B)
(poisonous)
temperature controlled 3123 139 Toxic liquid, which in contact 3130 139 Water-reactive liquid, toxic, n.o.s.
3140 151 Alkaloid salts, liquid, n.o.s.
3120 1 48 Organic peroxide type F, with water emits flammable 3131 138 Water-reactive solid,
(poisonous)
solid, temperature controlled gases, n.o.s. corrosive, n.o.s.
3141 157 Antimony compound,
3121 144 Oxidizing solid, water-reactive, 3123 139 Toxic liquid, which in contact 3132 138 Water-reactive solid,
inorganic, liquid, n.o.s.
n.o.s. with water emits flammable flammable, n.o.s.
gases, n.o.s. (Inhalation Hazard 3142 151 Disinfectant, liquid,
3122 142 Poisonous liquid, oxidizing, n.o.s. 3133 138 Water-reactive solid,
Zone A) poisonous, n.o.s.
oxidizing, n.o.s.
3122 142 Poisonous liquid, oxidizing, n.o.s. 3142 151 Disinfectant, liquid, toxic, n.o.s.
3123 139 Toxic liquid, which in contact 3134 139 Water-reactive solid,
(Inhalation Hazard Zone A) 3142 151 Disinfectants, liquid, n.o.s.
with water emits flammable poisonous, n.o.s.
3122 142 Poisonous liquid, oxidizing, n.o.s. gases, n.o.s. (Inhalation Hazard (poisonous)
3134 139 Water-reactive solid, toxic, n.o.s.
(Inhalation Hazard Zone B) Zone B) 3143 151 Dye, solid, poisonous, n.o.s.
3135 138 Water-reactive solid,
3122 142 Toxic liquid, oxidizing, n.o.s. 3124 136 Poisonous solid, self-heating, selfheating, n.o.s. 3143 151 Dye, solid, toxic, n.o.s.
3122 142 Toxic liquid, oxidizing, n.o.s. n.o.s. 3136 120 Trifluoromethane, 3143 151 Dye intermediate, solid,
(Inhalation Hazard Zone A) 3124 136 Toxic solid, self-heating, n.o.s. refrigerated liquid poisonous, n.o.s.
3122 142 Toxic liquid, oxidizing, n.o.s. 3125 139 Poisonous solid, waterreactive, 3137 140 Oxidizing solid, flammable, n.o.s. 3143 151 Dye intermediate, solid, toxic,
(Inhalation Hazard Zone B) n.o.s. n.o.s.
3138 115 Acetylene, Ethylene and
3123 139 Poisonous liquid, waterreactive, Propylene in mixture, 3144 151 Nicotine compound, liquid,
3125 139 Poisonous solid, which in
n.o.s. refrigerated liquid containing n.o.s.
contact with water emits
3123 139 Poisonous liquid, waterreactive, flammable gases, n.o.s. at least 71.5% Ethylene with 3144 151 Nicotine preparation, liquid,
n.o.s. (Inhalation Hazard Zone A) not more than 22.5% n.o.s.
3125 139 Toxic solid, water-reactive,
3123 139 Poisonous liquid, waterreactive, n.o.s. Acetylene and not more than 3145 153 Alkyl phenols, liquid, n.o.s.
n.o.s. (Inhalation Hazard Zone B) 6% Propylene (including C2-C12
3125 139 Toxic solid, which in contact homologues)
3138 115 Ethylene, Acetylene and
3123 139 Poisonous liquid, which in with water emits flammable
Propylene in mixture, 3146 153 Organotin compound, solid,
contact with water emits gases, n.o.s.
refrigerated liquid containing n.o.s.
flammable gases, n.o.s. 3126 136 Self-heating solid, corrosive, at least 71.5% Ethylene with 3147 154 Dye, solid, corrosive, n.o.s.
3123 139 Poisonous liquid, which in organic, n.o.s. not more than 22.5%
contact with water emits 3147 154 Dye intermediate, solid,
Acetylene and not more than corrosive, n.o.s.
flammable gases, n.o.s. 6% Propylene
(Inhalation Hazard Zone A) 3148 138 Water-reactive liquid, n.o.s.
Page 72 Page 73
3149 140 Hydrogen peroxide and 3160 119 Liquefied gas, poisonous, 3163 126 Liquefied gas, n.o.s. 3170 138 Aluminum dross
Peroxyacetic acid mixture, with flammable, n.o.s. (Inhalation 3164 126 Articles, pressurized, hydraulic 3170 138 Aluminum processing by-
acid(s), water and not more than Hazard Zone C) (containing non-flammable gas) products
5% Peroxyacetic acid, stabilized 3160 119 Liquefied gas, poisonous, 3164 126 Articles, pressurized, 3170 138 Aluminum remelting
3150 115 Devices, small, hydrocarbon gas flammable, n.o.s. (Inhalation pneumatic (containing byproducts
powered, with release device Hazard Zone D) nonflammable gas) 3170 138 Aluminum smelting by-
3150 115 Hydrocarbon gas refills for small 3160 119 Liquefied gas, toxic, flammable, 3165 131 Aircraft hydraulic power unit products
devices, with release device n.o.s. fuel tank 3171 154 Battery-powered equipment
3166 128 Engine, fuel cell, flammable (wet battery)
3151 171 Polyhalogenated biphenyls, 3160 119 Liquefied gas, toxic, flammable, gas powered 3171 154 Battery-powered vehicle (wet
liquid n.o.s. (Inhalation Hazard Zone A)
3166 128 Engine, fuel cell, flammable battery)
3151 171 Polyhalogenated terphenyls, 3160 119 Liquefied gas, toxic, flammable, liquid powered 3171 154 Wheelchair, electric, with
liquid n.o.s. (Inhalation Hazard Zone B) 3166 128 Engine, internal combustion batteries
3152 171 Polyhalogenated biphenyls, solid 3160 119 Liquefied gas, toxic, flammable, 3166 128 Engines, internal combustion, 3172 153 Toxins, extracted from living
n.o.s. (Inhalation Hazard Zone C) flammable gas powered sources, liquid, n.o.s.
3152 171 Polyhalogenated terphenyls,
solid 3160 119 Liquefied gas, toxic, flammable, 3166 128 Engines, internal combustion, 3172 153 Toxins, extracted from living
n.o.s. (Inhalation Hazard Zone D) flammable liquid powered sources, n.o.s.
3153 115 Perfluoromethyl vinyl ether
3166 128 Vehicle, flammable gas 3172 153 Toxins, extracted from living
3153 115 Perfluoro(methyl vinyl ether) 3161 115 Liquefied gas, flammable, n.o.s.
powered sources, solid, n.o.s.
3154 115 Perfluoroethyl vinyl ether 3162 123 Liquefied gas, poisonous, n.o.s. 3166 128 Vehicle, flammable liquid 3174 135 Titanium disulfide
3162 123 Liquefied gas, poisonous, n.o.s. powered 3174 135 Titanium disulphide
3154 115 Perfluoro(ethyl vinyl ether)
(Inhalation Hazard Zone A) 3166 128 Vehicle, fuel cell, flammable 3175 133 Solids containing flammable
3155 154 Pentachlorophenol gas powered liquid, n.o.s.
3162 123 Liquefied gas, poisonous, n.o.s.
3156 122 Compressed gas, oxidizing, n.o.s. (Inhalation Hazard Zone B) 3166 128 Vehicle, fuel cell, flammable 3176 133 Flammable solid, organic,
liquid powered molten, n.o.s.
3157 122 Liquefied gas, oxidizing, n.o.s. 3162 123 Liquefied gas, poisonous, n.o.s. 3167 115 Gas sample, non-pressurized, 3178 133 Flammable solid, inorganic,
3158 120 Gas, refrigerated liquid, n.o.s. (Inhalation Hazard Zone C) flammable, n.o.s., not n.o.s.
3159 126 Refrigerant gas R-134a 3162 123 Liquefied gas, poisonous, n.o.s. refrigerated liquid 3178 133 Smokeless powder for small
(Inhalation Hazard Zone D) 3168 119 Gas sample, non-pressurized, arms
3159 126 1,1,1,2-Tetrafluoroethane
3162 123 Liquefied gas, toxic, n.o.s. poisonous, flammable, n.o.s., 3179 134 Flammable solid, poisonous,
3160 119 Liquefied gas, poisonous, not refrigerated liquid
3162 123 Liquefied gas, toxic, n.o.s. inorganic, n.o.s.
flammable, n.o.s. 3168 119 Gas sample, non-pressurized,
(Inhalation Hazard Zone A) 3179 134 Flammable solid, toxic,
3160 119 Liquefied gas, poisonous, toxic, flammable, n.o.s., not inorganic, n.o.s.
flammable, n.o.s. (Inhalation 3162 123 Liquefied gas, toxic, n.o.s. refrigerated liquid 3180 134 Flammable solid, corrosive,
Hazard Zone A) (Inhalation Hazard Zone B) 3169 123 Gas sample, non-pressurized, inorganic, n.o.s.
3160 119 Liquefied gas, poisonous, 3162 123 Liquefied gas, toxic, n.o.s. poisonous, n.o.s., not 3180 134 Flammable solid, inorganic,
flammable, n.o.s. (Inhalation (Inhalation Hazard Zone C) refrigerated liquid corrosive, n.o.s.
Hazard Zone B) 3169 123 Gas sample, non-pressurized, 3181 133 Metal salts of organic
3162 123 Liquefied gas, toxic, n.o.s.
toxic, n.o.s., not refrigerated liquid compounds, flammable, n.o.s.
(Inhalation Hazard Zone D)
Page 74 Page 75
3182 170 Metal hydrides, flammable, n.o.s. 3206 136 Alkali metal alcoholates, 3220 126 Refrigerant gas R-125 3244 154 Solids containing corrosive
3183 135 Self-heating liquid, organic, n.o.s. selfheating, corrosive, n.o.s. 3221 149 Self-reactive liquid type B liquid, n.o.s.
3184 136 Self-heating liquid, poisonous, 3207 138 Organometallic compound, 3222 149 Self-reactive solid type B 3245 171 Genetically modified
organic, n.o.s. water-reactive, flammable, 3223 149 Self-reactive liquid type C microorganisms
n.o.s. 3224 149 Self-reactive solid type C 3245 171 Genetically modified
3184 136 Self-heating liquid, toxic,
3207 138 Organometallic compound organisms
organic, n.o.s. 3225 149 Self-reactive liquid type D
dispersion, water-reactive, 3246 156 Methanesulfonyl chloride
3185 136 Self-heating liquid, corrosive, 3226 149 Self-reactive solid type D
flammable, n.o.s. 3246 156 Methanesulphonyl chloride
organic, n.o.s. 3227 149 Self-reactive liquid type E
3207 138 Organometallic compound 3247 140 Sodium peroxoborate,
3186 135 Self-heating liquid, inorganic, n.o.s. 3228 149 Self-reactive solid type E
solution, water-reactive, anhydrous
3187 136 Self-heating liquid, poisonous, flammable, n.o.s. 3229 149 Self-reactive liquid type F
3248 131 Medicine, liquid, flammable,
inorganic, n.o.s. 3230 149 Self-reactive solid type F poisonous, n.o.s.
3208 138 Metallic substance,
3187 136 Self-heating liquid, toxic, waterreactive, n.o.s. 3231 150 Self-reactive liquid type B, 3248 131 Medicine, liquid, flammable,
inorganic, n.o.s. temperature controlled toxic, n.o.s.
3209 138 Metallic substance,
3188 136 Self-heating liquid, corrosive, 3232 150 Self-reactive solid type B, 3249 151 Medicine, solid, poisonous,
waterreactive, self-heating, n.o.s.
inorganic, n.o.s. temperature controlled n.o.s.
3210 140 Chlorates, inorganic, aqueous
3189 135 Metal powder, self-heating, n.o.s. 3233 150 Self-reactive liquid type C, 3249 151 Medicine, solid, toxic, n.o.s.
solution, n.o.s.
temperature controlled
3189 135 Self-heating metal powders, n.o.s. 3211 140 Perchlorates, inorganic, aqueous 3250 153 Chloroacetic acid, molten
3234 150 Self-reactive solid type C,
3190 135 Self-heating solid, inorganic, n.o.s. solution, n.o.s. 3251 133 Isosorbide-5-mononitrate
temperature controlled
3191 136 Self-heating solid, inorganic, 3212 140 Hypochlorites, inorganic, n.o.s. 3252 115 Difluoromethane
3235 150 Self-reactive liquid type D,
poisonous, n.o.s. 3213 140 Bromates, inorganic, aqueous temperature controlled 3252 115 Refrigerant gas R-32
3191 136 Self-heating solid, inorganic, solution, n.o.s. 3236 150 Self-reactive solid type D, 3253 154 Disodium trioxosilicate
toxic, n.o.s. 3214 140 Permanganates, inorganic, temperature controlled 3253 154 Disodium trioxosilicate,
3191 136 Self-heating solid, poisonous, aqueous solution, n.o.s. 3237 150 Self-reactive liquid type E, pentahydrate
inorganic, n.o.s. 3215 140 Persulfates, inorganic, n.o.s. temperature controlled 3254 135 Tributylphosphane
3191 136 Self-heating solid, toxic, 3238 150 Self-reactive solid type E, 3254 135 Tributylphosphine
3215 140 Persulphates, inorganic, n.o.s.
inorganic, n.o.s. temperature controlled 3255 135 tert-Butyl hypochlorite
3216 140 Persulfates, inorganic, aqueous
3192 136 Self-heating solid, corrosive, solution, n.o.s. 3239 150 Self-reactive liquid type F, 3256 128 Elevated temperature liquid,
inorganic, n.o.s. temperature controlled flammable, n.o.s., with flash
3216 140 Persulphates, inorganic, point above 37.8°C (100°F), at
3194 135 Pyrophoric liquid, inorganic, 3240 150 Self-reactive solid type F,
aqueous solution, n.o.s. or above its flash point
n.o.s. temperature controlled
3218 140 Nitrates, inorganic, aqueous 3241 133 2-Bromo-2-nitropropane-1, 3- 3256 128 Elevated temperature liquid,
3200 135 Pyrophoric solid, inorganic, n.o.s. solution, n.o.s. diol flammable, n.o.s., with flash
3203 135 Pyrophoric organometallic 3219 140 Nitrites, inorganic, aqueous point above 60°C (140°F), at
3242 149 Azodicarbonamide
compound, water-reactive, solution, n.o.s. or above its flash point
n.o.s. 3243 151 Solids containing poisonous
3220 126 Pentafluoroethane liquid, n.o.s.
3205 135 Alkaline earth metal alcoholates,
n.o.s. 3243 151 Solids containing toxic liquid,
n.o.s.
Page 76 Page 77
3257 128 Elevated temperature liquid, 3272 127 Esters, n.o.s. 3280 151 Organoarsenic compound, 3288 151 Poisonous solid, inorganic,
n.o.s., at or above 100°C 3273 131 Nitriles, flammable, poisonous, liquid, n.o.s. n.o.s.
(212°F), and below its flash n.o.s. 3280 151 Organoarsenic compound, 3288 151 Toxic solid, inorganic, n.o.s.
point n.o.s. 3289 154 Poisonous liquid, corrosive,
3273 131 Nitriles, flammable, toxic, n.o.s.
3258 171 Elevated temperature solid, 3281 151 Metal carbonyls, liquid, n.o.s. inorganic, n.o.s.
3274 132 Alcoholates solution, n.o.s., in
n.o.s., at or above 240°C (464°F) 3281 151 Metal carbonyls, n.o.s. 3289 154 Poisonous liquid, corrosive,
alcohol
3259 154 Amines, solid, corrosive, n.o.s. 3282 151 Organometallic compound, inorganic, n.o.s. (Inhalation
3275 131 Nitriles, poisonous, flammable,
3259 154 Polyamines, solid, corrosive, liquid, poisonous, n.o.s. Hazard Zone A)
n.o.s.
n.o.s. 3282 151 Organometallic compound, 3289 154 Poisonous liquid, corrosive,
3275 131 Nitriles, toxic, flammable, n.o.s. inorganic, n.o.s. (Inhalation
3260 154 Corrosive solid, acidic, liquid, toxic, n.o.s.
3276 151 Nitriles, liquid, poisonous, n.o.s. 3282 151 Organometallic compound, Hazard Zone B)
inorganic, n.o.s.
3276 151 Nitriles, liquid, toxic, n.o.s. poisonous, liquid, n.o.s. 3289 154 Toxic liquid, corrosive,
3261 154 Corrosive solid, acidic, organic,
3276 151 Nitriles, poisonous, liquid, n.o.s. 3282 151 Organometallic compound, inorganic, n.o.s.
n.o.s.
3276 151 Nitriles, poisonous, n.o.s. poisonous, n.o.s. 3289 154 Toxic liquid, corrosive,
3262 154 Corrosive solid, basic, inorganic, inorganic, n.o.s. (Inhalation
n.o.s. 3276 151 Nitriles, toxic, liquid, n.o.s. 3282 151 Organometallic compound,
toxic, liquid, n.o.s. Hazard Zone A)
3263 154 Corrosive solid, basic, organic, 3276 151 Nitriles, toxic, n.o.s. 3289 154 Toxic liquid, corrosive,
n.o.s. 3282 151 Organometallic compound,
3277 154 Chloroformates, poisonous, toxic, n.o.s. inorganic, n.o.s. (Inhalation
3264 154 Corrosive liquid, acidic, corrosive, n.o.s. Hazard Zone B)
3283 151 Selenium compound, n.o.s.
inorganic, n.o.s. 3277 154 Chloroformates, toxic, corrosive, 3290 154 Poisonous solid, corrosive,
3283 151 Selenium compound, solid,
3265 153 Corrosive liquid, acidic, organic, n.o.s. inorganic, n.o.s.
n.o.s.
n.o.s. 3278 151 Organophosphorus compound, 3290 154 Toxic solid, corrosive,
3284 151 Tellurium compound, n.o.s.
3266 154 Corrosive liquid, basic, liquid, poisonous, n.o.s. inorganic, n.o.s.
3285 151 Vanadium compound, n.o.s.
inorganic, n.o.s. 3278 151 Organophosphorus compound, 3291 158 (Bio)Medical waste, n.o.s.
3286 131 Flammable liquid, poisonous,
3267 153 Corrosive liquid, basic, organic, liquid, toxic, n.o.s. 3291 158 Clinical waste, unspecified,
corrosive, n.o.s.
n.o.s. 3278 151 Organophosphorus compound, n.o.s.
3286 131 Flammable liquid, toxic,
3268 171 Air bag inflators poisonous, liquid, n.o.s. 3291 158 Medical waste, n.o.s.
corrosive, n.o.s.
3268 171 Air bag inflators, pyrotechnic 3278 151 Organophosphorus compound, 3291 158 Regulated medical waste,
3287 151 Poisonous liquid, inorganic,
poisonous, n.o.s. n.o.s.
3268 171 Air bag modules n.o.s.
3278 151 Organophosphorus compound, 3292 138 Batteries, containing Sodium
3268 171 Air bag modules, pyrotechnic 3287 151 Poisonous liquid, inorganic,
toxic, liquid, n.o.s. n.o.s. (Inhalation Hazard Zone A) 3292 138 Cells, containing Sodium
3268 171 Seat-belt modules 3293 152 Hydrazine, aqueous solution,
3278 151 Organophosphorus compound, 3287 151 Poisonous liquid, inorganic,
3268 171 Seat-belt pre-tensioners with not more than 37%
toxic, n.o.s. n.o.s. (Inhalation Hazard Zone B)
3268 171 Seat-belt pre-tensioners, Hydrazine
3279 131 Organophosphorus compound, 3287 151 Toxic liquid, inorganic, n.o.s.
pyrotechnic 3294 131 Hydrogen cyanide, solution in
poisonous, flammable, n.o.s. 3287 151 Toxic liquid, inorganic, n.o.s.
3269 128 Polyester resin kit alcohol, with not more than
3279 131 Organophosphorus compound, (Inhalation Hazard Zone A)
45% Hydrogen cyanide
3270 133 Nitrocellulose membrane filters toxic, flammable, n.o.s. 3287 151 Toxic liquid, inorganic, n.o.s.
3295 128 Hydrocarbons, liquid, n.o.s.
3271 127 Ethers, n.o.s. (Inhalation Hazard Zone B)
Page 78 Page 79
3296 126 Heptafluoropropane 3303 124 Compressed gas, poisonous, 3304 123 Compressed gas, toxic, 3306 124 Compressed gas, poisonous,
3296 126 Refrigerant gas R-227 oxidizing, n.o.s. (Inhalation corrosive, n.o.s. (Inhalation oxidizing, corrosive, n.o.s.
3297 126 Chlorotetrafluoroethane and Hazard Zone C) Hazard Zone B) (Inhalation Hazard Zone A)
Ethylene oxide mixture, with 3303 124 Compressed gas, poisonous, 3304 123 Compressed gas, toxic, 3306 124 Compressed gas, poisonous,
not more than 8.8% Ethylene oxidizing, n.o.s. (Inhalation corrosive, n.o.s. (Inhalation oxidizing, corrosive, n.o.s.
oxide Hazard Zone D) Hazard Zone C) (Inhalation Hazard Zone B)
3297 126 Ethylene oxide and 3303 124 Compressed gas, toxic, 3304 123 Compressed gas, toxic, 3306 124 Compressed gas, poisonous,
Chlorotetrafluoroethane oxidizing, n.o.s. corrosive, n.o.s. (Inhalation oxidizing, corrosive, n.o.s.
mixture, with not more than 3303 124 Compressed gas, toxic, Hazard Zone D) (Inhalation Hazard Zone C)
8.8% Ethylene oxide oxidizing, n.o.s. (Inhalation 3305 119 Compressed gas, poisonous, 3306 124 Compressed gas, poisonous,
3298 126 Ethylene oxide and Hazard Zone A) flammable, corrosive, n.o.s. oxidizing, corrosive, n.o.s.
Pentafluoroethane mixture, 3303 124 Compressed gas, toxic, 3305 119 Compressed gas, poisonous, (Inhalation Hazard Zone D)
with not more than 7.9% oxidizing, n.o.s. (Inhalation flammable, corrosive, n.o.s. 3306 124 Compressed gas, toxic,
Ethylene oxide Hazard Zone B) (Inhalation Hazard Zone A) oxidizing, corrosive, n.o.s.
3298 126 Pentafluoroethane and Ethylene 3303 124 Compressed gas, toxic, 3305 119 Compressed gas, poisonous, 3306 124 Compressed gas, toxic,
oxide mixture, with not more oxidizing, n.o.s. (Inhalation flammable, corrosive, n.o.s. oxidizing, corrosive, n.o.s.
than 7.9% Ethylene oxide Hazard Zone C) (Inhalation Hazard Zone B) (Inhalation Hazard Zone A)
3299 126 Ethylene oxide and 3303 124 Compressed gas, toxic, 3305 119 Compressed gas, poisonous, 3306 124 Compressed gas, toxic,
Tetrafluoroethane mixture, with oxidizing, n.o.s. (Inhalation flammable, corrosive, n.o.s. oxidizing, corrosive, n.o.s.
not more than 5.6% Ethylene Hazard Zone D) (Inhalation Hazard Zone C) (Inhalation Hazard Zone B)
oxide 3304 123 Compressed gas, poisonous, 3305 119 Compressed gas, poisonous, 3306 124 Compressed gas, toxic,
3299 126 Tetrafluoroethane and Ethylene corrosive, n.o.s. flammable, corrosive, n.o.s. oxidizing, corrosive, n.o.s.
oxide mixture, with not more 3304 123 Compressed gas, poisonous, (Inhalation Hazard Zone D) (Inhalation Hazard Zone C)
than 5.6% Ethylene oxide corrosive, n.o.s. (Inhalation 3305 119 Compressed gas, toxic, 3306 124 Compressed gas, toxic,
3300 119P Carbon dioxide and Ethylene Hazard Zone A) flammable, corrosive, n.o.s. oxidizing, corrosive, n.o.s.
oxide mixture, with more than 3304 123 Compressed gas, poisonous, 3305 119 Compressed gas, toxic, (Inhalation Hazard Zone D)
87% Ethylene oxide corrosive, n.o.s. (Inhalation flammable, corrosive, n.o.s. 3307 124 Liquefied gas, poisonous,
3300 119P Ethylene oxide and Carbon Hazard Zone B) (Inhalation Hazard Zone A) oxidizing, n.o.s.
dioxide mixture, with more than 3304 123 Compressed gas, poisonous, 3305 119 Compressed gas, toxic, 3307 124 Liquefied gas, poisonous,
87% Ethylene oxide corrosive, n.o.s. (Inhalation flammable, corrosive, n.o.s. oxidizing, n.o.s. (Inhalation
3301 136 Corrosive liquid, self-heating, n.o.s. Hazard Zone C) (Inhalation Hazard Zone B) Hazard Zone A)
3302 152 2-Dimethylaminoethyl acrylate 3304 123 Compressed gas, poisonous, 3305 119 Compressed gas, toxic, 3307 124 Liquefied gas, poisonous,
corrosive, n.o.s. (Inhalation flammable, corrosive, n.o.s. oxidizing, n.o.s. (Inhalation
Hazard Zone D) (Inhalation Hazard Zone C) Hazard Zone B)
oxidizing, n.o.s.
3304 123 Compressed gas, toxic, 3305 119 Compressed gas, toxic, 3307 124 Liquefied gas, poisonous,
corrosive, n.o.s. flammable, corrosive, n.o.s. oxidizing, n.o.s. (Inhalation
oxidizing, n.o.s. (Inhalation
(Inhalation Hazard Zone D) Hazard Zone C)
Hazard Zone A) 3304 123 Compressed gas, toxic,
corrosive, n.o.s. (Inhalation 3306 124 Compressed gas, poisonous, 3307 124 Liquefied gas, poisonous,
Hazard Zone A) oxidizing, corrosive, n.o.s. oxidizing, n.o.s. (Inhalation
oxidizing, n.o.s. (Inhalation
Hazard Zone D)
Hazard Zone B)
Page 80 Page 81
3307 124 Liquefied gas, toxic, oxidizing, 3309 119 Liquefied gas, poisonous, 3310 124 Liquefied gas, poisonous, 3317 113 2-Amino-4,6-dinitrophenol,
n.o.s. flammable, corrosive, n.o.s. oxidizing, corrosive, n.o.s. wetted with not less than 20%
(Inhalation Hazard Zone C) water
3307 124 Liquefied gas, toxic, oxidizing, 3309 119 Liquefied gas, poisonous,
n.o.s. (Inhalation Hazard Zone A) flammable, corrosive, n.o.s. 3310 124 Liquefied gas, poisonous, 3318 125 Ammonia solution, with more
(Inhalation Hazard Zone A) oxidizing, corrosive, n.o.s. than 50% Ammonia
3307 124 Liquefied gas, toxic, oxidizing, (Inhalation Hazard Zone D) 3319 113 Nitroglycerin mixture,
n.o.s. (Inhalation Hazard Zone B) 3309 119 Liquefied gas, poisonous, 3310 124 Liquefied gas, toxic, oxidizing, desensitized, solid, n.o.s.,
flammable, corrosive, n.o.s. corrosive, n.o.s. with more than 2% but not
3307 124 Liquefied gas, toxic, oxidizing,
(Inhalation Hazard Zone B) more than 10% Nitroglycerin
n.o.s. (Inhalation Hazard Zone C) 3310 124 Liquefied gas, toxic, oxidizing,
3309 119 Liquefied gas, poisonous, corrosive, n.o.s. (Inhalation 3319 113 Nitroglycerin mixture with
3307 124 Liquefied gas, toxic, oxidizing,
flammable, corrosive, n.o.s. Hazard Zone A) more than 2% but not more
n.o.s. (Inhalation Hazard Zone D)
(Inhalation Hazard Zone C) 3310 124 Liquefied gas, toxic, oxidizing, than 10% Nitroglycerin,
3308 123 Liquefied gas, poisonous, corrosive, n.o.s. (Inhalation desensitized
3309 119 Liquefied gas, poisonous,
corrosive, n.o.s. Hazard Zone B) 3320 157 Sodium borohydride and
flammable, corrosive, n.o.s.
3308 123 Liquefied gas, poisonous, (Inhalation Hazard Zone D) 3310 124 Liquefied gas, toxic, oxidizing, Sodium hydroxide solution,
corrosive, n.o.s. (Inhalation corrosive, n.o.s. (Inhalation with not more than 12%
3309 119 Liquefied gas, toxic, flammable, Hazard Zone C) Sodium borohydride and not
Hazard Zone A)
corrosive, n.o.s. more than 40% Sodium
3308 123 Liquefied gas, poisonous, 3310 124 Liquefied gas, toxic, oxidizing,
3309 119 Liquefied gas, toxic, flammable, corrosive, n.o.s. (Inhalation hydroxide
corrosive, n.o.s. (Inhalation
corrosive, n.o.s. (Inhalation Hazard Zone D) 3321 162 Radioactive material, low
Hazard Zone B)
Hazard Zone A) 3311 122 Gas, refrigerated liquid, specific activity (LSA-II), non
3308 123 Liquefied gas, poisonous, oxidizing, n.o.s. fissile or fissile-excepted
3309 119 Liquefied gas, toxic, flammable,
corrosive, n.o.s. (Inhalation 3322 162 Radioactive material, low
corrosive, n.o.s. (Inhalation 3312 115 Gas, refrigerated liquid,
Hazard Zone C) specific activity (LSA-III), non
Hazard Zone B) flammable, n.o.s.
3308 123 Liquefied gas, poisonous, fissile or fissile-excepted
3313 135 Organic pigments, self-
3309 119 Liquefied gas, toxic, flammable, 3323 163 Radioactive material, Type C
corrosive, n.o.s. (Inhalation heating
corrosive, n.o.s. (Inhalation package, non-fissile or fissile
Hazard Zone D) 3314 171 Plastic molding compound
Hazard Zone C) excepted
3308 123 Liquefied gas, toxic, corrosive, 3314 171 Plastics moulding compound
3309 119 Liquefied gas, toxic, flammable, 3324 165 Radioactive material, low
n.o.s. 3315 151 Chemical sample, poisonous
corrosive, n.o.s. (Inhalation specific activity (LSA-II), fissile
3308 123 Liquefied gas, toxic, corrosive, Hazard Zone D) 3315 151 Chemical sample, poisonous 3325 165 Radioactive material, low
n.o.s. (Inhalation Hazard Zone A) liquid specific activity (LSA-III), fissile
3310 124 Liquefied gas, poisonous, 3315 151 Chemical sample, poisonous
3308 123 Liquefied gas, toxic, corrosive, oxidizing, corrosive, n.o.s. 3326 165 Radioactive material, surface
solid contaminated objects (SCO-I), fissile
n.o.s. (Inhalation Hazard Zone B)
3310 124 Liquefied gas, poisonous, 3315 151 Chemical sample, toxic 3326 165 Radioactive material, surface
3308 123 Liquefied gas, toxic, corrosive, oxidizing, corrosive, n.o.s. 3315 151 Chemical sample, toxic liquid contaminated objects (SCO-
n.o.s. (Inhalation Hazard Zone C) (Inhalation Hazard Zone A) 3315 151 Chemical sample, toxic solid II), fissile
3308 123 Liquefied gas, toxic, corrosive, 3310 124 Liquefied gas, poisonous, 3316 171 Chemical kit 3327 165 Radioactive material, Type A
n.o.s. (Inhalation Hazard Zone D) oxidizing, corrosive, n.o.s. 3316 171 First aid kit package, fissile, non-special form
(Inhalation Hazard Zone B)
Page 82 Page 83
3328 165 Radioactive material, Type B(U) 3344 113 PETN mixture, desensitized, 3353 126 Air bag inflators, compressed 3357 113 Nitroglycerin mixture,
package, fissile solid, n.o.s., with more than gas desensitized, liquid, n.o.s.,
3329 165 Radioactive material, Type B(M) 10% but not more than 20% 3353 126 Air bag modules, compressed with not more than 30%
package, fissile PETN gas Nitroglycerin
3330 165 Radioactive material, Type C 3345 153 Phenoxyacetic acid derivative 3353 126 Seat-belt pre-tensioners, 3358 115 Refrigerating machines,
package, fissile pesticide, solid, poisonous compressed gas containing flammable,
3331 165 Radioactive material, 3345 153 Phenoxyacetic acid derivative 3354 115 Insecticide gas, flammable, nonpoisonous, liquefied gases
transported under special pesticide, solid, toxic n.o.s. 3358 115 Refrigerating machines,
arrangement, fissile 3346 131 Phenoxyacetic acid derivative 3355 119 Insecticide gas, poisonous, containing flammable,
3332 164 Radioactive material, Type A pesticide, liquid, flammable, flammable, n.o.s. nontoxic, liquefied gases
package, special form, non poisonous 3355 119 Insecticide gas, poisonous, 3359 171 Fumigated cargo transport unit
fissile or fissile-excepted 3346 131 Phenoxyacetic acid derivative flammable, n.o.s. (Inhalation 3359 171 Fumigated unit
3333 165 Radioactive material, Type A pesticide, liquid, flammable, Hazard Zone A) 3360 133 Fibers, vegetable, dry
package, special form, fissile toxic 3355 119 Insecticide gas, poisonous, 3360 133 Fibres, vegetable, dry
3334 171 Aviation regulated liquid, n.o.s. 3347 131 Phenoxyacetic acid derivative flammable, n.o.s. (Inhalation 3361 156 Chlorosilanes, poisonous,
pesticide, liquid, poisonous, Hazard Zone B) corrosive, n.o.s.
3334 171 Self-defense spray, nonpressurized
flammable 3355 119 Insecticide gas, poisonous, 3361 156 Chlorosilanes, toxic, corrosive,
3335 171 Aviation regulated solid, n.o.s.
3347 131 Phenoxyacetic acid derivative flammable, n.o.s. (Inhalation n.o.s.
3336 130 Mercaptan mixture, liquid, Hazard Zone C)
pesticide, liquid, toxic, 3362 155 Chlorosilanes, poisonous,
flammable, n.o.s.
flammable 3355 119 Insecticide gas, poisonous, corrosive, flammable, n.o.s.
3336 130 Mercaptans, liquid, flammable, n.o.s. flammable, n.o.s. (Inhalation
3348 153 Phenoxyacetic acid derivative 3362 155 Chlorosilanes, toxic, corrosive,
3337 126 Refrigerant gas R-404A pesticide, liquid, poisonous Hazard Zone D) flammable, n.o.s.
3338 126 Refrigerant gas R-407A 3348 153 Phenoxyacetic acid derivative 3355 119 Insecticide gas, toxic, 3363 171 Dangerous goods in apparatus
3339 126 Refrigerant gas R-407B pesticide, liquid, toxic flammable, n.o.s. 3363 171 Dangerous goods in
3340 126 Refrigerant gas R-407C 3349 151 Pyrethroid pesticide, solid, 3355 119 Insecticide gas, toxic, machinery
3341 135 Thiourea dioxide poisonous flammable, n.o.s. (Inhalation 3364 113 Picric acid, wetted with not
3342 135 Xanthates Hazard Zone A) less than 10% water
3349 151 Pyrethroid pesticide, solid, toxic
3355 119 Insecticide gas, toxic, 3364 113 Trinitrophenol, wetted with
3343 113 Nitroglycerin mixture, 3350 131 Pyrethroid pesticide, liquid,
flammable, n.o.s. (Inhalation not less than 10% water
desensitized, liquid, flammable, flammable, poisonous
Hazard Zone B) 3365 113 Picryl chloride, wetted with
n.o.s., with not more than 30% 3350 131 Pyrethroid pesticide, liquid,
Nitroglycerin 3355 119 Insecticide gas, toxic, not less than 10% water
flammable, toxic flammable, n.o.s. (Inhalation
3344 113 Pentaerythrite tetranitrate 3351 131 Pyrethroid pesticide, liquid, 3365 113 Trinitrochlorobenzene, wetted
Hazard Zone C) with not less than 10% water
mixture, desensitized, solid, poisonous, flammable
n.o.s., with more than 10% but 3355 119 Insecticide gas, toxic, 3366 113 TNT, wetted with not less than
3351 131 Pyrethroid pesticide, liquid, flammable, n.o.s. (Inhalation
not more than 20% PETN toxic, flammable 10% water
Hazard Zone D)
3344 113 Pentaerythritol tetranitrate 3366 113 Trinitrotoluene, wetted with
3352 151 Pyrethroid pesticide, liquid, 3356 140 Oxygen generator, chemical
mixture, desensitized, solid, not less than 10% water
poisonous 3356 140 Oxygen generator, chemical,
n.o.s., with more than 10% but 3367 113 Trinitrobenzene, wetted with
3352 151 Pyrethroid pesticide, liquid, spent
not more than 20% PETN not less than 10% water
toxic
Page 84 Page 85
3368 113 Trinitrobenzoic acid, wetted 3383 131 Toxic by inhalation liquid, 3390 154 Poisonous by inhalation 3407 140 Chlorate and Magnesium
with not less than 10% water flammable, n.o.s. (Inhalation liquid, corrosive, n.o.s. chloride mixture, solution
3369 113 Sodium dinitro-o-cresolate, Hazard Zone A) (Inhalation Hazard Zone B) 3407 140 Magnesium chloride and
wetted with not less than 10% 3384 131 Poisonous by inhalation liquid, 3390 154 Toxic by inhalation liquid, Chlorate mixture, solution
water flammable, n.o.s. (Inhalation corrosive, n.o.s. (Inhalation 3408 141 Lead perchlorate, solution
3370 113 Urea nitrate, wetted with not Hazard Zone B) Hazard Zone B) 3409 152 Chloronitrobenzenes, liquid
less than 10% water 3384 131 Toxic by inhalation liquid, 3391 135 Organometallic substance, 3410 153 4-Chloro-o-toluidine
3371 129 2-Methylbutanal flammable, n.o.s. (Inhalation solid, pyrophoric hydrochloride, solution
Hazard Zone B) 3392 135 Organometallic substance, 3411 153 beta-Naphthylamine, solution
3372 138 Organometallic compound,
3385 139 Poisonous by inhalation liquid, liquid, pyrophoric 3411 153 Naphthylamine (beta), solution
solid, water-reactive,
flammable, n.o.s. water-reactive, n.o.s. 3393 135 Organometallic substance, 3412 153 Formic acid, with not less than
(Inhalation Hazard Zone A) solid, pyrophoric, 5% but less than 10% acid
3373 158 Biological substance, category B
3385 139 Toxic by inhalation liquid, water- waterreactive 3412 153 Formic acid, with not less
3373 158 Clinical specimens
reactive, n.o.s. (Inhalation 3394 135 Organometallic substance, than 10% but not more than
3373 158 Diagnostic specimens liquid, pyrophoric,
Hazard Zone A) 85% acid
3374 116 Acetylene, solvent free waterreactive
3386 139 Poisonous by inhalation liquid, 3413 157 Potassium cyanide, solution
3375 140 Ammonium nitrate emulsion water-reactive, n.o.s. 3395 135 Organometallic substance, 3414 157 Sodium cyanide, solution
3375 140 Ammonium nitrate gel (Inhalation Hazard Zone B) solid, water-reactive
3415 154 Sodium fluoride, solution
3375 140 Ammonium nitrate suspension 3386 139 Toxic by inhalation liquid, water- 3396 138 Organometallic substance,
3416 153 Chloroacetophenone, liquid
reactive, n.o.s. (Inhalation solid, water-reactive,
3376 113 4-Nitrophenylhydrazine, with 3417 152 Xylyl bromide, solid
Hazard Zone B) flammable
not less than 30% water 3418 151 2,4-Toluylenediamine,
3397 138 Organometallic substance,
3377 140 Sodium perborate monohydrate 3387 142 Poisonous by inhalation liquid, solution
solid, water-reactive,
3378 140 Sodium carbonate oxidizing, n.o.s. (Inhalation 3419 157 Boron trifluoride acetic acid
selfheating
peroxyhydrate Hazard Zone A) complex, solid
3379 128 Desensitized explosive, liquid, 3387 142 Toxic by inhalation liquid, 3420 157 Boron trifluoride propionic
liquid, water-reactive
n.o.s. oxidizing, n.o.s. (Inhalation acid complex, solid
Hazard Zone A) 3421 154 Potassium hydrogen
3380 133 Desensitized explosive, solid, n.o.s. liquid, water-reactive,
3388 142 Poisonous by inhalation liquid, flammable difluoride, solution
3381 151 Poisonous by inhalation liquid,
oxidizing, n.o.s. (Inhalation 3422 154 Potassium fluoride, solution
n.o.s. (Inhalation Hazard Zone A) 3400 138 Organometallic substance,
Hazard Zone B) 3423 153 Tetramethylammonium
3381 151 Toxic by inhalation liquid, n.o.s. solid, self-heating
3388 142 Toxic by inhalation liquid, 3401 138 Alkali metal amalgam, solid hydroxide, solid
(Inhalation Hazard Zone A)
oxidizing, n.o.s. (Inhalation 3424 141 Ammonium dinitro-o-
3382 151 Poisonous by inhalation liquid, 3402 138 Alkaline earth metal
Hazard Zone B) cresolate, solution
n.o.s. (Inhalation Hazard Zone B) amalgam, solid
3389 154 Poisonous by inhalation liquid, 3425 156 Bromoacetic acid, solid
3382 151 Toxic by inhalation liquid, n.o.s. 3403 138 Potassium, metal alloys, solid
corrosive, n.o.s. (Inhalation 3426 153P Acrylamide, solution
(Inhalation Hazard Zone B) 3404 138 Potassium sodium alloys, solid
Hazard Zone A) 3427 153 Chlorobenzyl chlorides, solid
3383 131 Poisonous by inhalation liquid, 3404 138 Sodium potassium alloys, solid
3389 154 Toxic by inhalation liquid, 3428 156 3-Chloro-4-methylphenyl
flammable, n.o.s. (Inhalation 3405 141 Barium chlorate, solution
corrosive, n.o.s. (Inhalation isocyanate, solid
Hazard Zone A) Hazard Zone A) 3406 141 Barium perchlorate, solution
Page 86 Page 87
3429 153 Chlorotoluidines, liquid 3456 157 Nitrosylsulphuric acid, solid 3468 115 Hydrogen in a metal hydride 3476 138 Fuel cell cartridges, containing
3430 153 Xylenols, liquid 3457 152 Chloronitrotoluenes, solid storage system packed with water-reactive substances
equipment 3476 138 Fuel cell cartridges packed
3431 152 Nitrobenzotrifluorides, solid 3458 152 Nitroanisoles, solid 3469 132 Paint, flammable, corrosive with equipment, containing
3432 171 Polychlorinated biphenyls, solid 3459 152 Nitrobromobenzenes, solid 3469 132 Paint related material, waterreactive substances
3433 135 Lithium alkyls, solid 3460 153 N-Ethylbenzyltoluidines, solid flammable, corrosive 3477 153 Fuel cell cartridges contained
3470 132 Paint, corrosive, flammable in equipment, containing
3434 153 Nitrocresols, liquid 3461 135 Aluminum alkyl halides, solid corrosive substances
3470 132 Paint related material,
3435 153 Hydroquinone, solution 3462 153 Toxins, extracted from living corrosive, flammable 3477 153 Fuel cell cartridges, containing
3436 151 Hexafluoroacetone hydrate, solid sources, solid, n.o.s. 3471 154 Hydrogendifluorides, solution, corrosive substances
3463 132 Propionic acid, with not less n.o.s. 3477 153 Fuel cell cartridges packed
3437 152 Chlorocresols, solid with equipment, containing
than 90% acid 3472 153 Crotonic acid, liquid
3438 153 alpha-Methylbenzyl alcohol, solid 3473 128 Fuel cell cartridges contained corrosive substances
3464 151 Organophosphorus compound, 3478 115 Fuel cell cartridges
3439 151 Nitriles, poisonous, solid, n.o.s. in equipment, containing
poisonous, solid, n.o.s. flammable liquids containedin equipment,
3439 151 Nitriles, solid, poisonous, n.o.s. 3464 151 Organophosphorus compound, containing liquefied
3473 128 Fuel cell cartridges containing
3439 151 Nitriles, solid, toxic, n.o.s. solid, poisonous, n.o.s. flammable liquids flammable gas
3439 151 Nitriles, toxic, solid, n.o.s. 3473 128 Fuel cell cartridges packed 3478 115 Fuel cell cartridges, containing
3464 151 Organophosphorus compound,
with equipment, containing liquefied flammable gas
3440 151 Selenium compound, liquid, n.o.s. solid, toxic, n.o.s.
flammable liquids 3478 115 Fuel cell cartridges packed
3441 153 Chlorodinitrobenzenes, solid 3464 151 Organophosphorus compound, 3474 113 1-Hydroxybenzotriazole, with equipment, containing
toxic, solid, n.o.s. anhydrous, wetted with not liquefied flammable gas
3442 153 Dichloroanilines, solid
3465 151 Organoarsenic compound, solid, less than 20% water 3479 115 Fuel cell cartridges contained
3443 152 Dinitrobenzenes, solid in equipment, containing
n.o.s. 3474 113 1-Hydroxybenzotriazole,
3444 151 Nicotine hydrochloride, solid monohydrate hydrogen in metal hydride
3466 151 Metal carbonyls, solid, n.o.s.
3445 151 Nicotine sulfate, solid 3475 127 Ethanol and gasoline mixture, 3479 115 Fuel cell cartridges, containing
3467 151 Organometallic compound, with more than 10% ethanol hydrogen in metal hydride
3445 151 Nicotine sulphate, solid poisonous, solid, n.o.s. 3479 115 Fuel cell cartridges packed
3475 127 Ethanol and motor spirit
3446 152 Nitrotoluenes, solid 3467 151 Organometallic compound, mixture, with more than 10% with equipment, containing
3447 152 Nitroxylenes, solid solid, poisonous, n.o.s. ethanol hydrogen in metal hydride
3475 127 Ethanol and petrol mixture, 3480 147 Lithium ion batteries
3448 159 Tear gas substance, solid, n.o.s. 3467 151 Organometallic compound,
with more than 10% ethanol (including lithium ion polymer
3449 159 Bromobenzyl cyanides, solid solid, toxic, n.o.s. batteries)
3475 127 Gasoline and ethanol mixture,
3450 151 Diphenylchloroarsine, solid 3467 151 Organometallic compound, with more than 10% ethanol 3481 147 Lithium ion batteries
toxic, solid, n.o.s. 3475 127 Motor spirit and ethanol contained in equipment
3451 153 Toluidines, solid (including lithium ion polymer
3468 115 Hydrogen in a metal hydride mixture, with more than 10%
3452 153 Xylidines, solid storage system ethanol batteries)
3453 154 Phosphoric acid, solid 3475 127 Petrol and ethanol mixture, 3481 147 Lithium ion batteries packed
3468 115 Hydrogen in a metal hydride with equipment (including
with more than 10% ethanol
3454 152 Dinitrotoluenes, solid storage system contained in lithium ion polymer batteries)
equipment 3476 138 Fuel cell cartridges contained
3455 153 Cresols, solid in equipment, containing 3482 138 Alkali metal dispersion,
3456 157 Nitrosylsulfuric acid, solid waterreactive substances flammable
Page 88 Page 89
3482 138 Alkaline earth metal dispersion, 3490 155 Toxic by inhalation liquid, 3505 118 Chemical under pressure,
flammable waterreactive, flammable, n.o.s. flammable, corrosive, n.o.s.
3483 131 Motor fuel anti-knock mixture, (Inhalation Hazard Zone A) 3506 172 Mercury contained in
flammable 3491 155 Poisonous by inhalation liquid, manufactured articles
3484 132 Hydrazine aqueous s o l u t i o n water-reactive, flammable,
8000 171 Consumer commodity
, flammable, with more than n.o.s. (Inhalation Hazard Zone B)
37% hydrazine, by mass 3491 155 Toxic by inhalation liquid, 9035 123 Gas identification set
3485 140 Calcium hypochlorite, dry, waterreactive, flammable, n.o.s. 9191 143 Chlorine dioxide, hydrate,
corrosive, with more than 39% (Inhalation Hazard Zone B) frozen
available chlorine (8.8% 3492 131 Poisonous by inhalation liquid, 9202 168 Carbon monoxide,
available oxygen) corrosive, flammable, n.o.s. refrigerated liquid (cryogenic
3485 140 Calcium hypochlorite mixture, (Inhalation Hazard Zone A) liquid)
dry, corrosive, with more than 3492 131 Toxic by inhalation liquid,
9206 137 Methyl phosphonic dichloride
39% available chlorine (8.8% corrosive, flammable, n.o.s.
available oxygen) (Inhalation Hazard Zone A) 9260 169 Aluminum, molten
3486 140 Calcium hypochlorite mixture, 3493 131 Poisonous by inhalation liquid, 9263 156 Chloropivaloyl chloride
dry, corrosive, with more than corrosive, flammable, n.o.s. 9264 151 3,5-Dichloro-2,4,6-
10% but not more than 39% (Inhalation Hazard Zone B) trifluoropyridine
available chlorine 3493 131 Toxic by inhalation liquid,
9269 132 Trimethoxysilane
3487 140 Calcium hypochlorite, hydrated, corrosive, flammable, n.o.s.
corrosive, with not less than 5.5% (Inhalation Hazard Zone B) 9279 115 Hydrogen absorbed in metal
but not more than 16% water 3494 131 Petroleum sour crude oil, hydride
3487 140 Calcium hypochlorite, hydrated flammable, toxic
mixture, corrosive, with not less 3495 154 Iodine
than 5.5% but not more than 3496 171 Batteries, nickel-metal hydride
16% water 3497 133 Krill meal
3488 131 Poisonous by inhalation liquid, 3498 157 Iodine monochloride, liquid
flammable, corrosive, n.o.s. 3499 171 Capacitor, electric double layer
(Inhalation Hazard Zone A) 3500 126 Chemical under pressure, n.o.s.
3488 131 Toxic by inhalation liquid, 3501 115 Chemical under pressure,
flammable, corrosive, n.o.s. flammable, n.o.s.
(Inhalation Hazard Zone A) 3502 123 Chemical under pressure,
3489 131 Poisonous by inhalation liquid, poisonous, n.o.s.
flammable, corrosive, n.o.s. 3502 123 Chemical under pressure, toxic, n.o.s.
(Inhalation Hazard Zone B) 3503 125 Chemical under pressure,
3489 131 Toxic by inhalation liquid, corrosive, n.o.s.
flammable, corrosive, n . o . s . 3504 119 Chemical under pressure,
(Inhalation Hazard Zone B) flammable, poisonous, n.o.s.
3490 155 Poisonous by inhalation liquid, 3504 119 Chemical under pressure,
water-reactive, flammable, flammable, toxic, n.o.s.
n.o.s. (Inhalation Hazard Zone A)
Page 90 Page 91
Name of Material Guid ID Name of Material Guid ID
No. No. No. No.
GREEN HIGHLIGHTED ENTRIES IN BLUE PAGES AC 117 1051 Acrolein dimer, stabilized 129P 2607
Acetal 127 1088 Acrylamide 153P 2074
Acetaldehyde 129 1089 Acrylamide, solid 153P 2074
For entries highlighted in green follow these steps: Acetaldehyde ammonia 171 1841 Acrylamide, solution 153P 3426
• IF THERE IS NO FIRE: Acetaldehyde oxime 129 2332 Acrylic acid, stabilized 132P 2218
-- Go directly to Table 1 (green bordered pages) Acetic acid, glacial 132 2789 Acrylonitrile, stabilized 131P 1093
Acetic acid, solution, more Adamsite 154 1698
– Look up the ID number and name of material than 10% but not more than
80% acid 153 2790 Adhesives (flammable) 128 1133
-- Identify initial isolation and protective action distances Acetic acid, solution, more Adiponitrile 153 2205
than 80% acid 132 2789
• IF THERE IS A FIRE or A FIRE IS INVOLVED: Aerosol dispensers 126 1950
Acetic anhydride 137 1715
Acetone 127 1090 Aerosols 126 1950
-- Also consult the assigned orange guide
Acetone cyanohydrin, Air, compressed 122 1002
– If applicable, apply the evacuation information shown under stabilized 155 1541 Air, refrigerated liquid
PUBLIC SAFETY Acetone oils 127 1091 (cryogenic liquid) 122 1003
Note: If the name in Table 1 is shown with “When Spilled In Water”, these Acetonitrile 127 1648 Air, refrigerated liquid
(cryogenic liquid),
materials produce large amounts of Toxic Inhalation Hazard (TIH) gases Acetyl bromide 156 1716 non-pressurized 122 1003
when spilled in water. Some Water Reactive materials are also TIH Acetyl chloride 155 1717 Air bag inflators 171 3268
materials themselves (e.g., Bromine trifluoride (1746), Thionyl chloride Acetylene 116 1001 Air bag inflators,
(1836), etc.). In these instances, two entries are provided in Table 1 for compressed gas 126 3353
Acetylene, dissolved 116 1001
land-based and water-based spills. If the Water Reactive material is NOT a Air bag inflators, pyrotechnic 171 3268
TIH and this material is NOT spilled in water, Table 1 and Table 2 do not Acetylene, solvent free 116 3374
Air bag modules 171 3268
apply and safety distances will be found within the appropriate orange Acetylene, Ethylene and
Propylene in mixture, Air bag modules,
guide. refrigerated liquid compressed gas 126 3353
containing at least 71.5% Air bag modules, pyrotechnic 171 3268
Ethylene with not more than
22.5% Acetylene and not Aircraft hydraulic power unit
more than 6% Propylene 115 3138 fuel tank 131 3165
Alcoholates solution, n.o.s.,
Acetylene tetrabromide 159 2504 in alcohol 132 3274
Acetyl iodide 156 1898 Alcoholic beverages 127 3065
Acetyl methyl carbinol 127 2621 Alcohols, flammable,
poisonous, n.o.s. 131 1986
Acid, sludge 153 1906
Alcohols, flammable, toxic,
Acid butyl phosphate 153 1718 n.o.s. 131 1986
Acridine 153 2713 Alcohols, n.o.s. 127 1987
Acrolein, stabilized 131P 1092 Alcohols, poisonous, n.o.s. 131 1986
Page 92 Page 93
Name of Material Guid ID Name of Material Guid ID Name of Material Guid ID Name of Material Guid ID
Alcohols, toxic, n.o.s. 131 1986 Alkaloid salts, solid, n.o.s. Allyl bromide 131 1099 Aluminum powder, uncoated 138 1396
Aldehydes, flammable, (poisonous) 151 1544 Allyl chloride 131 1100 Aluminum processing
poisonous, n.o.s. 131 1988 Alkylamines, n.o.s. 132 2733 Allyl chlorocarbonate 155 1722 byproducts 138 3170
Aldehydes, flammable, toxic, Alkylamines, n.o.s. 132 2734 Allyl chloroformate 155 1722 Aluminum remelting
n.o.s. 131 1988 byproducts 138 3170
Alkylamines, n.o.s. 153 2735 Allyl ethyl ether 131 2335 Aluminum resinate 133 2715
Aldehydes, n.o.s. 129 1989 Alkyl phenols, liquid, Allyl formate 131 2336 Aluminum silicon powder,
Aldehydes, poisonous, n.o.s. 131 1988 n.o.s. (including C2-C12 Allyl glycidyl ether 129 2219 uncoated 138 1398
Aldehydes, toxic, n.o.s. 131 1988 homologues) 153 3145
Allyl iodide 132 1723 Aluminum smelting
Aldol 153 2839 Alkyl phenols, solid, n.o.s. Allyl isothiocyanate, byproducts 138 3170
(including C2-C12 stabilized 155 1545 Amines, flammable,
Alkali metal alcoholates, homologues) 153 2430 corrosive, n.o.s. 132 2733
selfheating, corrosive, n.o.s. 136 3206 Allyltrichlorosilane, stabilized 155 1724
Alkyl sulfonic acids, liquid, Amines, liquid, corrosive,
Alkali metal alloy, liquid, n.o.s. 138 1421 with more than 5% free Aluminum, molten 169 9260 flammable, n.o.s. 132 2734
Alkali metal amalgam 138 1389 Sulfuric acid 153 2584 Aluminum alkyl halides 135 3052 Amines, liquid, corrosive,
Alkyl sulfonic acids, liquid, Aluminum alkyl halides, n.o.s. 153 2735
Alkali metal amalgam, liquid 138 1389 with not more than 5% free liquid 135 3052 Amines, solid, corrosive,
Alkali metal amalgam, solid 138 1389 Sulfuric acid 153 2586 Aluminum alkyl halides, solid 135 3052 n.o.s. 154 3259
Alkali metal amalgam, solid 138 3401 Alkyl sulfonic acids, solid, Aluminum alkyl halides, solid 135 3461 2-Amino-4-chlorophenol 151 2673
Alkali metal amides 139 1390 withmore than 5% free Aluminum alkyl hydrides 138 3076 2-Amino-5-
Sulfuric acid 153 2583 diethylaminopentane 153 2946
Alkali metal dispersion 138 1391 Aluminum alkyls 135 3051
Alkyl sulfonic acids, solid, 2-Amino-4,6-dinitrophenol,
Alkali metal dispersion, with not more than 5% free Aluminum borohydride 135 2870 wetted with not l ess than
flammable 138 3482 Sulfuric acid 153 2585 Aluminum borohydride in 20% water 113 3317
Alkaline earth metal Alkylsulfuric acids 156 2571 devices 135 2870 2-(2-Aminoethoxy)ethanol 154 3055
alcoholates, n.o.s. 135 3205 Aluminum bromide, N-Aminoethylpiperazine 153 2815
Alkyl sulphonic acids, liquid, anhydrous 137 1725
Alkaline earth metal alloy, with more than 5% free Aminophenols 152 2512
n.o.s. 138 1393 Sulphuric acid 153 2584 Aluminum bromide, solution 154 2580
Aminopyridines 153 2671
Alkaline earth metal amalgam 138 1392 Alkyl sulphonic acids, liquid, Aluminum carbide 138 1394
Ammonia, anhydrous 125 1005
Alkaline earth metal with not more than 5% free Aluminum chloride,
Sulphuric acid 153 2586 anhydrous 137 1726 Ammonia, solution, with more
amalgam, liquid 138 1392 than 10% but not more than
Alkyl sulphonic acids, solid, Aluminum chloride, solution 154 2581 35% Ammonia 154 2672
Alkaline earth metal with more than 5% free
amalgam, solid 138 3402 Aluminum dross 138 3170 Ammonia, solution, with more
Sulphuric acid 153 2583 than 35% but not more than
Alkaline earth metal Aluminum ferrosilicon
Alkyl sulphonic acids, solid, powder 139 1395 50% Ammonia 125 2073
dispersion 138 1391 with not more than 5% free Aluminum hydride 138 2463 Ammonia solution, with
Alkaline earth metal Sulphuric acid 153 2585 more than 50% Ammonia 125 3318
dispersion, flammable 138 3482 Aluminum nitrate 140 1438
Alkylsulphuric acids 156 2571 Ammonium arsenate 151 1546
Alkaloids, liquid, n.o.s. Aluminum phosphide 139 1397
Allyl acetate 131 2333 Ammonium bifluoride, solid 154 1727
(poisonous) 151 3140 Aluminum phosphide
Allyl alcohol 131 1098 pesticide 157 3048 Ammonium bifluoride,
Alkaloids, solid, n.o.s. solution 154 2817
(poisonous) 151 1544 Allylamine 131 2334 Aluminum powder, coated 170 1309
Ammonium dichromate 141 1439
Alkaloid salts, liquid, n.o.s. Aluminum powder,
pyrophoric 135 1383 Ammonium
(poisonous) 151 3140 dinitro-o-cresolate 141 1843
Page 94 Page 95
Ammonium Ammonium nitrate fertilizers, Amyl mercaptan 130 1111 Argon, compressed 121 1006
dinitro-ocresolate, solid 141 1843 with Calcium carbonate 140 2068
n-Amyl methyl ketone 127 1110 Argon, refrigerated liquid
Ammonium Ammonium nitrate fertilizers, (cryogenic liquid) 120 1951
dinitro-ocresolate, solution 141 3424 with Phosphate or Potash 143 2070 Amyl methyl ketone 127 1110
Amyl nitrate 140 1112 Arsenic 152 1558
Ammonium fluoride 154 2505 Ammonium nitrate-fuel oil
mixtures 112 —— Amyl nitrite 129 1113 Arsenic acid, liquid 154 1553
Ammonium fluorosilicate 151 2854
Ammonium nitrate gel 140 3375 Amyltrichlorosilane 155 1728 Arsenic acid, solid 154 1554
Ammonium
hydrogendifluoride, solid 154 1727 Ammonium nitrate mixed Anhydrous ammonia 125 1005 Arsenical dust 152 1562
fertilizers 140 2069 Arsenical pesticide, liquid,
Ammonium Aniline 153 1547
hydrogendifluoride, solution 154 2817 Ammonium nitrate flammable, poisonous 131 2760
suspension 140 3375 Aniline hydrochloride 153 1548 Arsenical pesticide, liquid,
Ammonium hydrogen
fluoride, solid 154 1727 Ammonium perchlorate 143 1442 Anisidines 153 2431 flammable, toxic 131 2760
Ammonium hydrogen Ammonium persulfate 140 1444 Anisidines, liquid 153 2431 Arsenical pesticide, liquid,
fluoride, solution 154 2817 Anisidines, solid 153 2431 poisonous 151 2994
Ammonium persulphate 140 1444
Ammonium hydrogen sulfate 154 2506 Anisole 128 2222 Arsenical pesticide, liquid,
Ammonium picrate, wetted poisonous, flammable 131 2993
Ammonium hydrogen with not less than 10% water 113 1310 Anisoyl chloride 156 1729
sulphate 154 2506 Arsenical pesticide, liquid,
Ammonium polysulfide, Antimony compound, toxic 151 2994
Ammonium hydroxide 154 2672 solution 154 2818
inorganic, liquid, n.o.s. 157 3141 Arsenical pesticide, liquid,
Ammonium hydroxide, with Ammonium polysulphide, toxic, flammable 131 2993
more than 10% but not more solution 154 2818 Antimony compound,
than 35% Ammonia 154 2672 inorganic, n.o.s. 157 1549 Arsenical pesticide, solid,
Ammonium polyvanadate 151 2861 poisonous 151 2759
Ammonium metavanadate 154 2859 Antimony compound,
Ammonium silicofluoride 151 2854 Arsenical pesticide, solid,
Ammonium nitrate, liquid inorganic, solid, n.o.s. 157 1549
(hotconcentrated solution) 140 2426 Ammonium sulfide, solution 132 2683 toxic 151 2759
Antimony lactate 151 1550
Ammonium nitrate, with not Ammonium sulphide, Arsenic bromide 151 1555
solution 132 2683 Antimony pentachloride,
more than 0.2% combustible liquid 157 1730 Arsenic chloride 157 1560
substances 140 1942 Ammunition, poisonous,
nonexplosive 151 2016 Antimony pentachloride, Arsenic compound, liquid,
Ammonium nitrate emulsion 140 3375 n.o.s. 152 1556
Ammunition, tear-producing, solution 157 1731
Ammonium nitrate fertilizer, Arsenic compound, liquid,
n.o.s. 140 2072 non-explosive 159 2017 Antimony pentafluoride 157 1732 n.o.s., inorganic 152 1556
Ammonium nitrate fertilizer, Ammunition, toxic, Antimony potassium tartrate 151 1551
nonexplosive 151 2016 Arsenic compound, solid,
with not more than 0.4% Antimony powder 170 2871 n.o.s. 152 1557
combustible material 140 2071 Amyl acetates 129 1104
Antimony trichloride 157 1733 Arsenic compound, solid,
Ammonium nitrate fertilizers 140 2067 Amyl acid phosphate 153 2819 n.o.s., inorganic 152 1557
Antimony trichloride, liquid 157 1733
Ammonium nitrate fertilizers 140 2071 Amyl alcohols 129 1105 Arsenic pentoxide 151 1559
Antimony trichloride, solid 157 1733
Ammonium nitrate fertilizers 140 2072 Amylamines 132 1106 Arsenic trichloride 157 1560
Antimony trichloride,
Ammonium nitrate fertilizers, Amyl butyrates 130 2620 Arsenic trioxide 151 1561
with Ammonium sulfate 140 2069 solution 157 1733
Amyl chloride 129 1107 Arsine 119 2188
Ammonium nitrate fertilizers, Aqua regia 157 1798
with Ammonium sulphate 140 2069 n-Amylene 128 1108
Argon 121 1006
Amyl formates 129 1109
Page 96 Page 97
Articles containing 1-Aziridinyl phosphine oxide Battery fluid, alkali, with Biological substance,
Polychlorinated biphenyls (Tris) 152 2501 electronic equipment or category B 158 3373
(PCB) 171 2315 Azodicarbonamide 149 3242 actuating device 154 2797 (Bio)Medical waste, n.o.s. 158 3291
Articles, pressurized, Barium 138 1400 Battery-powered equipment Bipyridilium pesticide, liquid,
hydraulic (containing (wet battery) 154 3171 flammable, poisonous 131 2782
nonflammable gas) 126 3164 Barium alloys, pyrophoric 135 1854
Barium azide, wetted with Battery-powered vehicle Bipyridilium pesticide, liquid,
Articles, pressurized, not less than 50% water 113 1571 flammable, toxic 131 2782
pneumatic (containing (wet battery) 154 3171
nonflammable gas) 126 3164 Barium bromate 141 2719 Bipyridilium pesticide, liquid,
Benzaldehyde 129 1990 poisonous 151 3016
Aryl sulfonic acids, liquid, Barium chlorate 141 1445 Benzene 130 1114 Bipyridilium pesticide, liquid,
withmore than 5% free Barium chlorate, solid 141 1445 poisonous, flammable 131 3015
Sulfuric acid 153 2584 Benzene phosphorus
Barium chlorate, solution 141 3405 dichloride 137 2798 Bipyridilium pesticide, liquid,
Aryl sulfonic acids, liquid, toxic 151 3016
with not more than 5% free Barium compound, n.o.s. 154 1564 Benzene phosphorus
Sulfuric acid 153 2586 Bipyridilium pesticide, liquid,
Barium cyanide 157 1565 thiodichloride 137 2799 toxic, flammable 131 3015
Aryl sulfonic acids, solid, with Barium hypochlorite, with
more than 5% free Sulfuric Benzenesulfonyl chloride 156 2225 Bipyridilium pesticide, solid,
acid 153 2583 more than 22% available poisonous 151 2781
Chlorine 141 2741 Benzenesulphonyl chloride 156 2225
Aryl sulfonic acids, solid, Bipyridilium pesticide, solid,
Barium nitrate 141 1446 Benzidine 153 1885 toxic 151 2781
with not more than 5% free
Sulfuric acid 153 2585 Barium oxide 157 1884 Benzonitrile 152 2224 Bisulfates, aqueous solution 154 2837
Aryl sulphonic acids, liquid, Barium perchlorate 141 1447 Benzoquinone 153 2587 Bisulfites, aqueous solution,
with more than 5% free n.o.s. 154 2693
Barium perchlorate, solid 141 1447 Benzotrichloride 156 2226
Sulphuric acid 153 2584 Bisulfites, inorganic,
Barium perchlorate, solution 141 3406 Benzotrifluoride 127 2338 aqueous solution, n.o.s. 154 2693
Aryl sulphonic acids, liquid,
with not more than 5% free Barium permanganate 141 1448 Benzoyl chloride 137 1736 Bisulphates, aqueous
Sulphuric acid 153 2586 Barium peroxide 141 1449 Benzyl bromide 156 1737 solution 154 2837
Aryl sulphonic acids, solid, Batteries, containing Sodium 138 3292 Benzyl chloride 156 1738 Bisulphites, aqueous
with more than 5% free solution, n.o.s. 154 2693
Sulphuric acid 153 2583 Batteries, dry, containing Benzyl chloroformate 137 1739 Bisulphites, inorganic,
Aryl sulphonic acids, solid, Potassium hydroxide solid 154 3028 Benzyldimethylamine 132 2619 aqueous solution, n.o.s. 154 2693
with not more than 5% free Batteries, nickel-metal Benzylidene chloride 156 1886 Blasting agent, n.o.s. 112 ——
Sulphuric acid 153 2585 hydride 171 3496
Benzyl iodide 156 2653 Bleaching powder 140 2208
Asbestos 171 2212 Batteries, wet, filled with
acid 154 2794 Beryllium compound, n.o.s. 154 1566 Blue asbestos 171 2212
Asbestos, blue 171 2212
Batteries, wet, filled with Beryllium nitrate 141 2464 Bombs, smoke,
Asbestos, brown 171 2212 alkali 154 2795 non-explosive, with corrosive
Beryllium powder 134 1567 liquid,without initiating
Asbestos, white 171 2590 Batteries, wet, non-spillable 154 2800 Bhusa, wet, damp or device 153 2028
Asphalt 130 1999 Battery fluid, acid 157 2796 contaminated with oil 133 1327
Borate and Chlorate mixtures 140 1458
Aviation regulated liquid, Battery fluid, alkali 154 2797 Bicyclo[2.2.1]hepta-2,5-diene,
n.o.s. 171 3334 Borneol 133 1312
Battery fluid, alkali, with stabilized 128P 2251
Aviation regulated solid, Boron tribromide 157 2692
n.o.s. 171 3335 battery 154 2797 Biological agents 158 ——
Boron trichloride 125 1741
Page 98 Page 99
93
Boron trifluoride 125 1008 Bromobenzyl cyanides 159 1694 n-Butylamine 132 1125 Butyronitrile 131 2411
Boron trifluoride, Bromobenzyl cyanides, liquid 159 1694 N-Butylaniline 153 2738 Butyryl chloride 132 2353
compressed 125 1008 Bromobenzyl cyanides, solid 159 1694 Butylbenzenes 128 2709 Buzz 153 2810
Boron trifluoride, dihydrate 157 2851 Bromobenzyl cyanides, solid 159 3449 n-Butyl bromide 130 1126 BZ 153 2810
Boron trifluoride acetic acid 1-Bromobutane 130 1126
complex 157 1742 Butyl chloride 130 1127 CA 159 1694
Boron trifluoride acetic acid 2-Bromobutane 130 2339 n-Butyl chloroformate 155 2743 Cacodylic acid 151 1572
complex, liquid 157 1742 Bromochlorodifluoromethane 126 1974 sec-Butyl chloroformate 155 2742 Cadmium compound 154 2570
Boron trifluoride acetic acid Bromochloromethane 160 1887 tert-Butylcyclohexyl Caesium 138 1407
complex, solid 157 3419 1-Bromo-3-chloropropane 159 2688 chloroformate 156 2747 Caesium hydroxide 157 2682
Boron trifluoride diethyl 2-Bromoethyl ethyl ether 130 2340
etherate 132 2604 Butylene 115 1012 Caesium hydroxide, solution 154 2681
Boron trifluoride dimethyl Bromoform 159 2515 Butylene 115 1075 Caesium nitrate 140 1451
etherate 139 2965 1-Bromo-3-methylbutane 130 2341 1,2-Butylene oxide, stabilized 127P 3022 Calcium 138 1401
Boron trifluoride propionic Bromomethylpropanes 130 2342 Butyl ethers 128 1149 Calcium, metal and alloys,
acid complex 157 1743 2-Bromo-2-nitropropane-1,3-diol 133 3241 n-Butyl formate 129 1128 pyrophoric 135 1855
Boron trifluoride propionic 2-Bromopentane 130 2343
acid complex, liquid 157 1743 tert-Butyl hypochlorite 135 3255 Calcium, pyrophoric 135 1855
Boron trifluoride propionic 2-Bromopropane 129 2344 N,n-Butylimidazole 152 2690 Calcium alloys, pyrophoric 135 1855
acid complex, solid 157 3420 Bromopropanes 129 2344 n-Butyl isocyanate 155 2485 Calcium arsenate 151 1573
Bromates, inorganic, aqueous 3-Bromopropyne 130 2345 tert-Butyl isocyanate 155 2484 Calcium arsenate and Calcium
solution, n.o.s. 140 3213 Bromotrifluoroethylene 116 2419 arsenite mixture, solid 151 1574
Butyl mercaptan 130 2347
Bromates, inorganic, n.o.s. 141 1450 Bromotrifluoromethane 126 1009 Calcium arsenite and Calcium
n-Butyl methacrylate,
Bromine 154 1744 Brown asbestos 171 2212 arsenate mixture, solid 151 1574
Bromine, solution 154 1744 stabilized 130P 2227
Brucine 152 1570 Calcium carbide 138 1402
Bromine, solution (Inhalation Butyl methyl ether 127 2350
Hazard Zone A) 154 1744 Butadienes, stabilized 116P 1010 Calcium chlorate 140 1452
Butyl nitrites 129 2351
Bromine, solution (Inhalation Butadienes and hydrocarbon Calcium chlorate, aqueous
Butyl propionates 130 1914
Hazard Zone B) 154 1744 mixture, stabilized 116P 1010 solution 140 2429
Butyltoluenes 152 2667
Bromine chloride 124 2901 Butane 115 1011 Calcium chlorate, solution 140 2429
Butyltrichlorosilane 155 1747
Bromine pentafluoride 144 1745 Butane 115 1075 Calcium chlorite 140 1453
5-tert-Butyl-2,4,6-trinitro-mxylene 149 2956
Bromine trifluoride 144 1746 Butanedione 127 2346 Calcium cyanamide, with
Butyl vinyl ether, stabilized 127P 2352 morethan 0.1% Calcium carbide 138 1403
Bromoacetic acid 156 1938 Butane mixture 115 1011
1,4-Butynediol 153 2716 Calcium cyanide 157 1575
Bromoacetic acid, solid 156 3425 Butane mixture 115 1075
Butyraldehyde 129 1129 Calcium dithionite 135 1923
Bromoacetic acid, solution 156 1938 Butanols 129 1120
Butyraldoxime 129 2840 Calcium hydride 138 1404
Bromoacetone 131 1569 Butyl acetates 129 1123
Butyric acid 153 2820 Calcium hydrosulfite 135 1923
Bromoacetyl bromide 156 2513 Butyl acid phosphate 153 1718
Butyric anhydride 156 2739 Calcium hydrosulphite 135 1923
Bromobenzene 130 2514 Butyl acrylates, stabilized 129P 2348
Page 100 Page 101

Calcium hypochlorite, dry 140 1748 Calcium phosphide 139 1360 Carbon dioxide and Ethylene Caustic potash, dry, solid 154 1813
Calcium hypochlorite, dry, Calcium resinate 133 1313 oxide mixture, with more Caustic potash, liquid 154 1814
corrosive, with more than than 9% but not more than
39% available chlorine Calcium resinate, fused 133 1314 87% Ethylene oxide 115 1041 Caustic potash, solution 154 1814
(8.8% available oxygen) 140 3485 Calcium silicide 138 1405 Carbon dioxide and Ethylene Caustic soda, bead 154 1823
Calcium hypochlorite, Camphor 133 2717 oxide mixture, with more Caustic soda, flake 154 1823
hydrated, corrosive, with than 87% Ethylene oxide 119P 3300
not less than 5.5% but not Camphor, synthetic 133 2717 Carbon dioxide and Ethylene Caustic soda, granular 154 1823
more than 16% water 140 3487 Camphor oil 128 1130 oxide mixtures, with more Caustic soda, solid 154 1823
Calcium hypochlorite, Capacitor, electric double than 6% Ethylene oxide 115 1041 Caustic soda, solution 154 1824
hydrated, with not less than layer 171 3499 Carbon dioxide and Ethylene Cells, containing Sodium 138 3292
5.5% but not more than 16% Caproic acid 153 2829
water 140 2880 oxide mixtures, with not Celluloid, in blocks, rods,
Calcium hypochlorite, Carbamate pesticide, liquid, more than 6% Ethylene oxide 126 1952 rolls, sheets, tubes, etc.,
hydrated mixture, corrosive, flammable, poisonous 131 2758 Carbon dioxide and Ethylene except scrap 133 2000
with not less than 5.5% but Carbamate pesticide, liquid, oxide mixtures, with not Celluloid, scrap 135 2002
not more than 16% water 140 3487 flammable, toxic 131 2758 more than 9% Ethylene Cerium, slabs, ingots or rods 170 1333
Calcium hypochlorite, Carbamate pesticide, liquid, oxide 126 1952
hydrated mixture, with not poisonous 151 2992 Carbon dioxide and Nitrous Cerium, turnings or gritty
less than 5.5% but not more oxide mixture 126 1015 powder 138 3078
than 16% water 140 2880 Carbamate pesticide, liquid, Cesium 138 1407
poisonous, flammable 131 2991 Carbon dioxide and Oxygen
Calcium hypochlorite mixture, Carbamate pesticide, liquid, mixture, compressed 122 1014 Cesium hydroxide 157 2682
dry, corrosive, with more Carbon disulfide 131 1131 Cesium hydroxide, solution 154 2681
than 10% but not more than toxic 151 2992
39% available chlorine 140 3486 Carbamate pesticide, liquid, Carbon disulphide 131 1131 Cesium nitrate 140 1451
Calcium hypochlorite mixture, toxic, flammable 131 2991 Carbon monoxide 119 1016 CG 125 1076
dry, corrosive, with more Carbamate pesticide, solid, Carbon monoxide, Charcoal 133 1361
than 39% available chlorine compressed 119 1016
(8.8% available oxygen) 140 3485 poisonous 151 2757 Chemical kit 154 1760
Calcium hypochlorite mixture, Carbamate pesticide, solid, Carbon monoxide, refrigerated Chemical kit 171 3316
dry, with more than 10% but liquid (cryogenic liquid) 168 9202
not more than 39% available toxic 151 2757 Carbon monoxide and Chemical sample, poisonous 151 3315
Chlorine 140 2208 Carbon, activated 133 1362 Hydrogen mixture, Chemical sample, poisonous
Calcium hypochlorite mixture, Carbon, animal or vegetable compressed 119 2600 liquid 151 3315
dry, with more than 39% origin 133 1361 Carbon tetrabromide 151 2516 Chemical sample, poisonous
available Chlorine (8.8% Carbon tetrachloride 151 1846 solid 151 3315
available Oxygen) 140 1748 Carbon bisulfide 131 1131 Chemical sample, toxic 151 3315
Calcium manganese silicon 138 2844 Carbon bisulphide 131 1131 Carbonyl fluoride 125 2417
Carbonyl fluoride, compressed 125 2417 Chemical sample, toxic liquid 151 3315
Calcium nitrate 140 1454 Carbon dioxide 120 1013 Chemical sample, toxic solid 151 3315
Calcium oxide 157 1910 Carbon dioxide, compressed 120 1013 Carbonyl sulfide 119 2204
Carbonyl sulphide 119 2204 Chemical under pressure,
Calcium perchlorate 140 1455 Carbon dioxide, refrigerated corrosive, n.o.s. 125 3503
Calcium permanganate 140 1456 liquid 120 2187 Castor beans, meal, pomace Chemical under pressure,
or flake 171 2969 flammable, corrosive, n.o.s. 118 3505
Calcium peroxide 140 1457 Carbon dioxide, solid 120 1845 Caustic alkali liquid, n.o.s. 154 1719
Page 102 Page 103

Chemical under pressure, Chloroacetic acid, solid 153 1751 Chlorodinitrobenzenes, liquid 153 1577 Chlorophenates, liquid 154 2904
flammable, n.o.s. 115 3501 Chloroacetic acid, solution 153 1750 Chlorodinitrobenzenes, solid 153 1577 Chlorophenates, solid 154 2905
Chemical under pressure, Chloroacetone, stabilized 131 1695 Chlorodinitrobenzenes, solid 153 3441 Chlorophenolates, liquid 154 2904
flammable, poisonous,
n.o.s. 119 3504 Chloroacetonitrile 131 2668 1-Chloro-2,3-epoxypropane 131P 2023 Chlorophenolates, solid 154 2905
Chemical under pressure, Chloroacetophenone 153 1697 2-Chloroethanal 153 2232 Chlorophenols, liquid 153 2021
flammable, toxic, n.o.s. 119 3504 Chloroacetophenone, liquid 153 1697 Chloroform 151 1888 Chlorophenols, solid 153 2020
Chemical under pressure, Chloroacetophenone, liquid 153 3416 Chloroformates, n.o.s. 155 2742 Chlorophenyltrichlorosilane 156 1753
n.o.s. 126 3500
Chemical under pressure, Chloroacetophenone, solid 153 1697 Chloroformates, poisonous, Chloropicrin 154 1580
poisonous, n.o.s. 123 3502 Chloroacetyl chloride 156 1752 corrosive, flammable, n.o.s. 155 2742 Chloropicrin and Methyl
Chemical under pressure, toxic, Chloroanilines, liquid 152 2019 Chloroformates, poisonous, bromide mixture 123 1581
n.o.s. 123 3502 corrosive, n.o.s. 154 3277 Chloropicrin and Methyl
Chloroanilines, solid 152 2018
Chloral, anhydrous, stabilized 153 2075 Chloroformates, toxic, chloride mixture 119 1582
Chloroanisidines 152 2233 corrosive, flammable, n.o.s. 155 2742
Chlorate and Borate mixtures 140 1458 Chloropicrin mixture, n.o.s. 154 1583
Chlorobenzene 130 1134 Chloroformates, toxic,
Chlorate and Magnesium Chloropivaloyl chloride 156 9263
chloride mixture 140 1459 Chlorobenzotrifluorides 130 2234 corrosive, n.o.s. 154 3277
Chloroplatinic acid, solid 154 2507
Chlorate and Magnesium Chlorobenzyl chlorides 153 2235 Chloromethyl chloroformate 157 2745
Chloroprene, stabilized 131P 1991
chloride mixture, solid 140 1459 Chlorobenzyl chlorides, liquid 153 2235 Chloromethyl ethyl ether 131 2354
1-Chloropropane 129 1278
Chlorate and Magnesium Chlorobenzyl chlorides, solid 153 3427 3-Chloro-4-methylphenyl
chloride mixture, solution 140 3407 isocyanate 156 2236 2-Chloropropane 129 2356
1-Chloro-3-bromopropane 159 2688
Chlorates, inorganic, aqueous 3-Chloro-4-methylphenyl 3-Chloropropanol-1 153 2849
solution, n.o.s. 140 3210 Chlorobutanes 130 1127
isocyanate, liquid 156 2236 2-Chloropropene 130P 2456
Chlorates, inorganic, n.o.s. 140 1461 Chlorocresols 152 2669
3-Chloro-4-methylphenyl 2-Chloropropionic acid 153 2511
Chloric acid, aqueous Chlorocresols, liquid 152 2669 isocyanate, solid 156 3428 2-Chloropropionic acid, solid 153 2511
solution, with not more than Chlorocresols, solid 152 2669 Chloronitroanilines 153 2237 2-Chloropropionic acid,
10% Chloric acid 140 2626 Chlorocresols, solid 152 3437 Chloronitrobenzenes 152 1578 solution 153 2511
Chlorine 124 1017 Chlorocresols, solution 152 2669 Chloronitrobenzenes, liquid 152 1578 2-Chloropyridine 153 2822
Chlorine dioxide, hydrate, Chlorodifluorobromomethane 126 1974 Chloronitrobenzenes, liquid 152 3409 Chlorosilanes, corrosive,
frozen 143 9191
1-Chloro-1,1-difluoroethane 115 2517 Chloronitrobenzenes, solid 152 1578 flammable, n.o.s. 155 2986
Chlorine pentafluoride 124 2548
Chlorodifluoroethanes 115 2517 Chloronitrotoluenes 152 2433 Chlorosilanes, corrosive,
Chlorine trifluoride 124 1749 n.o.s. 156 2987
Chlorodifluoromethane 126 1018 Chloronitrotoluenes, liquid 152 2433
Chlorite solution 154 1908 Chlorosilanes, flammable,
Chlorodifluoromethane and Chloronitrotoluenes, solid 152 2433
Chlorite solution, with more corrosive, n.o.s. 155 2985
than 5% available Chlorine 154 1908 Chloropentafluoroethane Chloronitrotoluenes, solid 152 3457 Chlorosilanes, n.o.s. 155 2985
Chlorites, inorganic, n.o.s. 143 1462 mixture 126 1973 Chloropentafluoroethane 126 1020 Chlorosilanes, n.o.s. 155 2986
Chloroacetaldehyde 153 2232 Chlorodinitrobenzenes 153 1577 Chloropentafluoroethane and Chlorosilanes, n.o.s. 156 2987
Chloroacetic acid, liquid 153 1750 Chlorodifluoromethane
mixture 126 1973
Chloroacetic acid, molten 153 3250
Page 104 Page 105

Chlorosilanes, n.o.s. 139 2988 Chlorotrifluoromethane and Compressed gas, flammable, Compressed gas, poisonous,
Trifluoromethane azeotropic poisonous, n.o.s. flammable, corrosive, n.o.s.
Chlorosilanes, poisonous, mixture with approximately (Inhalation Hazard Zone A) 119 1953 (Inhalation Hazard Zone A) 119 3305
corrosive, flammable, n.o.s. 155 3362 60% Chlorotrifluoromethane 126 2599 Compressed gas, flammable, Compressed gas, poisonous,
Chlorosilanes, poisonous, Chromic acid, solution 154 1755 poisonous, n.o.s. flammable, corrosive, n.o.s.
corrosive, n.o.s. 156 3361 (Inhalation Hazard Zone B) 119 1953 (Inhalation Hazard Zone B) 119 3305
Chlorosilanes, toxic, Chromic fluoride, solid 154 1756
Compressed gas, flammable, Compressed gas, poisonous,
corrosive, flammable, n.o.s. 155 3362 Chromic fluoride, solution 154 1757 poisonous, n.o.s. flammable, corrosive, n.o.s.
Chlorosilanes, toxic, Chromium nitrate 141 2720 (Inhalation Hazard Zone C) 119 1953 (Inhalation Hazard Zone C) 119 3305
corrosive, n.o.s. 156 3361 Chromium oxychloride 137 1758 Compressed gas, flammable, Compressed gas, poisonous,
Chlorosilanes, water-reactive, poisonous, n.o.s. flammable, corrosive, n.o.s.
flammable, corrosive, n.o.s. 139 2988 Chromium trioxide, anhydrous 141 1463 (Inhalation Hazard Zone D) 119 1953 (Inhalation Hazard Zone D) 119 3305
Chlorosulfonic acid 137 1754 Chromosulfuric acid 154 2240 Compressed gas, flammable, Compressed gas, poisonous,
flammable, n.o.s. 119 1953
Chlorosulfonic acid and Sulfur Chromosulphuric acid 154 2240 toxic, n.o.s. (Inhalation
Hazard Zone A) 119 1953 Compressed gas, poisonous,
trioxide mixture 137 1754 CK 125 1589 flammable, n.o.s.
Chlorosulphonic acid 137 1754 Clinical specimens 158 3373 Compressed gas, flammable, (Inhalation Hazard Zone A) 119 1953
toxic, n.o.s. (Inhalation
Chlorosulphonic acid and Clinical waste, unspecified, Hazard Zone B) 119 1953 Compressed gas, poisonous,
Sulphur trioxide mixture 137 1754 n.o.s. 158 3291 flammable, n.o.s.
Compressed gas, flammable, (Inhalation Hazard Zone B) 119 1953
1-Chloro-1,2,2,2- CN 153 1697 toxic, n.o.s. (Inhalation
tetrafluoroethane 126 1021 Hazard Zone C) 119 1953 Compressed gas, poisonous,
Coal gas 119 1023 flammable, n.o.s.
Chlorotetrafluoroethane 126 1021 Coal gas, compressed 119 1023 Compressed gas, flammable, (Inhalation Hazard Zone C) 119 1953
Chlorotetrafluoroethane and toxic, n.o.s. (Inhalation
Coal tar distillates, flammable 128 1136 Hazard Zone D) 119 1953 Compressed gas, poisonous,
Ethylene oxide mixture, flammable, n.o.s.
with not more than 8.8% Coating solution 127 1139 Compressed gas, n.o.s. 126 1956 (Inhalation Hazard Zone D) 119 1953
Ethylene oxide 126 3297 Cobalt naphthenates, powder 133 2001 Compressed gas, oxidizing, Compressed gas, poisonous,
Chlorotoluenes 129 2238 n.o.s. 122 3156 n.o.s. 123 1955
Cobalt resinate, precipitated 133 1318
4-Chloro-o-toluidine Compressed gas, poisonous, Compressed gas, poisonous,
hydrochloride 153 1579 Combustible liquid, n.o.s. 128 1993 corrosive, n.o.s. 123 3304 n.o.s. (Inhalation Hazard
Compound, cleaning liquid Zone A) 123 1955
4-Chloro-o-toluidine (corrosive) 154 1760 Compressed gas, poisonous,
hydrochloride, solid 153 1579 corrosive, n.o.s. (Inhalation Compressed gas, poisonous,
Compound, cleaning liquid Hazard Zone A) 123 3304 n.o.s. (Inhalation Hazard
4-Chloro-o-toluidine (flammable) 128 1993 Zone B) 123 1955
hydrochloride, solution 153 3410 Compressed gas, poisonous,
Compound, tree or weed corrosive, n.o.s. (Inhalation Compressed gas, poisonous,
Chlorotoluidines 153 2239 killing, liquid (corrosive) 154 1760 Hazard Zone B) 123 3304 n.o.s. (Inhalation Hazard
Chlorotoluidines, liquid 153 2239 Zone C) 123 1955
Compound, tree or weed Compressed gas, poisonous, Compressed gas, poisonous,
Chlorotoluidines, liquid 153 3429 killing, liquid (flammable) 128 1993 corrosive, n.o.s. (Inhalation n.o.s. (Inhalation Hazard
Chlorotoluidines, solid 153 2239 Compound, tree or weed Hazard Zone C) 123 3304 Zone D) 123 1955
1-Chloro-2,2,2-trifluoroethane 126 1983 killing, liquid (toxic) 153 2810 Compressed gas, poisonous, Compressed gas, poisonous,
Compressed gas, flammable, corrosive, n.o.s. (Inhalation oxidizing, corrosive, n.o.s. 124 3306
Chlorotrifluoroethane 126 1983 n.o.s. 115 1954 Hazard Zone D) 123 3304
Compressed gas, poisonous,
Chlorotrifluoromethane 126 1022 Compressed gas, poisonous, oxidizing, corrosive, n.o.s.
flammable, corrosive, n.o.s. 119 3305 (Inhalation Hazard Zone A) 124 3306
Page 106 Page 107

Compressed gas, poisonous, Compressed gas, toxic, Compressed gas, toxic, Corrosive liquid, acidic,
oxidizing, corrosive, n.o.s. flammable, corrosive, n.o.s. oxidizing, n.o.s. 124 3303 organic, n.o.s. 153 3265
(Inhalation Hazard Zone B) 124 3306 (Inhalation Hazard Zone C) 119 3305 Compressed gas, toxic, Corrosive liquid, basic,
Compressed gas, poisonous, Compressed gas, toxic, oxidizing, n.o.s. (Inhalation inorganic, n.o.s. 154 3266
oxidizing, corrosive, n.o.s. flammable, corrosive, n.o.s. Hazard Zone A) 124 3303
(Inhalation Hazard Zone C) 124 3306 (Inhalation Hazard Zone D) 119 3305 Corrosive liquid, basic,
Compressed gas, toxic, organic, n.o.s. 153 3267
Compressed gas, poisonous, Compressed gas, toxic, oxidizing, n.o.s. (Inhalation
oxidizing, corrosive, n.o.s. flammable, n.o.s. 119 1953 Hazard Zone B) 124 3303 Corrosive liquid, flammable,
(Inhalation Hazard Zone D) 124 3306 n.o.s. 132 2920
Compressed gas, toxic, Compressed gas, toxic, Corrosive liquid, n.o.s. 154 1760
Compressed gas, poisonous, flammable, n.o.s. oxidizing, n.o.s. (Inhalation
oxidizing, n.o.s. 124 3303 (Inhalation Hazard Zone A) 119 1953 Hazard Zone C) 124 3303 Corrosive liquid, oxidizing,
Compressed gas, poisonous, Compressed gas, toxic, Compressed gas, toxic, n.o.s. 140 3093
oxidizing, n.o.s. (Inhalation flammable, n.o.s. oxidizing, n.o.s. (Inhalation Corrosive liquid, poisonous,
Hazard Zone A) 124 3303
(Inhalation Hazard Zone B) 119 1953 Hazard Zone D) 124 3303 n.o.s. 154 2922
Compressed gas, poisonous,
oxidizing, n.o.s. (Inhalation Compressed gas, toxic, Consumer commodity 171 8000 Corrosive liquid, self-heating,
Hazard Zone B) 124 3303 flammable, n.o.s. Copper acetoarsenite 151 1585 n.o.s. 136 3301
(Inhalation Hazard Zone C) 119 1953 Corrosive liquid, toxic, n.o.s. 154 2922
Compressed gas, poisonous, Copper arsenite 151 1586
oxidizing, n.o.s. (Inhalation Compressed gas, toxic, Corrosive liquid, waterreactive,
Hazard Zone C) 124 3303 flammable, n.o.s. Copper based pesticide, n.o.s. 138 3094
(Inhalation Hazard Zone D) 119 1953 liquid, flammable,
Compressed gas, poisonous, poisonous 131 2776 Corrosive liquid, which in
oxidizing, n.o.s. (Inhalation Compressed gas, toxic, n.o.s. 123 1955 contact with water emits
Hazard Zone D) 124 3303 Compressed gas, toxic, n.o.s. Copper based pesticide, flammable gases, n.o.s. 138 3094
(Inhalation Hazard Zone A) 123 1955 liquid, flammable, toxic 131 2776
Compressed gas, toxic, Corrosive solid, acidic,
corrosive, n.o.s. 123 3304 Compressed gas, toxic, n.o.s. Copper based pesticide, inorganic, n.o.s. 154 3260
Compressed gas, toxic, (Inhalation Hazard Zone B) 123 1955 liquid, poisonous 151 3010
corrosive, n.o.s. (Inhalation Copper based pesticide, Corrosive solid, acidic,
Hazard Zone A) 123 3304 Compressed gas, toxic, n.o.s. liquid, poisonous, organic, n.o.s. 154 3261
(Inhalation Hazard Zone C) 123 1955 flammable 131 3009 Corrosive solid, basic,
Compressed gas, toxic,
corrosive, n.o.s. (Inhalation Compressed gas, toxic, n.o.s. Copper based pesticide, inorganic, n.o.s. 154 3262
Hazard Zone B) 123 3304 (Inhalation Hazard Zone D) 123 1955 liquid, toxic 151 3010 Corrosive solid, basic,
Compressed gas, toxic, Compressed gas, toxic, Copper based pesticide, organic, n.o.s. 154 3263
corrosive, n.o.s. (Inhalation oxidizing, corrosive, n.o.s. 124 3306 liquid, toxic, flammable 131 3009 Corrosive solid, flammable,
Hazard Zone C) 123 3304 Compressed gas, toxic, n.o.s. 134 2921
oxidizing, corrosive, n.o.s. Copper based pesticide, solid,
Compressed gas, toxic, poisonous 151 2775 Corrosive solid, n.o.s. 154 1759
corrosive, n.o.s. (Inhalation (Inhalation Hazard Zone A) 124 3306
Hazard Zone D) 123 3304 Compressed gas, toxic, Copper based pesticide, solid, Corrosive solid, oxidizing,
oxidizing, corrosive, n.o.s. toxic 151 2775 n.o.s. 140 3084
flammable, corrosive, n.o.s. 119 3305 (Inhalation Hazard Zone B) 124 3306 Copper chlorate 141 2721 Corrosive solid, poisonous,
Compressed gas, toxic, Copper chloride 154 2802 n.o.s. 154 2923
flammable, corrosive, n.o.s. oxidizing, corrosive, n.o.s. Copper cyanide 151 1587 Corrosive solid, self-heating,
(Inhalation Hazard Zone A) 119 3305 (Inhalation Hazard Zone C) 124 3306 n.o.s. 136 3095
Compressed gas, toxic, Copra 135 1363 Corrosive solid, toxic, n.o.s. 154 2923
flammable, corrosive, n.o.s. oxidizing, corrosive, n.o.s. Corrosive liquid, acidic, Corrosive solid, waterreactive,
(Inhalation Hazard Zone B) 119 3305 (Inhalation Hazard Zone D) 124 3306 inorganic, n.o.s. 154 3264 n.o.s. 138 3096
Page 108 Page 109

Corrosive solid, which in Cumene 130 1918 Cyclopentane 128 1146 Dibromochloropropanes 159 2872
contact with water emits Cupriethylenediamine, Cyclopentanol 129 2244 Dibromodifluoromethane 171 1941
flammable gases, n.o.s. 138 3096 solution 154 1761 Cyclopentanone 128 2245 Dibromomethane 160 2664
Cotton 133 1365 CX 154 2811 Cyclopentene 128 2246 Di-n-butylamine 132 2248
Cotton, wet 133 1365 Cyanide solution, n.o.s. 157 1935 Cyclopropane 115 1027 Dibutylaminoethanol 153 2873
Cotton waste, oily 133 1364 Cyanides, inorganic, n.o.s. 157 1588 Cymenes 130 2046 Dibutyl ethers 128 1149
Coumarin derivative pesticide,
liquid, flammable, Cyanides, inorganic, solid, DA 151 1699 Dichloroacetic acid 153 1764
poisonous 131 3024 n.o.s. 157 1588 Dangerous goods in apparatus 171 3363 1,3-Dichloroacetone 153 2649
Coumarin derivative pesticide, Cyanogen 119 1026 Dangerous goods in machinery 171 3363 Dichloroacetyl chloride 156 1765
liquid, flammable, toxic 131 3024 Cyanogen bromide 157 1889 DC 153 2810 Dichloroanilines 153 1590
Coumarin derivative pesticide, Cyanogen chloride, stabilized 125 1589
liquid, poisonous 151 3026 Decaborane 134 1868 Dichloroanilines, liquid 153 1590
Cyanogen gas 119 1026 Decahydronaphthalene 130 1147 Dichloroanilines, solid 153 1590
Coumarin derivative
pesticide, liquid, poisonous, Cyanuric chloride 157 2670 n-Decane 128 2247 Dichloroanilines, solid 153 3442
flammable 131 3025 Cyclobutane 115 2601 Desensitized explosive, liquid, o-Dichlorobenzene 152 1591
Coumarin derivative pesticide, Cyclobutyl chloroformate 155 2744 n.o.s. 128 3379
2,2'-Dichlorodiethyl ether 152 1916
liquid, toxic 151 3026 Desensitized explosive, solid,
1,5,9-Cyclododecatriene 153 2518 Dichlorodifluoromethane 126 1028
Coumarin derivative pesticide, n.o.s. 133 3380
liquid, toxic, flammable 131 3025 Cycloheptane 128 2241 Dichlorodifluoromethane
Deuterium 115 1957
Coumarin derivative pesticide, Cycloheptatriene 131 2603 and Difluoroethane
Deuterium, compressed 115 1957 azeotropic mixture with
solid, poisonous 151 3027 Cycloheptene 128 2242
Devices, small, hydrocarbon approximately 74%
Coumarin derivative pesticide, Cyclohexane 128 1145 gas powered, with release Dichlorodifluoromethane 126 2602
solid, toxic 151 3027 Cyclohexanethiol 129 3054 device 115 3150 Dichlorodifluoromethane and
Cresols 153 2076 Cyclohexanone 127 1915 Diacetone alcohol 129 1148 Ethylene oxide mixture,
Cresols, liquid 153 2076 with not more than 12.5%
Cyclohexene 130 2256 Diacetyl 127 2346 Ethylene oxide 126 3070
Cresols, solid 153 2076 Diagnostic specimens 158 3373
Cyclohexenyltrichlorosilane 156 1762 Dichlorodifluoromethane and
Cresols, solid 153 3455 Diallylamine 132 2359 Ethylene oxide mixtures,
Cyclohexyl acetate 130 2243
Cresylic acid 153 2022 Diallyl ether 131P 2360 with not more than 12%
Cyclohexylamine 132 2357 Ethylene oxide 126 3070
Crotonaldehyde 131P 1143 4,4'-Diaminodiphenylmethane 153 2651
Cyclohexyl isocyanate 155 2488 Dichlorodimethyl ether,
Crotonaldehyde, stabilized 131P 1143 Di-n-amylamine 131 2841
Cyclohexyl mercaptan 129 3054 symmetrical 131 2249
Crotonic acid 153 2823
Cyclohexyltrichlorosilane 156 1763 Dibenzyldichlorosilane 156 2434 1,1-Dichloroethane 130 2362
Crotonic acid, liquid 153 2823
Cyclooctadiene phosphines 135 2940 Diborane 119 1911 1,2-Dichloroethylene 130P 1150
Crotonic acid, liquid 153 3472
Cyclooctadienes 130P 2520 Diborane, compressed 119 1911 Dichloroethylene 130P 1150
Crotonic acid, solid 153 2823
Cyclooctatetraene 128P 2358 Diborane mixtures 119 1911 Dichloroethyl ether 152 1916
Crotonylene 128 1144
1,2-Dibromobutan-3-one 154 2648
CS 153 2810
Page 110 Page 111

Dichlorofluoromethane 126 1029 N,N-Diethylaniline 153 2432 Diisopropyl ether 127 1159 Dimethylhydrazine,
Dichloroisocyanuric acid, dry 140 2465 Diethylbenzene 130 2049 Diketene, stabilized 131P 2521 symmetrical 131 2382
Dichloroisocyanuric acid salts 140 2465 Diethyl carbonate 128 2366 1,1-Dimethoxyethane 127 2377 Dimethylhydrazine,
unsymmetrical 131 1163
Dichloroisopropyl ether 153 2490 Diethyldichlorosilane 155 1767 1,2-Dimethoxyethane 127 2252
2,2-Dimethylpropane 115 2044
Dichloromethane 160 1593 Diethylenetriamine 154 2079 Dimethylamine, anhydrous 118 1032
Dimethyl-N-propylamine 132 2266
1,1-Dichloro-1-nitroethane 153 2650 Diethyl ether 127 1155 Dimethylamine, aqueous Dimethyl sulfate 156 1595
Dichloropentanes 130 1152 N,N-Diethylethylenediamine 132 2685 solution 132 1160
Dimethyl sulfide 130 1164
Dichlorophenyl isocyanates 156 2250 Diethyl ketone 127 1156 Dimethylamine, solution 132 1160
Dimethyl sulphate 156 1595
Dichlorophenyltrichlorosilane 156 1766 Diethyl sulfate 152 1594 2-Dimethylaminoacetonitrile 131 2378
Dimethyl sulphide 130 1164
1,2-Dichloropropane 130 1279 Diethyl sulfide 129 2375 2-Dimethylaminoethanol 132 2051
Dimethyl thiophosphoryl
Dichloropropane 130 1279 Diethyl sulphate 152 1594 2-Dimethylaminoethyl acrylate 152 3302
chloride 156 2267
1,3-Dichloropropanol-2 153 2750 Diethyl sulphide 129 2375 2-Dimethylaminoethyl
methacrylate 153P 2522 Dimethylzinc 135 1370
Dichloropropenes 129 2047 Diethylthiophosphoryl chloride 155 2751 Dinitroanilines 153 1596
Dimethylaminoethyl
Dichlorosilane 119 2189 Diethylzinc 135 1366 methacrylate 153P 2522 Dinitrobenzenes 152 1597
1,2-Dichloro-1,1,2,2- Difluorochloroethanes 115 2517 N,N-Dimethylaniline 153 2253 Dinitrobenzenes, liquid 152 1597
tetrafluoroethane 126 1958 1,1-Difluoroethane 115 1030 Dinitrobenzenes, solid 152 1597
2,3-Dimethylbutane 128 2457
Dichlorotetrafluoroethane 126 1958 Difluoroethane 115 1030 Dinitrobenzenes, solid 152 3443
1,3-Dimethylbutylamine 132 2379
3,5-Dichloro-2,4,6- Difluoroethane and Dinitrochlorobenzenes 153 1577
Dimethylcarbamoyl chloride 156 2262
trifluoropyridine 151 9264 Dichlorodifluoromethane Dinitro-o-cresol 153 1598
Dimethyl carbonate 129 1161
Dicyclohexylamine 153 2565 azeotropic mixture with Dinitrogen tetroxide 124 1067
approximately 74% Dimethylcyclohexanes 128 2263
Dicyclohexylammonium nitrite 133 2687 Dinitrogen tetroxide and Nitric
Dichlorodifluoromethane 126 2602 N,N-Dimethylcyclohexylamine 132 2264
Dicyclopentadiene 130 2048 oxide mixture 124 1975
1,1-Difluoroethylene 116P 1959 Dimethylcyclohexylamine 132 2264
1,2-Di-(dimethylamino)ethane 129 2372 Dinitrophenol, solution 153 1599
Difluoromethane 115 3252 Dimethyldichlorosilane 155 1162
Didymium nitrate 140 1465 Dinitrophenol, wetted with not
Difluorophosphoric acid, Dimethyldiethoxysilane 127 2380 less than 15% water 113 1320
Diesel fuel 128 1202
anhydrous 154 1768 Dimethyldioxanes 127 2707 Dinitrophenolates, wetted with
Diesel fuel 128 1993
2,3-Dihydropyran 127 2376 Dimethyl disulfide 130 2381 not less than 15% water 113 1321
Diethoxymethane 127 2373
Diisobutylamine 132 2361 Dimethyl disulphide 130 2381 Dinitroresorcinol, wetted with
3,3-Diethoxypropene 127 2374 not less than 15% water 113 1322
Diisobutylene, isomeric Dimethylethanolamine 132 2051
Diethylamine 132 1154 compounds 128 2050 Dinitrotoluenes 152 2038
Dimethyl ether 115 1033
2-Diethylaminoethanol 132 2686 Diisobutyl ketone 128 1157 Dinitrotoluenes, liquid 152 2038
N,N-Dimethylformamide 129 2265
Diethylaminoethanol 132 2686 Diisooctyl acid phosphate 153 1902 Dinitrotoluenes, molten 152 1600
1,1-Dimethylhydrazine 131 1163
3-Diethylaminopropylamine 132 2684 Diisopropylamine 132 1158 Dinitrotoluenes, solid 152 2038
1,2-Dimethylhydrazine 131 2382 Dinitrotoluenes, solid 152 3454
Diethylaminopropylamine 132 2684
Page 112 Page 113

Dioxane 127 1165 Disodium trioxosilicate, Dye intermediate, liquid, toxic, Esters, n.o.s. 127 3272
Dioxolane 127 1166 pentahydrate 154 3253 n.o.s. 151 1602 Ethane 115 1035
Dipentene 128 2052 Dispersant gas, n.o.s. 126 1078 Dye intermediate, solid, Ethane, compressed 115 1035
Dispersant gas, n.o.s. corrosive, n.o.s. 154 3147
Diphenylamine chloroarsine 154 1698 Ethane, refrigerated liquid 115 1961
(flammable) 115 1954 Dye intermediate, solid,
Diphenylchloroarsine 151 1699 poisonous, n.o.s. 151 3143 Ethane-Propane mixture,
Dithiocarbamate pesticide, refrigerated liquid 115 1961
Diphenylchloroarsine, liquid 151 1699 liquid, flammable, Dye intermediate, solid, toxic,
Diphenylchloroarsine, solid 151 1699 poisonous 131 2772 n.o.s. 151 3143 Ethanol 127 1170
Diphenylchloroarsine, solid 151 3450 Dithiocarbamate pesticide, ED 151 1892 Ethanol and gasoline mixture,
liquid, flammable, toxic 131 2772 with more than 10% ethanol 127 3475
Diphenyldichlorosilane 156 1769 Elevated temperature liquid,
Dithiocarbamate pesticide, flammable, n.o.s., with flash Ethanol and motor spirit
Diphenylmethyl bromide 153 1770 mixture, with more than 10%
liquid, poisonous 151 3006 point above 37.8oC (100oF),
Diphosgene 125 1076 at or above its flash point 128 3256 ethanol 127 3475
Dithiocarbamate pesticide,
Dipicryl sulfide, wetted with liquid, poisonous, Elevated temperature liquid, Ethanol and petrol mixture,
not less than 10% water 113 2852 flammable 131 3005 flammable, n.o.s., with flash with more than 10% ethanol 127 3475
Dipicryl sulphide, wetted with Dithiocarbamate pesticide, point above 60oC (140oF), at Ethanol, solution 127 1170
not less than 10% water 113 2852 liquid, toxic 151 3006 or above its flash point 128 3256 Ethanolamine 153 2491
Dipropylamine 132 2383 Dithiocarbamate pesticide, Elevated temperature liquid, Ethers, n.o.s. 127 3271
Di-n-propyl ether 127 2384 liquid, toxic, flammable 131 3005 n.o.s., at or above 100oC
(212oF), and below its flash Ethyl acetate 129 1173
Dipropyl ether 127 2384 Dithiocarbamate pesticide, point 128 3257 Ethylacetylene, stabilized 116P 2452
Dipropyl ketone 128 2710 solid, poisonous 151 2771
Elevated temperature solid, Ethyl acrylate, stabilized 129P 1917
Disinfectant, liquid, corrosive, Dithiocarbamate pesticide, n.o.s., at or above 240oC Ethyl alcohol 127 1170
n.o.s. 153 1903 solid, toxic 151 2771 (464oF) 171 3258
Divinyl ether, stabilized 128P 1167 Ethyl alcohol, solution 127 1170
Disinfectant, liquid, Engine, fuel cell, flammable
poisonous, n.o.s. 151 3142 DM 154 1698 gas powered 128 3166 Ethylamine 118 1036
Disinfectant, liquid, toxic, Dodecyltrichlorosilane 156 1771 Engine, fuel cell, flammable Ethylamine, aqueous solution,
n.o.s. 151 3142 DP 125 1076 liquid powered 128 3166 with not less than 50%
but not more than 70%
Disinfectant, solid, poisonous, Dry ice 120 1845 Engine, internal combustion 128 3166 Ethylamine 132 2270
n.o.s. 151 1601 Dye, liquid, corrosive, n.o.s. 154 2801 Engines, internal combustion, Ethyl amyl ketone 128 2271
Disinfectant, solid, toxic, Dye, liquid, poisonous, n.o.s. 151 1602 flammable gas powered 128 3166
n.o.s. 151 1601 2-Ethylaniline 153 2273
Dye, liquid, toxic, n.o.s. 151 1602 Engines, internal combustion,
Disinfectants, corrosive, flammable liquid powered 128 3166 N-Ethylaniline 153 2272
Dye, solid, corrosive, n.o.s. 154 3147
liquid, n.o.s. 153 1903 Dye, solid, poisonous, n.o.s. 151 3143 Environmentally hazardous Ethylbenzene 130 1175
Disinfectants, liquid, n.o.s. Dye, solid, toxic, n.o.s. 151 3143 substances, liquid, n.o.s. 171 3082 N-Ethyl-N-benzylaniline 153 2274
(poisonous) 151 3142 Environmentally hazardous N-Ethylbenzyltoluidines 153 2753
Dye intermediate, liquid,
Disinfectants, solid, n.o.s. corrosive, n.o.s. 154 2801 substances, solid, n.o.s. 171 3077 N-Ethylbenzyltoluidines, liquid 153 2753
(poisonous) 151 1601 Epibromohydrin 131 2558
Dye intermediate, liquid, N-Ethylbenzyltoluidines, solid 153 2753
Disodium trioxosilicate 154 3253 poisonous, n.o.s. 151 1602 Epichlorohydrin 131P 2023 N-Ethylbenzyltoluidines, solid 153 3460
1,2-Epoxy-3-ethoxypropane 127 2752
Page 114 Page 115

Ethyl borate 129 1176 Ethylene oxide and Propylene Ethylsulfuric acid 156 2571
Ethyl bromide 131 1891 Ethylene glycol monoethyl oxide mixture, with not more Ethylsulphuric acid 156 2571
Ethyl bromoacetate 155 1603 ether 127 1171 than 30% Ethylene oxide 129P 2983 N-Ethyltoluidines 153 2754
2-Ethylbutanol 129 2275 Ethylene glycol monoethyl Ethylene oxide and Ethyltrichlorosilane 155 1196
ether acetate 129 1172
2-Ethylbutyl acetate 130 1177 Tetrafluoroethane mixture, Explosives, division 1.1, 1.2,
Ethylene glycol monomethyl with not more than 5.6%
Ethylbutyl acetate 130 1177 ether 127 1188 1.3 or 1.5 112 ——
Ethylene oxide 126 3299 Explosives, division 1.4 or 1.6 114 ——
Ethyl butyl ether 127 1179 Ethylene glycol monomethyl
ether acetate 129 1189 Ethylene oxide with Nitrogen 119P 1040 Extracts, aromatic, liquid 127 1169
2-Ethylbutyraldehyde 130 1178
Ethyleneimine, stabilized 131P 1185 Ethyl ether 127 1155 Extracts, flavoring, liquid 127 1197
Ethyl butyrate 130 1180
Ethylene oxide 119P 1040 Ethyl fluoride 115 2453 Extracts, flavouring, liquid 127 1197
Ethyl chloride 115 1037
Ethylene oxide and Carbon Ethyl formate 129 1190 Fabrics, animal or vegetable
Ethyl chloroacetate 155 1181 dioxide mixture, with more Ethylhexaldehydes 129 1191 or synthetic, n.o.s. with oil 133 1373
Ethyl chloroformate 155 1182 than 9% but not more than
87% Ethylene oxide 115 1041 2-Ethylhexylamine 132 2276 Fabrics impregnated
Ethyl 2-chloropropionate 129 2935
Ethylene oxide and Carbon 2-Ethylhexyl chloroformate 156 2748 with weakly nitrated
Ethyl chlorothioformate 155 2826 dioxide mixture, with more Ethyl isobutyrate 129 2385 Nitrocellulose, n.o.s. 133 1353
Ethyl crotonate 130 1862 than 87% Ethylene oxide 119P 3300
Ethyl isocyanate 155 2481 Ferric arsenate 151 1606
Ethyldichloroarsine 151 1892 Ethylene oxide and Carbon
dioxide mixtures, with more Ethyl lactate 129 1192 Ferric arsenite 151 1607
Ethyldichlorosilane 139 1183 than 6 % Ethylene oxide 115 1041 Ethyl mercaptan 129 2363 Ferric chloride 157 1773
Ethylene 116P 1962 Ethylene oxide and Carbon Ethyl methacrylate 130P 2277 Ferric chloride, anhydrous 157 1773
Ethylene, Acetylene and dioxide mixtures, with not
Propylene in mixture, more than 6% Ethylene oxide 126 1952 Ethyl methacrylate, stabilized 130P 2277 Ferric chloride, solution 154 2582
refrigerated liquid Ethylene oxide and Carbon Ethyl methyl ether 115 1039 Ferric nitrate 140 1466
dioxide mixtures, with not Ethyl methyl ketone 127 1193 Ferrocerium 170 1323
containing at least 71.5% more than 9% Ethylene oxide 126 1952
Ethylene with not more than Ethyl nitrite, solution 131 1194 Ferrosilicon 139 1408
Ethylene oxide and
22.5% Acetylene and not Chlorotetrafluoroethane Ethyl orthoformate 129 2524 Ferrous arsenate 151 1608
more than 6% Propylene 115 3138 mixture, with not more than Ethyl oxalate 156 2525 Ferrous chloride, solid 154 1759
8.8% Ethylene oxide 126 3297
Ethylene, compressed 116P 1962 Ethylphenyldichlorosilane 156 2435 Ferrous chloride, solution 154 1760
Ethylene oxide and
Ethylene, refrigerated liquid Dichlorodifluoromethane Ethyl phosphonothioic Ferrous metal borings,
(cryogenic liquid) 115 1038 mixture, with not more than dichloride, anhydrous 154 2927 shavings, turnings or
Ethylene chlorohydrin 131 1135 12.5% Ethylene oxide 126 3070
Ethyl phosphonous dichloride, cuttings 170 2793
Ethylenediamine 132 1604 Ethylene oxide and
Dichlorodifluoromethane anhydrous 135 2845 Fertilizer, ammoniating
Ethylene dibromide 154 1605 mixtures, with not more than Ethyl phosphorodichloridate 154 2927 solution, with free Ammonia 125 1043
Ethylene dibromide and Methyl 12% Ethylene oxide 126 3070
1-Ethylpiperidine 132 2386 Fiber, animal or vegetable,
bromide mixture, liquid 151 1647 Ethylene oxide and n.o.s., burnt, wet or damp 133 1372
Pentafluoroethane mixture, Ethyl propionate 129 1195
Ethylene dichloride 131 1184 with not more than 7.9% Ethyl propyl ether 127 2615 Fibers, animal or vegetable or
Ethylene glycol diethyl ether 127 1153 Ethylene oxide 126 3298 synthetic, n.o.s. with oil 133 1373
Ethyl silicate 129 1292
Page 116 Page 117

Fibers, animal or vegetable, Flammable solid, corrosive, Fluorotoluenes 130 2388 Fuel cell cartridges, containing
burnt, wet or damp 133 1372 n.o.s. 134 2925 water-reactive substances 138 3476
Fluosilicic acid 154 1778
Fibers, vegetable, dry 133 3360 Flammable solid, corrosive, Fuel cell cartridges packed
organic, n.o.s. 134 2925 Formaldehyde, solution, with equipment, containing
Fibers impregnated flammable 132 1198
with weakly nitrated Flammable solid, inorganic, corrosive substances 153 3477
Nitrocellulose, n.o.s. 133 1353 corrosive, n.o.s. 134 3180 Formaldehyde, solutions Fuel cell cartridges packed
(Formalin) 132 1198 with equipment, containing
Fibres, animal or vegetable, Flammable solid, inorganic,
burnt, wet or damp 133 1372 n.o.s. 133 3178 Formaldehyde, solutions flammable liquids 128 3473
Fibres, animal or vegetable or (Formalin) (corrosive) 132 2209
Flammable solid, n.o.s. 133 1325 Fuel cell cartridges packed
synthetic, n.o.s. with oil 133 1373 Formic acid 153 1779 with equipment, containing
Flammable solid, organic, hydrogen in metal hydride 115 3479
Fibres, vegetable, dry 133 3360 molten, n.o.s. 133 3176 Formic acid, with more than
Fibres impregnated 85% acid 153 1779 Fuel cell cartridges packed
Flammable solid, organic, with equipment, containing
with weakly nitrated n.o.s. 133 1325 Formic acid, with not less than
Nitrocellulose, n.o.s. 133 1353 5% but less than 10% acid 153 3412 liquefied flammable gas 115 3478
Flammable solid, oxidizing,
Films, nitrocellulose base 133 1324 n.o.s. 140 3097 Formic acid, with not less than Fuel cell cartridges packed
10% but not more than 85% acid 153 3412 with equipment, containing
Fire extinguisher charges, Flammable solid, poisonous, water-reactive substances 138 3476
corrosive liquid 154 1774 inorganic, n.o.s. 134 3179 Fuel, aviation, turbine engine 128 1863
Fire extinguishers with Fuel cell cartridges contained Fuel oil 128 1202
Flammable solid, poisonous,
compressed gas 126 1044 in equipment, containing Fuel oil 128 1993
n.o.s. 134 2926 corrosive substances 153 3477
Fire extinguishers with Fuel oil, no. 1,2,4,5,6 128 1202
liquefied gas 126 1044 Flammable solid, poisonous, Fuel cell cartridges contained
organic, n.o.s. 134 2926 Fumaryl chloride 156 1780
Firelighters, solid, with Flammable solid, toxic, in equipment, containing
flammable liquid 133 2623 flammable liquids 128 3473 Fumigated cargo transport unit 171 3359
inorganic, n.o.s. 134 3179
First aid kit 171 3316 Fuel cell cartridges contained Fumigated unit 171 3359
Flammable solid, toxic, in equipment, containing
Fish meal, stabilized 171 2216 organic, n.o.s. 134 2926 Furaldehydes 132P 1199
hydrogen in metal hydride 115 3479
Fish meal, unstabilized 133 1374 Fluoboric acid 154 1775 Furan 128 2389
Fuel cell cartridges contained
Fish scrap, stabilized 171 2216 Fluorine 124 1045 in equipment, containing
liquefied flammable gas 115 3478 Furfural 132P 1199
Fish scrap, unstabilized 133 1374 Fluorine, compressed 124 1045
Fuel cell cartridges contained Furfuraldehydes 132P 1199
Flammable liquid, corrosive, Fluoroacetic acid 154 2642
n.o.s 132 2924 in equipment, containing Furfuryl alcohol 153 2874
Fluoroanilines 153 2941 water-reactive substances 138 3476
Flammable liquid, n.o.s. 128 1993 Furfurylamine 132 2526
Fluorobenzene 130 2387 Fuel cell cartridges,
Flammable liquid, poisonous, containing corrosive Fusee (rail or highway) 133 1325
corrosive, n.o.s. 131 3286 Fluoroboric acid 154 1775 substances 153 3477
Fluorophosphoric acid, Fusel oil 127 1201
Flammable liquid, poisonous, Fuel cell cartridges,
n.o.s. 131 1992 anhydrous 154 1776 containing flammable liquids 128 3473 GA 153 2810
Flammable liquid, toxic, Fluorosilicates, n.o.s. 151 2856 Fuel cell cartridges, Gallium 172 2803
corrosive, n.o.s. 131 3286 Fluorosilicic acid 154 1778 containing hydrogen in Gas, refrigerated liquid,
Flammable liquid, toxic, n.o.s. 131 1992 Fluorosulfonic acid 137 1777 metal hydride 115 3479 flammable, n.o.s. 115 3312
Flammable solid, corrosive, Fluorosulphonic acid 137 1777 Fuel cell cartridges, containing Gas, refrigerated liquid, n.o.s. 120 3158
inorganic, n.o.s. 134 3180 liquefied flammable gas 115 3478
Page 118 Page 119

Gas, refrigerated liquid, Hafnium powder, dry 135 2545 Hexafluoroacetone Hydrazine, aqueous solution,
oxidizing, n.o.s. 122 3311 hydrate, solid 151 3436 with not more than 37%
Hafnium powder, wetted with
Gas cartridges 115 2037 not less than 25% water 170 1326 Hexafluoroethane 126 2193 Hydrazine 152 3293
Gas identification set 123 9035 Hay, wet, damp or Hexafluoroethane, compressed 126 2193 Hydrazine, aqueous solutions,
contaminated with oil 133 1327 with more than 64%
Gasohol 128 1203 Hexafluorophosphoric acid 154 1782 Hydrazine 132 2029
Gas oil 128 1202 Hazardous waste, liquid, n.o.s. 171 3082 Hexafluoropropylene 126 1858 Hydrazine hydrate 153 2030
Gasoline 128 1203 Hazardous waste, solid, n.o.s. 171 3077 Hexafluoropropylene, Hydrides, metal, n.o.s. 138 1409
HD 153 2810 compressed 126 1858
Gasoline and ethanol mixture, Hydriodic acid 154 1787
with more than 10% ethanol 127 3475 Hexaldehyde 130 1207
Heating oil, light 128 1202 Hydriodic acid, solution 154 1787
Hexamethylenediamine, solid 153 2280
Gas sample, non-pressurized, Helium 121 1046 Hydrobromic acid 154 1788
flammable, n.o.s., not Hexamethylenediamine,
refrigerated liquid 115 3167 Helium, compressed 121 1046 solution 153 1783 Hydrobromic acid, solution 154 1788
Gas sample, non-pressurized, Helium, refrigerated liquid Hexamethylene diisocyanate 156 2281 Hydrocarbon gas,
poisonous, flammable, n.o.s., (cryogenic liquid) 120 1963 compressed, n.o.s. 115 1964
Hexamethyleneimine 132 2493
not refrigerated liquid 119 3168 Heptafluoropropane 126 3296 Hydrocarbon gas, liquefied,
Hexamethylenetetramine 133 1328 n.o.s. 115 1965
Gas sample, non-pressurized, n-Heptaldehyde 129 3056
poisonous, n.o.s., not Hexamine 133 1328 Hydrocarbon gas mixture,
refrigerated liquid 123 3169 Heptanes 128 1206 Hexanes 128 1208 compressed, n.o.s. 115 1964
Gas sample, non-pressurized, n-Heptene 128 2278 Hexanoic acid 153 2829 Hydrocarbon gas mixture,
toxic, flammable, n.o.s., not liquefied, n.o.s. 115 1965
refrigerated liquid 119 3168 Hexachloroacetone 153 2661 Hexanols 129 2282
Hydrocarbon gas refills for
Gas sample, non-pressurized, Hexachlorobenzene 152 2729 1-Hexene 128 2370 small devices, with release
toxic, n.o.s., not Hexyltrichlorosilane 156 1784 device 115 3150
Hexachlorobutadiene 151 2279
refrigerated liquid 123 3169 HL 153 2810 Hydrocarbons, liquid, n.o.s. 128 3295
Hexachlorocyclopentadiene 151 2646
GB 153 2810 HN-1 153 2810 Hydrochloric acid 157 1789
Hexachlorophene 151 2875 Hydrochloric acid, solution 157 1789
GD 153 2810 HN-2 153 2810
Hexadecyltrichlorosilane 156 1781 Hydrocyanic acid, aqueous
Genetically modified HN-3 153 2810
microorganisms 171 3245 Hexadiene 130 2458 solution, with less than 5%
Hydrazine, anhydrous 132 2029 Hydrogen cyanide 154 1613
Genetically modified Hexaethyl tetraphosphate 151 1611 Hydrazine aqueous solution,
organisms 171 3245 Hydrocyanic acid, aqueous
Hexaethyl tetraphosphate, flammable, with more than solution, with not more than
Germane 119 2192 liquid 151 1611 37% hydrazine, by mass 132 3484 20% Hydrogen cyanide 154 1613
GF 153 2810 Hexaethyl tetraphosphate, solid 151 1611 Hydrazine, aqueous solution, Hydrocyanic acid, aqueous
with more than 37% solutions, with more than
Glycerol Hexaethyl tetraphosphate and 20% Hydrogen cyanide 117 1051
alphamonochlorohydrin 153 2689 compressed gas mixture 123 1612 Hydrazine 153 2030
Hydrazine, aqueous solution, Hydrofluoric acid 157 1790
Glycidaldehyde 131P 2622 Hexafluoroacetone 125 2420
with not less than 37% Hydrofluoric acid, solution 157 1790
Guanidine nitrate 143 1467 Hexafluoroacetone hydrate 151 2552 but not more than 64% Hydrofluoric acid and Sulfuric
H 153 2810 Hexafluoroacetone hydrate, Hydrazine 153 2030 acid mixture 157 1786
liquid 151 2552
Page 120 Page 121

Hydrofluoric acid and Hydrogendifluorides, solution, Hypochlorites, inorganic, Insecticide gas, toxic, n.o.s. 123 1967
Sulphuric acid mixture 157 1786 n.o.s. 154 3471 n.o.s. 140 3212 Iodine 154 3495
Hydrofluorosilicic acid 154 1778 Hydrogen fluoride, anhydrous 125 1052 3,3'-Iminodipropylamine 153 2269 Iodine monochloride, liquid 157 3498
Hydrogen 115 1049 Hydrogen iodide, anhydrous 125 2197 Infectious substance, Iodine monochloride, solid 157 1792
Hydrogen absorbed in metal Hydrogen peroxide, aqueous affecting animals only 158 2900
hydride 115 9279 solution, stabilized, with Infectious substance, Iodine pentafluoride 144 2495
Hydrogen, compressed 115 1049 more than 60% Hydrogen affecting humans 158 2814 2-Iodobutane 129 2390
peroxide 143 2015 Ink, printer's, flammable 129 1210 Iodomethylpropanes 129 2391
Hydrogen in a metal hydride Hydrogen peroxide, aqueous
storage system 115 3468 solution, with not less Insecticide gas, flammable, Iodopropanes 129 2392
Hydrogen in a metal hydride than 8% but less than 20% n.o.s. 115 3354 IPDI 156 2290
storage system contained in Hydrogen peroxide 140 2984 Insecticide gas, n.o.s. 126 1968 Iron oxide, spent 135 1376
equipment 115 3468 Hydrogen peroxide, aqueous Insecticide gas, poisonous,
Hydrogen in a metal hydride solution, with not less than flammable, n.o.s. 119 3355 Iron pentacarbonyl 131 1994
storage system packed with 20% but not more than Insecticide gas, poisonous, Iron sponge, spent 135 1376
equipment 115 3468 60% Hydrogen peroxide flammable, n.o.s. Isobutane 115 1075
Hydrogen, refrigerated liquid (stabilized as necessary) 140 2014 (Inhalation Hazard Zone A) 119 3355
(cryogenic liquid) 115 1966 Hydrogen peroxide, stabilized 143 2015 Isobutane 115 1969
Insecticide gas, poisonous, Isobutane mixture 115 1075
Hydrogen and Carbon Hydrogen peroxide and flammable, n.o.s.
monoxide mixture, Peroxyacetic acid mixture, (Inhalation Hazard Zone B) 119 3355 Isobutane mixture 115 1969
compressed 119 2600 with acid(s), water and not Insecticide gas, poisonous, Isobutanol 129 1212
Hydrogen and Methane more than 5% Peroxyacetic flammable, n.o.s.
mixture, compressed 115 2034 acid, stabilized 140 3149 (Inhalation Hazard Zone C) 119 3355 Isobutyl acetate 129 1213
Hydrogen bromide, anhydrous 125 1048 Hydrogen selenide, anhydrous 117 2202 Insecticide gas, poisonous, Isobutyl acrylate, stabilized 129P 2527
Hydrogen chloride, anhydrous 125 1050 Hydrogen sulfide 117 1053 flammable, n.o.s. Isobutyl alcohol 129 1212
Hydrogen sulphide 117 1053 (Inhalation Hazard Zone D) 119 3355 Isobutyl aldehyde 130 2045
Hydrogen chloride, Insecticide gas, poisonous,
refrigerated liquid 125 2186 Hydroquinone 153 2662 n.o.s. 123 1967 Isobutylamine 132 1214
Hydrogen cyanide, anhydrous, Hydroquinone, solid 153 2662 Insecticide gas, toxic, Isobutyl chloroformate 155 2742
stabilized 117 1051 Hydroquinone, solution 153 3435 flammable, n.o.s. 119 3355 Isobutylene 115 1055
Hydrogen cyanide, aqueous 1-Hydroxybenzotriazole, Insecticide gas, toxic, Isobutylene 115 1075
solution, with not more than anhydrous, wetted with not flammable, n.o.s.
20% Hydrogen cyanide 154 1613 less than 20% water 113 3474 (Inhalation Hazard Zone A) 119 3355 Isobutyl formate 129 2393
Hydrogen cyanide, solution in 1-Hydroxybenzotriazole, Insecticide gas, toxic, Isobutyl isobutyrate 130 2528
alcohol, with not more than monohydrate 113 3474 flammable, n.o.s. Isobutyl isocyanate 155 2486
45% Hydrogen cyanide 131 3294 (Inhalation Hazard Zone B) 119 3355
Hydrogen cyanide, stabilized 117 1051 Hydroxylamine sulfate 154 2865 Isobutyl methacrylate,
Hydroxylamine sulphate 154 2865 Insecticide gas, toxic, stabilized 130P 2283
Hydrogen cyanide, stabilized flammable, n.o.s.
(absorbed) 152 1614 Hypochlorite solution 154 1791 (Inhalation Hazard Zone C) 119 3355 Isobutyl propionate 129 2394
Hydrogendifluorides, n.o.s. 154 1740 Hypochlorite solution, with Insecticide gas, toxic, Isobutyraldehyde 130 2045
Hydrogendifluorides, solid, more than 5% available flammable, n.o.s. Isobutyric acid 132 2529
n.o.s. 154 1740 Chlorine 154 1791 (Inhalation Hazard Zone D) 119 3355
Page 122 Page 123

Isobutyronitrile 131 2284 Isopentenes 128 2371 Lead arsenites 151 1618 Liquefied gas, poisonous,
corrosive, n.o.s. (Inhalation
Isobutyryl chloride 132 2395 Isophoronediamine 153 2289 Lead compound, soluble, Hazard Zone D) 123 3308
n.o.s. 151 2291
Isocyanate solution, Isophorone diisocyanate 156 2290 Liquefied gas, poisonous,
flammable, poisonous, Lead cyanide 151 1620 flammable, corrosive, n.o.s. 119 3309
n.o.s. 155 2478 Isoprene, stabilized 130P 1218
Lead dioxide 141 1872 Liquefied gas, poisonous,
Isocyanate solution, Isopropanol 129 1219 flammable, corrosive, n.o.s.
flammable, toxic, n.o.s. 155 2478 Lead nitrate 141 1469 (Inhalation Hazard Zone A) 119 3309
Isopropenyl acetate 129P 2403
Isocyanate solution, Lead perchlorate 141 1470 Liquefied gas, poisonous,
Isopropenylbenzene 128 2303
poisonous, flammable,n.o.s. 155 3080 Lead perchlorate, solid 141 1470 flammable, corrosive, n.o.s.
Isopropyl acetate 129 1220 (Inhalation Hazard Zone B) 119 3309
Isocyanate solution, Lead perchlorate, solution 141 1470
poisonous, n.o.s. 155 2206 Isopropyl acid phosphate 153 1793 Liquefied gas, poisonous,
Lead perchlorate, solution 141 3408 flammable, corrosive, n.o.s.
Isocyanate solution, toxic, Isopropyl alcohol 129 1219 (Inhalation Hazard Zone C) 119 3309
flammable, n.o.s. 155 3080 Lead phosphite, dibasic 133 2989
Isopropylamine 132 1221 Liquefied gas, poisonous,
Isocyanate solution, toxic, n.o.s. 155 2206 Lead sulfate, with more than flammable, corrosive, n.o.s.
Isopropylbenzene 130 1918 3% free acid 154 1794 (Inhalation Hazard Zone D) 119 3309
Isocyanate solutions, n.o.s. 155 2206 Isopropyl butyrate 129 2405 Lead sulphate, with more than Liquefied gas, poisonous,
Isocyanate solutions, n.o.s. 155 2478 Isopropyl chloroacetate 155 2947 3% free acid 154 1794 flammable, n.o.s. 119 3160
Isocyanate solutions, n.o.s. 155 3080 Isopropyl chloroformate 155 2407 Lewisite 153 2810 Liquefied gas, poisonous,
Isocyanates, flammable, Life-saving appliances, not flammable, n.o.s.
Isopropyl 2-chloropropionate 129 2934 (Inhalation Hazard Zone A) 119 3160
poisonous, n.o.s. 155 2478 self-inflating 171 3072
Isopropyl isobutyrate 127 2406 Liquefied gas, poisonous,
Isocyanates, flammable, toxic, Life-saving appliances, flammable, n.o.s.
n.o.s. 155 2478 Isopropyl isocyanate 155 2483 selfinflating 171 2990 (Inhalation Hazard Zone B) 119 3160
Isocyanates, n.o.s. 155 2206 Isopropyl nitrate 130 1222 Lighter refills (cigarettes) Liquefied gas, poisonous,
(flammable gas) 115 1057 flammable, n.o.s.
Isocyanates, n.o.s. 155 2478 Isopropyl propionate 129 2409
Lighters (cigarettes) (Inhalation Hazard Zone C) 119 3160
Isocyanates, n.o.s. 155 3080 Isosorbide dinitrate mixture 133 2907 (flammable gas) 115 1057 Liquefied gas, poisonous,
Isocyanates, poisonous, Isosorbide-5-mononitrate 133 3251 Liquefied gas, flammable, n.o.s. 115 3161 flammable, n.o.s.
flammable, n.o.s. 155 3080 (Inhalation Hazard Zone D) 119 3160
Kerosene 128 1223 Liquefied gas, n.o.s. 126 3163
Isocyanates, poisonous, n.o.s. 155 2206 Liquefied gas, poisonous,
Ketones, liquid, n.o.s. 127 1224 Liquefied gas, oxidizing, n.o.s. 122 3157 n.o.s. 123 3162
Isocyanates, toxic, flammable, Krill meal 133 3497
n.o.s. 155 3080 Liquefied gas, poisonous, Liquefied gas, poisonous,
Krypton 121 1056 corrosive, n.o.s. 123 3308 n.o.s. (Inhalation Hazard
Isocyanates, toxic, n.o.s. 155 2206 Zone A) 123 3162
Krypton, compressed 121 1056 Liquefied gas, poisonous,
Isocyanatobenzotrifluorides 156 2285 corrosive, n.o.s. (Inhalation Liquefied gas, poisonous,
Krypton, refrigerated liquid Hazard Zone A) 123 3308 n.o.s. (Inhalation Hazard
Isoheptenes 128 2287 (cryogenic liquid) 120 1970 Zone B) 123 3162
Liquefied gas, poisonous,
Isohexenes 128 2288 L (Lewisite) 153 2810 corrosive, n.o.s. (Inhalation Liquefied gas, poisonous,
Hazard Zone B) 123 3308 n.o.s. (Inhalation Hazard
Isooctane 128 1262 Lead acetate 151 1616 Zone C) 123 3162
Isooctenes 128 1216 Liquefied gas, poisonous, Liquefied gas, poisonous,
Lead arsenates 151 1617 corrosive, n.o.s. (Inhalation
Isopentane 128 1265 n.o.s. (Inhalation Hazard
Hazard Zone C) 123 3308 Zone D) 123 3162
Page 124 Page 125

Liquefied gas, poisonous, Liquefied gas, toxic, Liquefied gas, toxic, oxidizing, Lithium borohydride 138 1413
oxidizing, corrosive, n.o.s. 124 3310 flammable, corrosive, n.o.s. corrosive, n.o.s. (Inhalation Lithium ferrosilicon 139 2830
Liquefied gas, poisonous, (Inhalation Hazard Zone A) 119 3309 Hazard Zone C) 124 3310
oxidizing, corrosive, n.o.s. Liquefied gas, toxic, Liquefied gas, toxic, oxidizing, Lithium hydride 138 1414
(Inhalation Hazard Zone A) 124 3310 flammable, corrosive, n.o.s. corrosive, n.o.s. (Inhalation Lithium hydride, fused solid 138 2805
Liquefied gas, poisonous, (Inhalation Hazard Zone B) 119 3309 Hazard Zone D) 124 3310 Lithium hydroxide 154 2680
oxidizing, corrosive, n.o.s. Liquefied gas, toxic, Liquefied gas, toxic, oxidizing, Lithium hydroxide,
(Inhalation Hazard Zone B) 124 3310 flammable, corrosive, n.o.s. n.o.s. 124 3307 monohydrate 154 2680
Liquefied gas, poisonous, (Inhalation Hazard Zone C) 119 3309 Liquefied gas, toxic, oxidizing,
oxidizing, corrosive, n.o.s. Liquefied gas, toxic, n.o.s. (Inhalation Hazard Lithium hydroxide, solid 154 2680
(Inhalation Hazard Zone C) 124 3310 flammable, corrosive, n.o.s. Zone A) 124 3307 Lithium hydroxide, solution 154 2679
Liquefied gas, poisonous, (Inhalation Hazard Zone D) 119 3309 Liquefied gas, toxic, oxidizing, Lithium hypochlorite, dry 140 1471
oxidizing, corrosive, n.o.s. Liquefied gas, toxic, n.o.s. (Inhalation Hazard Lithium hypochlorite mixture 140 1471
(Inhalation Hazard Zone D) 124 3310 flammable, n.o.s. 119 3160 Zone B) 124 3307
Liquefied gas, poisonous, Liquefied gas, toxic, Liquefied gas, toxic, oxidizing, Lithium hypochlorite
oxidizing, n.o.s. 124 3307 flammable, n.o.s. n.o.s. (Inhalation Hazard mixtures, dry 140 1471
Liquefied gas, poisonous, (Inhalation Hazard Zone A) 119 3160 Zone C) 124 3307 Lithium ion batteries
oxidizing, n.o.s. (Inhalation Liquefied gas, toxic, Liquefied gas, toxic, oxidizing, contained in equipment
Hazard Zone A) 124 3307 flammable, n.o.s. n.o.s. (Inhalation Hazard (including lithium ion
(Inhalation Hazard Zone B) 119 3160 Zone D) 124 3307 polymer batteries) 147 3481
Liquefied gas, poisonous, Lithium ion batteries
oxidizing, n.o.s. (Inhalation Liquefied gas, toxic, Liquefied gases, nonflammable, (including lithium ion
Hazard Zone B) 124 3307 flammable, n.o.s. charged with Nitrogen, Carbon polymer batteries) 147 3480
Liquefied gas, poisonous, (Inhalation Hazard Zone C) 119 3160 dioxide or Air 120 1058
oxidizing, n.o.s. (Inhalation Liquefied gas, toxic, Liquefied natural gas Lithium ion batteries packed
Hazard Zone C) 124 3307 flammable, n.o.s. with equipment (including
(cryogenic liquid) 115 1972 lithium ion polymer
Liquefied gas, poisonous, (Inhalation Hazard Zone D) 119 3160 batteries) 147 3481
Liquefied petroleum gas 115 1075
oxidizing, n.o.s. (Inhalation Liquefied gas, toxic, n.o.s. 123 3162 Lithium metal batteries
Hazard Zone D) 124 3307 Lithium 138 1415
Liquefied gas, toxic, n.o.s. contained in equipment
Liquefied gas, toxic, (Inhalation Hazard Zone A) 123 3162 Lithium alkyls 135 2445 (including lithium alloy
corrosive, n.o.s. 123 3308 Liquefied gas, toxic, n.o.s. Lithium alkyls, liquid 135 2445 batteries) 138 3091
Liquefied gas, toxic, (Inhalation Hazard Zone B) 123 3162 Lithium alkyls, solid 135 3433 Lithium metal batteries
corrosive, n.o.s. (Inhalation Liquefied gas, toxic, n.o.s. (including lithium alloy
Hazard Zone A) 123 3308 Lithium aluminum hydride 138 1410 batteries) 138 3090
(Inhalation Hazard Zone C) 123 3162
Liquefied gas, toxic, Lithium aluminum hydride, Lithium metal batteries packed
corrosive, n.o.s. (Inhalation Liquefied gas, toxic, n.o.s. ethereal 138 1411 with equipment (including
Hazard Zone B) 123 3308 (Inhalation Hazard Zone D) 123 3162 lithium alloy batteries) 138 3091
Lithium batteries 138 3090
Liquefied gas, toxic, Liquefied gas, toxic, oxidizing, Lithium nitrate 140 2722
corrosive, n.o.s. 124 3310 Lithium batteries contained in
corrosive, n.o.s. (Inhalation equipment 138 3091 Lithium nitride 138 2806
Hazard Zone C) 123 3308 Liquefied gas, toxic, oxidizing,
corrosive, n.o.s. (Inhalation Lithium batteries, liquid or Lithium peroxide 143 1472
Liquefied gas, toxic, Hazard Zone A) 124 3310 solid cathode 138 3090
corrosive, n.o.s. (Inhalation Lithium silicon 138 1417
Hazard Zone D) 123 3308 Liquefied gas, toxic, oxidizing, Lithium batteries packed with LNG (cryogenic liquid) 115 1972
Liquefied gas, toxic, corrosive, n.o.s. (Inhalation equipment 138 3091
Hazard Zone B) 124 3310
flammable, corrosive, n.o.s. 119 3309
Page 126 Page 127

London purple 151 1621 Malononitrile 153 2647 Mercaptans, liquid, Mercury based pesticide,
LPG 115 1075 Maneb 135 2210 flammable, n.o.s. 130 3336 solid, poisonous 151 2777
Magnesium 138 1869 Maneb, stabilized 135 2968 Mercaptans, liquid, Mercury based pesticide,
flammable, poisonous, n.o.s. 131 1228 solid, toxic 151 2777
Magnesium, in pellets, Maneb preparation, stabilized 135 2968
turnings or ribbons 138 1869 Mercaptans, liquid, Mercury benzoate 154 1631
Maneb preparation, with not flammable, toxic, n.o.s. 131 1228
Magnesium alkyls 135 3053 Mercury bromides 154 1634
less than 60% Maneb 135 2210 Mercaptans, liquid, poisonous,
Magnesium alloys, with more Mercury compound, liquid,
Manganese nitrate 140 2724 flammable, n.o.s. 131 3071 n.o.s. 151 2024
than 50% Magnesium, in Mercaptans, liquid, toxic,
pellets, turnings or ribbons 138 1869 Manganese resinate 133 1330 Mercury compound, solid, n.o.s. 151 2025
flammable, n.o.s. 131 3071
Magnesium alloys powder 138 1418 Matches, fusee 133 2254 Mercury contained in
Mercuric arsenate 151 1623 manufactured articles 172 3506
Magnesium aluminum Matches, safety 133 1944
Mercuric bromide 154 1634 Mercury cyanide 154 1636
phosphide 139 1419 Matches, "strike anywhere" 133 1331
Mercuric chloride 154 1624 Mercury gluconate 151 1637
Magnesium arsenate 151 1622 Matches, wax "vesta" 133 1945
Mercuric cyanide 154 1636 Mercury iodide 151 1638
Magnesium bromate 140 1473 MD 152 1556
Mercuric nitrate 141 1625 Mercury metal 172 2809
Magnesium chlorate 140 2723 Medical waste, n.o.s. 158 3291
Mercuric oxycyanide 151 1642 Mercury nucleate 151 1639
Magnesium chloride and Medicine, liquid, flammable,
Chlorate mixture 140 1459 Mercuric potassium cyanide 157 1626 Mercury oleate 151 1640
poisonous, n.o.s. 131 3248
Magnesium chloride and Mercuric sulfate 151 1645 Mercury oxide 151 1641
Medicine, liquid, flammable,
Chlorate mixture, solid 140 1459 Mercuric sulphate 151 1645 Mercury oxycyanide,
toxic, n.o.s. 131 3248
Magnesium chloride and Mercurous bromide 154 1634 desensitized 151 1642
Chlorate mixture, solution 140 3407 Medicine, liquid, poisonous,
Mercurous nitrate 141 1627 Mercury potassium iodide 151 1643
Magnesium diamide 135 2004 n.o.s. 151 1851
Mercury 172 2809 Mercury salicylate 151 1644
Magnesium diphenyl 135 2005 Medicine, liquid, toxic, n.o.s. 151 1851
Mercury acetate 151 1629 Mercury sulfate 151 1645
Magnesium fluorosilicate 151 2853 Medicine, solid, poisonous, n.o.s. 151 3249
Mercury ammonium chloride 151 1630 Mercury sulphate 151 1645
Magnesium granules, coated 138 2950 Medicine, solid, toxic, n.o.s. 151 3249
Mercury based pesticide, Mercury thiocyanate 151 1646
Magnesium hydride 138 2010 Mercaptan mixture, liquid, liquid, flammable, poisonous 131 2778 Mesityl oxide 129 1229
Magnesium nitrate 140 1474 flammable, n.o.s. 130 3336 Mercury based pesticide,
liquid, flammable, toxic 131 2778 Metal alkyl halides,
Magnesium perchlorate 140 1475 Mercaptan mixture, liquid, waterreactive, n.o.s. 138 3049
flammable, poisonous, n.o.s. 131 1228 Mercury based pesticide, Metal alkyl hydrides,
Magnesium peroxide 140 1476 liquid, poisonous 151 3012
Mercaptan mixture, liquid, waterreactive, n.o.s. 138 3050
Magnesium phosphide 139 2011 Mercury based pesticide,
flammable, toxic, n.o.s. 131 1228 liquid, poisonous, Metal alkyls,
Magnesium powder 138 1418 water-reactive, n.o.s. 135 2003
Mercaptan mixture, liquid, flammable 131 3011
Magnesium silicide 138 2624 Metal aryl halides,
poisonous, flammable, n.o.s. 131 3071 Mercury based pesticide, waterreactive, n.o.s. 138 3049
Magnesium silicofluoride 151 2853 liquid, toxic 151 3012
Magnetized material 171 2807 Mercaptan mixture, liquid, Metal aryl hydrides,
Mercury based pesticide, waterreactive, n.o.s. 138 3050
Maleic anhydride 156 2215 toxic, flammable, n.o.s. 131 3071 liquid, toxic, flammable 131 3011
Maleic anhydride, molten 156 2215
Page 128 Page 129

Metal aryls, water-reactive, 4-Methoxy-4-methylpentan- N-Methylbutylamine 132 2945 Methyl iodide 151 2644
n.o.s. 135 2003 2-one 128 2293 Methyl tert-butyl ether 127 2398 Methyl isobutyl carbinol 129 2053
Metal carbonyls, liquid, n.o.s. 151 3281 1-Methoxy-2-propanol 129 3092 Methyl butyrate 129 1237 Methyl isobutyl ketone 127 1245
Metal carbonyls, n.o.s. 151 3281 Methyl acetate 129 1231
Methyl chloride 115 1063 Methyl isocyanate 155 2480
Metal carbonyls, solid, n.o.s. 151 3466 Methylacetylene and
Methyl chloride and Methyl isopropenyl ketone,
Metal catalyst, dry 135 2881 Propadiene mixture, stabilized 116P 1060
Chloropicrin mixture 119 1582 stabilized 127P 1246
Metal catalyst, wetted 170 1378 Methyl acrylate, stabilized 129P 1919
Methyl chloride and Methylene Methyl isothiocyanate 131 2477
Metaldehyde 133 1332 Methylal 127 1234
chloride mixture 115 1912 Methyl isovalerate 130 2400
Metal hydrides, flammable, Methyl alcohol 131 1230
n.o.s. 170 3182 Methyl chloroacetate 155 2295 Methyl magnesium bromide
Methylallyl chloride 130P 2554
Metal hydrides, Methyl chloroformate 155 1238 in Ethyl ether 135 1928
Methylamine, anhydrous 118 1061
waterreactive, n.o.s. 138 1409 Methyl chloromethyl ether 131 1239 Methyl mercaptan 117 1064
Methylamine, aqueous
Metallic substance, solution 132 1235 Methyl 2-chloropropionate 129 2933 Methyl methacrylate monomer,
waterreactive, n.o.s. 138 3208
Methylamyl acetate 130 1233 Methylchlorosilane 119 2534 stabilized 129P 1247
Metallic substance, waterreactive,
self-heating, n.o.s. 138 3209 Methylamyl alcohol 129 2053 Methyl cyanide 127 1648 4-Methylmorpholine 132 2535
Metal powder, flammable, Methyl amyl ketone 127 1110 Methylcyclohexane 128 2296 N-Methylmorpholine 132 2535
n.o.s. 170 3089 N-Methylaniline 153 2294 Methylcyclohexanols 129 2617 Methylmorpholine 132 2535
Metal powder, self-heating, alpha-Methylbenzyl alcohol 153 2937 Methylcyclohexanone 128 2297 Methyl nitrite 116 2455
n.o.s. 135 3189 alpha-Methylbenzyl alcohol, Methylcyclopentane 128 2298 Methyl orthosilicate 155 2606
Metal salts of organic liquid 153 2937
compounds, flammable, Methyl dichloroacetate 155 2299 Methylpentadiene 128 2461
alpha-Methylbenzyl alcohol,
n.o.s. 133 3181 solid 153 3438 Methyldichloroarsine 152 1556 2-Methylpentan-2-ol 129 2560
Methacrylaldehyde, stabilized 131P 2396 Methylbenzyl alcohol (alpha) 153 2937 Methyldichlorosilane 139 1242 Methylphenyldichlorosilane 156 2437
Methacrylic acid, stabilized 153P 2531 Methyl bromide 123 1062 Methylene chloride 160 1593 Methyl phosphonic dichloride 137 9206
Methacrylonitrile, stabilized 131P 3079 Methyl bromide and Methylene chloride and Methyl phosphonous dichloride 135 2845
Methallyl alcohol 129 2614 Chloropicrin mixture 123 1581 Methyl chloride mixture 115 1912 1-Methylpiperidine 132 2399
Methane 115 1971 Methyl bromide and Ethylene Methyl ethyl ether 115 1039 Methyl propionate 129 1248
Methane, compressed 115 1971 dibromide mixture, liquid 151 1647
Methyl ethyl ketone 127 1193 Methyl propyl ether 127 2612
Methane, refrigerated liquid Methyl bromoacetate 155 2643
(cryogenic liquid) 115 1972 2-Methyl-5-ethylpyridine 153 2300 Methyl propyl ketone 127 1249
2-Methylbutanal 129 3371
Methane and Hydrogen Methyl fluoride 115 2454 Methyltetrahydrofuran 127 2536
3-Methylbutan-2-one 127 2397
mixture, compressed 115 2034 Methyl formate 129 1243 Methyl trichloroacetate 156 2533
2-Methyl-1-butene 128 2459
Methanesulfonyl chloride 156 3246 2-Methylfuran 128 2301 Methyltrichlorosilane 155 1250
Methanesulphonyl chloride 156 3246 2-Methyl-2-heptanethiol 131 3023 alpha-Methylvaleraldehyde 130 2367
Methanol 131 1230 5-Methylhexan-2-one 127 2302 Methyl valeraldehyde (alpha) 130 2367
Methoxymethyl isocyanate 155 2605 Methylhydrazine 131 1244
Page 130 Page 131

Methyl vinyl ketone, stabilized 131P 1251 liquid (cryogenic liquid) 115 1972 Nitrates, inorganic, aqueous Nitriles, poisonous, n.o.s. 151 3276
M.I.B.C. 129 2053 Neohexane 128 1208 solution, n.o.s. 140 3218 Nitriles, poisonous, solid, n.o.s. 151 3439
Molybdenum pentachloride 156 2508 Neon 121 1065 Nitrates, inorganic, n.o.s. 140 1477
Nitriles, solid, poisonous, n.o.s. 151 3439
Monoethanolamine 153 2491 Neon, compressed 121 1065 Nitrating acid mixture with
more than 50% nitric acid 157 1796 Nitriles, solid, toxic, n.o.s. 151 3439
Mononitrotoluidines 153 2660 Neon, refrigerated liquid Nitriles, toxic, flammable, n.o.s. 131 3275
Nitrating acid mixture with
Monopropylamine 132 1277 (cryogenic liquid) 120 1913 not more than 50% nitric acid 157 1796 Nitriles, toxic, liquid, n.o.s. 151 3276
Morpholine 132 2054 Nickel carbonyl 131 1259 Nitrating acid mixture, spent, Nitriles, toxic, n.o.s. 151 3276
Motor fuel anti-knock mixture 131 1649 Nickel catalyst, dry 135 2881 with more than 50% Nitriles, toxic, solid, n.o.s. 151 3439
Motor fuel anti-knock mixture, Nickel cyanide 151 1653 nitric acid 157 1826
flammable 131 3483 Nitrites, inorganic, aqueous
Nickel nitrate 140 2725 Nitrating acid mixture, spent, solution, n.o.s. 140 3219
Motor spirit 128 1203 Nickel nitrite 140 2726 with not more than 50%
Motor spirit and ethanol nitric acid 157 1826 Nitrites, inorganic, n.o.s. 140 2627
Nicotine 151 1654
mixture, with more than 10% Nitric acid, fuming 157 2032 Nitroanilines 153 1661
ethanol 127 3475 Nicotine compound, liquid,
Nitric acid, other than red Nitroanisoles 152 2730
Muriatic acid 157 1789 n.o.s. 151 3144 fuming, with more than 70%
Nicotine compound, solid, nitric acid 157 2031 Nitroanisoles, liquid 152 2730
Musk xylene 149 2956
n.o.s. 151 1655 Nitric acid, other than red Nitroanisoles, solid 152 2730
Mustard 153 2810 fuming, with not more than
Nicotine hydrochloride 151 1656 70% nitric acid 157 2031 Nitroanisoles, solid 152 3458
Mustard Lewisite 153 2810
Naphthalene, crude 133 1334 Nicotine hydrochloride, liquid 151 1656 Nitric acid, red fuming 157 2032 Nitrobenzene 152 1662
Naphthalene, molten 133 2304 Nicotine hydrochloride, solid 151 1656 Nitric oxide 124 1660 Nitrobenzenesulfonic acid 153 2305
Naphthalene, refined 133 1334 Nicotine hydrochloride, solid 151 3444 Nitric oxide, compressed 124 1660 Nitrobenzenesulphonic acid 153 2305
alpha-Naphthylamine 153 2077 Nicotine hydrochloride, Nitric oxide and Dinitrogen Nitrobenzotrifluorides 152 2306
Naphthylamine (alpha) 153 2077 solution 151 1656 tetroxide mixture 124 1975 Nitrobenzotrifluorides, liquid 152 2306
beta-Naphthylamine 153 1650 Nicotine preparation, liquid, Nitric oxide and Nitrogen
dioxide mixture 124 1975 Nitrobenzotrifluorides, solid 152 3431
beta-Naphthylamine, solid 153 1650 n.o.s. 151 3144
Nitric oxide and Nitrogen Nitrobromobenzenes 152 2732
beta-Naphthylamine, solution 153 3411 Nicotine preparation, solid,
tetroxide mixture 124 1975 Nitrobromobenzenes, liquid 152 2732
Naphthylamine (beta) 153 1650 n.o.s. 151 1655
Nitriles, flammable, Nitrobromobenzenes, solid 152 2732
Naphthylamine (beta), solid 153 1650 Nicotine salicylate 151 1657 poisonous, n.o.s. 131 3273
Nicotine sulfate, solid 151 1658 Nitrobromobenzenes, solid 152 3459
Naphthylamine (beta), Nitriles, flammable, toxic,
solution 153 3411 Nicotine sulfate, solid 151 3445 n.o.s. 131 3273 Nitrocellulose 133 2557
Naphthylthiourea 153 1651 Nicotine sulfate, solution 151 1658 Nitriles, liquid, poisonous, n.o.s. 151 3276 Nitrocellulose membrane
filters 133 3270
Naphthylurea 153 1652 Nicotine sulphate, solid 151 1658 Nitriles, liquid, toxic, n.o.s. 151 3276
Nitrocellulose mixture,
Natural gas, compressed 115 1971 Nicotine sulphate, solid 151 3445 Nitriles, poisonous, without pigment 133 2557
Natural gas, refrigerated Nicotine sulphate, solution 151 1658 flammable, n.o.s. 131 3275
Nitrocellulose mixture,
Nicotine tartrate 151 1659 Nitriles, poisonous, liquid, without plasticizer 133 2557
n.o.s. 151 3276
Page 132 Page 133

Nitrocellulose mixture, with Nitroglycerin, solution in Nitrosylsulphuric acid 157 2308 Organic peroxide type B, liquid 146 3101
pigment 133 2557 alcohol, with not more than Nitrosylsulphuric acid, liquid 157 2308 Organic peroxide type B,
Nitrocellulose mixture, with 1% Nitroglycerin 127 1204
pigment and plasticizer 133 2557 Nitroglycerin mixture, Nitrosylsulphuric acid, solid 157 2308 liquid, temperature
Nitrocellulose mixture, with desensitized, liquid, Nitrosylsulphuric acid, solid 157 3456 controlled 148 3111
plasticizer 133 2557 flammable, n.o.s., with not Nitrotoluenes 152 1664 Organic peroxide type B, solid 146 3102
more than 30% Nitroglycerin 113 3343
Nitrocellulose, solution, Nitroglycerin mixture, Nitrotoluenes, liquid 152 1664 Organic peroxide type B, solid,
flammable 127 2059 desensitized, liquid, n.o.s., Nitrotoluenes, solid 152 1664 temperature controlled 148 3112
Nitrocellulose, solution, in a with not more than 30% Nitrotoluenes, solid 152 3446 Organic peroxide type C, liquid 146 3103
flammable liquid 127 2059 Nitroglycerin 113 3357
Nitrocellulose with alcohol 113 2556 Nitroglycerin mixture, Nitrotoluidines (mono) 153 2660 Organic peroxide type C,
Nitrocellulose with not less desensitized, solid, n.o.s., Nitrous oxide 122 1070 liquid, temperature controlled 148 3113
than 25% alcohol 113 2556 with more than 2% but not Nitrous oxide, compressed 122 1070 Organic peroxide type C, solid 146 3104
more than 10% Nitroglycerin 113 3319
Nitrocellulose with water, not Nitroglycerin mixture with Nitrous oxide, refrigerated Organic peroxide type C,
less than 25% water 113 2555 more than 2% but not more liquid 122 2201 solid, temperature
3-Nitro-4- than 10% Nitroglycerin, Nitrous oxide and Carbon controlled 148 3114
chlorobenzotrifluoride 152 2307 desensitized 113 3319
Nitrocresols 153 2446 Nitroguanidine (Picrite), dioxide mixture 126 1015 Organic peroxide type D, liquid 145 3105
Nitrocresols, liquid 153 3434 wetted with not less than Nitroxylenes 152 1665 Organic peroxide type D,
20% water 113 1336 Nitroxylenes, liquid 152 1665 liquid, temperature controlled 148 3115
Nitrocresols, solid 153 2446 Nitroguanidine, wetted with
Nitroethane 129 2842 not less than 20% water 113 1336 Nitroxylenes, solid 152 1665 Organic peroxide type D, solid 145 3106
Nitrogen 121 1066 Nitrohydrochloric acid 157 1798 Nitroxylenes, solid 152 3447 Organic peroxide type D,
Nitrogen, compressed 121 1066 Nitromethane 129 1261 Nonanes 128 1920 solid, temperature
Nitrogen, refrigerated liquid Nitronaphthalene 133 2538 Nonyltrichlorosilane 156 1799 controlled 148 3116
(cryogenic liquid) 120 1977 Nitrophenols 153 1663 2,5-Norbornadiene, stabilized 128P 2251 Organic peroxide type E, liquid 145 3107
Nitrogen and Rare gases 4-Nitrophenylhydrazine, with Octadecyltrichlorosilane 156 1800 Organic peroxide type E,
mixture, compressed 121 1981 not less than 30% water 113 3376 Octadiene 128P 2309 liquid, temperature controlled 148 3117
Nitrogen dioxide 124 1067 Nitropropanes 129 2608 Octafluorobut-2-ene 126 2422 Organic peroxide type E, solid 145 3108
Nitrogen dioxide and Nitric p-Nitrosodimethylaniline 135 1369 Octafluorocyclobutane 126 1976 Organic peroxide type E, solid,
oxide mixture 124 1975
Nitrogen tetroxide and Nitric Nitrostarch, wetted with not Octafluoropropane 126 2424 temperature controlled 148 3118
oxide mixture 124 1975 less than 20% water 113 1337 Octanes 128 1262 Organic peroxide type F, liquid 145 3109
Nitrogen trifluoride 122 2451 Nitrostarch, wetted with not Octyl aldehydes 129 1191 Organic peroxide type F,
less than 30% solvent 113 1337
Nitrogen trifluoride, Nitrosyl chloride 125 1069 tert-Octyl mercaptan 131 3023 liquid, temperature controlled 148 3119
compressed 122 2451 Octyltrichlorosilane 156 1801 Organic peroxide type F, solid 145 3110
Nitrogen trioxide 124 2421 Nitrosylsulfuric acid 157 2308
Nitrosylsulfuric acid, liquid 157 2308 Oil, petroleum 128 1270 Organic peroxide type F, solid,
Nitroglycerin, solution in Oil gas 119 1071 temperature controlled 148 3120
alcohol, with more than Nitrosylsulfuric acid, solid 157 2308
1% but not more than 5% Nitrosylsulfuric acid, solid 157 3456 Oil gas, compressed 119 1071
Nitroglycerin 127 3064
Page 134 Page 135

Organic phosphate compound Organometallic compound, Organometallic substance, solid, Organophosphorus pesticide,
mixed with compressed gas 123 1955 solid, poisonous, n.o.s. 151 3467 solid, toxic 152 2783
water-reactive, selfheating 138 3397
Organic phosphate mixed with Organometallic compound, Organotin compound, liquid,
compressed gas 123 1955 solid, toxic, n.o.s. 151 3467 Organophosphorus compound, n.o.s. 153 2788
liquid, poisonous, n.o.s. 151 3278
Organic phosphorus Organometallic compound, Organotin compound, solid,
compound mixed with solid, water-reactive, Organophosphorus compound, n.o.s. 153 3146
compressed gas 123 1955 flammable, n.o.s. 138 3372 liquid, toxic, n.o.s. 151 3278
Organotin pesticide, liquid,
Organic pigments, selfheating 135 3313 Organometallic compound, Organophosphorus compound, flammable, poisonous 131 2787
toxic, liquid, n.o.s. 151 3282 poisonous, flammable, n.o.s. 131 3279
Organoarsenic compound, Organotin pesticide, liquid,
liquid, n.o.s. 151 3280 Organometallic compound, Organophosphorus compound, flammable, toxic 131 2787
toxic, n.o.s. 151 3282 poisonous, liquid, n.o.s. 151 3278
Organoarsenic compound, n.o.s. 151 3280 Organotin pesticide, liquid,
Organometallic compound, Organophosphorus compound, poisonous 153 3020
Organoarsenic compound, toxic, solid, n.o.s. 151 3467 poisonous, n.o.s. 151 3278
solid, n.o.s. 151 3465 Organotin pesticide, liquid,
Organometallic compound, Organophosphorus compound, poisonous, flammable 131 3019
Organochlorine pesticide, water-reactive, flammable, poisonous, solid, n.o.s. 151 3464
liquid, flammable, n.o.s. 138 3207 Organotin pesticide, liquid,
poisonous 131 2762 Organophosphorus compound, toxic 153 3020
Organochlorine pesticide, Organometallic compound solid, poisonous, n.o.s. 151 3464
liquid, flammable, toxic 131 2762 dispersion, water-reactive, Organotin pesticide, liquid,
flammable, n.o.s. 138 3207 Organophosphorus compound, toxic, flammable 131 3019
Organochlorine pesticide, solid, toxic, n.o.s. 151 3464
liquid, poisonous 151 2996 Organometallic compound Organotin pesticide, solid,
solution, water-reactive, Organophosphorus compound, poisonous 153 2786
Organochlorine pesticide, flammable, n.o.s. 138 3207 toxic, flammable, n.o.s. 131 3279
liquid, poisonous, flammable 131 2995 Organotin pesticide, solid,
Organometallic substance, Organophosphorus compound, toxic 153 2786
Organochlorine pesticide, liquid, pyrophoric 135 3392 toxic, liquid, n.o.s. 151 3278
liquid, toxic 151 2996 Osmium tetroxide 154 2471
Organometallic substance, Organophosphorus compound,
Organochlorine pesticide, liquid, pyrophoric, waterreactive 135 3394 toxic, n.o.s. 151 3278 Other regulated substances,
liquid, toxic, flammable 131 2995 liquid, n.o.s. 171 3082
Organometallic substance, Organophosphorus compound,
Organochlorine pesticide, liquid, water-reactive 135 3398 toxic, solid, n.o.s. 151 3464 Other regulated substances,
solid, poisonous 151 2761 solid, n.o.s. 171 3077
Organometallic substance, Organophosphorus pesticide,
Organochlorine pesticide, liquid, water-reactive, liquid, flammable, poisonous 131 2784 Oxidizing liquid, corrosive, n.o.s. 140 3098
solid, toxic 151 2761 flammable 138 3399 Organophosphorus pesticide, Oxidizing liquid, n.o.s. 140 3139
Organometallic compound, Organometallic substance, liquid, flammable, toxic 131 2784
liquid, poisonous, n.o.s. 151 3282 solid, pyrophoric 135 3391 Oxidizing liquid, poisonous, n.o.s. 142 3099
Organophosphorus pesticide,
Organometallic compound, Organometallic substance, liquid, poisonous 152 3018 Oxidizing liquid, toxic, n.o.s. 142 3099
liquid, toxic, n.o.s. 151 3282 solid, pyrophoric, waterreactive 135 3393 Oxidizing solid, corrosive, n.o.s. 140 3085
Organophosphorus pesticide,
Organometallic compound, Organometallic substance, liquid, poisonous, flammable 131 3017 Oxidizing solid, flammable, n.o.s. 140 3137
poisonous, liquid, n.o.s. 151 3282 solid, self-heating 138 3400
Organophosphorus pesticide, Oxidizing solid, n.o.s. 140 1479
Organometallic compound, Organometallic substance, liquid, toxic 152 3018
poisonous, n.o.s. 151 3282 solid, water-reactive 135 3395 Oxidizing solid, poisonous,
Organophosphorus pesticide, n.o.s. 141 3087
Organometallic compound, Organometallic substance, liquid, toxic, flammable 3131 3017
poisonous, solid, n.o.s. 151 3467 solid, water-reactive, Oxidizing solid, self-heating,
flammable 138 3396 Organophosphorus pesticide, n.o.s. 135 3100
solid, poisonous 152 2783
Page 136 Page 137

Oxidizing solid, toxic, n.o.s. 141 3087 Pentachlorophenol 154 3155 Perfluoro(ethyl vinyl ether) 115 3154 Petroleum distillates, n.o.s. 128 1268
Oxidizing solid, water Pentaerythrite tetranitrate Perfluoromethyl vinyl ether 115 3153 Petroleum gases, liquefied 115 1075
reactive, n.o.s. 144 3121 mixture, desensitized, solid, Perfluoro(methyl vinyl ether) 115 3153 Petroleum oil 128 1270
Oxygen 122 1072 n.o.s., with more than 10% Perfumery products, with Petroleum products, n.o.s. 128 1268
Oxygen, compressed 122 1072 but not more than 20% PETN 113 3344 flammable solvents 127 1266 Petroleum sour crude oil,
Oxygen, refrigerated liquid Pentaerythritol tetranitrate Permanganates, inorganic, flammable, toxic 131 3494
(cryogenic liquid) 122 1073 aqueous solution, n.o.s. 140 3214 Phenacyl bromide 153 2645
mixture, desensitized, solid,
Oxygen and Carbon dioxide Permanganates, inorganic, n.o.s.140 1482 Phenetidines 153 2311
mixture, compressed 122 1014 n.o.s., with more than 10%
Peroxides, inorganic, n.o.s. 140 1483 Phenol, molten 153 2312
Oxygen and Rare gases but not more than 20% PETN 113 3344
Persulfates, inorganic, Phenol, solid 153 1671
mixture, compressed 121 1980 Pentafluoroethane 126 3220 aqueous solution, n.o.s. 140 3216
Oxygen difluoride 124 2190 Pentafluoroethane and Phenol solution 153 2821
Persulfates, inorganic, n.o.s. 140 3215
Oxygen difluoride, compressed 124 2190 Ethylene oxide mixture, Phenolates, liquid 154 2904
Persulphates, inorganic,
Oxygen generator, chemical 140 3356 with not more than 7.9% aqueous solution, n.o.s. 140 3216 Phenolates, solid 154 2905
Oxygen generator, Ethylene oxide 126 3298 Persulphates, inorganic, n.o.s. 140 3215 Phenolsulfonic acid, liquid 153 1803
chemical, spent 140 3356 Pentamethylheptane 128 2286 Pesticide, liquid, flammable, Phenolsulphonic acid, liquid 153 1803
Paint (corrosive) 153 3066 Pentan-2,4-dione 131 2310 poisonous, n.o.s. 131 3021 Phenoxyacetic acid derivative
Paint, corrosive, flammable 132 3470 Pesticide, liquid, flammable, pesticide, liquid, flammable,
n-Pentane 128 1265 poisonous 131 3346
Paint (flammable) 128 1263 toxic, n.o.s. 131 3021
2,4-Pentanedione 131 2310 Phenoxyacetic acid derivative
Paint, flammable, corrosive 132 3469 Pesticide, liquid, poisonous,
Pentane-2,4-dione 131 2310 flammable, n.o.s. 131 2903 pesticide, liquid, flammable,
Paint related material Pentanes 128 1265 toxic 131 3346
(corrosive) 153 3066 Pesticide, liquid, poisonous,
Pentanols 129 1105 n.o.s. 151 2902 Phenoxyacetic acid derivative
Paint related material, pesticide, liquid, poisonous 153 3348
corrosive, flammable 132 3470 1-Pentene 128 1108 Pesticide, liquid, toxic,
flammable, n.o.s. 131 2903 Phenoxyacetic acid derivative
Paint related material 1-Pentol 153P 2705 pesticide, liquid, poisonous,
(flammable) 128 1263 Perchlorates, inorganic, Pesticide, liquid, toxic, n.o.s. 151 2902 flammable 131 3347
Paint related material, aqueous solution, n.o.s. 140 3211 Pesticide, solid, poisonous 151 2588 Phenoxyacetic acid derivative
flammable, corrosive 132 3469 Perchlorates, inorganic, n.o.s. 140 1481 Pesticide, solid, poisonous, pesticide, liquid, toxic 153 3348
Paper, unsaturated oil treated 133 1379 n.o.s. 151 2588 Phenoxyacetic acid derivative
Perchloric acid, with more than
Paraformaldehyde 133 2213 Pesticide, solid, toxic, n.o.s. 151 2588 pesticide, liquid, toxic,
50% but not more than 72% acid 143 1873 flammable 131 3347
Paraldehyde 129 1264 PETN mixture, desensitized,
Perchloric acid, with not more solid, n.o.s., with more than Phenoxyacetic acid derivative
Parathion and compressed than 50% acid 140 1802 10% but not more than 20% pesticide, solid, poisonous 153 3345
gas mixture 123 1967 PETN 113 3344
Perchloroethylene 160 1897 Phenoxyacetic acid derivative
PCB 171 2315 Petrol 128 1203 pesticide, solid, toxic 153 3345
Perchloromethyl mercaptan 157 1670
PD 152 1556 Petrol and ethanol mixture, Phenylacetonitrile, liquid 152 2470
Perchloryl fluoride 124 3083 with more than 10% ethanol 127 3475
Pentaborane 135 1380 Perfluoroethyl vinyl ether 115 3154 Phenylacetyl chloride 156 2577
Petroleum crude oil 128 1267
Pentachloroethane 151 1669 Phenylcarbylamine chloride 151 1672
Page 138 Page 139

Phenyl chloroformate 156 2746 Phosphorus heptasulfide, Picric acid, wetted with not Poisonous by inhalation
Phenylenediamines 153 1673 free from yellow and white less than 10% water 113 3364 liquid, flammable, n.o.s.
Phosphorus 139 1339 Picric acid, wetted with not (Inhalation Hazard Zone B) 131 3384
Phenylhydrazine 153 2572 Phosphorus heptasulphide, less than 30% water 113 1344 Poisonous by inhalation liquid,
Phenyl isocyanate 155 2487 free from yellow and white Picrite, wetted 113 1336 n.o.s. (Inhalation Hazard
Phenyl mercaptan 131 2337 Phosphorus 139 1339 Zone A) 151 3381
Phosphorus oxybromide 137 1939 Picryl chloride, wetted with Poisonous by inhalation liquid,
Phenylmercuric acetate 151 1674 Phosphorus oxybromide, not less than 10% water 113 3365 n.o.s. (Inhalation Hazard
Phenylmercuric compound, molten 137 2576 alpha-Pinene 128 2368 Zone B) 151 3382
n.o.s. 151 2026 Phosphorus oxybromide, solid 137 1939 Pinene (alpha) 128 2368 Poisonous by inhalation liquid,
Phenylmercuric hydroxide 151 1894 Phosphorus oxychloride 137 1810 Pine oil 129 1272 oxidizing, n.o.s. (Inhalation
Phenylmercuric nitrate 151 1895 Hazard Zone A) 142 3387
Phosphorus pentabromide 137 2691 Piperazine 153 2579 Poisonous by inhalation liquid,
Phenylphosphorus dichloride 137 2798 Phosphorus pentachloride 137 1806 Piperidine 132 2401 oxidizing, n.o.s. (Inhalation
Phenylphosphorus Phosphorus pentafluoride 125 2198 Plastic molding compound 171 3314 Hazard Zone B) 142 3388
thiodichloride 137 2799 Poisonous by inhalation liquid,
Phenyltrichlorosilane 156 1804 Phosphorus pentafluoride, Plastic, nitrocellulose-based, water-reactive, flammable,
compressed 125 2198 spontaneously combustible, n.o.s. (Inhalation Hazard Zone A) 155 3490
Phenyl urea pesticide, liquid, Phosphorus pentasulfide, n.o.s. 135 2006
poisonous 151 3002 free from yellow and white Plastics moulding compound 171 3314 Poisonous by inhalation liquid,
Phenyl urea pesticide, liquid, Phosphorus 139 1340 water-reactive, flammable,
toxic 151 3002 Plastics, nitrocellulose-based, n.o.s. (Inhalation Hazard Zone B)155 3491
Phosphorus pentasulphide, self-heating, n.o.s. 135 2006 Poisonous by inhalation
Phosgene 125 1076 free from yellow and white Poisonous by inhalation liquid, liquid, water-reactive, n.o.s.
9-Phosphabicyclononanes 135 2940 Phosphorus 139 1340 corrosive, flammable, n.o.s. (Inhalation Hazard Zone A) 139 3385
Phosphine 119 2199 Phosphorus pentoxide 137 1807 (Inhalation Hazard Zone A) 131 3492 Poisonous by inhalation
Phosphoric acid 154 1805 Phosphorus sesquisulfide, Poisonous by inhalation liquid, liquid, water-reactive, n.o.s.
free from yellow and white corrosive, flammable, n.o.s. (Inhalation Hazard Zone B) 139 3386
Phosphoric acid, liquid 154 1805 Phosphorus 139 1341 (Inhalation Hazard Zone B) 131 3493 Poisonous liquid, corrosive,
Phosphoric acid, solid 154 1805 Phosphorus sesquisulphide, Poisonous by inhalation liquid, inorganic, n.o.s. 154 3289
Phosphoric acid, solid 154 3453 free from yellow and white corrosive, n.o.s. (Inhalation Poisonous liquid, corrosive,
Phosphorus 139 1341 Hazard Zone A) 154 3389 inorganic, n.o.s. (Inhalation
Phosphoric acid, solution 154 1805 Phosphorus tribromide 137 1808 Poisonous by inhalation liquid, Hazard Zone A) 154 3289
Phosphorous acid 154 2834 Phosphorus trichloride 137 1809 corrosive, n.o.s. (Inhalation Poisonous liquid, corrosive,
Phosphorous acid, ortho 154 2834 Hazard Zone B) 154 3390 inorganic, n.o.s. (Inhalation
Phosphorus trioxide 157 2578 Poisonous by inhalation liquid, Hazard Zone B) 154 3289
Phosphorus, amorphous 133 1338 Phosphorus trisulfide, free flammable, corrosive, n.o.s.
Phosphorus, amorphous, red 133 1338 from yellow and white (Inhalation Hazard Zone A) 131 3488 Poisonous liquid, corrosive,
Phosphorus 139 1343 n.o.s. 154 2927
Phosphorus, white, dry or Poisonous by inhalation liquid, Poisonous liquid, corrosive,
under water or in solution 136 1381 Phosphorus trisulphide, flammable, corrosive, n.o.s. n.o.s. (Inhalation Hazard
Phosphorus, white, molten 136 2447 free from yellow and white (Inhalation Hazard Zone B) 131 3489 Zone A) 154 2927
Phosphorus 139 1343 Poisonous by inhalation
Phosphorus, yellow, dry or Phthalic anhydride 156 2214 liquid, flammable, n.o.s. Poisonous liquid, corrosive,
under water or in solution 136 1381 (Inhalation Hazard Zone A) 131 3383 n.o.s. (Inhalation Hazard
Picolines 129 2313 Zone B) 154 2927
Page 140 Page 141

Poisonous liquid, corrosive, Poisonous liquid, organic, Poisonous solid, self-heating, Potassium, metal 138 2257
organic, n.o.s. 154 2927 n.o.s. (Inhalation Hazard n.o.s. 136 3124 Potassium, metal alloys 138 1420
Zone B) 153 2810
Poisonous liquid, corrosive, Poisonous solid, Potassium, metal alloys, liquid 138 1420
organic, n.o.s. (Inhalation Poisonous liquid, oxidizing, waterreactive, n.o.s. 139 3125
Hazard Zone A) 154 2927 n.o.s. 142 3122 Potassium, metal alloys, solid 138 3403
Poisonous solid, which in
Poisonous liquid, corrosive, Poisonous liquid, oxidizing, contact with water emits Potassium arsenate 151 1677
organic, n.o.s. (Inhalation n.o.s. (Inhalation Hazard flammable gases, n.o.s. 139 3125 Potassium arsenite 154 1678
Zone A) 142 3122
Hazard Zone B) 154 2927 Polyalkylamines, n.o.s. 132 2733 Potassium borohydride 138 1870
Poisonous liquid, oxidizing,
Poisonous liquid, flammable, n.o.s. (Inhalation Hazard Polyalkylamines, n.o.s. 132 2734 Potassium bromate 140 1484
n.o.s. 131 2929 Zone B) 142 3122 Polyalkylamines, n.o.s. 153 2735 Potassium chlorate 140 1485
Poisonous liquid, flammable, Poisonous liquid,
n.o.s. (Inhalation Hazard waterreactive, n.o.s. 139 3123 Polyamines, flammable, Potassium chlorate, aqueous
Zone A) 131 2929 corrosive, n.o.s. 132 2733 solution 140 2427
Poisonous liquid, waterreactive,
Poisonous liquid, flammable, n.o.s. (Inhalation Hazard Zone A) 139 3123 Polyamines, liquid, corrosive, Potassium chlorate, solution 140 2427
n.o.s. (Inhalation Hazard flammable, n.o.s. 132 2734 Potassium cuprocyanide 157 1679
Poisonous liquid, waterreactive,
Zone B) 131 2929 n.o.s. (Inhalation Hazard Zone B) 139 3123 Polyamines, liquid, corrosive, Potassium cyanide 157 1680
Poisonous liquid, flammable, n.o.s. 153 2735
Poisonous liquid, which in Potassium cyanide, solid 157 1680
organic, n.o.s. 131 2929 contact with water emits Polyamines, solid, corrosive,
flammable gases, n.o.s. 139 3123 n.o.s. 154 3259 Potassium cyanide, solution 157 3413
Poisonous liquid, flammable,
organic, n.o.s. (Inhalation Poisonous liquid, which in Polychlorinated biphenyls 171 2315 Potassium dithionite 135 1929
Hazard Zone A) 131 2929 contact with water emits Polychlorinated biphenyls, Potassium fluoride 154 1812
flammable gases, n.o.s.
Poisonous liquid, flammable, (Inhalation Hazard Zone A) 139 3123 liquid 171 2315 Potassium fluoride, solid 154 1812
organic, n.o.s. (Inhalation Polychlorinated biphenyls, Potassium fluoride, solution 154 3422
Hazard Zone B) 131 2929 Poisonous liquid, which in
contact with water emits solid 171 2315 Potassium fluoroacetate 151 2628
Poisonous liquid, inorganic, flammable gases, n.o.s. Polychlorinated biphenyls,
n.o.s. 151 3287 (Inhalation Hazard Zone B) 139 3123 Potassium fluorosilicate 151 2655
solid 171 3432
Poisonous liquid, inorganic, Poisonous solid, corrosive, Potassium hydrogendifluoride 154 1811
n.o.s. (Inhalation Hazard Polyester resin kit 128 3269
inorganic, n.o.s. 154 3290 Potassium hydrogen
Zone A) 151 3287 Polyhalogenated biphenyls, difluoride, solid 154 1811
Poisonous solid, corrosive, liquid 171 3151
Poisonous liquid, inorganic, n.o.s. 154 2928 Potassium hydrogen
n.o.s. (Inhalation Hazard Polyhalogenated biphenyls, difluoride, solution 154 3421
Zone B) 151 3287 Poisonous solid, flammable,
n.o.s. 134 2930 solid 171 3152
Poisonous liquid, n.o.s. 153 2810 Potassium hydrogen sulfate 154 2509
Poisonous solid, flammable, Polyhalogenated terphenyls,
Poisonous liquid, n.o.s. liquid 171 3151 Potassium hydrogen sulphate 154 2509
(Inhalation Hazard Zone A) 153 2810 organic, n.o.s. 134 2930
Polyhalogenated terphenyls, Potassium hydrosulfite 135 1929
Poisonous liquid, n.o.s. Poisonous solid, inorganic,
(Inhalation Hazard Zone B) 153 2810 n.o.s. 151 3288 solid 171 3152 Potassium hydrosulphite 135 1929
Poisonous liquid, organic, Poisonous solid, organic, Polymeric beads, expandable 133 2211 Potassium hydroxide, dry,
n.o.s. 153 2810 n.o.s. 154 2811 solid 154 1813
Polystyrene beads,
Poisonous liquid, organic, Poisonous solid, oxidizing, expandable 133 2211 Potassium hydroxide, flake 154 1813
n.o.s. (Inhalation Hazard n.o.s. 141 3086 Potassium hydroxide, solid 154 1813
Zone A) 153 2810 Potassium 138 2257
Page 142 Page 143

Potassium hydroxide, solution 154 1814 Potassium sulphide, hydrated, n-Propyl benzene 128 2364 Pyrethroid pesticide, solid,
Potassium metavanadate 151 2864 with not less than 30% water Propyl chloride 129 1278 poisonous 151 3349
of hydration 153 1847 Pyrethroid pesticide, solid,
Potassium monoxide 154 2033 n-Propyl chloroformate 155 2740
Potassium sulphide, with toxic 151 3349
Potassium nitrate 140 1486 less than 30% water of Propylene 115 1075
Pyridine 129 1282
Potassium nitrate and Sodium crystallization 135 1382 Propylene 115 1077
nitrate mixture 140 1499 Pyrophoric alloy, n.o.s. 135 1383
Potassium sulphide, with less Propylene, Ethylene and
Potassium nitrate and Sodium than 30% water of hydration 135 1382 Acetylene in mixture, Pyrophoric liquid, inorganic,
nitrite mixture 140 1487 refrigerated liquid n.o.s. 135 3194
Potassium superoxide 143 2466
Potassium nitrite 140 1488 containing at least 71.5% Pyrophoric liquid, n.o.s. 135 2845
Printing ink, flammable 129 1210 Ethylene with not more than
Potassium perchlorate 140 1489 Pyrophoric liquid, organic,
Printing ink related material 129 1210 22.5% Acetylene and not n.o.s. 135 2845
Potassium permanganate 140 1490 Propadiene, stabilized 116P 2200 more than 6% Propylene 115 3138
Pyrophoric metal, n.o.s. 135 1383
Potassium peroxide 144 1491 Propadiene and Propylene chlorohydrin 131 2611
Pyrophoric organometallic
Potassium persulfate 140 1492 Methylacetylene mixture, 1,2-Propylenediamine 132 2258 compound, water-reactive,
Potassium persulphate 140 1492 stabilized 116P 1060 1,3-Propylenediamine 132 2258 n.o.s. 135 3203
Potassium phosphide 139 2012 Propane 115 1075 Propylene dichloride 130 1279 Pyrophoric solid, inorganic, n.o.s. 135 3200
Potassium silicofluoride 151 2655 Propane 115 1978 Propyleneimine, stabilized 131P 1921 Pyrophoric solid, n.o.s. 135 2846
Potassium sodium alloys 138 1422 Propane-Ethane mixture, Propylene oxide 127P 1280 Pyrophoric solid, organic, n.o.s. 135 2846
refrigerated liquid 115 1961
Potassium sodium alloys, Propylene oxide and Ethylene Pyrosulfuryl chloride 137 1817
liquid 138 1422 Propane mixture 115 1075 oxide mixture, with not more Pyrosulphuryl chloride 137 1817
Potassium sodium alloys, solid 138 3404 Propane mixture 115 1978 than 30% Ethylene oxide 129P 2983
Pyrrolidine 132 1922
Potassium sulfide, anhydrous 135 1382 Propanethiols 130 2402 Propylene tetramer 128 2850
Quinoline 154 2656
Potassium sulfide, hydrated, n-Propanol 129 1274 Propyl formates 129 1281
Radioactive material,
with not less than 30% water Propionaldehyde 129 1275 n-Propyl isocyanate 155 2482 excepted package, articles
of crystallization 153 1847 Propionic acid 132 1848 n-Propyl nitrate 131 1865 manufactured from depleted
Potassium sulfide, hydrated, Uranium 161 2909
Propionic acid, with not less Propyltrichlorosilane 155 1816
with not less than 30% water than 10% and less than 90% acid 132 1848 Radioactive material,
of hydration 153 1847 Pyrethroid pesticide, liquid, excepted package, articles
Propionic acid, with not less flammable, poisonous 131 3350 manufactured from natural
Potassium sulfide, with than 90% acid 132 3463 Thorium 161 2909
less than 30% water of Pyrethroid pesticide, liquid,
crystallization 135 1382 Propionic anhydride 156 2496 flammable, toxic 131 3350 Radioactive material,
Propionitrile 131 2404 Pyrethroid pesticide, liquid, excepted package, articles
Potassium sulfide, with less manufactured from natural
than 30% water of hydration 135 1382 Propionyl chloride 132 1815 poisonous 151 3352 Uranium 161 2909
Potassium sulphide, n-Propyl acetate 129 1276 Pyrethroid pesticide, liquid, Radioactive material,
anhydrous 135 1382 poisonous, flammable 131 3351 excepted package, empty
normal Propyl alcohol 129 1274 packaging 161 2908
Potassium sulphide, hydrated, Pyrethroid pesticide, liquid,
Propyl alcohol, normal 129 1274 toxic 151 3352 Radioactive material,
with not less than 30% water
of crystallization 153 1847 Propylamine 132 1277 Pyrethroid pesticide, liquid, excepted package, empty
toxic, flammable 131 3351 packaging 161 2910
Page 144 Page 145

Radioactive material, Radioactive material, surface Rare gases and Nitrogen Refrigerant gas R-115 126 1020
excepted package, contaminated objects mixture, compressed 121 1981 Refrigerant gas R-116 126 2193
instruments or articles 161 2910 (SCO-II), non fissile or Rare gases and Oxygen
Radioactive material, fissile-excepted 162 2913 mixture, compressed 121 1980 Refrigerant gas R-116,
excepted package, Radioactive material, compressed 126 2193
instruments or articles 161 2911 transported under special Rare gases mixture, Refrigerant gas R-124 126 1021
arrangement, fissile 165 3331 compressed 121 1979
Radioactive material, Receptacles, small, Refrigerant gas R-125 126 3220
excepted package, limited Radioactive material, containing gas 115 2037 Refrigerant gas R-133a 126 1983
quantity of material 161 2910 transported under special
Radioactive material, fissile, arrangement, non fissile or Red phosphorus 133 1338 Refrigerant gas R-134a 126 3159
n.o.s. 165 2918 fissile-excepted 163 2919 Red phosphorus, amorphous 133 1338 Refrigerant gas R-142b 115 2517
Radioactive material, low Radioactive material, Type A Refrigerant gas, n.o.s. 126 1078 Refrigerant gas R-143a 115 2035
specific activity (LSA), n.o.s. 162 2912 package, fissile,
non-special form 165 3327 Refrigerant gas, n.o.s. Refrigerant gas R-152a 115 1030
Radioactive material, low Radioactive material, Type A (flammable) 115 1954 Refrigerant gas R-152a and
specific activity (LSA-I), non package non-special form, Refrigerant gas R-12 126 1028 Refrigerant gas R-12
fissile or fissile-excepted 162 2912 non fissile or fissileexcepted 163 2915 azeotropic mixture with 74%
Radioactive material, low Refrigerant gas R-12 and Refrigerant gas R-12 126 2602
Radioactive material, Type A Refrigerant gas R-152a
specific activity (LSA-II), fissile 165 3324 package, special form, fissile 165 3333 azeotropic mixture with 74% Refrigerant gas R-161 115 2453
Radioactive material, low Radioactive material, Type A Refrigerant gas R-12 126 2602 Refrigerant gas R-218 126 2424
specific activity (LSA-II), package, special form, non Refrigerant gas R-12B1 126 1974 Refrigerant gas R-227 126 3296
non fissile or fissileexcepted 162 3321 fissile or fissile-excepted 164 3332 Refrigerant gas R-13 126 1022
Radioactive material, low Radioactive material, Type Refrigerant gas R-404A 126 3337
specific activity (LSA-III), fissile 165 3325 B(M) package, fissile 165 3329 Refrigerant gas R-13 and Refrigerant gas R-407A 126 3338
Refrigerant gas R-23
Radioactive material, low Radioactive material, Type azeotropic mixture with 60% Refrigerant gas R-407B 126 3339
specific activity (LSA-III), B(M) package, non fissile or Refrigerant gas R-13 126 2599 Refrigerant gas R-407C 126 3340
non fissile or fissile-excepted 162 3322 fissile-excepted 163 2917 Refrigerant gas R-13B1 126 1009
Radioactive material, n.o.s. 163 2982 Radioactive material, Type Refrigerant gas R-500
B(U) package, fissile 165 3328 Refrigerant gas R-14 126 1982 (azeotropic mixture of
Radioactive material, Refrigerant gas R-14, Refrigerant gas R-12 and
special form, n.o.s. 164 2974 Radioactive material, Type compressed 126 1982 Refrigerant gas R-152a
Radioactive material, surface B(U) package, non fissile or with approximately 74%
contaminated objects (SCO) 162 2913 fissile-excepted 163 2916 Refrigerant gas R-21 126 1029 Refrigerant gas R-12) 126 2602
Radioactive material, surface Radioactive material, Type C Refrigerant gas R-22 126 1018 Refrigerant gas R-502 126 1973
contaminated objects package, non fissile or Refrigerant gas R-23 126 1984 Refrigerant gas R-503
(SCO-I), fissile 165 3326 fissile excepted 163 3323 (azeotropic mixture of
Radioactive material, Type C Refrigerant gas R-23 and Refrigerant gas R-13
Radioactive material, surface package, fissile 165 3330 Refrigerant gas R-13 and Refrigerant gas R-23
contaminated objects azeotropic mixture with 60% with approximately 60%
(SCO-I), non fissile or Radioactive material, Refrigerant gas R-13 126 2599 Refrigerant gas R-13) 126 2599
fissile-excepted 162 2913 Uranium hexafluoride 166 2978 Refrigerant gas R-32 115 3252
Radioactive material, surface Radioactive material, Refrigerant gas R-1132a 116P 1959
contaminated objects Uranium hexafluoride, fissile 166 2977 Refrigerant gas R-40 115 1063 Refrigerant gas R-1216 126 1858
(SCO-II), fissile 165 3326 Rags, oily 133 1856 Refrigerant gas R-41 115 2454 Refrigerant gas R-1318 126 2422
Refrigerant gas R-114 126 1958
Page 146 Page 147

Refrigerant gas RC-318 126 1976 Seed cake, with more than Self-heating solid, corrosive, Self-reactive solid type C,
Refrigerating machines, 1.5% oil and not more than organic, n.o.s. 136 3126 temperature controlled 150 3234
containing Ammonia 11% moisture 135 1386 Self-heating solid, inorganic, Self-reactive solid type D 149 3226
solutions (Un2672) 126 2857 Seed cake, with not more n.o.s. 135 3190
Refrigerating machines, than 1.5% oil and not more Self-reactive solid type D,
containing flammable, than 11% moisture 135 2217 Self-heating solid, inorganic, temperature controlled 150 3236
nonpoisonous, liquefied gases 115 3358 poisonous, n.o.s. 136 3191 Self-reactive solid type E 149 3228
Selenates 151 2630 Self-heating solid, inorganic,
Refrigerating machines, Selenic acid 154 1905 toxic, n.o.s. 136 3191 Self-reactive solid type E,
containing flammable, temperature controlled 150 3238
nontoxic, liquefied gases 115 3358 Selenites 151 2630 Self-heating solid, organic, Self-reactive solid type F 149 3230
Refrigerating machines, Selenium compound, liquid, n.o.s. 135 3088
containing non-flammable, n.o.s. 151 3440 Self-heating solid, oxidizing, Self-reactive solid type F,
non-poisonous gases 126 2857 n.o.s. 135 3127 temperature controlled 150 3240
Selenium compound, n.o.s. 151 3283 Shale oil 128 1288
Refrigerating machines, Selenium compound, solid, Self-heating solid, poisonous,
containing non-flammable, n.o.s. 151 3283 inorganic, n.o.s. 136 3191 Silane 116 2203
non-toxic gases 126 2857 Self-heating solid, poisonous, Silicofluorides, n.o.s. 151 2856
Regulated medical waste, Selenium disulfide 153 2657 organic, n.o.s. 136 3128
n.o.s. 158 3291 Selenium disulphide 153 2657 Silane, compressed 116 2203
Self-heating solid, toxic, Silicon powder, amorphous 170 1346
Resin solution 127 1866 Selenium hexafluoride 125 2194 inorganic, n.o.s. 136 3191
Resorcinol 153 2876 Selenium oxychloride 157 2879 Self-heating solid, toxic, Silicon tetrachloride 157 1818
Rosin oil 127 1286 Self-defense spray, organic, n.o.s. 136 3128 Silicon tetrafluoride 125 1859
Rubber scrap, powdered or nonpressurized 171 3334 Self-reactive liquid type B 149 3221 Silicon tetrafluoride,
granulated 133 1345 Self-heating liquid, corrosive, Self-reactive liquid type B, compressed 125 1859
Rubber shoddy, powdered inorganic, n.o.s. 136 3188 temperature controlled 150 3231 Silver arsenite 151 1683
or granulated 133 1345 Self-heating liquid, corrosive, Self-reactive liquid type C 149 3223 Silver cyanide 151 1684
Rubber solution 127 1287 organic, n.o.s. 136 3185 Self-reactive liquid type C, Silver nitrate 140 1493
Rubidium 138 1423 Self-heating liquid, inorganic, temperature controlled 150 3233 Silver picrate, wetted with
n.o.s. 135 3186 Self-reactive liquid type D 149 3225 not less than 30% water 113 1347
Rubidium hydroxide 154 2678 Self-heating liquid, organic,
Rubidium hydroxide, solid 154 2678 n.o.s. 135 3183 Self-reactive liquid type D, Sludge acid 153 1906
temperature controlled 150 3235 Smokeless powder for
Rubidium hydroxide, solution 154 2677 Self-heating liquid, poisonous, Self-reactive liquid type E 149 3227 small arms 133 3178
Rubidium metal 138 1423 inorganic, n.o.s. 136 3187
Self-heating liquid, poisonous, Self-reactive liquid type E, Soda lime, with more than
SA 119 2188 organic, n.o.s. 136 3184 temperature controlled 150 3237 4% Sodium hydroxide 154 1907
Sarin 153 2810 Self-heating liquid, toxic, Self-reactive liquid type F 149 3229 Sodium 138 1428
Seat-belt modules 171 3268 inorganic, n.o.s. 136 3187 Self-reactive liquid type F, Sodium aluminate, solid 154 2812
Seat-belt pre-tensioners 171 3268 Self-heating liquid, toxic, temperature controlled 150 3239 Sodium aluminate, solution 154 1819
Seat-belt pre-tensioners, organic, n.o.s. 136 3184 Self-reactive solid type B 149 3222 Sodium aluminum hydride 138 2835
compressed gas 126 3353 Self-heating metal powders, Self-reactive solid type B, Sodium ammonium vanadate 154 2863
Seat-belt pre-tensioners, n.o.s. 135 3189 temperature controlled 150 3232
pyrotechnic 171 3268 Self-heating solid, corrosive, Self-reactive solid type C 149 3224 Sodium arsanilate 154 2473
inorganic, n.o.s. 136 3192 Sodium arsenate 151 1685
Page 148 Page 149

Sodium arsenite, aqueous Sodium dinitro-orthocresolate, Sodium hydroxide, solution 154 1824 Sodium sulphide, hydrated,
solution 154 1686 wetted 113 1348 Sodium methylate 138 1431 with not less than 30% water 153 1849
Sodium arsenite, solid 151 2027 Sodium dithionite 135 1384 Sodium methylate, dry 138 1431 Sodium sulphide, with
Sodium azide 153 1687 Sodium fluoride 154 1690 less than 30% water of
Sodium methylate, solution crystallization 135 1385
Sodium bisulfate, solution 154 2837 Sodium fluoride, solid 154 1690 in alcohol 132 1289
Sodium superoxide 143 2547
Sodium bisulphate, solution 154 2837 Sodium fluoride, solution 154 3415 Sodium monoxide 157 1825
Solids containing corrosive
Sodium borohydride 138 1426 Sodium fluoroacetate 151 2629 Sodium nitrate 140 1498 liquid, n.o.s. 154 3244
Sodium borohydride and Sodium fluorosilicate 154 2674 Sodium nitrate and Solids containing flammable
Sodium hydroxide solution, Sodium hydride 138 1427 Potassium nitrate mixture 140 1499
with not more than 12% liquid, n.o.s. 133 3175
Sodium borohydride and Sodium hydrogendifluoride 154 2439 Sodium nitrite 140 1500 Solids containing poisonous
not more than 40% Sodium Sodium nitrite and Potassium liquid, n.o.s. 151 3243
hydroxide 157 3320 Sodium hydrogen sulfate, nitrate mixture 140 1487
solution 154 2837 Solids containing toxic liquid,
Sodium bromate 141 1494 Sodium hydrogen sulphate, Sodium pentachlorophenate 154 2567 n.o.s. 151 3243
Sodium cacodylate 152 1688 solution 154 2837 Sodium perborate Soman 153 2810
Sodium carbonate Sodium hydrosulfide, solid, monohydrate 140 3377
Stannic chloride, anhydrous 137 1827
peroxyhydrate 140 3378 with less than 25% water of Sodium perchlorate 140 1502
Stannic chloride, pentahydrate 154 2440
Sodium chlorate 140 1495 crystallization 135 2318 Sodium permanganate 140 1503
Stannic phosphides 139 1433
Sodium chlorate, aqueous Sodium hydrosulfide, with Sodium peroxide 144 1504
solution 140 2428 less than 25% water of Stibine 119 2676
crystallization 135 2318 Sodium peroxoborate,
Sodium chlorite 143 1496 anhydrous 140 3247 Straw, wet, damp or
Sodium chlorite, solution, Sodium hydrosulfide, with contaminated with oil 133 1327
not less than 25% water of Sodium persulfate 140 1505
with more than 5% crystallization 154 2949 Strontium arsenite 151 1691
available Chlorine 154 1908 Sodium persulphate 140 1505
Sodium hydrosulfite 135 1384 Strontium chlorate 143 1506
Sodium chloroacetate 151 2659 Sodium phosphide 139 1432
Sodium hydrosulphide, solid, Strontium chlorate, solid 143 1506
Sodium cuprocyanide, solid 157 2316 Sodium picramate, wetted
with less than 25% water of with not less than 20% water 113 1349 Strontium chlorate, solution 143 1506
Sodium cuprocyanide, solution 157 2317 crystallization 135 2318 Strontium nitrate 140 1507
Sodium potassium alloys 138 1422
Sodium cyanide 157 1689 Sodium hydrosulphide, with Strontium perchlorate 140 1508
less than 25% water of Sodium potassium alloys,
Sodium cyanide, solid 157 1689 crystallization 135 2318 liquid 138 1422 Strontium peroxide 143 1509
Sodium cyanide, solution 157 3414 Sodium hydrosulphide, with Sodium potassium alloys, solid 138 3404 Strontium phosphide 139 2013
Sodium dichloroisocyanurate 140 2465 not less than 25% water of Sodium silicofluoride 154 2674 Strychnine 151 1692
Sodium dichloro-striazinetrione140 2465 crystallization 154 2949
Sodium hydrosulphite 135 1384 Sodium sulfide, anhydrous 135 1385 Strychnine salts 151 1692
Sodium dinitro-o-cresolate, Sodium sulfide, hydrated, Styrene monomer, stabilized 128P 2055
wetted with not less than Sodium hydroxide, bead 154 1823
10% water 113 3369 with not less than 30% water 153 1849 Substituted nitrophenol
Sodium hydroxide, dry 154 1823
Sodium dinitro-o-cresolate, Sodium sulfide, with less than pesticide, liquid, flammable,
wetted with not less than Sodium hydroxide, flake 154 1823 30% water of crystallization 135 1385 poisonous 131 2780
15% water 113 1348 Sodium hydroxide, granular 154 1823 Sodium sulphide, anhydrous 135 1385
Sodium hydroxide, solid 154 1823
Page 150 Page 151

Substituted nitrophenol Sulfur tetrafluoride 125 2418 Tear gas candles 159 1700 Tetrahydrophthalic anhydrides 156 2698
pesticide, liquid, flammable, Sulfur trioxide, stabilized 137 1829 Tear gas devices 159 1693 1,2,3,6-Tetrahydropyridine 129 2410
toxic 131 2780
Substituted nitrophenol Sulfur trioxide and Tear gas grenades 159 1700 1,2,5,6-Tetrahydropyridine 129 2410
pesticide, liquid, poisonous 153 3014 Chlorosulfonic acid mixture 137 1754 Tear gas substance, liquid, Tetrahydrothiophene 130 2412
Substituted nitrophenol Sulfuryl chloride 137 1834 n.o.s. 159 1693 Tetramethylammonium
pesticide, liquid, poisonous, Sulfuryl fluoride 123 2191 Tear gas substance, solid, hydroxide 153 1835
flammable 131 3013 Sulphamic acid 154 2967 n.o.s. 159 1693 Tetramethylammonium
Substituted nitrophenol Sulphur 133 1350 Tear gas substance, solid, hydroxide, solid 153 3423
pesticide, liquid, toxic 153 3014 n.o.s. 159 3448
Sulphur, molten 133 2448 Tetramethylammonium
Substituted nitrophenol Tellurium compound, n.o.s. 151 3284 hydroxide, solution 153 1835
pesticide, liquid, toxic, Sulphur chlorides 137 1828
flammable 131 3013 Tellurium hexafluoride 125 2195 Tetramethylsilane 130 2749
Sulphur dioxide 125 1079
Substituted nitrophenol Terpene hydrocarbons, n.o.s. 128 2319 Tetranitromethane 143 1510
pesticide, solid, poisonous 153 2779 Sulphur hexafluoride 126 1080
Terpinolene 128 2541 Tetrapropyl orthotitanate 128 2413
Substituted nitrophenol Sulphuric acid 137 1830
Tetrabromoethane 159 2504 Textile waste, wet 133 1857
pesticide, solid, toxic 153 2779 Sulphuric acid, fuming 137 1831
1,1,2,2-Tetrachloroethane 151 1702 Thallium chlorate 141 2573
Sulfamic acid 154 2967 Sulphuric acid, fuming, with
less than 30% free Sulphur Tetrachloroethane 151 1702 Thallium compound, n.o.s. 151 1707
Sulfur 133 1350 trioxide 137 1831 Tetrachloroethylene 160 1897 Thallium nitrate 141 2727
Sulfur, molten 133 2448 Sulphuric acid, fuming, with Tetraethyl 4-Thiapentanal 152 2785
Sulfur chlorides 137 1828 not less than 30% free dithiopyrophosphate 153 1704
Sulphur trioxide 137 1831 Thia-4-pentanal 152 2785
Sulfur dioxide 125 1079 Tetraethyl
Sulphuric acid, spent 137 1832 Thickened GD 153 2810
Sulfur hexafluoride 126 1080 dithiopyrophosphate,
Sulphuric acid, with more mixture, dry or liquid 153 1704 Thioacetic acid 129 2436
Sulfuric acid 137 1830 than 51% acid 137 1830
Tetraethylenepentamine 153 2320 Thiocarbamate pesticide,
Sulfuric acid, fuming 137 1831 Sulphuric acid, with not more liquid, flammable,
Sulfuric acid, fuming, with than 51% acid 157 2796 Tetraethyl silicate 129 1292 poisonous 131 2772
less than 30% free Sulfur Sulphuric acid and 1,1,1,2-Tetrafluoroethane 126 3159
trioxide 137 1831 Thiocarbamate pesticide,
Hydrofluoric acid mixture 157 1786 Tetrafluoroethane and liquid, flammable, toxic 131 2772
Sulfuric acid, fuming, with Sulphurous acid 154 1833 Ethylene oxide mixture,
not less than 30% free Sulfur Thiocarbamate pesticide,
trioxide 137 1831 Sulphur tetrafluoride 125 2418 with not more than 5.6% liquid, poisonous 151 3006
Ethylene oxide 126 3299
Sulfuric acid, spent 137 1832 Sulphur trioxide, stabilized 137 1829 Thiocarbamate pesticide,
Tetrafluoroethylene, stabilized 116P 1081 liquid, poisonous,
Sulfuric acid, with more than Sulphur trioxide and
51% acid 137 1830 Chlorosulphonic acid Tetrafluoromethane 126 1982 flammable 131 3005
Sulfuric acid, with not more mixture 137 1754 Tetrafluoromethane, Thiocarbamate pesticide,
than 51% acid 157 2796 Sulphuryl chloride 137 1834 compressed 126 1982 liquid, toxic 151 3006
Sulfuric acid and Hydrofluoric Sulphuryl fluoride 123 2191 1,2,3,6-Tetrahydrobenzaldehyde 129 2498 Thiocarbamate pesticide,
acid mixture 157 1786 Tetrahydrofuran 127 2056 liquid, toxic, flammable 131 3005
Tabun 153 2810
Sulfurous acid 154 1833 Tetrahydrofurfurylamine 129 2943 Thiocarbamate pesticide,
Tars, liquid 130 1999 solid, poisonous 151 2771
Page 152 Page 153

Thiocarbamate pesticide, 2,4-Toluenediamine 151 1709 Toxic by inhalation liquid, Toxic liquid, flammable, n.o.s.
solid, toxic 151 2771 oxidizing, n.o.s. (Inhalation (Inhalation Hazard Zone A) 131 2929
Toluene diisocyanate 156 2078 Hazard Zone A) 142 3387
Thioglycol 153 2966 Toxic liquid, flammable, n.o.s.
Toluidines 153 1708 Toxic by inhalation liquid, (Inhalation Hazard Zone B) 131 2929
Thioglycolic acid 153 1940 Toluidines, liquid 153 1708 oxidizing, n.o.s. (Inhalation Toxic liquid, flammable,
Thiolactic acid 153 2936 Toluidines, solid 153 1708 Hazard Zone B) 142 3388 organic, n.o.s. 131 2929
Thionyl chloride 137 1836 Toluidines, solid 153 3451 Toxic by inhalation liquid, Toxic liquid, flammable,
water-reactive, flammable, organic, n.o.s. (Inhalation
Thiophene 130 2414 2,4-Toluylenediamine 151 1709 n.o.s. (Inhalation Hazard Hazard Zone A) 131 2929
Thiophosgene 157 2474 2,4-Toluylenediamine, solid 151 1709 Zone A) 155 3490 Toxic liquid, flammable,
Thiophosphoryl chloride 157 1837 Toxic by inhalation liquid, organic, n.o.s. (Inhalation
2,4-Toluylenediamine, water-reactive, flammable, Hazard Zone B) 131 2929
Thiourea dioxide 135 3341 solution 151 3418 n.o.s. (Inhalation Hazard Toxic liquid, inorganic, n.o.s. 151 3287
Thorium metal, pyrophoric 162 2975 Toxic by inhalation liquid, Zone B) 155 3491
Toxic liquid, inorganic, n.o.s.
Thorium nitrate, solid 162 2976 corrosive, flammable, n.o.s. Toxic by inhalation liquid, (Inhalation Hazard Zone A) 151 3287
(Inhalation Hazard Zone A) 131 3492 water-reactive, n.o.s.
Tinctures, medicinal 127 1293 (Inhalation Hazard Zone A) 139 3385 Toxic liquid, inorganic, n.o.s.
Toxic by inhalation liquid, (Inhalation Hazard Zone B) 151 3287
Tin tetrachloride 137 1827 corrosive, flammable, n.o.s. Toxic by inhalation liquid, Toxic liquid, n.o.s. 153 2810
Tin tetrachloride, (Inhalation Hazard Zone B) 131 3493 water-reactive, n.o.s.
pentahydrate 154 2440 (Inhalation Hazard Zone B) 139 3386 Toxic liquid, n.o.s. (Inhalation
Toxic by inhalation liquid, Hazard Zone A) 153 2810
Titanium disulfide 135 3174 corrosive, n.o.s. (Inhalation Toxic liquid, corrosive,
inorganic, n.o.s. 154 3289 Toxic liquid, n.o.s. (Inhalation
Titanium disulphide 135 3174 Hazard Zone A) 154 3389 Hazard Zone B) 153 2810
Toxic by inhalation liquid, Toxic liquid, corrosive,
Titanium hydride 170 1871 inorganic, n.o.s. (Inhalation Toxic liquid, organic, n.o.s. 153 2810
corrosive, n.o.s. (Inhalation Hazard Zone A) 154 3289
Titanium powder, dry 135 2546 Hazard Zone B) 154 3390 Toxic liquid, organic, n.o.s.
Toxic liquid, corrosive, (Inhalation Hazard Zone A) 153 2810
Titanium powder, wetted with Toxic by inhalation liquid,
not less than 25% water 170 1352 inorganic, n.o.s. (Inhalation Toxic liquid, organic, n.o.s.
flammable, corrosive, n.o.s. Hazard Zone B) 154 3289 (Inhalation Hazard Zone B) 153 2810
Titanium sponge granules 170 2878 (Inhalation Hazard Zone A) 131 3488 Toxic liquid, oxidizing, n.o.s. 142 3122
Toxic liquid, corrosive, n.o.s. 154 2927
Titanium sponge powders 170 2878 Toxic by inhalation liquid, Toxic liquid, oxidizing, n.o.s.
flammable, corrosive, n.o.s. Toxic liquid, corrosive, n.o.s.
Titanium tetrachloride 137 1838 (Inhalation Hazard Zone A) 154 2927 (Inhalation Hazard Zone A) 142 3122
(Inhalation Hazard Zone B) 131 3489
Titanium trichloride, Toxic liquid, corrosive, n.o.s. Toxic liquid, oxidizing, n.o.s.
pyrophoric 135 2441 Toxic by inhalation liquid, (Inhalation Hazard Zone B) 154 2927 (Inhalation Hazard Zone B) 142 3122
flammable, n.o.s. Toxic liquid, water-reactive,
Titanium trichloride mixture 157 2869 (Inhalation Hazard Zone A) 131 3383 Toxic liquid, corrosive,
organic, n.o.s. 154 2927 n.o.s. 139 3123
Titanium trichloride mixture, Toxic by inhalation liquid,
pyrophoric 135 2441 Toxic liquid, corrosive, Toxic liquid, water-reactive,
flammable, n.o.s. n.o.s. (Inhalation Hazard
TNT, wetted with not less (Inhalation Hazard Zone B) 131 3384 organic, n.o.s. (Inhalation
Hazard Zone A) 154 2927 Zone A) 139 3123
than 10% water 113 3366 Toxic by inhalation liquid, Toxic liquid, water-reactive,
Toxic liquid, corrosive,
TNT, wetted with not less n.o.s. (Inhalation Hazard organic, n.o.s. (Inhalation n.o.s. (Inhalation Hazard
than 30% water 113 1356 Zone A) 151 3381 Hazard Zone B) 154 2927 Zone B) 139 3123
Toe puffs, nitrocellulose base 133 1353 Toxic by inhalation liquid, Toxic liquid, flammable, n.o.s. 131 2929 Toxic liquid, which in contact
n.o.s. (Inhalation Hazard with water emits flammable
Toluene 130 1294 gases, n.o.s. 139 3123
Zone B) 151 3382
Page 154 Page 155

Toxic liquid, which in contact Triazine pesticide, liquid, Trifluoromethane, Trinitrotoluene, wetted with
with water emits flammable poisonous 151 2998 refrigerated liquid 120 3136 not less than 10% water 113 3366
gases, n.o.s. (Inhalation Triazine pesticide, liquid, Trifluoromethane and Trinitrotoluene, wetted with
Hazard Zone A) 139 3123 poisonous, flammable 131 2997 Chlorotrifluoromethane not less than 30% water 113 1356
Toxic liquid, which in contact Triazine pesticide, liquid, toxic 151 2998 azeotropic mixture with Tripropylamine 132 2260
with water emits flammable approximately 60%
gases, n.o.s. (Inhalation Triazine pesticide, liquid, Chlorotrifluoromethane 126 2599 Tripropylene 128 2057
Hazard Zone B) 139 3123 toxic, flammable 131 2997 Tris-(1-aziridinyl)phosphine
2-Trifluoromethylaniline 153 2942
Toxic solid, corrosive, Triazine pesticide, solid, oxide, solution 152 2501
poisonous 151 2763 3-Trifluoromethylaniline 153 2948
inorganic, n.o.s. 154 3290 Tungsten hexafluoride 125 2196
Triazine pesticide, solid, toxic 151 2763 Triisobutylene 128 2324
Toxic solid, corrosive, Turpentine 128 1299
organic, n.o.s. 154 2928 Tri-(1-aziridinyl)phosphine Triisopropyl borate 129 2616
Turpentine substitute 128 1300
Toxic solid, flammable, n.o.s. 134 2930 oxide, solution 152 2501 Trimethoxysilane 132 9269
Undecane 128 2330
Toxic solid, flammable, Tributylamine 153 2542 Trimethylacetyl chloride 132 2438
Uranium hexafluoride 166 2978
organic, n.o.s. 134 2930 Tributylphosphane 135 3254 Trimethylamine, anhydrous 118 1083
Uranium hexafluoride, fissile
Toxic solid, inorganic, n.o.s. 151 3288 Tributylphosphine 135 3254 Trimethylamine, aqueous containing more than 1%
Toxic solid, organic, n.o.s. 154 2811 Trichloroacetic acid 153 1839 solution 132 1297 Uranium-235 166 2977
Toxic solid, oxidizing, n.o.s. 141 3086 Trichloroacetic acid, solution 153 2564 1,3,5-Trimethylbenzene 129 2325 Uranium hexafluoride,
Toxic solid, self-heating, n.o.s. 136 3124 Trichloroacetyl chloride 156 2442 Trimethyl borate 129 2416 non fissile or fissile-excepted 166 2978
Toxic solid, water-reactive, Trichlorobenzenes, liquid 153 2321 Trimethylchlorosilane 155 1298 Uranium metal, pyrophoric 162 2979
n.o.s. 139 3125 Trichlorobutene 152 2322 Trimethylcyclohexylamine 153 2326 Uranyl nitrate, hexahydrate,
Toxic solid, which in contact 1,1,1-Trichloroethane 160 2831 Trimethylhexamethylenediamines153 2327 solution 162 2980
with water emits flammable Trimethylhexamethylene Uranyl nitrate, solid 162 2981
gases, n.o.s. 139 3125 Trichloroethylene 160 1710
diisocyanate 156 2328 Urea hydrogen peroxide 140 1511
Toxins 153 —— Trichloroisocyanuric acid, dry 140 2468
Trimethyl phosphite 130 2329 Urea nitrate, wetted with not
Toxins, extracted from living Trichlorosilane 139 1295
Trinitrobenzene, wetted with less than 10% water 113 3370
sources, liquid, n.o.s. 153 3172 Tricresyl phosphate 151 2574 not less than 10% water 113 3367 Urea nitrate, wetted with not
Toxins, extracted from living Triethylamine 132 1296 Trinitrobenzene, wetted with less than 20% water 113 1357
sources, n.o.s. 153 3172 Triethylenetetramine 153 2259 not less than 30% water 113 1354 Valeraldehyde 129 2058
Toxins, extracted from living Triethyl phosphite 130 2323 Trinitrobenzoic acid, wetted
sources, solid, n.o.s. 153 3172 Valeryl chloride 132 2502
Trifluoroacetic acid 154 2699 with not less than 10% water 113 3368
Toxins, extracted from living Vanadium compound, n.o.s. 151 3285
Trifluoroacetyl chloride 125 3057 Trinitrobenzoic acid, wetted
sources, solid, n.o.s. 153 3462 with not less than 30% water 113 1355 Vanadium oxytrichloride 137 2443
Triallylamine 132 2610 Trifluorochloroethylene, Vanadium pentoxide 151 2862
stabilized 119P 1082 Trinitrochlorobenzene, wetted
Triallyl borate 156 2609 with not less than 10% water 113 3365 Vanadium tetrachloride 137 2444
1,1,1-Trifluoroethane 115 2035
Triazine pesticide, liquid, Trinitrophenol, wetted with Vanadium trichloride 157 2475
flammable, poisonous 131 2764 Trifluoroethane, compressed 115 2035 not less than 10% water 113 3364 Vanadyl sulfate 151 2931
Triazine pesticide, liquid, Trifluoromethane 126 1984 Trinitrophenol, wetted with
flammable, toxic 131 2764 not less than 30% water 113 1344
Page 156 Page 157

Vanadyl sulphate 151 2931 Water-reactive solid, Yellow phosphorus, in solution 136 1381 Zirconium, dry, coiled wire,
Vehicle, flammable gas oxidizing, n.o.s. 138 3133 Yellow phosphorus, molten 136 2447 finished metal sheets or
powered 128 3166 Water-reactive solid,
Vehicle, flammable liquid poisonous, n.o.s. 139 3134 Yellow phosphorus, under strips 170 2858
powered 128 3166 water 136 1381 Zirconium, dry, finished
Water-reactive solid,
Vehicle, fuel cell, flammable selfheating, n.o.s. 138 3135 Zinc ammonium nitrite 140 1512 sheets, strips or coiled wire 135 2009
gas powered 128 3166 Water-reactive solid, toxic, Zinc arsenate 151 1712 Zirconium hydride 138 1437
Vehicle, fuel cell, flammable n.o.s. 139 3134 Zinc arsenate and Zinc
liquid powered 128 3166 Zirconium metal, liquid
Wheelchair, electric, with arsenite mixture 151 1712
Vinyl acetate, stabilized 129P 1301 batteries 154 3171 suspension 170 1308
Zinc arsenite 151 1712
Vinyl bromide, stabilized 116P 1085 White asbestos 171 2590 Zirconium metal, powder, wet 170 1358
Zinc arsenite and Zinc
Vinyl butyrate, stabilized 129P 2838 White phosphorus, dry 136 1381 Zirconium nitrate 140 2728
arsenate mixture 151 1712
Vinyl chloride, stabilized 116P 1086 White phosphorus, in solution 136 1381 Zirconium picramate, wetted
Zinc ashes 138 1435
Vinyl chloroacetate 155 2589 White phosphorus, molten 136 2447 with not less than 20% water 113 1517
Zinc bromate 140 2469
Vinyl ethyl ether, stabilized 127P 1302 White phosphorus, under Zirconium powder, dry 135 2008
Vinyl fluoride, stabilized 116P 1860 water 136 1381 Zinc chlorate 140 1513
Zirconium powder, wetted with
Vinylidene chloride, stabilized 130P 1303 Wood preservatives, liquid 129 1306 Zinc chloride, anhydrous 154 2331
Wool waste, wet 133 1387 not less than 25% water 170 1358
Vinyl isobutyl ether, stabilized 127P 1304 Zinc chloride, solution 154 1840
Xanthates 135 3342 Zirconium scrap 135 1932
Vinyl methyl ether, stabilized 116P 1087 Zinc cyanide 151 1713
Xenon 121 2036 Zirconium suspended in a
Vinylpyridines, stabilized 131P 3073 Zinc dithionite 171 1931
Vinyltoluenes, stabilized 130P 2618 Xenon, compressed 121 2036 flammable liquid 170 1308
Zinc dross 138 1435
Vinyltrichlorosilane 155P 1305 Xenon, refrigerated liquid Zirconium suspended in a
(cryogenic liquid) 120 2591 Zinc dust 138 1436
Vinyltrichlorosilane, stabilized 155P 1305 liquid (flammable) 170 1308
Xylenes 130 1307 Zinc fluorosilicate 151 2855
VX 153 2810 Zirconium tetrachloride 137 2503
Xylenols 153 2261 Zinc hydrosulfite 171 1931
Water-reactive liquid,
corrosive, n.o.s. 138 3129 Xylenols, liquid 153 3430 Zinc hydrosulphite 171 1931
Water-reactive liquid, n.o.s. 138 3148 Xylenols, solid 153 2261 Zinc nitrate 140 1514
Water-reactive liquid, Xylidines 153 1711 Zinc permanganate 140 1515
poisonous, n.o.s. 139 3130 Xylidines, liquid 153 1711 Zinc peroxide 143 1516
Water-reactive liquid, toxic, Xylidines, solid 153 1711 Zinc phosphide 139 1714
n.o.s. 139 3130 Xylidines, solid 153 3452 Zinc powder 138 1436
Water-reactive solid, Xylyl bromide 152 1701
corrosive, n.o.s. 138 3131 Zinc residue 138 1435
Xylyl bromide, liquid 152 1701
Water-reactive solid, Zinc resinate 133 2714
flammable, n.o.s. 138 3132 Xylyl bromide, solid 152 3417
Zinc silicofluoride 151 2855
Water-reactive solid, n.o.s. 138 2813 Yellow phosphorus, dry 136 1381
Zinc skimmings 138 1435
Page 158 Page 159

GUIDE INDEX
Guide No. Type of Substance Page No.

111 Mixed Load/Unidentified Cargo 162 144 Oxidizers (Water-Reactive) 228
112 Explosives - Division 1.1, 1.2, 1.3 or 1.5 164 145 Organic Peroxides (Heat and Contamination Sensitive) 230
113 Flammable Solids – Toxic (Wet/Desensitized Explosive) 166 146 Organic Peroxides (Heat, Contamination and Friction Sensitive) 232
114 Explosives - Division 1.4 or 1.6 168 147 Lithium Ion Batteries 234
115 Gases – Flammable (Including Refrigerated Liquids) 170 148 Organic Peroxides (Heat and Contamination Sensitive/Temperature
116 Gases - Flammable (Unstable) 172 Controlled) 236
117 Gases - Toxic – Flammable (Extreme Hazard) 174 149 Substances (Self-Reactive) 238
118 Gases - Flammable - Corrosive 176 150 Substances (Self-Reactive/ Temperature Controlled) 240
119 Gases - Toxic - Flammable 178 151 Substances - Toxic (Non-Combustible) 242
120 Gases – Inert (Including Refrigerated Liquids) 180 152 Substances - Toxic (Combustible) 244
121 Gases - Inert 182 153 Substances - Toxic and/or Corrosive (Combustible) 246
122 Gases – Oxidizing (Including Refrigerated Liquids) 184 154 Substances - Toxic and/or Corrosive (Non-Combustible) 248
123 Gases - Toxic and/or Corrosive 186 155 Substances - Toxic and/or Corrosive (Flammable/Water-Sensitive) 250
124 Gases - Toxic and/or Corrosive - Oxidizing 188 156 Substances - Toxic and/or Corrosive (Combustible/Water-Sensitive) 252
125 Gases - Corrosive 190 157 Substances - Toxic and/or Corrosive (Non-Combustible/Water-Sensitive) 254
126 Gases - Compressed or Liquefied (Including Refrigerated Gases) 192 158 Infectious Substances 256
127 Flammable Liquids (Polar/Water-Miscible) 194 159 Substances (Irritating) 258
128 Flammable Liquids (Non-Polar/Water-Immiscible) 196 160 Halogenated Solvents 260
129 Flammable Liquids (Polar/Water-Miscible/Noxious) 198 161 Radioactive Materials (Low Level Radiation) 262
130 Flammable Liquids (Non-Polar/Water-Immiscible/Noxious) 200 162 Radioactive Materials (Low to Moderate Level Radiation) 264
131 Flammable Liquids - Toxic 202 163 Radioactive Materials (Low to High Level Radiation) 266
132 Flammable Liquids - Corrosive 204 164 Radioactive Materials (Special Form/Low to High Level External Radiation) 268
133 Flammable Solids 206 165 Radioactive Materials (Fissile/Low to High Level Radiation) 270
134 Flammable Solids - Toxic and/or Corrosive 208 166 Radioactive Materials – Corrosive (Uranium Hexafluoride/Water-Sensitive) 272
135 Substances - Spontaneously Combustible 210 167 Fluorine (Refrigerated Liquid) 274
136 Substances - Spontaneously Combustible – Toxic and/or Corrosive 168 Carbon Monoxide (Refrigerated Liquid) 276
(Air-Reactive) 212 169 Aluminum (Molten) 278
137 Substances - Water-Reactive - Corrosive 214 170 Metals (Powders, Dusts, Shavings, Borings, Turnings, or Cuttings, etc.) 280
138 Substances - Water-Reactive (Emitting Flammable Gases) 216 171 Substances (Low to Moderate Hazard) 282
139 Substances - Water-Reactive (Emitting Flammable And Toxic Gases) 218 172 Gallium and Mercury 284
140 Oxidizers 220
141 Oxidizers - Toxic 222
142 Oxidizers - Toxic (Liquid) 224
143 Oxidizers (Unstable) 226
Page 160 Page 161

GUIDE Mixed Load/Unidentified Cargo ERG2012 ERG2012 Mixed Load/Unidentified Cargo GUIDE
111 111
POTENTIAL HAZARDS EMERGENCY RESPONSE
FIRE OR EXPLOSION FIRE
• May explode from heat, shock, friction or contamination. CAUTION: Material may react with extinguishing agent.
• May react violently or explosively on contact with air, water or foam. Small Fire
• May be ignited by heat, sparks or flames. • Dry chemical, CO2, water spray or regular foam.
• Vapours may travel to source of ignition and flash back. Large Fire
• Containers may explode when heated. • Water spray, fog or regular foam.
• Ruptured cylinders may rocket. • Move containers from fire area if you can do it without risk.
Fire involving Tanks
HEALTH
• Cool containers with flooding quantities of water until well after fire is out.
• Inhalation, ingestion or contact with substance may cause severe injury, infection, disease or death.
• Do not get water inside containers.
• High concentration of gas may cause asphyxiation without warning.
• Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank.
• Contact may cause burns to skin and eyes.
• ALWAYS stay away from tanks engulfed in fire.
• Fire or contact with water may produce irritating, toxic and/or corrosive gases.
• Runoff from fire control may cause pollution. SPILL OR LEAK
• Do not touch or walk through spilled material.
• ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).
PUBLIC SAFETY • All equipment used when handling the product must be grounded.
• Keep combustibles (wood, paper, oil, etc.) away from spilled material.
• CALL EMERGENCY RESPONSE Telephone Number on Shipping Paper first. If Shipping Paper not
• Use water spray to reduce Vapours or divert Vapour cloud drift. Avoid allowing water runoff to
available or no answer, refer to appropriate telephone number listed on the inside back cover.
contact spilled material.
• As an immediate precautionary measure, isolate spill or leak area for at least 100 meters (330 feet) in
• Prevent entry into waterways, sewers, basements or confined areas.
all directions.
Small Spill
• Keep unauthorized personnel away.
• Take up with sand or other non-combustible absorbent material and place into containers for later
• Stay upwind.
disposal.
• Keep out of low areas.
Large Spill
PROTECTIVE CLOTHING • Dike far ahead of liquid spill for later disposal.
• Wear positive pressure self-contained breathing apparatus (SCBA).
FIRST AID
• Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it may
• Move victim to fresh air.
not be effective in spill situations.
• Call 108 or emergency medical service.
EVACUATION • Give artificial respiration if victim is not breathing.
Fire • Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial
• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; respiration with the aid of a pocket mask equipped with a one-way valve or other proper
also, consider initial evacuation for 800 meters (1/2 mile) in all directions. respiratory medical device.
• Administer oxygen if breathing is difficult.
• Remove and isolate contaminated clothing and shoes.
• In case of contact with substance, immediately flush skin or eyes with running water for at least 20
minutes.
• Shower and wash with soap and water.
• Keep victim warm and quiet.
• Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed.
• Ensure that medical personnel are aware of the material(s) involved and take precautions to protect
themselves.
Page 162 Page 163

GUIDE Explosives* - Division 1.1, 1.2, 1.3 or 1.5 ERG2012 ERG2012 Explosives* - Division 1.1, 1.2, 1.3 or 1.5 GUIDE
112 112
• MAY EXPLODE AND THROW FRAGMENTS 1600 meters (1 MILE) OR MORE IF FIRE REACHES CARGO. CARGO Fire
• For information on “Compatibility Group” letters, refer to Glossary section. • DO NOT fight fire when fire reaches cargo! Cargo may EXPLODE!
HEALTH • Stop all traffic and clear the area for at least 1600 meters (1 mile) in all directions and let burn.
• Fire may produce irritating, corrosive and/or toxic gases. • Do not move cargo or vehicle if cargo has been exposed to heat.
TIRE or VEHICLE Fire
• Use plenty of water - FLOOD it! If water is not available, use CO2, dry chemical or dirt.
PUBLIC SAFETY • If possible, and WITHOUT RISK, use unmanned hose holders or monitor nozzles from maximum
distance to prevent fire from spreading to cargo area.
• Pay special attention to tire fires as re-ignition may occur. Stand by with extinguisher ready.
• Isolate spill or leak area immediately for at least 500 meters (1/3 mile) in all directions. SPILL OR LEAK
• Move people out of line of sight of the scene and away from windows. • ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).
• Keep unauthorized personnel away. • All equipment used when handling the product must be grounded.
• Stay upwind. • Do not touch or walk through spilled material.
• Ventilate closed spaces before entering. • DO NOT OPERATE RADIO TRANSMITTERS WITHIN 100 meters (330 feet) OF ELECTRIC DETONATORS.
PROTECTIVE CLOTHING • DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERVISION OF A SPECIALIST.
• Wear positive pressure self-contained breathing apparatus (SCBA). FIRST AID
• Structural firefighters’ protective clothing will only provide limited protection. • Move victim to fresh air.
EVACUATION • Call 108 or emergency medical service.
Large Spill • Give artificial respiration if victim is not breathing.
• Consider initial EVACUATION for 800 meters (1/2 mile) in all directions. • Administer oxygen if breathing is difficult.
Fire • Remove and isolate contaminated clothing and shoes.
• If rail car or trailer is involved in a fire, ISOLATE for 1600 meters (1 mile) in all directions; also, initiate • In case of contact with substance, immediately flush skin or eyes with running water for at least 20
evacuation including emergency responders for 1600 meters (1 mile) in all directions. minutes.
themselves.
* FOR INFORMATION ON "COMPATIBILITY GROUP" LETTERS, * FOR INFORMATION ON "COMPATIBILITY GROUP" LETTERS,
REFER TO THE GLOSSARY SECTION. REFER TO THE GLOSSARY SECTION.
Page 164 Page 165

GUIDE Flammable Solids - Toxic ERG2012 ERG2012 Flammable Solids - Toxic GUIDE
113 (Wet/Desensitized Explosive) (Wet/Desensitized Explosive) 113
• Flammable/combustible material. CARGO Fire
• May be ignited by heat, sparks or flames. • DO NOT fight fire when fire reaches cargo! Cargo may EXPLODE!
• DRIED OUT material may explode if exposed to heat, flame, friction or shock; Treat as an explosive • Stop all traffic and clear the area for at least 800 meters (1/2 mile) in all directions and let burn.
(GUIDE 112). • Do not move cargo or vehicle if cargo has been exposed to heat.
• Keep material wet with water or treat as an explosive (GUIDE 112). TIRE or VEHICLE Fire
• Runoff to sewer may create fire or explosion hazard. • Use plenty of water - FLOOD it! If water is not available, use CO2, dry chemical or dirt.
HEALTH • If possible, and WITHOUT RISK, use unmanned hose holders or monitor nozzles from maximum
• Some are toxic and may be fatal if inhaled, swallowed or absorbed through skin. distance to prevent fire from spreading to cargo area.
• Contact may cause burns to skin and eyes. • Pay special attention to tire fires as re-ignition may occur. Stand by with extinguisher ready.
• Fire may produce irritating, corrosive and/or toxic gases. SPILL OR LEAK
• Runoff from fire control or dilution water may cause pollution. • ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).
• All equipment used when handling the product must be grounded.
PUBLIC SAFETY • Do not touch or walk through spilled material.
• CALL EMERGENCY RESPONSE Telephone Number on Shipping Paper first. If Shipping Paper not Small Spill
available or no answer, refer to appropriate telephone number listed on the inside back cover. • Flush area with flooding quantities of water.
• Isolate spill or leak area immediately for at least 100 meters (330 feet) in all directions. Large Spill
• Keep unauthorized personnel away. • Wet down with water and dike for later disposal.
• Stay upwind. • KEEP “WETTED” PRODUCT WET BY SLOWLY ADDING FLOODING QUANTITIES OF WATER.
• Ventilate closed spaces before entering. FIRST AID
PROTECTIVE CLOTHING • Move victim to fresh air.
• Wear positive pressure self-contained breathing apparatus (SCBA). • Call 108 or emergency medical service.
• Structural firefighters’ protective clothing will only provide limited protection. • Give artificial respiration if victim is not breathing.
EVACUATION • Remove and isolate contaminated clothing and shoes.
Large Spill • In case of contact with substance, immediately flush skin or eyes with running water for at least 20
• Consider initial EVACUATION for 500 meters (1/3 mile) in all directions. minutes.
Fire • Ensure that medical personnel are aware of the material(s) involved and take precautions to protect
• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; themselves.
also, consider initial evacuation for 800 meters (1/2 mile) in all directions.
Page 166 Page 167

GUIDE Explosives* - Division 1.4 or 1.6 ERG2012 ERG2012 Explosives* - Division 1.4 or 1.6 GUIDE
114 114
• MAY EXPLODE AND THROW FRAGMENTS 500 meters (1/3 MILE) OR MORE IF FIRE REACHES CARGO. CARGO Fire
• For information on “Compatibility Group” letters, refer to Glossary section. • DO NOT fight fire when fire reaches cargo! Cargo may EXPLODE!
HEALTH • Stop all traffic and clear the area for at least 500 meters (1/3 mile) in all directions and let burn.
• Fire may produce irritating, corrosive and/or toxic gases. • Do not move cargo or vehicle if cargo has been exposed to heat.
TIRE or VEHICLE Fire
• Use plenty of water - FLOOD it! If water is not available, use CO2, dry chemical or dirt.
PUBLIC SAFETY • If possible, and WITHOUT RISK, use unmanned hose holders or monitor nozzles from maximum
• CALL EMERGENCY RESPONSE Telephone Number on Shipping Paper first. If Shipping Paper not distance to prevent fire from spreading to cargo area.
available or no answer, refer to appropriate telephone number listed on the inside back cover. • Pay special attention to tire fires as re-ignition may occur. Stand by with extinguisher ready.
• Isolate spill or leak area immediately for at least 100 meters (330 feet) in all directions.
• Move people out of line of sight of the scene and away from windows. SPILL OR LEAK
• Keep unauthorized personnel away. • ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).
• Stay upwind. • All equipment used when handling the product must be grounded.
• Ventilate closed spaces before entering. • Do not touch or walk through spilled material.
• DO NOT OPERATE RADIO TRANSMITTERS WITHIN 100 meters (330 feet) OF ELECTRIC DETONATORS.
• Structural firefighters’ protective clothing will only provide limited protection. FIRST AID
• Consider initial EVACUATION for 250 meters (800 feet) in all directions. • Administer oxygen if breathing is difficult.
• If rail car or trailer is involved in a fire, ISOLATE for 500 meters (1/3 mile) in all directions; also initiate • In case of contact with substance, immediately flush skin or eyes with running water for at least 20
evacuation including emergency responders for 500 meters (1/3 mile) in all directions. minutes.
themselves.
SUPPLEMENTAL INFORMATION
• Packages bearing the 1.4S label or packages containing material classified as 1.4S are designed or
packaged in such a manner that when involved in a fire, may burn vigorously with localized
detonations and projection of fragments.
• Effects are usually confined to immediate vicinity of packages.
• If fire threatens cargo area containing packages bearing the 1.4S label or packages containing material
classified as 1.4S, consider isolating at least 15 meters (50 feet) in all directions. Fight fire with normal
precautions from a reasonable distance.
* FOR INFORMATION ON "COMPATIBILITY GROUP" LETTERS, * FOR INFORMATION ON "COMPATIBILITY GROUP" LETTERS,
REFER TO THE GLOSSARY SECTION. REFER TO THE GLOSSARY SECTION.
Page 168 Page 169

GUIDE Gases - Flammable ERG2012 ERG2012 Gases - Flammable GUIDE
115 (Including Refrigerated Liquids) (Including Refrigerated Liquids) 115
• EXTREMELY FLAMMABLE. • DO NOT EXTINGUISH A LEAKING GAS FIRE UNLESS LEAK CAN BE STOPPED.
• Will be easily ignited by heat, sparks or flames. CAUTION: Hydrogen (UN1049), Deuterium (UN1957) and Hydrogen, refrigerated liquid (Un1966) burn
• Will form explosive mixtures with air. with an invisible flame. Hydrogen and Methane mixture, compressed (UN2034) may burn with an
• Vapours from liquefied gas are initially heavier than air and spread along ground. invisible flame.
CAUTION: Hydrogen (UN1049), Deuterium (UN1957), Hydrogen, refrigerated liquid (UN1966) and Small Fire
Methane (UN1971) are lighter than air and will rise. Hydrogen and Deuterium fires are difficult to • Dry chemical or CO2.
detect since they burn with an invisible flame. Use an alternate method of detection (thermal Large Fire
camera, broom handle, etc.) • Water spray or fog.
• Vapours may travel to source of ignition and flash back. • Move containers from fire area if you can do it without risk.
• Cylinders exposed to fire may vent and release flammable gas through pressure relief devices. Fire involving Tanks
• Containers may explode when heated. • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.
• Ruptured cylinders may rocket. • Cool containers with flooding quantities of water until well after fire is out.
• Do not direct water at source of leak or safety devices; icing may occur.
HEALTH • Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank.
• Vapours may cause dizziness or asphyxiation without warning. • ALWAYS stay away from tanks engulfed in fire.
• Some may be irritating if inhaled at high concentrations. • For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from
• Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite. area and let fire burn.
• Fire may produce irritating and/or toxic gases.
SPILL OR LEAK
• CALL EMERGENCY RESPONSE Telephone Number on Shipping Paper first. If Shipping Paper not • Do not touch or walk through spilled material.
available or no answer, refer to appropriate telephone number listed on the inside back cover. • Stop leak if you can do it without risk.
• As an immediate precautionary measure, isolate spill or leak area for at least 100 meters (330 feet) in • If possible, turn leaking containers so that gas escapes rather than liquid.
all directions. • Use water spray to reduce Vapours or divert Vapour cloud drift. Avoid allowing water runoff to
• Keep unauthorized personnel away. contact spilled material.
• Stay upwind. • Do not direct water at spill or source of leak.
• Many gases are heavier than air and will spread along ground and collect in low or confined areas • Prevent spreading of Vapours through sewers, ventilation systems and confined areas.
(sewers, basements, tanks). • Isolate area until gas has dispersed.
• Keep out of low areas. CAUTION: When in contact with refrigerated/cryogenic liquids, many materials become brittle and are
likely to break without warning.
PROTECTIVE CLOTHING
FIRST AID
• Structural firefighters’ protective clothing will only provide limited protection.
• Always wear thermal protective clothing when handling refrigerated/cryogenic liquids.
• Give artificial respiration if victim is not breathing.
EVACUATION • Administer oxygen if breathing is difficult.
Large Spill • Remove and isolate contaminated clothing and shoes.
• Consider initial downwind evacuation for at least 800 meters (1/2 mile). • Clothing frozen to the skin should be thawed before being removed.
Fire • In case of contact with liquefied gas, thaw frosted parts with lukewarm water.
• If tank, rail car or tank truck is involved in a fire, ISOLATE for 1600 meters (1 mile) in all directions; • In case of burns, immediately cool affected skin for as long as possible with cold water. Do not remove
also, consider initial evacuation for 1600 meters (1 mile) in all directions. clothing if adhering to skin.
themselves.
Page 170 Page 171

GUIDE Gases - Flammable (Unstable) ERG2012 ERG2012 Gases - Flammable (Unstable) GUIDE
116 116
• Will be easily ignited by heat, sparks or flames. Small Fire
• Will form explosive mixtures with air. • Dry chemical or CO2.
• Silane will ignite spontaneously in air. Large Fire
• Those substances designated with a (P) may polymerize explosively when heated or involved in a fire. • Water spray or fog.
• Vapours from liquefied gas are initially heavier than air and spread along ground. • Move containers from fire area if you can do it without risk.
• Vapours may travel to source of ignition and flash back. Fire involving Tanks
• Cylinders exposed to fire may vent and release flammable gas through pressure relief devices. • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.
• Containers may explode when heated. • Cool containers with flooding quantities of water until well after fire is out.
• Ruptured cylinders may rocket. • Do not direct water at source of leak or safety devices; icing may occur.
HEALTH
• Vapours may cause dizziness or asphyxiation without warning.
• For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from
• Some may be toxic if inhaled at high concentrations.
area and let fire burn.
• Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite.
• Fire may produce irritating and/or toxic gases. SPILL OR LEAK
PUBLIC SAFETY • Stop leak if you can do it without risk.
available or no answer, refer to appropriate telephone number listed on the inside back cover. • Do not direct water at spill or source of leak.
• As an immediate precautionary measure, isolate spill or leak area for at least 100 meters (330 feet) in • Use water spray to reduce Vapours or divert Vapour cloud drift. Avoid allowing water runoff to
all directions. contact spilled material.
• Keep unauthorized personnel away. • If possible, turn leaking containers so that gas escapes rather than liquid.
• Stay upwind. • Prevent entry into waterways, sewers, basements or confined areas.
• Many gases are heavier than air and will spread along ground and collect in low or confined areas • Isolate area until gas has dispersed.
(sewers, basements, tanks). FIRST AID
• Keep out of low areas. • Move victim to fresh air.
PROTECTIVE CLOTHING • Call 108 or emergency medical service.
• Wear positive pressure self-contained breathing apparatus (SCBA). • Give artificial respiration if victim is not breathing.
• Structural firefighters’ protective clothing will only provide limited protection. • Administer oxygen if breathing is difficult.
EVACUATION • In case of contact with liquefied gas, thaw frosted parts with lukewarm water.
Large Spill • In case of burns, immediately cool affected skin for as long as possible with cold water. Do not remove
• Consider initial downwind evacuation for at least 800 meters (1/2 mile). clothing if adhering to skin.
Fire • Keep victim warm and quiet.
• If tank, rail car or tank truck is involved in a fire, ISOLATE for 1600 meters (1 mile) in all directions; also, • Ensure that medical personnel are aware of the material(s) involved and take precautions to protect
consider initial evacuation for 1600 meters (1 mile) in all directions. themselves.
Page 172 Page 173

GUIDE Gases - Toxic - Flammable ERG2012 ERG2012 Gases - Toxic - Flammable GUIDE
117 (Extreme Hazard) (Extreme Hazard) 117
HEALTH FIRE
• TOXIC; Extremely Hazardous. DO NOT EXTINGUISH A LEAKING GAS FIRE UNLESS LEAK CAN BE STOPPED.
• May be fatal if inhaled or absorbed through skin. Small Fire
• Initial odor may be irritating or foul and may deaden your sense of smell. • Dry chemical, CO2, water spray or regular foam.
• Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite. Large Fire
• Fire will produce irritating, corrosive and/or toxic gases. • Water spray, fog or regular foam.
• Runoff from fire control may cause pollution. • Move containers from fire area if you can do it without risk.
• Damaged cylinders should be handled only by specialists.
FIRE OR EXPLOSION Fire involving Tanks
• These materials are extremely flammable. • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.
• May form explosive mixtures with air. • Cool containers with flooding quantities of water until well after fire is out.
• May be ignited by heat, sparks or flames. • Do not direct water at source of leak or safety devices; icing may occur.
• Vapours from liquefied gas are initially heavier than air and spread along ground. • Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank.
• Vapours may travel to source of ignition and flash back. • ALWAYS stay away from tanks engulfed in fire.
• Runoff may create fire or explosion hazard. SPILL OR LEAK
• Cylinders exposed to fire may vent and release toxic and flammable gas through pressure relief • ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).
devices. • All equipment used when handling the product must be grounded.
• Containers may explode when heated. • Fully encapsulating, Vapour protective clothing should be worn for spills and leaks with no fire.
• Ruptured cylinders may rocket. • Do not touch or walk through spilled material.
• Stop leak if you can do it without risk.
PUBLIC SAFETY contact spilled material.
• CALL EMERGENCY RESPONSE Telephone Number on Shipping Paper first. If Shipping Paper not • Do not direct water at spill or source of leak.
available or no answer, refer to appropriate telephone number listed on the inside back cover. • If possible, turn leaking containers so that gas escapes rather than liquid.
• As an immediate precautionary measure, isolate spill or leak area for at least 100 meters (330 feet) in • Prevent entry into waterways, sewers, basements or confined areas.
all directions. • Isolate area until gas has dispersed.
• Keep unauthorized personnel away. • Consider igniting spill or leak to eliminate toxic gas concerns.
• Stay upwind. FIRST AID
• Many gases are heavier than air and will spread along ground and collect in low or confined areas • Move victim to fresh air.
(sewers, basements, tanks). • Call 108 or emergency medical service.
• Keep out of low areas. • Give artificial respiration if victim is not breathing.
• Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial
• Ventilate closed spaces before entering.
respiration with the aid of a pocket mask equipped with a one-way valve or other proper
PROTECTIVE CLOTHING respiratory medical device.
• Wear positive pressure self-contained breathing apparatus (SCBA). • Administer oxygen if breathing is difficult.
• Wear chemical protective clothing that is specifically recommended by the manufacturer. It may • Remove and isolate contaminated clothing and shoes.
provide little or no thermal protection. • In case of contact with substance, immediately flush skin or eyes with running water for at least 20
• Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not minutes.
effective in spill situations where direct contact with the substance is possible. • In case of contact with liquefied gas, thaw frosted parts with lukewarm water.
• In case of burns, immediately cool affected skin for as long as possible with cold water. Do not remove
EVACUATION clothing if adhering to skin.
Spill • Keep victim warm and quiet.
• See Table 1 - Initial Isolation and Protective Action Distances. • Keep victim under observation.
Fire • Effects of contact or inhalation may be delayed.
• If tank, rail car or tank truck is involved in a fire, ISOLATE for 1600 meters (1 mile) in all directions; also, • Ensure that medical personnel are aware of the material(s) involved and take precautions to protect
consider initial evacuation for 1600 meters (1 mile) in all directions. themselves.
Page 174 Page 175

GUIDE Gases - Flammable - Corrosive ERG2012 ERG2012 Gases - Flammable - Corrosive GUIDE
118 118
• May be ignited by heat, sparks or flames. Small Fire
• May form explosive mixtures with air. • Dry chemical or CO2.
• Vapours from liquefied gas are initially heavier than air and spread along ground. Large Fire
• Vapours may travel to source of ignition and flash back. • Water spray, fog or regular foam.
• Some of these materials may react violently with water. • Move containers from fire area if you can do it without risk.
• Cylinders exposed to fire may vent and release flammable gas through pressure relief devices. • Damaged cylinders should be handled only by specialists.
• Containers may explode when heated. Fire involving Tanks
• Ruptured cylinders may rocket. • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.
HEALTH
• May cause toxic effects if inhaled.
• Vapours are extremely irritating.
• Fire will produce irritating, corrosive and/or toxic gases. SPILL OR LEAK
• Runoff from fire control may cause pollution. • ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).
• Fully encapsulating, Vapour protective clothing should be worn for spills and leaks with no fire.
• CALL EMERGENCY RESPONSE Telephone Number on Shipping Paper first. If Shipping Paper not • Stop leak if you can do it without risk.
available or no answer, refer to appropriate telephone number listed on the inside back cover. • If possible, turn leaking containers so that gas escapes rather than liquid.
• Keep unauthorized personnel away. • Do not direct water at spill or source of leak.
• Stay upwind. • Isolate area until gas has dispersed.
• Many gases are heavier than air and will spread along ground and collect in low or confined areas
(sewers, basements, tanks). FIRST AID
• Keep out of low areas. • Move victim to fresh air.
• Ventilate closed spaces before entering. • Call 108 or emergency medical service.
PROTECTIVE CLOTHING • Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial
• Wear positive pressure self-contained breathing apparatus (SCBA). respiration with the aid of a pocket mask equipped with a one-way valve or other proper
• Wear chemical protective clothing that is specifically recommended by the manufacturer. It may respiratory medical device.
provide little or no thermal protection. • Administer oxygen if breathing is difficult.
• Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not • Remove and isolate contaminated clothing and shoes.
effective in spill situations where direct contact with the substance is possible. • In case of contact with liquefied gas, thaw frosted parts with lukewarm water.
EVACUATION • In case of burns, immediately cool affected skin for as long as possible with cold water. Do not
Large Spill remove clothing if adhering to skin.
• Consider initial downwind evacuation for at least 800 meters (1/2 mile). • Keep victim warm and quiet.
Fire • Keep victim under observation.
• If tank, rail car or tank truck is involved in a fire, ISOLATE for 1600 meters (1 mile) in all directions; • Effects of contact or inhalation may be delayed.
also, consider initial evacuation for 1600 meters (1 mile) in all directions. • Ensure that medical personnel are aware of the material(s) involved and take precautions to protect
themselves.
Page 176 Page 177

GUIDE Gases - Toxic - Flammable ERG2012 ERG2012 Gases - Toxic - Flammable GUIDE
119 119
HEALTH FIRE
• TOXIC; may be fatal if inhaled or absorbed through skin. • DO NOT EXTINGUISH A LEAKING GAS FIRE UNLESS LEAK CAN BE STOPPED.
• Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite. Small Fire
• Fire will produce irritating, corrosive and/or toxic gases. • Dry chemical, CO2, water spray or alcohol-resistant foam.
• Runoff from fire control may cause pollution. Large Fire
• Water spray, fog or alcohol-resistant foam.
FIRE OR EXPLOSION • FOR CHLOROSILANES, DO NOT USE WATER; use AFFF alcohol-resistant medium expansion foam.
• Flammable; may be ignited by heat, sparks or flames. • Move containers from fire area if you can do it without risk.
• May form explosive mixtures with air. • Damaged cylinders should be handled only by specialists.
• Those substances designated with a (P) may polymerize explosively when heated or involved in a fire. Fire involving Tanks
• Vapours from liquefied gas are initially heavier than air and spread along ground. • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.
• Vapours may travel to source of ignition and flash back. • Cool containers with flooding quantities of water until well after fire is out.
• Some of these materials may react violently with water. • Do not direct water at source of leak or safety devices; icing may occur.
• Cylinders exposed to fire may vent and release toxic and flammable gas through pressure relief devices. • Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank.
• Containers may explode when heated. • ALWAYS stay away from tanks engulfed in fire.
• Ruptured cylinders may rocket. SPILL OR LEAK
• Runoff may create fire or explosion hazard. • ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).
available or no answer, refer to appropriate telephone number listed on the inside back cover. • Do not direct water at spill or source of leak.
• Keep unauthorized personnel away. • FOR CHLOROSILANES, use AFFF alcohol-resistant medium expansion foam to reduce Vapours.
• Stay upwind. • If possible, turn leaking containers so that gas escapes rather than liquid.
• Many gases are heavier than air and will spread along ground and collect in low or confined areas • Prevent entry into waterways, sewers, basements or confined areas.
• Isolate area until gas has dispersed.
(sewers, basements, tanks).
• Keep out of low areas. FIRST AID
• Ventilate closed spaces before entering. • Move victim to fresh air. • Call 108 or emergency medical service.
PROTECTIVE CLOTHING • Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial
• Wear positive pressure self-contained breathing apparatus (SCBA). respiration with the aid of a pocket mask equipped with a one-way valve or other proper
• Wear chemical protective clothing that is specifically recommended by the manufacturer. It may respiratory medical device.
effective in spill situations where direct contact with the substance is possible. • In case of contact with substance, immediately flush skin or eyes with running water for at least 20
minutes.
Spill • In case of burns, immediately cool affected skin for as long as possible with cold water. Do not remove
• See Table 1 - Initial Isolation and Protective Action Distances for highlighted materials. For clothing if adhering to skin.
nonhighlighted materials, increase, in the downwind direction, as necessary, the isolation distance • Keep victim warm and quiet.
shown under “PUBLIC SAFETY”. • Keep victim under observation.
Fire • Effects of contact or inhalation may be delayed.
• If tank, rail car or tank truck is involved in a fire, ISOLATE for 1600 meters (1 mile) in all directions; • Ensure that medical personnel are aware of the material(s) involved and take precautions to protect
also, consider initial evacuation for 1600 meters (1 mile) in all directions. themselves.
Page 178 Page 179

GUIDE Gases - Inert ERG2012 ERG2012 Gases - Inert GUIDE
HEALTH FIRE
• Vapours may cause dizziness or asphyxiation without warning. • Use extinguishing agent suitable for type of surrounding fire.
• Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite. • Damaged cylinders should be handled only by specialists.
FIRE OR EXPLOSION Fire involving Tanks
• Non-flammable gases. • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.
• Containers may explode when heated. • Cool containers with flooding quantities of water until well after fire is out.
• Ruptured cylinders may rocket. • Do not direct water at source of leak or safety devices; icing may occur.
PUBLIC SAFETY
• CALL EMERGENCY RESPONSE Telephone Number on Shipping Paper first. If Shipping Paper not SPILL OR LEAK
available or no answer, refer to appropriate telephone number listed on the inside back cover. • Do not touch or walk through spilled material.
• As an immediate precautionary measure, isolate spill or leak area for at least 100 meters (330 feet) in • Stop leak if you can do it without risk.
• Many gases are heavier than air and will spread along ground and collect in low or confined areas • If possible, turn leaking containers so that gas escapes rather than liquid.
(sewers, basements, tanks). • Prevent entry into waterways, sewers, basements or confined areas.
• Keep out of low areas. • Allow substance to eVapourate.
• Ventilate closed spaces before entering. • Ventilate the area.
CAUTION: When in contact with refrigerated/cryogenic liquids, many materials become brittle and are
PROTECTIVE CLOTHING likely to break without warning.
• Always wear thermal protective clothing when handling refrigerated/cryogenic liquids or solids. • Move victim to fresh air.
Large Spill • Administer oxygen if breathing is difficult.
• Consider initial downwind evacuation for at least 100 meters (330 feet). • Clothing frozen to the skin should be thawed before being removed.
Fire • In case of contact with liquefied gas, thaw frosted parts with lukewarm water.
• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; • Keep victim warm and quiet.
also, consider initial evacuation for 800 meters (1/2 mile) in all directions. • Ensure that medical personnel are aware of the material(s) involved and take precautions to protect
themselves.
Page 180 Page 181

GUIDE Gases - Inert ERG2012 ERG2012 Gases - Inert GUIDE
121 121
HEALTH FIRE
• Vapours may cause dizziness or asphyxiation without warning. • Use extinguishing agent suitable for type of surrounding fire.
FIRE OR EXPLOSION • Damaged cylinders should be handled only by specialists.
• Non-flammable gases. Fire involving Tanks
• Containers may explode when heated. • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.
• Ruptured cylinders may rocket. • Cool containers with flooding quantities of water until well after fire is out.
PUBLIC SAFETY • ALWAYS stay away from tanks engulfed in fire.
PROTECTIVE CLOTHING FIRST AID
• Wear positive pressure self-contained breathing apparatus (SCBA). • Move victim to fresh air.
• Structural firefighters’ protective clothing will only provide limited protection. • Call 108 or emergency medical service.
EVACUATION
Large Spill
• Consider initial downwind evacuation for at least 100 meters (330 feet).
Fire
themselves.
• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions;
Page 182 Page 183

GUIDE Gases - Oxidizing ERG2012 ERG2012 Gases - Oxidizing GUIDE
• Substance does not burn but will support combustion. • Use extinguishing agent suitable for type of surrounding fire.
• Some may react explosively with fuels. Small Fire
• May ignite combustibles (wood, paper, oil, clothing, etc.). • Dry chemical or CO2.
Large Fire
• Vapours from liquefied gas are initially heavier than air and spread along ground.
• Water spray, fog or regular foam.
• Runoff may create fire or explosion hazard. • Move containers from fire area if you can do it without risk.
• Containers may explode when heated. • Damaged cylinders should be handled only by specialists.
• Ruptured cylinders may rocket. Fire involving Tanks
• Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.
HEALTH • Cool containers with flooding quantities of water until well after fire is out.
• Vapours may cause dizziness or asphyxiation without warning. • Do not direct water at source of leak or safety devices; icing may occur.
• Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite. • Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank.
• Fire may produce irritating and/or toxic gases. • ALWAYS stay away from tanks engulfed in fire.
PUBLIC SAFETY SPILL OR LEAK
• CALL EMERGENCY RESPONSE Telephone Number on Shipping Paper first. If Shipping Paper not • Keep combustibles (wood, paper, oil, etc.) away from spilled material.
all directions. • If possible, turn leaking containers so that gas escapes rather than liquid.
• Stay upwind. • Use water spray to reduce Vapours or divert Vapour cloud drift. Avoid allowing water runoff to
• Many gases are heavier than air and will spread along ground and collect in low or confined areas contact spilled material.
• Ventilate closed spaces before entering. • Isolate area until gas has dispersed.
PROTECTIVE CLOTHING CAUTION: When in contact with refrigerated/cryogenic liquids, many materials become brittle and are
• Wear positive pressure self-contained breathing apparatus (SCBA). likely to break without warning.
• Wear chemical protective clothing that is specifically recommended by the manufacturer. It may FIRST AID
provide little or no thermal protection. • Move victim to fresh air.
• Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not • Call 108 or emergency medical service.
effective in spill situations where direct contact with the substance is possible. • Give artificial respiration if victim is not breathing.
• Always wear thermal protective clothing when handling refrigerated/cryogenic liquids. • Administer oxygen if breathing is difficult.
Large Spill • Clothing frozen to the skin should be thawed before being removed.
• Consider initial downwind evacuation for at least 500 meters (1/3 mile). • In case of contact with liquefied gas, thaw frosted parts with lukewarm water.
• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; • Ensure that medical personnel are aware of the material(s) involved and take precautions to protect
also,consider initial evacuation for 800 meters (1/2 mile) in all directions. themselves.
Page 184 Page 185

GUIDE Gases - Toxic and/or Corrosive ERG2012 ERG2012 Gases - Toxic and/or Corrosive GUIDE
123 123
HEALTH FIRE
• TOXIC; may be fatal if inhaled or absorbed through skin. Small Fire
• Vapours may be irritating. • Dry chemical or CO2.
• Runoff from fire control may cause pollution. • Do not get water inside containers.
• Move containers from fire area if you can do it without risk.
FIRE OR EXPLOSION
• Some may burn but none ignite readily.
• Cylinders exposed to fire may vent and release toxic and/or corrosive gas through pressure relief
devices.
• Containers may explode when heated.
• Ruptured cylinders may rocket.
SPILL OR LEAK
PUBLIC SAFETY • Fully encapsulating, Vapour protective clothing should be worn for spills and leaks with no fire.
• As an immediate precautionary measure, isolate spill or leak area for at least 100 meters (330 feet) in • If possible, turn leaking containers so that gas escapes rather than liquid.
all directions. • Prevent entry into waterways, sewers, basements or confined areas.
• Keep unauthorized personnel away. • Use water spray to reduce Vapours or divert Vapour cloud drift. Avoid allowing water runoff to
• Stay upwind. contact spilled material.
• Many gases are heavier than air and will spread along ground and collect in low or confined areas • Do not direct water at spill or source of leak.
• Wear chemical protective clothing that is specifically recommended by the manufacturer. It may • Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial
provide little or no thermal protection. respiration with the aid of a pocket mask equipped with a one-way valve or other proper
• Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not respiratory medical device.
effective in spill situations where direct contact with the substance is possible. • Administer oxygen if breathing is difficult.
Spill • In case of contact with liquefied gas, thaw frosted parts with lukewarm water.
• See Table 1 - Initial Isolation and Protective Action Distances for highlighted materials. For • In case of contact with substance, immediately flush skin or eyes with running water for at least 20
nonhighlighted materials, increase, in the downwind direction, as necessary, the isolation distance minutes.
shown under “PUBLIC SAFETY”. • Keep victim warm and quiet.
Fire • Keep victim under observation.
• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, • Effects of contact or inhalation may be delayed.
consider initial evacuation for 800 meters (1/2 mile) in all directions. • Ensure that medical personnel are aware of the material(s) involved and take precautions to protect
themselves.
Page 186 Page 187

GUIDE Gases - Toxic and/or Corrosive - Oxidizing ERG2012 ERG2012 Gases - Toxic and/or Corrosive - Oxidizing GUIDE
124 124
HEALTH FIRE
• TOXIC; may be fatal if inhaled or absorbed through skin. Small Fire
• Fire will produce irritating, corrosive and/or toxic gases. CAUTION: These materials do not burn but will support combustion. Some will react violently with water.
• Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite. • Contain fire and let burn. If fire must be fought, water spray or fog is recommended.
• Runoff from fire control may cause pollution. • Water only; no dry chemical, CO2 or Halon®.
FIRE OR EXPLOSION
• Substance does not burn but will support combustion.
• These are strong oxidizers and will react vigorously or explosively with many materials including fuels.
• May ignite combustibles (wood, paper, oil, clothing, etc.).
• Some will react violently with air, moist air and/or water.
• Cylinders exposed to fire may vent and release toxic and/or corrosive gas through pressure relief
devices.
SPILL OR LEAK
available or no answer, refer to appropriate telephone number listed on the inside back cover. • Keep combustibles (wood, paper, oil, etc.) away from spilled material.
• Keep out of low areas. • Isolate area until gas has dispersed.
• Wear chemical protective clothing that is specifically recommended by the manufacturer. It may • Call 108 or emergency medical service.
provide little or no thermal protection. • Give artificial respiration if victim is not breathing.
• Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not • Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial
effective in spill situations where direct contact with the substance is possible. respiration with the aid of a pocket mask equipped with a one-way valve or other proper
EVACUATION respiratory medical device.
Spill • Administer oxygen if breathing is difficult.
• See Table 1 - Initial Isolation and Protective Action Distances. • Clothing frozen to the skin should be thawed before being removed.
• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; • In case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes.
also, consider initial evacuation for 800 meters (1/2 mile) in all directions. • Keep victim warm and quiet.
• Keep victim under observation.
• Effects of contact or inhalation may be delayed.
themselves.
Page 188 Page 189

GUIDE Gases - Corrosive ERG2012 ERG2012 Gases - Corrosive GUIDE
125 125
HEALTH FIRE
• TOXIC; may be fatal if inhaled, ingested or absorbed through skin. Small Fire
• Vapours are extremely irritating and corrosive. • Dry chemical or CO2.
• Runoff from fire control may cause pollution. • Move containers from fire area if you can do it without risk.
FIRE OR EXPLOSION
• Some may burn but none ignite readily.
• Some of these materials may react violently with water.
• Cylinders exposed to fire may vent and release toxic and/or corrosive gas through pressure relief devices.
SPILL OR LEAK
• If possible, turn leaking containers so that gas escapes rather than liquid.
• As an immediate precautionary measure, isolate spill or leak area for at least 100 meters (330 feet) in
all directions.
• Do not direct water at spill or source of leak.
• Stay upwind.
• Many gases are heavier than air and will spread along ground and collect in low or confined areas
• Isolate area until gas has dispersed.
(sewers, basements, tanks).
• Ventilate closed spaces before entering. • Move victim to fresh air.
PROTECTIVE CLOTHING
• Wear chemical protective clothing that is specifically recommended by the manufacturer. It may
provide little or no thermal protection.
respiratory medical device.
• Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not
effective in spill situations where direct contact with the substance is possible.
Spill • In case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes.
• See Table 1 - Initial Isolation and Protective Action Distances for highlighted materials. For • In case of contact with Hydrogen fluoride, anhydrous (UN1052), flush skin and eyes with water for 5
nonhighlighted materials, increase, in the downwind direction, as necessary, the isolation distance minutes; then, for skin exposures rub on a calcium/gel combination; for eyes flush with a
shown under “PUBLIC SAFETY”. water/calcium solution for 15 minutes.
• If tank, rail car or tank truck is involved in a fire, ISOLATE for 1600 meters (1 mile) in all directions; • Keep victim under observation.
also, consider initial evacuation for 1600 meters (1 mile) in all directions • Effects of contact or inhalation may be delayed.
themselves.
Page 190 Page 191

GUIDE Gases - Compressed or Liquefied ERG2012 ERG2012 Gases - Compressed or Liquefied GUIDE
126 (Including Refrigerated Gases) (Including Refrigerated Gases) 126
• Some may burn but none ignite readily. • Use extinguishing agent suitable for type of surrounding fire.
• Containers may explode when heated. Small Fire
• Ruptured cylinders may rocket. • Dry chemical or CO2.
Large Fire
HEALTH
• Vapours may cause dizziness or asphyxiation without warning.
• Fire may produce irritating, corrosive and/or toxic gases.
PUBLIC SAFETY • Do not direct water at source of leak or safety devices; icing may occur.
• CALL EMERGENCY RESPONSE Telephone Number on Shipping Paper first. If Shipping Paper not • Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank.
available or no answer, refer to appropriate telephone number listed on the inside back cover. • ALWAYS stay away from tanks engulfed in fire.
• As an immediate precautionary measure, isolate spill or leak area for at least 100 meters (330 feet) in • Some of these materials, if spilled, may eVapourate leaving a flammable residue.
all directions. SPILL OR LEAK
• Keep unauthorized personnel away. • Do not touch or walk through spilled material.
• Stay upwind. • Stop leak if you can do it without risk.
• Many gases are heavier than air and will spread along ground and collect in low or confined areas • Do not direct water at spill or source of leak.
(sewers, basements, tanks). • Use water spray to reduce Vapours or divert Vapour cloud drift. Avoid allowing water runoff to
• Keep out of low areas. contact spilled material.
• Ventilate closed spaces before entering. • If possible, turn leaking containers so that gas escapes rather than liquid.
PROTECTIVE CLOTHING • Prevent entry into waterways, sewers, basements or confined areas.
• Wear positive pressure self-contained breathing apparatus (SCBA). • Allow substance to eVapourate.
• Wear chemical protective clothing that is specifically recommended by the manufacturer. It may • Ventilate the area.
provide little or no thermal protection. FIRST AID
• Consider initial downwind evacuation for at least 500 meters (1/3 mile). • Administer oxygen if breathing is difficult.
• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; • In case of contact with liquefied gas, thaw frosted parts with lukewarm water.
themselves.
Page 192 Page 193

GUIDE Flammable Liquids ERG2012 ERG2012 Flammable Liquids GUIDE
127 (Polar/Water-Miscible) (Polar/Water-Miscible) 127
• HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. CAUTION: All these products have a very low flash point: Use of water spray when fighting fire may
• Vapours may form explosive mixtures with air. be inefficient.
• Vapours may travel to source of ignition and flash back. Small Fire
• Most Vapours are heavier than air. They will spread along ground and collect in low or confined areas • Dry chemical, CO2, water spray or alcohol-resistant foam.
(sewers, basements, tanks). Large Fire
• Vapour explosion hazard indoors, outdoors or in sewers. • Water spray, fog or alcohol-resistant foam.
• Those substances designated with a (P) may polymerize explosively when heated or involved in a fire. • Do not use straight streams.
• Runoff to sewer may create fire or explosion hazard. • Move containers from fire area if you can do it without risk.
• Containers may explode when heated. Fire involving Tanks or Car/Trailer Loads
• Many liquids are lighter than water. • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.
HEALTH
• Inhalation or contact with material may irritate or burn skin and eyes.
• Vapours may cause dizziness or suffocation.
• Runoff from fire control may cause pollution.
SPILL OR LEAK
all directions. • A Vapour suppressing foam may be used to reduce Vapours.
• Keep unauthorized personnel away. • Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers.
• Stay upwind. • Use clean non-sparking tools to collect absorbed material.
• Keep out of low areas. Large Spill
• Ventilate closed spaces before entering. • Dike far ahead of liquid spill for later disposal.
PROTECTIVE CLOTHING • Water spray may reduce Vapour; but may not prevent ignition in closed spaces.
• Consider initial downwind evacuation for at least 300 meters (1000 feet). • Administer oxygen if breathing is difficult.
• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; • In case of contact with substance, immediately flush skin or eyes with running water for at least 20
also, consider initial evacuation for 800 meters (1/2 mile) in all directions. minutes.
• Wash skin with soap and water.
• In case of burns, immediately cool affected skin for as long as possible with cold water. Do not remove
clothing if adhering to skin.
themselves.
Page 194 Page 195

128 (Non-Polar/Water-Immiscible) (Non-Polar/Water-Immiscible) 128
• HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. CAUTION: All these products have a very low flash point: Use of water spray when fighting fire may be
• Vapours may form explosive mixtures with air. inefficient.
• Vapours may travel to source of ignition and flash back. CAUTION: For mixtures containing alcohol or polar solvent, alcohol-resistant foam may be more
• Most Vapours are heavier than air. They will spread along ground and collect in low or confined areas effective.
(sewers, basements, tanks). Small Fire
• Vapour explosion hazard indoors, outdoors or in sewers. • Dry chemical, CO2, water spray or regular foam.
• Those substances designated with a (P) may polymerize explosively when heated or involved in a fire. Large Fire
• Runoff to sewer may create fire or explosion hazard. • Water spray, fog or regular foam.
• Containers may explode when heated. • Do not use straight streams.
• Many liquids are lighter than water. • Move containers from fire area if you can do it without risk.
• Substance may be transported hot. Fire involving Tanks or Car/Trailer Loads
• For UN3166, if Lithium ion batteries are involved, also consult GUIDE 147. • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.
• If molten aluminum is involved, refer to GUIDE 169. • Cool containers with flooding quantities of water until well after fire is out.
HEALTH
• Runoff from fire control or dilution water may cause pollution. SPILL OR LEAK
available or no answer, refer to appropriate telephone number listed on the inside back cover. • Prevent entry into waterways, sewers, basements or confined areas.
• As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet) in • A Vapour suppressing foam may be used to reduce Vapours.
all directions. • Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers.
• Keep unauthorized personnel away. • Use clean non-sparking tools to collect absorbed material.
• Stay upwind. Large Spill
• Keep out of low areas. • Dike far ahead of liquid spill for later disposal.
• Ventilate closed spaces before entering. • Water spray may reduce Vapour; but may not prevent ignition in closed spaces.
• Consider initial downwind evacuation for at least 300 meters (1000 feet). • Remove and isolate contaminated clothing and shoes.
Fire • In case of contact with substance, immediately flush skin or eyes with running water for at least 20
• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; minutes.
also, consider initial evacuation for 800 meters (1/2 mile) in all directions. • Wash skin with soap and water.
• In case of burns, immediately cool affected skin for as long as possible with cold water.
Do not remove clothing if adhering to skin.
themselves.
Page 196 Page 197

129 (Polar/Water-Miscible/Noxious) (Polar/Water-Miscible/Noxious) 129
• Most Vapours are heavier than air. They will spread along ground and collect in low or confined areas • Dry chemical, CO2, water spray or alcohol-resistant foam.
(sewers, basements, tanks). • Do not use dry chemical extinguishers to control fires involving nitromethane or nitroethane.
• Vapour explosion hazard indoors, outdoors or in sewers. Large Fire
• Those substances designated with a (P) may polymerize explosively when heated or involved in a fire. • Water spray, fog or alcohol-resistant foam.
• Runoff to sewer may create fire or explosion hazard. • Do not use straight streams.
• Containers may explode when heated. • Move containers from fire area if you can do it without risk.
• Many liquids are lighter than water. Fire involving Tanks or Car/Trailer Loads
HEALTH
• May cause toxic effects if inhaled or absorbed through skin.
• Fire will produce irritating, corrosive and/or toxic gases.
• Runoff from fire control or dilution water may cause pollution.
SPILL OR LEAK
• Keep unauthorized personnel away. • Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers.
• Stay upwind. • Use clean non-sparking tools to collect absorbed material.
• Ventilate closed spaces before entering. • Dike far ahead of liquid spill for later disposal.
• Water spray may reduce Vapour; but may not prevent ignition in closed spaces.
PROTECTIVE CLOTHING
also, consider initial evacuation for 800 meters (1/2 mile) in all directions. • Wash skin with soap and water.
themselves.
Page 198 Page 199

130 (Non-Polar/Water-Immiscible/Noxious) (Non-Polar/Water-Immiscible/Noxious) 130
• Most Vapours are heavier than air. They will spread along ground and collect in low or confined areas • Dry chemical, CO2, water spray or regular foam.
(sewers, basements, tanks). Large Fire
• Vapour explosion hazard indoors, outdoors or in sewers. • Water spray, fog or alcohol-resistant foam.
• Those substances designated with a (P) may polymerize explosively when heated or involved in a fire. • Do not use straight streams.
• Runoff to sewer may create fire or explosion hazard. • Move containers from fire area if you can do it without risk.
• Containers may explode when heated. Fire involving Tanks or Car/Trailer Loads
• Many liquids are lighter than water. • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.
HEALTH
• May cause toxic effects if inhaled or absorbed through skin.
• As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet) in • A Vapour suppressing foam may be used to reduce Vapours.
all directions. • Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers.
• Ventilate closed spaces before entering. • Water spray may reduce Vapour; but may not prevent ignition in closed spaces.
• Consider initial downwind evacuation for at least 300 meters (1000 feet). • In case of contact with substance, immediately flush skin or eyes with running water for at least 20
Fire minutes.
• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; • Wash skin with soap and water.
also, consider initial evacuation for 800 meters (1/2 mile) in all directions. • In case of burns, immediately cool affected skin for as long as possible with cold water.
themselves.
Page 200 Page 201

GUIDE Flammable Liquids - Toxic ERG2012 ERG2012 Flammable Liquids - Toxic GUIDE
131 131
HEALTH FIRE
• TOXIC; may be fatal if inhaled, ingested or absorbed through skin. CAUTION: All these products have a very low flash point: Use of water spray when fighting fire may be
• Inhalation or contact with some of these materials will irritate or burn skin and eyes. inefficient.
• Fire will produce irritating, corrosive and/or toxic gases. Small Fire
• Vapours may cause dizziness or suffocation. • Dry chemical, CO2, water spray or alcohol-resistant foam.
• Runoff from fire control or dilution water may cause pollution. Large Fire
• Water spray, fog or alcohol-resistant foam.
FIRE OR EXPLOSION
• HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. • Dike fire-control water for later disposal; do not scatter the material.
• Vapours may form explosive mixtures with air. • Use water spray or fog; do not use straight streams.
• Vapours may travel to source of ignition and flash back. Fire involving Tanks or Car/Trailer Loads
• Most Vapours are heavier than air. They will spread along ground and collect in low or confined areas • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.
(sewers, basements, tanks). • Cool containers with flooding quantities of water until well after fire is out.
• Vapour explosion and poison hazard indoors, outdoors or in sewers. • Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank.
• Those substances designated with a (P) may polymerize explosively when heated or involved in a fire. • ALWAYS stay away from tanks engulfed in fire.
• Runoff to sewer may create fire or explosion hazard. • For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from
• Containers may explode when heated. area and let fire burn.
• Many liquids are lighter than water. SPILL OR LEAK
PUBLIC SAFETY • ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).
• Keep unauthorized personnel away. • Small Spill • Absorb with earth, sand or other non-combustible material and transfer to containers
• Stay upwind. for later disposal.
• Keep out of low areas. • Use clean non-sparking tools to collect absorbed material.
• Ventilate closed spaces before entering. • Large Spill • Dike far ahead of liquid spill for later disposal.
PROTECTIVE CLOTHING
FIRST AID
• Move victim to fresh air. • Call 108 or emergency medical service.
• Wear chemical protective clothing that is specifically recommended by the manufacturer. It may • Give artificial respiration if victim is not breathing.
provide little or no thermal protection. • Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial
• Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not respiration with the aid of a pocket mask equipped with a one-way valve or other proper
effective in spill situations where direct contact with the substance is possible. respiratory medical device.
Spill • Remove and isolate contaminated clothing and shoes.
• See Table 1 - Initial Isolation and Protective Action Distances for highlighted materials. For • In case of contact with substance, immediately flush skin or eyes with running water for at least 20
minutes.
nonhighlighted materials, increase, in the downwind direction, as necessary, the isolation distance
• Wash skin with soap and water.
shown under “PUBLIC SAFETY”.
Fire Do not remove clothing if adhering to skin. • Keep victim warm and quiet.
• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; • Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed.
themselves.
Page 202 Page 203

GUIDE Flammable Liquids - Corrosive ERG2012 ERG2012 Flammable Liquids - Corrosive GUIDE
132 132
• Flammable/combustible material. • Some of these materials may react violently with water.
• May be ignited by heat, sparks or flames. Small Fire
• Vapours may form explosive mixtures with air. • Dry chemical, CO2, water spray or alcohol-resistant foam.
• Most Vapours are heavier than air. They will spread along ground and collect in low or confined areas • Water spray, fog or alcohol-resistant foam.
(sewers, basements, tanks). • Move containers from fire area if you can do it without risk.
• Vapour explosion hazard indoors, outdoors or in sewers. • Dike fire-control water for later disposal; do not scatter the material.
• Those substances designated with a (P) may polymerize explosively when heated or involved in a fire. • Do not get water inside containers.
• Runoff to sewer may create fire or explosion hazard. Fire involving Tanks or Car/Trailer Loads
• Many liquids are lighter than water.
HEALTH • ALWAYS stay away from tanks engulfed in fire.
• May cause toxic effects if inhaled or ingested/swallowed. • For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from
• Contact with substance may cause severe burns to skin and eyes. area and let fire burn.
• Vapours may cause dizziness or suffocation. • Fully encapsulating, Vapour protective clothing should be worn for spills and leaks with no fire.
• Runoff from fire control or dilution water may cause pollution. • ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).
• CALL EMERGENCY RESPONSE Telephone Number on Shipping Paper first. If Shipping Paper not • Prevent entry into waterways, sewers, basements or confined areas.
available or no answer, refer to appropriate telephone number listed on the inside back cover. • A Vapour suppressing foam may be used to reduce Vapours.
• As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet) in • Absorb with earth, sand or other non-combustible material and transfer to containers (except for
all directions. Hydrazine).
FIRST AID
PROTECTIVE CLOTHING • Move victim to fresh air. • Call 108 or emergency medical service.
provide little or no thermal protection. respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory
• Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not medical device.
EVACUATION • In case of contact with substance, immediately flush skin or eyes with running water for at least 20
Spill minutes.
• See Table 1 - Initial Isolation and Protective Action Distances for highlighted materials. For • In case of burns, immediately cool affected skin for as long as possible with cold water. Do not remove
nonhighlighted materials, increase, in the downwind direction, as necessary, the isolation distance clothing if adhering to skin.
Fire • Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed.
also, consider initial evacuation for 800 meters (1/2 mile) in all directions. themselves.
Page 204 Page 205

GUIDE Flammable Solids ERG2012 ERG2012 Flammable Solids GUIDE
133 133
• Flammable/combustible material. Small Fire
• May be ignited by friction, heat, sparks or flames. • Dry chemical, CO2, sand, earth, water spray or regular foam.
• Some may burn rapidly with flare burning effect. Large Fire
• Powders, dusts, shavings, borings, turnings or cuttings may explode or burn with explosive violence. • Water spray, fog or regular foam.
• Substance may be transported in a molten form at a temperature that may be above its flash point. • Move containers from fire area if you can do it without risk.
• May re-ignite after fire is extinguished. Fire Involving Metal Pigments or Pastes (e.g. “Aluminum Paste”)
• Aluminum Paste fires should be treated as a combustible metal fire. Use DRY sand, graphite powder,
HEALTH
dry sodium chloride based extinguishers, G-1® or Met-L-X® powder. Also, see GUIDE 170.
Fire involving Tanks or Car/Trailer Loads
• Contact with molten substance may cause severe burns to skin and eyes.
available or no answer, refer to appropriate telephone number listed on the inside back cover. • ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).
• As an immediate precautionary measure, isolate spill or leak area for at least 25 meters (75 feet) in all • Do not touch or walk through spilled material.
directions. Small Dry Spill
• Keep unauthorized personnel away. • With clean shovel place material into clean, dry container and cover loosely; move containers from
• Stay upwind. spill area.
PROTECTIVE CLOTHING • Wet down with water and dike for later disposal.
• Wear positive pressure self-contained breathing apparatus (SCBA). • Prevent entry into waterways, sewers, basements or confined areas.
EVACUATION • Move victim to fresh air.
Large Spill • Call 108 or emergency medical service.
• Consider initial downwind evacuation for at least 100 meters (330 feet). • Give artificial respiration if victim is not breathing.
Fire • Administer oxygen if breathing is difficult.
• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; • Remove and isolate contaminated clothing and shoes.
also, consider initial evacuation for 800 meters (1/2 mile) in all directions. • In case of contact with substance, immediately flush skin or eyes with running water for at least 20
minutes.
• Removal of solidified molten material from skin requires medical assistance.
themselves.
Page 206 Page 207

GUIDE Flammable Solids - Toxic and/or Corrosive ERG2012 ERG2012 Flammable Solids - Toxic and/or Corrosive GUIDE
134 134
• Flammable/combustible material. Small Fire
• May be ignited by heat, sparks or flames. • Dry chemical, CO2, water spray or alcohol-resistant foam.
• When heated, Vapours may form explosive mixtures with air: indoors, outdoors and sewers explosion Large Fire
hazards. • Water spray, fog or alcohol-resistant foam.
• Contact with metals may evolve flammable hydrogen gas. • Move containers from fire area if you can do it without risk.
• Containers may explode when heated. • Use water spray or fog; do not use straight streams.
HEALTH
• Dike fire-control water for later disposal; do not scatter the material.
• TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death.
• Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.
available or no answer, refer to appropriate telephone number listed on the inside back cover. • Fully encapsulating, Vapour protective clothing should be worn for spills and leaks with no fire.
• As an immediate precautionary measure, isolate spill or leak area for at least 25 meters (75 feet) in all • ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).
directions. • Stop leak if you can do it without risk.
• Stay upwind. • Do not touch damaged containers or spilled material unless wearing appropriate protective clothing.
• Keep unauthorized personnel away. • Prevent entry into waterways, sewers, basements or confined areas.
• Keep out of low areas. • Use clean non-sparking tools to collect material and place it into loosely covered plastic containers for
• Ventilate enclosed areas. later disposal.
• Wear chemical protective clothing that is specifically recommended by the manufacturer. It may • Call 108 or emergency medical service.
provide little or no thermal protection. • Give artificial respiration if victim is not breathing.
• Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not • Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial
effective in spill situations where direct contact with the substance is possible. respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory
EVACUATION medical device.
also, consider initial evacuation for 800 meters (1/2 mile) in all directions. • For minor skin contact, avoid spreading material on unaffected skin.
themselves.
Page 208 Page 209

GUIDE Substances - Spontaneously Combustible ERG2012 ERG2012 Substances - Spontaneously Combustible GUIDE
135 135
• Flammable/combustible material. • DO NOT USE WATER, CO2 OR FOAM ON MATERIAL ITSELF.
• May ignite on contact with moist air or moisture. • Some of these materials may react violently with water.
• May burn rapidly with flare-burning effect. EXCEPTION: For Xanthates, UN3342 and for Dithionite (Hydrosulfite/Hydrosulphite) UN1384, Un1923
• Some react vigorously or explosively on contact with water. and UN1929, USE FLOODING AMOUNTS OF WATER for SMALL AND LARGE fires to stop the reaction.
Smothering will not work for these materials, they do not need air to burn.
• Some may decompose explosively when heated or involved in a fire.
Small Fire
• May re-ignite after fire is extinguished. • Dry chemical, soda ash, lime or DRY sand, EXCEPT for UN1384, UN1923, UN1929 and UN3342.
• Runoff may create fire or explosion hazard. Large Fire
• Containers may explode when heated. • DRY sand, dry chemical, soda ash or lime EXCEPT for UN1384, UN1923, UN1929 and UN3342, or
withdraw from area and let fire burn.
HEALTH
• CAUTION: UN3342 when flooded with water will continue to evolve flammable Carbon
• Fire will produce irritating, corrosive and/or toxic gases. disulfide/Carbon disulphide Vapours.
• Inhalation of decomposition products may cause severe injury or death. • Move containers from fire area if you can do it without risk.
• Contact with substance may cause severe burns to skin and eyes. Fire involving Tanks or Car/Trailer Loads
• Runoff from fire control may cause pollution. • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.
• Do not get water inside containers or in contact with substance.
PUBLIC SAFETY • Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank.
• CALL EMERGENCY RESPONSE Telephone Number on Shipping Paper first. If Shipping Paper not • ALWAYS stay away from tanks engulfed in fire.
available or no answer, refer to appropriate telephone number listed on the inside back cover. SPILL OR LEAK
• As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 • Fully encapsulating, Vapour protective clothing should be worn for spills and leaks with no fire.
meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. • ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).
• Stay upwind. • Do not touch or walk through spilled material.
• Keep unauthorized personnel away. Small Spill
• Keep out of low areas. EXCEPTION: For spills of Xanthates, UN3342 and for Dithionite (Hydrosulfite/Hydrosulphite), UN1384,
PROTECTIVE CLOTHING UN1923 and UN1929, dissolve in 5 parts water and collect for proper disposal.
• Wear positive pressure self-contained breathing apparatus (SCBA). • CAUTION: UN3342 when flooded with water will continue to evolve flammable Carbon
disulfide/Carbon disulphide Vapours.
• Wear chemical protective clothing that is specifically recommended by the manufacturer. It may • Cover with DRY earth, DRY sand or other non-combustible material followed with plastic sheet to
provide little or no thermal protection. minimize spreading or contact with rain.
• Structural firefighters’ protective clothing will only provide limited protection. • Use clean non-sparking tools to collect material and place it into loosely covered plastic containers for
EVACUATION later disposal.
Spill
• See Table 1 - Initial Isolation and Protective Action Distances for highlighted materials. For FIRST AID
nonhighlighted materials, increase, in the downwind direction, as necessary, the isolation distance • Call 108 or emergency medical service.
shown under “PUBLIC SAFETY”. • Give artificial respiration if victim is not breathing.
Fire • Administer oxygen if breathing is difficult.
• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; • Remove and isolate contaminated clothing and shoes.
minutes.
themselves.
Page 210 Page 211

GUIDE Substances - Spontaneously Combustible - Toxic ERG2012 ERG2012 Substances - Spontaneously Combustible - Toxic GUIDE
136 and/or Corrosive (Air-Reactive) and/or Corrosive (Air-Reactive) 136
• Extremely flammable; will ignite itself if exposed to air. Small Fire
• Burns rapidly, releasing dense, white, irritating fumes. • Water spray, wet sand or wet earth.
• Substance may be transported in a molten form. Large Fire
• May re-ignite after fire is extinguished. • Water spray or fog.
• Corrosive substances in contact with metals may produce flammable hydrogen gas. Do not scatter spilled material with high pressure water streams.
HEALTH
• TOXIC; ingestion of substance or inhalation of decomposition products will cause severe injury or
death.
• Contact with substance may cause severe burns to skin and eyes.
• Some effects may be experienced due to skin absorption. SPILL OR LEAK
• Runoff from fire control may be corrosive and/or toxic and cause pollution. • Fully encapsulating, Vapour protective clothing should be worn for spills and leaks with no fire.
PUBLIC SAFETY • Do not touch damaged containers or spilled material unless wearing appropriate protective clothing.
available or no answer, refer to appropriate telephone number listed on the inside back cover. Small Spill
• As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 • Cover with water, sand or earth. Shovel into metal container and keep material under water.
meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. Large Spill
• Stay upwind. • Dike for later disposal and cover with wet sand or earth.
FIRST AID
• Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not • In case of contact with substance, keep exposed skin areas immersed in water or covered with wet
effective in spill situations where direct contact with the substance is possible. bandages until medical attention is received.
• For Phosphorus (UN1381): Special aluminized protective clothing should be worn when direct contact • Removal of solidified molten material from skin requires medical assistance.
with the substance is possible. • Remove and isolate contaminated clothing and shoes at the site and place in metal container filled
EVACUATION with water. Fire hazard if allowed to dry.
Spill • Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed.
• Consider initial downwind evacuation for at least 300 meters (1000 feet). • Keep victim warm and quiet.
Page 212 Page 213

GUIDE Substances - Water-Reactive - Corrosive ERG2012 ERG2012 Substances - Water-Reactive - Corrosive GUIDE
137 137
HEALTH FIRE
• CORROSIVE and/or TOXIC; inhalation, ingestion or contact (skin, eyes) with Vapours, dusts or • When material is not involved in fire, do not use water on material itself.
substance may cause severe injury, burns or death. Small Fire
• Fire will produce irritating, corrosive and/or toxic gases. • Dry chemical or CO2.
• Reaction with water may generate much heat that will increase the concentration of fumes in the air. • Move containers from fire area if you can do it without risk.
• Contact with molten substance may cause severe burns to skin and eyes. Large Fire
• Runoff from fire control or dilution water may cause pollution. • Flood fire area with large quantities of water, while knocking down Vapours with water fog. If
insufficient water supply: knock down Vapours only.
FIRE OR EXPLOSION
• EXCEPT FOR ACETIC ANHYDRIDE (UN1715), THAT IS FLAMMABLE, some of these materials may burn,
but none ignite readily.
• Substance will react with water (some violently), releasing corrosive and/or toxic gases and runoff.
• Flammable/toxic gases may accumulate in confined areas (basement, tanks, hopper/tank cars, etc.).
• Contact with metals may evolve flammable hydrogen gas. SPILL OR LEAK
• Containers may explode when heated or if contaminated with water. • Fully encapsulating, Vapour protective clothing should be worn for spills and leaks with no fire.
• Substance may be transported in a molten form. • Do not touch damaged containers or spilled material unless wearing appropriate protective clothing.
• Use water spray to reduce Vapours; do not put water directly on leak, spill area or inside container.
PUBLIC SAFETY • Keep combustibles (wood, paper, oil, etc.) away from spilled material.
• CALL EMERGENCY RESPONSE Telephone Number on Shipping Paper first. If Shipping Paper not Small Spill
available or no answer, refer to appropriate telephone number listed on the inside back cover. • Cover with DRY earth, DRY sand or other non-combustible material followed with plastic sheet to
• As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 minimize spreading or contact with rain.
meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. • Use clean non-sparking tools to collect material and place it into loosely covered plastic containers for
• Keep unauthorized personnel away. later disposal.
• Ventilate enclosed areas. FIRST AID
provide little or no thermal protection. respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory
• Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not medical device.
Spill • In case of contact with substance, immediately flush skin or eyes with running water for at least 20
• See Table 1 - Initial Isolation and Protective Action Distances for highlighted materials. For minutes.
nonhighlighted materials, increase, in the downwind direction, as necessary, the isolation distance • For minor skin contact, avoid spreading material on unaffected skin.
shown under “PUBLIC SAFETY”. • Removal of solidified molten material from skin requires medical assistance.
• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; • Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed.
themselves.
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GUIDE Substances - Water - Reactive ERG2012 ERG2012 Substances - Water-Reactive GUIDE
138 (Emitting Flammable Gases) (Emitting Flammable Gases) 138
• Produce flammable gases on contact with water. • DO NOT USE WATER OR FOAM.
• May ignite on contact with water or moist air. Small Fire
• Some react vigorously or explosively on contact with water. • Dry chemical, soda ash, lime or sand.
• May be ignited by heat, sparks or flames. Large Fire
• May re-ignite after fire is extinguished. • DRY sand, dry chemical, soda ash or lime or withdraw from area and let fire burn.
• Some are transported in highly flammable liquids. • Move containers from fire area if you can do it without risk.
• Runoff may create fire or explosion hazard. Fire Involving Metals or Powders (Aluminum, Lithium, Magnesium, etc.)
• Use dry chemical, DRY sand, sodium chloride powder, graphite powder or Met-L-X® powder; in
HEALTH
addition, for Lithium you may use Lith-X® powder or copper powder. Also, see GUIDE 170.
• Inhalation or contact with Vapours, substance or decomposition products may cause severe injury or
death.
• May produce corrosive solutions on contact with water.
• CALL EMERGENCY RESPONSE Telephone Number on Shipping Paper first. If Shipping Paper not • ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).
• As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 • Stop leak if you can do it without risk.
meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. • Use water spray to reduce Vapours or divert Vapour cloud drift. Avoid allowing water runoff to
• Stay upwind. DO NOT GET WATER on spilled substance or inside containers.
• Keep out of low areas. Small Spill
• Ventilate the area before entry. • Cover with DRY earth, DRY sand or other non-combustible material followed with plastic sheet to
PROTECTIVE CLOTHING minimize spreading or contact with rain.
• Wear positive pressure self-contained breathing apparatus (SCBA). • Dike for later disposal; do not apply water unless directed to do so.
• Wear chemical protective clothing that is specifically recommended by the manufacturer. It may Powder Spill
provide little or no thermal protection. • Cover powder spill with plastic sheet or tarp to minimize spreading and keep powder dry.
• Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not • DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERVISION OF A SPECIALIST.
effective in spill situations where direct contact with the substance is possible. FIRST AID
EVACUATION • Move victim to fresh air.
Spill • Call 108 or emergency medical service.
• See Table 1 - Initial Isolation and Protective Action Distances for highlighted materials. For • Give artificial respiration if victim is not breathing.
nonhighlighted materials, increase, in the downwind direction, as necessary, the isolation distance • Administer oxygen if breathing is difficult.
shown under “PUBLIC SAFETY”. • Remove and isolate contaminated clothing and shoes.
Fire • In case of contact with substance, wipe from skin immediately; flush skin or eyes with running water
• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; for at least 20 minutes.
themselves.
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GUIDE Substances - Water - Reactive ERG2012 ERG2012 Substances - Water - Reactive GUIDE
139 (Emitting Flammable And Toxic Gases) (Emitting Flammable And Toxic Gases) 139
• Produce flammable and toxic gases on contact with water. • DO NOT USE WATER OR FOAM. (FOAM MAY BE USED FOR CHLOROSILANES, SEE BELOW)
• May ignite on contact with water or moist air. Small Fire
• Some react vigorously or explosively on contact with water. • Dry chemical, soda ash, lime or sand.
• DRY sand, dry chemical, soda ash or lime or withdraw from area and let fire burn.
• May re-ignite after fire is extinguished. • FOR CHLOROSILANES, DO NOT USE WATER; use AFFF alcohol-resistant medium expansion foam; DO
• Some are transported in highly flammable liquids. NOT USE dry chemicals, soda ash or lime on chlorosilane fires (large or small) as they may release
• Containers may explode when heated. large quantities of hydrogen gas that may explode.
HEALTH • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.
• Highly toxic: contact with water produces toxic gas, may be fatal if inhaled. • Cool containers with flooding quantities of water until well after fire is out.
• Inhalation or contact with Vapours, substance or decomposition products may cause severe injury or • Do not get water inside containers.
death. • Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank.
• May produce corrosive solutions on contact with water. • ALWAYS stay away from tanks engulfed in fire.
• Runoff from fire control may cause pollution. • Fully encapsulating, Vapour protective clothing should be worn for spills and leaks with no fire.
• CALL EMERGENCY RESPONSE Telephone Number on Shipping Paper first. If Shipping Paper not DO NOT GET WATER on spilled substance or inside containers.
available or no answer, refer to appropriate telephone number listed on the inside back cover. • Use water spray to reduce Vapours or divert Vapour cloud drift. Avoid allowing water runoff to
• As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50
• FOR CHLOROSILANES, use AFFF alcohol-resistant medium expansion foam to reduce Vapours.
meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. Small Spill
• Keep unauthorized personnel away. • Cover with DRY earth, DRY sand or other non-combustible material followed with plastic sheet to
• Stay upwind. minimize spreading or contact with rain.
• Keep out of low areas. • Dike for later disposal; do not apply water unless directed to do so.
• Ventilate the area before entry. Powder Spill
• Cover powder spill with plastic sheet or tarp to minimize spreading and keep powder dry.
• Wear chemical protective clothing that is specifically recommended by the manufacturer. It may • Move victim to fresh air.
provide little or no thermal protection. • Call 108 or emergency medical service.
• Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not • Give artificial respiration if victim is not breathing.
effective in spill situations where direct contact with the substance is possible. • Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial
EVACUATION respiratory medical device.
• See Table 1 - Initial Isolation and Protective Action Distances for highlighted materials. For • Remove and isolate contaminated clothing and shoes.
nonhighlighted materials, increase, in the downwind direction, as necessary, the isolation distance • In case of contact with substance, wipe from skin immediately; flush skin or eyes with running water
shown under “PUBLIC SAFETY”. for at least 20 minutes.
themselves.
Page 218 Page 219

GUIDE Oxidizers ERG2012 ERG2012 Oxidizers GUIDE
140 140
• These substances will accelerate burning when involved in a fire. Small Fire
• Some may decompose explosively when heated or involved in a fire. • Use water. Do not use dry chemicals or foams. CO2 or Halon® may provide limited control.
• May explode from heat or contamination. Large Fire
• Some will react explosively with hydrocarbons (fuels). • Flood fire area with water from a distance.
• May ignite combustibles (wood, paper, oil, clothing, etc.). • Do not move cargo or vehicle if cargo has been exposed to heat.
• Runoff may create fire or explosion hazard. Fire involving Tanks or Car/Trailer Loads
HEALTH
• Inhalation, ingestion or contact (skin, eyes) with Vapours or substance may cause severe injury, burns
or death.
SPILL OR LEAK
Small Dry Spill
meters
• With clean shovel place material into clean, dry container and cover loosely; move containers from
spill area.
meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.
Small Liquid Spill
• Use a non-combustible material like vermiculite or sand to soak up the product and place into a
• Stay upwind.
container for later disposal.
Large Spill
• Dike far ahead of liquid spill for later disposal.
PROTECTIVE CLOTHING • Following product recovery, flush area with water.
FIRST AID
• Consider initial downwind evacuation for at least 100 meters (330 feet). • Contaminated clothing may be a fire risk when dry.
themselves.
Page 220 Page 221

GUIDE Oxidizers - Toxic ERG2012 ERG2012 Oxidizers - Toxic GUIDE
141 141
• May explode from heat or contamination. • Use water. Do not use dry chemicals or foams. CO2 or Halon® may provide limited control.
• Some may burn rapidly. Large Fire
• May ignite combustibles (wood, paper, oil, clothing, etc.). • Do not move cargo or vehicle if cargo has been exposed to heat.
• Runoff may create fire or explosion hazard. Fire involving Tanks or Car/Trailer Loads
HEALTH
• Toxic by ingestion.
• Inhalation of dust is toxic.
• Contact with substance may cause severe burns to skin and eyes.
• Do not touch damaged containers or spilled material unless wearing appropriate protective clothing.
Small Dry Spill
• With clean shovel place material into clean, dry container and cover loosely; move containers from
spill area.
Large Spill
• Dike far ahead of spill for later disposal.
• Stay upwind.
• Ventilate closed spaces before entering. • Move victim to fresh air.
PROTECTIVE CLOTHING
• Contaminated clothing may be a fire risk when dry.
EVACUATION minutes.
Large Spill • Keep victim warm and quiet.
• Consider initial downwind evacuation for at least 100 meters (330 feet). • Ensure that medical personnel are aware of the material(s) involved and take precautions to protect
Fire themselves.
Page 222 Page 223

GUIDE Oxidizers - Toxic (Liquid) ERG2012 ERG2012 Oxidizers - Toxic (Liquid) GUIDE
142 142
• May explode from heat or contamination. • Use water. Do not use dry chemicals or foams. CO2 or Halon® may provide limited control.
• Some will react explosively with hydrocarbons (fuels). Large Fire
• May ignite combustibles (wood, paper, oil, clothing, etc.). • Flood fire area with water from a distance.
• Containers may explode when heated. • Do not move cargo or vehicle if cargo has been exposed to heat.
HEALTH
• TOXIC; inhalation, ingestion or contact (skin, eyes) with Vapours or substance may cause severe injury,
burns or death.
• Toxic/flammable fumes may accumulate in confined areas (basement, tanks, tank cars, etc.).
SPILL OR LEAK
• CALL EMERGENCY RESPONSE Telephone Number on Shipping Paper first. If Shipping Paper not • Do not touch damaged containers or spilled material unless wearing appropriate protective clothing.
• As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet) in • Use water spray to reduce Vapours or divert Vapour cloud drift.
all directions. • Do not get water inside containers.
• Keep unauthorized personnel away. Small Liquid Spill
• Stay upwind. • Use a non-combustible material like vermiculite or sand to soak up the product and place into a
• Keep out of low areas. container for later disposal.
• Ventilate closed spaces before entering. Large Spill
PROTECTIVE CLOTHING • Dike far ahead of liquid spill for later disposal.
EVACUATION respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory
Spill medical device.
• See Table 1 - Initial Isolation and Protective Action Distances for highlighted materials. For • Administer oxygen if breathing is difficult.
nonhighlighted materials, increase, in the downwind direction, as necessary, the isolation distance • Remove and isolate contaminated clothing and shoes.
shown under “PUBLIC SAFETY”. • Contaminated clothing may be a fire risk when dry.
themselves.
Page 224 Page 225

GUIDE Oxidizers (Unstable) ERG2012 ERG2012 Oxidizers (Unstable) GUIDE
143 143
• May explode from friction, heat or contamination. Small Fire
• These substances will accelerate burning when involved in a fire. • Use water. Do not use dry chemicals or foams. CO2 or Halon® may provide limited control.
• May ignite combustibles (wood, paper, oil, clothing, etc.). Large Fire
• Do not get water inside containers: a violent reaction may occur.
HEALTH
• TOXIC; inhalation, ingestion or contact (skin, eyes) with Vapours, dusts or substance may cause severe
injury, burns or death.
• Dike fire-control water for later disposal.
• Toxic fumes or dust may accumulate in confined areas (basement, tanks, hopper/tank cars, etc.).
SPILL OR LEAK
PUBLIC SAFETY • Keep combustibles (wood, paper, oil, etc.) away from spilled material.
• CALL EMERGENCY RESPONSE Telephone Number on Shipping Paper first. If Shipping Paper not • Do not touch damaged containers or spilled material unless wearing appropriate protective clothing.
available or no answer, refer to appropriate telephone number listed on the inside back cover. • Use water spray to reduce Vapours or divert Vapour cloud drift.
• As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 • Prevent entry into waterways, sewers, basements or confined areas.
• Keep unauthorized personnel away. • Flush area with flooding quantities of water.
• Keep out of low areas. • DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERVISION OF A SPECIALIST.
FIRST AID
effective in spill situations where direct contact with the substance is possible. • Contaminated clothing may be a fire risk when dry.
Spill minutes.
• See Table 1 - Initial Isolation and Protective Action Distances for highlighted materials. For • Keep victim warm and quiet.
nonhighlighted materials, increase, in the downwind direction, as necessary, the isolation distance • Ensure that medical personnel are aware of the material(s) involved and take precautions to protect
shown under “PUBLIC SAFETY”. themselves.
Fire
Page 226 Page 227

GUIDE Oxidizers (Water-Reactive) ERG2012 ERG2012 Oxidizers (Water-Reactive) GUIDE
144 144
• May ignite combustibles (wood, paper, oil, clothing, etc.). • DO NOT USE WATER OR FOAM.
• React vigorously and/or explosively with water. Small Fire
• Produce toxic and/or corrosive substances on contact with water. • Dry chemical, soda ash or lime.
• Flammable/toxic gases may accumulate in tanks and hopper cars. Large Fire
• Some may produce flammable hydrogen gas upon contact with metals. • DRY sand, dry chemical, soda ash or lime or withdraw from area and let fire burn.
HEALTH
• TOXIC; inhalation or contact with Vapour, substance, or decomposition products may cause severe
injury or death.
SPILL OR LEAK
• As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 contact spilled material.
meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. • DO NOT GET WATER on spilled substance or inside containers.
• Keep unauthorized personnel away. Small Spill
• Stay upwind. • Cover with DRY earth, DRY sand or other non-combustible material followed with plastic sheet to
• Keep out of low areas. minimize spreading or contact with rain.
• Ventilate closed spaces before entering. Large Spill
EVACUATION respiration with the aid of a pocket mask equipped with a one-way valve or other proper
Spill respiratory medical device.
• See Table 1 - Initial Isolation and Protective Action Distances for highlighted materials. For • Administer oxygen if breathing is difficult.
nonhighlighted materials, increase, in the downwind direction, as necessary, the isolation distance • Remove and isolate contaminated clothing and shoes.
shown under “PUBLIC SAFETY”. • Contaminated clothing may be a fire risk when dry.
themselves.
Page 228 Page 229

GUIDE Organic Peroxides ERG2012 ERG2012 Organic Peroxides GUIDE
145 (Heat and Contamination Sensitive) (Heat and Contamination Sensitive) 145
• May explode from heat or contamination. Small Fire
• May ignite combustibles (wood, paper, oil, clothing, etc.). • Water spray or fog is preferred; if water not available use dry chemical, CO2 or regular foam.
• May burn rapidly with flare-burning effect. • Flood fire area with water from a distance.
• Runoff may create fire or explosion hazard. • Do not move cargo or vehicle if cargo has been exposed to heat.
HEALTH
• Ingestion or contact (skin, eyes) with substance may cause severe injury or burns.
PUBLIC SAFETY area and let fire burn.
• As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 • Keep combustibles (wood, paper, oil, etc.) away from spilled material.
meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. • Do not touch damaged containers or spilled material unless wearing appropriate protective clothing.
• Keep unauthorized personnel away. • Keep substance wet using water spray.
PROTECTIVE CLOTHING • Take up with inert, damp, non-combustible material using clean non-sparking tools and place into
• Wear positive pressure self-contained breathing apparatus (SCBA). loosely covered plastic containers for later disposal.
• Wear chemical protective clothing that is specifically recommended by the manufacturer. It may Large Spill
provide little or no thermal protection. • Wet down with water and dike for later disposal.
• Structural firefighters’ protective clothing will only provide limited protection. • Prevent entry into waterways, sewers, basements or confined areas.
• DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERVISION OF A SPECIALIST.
EVACUATION
Large Spill FIRST AID
• Consider initial evacuation for at least 250 meters (800 feet) in all directions. • Move victim to fresh air.
Fire • Call 108 or emergency medical service.
• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; • Give artificial respiration if victim is not breathing.
also, consider initial evacuation for 800 meters (1/2 mile) in all directions. • Administer oxygen if breathing is difficult.
• Remove material from skin immediately.
minutes.
themselves.
Page 230 Page 231

GUIDE Organic Peroxides (Heat, Contamination and ERG2012 ERG2012 Organic Peroxides (Heat, Contamination and GUIDE
146 Friction Sensitive) Friction Sensitive) 146
• May explode from heat, shock, friction or contamination. Small Fire
• May burn rapidly with flare-burning effect. • Flood fire area with water from a distance.
• Runoff may create fire or explosion hazard. • Do not move cargo or vehicle if cargo has been exposed to heat.
HEALTH
• Keep unauthorized personnel away. • Keep substance wet using water spray.
PROTECTIVE CLOTHING • Take up with inert, damp, non-combustible material using clean non-sparking tools and place into
• Wear positive pressure self-contained breathing apparatus (SCBA). loosely covered plastic containers for later disposal.
• Wear chemical protective clothing that is specifically recommended by the manufacturer. It may Large Spill
provide little or no thermal protection. • Wet down with water and dike for later disposal.
• Structural firefighters’ protective clothing will only provide limited protection. • Prevent entry into waterways, sewers, basements or confined areas.
• DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERVISION OF A SPECIALIST.
EVACUATION
Large Spill FIRST AID
• Consider initial evacuation for at least 250 meters (800 feet) in all directions. • Move victim to fresh air.
Fire • Call 108 or emergency medical service.
• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; • Give artificial respiration if victim is not breathing.
also, consider initial evacuation for 800 meters (1/2 mile) in all directions. • Administer oxygen if breathing is difficult.
• Remove material from skin immediately.
minutes.
themselves.
Page 232 Page 233

GUIDE Lithium Ion Batteries ERG2012 ERG2012 Lithium Ion Batteries GUIDE
147 147
• Lithium ion batteries contain flammable liquid electrolyte that may vent, ignite and produce sparks Small Fire
when subjected to high temperatures (> 150 0C (302 0F)), when damaged or abused (e.g., mechanical • Dry chemical, CO2, water spray or regular foam.
damage or electrical overcharging). Large Fire
• May burn rapidly with flare-burning effect. • Water spray, fog or regular foam.
• May ignite other batteries in close proximity. • Move containers from fire area if you can do it without risk.
HEALTH SPILL OR LEAK
• Contact with battery electrolyte may be irritating to skin, eyes and mucous membranes. • ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).
• Fire will produce irritating, corrosive and/or toxic gases. • Do not touch or walk through spilled material.
• Burning batteries may produce toxic hydrogen fluoride gas (see GUIDE 125). • Absorb with earth, sand or other non-combustible material.
• Fumes may cause dizziness or suffocation. • Leaking batteries and contaminated absorbent material should be placed in metal containers.
FIRST AID
PUBLIC SAFETY • Move victim to fresh air.
• CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not • Call 108 or emergency medical service.
available or no answer, refer to appropriate telephone number listed on the inside back cover. • Give artificial respiration if victim is not breathing.
• As an immediate precautionary measure, isolate spill or leak area for at least 25 meters (75 feet) in all • Administer oxygen if breathing is difficult.
directions. • Remove and isolate contaminated clothing and shoes.
• Keep unauthorized personnel away. • In case of contact with substance, immediately flush skin or eyes with running water for at least 20
• Stay upwind. minutes.
• Keep out of low areas. • Ensure that medical personnel are aware of the material(s) involved and take precautions to protect
• Ventilate closed spaces before entering. themselves.
PROTECTIVE CLOTHING
EVACUATION
Large Spill
Fire
• If rail car or trailer is involved in a fire, ISOLATE for 500 meters (1/3 mile) in all directions; also initiate
evacuation including emergency responders for 500 meters (1/3 mile) in all directions.
Page 234 Page 235

GUIDE Organic Peroxides (Heat and Contamination ERG2012 ERG2012 Organic Peroxides (Heat and Contamination GUIDE
148 Sensitive/Temperature Controll ed) Sensitive/Temperature Controll ed) 148
• May explode from heat, contamination or loss of temperature control. • The temperature of the substance must be maintained at or below the “Control Temperature” at all
• These materials are particularly sensitive to temperature rises. Above a given “Control Temperature” times.
they decompose violently and catch fire. Small Fire
• May ignite spontaneously if exposed to air. Large Fire
• May be ignited by heat, sparks or flames. • Flood fire area with water from a distance.
• May burn rapidly with flare-burning effect. • Use water spray or fog; do not use straight streams.
HEALTH
• BEWARE OF POSSIBLE CONTAINER EXPLOSION.
meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. • Do not touch or walk through spilled material.
• Keep unauthorized personnel away. • Stop leak if you can do it without risk.
• Stay upwind. Small Spill
• Keep out of low areas. • Take up with inert, damp, non-combustible material using clean non-sparking tools and place into
• DO NOT allow the substance to warm up. Obtain liquid nitrogen (wear thermal protective clothing, loosely covered plastic containers for later disposal.
see GUIDE 120), dry ice or ice for cooling. If this is not possible or none can be obtained, evacuate Large Spill
the area immediately. • Dike far ahead of liquid spill for later disposal.
PROTECTIVE CLOTHING • Prevent entry into waterways, sewers, basements or confined areas.
• Wear positive pressure self-contained breathing apparatus (SCBA). • DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERVISION OF A SPECIALIST.
• Consider initial evacuation for at least 250 meters (800 feet) in all directions. • Remove and isolate contaminated clothing and shoes.
Fire • Contaminated clothing may be a fire risk when dry.
• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; • Remove material from skin immediately.
minutes.
themselves.
Page 236 Page 237

GUIDE Substances (Self-Reactive) ERG2012 ERG2012 Substances (Self-Reactive) GUIDE
149 149
• Self-decomposition or self-ignition may be triggered by heat, chemical reaction, friction or impact. Small Fire
• May be ignited by heat, sparks or flames. • Dry chemical, CO2, water spray or regular foam.
• Some may decompose explosively when heated or involved in a fire. Large Fire
• May burn violently. Decomposition may be self-accelerating and produce large amounts of gases. • Flood fire area with water from a distance.
• Vapours or dust may form explosive mixtures with air. • Move containers from fire area if you can do it without risk.
HEALTH
death.
• May produce irritating, toxic and/or corrosive gases.
SPILL OR LEAK
• As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 Small Spill
meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. • Take up with inert, damp, non-combustible material using clean non-sparking tools and place into
• Keep unauthorized personnel away. loosely covered plastic containers for later disposal.
FIRST AID
• Structural firefighters’ protective clothing will only provide limited protection. • Remove and isolate contaminated clothing and shoes.
Large Spill minutes.
• Consider initial downwind evacuation for at least 250 meters (800 feet) in all directions. • Keep victim warm and quiet.
Page 238 Page 239

GUIDE Substances (Self-Reactive/ ERG2012 ERG2012 Substances (Self-Reactive/ GUIDE
150 Temperature Controlled) Temperature Controlled) 150
• Self-decomposition or self-ignition may be triggered by heat, chemical reaction, friction or impact. • The temperature of the substance must be maintained at or below the “Control Temperature” at all
• Self-accelerating decomposition may occur if the specific control temperature is not maintained. times.
• These materials are particularly sensitive to temperature rises. Above a given “Control Temperature” Small Fire
they decompose violently and catch fire. • Dry chemical, CO2, water spray or regular foam.
• Some may decompose explosively when heated or involved in a fire. • Flood fire area with water from a distance.
• May burn violently. Decomposition may be self-accelerating and produce large amounts of gases. • Move containers from fire area if you can do it without risk.
• Vapours or dust may form explosive mixtures with air. Fire involving Tanks or Car/Trailer Loads
HEALTH
death.
• May produce irritating, toxic and/or corrosive gases.
SPILL OR LEAK
available or no answer, refer to appropriate telephone number listed on the inside back cover. Small Spill
• As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 • Take up with inert, damp, non-combustible material using clean non-sparking tools and place into
meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. loosely covered plastic containers for later disposal.
• Stay upwind. • DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERVISION OF A SPECIALIST.
• DO NOT allow the substance to warm up. Obtain liquid nitrogen (wear thermal protective clothing, FIRST AID
see GUIDE 120), dry ice or ice for cooling. If this is not possible or none can be obtained, evacuate • Move victim to fresh air.
the area immediately. • Call 108 or emergency medical service.
PROTECTIVE CLOTHING • Administer oxygen if breathing is difficult.
• Wear positive pressure self-contained breathing apparatus (SCBA). • Remove and isolate contaminated clothing and shoes.
• Wear chemical protective clothing that is specifically recommended by the manufacturer. It may • In case of contact with substance, immediately flush skin or eyes with running water for at least 20
provide little or no thermal protection. minutes.
• Structural firefighters’ protective clothing will only provide limited protection. • Keep victim warm and quiet.
EVACUATION • Ensure that medical personnel are aware of the material(s) involved and take precautions to protect
Large Spill themselves.
• Consider initial evacuation for at least 250 meters (800 feet) in all directions.
Fire
Page 240 Page 241

GUIDE Substances - Toxic (Non-Combustible) ERG2012 ERG2012 Substances - Toxic (Non-Combustible) GUIDE
151 151
HEALTH FIRE
• Highly toxic, may be fatal if inhaled, swallowed or absorbed through skin. Small Fire
• Avoid any skin contact. • Dry chemical, CO2 or water spray.
• Effects of contact or inhalation may be delayed. Large Fire
• Fire may produce irritating, corrosive and/or toxic gases. • Water spray, fog or regular foam.
• Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution. • Move containers from fire area if you can do it without risk.
• Dike fire-control water for later disposal; do not scatter the material.
FIRE OR EXPLOSION
• Use water spray or fog; do not use straight streams.
• Non-combustible, substance itself does not burn but may decompose upon heating to produce
corrosive and/or toxic fumes.
• Runoff may pollute waterways.
• CALL EMERGENCY RESPONSE Telephone Number on Shipping Paper first. If Shipping Paper not • For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from
available or no answer, refer to appropriate telephone number listed on the inside back cover. area and let fire burn.
• As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 SPILL OR LEAK
• Keep out of low areas. • Cover with plastic sheet to prevent spreading.
PROTECTIVE CLOTHING • Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers.
• Wear positive pressure self-contained breathing apparatus (SCBA). • DO NOT GET WATER INSIDE CONTAINERS.
EVACUATION • Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial
Spill respiration with the aid of a pocket mask equipped with a one-way valve or other proper
• See Table 1 - Initial Isolation and Protective Action Distances for highlighted materials. For non- respiratory medical device.
highlighted materials, increase, in the downwind direction, as necessary, the isolation distance shown • Administer oxygen if breathing is difficult.
under “PUBLIC SAFETY”. • Remove and isolate contaminated clothing and shoes.
themselves.
Page 242 Page 243

GUIDE Substances - Toxic (Combustible) ERG2012 ERG2012 Substances - Toxic (Combustible) GUIDE
152 152
HEALTH FIRE
• Highly toxic, may be fatal if inhaled, swallowed or absorbed through skin. Small Fire
• Contact with molten substance may cause severe burns to skin and eyes. • Dry chemical, CO2 or water spray.
• Avoid any skin contact. Large Fire
• Effects of contact or inhalation may be delayed. • Water spray, fog or regular foam.
• Fire may produce irritating, corrosive and/or toxic gases. • Move containers from fire area if you can do it without risk.
• Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution. • Dike fire-control water for later disposal; do not scatter the material.
FIRE OR EXPLOSION
• Combustible material: may burn but does not ignite readily.
• Runoff may pollute waterways.
• Substance may be transported in a molten form.
PUBLIC SAFETY • For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from
• CALL EMERGENCY RESPONSE Telephone Number on Shipping Paper first. If Shipping Paper not area and let fire burn.
• As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 • ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).
• Keep out of low areas. • Cover with plastic sheet to prevent spreading.
PROTECTIVE CLOTHING • Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers.
• Wear positive pressure self-contained breathing apparatus (SCBA). • DO NOT GET WATER INSIDE CONTAINERS.
EVACUATION • Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial
Spill respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory
• See Table 1 - Initial Isolation and Protective Action Distances for highlighted materials. For non- medical device.
highlighted materials, increase, in the downwind direction, as necessary, the isolation distance shown • Administer oxygen if breathing is difficult.
under “PUBLIC SAFETY”. • Remove and isolate contaminated clothing and shoes.
themselves.
Page 244 Page 245

GUIDE Substances - Toxic and/or Corrosive ERG2012 ERG2012 Substances - Toxic and/or Corrosive GUIDE
153 (Combustible) (Combustible) 153
HEALTH FIRE
• TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Small Fire
• Effects of contact or inhalation may be delayed. • Dry chemical, CO2, alcohol-resistant foam or water spray.
FIRE OR EXPLOSION Fire involving Tanks or Car/Trailer Loads
• Combustible material: may burn but does not ignite readily. • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.
• When heated, Vapours may form explosive mixtures with air: indoors, outdoors and sewers explosion • Do not get water inside containers.
hazards. • Cool containers with flooding quantities of water until well after fire is out.
• Those substances designated with a (P) may polymerize explosively when heated or involved in a fire. • Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank.
• Contact with metals may evolve flammable hydrogen gas. • ALWAYS stay away from tanks engulfed in fire.
• Containers may explode when heated. SPILL OR LEAK
• Runoff may pollute waterways. • ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).
• Substance may be transported in a molten form. • Do not touch damaged containers or spilled material unless wearing appropriate protective clothing.
PUBLIC SAFETY • Prevent entry into waterways, sewers, basements or confined areas.
• Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers.
• CALL EMERGENCY RESPONSE Telephone Number on Shipping Paper first. If Shipping Paper not • DO NOT GET WATER INSIDE CONTAINERS.
• As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 FIRST AID
meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. • Move victim to fresh air.
• Keep unauthorized personnel away. • Call 108 or emergency medical service.
• Stay upwind. • Give artificial respiration if victim is not breathing.
• Keep out of low areas. • Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial
• Ventilate enclosed areas. respiration with the aid of a pocket mask equipped with a one-way valve or other proper
respiratory medical device.
PROTECTIVE CLOTHING • Administer oxygen if breathing is difficult.
• Wear positive pressure self-contained breathing apparatus (SCBA). • Remove and isolate contaminated clothing and shoes.
• Wear chemical protective clothing that is specifically recommended by the manufacturer. It may • In case of contact with substance, immediately flush skin or eyes with running water for at least 20
provide little or no thermal protection. minutes.
• Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not • For minor skin contact, avoid spreading material on unaffected skin.
effective in spill situations where direct contact with the substance is possible. • Keep victim warm and quiet.
EVACUATION • Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed.
Spill • Ensure that medical personnel are aware of the material(s) involved and take precautions to protect
• See Table 1 - Initial Isolation and Protective Action Distances for highlighted materials. For non- themselves.
highlighted materials, increase, in the downwind direction, as necessary, the isolation distance shown
under “PUBLIC SAFETY”.
Fire
Page 246 Page 247

154 (Non-Combustible) (Non-Combustible) 154
HEALTH FIRE
• TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Small Fire
• Effects of contact or inhalation may be delayed. • Dry chemical, CO2, alcohol-resistant foam or water spray.
FIRE OR EXPLOSION Fire involving Tanks or Car/Trailer Loads
• Non-combustible, substance itself does not burn but may decompose upon heating to produce • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.
corrosive and/or toxic fumes. • Do not get water inside containers.
• Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). • Cool containers with flooding quantities of water until well after fire is out.
• Contact with metals may evolve flammable hydrogen gas. • Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank.
• Containers may explode when heated. • ALWAYS stay away from tanks engulfed in fire.
• For UN3171, if Lithium ion batteries are involved, also consult GUIDE 147. SPILL OR LEAK
• CALL EMERGENCY RESPONSE Telephone Number on Shipping Paper first. If Shipping Paper not • Prevent entry into waterways, sewers, basements or confined areas.
available or no answer, refer to appropriate telephone number listed on the inside back cover. • Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers.
• As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 • DO NOT GET WATER INSIDE CONTAINERS.
• Keep unauthorized personnel away. FIRST AID
• Stay upwind. • Move victim to fresh air.
• Keep out of low areas. • Call 108 or emergency medical service.
• Ventilate enclosed areas. • Give artificial respiration if victim is not breathing.
PROTECTIVE CLOTHING respiration with the aid of a pocket mask equipped with a one-way valve or other proper
• Wear positive pressure self-contained breathing apparatus (SCBA). respiratory medical device.
• Wear chemical protective clothing that is specifically recommended by the manufacturer. It may • Administer oxygen if breathing is difficult.
provide little or no thermal protection. • Remove and isolate contaminated clothing and shoes.
• Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not • In case of contact with substance, immediately flush skin or eyes with running water for at least 20
effective in spill situations where direct contact with the substance is possible. minutes.
EVACUATION • For minor skin contact, avoid spreading material on unaffected skin.
Spill • Keep victim warm and quiet.
• See Table 1 - Initial Isolation and Protective Action Distances for highlighted materials. For • Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed.
nonhighlighted materials, increase, in the downwind direction, as necessary, the isolation distance • Ensure that medical personnel are aware of the material(s) involved and take precautions to protect
shown under “PUBLIC SAFETY”. themselves.
Fire
Page 248 Page 249

155 (Flammable/Water-Sensitive) (Flammable/Water-Sensitive) 155
• HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. • Note: Most foams will react with the material and release corrosive/toxic gases.
• Vapours form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. CAUTION: For Acetyl chloride (UN1717), use CO2 or dry chemical only.
• Most Vapours are heavier than air. They will spread along ground and collect in low or confined areas Small Fire
(sewers, basements, tanks). • CO2, dry chemical, dry sand, alcohol-resistant foam.
• Those substances designated with a (P) may polymerize explosively when heated or involved in a fire. • Water spray, fog or alcohol-resistant foam.
• Substance will react with water (some violently) releasing flammable, toxic or corrosive gases and • FOR CHLOROSILANES, DO NOT USE WATER; use AFFF alcohol-resistant medium expansion foam.
runoff. • Move containers from fire area if you can do it without risk.
• Contact with metals may evolve flammable hydrogen gas. • Use water spray or fog; do not use straight streams.
• Containers may explode when heated or if contaminated with water. Fire involving Tanks or Car/Trailer Loads
HEALTH • Do not get water inside containers.
• TOXIC; inhalation, ingestion or contact (skin, eyes) with Vapours, dusts or substance may cause severe • Cool containers with flooding quantities of water until well after fire is out.
injury, burns or death. • Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank.
• Bromoacetates and chloroacetates are extremely irritating/lachrymators. • ALWAYS stay away from tanks engulfed in fire.
• Reaction with water or moist air will release toxic, corrosive or flammable gases. SPILL OR LEAK
• Reaction with water may generate much heat that will increase the concentration of fumes in the air. • ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).
• Fire will produce irritating, corrosive and/or toxic gases. • All equipment used when handling the product must be grounded.
• Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution. • Do not touch damaged containers or spilled material unless wearing appropriate protective clothing.
• A Vapour suppressing foam may be used to reduce Vapours.
PUBLIC SAFETY • FOR CHLOROSILANES, use AFFF alcohol-resistant medium expansion foam to reduce Vapours.
• CALL EMERGENCY RESPONSE Telephone Number on Shipping Paper first. If Shipping Paper not • DO NOT GET WATER on spilled substance or inside containers.
• Wear positive pressure self-contained breathing apparatus (SCBA). • Move victim to fresh air. • Call 108 or emergency medical service.
provide little or no thermal protection. • Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial
• Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not respiration with the aid of a pocket mask equipped with a one-way valve or other proper
effective in spill situations where direct contact with the substance is possible. respiratory medical device.
Spill • Remove and isolate contaminated clothing and shoes.
• See Table 1 - Initial Isolation and Protective Action Distances for highlighted materials. For
minutes.
nonhighlighted materials, increase, in the downwind direction, as necessary, the isolation distance • For minor skin contact, avoid spreading material on unaffected skin.
Fire • Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed.
also, consider initial evacuation for 800 meters (1/2 mile) in all directions. themselves.
Page 250 Page 251

156 (Combustible/Water-Sensitive) (Combustible/Water-Sensitive) 156
• Combustible material: may burn but does not ignite readily. • Note: Most foams will react with the material and release corrosive/toxic gases.
• Substance will react with water (some violently) releasing flammable, toxic or corrosive gases and Small Fire
runoff. • CO2, dry chemical, dry sand, alcohol-resistant foam.
• When heated, Vapours may form explosive mixtures with air: indoors, outdoors and sewers explosion Large Fire
hazards. • Water spray, fog or alcohol-resistant foam.
• FOR CHLOROSILANES, DO NOT USE WATER; use AFFF alcohol-resistant medium expansion foam.
• Most Vapours are heavier than air. They will spread along ground and collect in low or confined areas
(sewers, basements, tanks). • Use water spray or fog; do not use straight streams.
• Vapours may travel to source of ignition and flash back. Fire involving Tanks or Car/Trailer Loads
• Contact with metals may evolve flammable hydrogen gas. • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.
• Containers may explode when heated or if contaminated with water. • Do not get water inside containers.
HEALTH • Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank.
• TOXIC; inhalation, ingestion or contact (skin, eyes) with Vapours, dusts or substance may cause severe • ALWAYS stay away from tanks engulfed in fire.
injury, burns or death.
• Contact with molten substance may cause severe burns to skin and eyes. SPILL OR LEAK
• Reaction with water or moist air will release toxic, corrosive or flammable gases.
• Reaction with water may generate much heat that will increase the concentration of fumes in the air. • Do not touch damaged containers or spilled material unless wearing appropriate protective clothing.
• Fire will produce irritating, corrosive and/or toxic gases. • Stop leak if you can do it without risk.
• Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution. • A Vapour suppressing foam may be used to reduce Vapours.
• FOR CHLOROSILANES, use AFFF alcohol-resistant medium expansion foam to reduce Vapours.
PUBLIC SAFETY • DO NOT GET WATER on spilled substance or inside containers.
• CALL EMERGENCY RESPONSE Telephone Number on Shipping Paper first. If Shipping Paper not contact spilled material.
• As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 Small Spill
meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. • Cover with DRY earth, DRY sand or other non-combustible material followed with plastic sheet to
• Keep unauthorized personnel away. minimize spreading or contact with rain.
• Stay upwind. • Use clean non-sparking tools to collect material and place it into loosely covered plastic containers for
• Keep out of low areas. later disposal.
• Ventilate enclosed areas. FIRST AID
• Move victim to fresh air. • Call 108 or emergency medical service.
PROTECTIVE CLOTHING • Give artificial respiration if victim is not breathing.
• Wear positive pressure self-contained breathing apparatus (SCBA). • Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial
• Wear chemical protective clothing that is specifically recommended by the manufacturer. It may respiration with the aid of a pocket mask equipped with a one-way valve or other proper
provide little or no thermal protection. respiratory medical device.
• Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not • Administer oxygen if breathing is difficult.
effective in spill situations where direct contact with the substance is possible. • Remove and isolate contaminated clothing and shoes.
Spill minutes.
• See Table 1 - Initial Isolation and Protective Action Distances for highlighted materials. For • For minor skin contact, avoid spreading material on unaffected skin.
nonhighlighted materials, increase, in the downwind direction, as necessary, the isolation distance • Keep victim warm and quiet.
shown under “PUBLIC SAFETY”. • Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed.
Page 252 Page 253

157 (Non-Combustible/Water-Sensitive) (Non-Combustible/Water-Sensitive) 157
HEALTH FIRE
• TOXIC; inhalation, ingestion or contact (skin, eyes) with Vapours, dusts or substance may cause severe • Note: Some foams will react with the material and release corrosive/toxic gases.
injury, burns or death. Small Fire
• Reaction with water or moist air may release toxic, corrosive or flammable gases. • CO2 (except for Cyanides), dry chemical, dry sand, alcohol-resistant foam.
• Reaction with water may generate much heat that will increase the concentration of fumes in the air. Large Fire
• Fire will produce irritating, corrosive and/or toxic gases. • Water spray, fog or alcohol-resistant foam.
• Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.
FIRE OR EXPLOSION • Dike fire-control water for later disposal; do not scatter the material.
• Non-combustible, substance itself does not burn but may decompose upon heating to produce Fire involving Tanks or Car/Trailer Loads
corrosive and/or toxic fumes. • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.
• For UN1796, UN1826, UN2031 at high concentrations and for UN2032, these may act as oxidizers,
also consult GUIDE 140. • Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank.
• Vapours may accumulate in confined areas (basement, tanks, hopper/tank cars etc.). • ALWAYS stay away from tanks engulfed in fire.
• Substance may react with water (some violently), releasing corrosive and/or toxic gases and runoff. SPILL OR LEAK
• Contact with metals may evolve flammable hydrogen gas. • ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).
• Containers may explode when heated or if contaminated with water. • All equipment used when handling the product must be grounded.
PUBLIC SAFETY • A Vapour suppressing foam may be used to reduce Vapours.
• CALL EMERGENCY RESPONSE Telephone Number on Shipping Paper first. If Shipping Paper not • DO NOT GET WATER INSIDE CONTAINERS.
• As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 contact spilled material.
meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. • Prevent entry into waterways, sewers, basements or confined areas.
Small Spill
• Wear positive pressure self-contained breathing apparatus (SCBA). • Move victim to fresh air. • Call 108 or emergency medical service.
provide little or no thermal protection. respiration with the aid of a pocket mask equipped with a one-way valve or other proper
• Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not respiratory medical device.
Spill minutes.
• See Table 1 - Initial Isolation and Protective Action Distances for highlighted materials. For • In case of contact with Hydrofluoric acid (UN1790), flush skin and eyes with water for 5 minutes;
nonhighlighted materials, increase, in the downwind direction, as necessary, the isolation distance then, for skin exposures rub on a calcium/gel combination; for eyes flush with a water/calcium
shown under “PUBLIC SAFETY”. solution if available, otherwise continue with water for 15 minutes.
Fire • For minor skin contact, avoid spreading material on unaffected skin.
• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; • Keep victim warm and quiet.
also, consider initial evacuation for 800 meters (1/2 mile) in all directions. • Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed.
themselves.
Page 254 Page 255

GUIDE Infectious Substances ERG2012 ERG2012 Infectious Substances GUIDE
158 158
HEALTH FIRE
• Inhalation or contact with substance may cause infection, disease or death. Small Fire
• Runoff from fire control may cause pollution. • Dry chemical, soda ash, lime or sand.
• Note: Damaged packages containing solid CO2 as a refrigerant may produce water or frost from Large Fire
condensation of air. Do not touch this liquid as it could be contaminated by the contents of the parcel. • Use extinguishing agent suitable for type of surrounding fire.
• Do not scatter spilled material with high pressure water streams.
FIRE OR EXPLOSION
• Some of these materials may burn, but none ignite readily.
• Some may be transported in flammable liquids. SPILL OR LEAK
PUBLIC SAFETY • Absorb with earth, sand or other non-combustible material.
• CALL EMERGENCY RESPONSE Telephone Number on Shipping Paper first. If Shipping Paper not • Cover damaged package or spilled material with damp towel or rag and keep wet with liquid bleach or
available or no answer, refer to appropriate telephone number listed on the inside back cover. other disinfectant.
• As an immediate precautionary measure, isolate spill or leak area for at least 25 meters (75 feet) in all • DO NOT CLEAN-UP OR DISPOSE OF, EXCEPT UNDER SUPERVISION OF A SPECIALIST.
directions.
• Keep unauthorized personnel away. FIRST AID
• Stay upwind. • Move victim to a safe isolated area.
• Obtain identity of substance involved. CAUTION: Victim may be a source of contamination.
PROTECTIVE CLOTHING • Remove and isolate contaminated clothing and shoes.
• Wear positive pressure self-contained breathing apparatus (SCBA). • In case of contact with substance, immediately flush skin or eyes with running water for at least 20
• Structural firefighters’ protective clothing will only provide limited protection minutes.
• For further assistance, contact your local Poison Control Center.
themselves.
Page 256 Page 257

GUIDE Substances (Irritating) ERG2012 ERG2012 Substances (Irritating) GUIDE
159 159
HEALTH FIRE
• Inhalation of Vapours or dust is extremely irritating. Small Fire
• May cause burning of eyes and flow of tears. • Dry chemical, CO2, water spray or regular foam.
• May cause coughing, difficult breathing and nausea. Large Fire
• Brief exposure effects last only a few minutes. • Water spray, fog or regular foam.
• Exposure in an enclosed area may be very harmful. • Move containers from fire area if you can do it without risk.
• Fire will produce irritating, corrosive and/or toxic gases. • Dike fire-control water for later disposal; do not scatter the material.
• Runoff from fire control or dilution water may cause pollution. Fire involving Tanks or Car/Trailer Loads
FIRE OR EXPLOSION
PUBLIC SAFETY • For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from
• CALL EMERGENCY RESPONSE Telephone Number on Shipping Paper first. If Shipping Paper not area and let fire burn.
• As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 • Do not touch or walk through spilled material.
meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. • Stop leak if you can do it without risk.
• Keep unauthorized personnel away. • Fully encapsulating, Vapour protective clothing should be worn for spills and leaks with no fire.
• Stay upwind. Small Spill
• Keep out of low areas. • Take up with sand or other non-combustible absorbent material and place into containers for later
• Ventilate closed spaces before entering. disposal.
PROTECTIVE CLOTHING Large Spill
• Wear positive pressure self-contained breathing apparatus (SCBA). • Dike far ahead of liquid spill for later disposal.
• Wear chemical protective clothing that is specifically recommended by the manufacturer. It may • Prevent entry into waterways, sewers, basements or confined areas.
provide little or no thermal protection. FIRST AID
• Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not • Move victim to fresh air.
effective in spill situations where direct contact with the substance is possible. • Call 108 or emergency medical service.
Spill • Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial
• See Table 1 - Initial Isolation and Protective Action Distances for highlighted materials. For respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory
nonhighlighted materials, increase, in the downwind direction, as necessary, the isolation distance medical device.
shown under “PUBLIC SAFETY”. • Administer oxygen if breathing is difficult.
• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; • In case of contact with substance, immediately flush skin or eyes with running water for at least 20
also, consider initial evacuation for 800 meters (1/2 mile) in all directions. minutes.
• For minor skin contact, avoid spreading material on unaffected skin.
• Effects should disappear after individual has been exposed to fresh air for approximately 10 minutes.
themselves.
Page 258 Page 259

GUIDE Halogenated Solvents ERG2012 ERG2012 Halogenated Solvents GUIDE
160 160
HEALTH FIRE
• Toxic by ingestion. Small Fire
• Vapours may cause dizziness or suffocation. • Dry chemical, CO2 or water spray.
• Exposure in an enclosed area may be very harmful. Large Fire
• Contact may irritate or burn skin and eyes. • Dry chemical, CO2, alcohol-resistant foam or water spray.
• Fire may produce irritating and/or toxic gases. • Move containers from fire area if you can do it without risk.
• Runoff from fire control or dilution water may cause pollution. • Dike fire-control water for later disposal; do not scatter the material.
FIRE OR EXPLOSION
• Most Vapours are heavier than air.
• Air/Vapour mixtures may explode when ignited.
• Container may explode in heat of fire.
SPILL OR LEAK
• CALL EMERGENCY RESPONSE Telephone Number on Shipping Paper first. If Shipping Paper not Small Liquid Spill
available or no answer, refer to appropriate telephone number listed on the inside back cover. • Take up with sand, earth or other non-combustible absorbent material.
• As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet) in Large Spill
all directions. • Dike far ahead of liquid spill for later disposal.
• Stay upwind.
• Many gases are heavier than air and will spread along ground and collect in low or confined areas FIRST AID
(sewers, basements, tanks). • Move victim to fresh air.
• Keep out of low areas. • Call 108 or emergency medical service.
• Ventilate closed spaces before entering. • Give artificial respiration if victim is not breathing.
PROTECTIVE CLOTHING • Remove and isolate contaminated clothing and shoes.
• Wear positive pressure self-contained breathing apparatus (SCBA). • In case of contact with substance, immediately flush skin or eyes with running water for at least 20
• Wear chemical protective clothing that is specifically recommended by the manufacturer. minutes.
• Structural firefighters’ protective clothing will only provide limited protection. • For minor skin contact, avoid spreading material on unaffected skin.
EVACUATION • Wash skin with soap and water.
Large Spill • Keep victim warm and quiet.
• Consider initial downwind evacuation for at least 100 meters (330 feet). • Ensure that medical personnel are aware of the material(s) involved and take precautions to protect
Fire themselves.
Page 260 Page 261

GUIDE Radioactive Materials ERG2012 ERG2012 Radioactive Materials GUIDE
161 (Low Level Radiation) (Low Level Radiation) 161
HEALTH FIRE
• Radiation presents minimal risk to transport workers, emergency response personnel and the public • Presence of radioactive material will not influence the fire control processes and should not influence
during transportation accidents. Packaging durability increases as potential hazard of radioactive selection of techniques.
content increases. • Move containers from fire area if you can do it without risk.
• Very low levels of contained radioactive materials and low radiation levels outside packages result in • Do not move damaged packages; move undamaged packages out of fire zone.
low risks to people. Damaged packages may release measurable amounts of radioactive material, but Small Fire
the resulting risks are expected to be low. • Dry chemical, CO2, water spray or regular foam.
• Some radioactive materials cannot be detected by commonly available instruments. Large Fire
• Packages do not have RADIOACTIVE I, II, or III labels. Some may have EMPTY labels or may have the • Water spray, fog (flooding amounts).
word “Radioactive” in the package marking.
SPILL OR LEAK
FIRE OR EXPLOSION • Do not touch damaged packages or spilled material.
• Some of these materials may burn, but most do not ignite readily. • Cover liquid spill with sand, earth or other non-combustible absorbent material.
• Many have cardboard outer packaging; content (physically large or small) can be of many different • Cover powder spill with plastic sheet or tarp to minimize spreading.
physical forms.
FIRST AID
• Radioactivity does not change flammability or other properties of materials.
• Medical problems take priority over radiological concerns.
PUBLIC SAFETY • Use first aid treatment according to the nature of the injury.
• CALL EMERGENCY RESPONSE Telephone Number on Shipping Paper first. If Shipping Paper not • Do not delay care and transport of a seriously injured person.
available or no answer, refer to appropriate telephone number listed on the inside back cover. • Give artificial respiration if victim is not breathing.
• Priorities for rescue, life-saving, first aid, fire control and other hazards are higher than the priority • Administer oxygen if breathing is difficult.
for measuring radiation levels. • In case of contact with substance, immediately flush skin or eyes with running water for at least 20
• Radiation Authority must be notified of accident conditions. Radiation Authority is usually responsible minutes.
for decisions about radiological consequences and closure of emergencies. • Injured persons contaminated by contact with released material are not a serious hazard to health
• As an immediate precautionary measure, isolate spill or leak area for at least 25 meters (75 feet) in all care personnel, equipment or facilities.
directions. • Ensure that medical personnel are aware of the material(s) involved, take precautions to protect
• Stay upwind. themselves and prevent spread of contamination.
• Detain or isolate uninjured persons or equipment suspected to be contaminated; delay
decontamination and cleanup until instructions are received from Radiation Authority.
PROTECTIVE CLOTHING
• Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters’ protective
clothing will provide adequate protection.
EVACUATION
Large Spill
Fire
• When a large quantity of this material is involved in a major fire, consider an initial evacuation
distance of 300 meters (1000 feet) in all directions.
Page 262 Page 263

162 (Low to Moderate Level Radiation) (Low to Moderate Level Radiation) 162
HEALTH FIRE
content increases. • Move containers from fire area if you can do it without risk.
• Undamaged packages are safe. Contents of damaged packages may cause higher external radiation • Do not move damaged packages; move undamaged packages out of fire zone.
exposure, or both external and internal radiation exposure if contents are released.
• Low radiation hazard when material is inside container. If material is released from package or bulk Small Fire
container, hazard will vary from low to moderate. Level of hazard will depend on the type and amount • Dry chemical, CO2, water spray or regular foam.
of radioactivity, the kind of material it is in, and/or the surfaces it is on. Large Fire
• Some material may be released from packages during accidents of moderate severity but risks to • Water spray, fog (flooding amounts).
people are not great. • Dike fire-control water for later disposal.
• Released radioactive materials or contaminated objects usually will be visible if packaging fails.
• Some exclusive use shipments of bulk and packaged materials will not have “RADIOACTIVE” labels. SPILL OR LEAK
Placards, markings and shipping papers provide identification. • Do not touch damaged packages or spilled material.
• Some packages may have a “RADIOACTIVE” label and a second hazard label. The second hazard is • Cover liquid spill with sand, earth or other non-combustible absorbent material.
usually greater than the radiation hazard; so follow this GUIDE as well as the response GUIDE for the • Dike to collect large liquid spills.
second hazard class label. • Cover powder spill with plastic sheet or tarp to minimize spreading.
• Some radioactive materials cannot be detected by commonly available instruments.
• Runoff from control of cargo fire may cause low-level pollution. FIRST AID
FIRE OR EXPLOSION • Medical problems take priority over radiological concerns.
• Some of these materials may burn, but most do not ignite readily.
• Uranium and Thorium metal cuttings may ignite spontaneously if exposed to air (see GUIDE 136). • Use first aid treatment according to the nature of the injury.
• Nitrates are oxidizers and may ignite other combustibles (see GUIDE 141). • Do not delay care and transport of a seriously injured person.
PUBLIC SAFETY • In case of contact with substance, wipe from skin immediately; flush skin or eyes with running water
• CALL EMERGENCY RESPONSE Telephone Number on Shipping Paper first. If Shipping Paper not for at least 20 minutes.
available or no answer, refer to appropriate telephone number listed on the inside back cover. • Injured persons contaminated by contact with released material are not a serious hazard to health
• Priorities for rescue, life-saving, first aid, fire control and other hazards are higher than the priority
care personnel, equipment or facilities.
for measuring radiation levels.
• Radiation Authority must be notified of accident conditions. Radiation Authority is usually responsible • Ensure that medical personnel are aware of the material(s) involved, take precautions to protect
for decisions about radiological consequences and closure of emergencies. themselves and prevent spread of contamination.
• As an immediate precautionary measure, isolate spill or leak area for at least 25 meters (75 feet) in all
directions.
• Stay upwind.
PROTECTIVE CLOTHING
clothing will provide adequate protection.
EVACUATION
Large Spill
Fire
Page 264 Page 265

163 (Low to High Level Radiation) (Low to High Level Radiation) 163
HEALTH FIRE
content increases.
• Undamaged packages are safe. Contents of damaged packages may cause higher external radiation • Move containers from fire area if you can do it without risk.
exposure, or both external and internal radiation exposure if contents are released. • Do not move damaged packages; move undamaged packages out of fire zone.
• Type A packages (cartons, boxes, drums, articles, etc.) identified as “Type A” by marking on packages Small Fire
or by shipping papers contain non-life endangering amounts. Partial releases might be expected if • Dry chemical, CO2, water spray or regular foam.
“Type A” packages are damaged in moderately severe accidents.
Large Fire
• Type B packages, and the rarely occurring Type C packages, (large and small, usually metal) contain
the most hazardous amounts. They can be identified by package markings or by shipping papers. Life • Water spray, fog (flooding amounts).
threatening conditions may exist only if contents are released or package shielding fails. Because of • Dike fire-control water for later disposal.
design, evaluation and testing of packages, these conditions would be expected only for accidents of
utmost severity. SPILL OR LEAK
• The rarely occurring "Special Arrangement" shipments may be of Type A, Type B or Type C packages. • Do not touch damaged packages or spilled material.
Package type will be marked on packages, and shipment details will be on shipping papers. • Damp surfaces on undamaged or slightly damaged packages are seldom an indication of packaging
• Radioactive White-I labels indicate radiation levels outside single, isolated, undamaged packages are failure. Most packaging for liquid content have inner containers and/or inner absorbent materials.
very low (less than 0.005 mSv/h (0.5 mrem/h)).
• Radioactive Yellow-II and Yellow-III labeled packages have higher radiation levels. The transport index • Cover liquid spill with sand, earth or other non-combustible absorbent material.
(TI) on the label identifies the maximum radiation level in mrem/h one meter from a single, isolated, FIRST AID
undamaged package.
• Some radioactive materials cannot be detected by commonly available instruments. • Call 108 or emergency medical service.
• Water from cargo fire control may cause pollution. • Medical problems take priority over radiological concerns.
• Use first aid treatment according to the nature of the injury.
FIRE OR EXPLOSION
• Do not delay care and transport of a seriously injured person.
• Some of these materials may burn, but most do not ignite readily.
• Radioactivity does not change flammability or other properties of materials. • Give artificial respiration if victim is not breathing.
• Type B packages are designed and evaluated to withstand total engulfment in flames at temperatures • Administer oxygen if breathing is difficult.
of 800°C (1475°F) for a period of 30 minutes. • In case of contact with substance, immediately flush skin or eyes with running water for at least 20
minutes.
PUBLIC SAFETY • Injured persons contaminated by contact with released material are not a serious hazard to health
care personnel, equipment or facilities.
• CALL EMERGENCY RESPONSE Telephone Number on Shipping Paper first. If Shipping Paper not • Ensure that medical personnel are aware of the material(s) involved, take precautions to protect
• Priorities for rescue, life-saving, first aid, fire control and other hazards are higher than the priority for themselves and prevent spread of contamination.
measuring radiation levels.
• Radiation Authority must be notified of accident conditions. Radiation Authority is usually responsible
for decisions about radiological consequences and closure of emergencies.
directions. • Stay upwind. • Keep unauthorized personnel away.
PROTECTIVE CLOTHING
clothing will provide adequate protection against internal radiation exposure, but not external
radiation exposure.
EVACUATION
Large Spill
Fire
Page 266 Page 267

GUIDE Radioactive Materials (Special Form/Low to ERG2012 ERG2012 Radioactive Materials (Special Form/Low to GUIDE
164 High Level External Radiation) High Level External Radiation) 164
HEALTH FIRE
• Undamaged packages are safe; contents of damaged packages may cause external radiation exposure, • Presence of radioactive material will not influence the fire control processes and should not influence
and much higher external exposure if contents (source capsules) are released. selection of techniques.
• Contamination and internal radiation hazards are not expected, but not impossible.
• Type A packages (cartons, boxes, drums, articles, etc.) identified as “Type A” by marking on packages
or by shipping papers contain non-life endangering amounts. Radioactive sources may be released if • Do not move damaged packages; move undamaged packages out of fire zone.
“Type A” packages are damaged in moderately severe accidents. Small Fire
• Type B packages, and the rarely occurring Type C packages, (large and small, usually metal) contain • Dry chemical, CO2, water spray or regular foam.
the most hazardous amounts. They can be identified by package markings or by shipping papers. Life Large Fire
threatening conditions may exist only if contents are released or package shielding fails. Because of
design, evaluation and testing of packages, these conditions would be expected only for accidents of • Water spray, fog (flooding amounts).
utmost severity.
• Radioactive White-I labels indicate radiation levels outside single, isolated, undamaged packages are SPILL OR LEAK
very low (less than 0.005 mSv/h (0.5 mrem/h)). • Do not touch damaged packages or spilled material.
• Radioactive Yellow-II and Yellow-III labeled packages have higher radiation levels. The transport index • Damp surfaces on undamaged or slightly damaged packages are seldom an indication of packaging
(TI) on the label identifies the maximum radiation level in mrem/h one meter from a single, isolated, failure. Contents are seldom liquid. Content is usually a metal capsule, easily seen if released from
undamaged package. package.
• Radiation from the package contents, usually in durable metal capsules, can be detected by most
radiation instruments. • If source capsule is identified as being out of package, DO NOT TOUCH. Stay away and await advice
• Water from cargo fire control is not expected to cause pollution. from Radiation Authority.
FIRE OR EXPLOSION FIRST AID

• Packagings can burn completely without risk of content loss from sealed source capsule. • Call 108 or emergency medical service.
• Radioactivity does not change flammability or other properties of materials. • Medical problems take priority over radiological concerns.
• Radioactive source capsules and Type B packages are designed and evaluated to withstand total • Use first aid treatment according to the nature of the injury.
engulfment in flames at temperatures of 800°C (1475°F) for a period of 30 minutes. • Do not delay care and transport of a seriously injured person.
• Persons exposed to special form sources are not likely to be contaminated with radioactive material.
PUBLIC SAFETY • Give artificial respiration if victim is not breathing.
• CALL EMERGENCY RESPONSE Telephone Number on Shipping Paper first. If Shipping Paper not • Administer oxygen if breathing is difficult.
available or no answer, refer to appropriate telephone number listed on the inside back cover. • Injured persons contaminated by contact with released material are not a serious hazard to health
• Priorities for rescue, life-saving, first aid, fire control and other hazards are higher than the priority for care personnel, equipment or facilities.
measuring radiation levels. • Ensure that medical personnel are aware of the material(s) involved, take precautions to protect
for decisions about radiological consequences and closure of emergencies. themselves and prevent spread of contamination.
directions.
• Stay upwind. • Keep unauthorized personnel away.
• Delay final cleanup until instructions or advice is received from Radiation Authority.
PROTECTIVE CLOTHING
radiation exposure.
EVACUATION
Large Spill
Fire
Page 268 Page 269

165 (Fissile/Low to High Level Radiation) (Fissile/Low to High Level Radiation) 165
HEALTH FIRE
during transportation accidents. Packaging durability increases as potential radiation and criticality selection of techniques.
hazards of the content increase. • Move containers from fire area if you can do it without risk.
• Undamaged packages are safe. Contents of damaged packages may cause higher external radiation • Do not move damaged packages; move undamaged packages out of fire zone.
exposure, or both external and internal radiation exposure if contents are released. Small Fire
• Type AF or IF packages, identified by package markings, do not contain life-threatening amounts of
material. External radiation levels are low and packages are designed, evaluated and tested to control • Dry chemical, CO2, water spray or regular foam.
releases and to prevent a fission chain reaction under severe transport conditions. Large Fire
• Type B(U)F, B(M)F and CF packages (identified by markings on packages or shipping papers) contain • Water spray, fog (flooding amounts).
potentially life endangering amounts. Because of design, evaluation and testing of packages, fission
chain reactions are prevented and releases are not expected to be life endangering for all accidents SPILL OR LEAK
except those of utmost severity. • Do not touch damaged packages or spilled material.
• The rarely occurring "Special Arrangement" shipments may be of Type AF, BF or CF packages. Package • Damp surfaces on undamaged or slightly damaged packages are seldom an indication of packaging
type will be marked on packages, and shipment details will be on shipping papers.
• The transport index (TI) shown on labels or a shipping paper might not indicate the radiation level at failure. Most packaging for liquid content have inner containers and/or inner absorbent materials.
one meter from a single, isolated, undamaged package; instead, it might relate to controls needed Liquid Spill
during transport because of the fissile properties of the materials. Alternatively, the fissile nature of • Package contents are seldom liquid. If any radioactive contamination resulting from a liquid release is
the contents may be indicated by a criticality safety index (CSI) on a special FISSILE label or on the present, it probably will be low-level.
shipping paper.
• Some radioactive materials cannot be detected by commonly available instruments. FIRST AID
• Water from cargo fire control is not expected to cause pollution. • Call 108 or emergency medical service.
FIRE OR EXPLOSION • Medical problems take priority over radiological concerns.
• These materials are seldom flammable. Packages are designed to withstand fires without damage to • Use first aid treatment according to the nature of the injury.
contents. • Do not delay care and transport of a seriously injured person.
• Radioactivity does not change flammability or other properties of materials. • Give artificial respiration if victim is not breathing.
• Type AF, IF, B(U)F, B(M)F and CF packages are designed and evaluated to withstand total engulfment in
flames at temperatures of 800°C (1475°F) for a period of 30 minutes. • Administer oxygen if breathing is difficult.
minutes.
PUBLIC SAFETY • Injured persons contaminated by contact with released material are not a serious hazard to health
• CALL EMERGENCY RESPONSE Telephone Number on Shipping Paper first. If Shipping Paper not care personnel, equipment or facilities.
available or no answer, refer to appropriate telephone number listed on the inside back cover • Ensure that medical personnel are aware of the material(s) involved, take precautions to protect
• Priorities for rescue, life-saving, first aid, fire control and other hazards are higher than the priority themselves and prevent spread of contamination.
for measuring radiation levels.
for decisions about radiological consequences and closure of emergencies.
directions. • Stay upwind. • Keep unauthorized personnel away.
PROTECTIVE CLOTHING
radiation exposure.
EVACUATION
Large Spill
Fire
• When a large quantity of this material is involved in a major fire, consider an initial evacuation distance
of 300 meters (1000 feet) in all directions.
Page 270 Page 271

GUIDE Radioactive Materials - Corrosive ERG2012 ERG2012 Radioactive Materials - Corrosive GUIDE
166 (Uranium Hexaflu oride/Water-Sensitive) (Uranium Hexaflu oride/Water-Sensitive) 166
HEALTH FIRE
• Radiation presents minimal risk to transport workers, emergency response personnel and the public • DO NOT USE WATER OR FOAM ON MATERIAL ITSELF.
during transportation accidents. Packaging durability increases as potential radiation and criticality • Move containers from fire area if you can do it without risk.
hazards of the content increase. Small Fire
• Chemical hazard greatly exceeds radiation hazard. • Dry chemical or CO2.
• Substance reacts with water and water Vapour in air to form toxic and corrosive hydrogen fluoride gas Large Fire
and an extremely irritating and corrosive, white-colored, water-soluble residue.
• If inhaled, may be fatal. • Water spray, fog or regular foam.
• Direct contact causes burns to skin, eyes, and respiratory tract. • Cool containers with flooding quantities of water until well after fire is out.
• Low-level radioactive material; very low radiation hazard to people. • If this is impossible, withdraw from area and let fire burn.
• Runoff from control of cargo fire may cause low-level pollution. • ALWAYS stay away from tanks engulfed in fire.
FIRE OR EXPLOSION
• Substance does not burn. SPILL OR LEAK
• The material may react violently with fuels. • Do not touch damaged packages or spilled material.
• Containers in protective overpacks (horizontal cylindrical shape with short legs for tie-downs), are • Without fire or smoke, leak will be evident by visible and irritating Vapours and residue forming at the
identified with "AF", "B(U)F" or "H(U)" on shipping papers or by markings on the overpacks. They are point of release.
designed and evaluated to withstand severe conditions including total engulfment in flames at • Use fine water spray to reduce Vapours; do not put water directly on point of material release from
temperatures of 800°C (1475°F) for a period of 30 minutes.
• Bare filled cylinders, identified with UN2978 as part of the marking (may also be marked H(U) or container.
H(M)), may rupture in heat of engulfing fire; bare empty (except for residue) cylinders will not rupture • Residue buildup may self-seal small leaks.
in fires. • Dike far ahead of spill to collect runoff water.
• Radioactivity does not change flammability or other properties of materials.
FIRST AID
PUBLIC SAFETY • Call 108 or emergency medical service.
• Medical problems take priority over radiological concerns.
• CALL EMERGENCY RESPONSE Telephone Number on Shipping Paper first. If Shipping Paper not • Use first aid treatment according to the nature of the injury.
• Priorities for rescue, life-saving, first aid, fire control and other hazards are higher than the priority • Do not delay care and transport of a seriously injured person.
for measuring radiation levels. • Give artificial respiration if victim is not breathing.
• Radiation Authority must be notified of accident conditions. Radiation Authority is usually responsible • Administer oxygen if breathing is difficult.
for decisions about radiological consequences and closure of emergencies. • In case of contact with substance, immediately flush skin or eyes with running water for at least 20
• As an immediate precautionary measure, isolate spill or leak area for at least 25 meters (75 feet) in all minutes.
directions.
• Stay upwind. • Effects of exposure (inhalation, ingestion or skin contact) to substance may be delayed.
• Keep unauthorized personnel away. • Injured persons contaminated by contact with released material are not a serious hazard to health
• Detain or isolate uninjured persons or equipment suspected to be contaminated; delay care personnel, equipment or facilities.
decontamination and cleanup until instructions are received from Radiation Authority. • Ensure that medical personnel are aware of the material(s) involved, take precautions to protect
PROTECTIVE CLOTHING themselves and prevent spread of contamination.
• Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not
effective in spill situations where direct contact with the substance is possible.
EVACUATION
Spill
• See Table 1 - Initial Isolation and Protective Action Distances.
Fire
distance of 300 meters (1000 feet) in all directions. also, consider initial evacuation for 800 meters
(1/2 mile) in all directions.
Page 272 Page 273

GUIDE Fluorine (Refrigerated Liquid) ERG2012 ERG2012 Fluorine (Refrigerated Liquid) GUIDE
167 167
HEALTH FIRE
• TOXIC; may be fatal if inhaled. Small Fire
• Vapours are extremely irritating. • Dry chemical, soda ash, lime or sand.
• Contact with gas or liquefied gas will cause burns, severe injury and/or frostbite. Large Fire
• Vapours from liquefied gas are initially heavier than air and spread along ground. • Water spray, fog (flooding amounts).
• Runoff from fire control may cause pollution. • Do not get water inside containers.
FIRE OR EXPLOSION
• Substance does not burn but will support combustion.
• This is a strong oxidizer and will react vigorously or explosively with many materials including fuels.
• Vapour explosion and poison hazard indoors, outdoors or in sewers.
available or no answer, refer to appropriate telephone number listed on the inside back cover. • If you have not donned special protective clothing approved for this material, do not expose yourself
• As an immediate precautionary measure, isolate spill or leak area for at least 100 meters (330 feet) in to any risk of this material touching you.
all directions. • Do not direct water at spill or source of leak.
• Keep unauthorized personnel away. • A fine water spray remotely directed to the edge of the spill pool can be used to direct and maintain a
• Stay upwind. hot flare fire that will burn the spilled material in a controlled manner.
• Many gases are heavier than air and will spread along ground and collect in low or confined areas • Keep combustibles (wood, paper, oil, etc.) away from spilled material.
(sewers, basements, tanks). • Stop leak if you can do it without risk.
• Keep out of low areas. • Use water spray to reduce Vapours or divert Vapour cloud drift. Avoid allowing water runoff to
• Ventilate closed spaces before entering. contact spilled material.
PROTECTIVE CLOTHING • If possible, turn leaking containers so that gas escapes rather than liquid.
• Wear positive pressure self-contained breathing apparatus (SCBA). • Prevent entry into waterways, sewers, basements or confined areas.
• Wear chemical protective clothing that is specifically recommended by the manufacturer. It may • Isolate area until gas has dispersed.
provide little or no thermal protection. • Ventilate the area.
• Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not FIRST AID
effective in spill situations where direct contact with the substance is possible. • Move victim to fresh air.
• Always wear thermal protective clothing when handling refrigerated/cryogenic liquids. • Call 108 or emergency medical service.
• See Table 1 - Initial Isolation and Protective Action Distances. • Clothing frozen to the skin should be thawed before being removed.
• If tank, rail car or tank truck is involved in a fire, ISOLATE for 1600 meters (1 mile) in all directions; • In case of contact with substance, immediately flush skin or eyes with running water for at least 20
also, consider initial evacuation for 1600 meters (1 mile) in all directions. minutes.
themselves.
Page 274 Page 275

GUIDE Carbon Monoxide (Refrigerated Liquid) ERG2012 ERG2012 Carbon Monoxide (Refrigerated Liquid) GUIDE
168 168
HEALTH FIRE
• TOXIC; Extremely Hazardous. • DO NOT EXTINGUISH A LEAKING GAS FIRE UNLESS LEAK CAN BE STOPPED.
• Inhalation extremely dangerous; may be fatal. Small Fire
• Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite. • Dry chemical, CO2 or water spray.
• Odorless, will not be detected by sense of smell. Large Fire
FIRE OR EXPLOSION
• EXTREMELY FLAMMABLE.
• May be ignited by heat, sparks or flames.
• Flame may be invisible.
• Vapour explosion and poison hazard indoors, outdoors or in sewers.
• Vapours may travel to source of ignition and flash back.
• Runoff may create fire or explosion hazard. SPILL OR LEAK
• Stay upwind. • If possible, turn leaking containers so that gas escapes rather than liquid.
• Many gases are heavier than air and will spread along ground and collect in low or confined areas • Prevent entry into waterways, sewers, basements or confined areas.
• Wear chemical protective clothing that is specifically recommended by the manufacturer. It may • Administer oxygen if breathing is difficult.
provide little or no thermal protection. • Remove and isolate contaminated clothing and shoes.
• Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not • In case of contact with substance, immediately flush skin or eyes with running water for at least 20
effective in spill situations where direct contact with the substance is possible. minutes.
• Always wear thermal protective clothing when handling refrigerated/cryogenic liquids. • In case of contact with liquefied gas, thaw frosted parts with lukewarm water.
EVACUATION • Keep victim warm and quiet.
Spill • Keep victim under observation.
• See Table 1 - Initial Isolation and Protective Action Distances. • Effects of contact or inhalation may be delayed.
Page 276 Page 277

GUIDE Aluminum (Molten) ERG2012 ERG2012 Aluminum (Molten) GUIDE
169 169
• Substance is transported in molten form at a temperature above 705°C (1300°F). • Do Not Use Water, except in life threatening situations and then only in a fine spray.
• Violent reaction with water; contact may cause an explosion or may produce a flammable gas. • Do not use halogenated extinguishing agents or foam.
• Will ignite combustible materials (wood, paper, oil, debris, etc.). • Move combustibles out of path of advancing pool if you can do so without risk.
• Contact with nitrates or other oxidizers may cause an explosion. • Extinguish fires started by molten material by using appropriate method for the burning material;
• Contact with containers or other materials, including cold, wet or dirty tools, may cause an explosion. keep water, halogenated extinguishing agents and foam away from the molten material.
• Contact with concrete will cause spalling and small pops.
SPILL OR LEAK
HEALTH • Do not touch or walk through spilled material.
• Contact causes severe burns to skin and eyes. • Do not attempt to stop leak, due to danger of explosion.
• Fire may produce irritating and/or toxic gases. • Keep combustibles (wood, paper, oil, etc.) away from spilled material.
• Substance is very fluid, spreads quickly, and may splash. Do not try to stop it with shovels or other
objects.
PUBLIC SAFETY • Dike far ahead of spill; use dry sand to contain the flow of material.
• CALL EMERGENCY RESPONSE Telephone Number on Shipping Paper first. If Shipping Paper not • Where possible allow molten material to solidify naturally.
available or no answer, refer to appropriate telephone number listed on the inside back cover. • Avoid contact even after material solidifies. Molten, heated and cold aluminum look alike; do not
• As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet) in touch unless you know it is cold.
all directions. • Clean up under the supervision of an expert after material has solidified.
• Wear flame retardant structural firefighters’ protective clothing, including faceshield, helmet and • Administer oxygen if breathing is difficult.
gloves, this will provide limited thermal protection. • For severe burns, immediate medical attention is required.
• Removal of solidified molten material from skin requires medical assistance.
minutes.
Page 278 Page 279

GUIDE Metals (Powders, Dusts, Shavings, Borings, ERG2012 ERG2012 Metals (Powders, Dusts, Shavings, Borings, GUIDE
170 Turnings, or Cuttings, etc.) Turnings, or Cuttings, etc.) 170
• May react violently or explosively on contact with water. • DO NOT USE WATER, FOAM OR CO2.
• Some are transported in flammable liquids. • Dousing metallic fires with water will generate hydrogen gas, an extremely dangerous explosion
• May be ignited by friction, heat, sparks or flames. hazard, particularly if fire is in a confined environment (i.e., building, cargo hold, etc.).
• Some of these materials will burn with intense heat. • Use DRY sand, graphite powder, dry sodium chloride based extinguishers, G-1® or Met-L-X® powder.
• Dusts or fumes may form explosive mixtures in air. • Confining and smothering metal fires is preferable rather than applying water.
• May re-ignite after fire is extinguished. Fire involving Tanks or Car/Trailer Loads
• If impossible to extinguish, protect surroundings and allow fire to burn itself out.
HEALTH
• Oxides from metallic fires are a severe health hazard. SPILL OR LEAK
• Inhalation or contact with substance or decomposition products may cause severe injury or death. • ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).
• Fire may produce irritating, corrosive and/or toxic gases. • Do not touch or walk through spilled material.
• Runoff from fire control or dilution water may cause pollution. • Stop leak if you can do it without risk.
PUBLIC SAFETY FIRST AID
• CALL EMERGENCY RESPONSE Telephone Number on Shipping Paper first. If Shipping Paper not • Move victim to fresh air.
available or no answer, refer to appropriate telephone number listed on the inside back cover. • Call 108 or emergency medical service.
• As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 • Give artificial respiration if victim is not breathing.
meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. • Administer oxygen if breathing is difficult.
• Stay upwind. • Remove and isolate contaminated clothing and shoes.
• Keep unauthorized personnel away. • In case of contact with substance, immediately flush skin or eyes with running water for at least 20
minutes.
PROTECTIVE CLOTHING • Keep victim warm and quiet.
• Wear positive pressure self-contained breathing apparatus (SCBA). • Ensure that medical personnel are aware of the material(s) involved and take precautions to protect
• Structural firefighters’ protective clothing will only provide limited protection. themselves.
EVACUATION
Large Spill
Fire
Page 280 Page 281

GUIDE Substances (Low to Moderate Hazard) ERG2012 ERG2012 Substances (Low to Moderate Hazard) GUIDE
171 171
• Some may burn but none ignite readily. Small Fire
• Containers may explode when heated. • Dry chemical, CO2, water spray or regular foam.
• Some may be transported hot. Large Fire
HEALTH
• Do not scatter spilled material with high pressure water streams.
• Inhalation of material may be harmful.
• Dike fire-control water for later disposal.
• Inhalation of Asbestos dust may have a damaging effect on the lungs.
• Some liquids produce Vapours that may cause dizziness or suffocation.
SPILL OR LEAK
available or no answer, refer to appropriate telephone number listed on the inside back cover. • Prevent dust cloud.
• As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 • Avoid inhalation of asbestos dust.
meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. Small Dry Spill
• Keep unauthorized personnel away. • With clean shovel place material into clean, dry container and cover loosely; move containers from
• Stay upwind. spill area.
PROTECTIVE CLOTHING Small Spill
• Wear positive pressure self-contained breathing apparatus (SCBA). • Take up with sand or other non-combustible absorbent material and place into containers for later
• Structural firefighters’ protective clothing will only provide limited protection. disposal.
Large Spill
EVACUATION • Dike far ahead of liquid spill for later disposal.
Spill • Cover powder spill with plastic sheet or tarp to minimize spreading.
• See Table 1 - Initial Isolation and Protective Action Distances for highlighted materials. For • Prevent entry into waterways, sewers, basements or confined areas.
nonhighlighted materials, increase, in the downwind direction, as necessary, the isolation distance
shown under “PUBLIC SAFETY”. FIRST AID
Fire • Move victim to fresh air.
• If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; • Call 108 or emergency medical service.
also, consider initial evacuation for 800 meters (1/2 mile) in all directions. • Give artificial respiration if victim is not breathing.
minutes.
themselves.
Page 282 Page 283

GUIDE Gallium and Mercury ERG2012 ERG2012 Gallium and Mercury GUIDE
172 172
HEALTH FIRE
• Inhalation of Vapours or contact with substance will result in contamination and potential harmful • Use extinguishing agent suitable for type of surrounding fire.
effects. • Do not direct water at the heated metal.
SPILL OR LEAK
FIRE OR EXPLOSION • Do not touch or walk through spilled material.
• Non-combustible, substance itself does not burn but may react upon heating to produce corrosive • Do not touch damaged containers or spilled material unless wearing appropriate protective clothing.
and/or toxic fumes. • Stop leak if you can do it without risk.
• Runoff may pollute waterways. • Prevent entry into waterways, sewers, basements or confined areas.
• Do not use steel or aluminum tools or equipment.
• Cover with earth, sand or other non-combustible material followed with plastic sheet to minimize
PUBLIC SAFETY spreading or contact with rain.
• CALL EMERGENCY RESPONSE Telephone Number on Shipping Paper first. If Shipping Paper not • For mercury, use a mercury spill kit.
available or no answer, refer to appropriate telephone number listed on the inside back cover. • Mercury spill areas may be subsequently treated with calcium sulphide/calcium sulfide or with
• As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet) in sodium thiosulphate/sodium thiosulfate wash to neutralize any residual mercury.
all directions.
• Stay upwind. FIRST AID
• Keep unauthorized personnel away. • Move victim to fresh air.
PROTECTIVE CLOTHING • Give artificial respiration if victim is not breathing.
• Wear positive pressure self-contained breathing apparatus (SCBA). • Administer oxygen if breathing is difficult.
• Structural firefighters’ protective clothing will only provide limited protection. • Remove and isolate contaminated clothing and shoes.
Large Spill minutes.
• Consider initial downwind evacuation for at least 100 meters (330 feet). • Keep victim warm and quiet.
• When any large container is involved in a fire, consider initial evacuation for 500 meters (1/3 mile) in themselves.
all directions.
Page 284 Page 285

NOTES INTRODUCTION TO GREEN TABLES - INITIAL ISOLATION
AND PROTECTIVE ACTION DISTANCES
Table 1 - Initial Isolation and Protective Action Distances suggests distances useful to protect
people from Vapours resulting from spills involving dangerous goods that are considered toxic by
inhalation (TIH). This list includes certain chemical warfare agents and materials that produce
toxic gases upon contact with water. Table 1 provides first responders with initial guidance until
technically qualified emergency response personnel are available.
The Initial Isolation Zone defines an area SURROUNDING the incident in which persons may be
exposed to dangerous (upwind) and life threatening (downwind) concentrations of material. The
Protective Action Zone defines an area DOWNWIND from the incident in which persons may
become incapacitated and unable to take protective action and/or incur serious or irreversible
health effects. Table 1 provides specific guidance for small and large spills occurring day or night.
Adjusting distances for a specific incident involves many interdependent variables and should be
made only by personnel technically qualified to make such adjustments. For this reason, no
precise guidance can be provided in this document to aid in adjusting the table distances;
however, general guidance follows.
Factors That May Change the Protective Action Distances

The orange-bordered guide for a material clearly indicates under the section EVACUATION – Fire,
the evacuation distance required to protect against fragmentation hazard of a large container. If
the material becomes involved in a FIRE, the toxic hazard may be less than the fire or explosion
hazard. In these cases, the Fire hazard distance should be used.
Initial isolation and protective action distances in this guidebook are derived from historical data
on transportation incidents and the use of statistical models. For worst-case scenarios involving
the instantaneous release of the entire contents of a package (e.g., as a result of terrorism,
sabotage or catastrophic accident) the distances may increase substantially. For such events,
doubling of the initial isolation and protective action distances is appropriate in absence of other
information.
If more than one tank car containing TIH materials involved in the incident is leaking, LARGE SPILL
distances may need to be increased.
For a material with a protective action distance of 11.0+ km (7.0+ miles), the actual distance can
be larger in certain atmospheric conditions. If the dangerous goods Vapour plume is channeled in
a valley or between many tall buildings, distances may be larger than shown in Table 1 due to less
mixing of the plume with the atmosphere. Daytime spills in regions with known strong inversions
or snow cover, or occurring near sunset, may require an increase of the protective action distance
because airborne contaminants mix and disperse more slowly and may travel much farther
downwind. In such cases, the nighttime protective action distance may be more appropriate. In
addition, protective action distances may be larger for liquid spills when either the material or
outdoor temperature exceeds 30°C (86°F).
Page 286 Page 287
Materials which react with water to produce large amounts of toxic gases are included in Table 1 - PROTECTIVE ACTION DECISION FACTORS TO CONSIDER
Initial Isolation and Protective Action Distances. Note that some water-reactive materials (WRM)
which are also TIH (e.g., Bromine trifluoride (1746), Thionyl chloride (1836), etc.) produce
additional TIH materials when spilled in water. For these materials, two entries are provided in
The choice of protective actions for a given situation depends on a number of factors. For some
Table 1 - Initial Isolation and Protective Action Distances (i.e., for spills on land and for spills in
cases, evacuation may be the best option; in others, sheltering in-place may be the best course.
water). If it is not clear whether the spill is on land or in water, or in cases where the spill occurs
Sometimes, these two actions may be used in combination. In any emergency, officials need to
both on land and in water, choose the larger Protective Action Distance.
quickly give the public instructions. The public will need continuing information and instructions
Following Table 1, Table 2 – Water-Reactive Materials Which Produce Toxic Gases lists materials while being evacuated or sheltered in-place.
that produce large amounts of Toxic Inhalation Hazard gases (TIH) when spilled in water as well as
Proper evaluation of the factors listed below will determine the effectiveness of evacuation or in-
the toxic gases that are produced when spilled in water.
place protection (shelter in-place). The importance of these factors can vary with emergency
When a water-reactive TIH producing material is spilled into a river or stream, the source of the conditions. In specific emergencies, other factors may need to be identified and considered as
toxic gas may move with the current and stretch from the spill point downstream for a substantial well. This list indicates what kind of information may be needed to make the initial decision.
distance.
The Dangerous Goods
Finally, Table 3 lists Initial Isolation and Protective Action Distances for Toxic Inhalation Hazard • Degree of health hazard
materials that may be more commonly encountered. • Chemical and physical properties
The selected materials are: • Amount involved
• Containment/control of release
• Ammonia, anhydrous (Un1005) • Rate of Vapour movement
• Chlorine (UN1017)
The Population Threatened
• Ethylene oxide (UN1040)
• Hydrogen chloride (UN1050) and Hydrogen chloride, refrigerated liquid (UN2186) • Location
• Hydrogen fluoride (UN1052) • Number of people
• Sulfur dioxide/Sulphur dioxide (UN1079) • Time available to evacuate or shelter in-place
• Ability to control evacuation or shelter in-place
• Building types and availability
The materials are presented in alphabetical order and provide Initial Isolation and Protective
Action Distances for large spills (more than 208 liters) involving different container types • Special institutions or populations, e.g., nursing homes, hospitals, prisons
(therefore different volume capacities) for day time and night time situations and for different Weather Conditions
wind speeds. • Effect on Vapour and cloud movement
• Potential for change
• Effect on evacuation or shelter in-place
Page 288 Page 289

PROTECTIVE ACTIONS BACKGROUND ON TABLE 1 - INITIAL ISOLATION
AND PROTECTIVE ACTION DISTANCES
Protective Actions are those steps taken to preserve the health and safety of emergency Initial Isolation and Protective Action Distances in this guidebook were determined for small and
responders and the public during an incident involving releases of dangerous goods. Table 1 - large spills occurring during day or night. The overall analysis was statistical in nature and utilized
Initial Isolation and Protective Action Distances (green-bordered pages) predicts the size of state-of-the-art emission rate and dispersion models; statistical release data from the U.S. DOT
downwind areas which could be affected by a cloud of toxic gas. People in this area should be HMIS (Hazardous Materials Information System) database; meteorological observations from
evacuated and/or sheltered in-place inside buildings. over 120 locations in United States, Canada and Mexico; and the most current toxicological
exposure guidelines.
Isolate Hazard Area and Deny Entry means to keep everybody away from the area if they are not
For each chemical, thousands of hypothetical releases were modeled to account for the statistical
directly involved in emergency response operations. Unprotected emergency responders should
variation in both release amount and atmospheric conditions. Based on this statistical sample,
not be allowed to enter the isolation zone. This “isolation” task is done first to establish control the 90th percentile Protective Action Distance for each chemical and category was selected to
over the area of operations. This is the first step for any protective actions that may follow. See appear in the Table. A brief description of the analysis is provided below. A detailed report
Table 1 - Initial Isolation and Protective Action Distances (green-bordered pages) for more outlining the methodology and data used in the generation of the Initial Isolation and Protective
detailed information on specific materials. Action Distances may be obtained from the U.S. Department of Transportation, Pipeline and
Evacuate means to move all people from a threatened area to a safer place. To perform an Hazardous Materials Safety Administration.
evacuation, there must be enough time for people to be warned, to get ready, and to leave an Release amounts and emission rates into the atmosphere were statistically modeled based on
area. If there is enough time, evacuation is the best protective action. Begin evacuating people (1) data from the U.S. DOT HMIS database; (2) container types and sizes authorized for transport
nearby and those outdoors in direct view of the scene. When additional help arrives, expand the as specified in 49 CFR §172.101 and Part 173; (3) physical properties of the individual materials,
area to be evacuated downwind and crosswind to at least the extent recommended in this and (4) atmospheric data from a historical database. The emission model calculated the release of
guidebook. Even after people move to the distances recommended, they may not be completely Vapour due to eVapouration of pools on the ground, direct release of Vapours from the container,
safe from harm. They should not be permitted to congregate at such distances. Send evacuees to or a combination of both, as would occur for liquefied gases which can flash to form both a
a definite place, by a specific route, far enough away so they will not have to be moved again if the Vapour/aerosol mixture and an eVapourating pool. In addition, the emission model also
wind shifts. calculated the emission of toxic Vapour by-products generated from spilling water-reactive
materials in water. Spills that involve releases of approximately 208 liters for liquids and 300 kg for
Shelter In-Place means people should seek shelter inside a building and remain inside until the solids (660 pounds) or less are considered Small Spills, while spills that involve greater quantities
danger passes. Sheltering in-place is used when evacuating the public would cause greater risk are considered Large Spills. An exception to this is certain chemical warfare agents where Small
than staying where they are, or when an evacuation cannot be performed. Direct the people Spills include releases up to 2 kg (4.4 lbs), and Large Spills include releases up to 25 kg (55 lbs).
inside to close all doors and windows and to shut off all ventilating, heating and cooling systems. These agents are BZ, CX, GA, GB, GD, GF, HD, HL, HN1, HN2, HN3, L and VX.
In-place protection (shelter in-place) may not be the best option if (a) the Vapours are flammable; Downwind dispersion of the Vapour was estimated for each case modeled. Atmospheric
(b) if it will take a long time for the gas to clear the area; or (c) if buildings cannot be closed tightly. parameters affecting the dispersion, and the emission rate, were selected in a statistical fashion
Vehicles can offer some protection for a short period if the windows are closed and the ventilating from a database containing hourly meteorological data from 120 cities in the United States,
systems are shut off. Vehicles are not as effective as buildings for in-place protection. Canada and Mexico. The dispersion calculation accounted for the time dependent emission rate
from the source as well as the density of the Vapour plume (i.e., heavy gas effects). Since
It is vital to maintain communications with competent persons inside the building so that they
atmospheric mixing is less effective at dispersing Vapour plumes during nighttime, day and night
are advised about changing conditions. Persons protected-in-place should be warned to stay far were separated in the analysis. In Table 1, “Day” refers to time periods after sunrise and before
from windows because of the danger from glass and projected metal fragments in a fire and/or sunset, while “Night” includes all hours between sunset and sunrise.
explosion.
Toxicological short-term exposure guidelines for the materials were applied to determine the
Every dangerous goods incident is different. Each will have special problems and concerns. Action downwind distance to which persons may become incapacitated and unable to take protective
to protect the public must be selected carefully. These pages can help with initial decisions on action or may incur serious health effects after a once-in-a-lifetime, or rare, exposure. When
how to protect the public. Officials must continue to gather information and monitor the situation available, toxicological exposure guidelines were chosen from AEGL-2 or ERPG-2 emergency
until the threat is removed. response guidelines, with AEGL-2 values being the first choice. For materials that do not have
AEGL-2 or ERPG-2 values, emergency response guidelines estimated from lethal concentration
limits derived from animal studies were used, as recommended by an independent panel of
toxicological experts from industry and academia.
Page 290 Page 291

HOW TO USE TABLE 1 - INITIAL ISOLATION AND (6) Initiate Protective Actions to the extent possible, beginning with those closest to
the spill site and working away from the site in the downwind direction. When a
PROTECTIVE ACTION DISTANCES water-reactive TIH producing material is spilled into a river or stream, the source
(1) The responder should already have: of the toxic gas may move with the current or stretch from the spill point
• IdentifiedthematerialbyitsIDNumberandName;(ifanIDNumber cannotbefound, downstream for a substantial distance.
use the Name of Material index in the blue-bordered pages to locate that number.)
• Found the three-digit guide for that material in order to consult the emergency The shape of the area in which protective actions should be taken (the Protective
actions recommended jointly with this table; Action Zone) is shown in this figure. The spill is located at the center of the small
• Noted the wind direction. circle. The larger circle represents the INITIAL ISOLATION zonearound the spill.
(2) Look in Table 1 (the green-bordered pages) for the ID Number and Name of the
Material involved in the incident. Some ID Numbers have more than one
UPWIND Wind Direction DOWNWIND
shipping name listed look for the specific name of the material. (If the shipping
name is not known and Table 1 lists more than one name for the same ID Protective
Number, use the entry with the largest protective action distances.) Action Zone ½ Downwind
Distance
(3) Determine if the incident involves a SMALL or LARGE spill and if DAY or NIGHT. Initial
Generally, a SMALL SPILL is one which involves a single, small package (e.g., a d r u m Isolation DistanceWind Direction
containing up to approximately 208 liters, a small cylinder, or a small leak from a Zone
½ Downwind
large package. A LARGE SPILL is one which involves a spill from a large package,
Distance
or multiple spills from many small packages. DAY is any time after sunrise and
Spill
before sunset. NIGHT is any time between sunset and sunrise.
(4) Look up the initial ISOLATION distance. Initial Isolation

Direct all persons to move, in a crosswind Zone
direction, away from the spill to the distance NOTE 1: See “Introduction To Green Tables – Initial
specified—in meters and feet. Initial Isolation Isolation And Protective Action Distances” under
Distance "Factors That May Change the Protective Action
Distances" (page 285)
Spill
NOTE 2: See Table 2 – Water-Reactive Materials which
(5) Look up the initial PROTECTIVE ACTION DISTANCE shown in Table 1. For a given Produce Toxic Gases for the list of gases produced
material, spill size, and whether day or night, Table 1 gives the downwind when these materials are spilled in water.
distance—in kilometers and miles— for which protective actions should be
considered. For practical purposes, the Protective Action Zone (i.e., the area in Call the emergency response telephone number listed on the shipping paper
which people are at risk of harmful exposure) is a square, whose length and or the appropriate response agency as soon as possible for additional
width are the same as the downwind distance shown in Table 1. information on the material, safety precautions and mitigation procedures.
Page 292 Page 293

TABLE 1 - INITIAL ISOLATION AND PROTECTIVE ACTION DISTANCES
SMALL SPILLS LARGE SPILLS
(From a small package or small leak from a large package) (From a large package or from many small packages)
Page 294
First Then First Then
ISOLATE PROTECT ISOLATE PROTECT
in all Directions persons Downwind during- in all Directions persons Downwind during-
ID DAY NIGHT DAY NIGHT
No. Guide NAME OF MATERIAL Meters (Feet) Kilometers (Miles) Kilometers (Miles) Meters (Feet) Kilometers (Miles) Kilometers (Miles)
1005 * 125 Ammonia, anhydrous 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 150 m (500 ft) 0.8 km (0.5 mi) 2.0 km (1.3 mi)
1005 * 125 Anhydrous ammonia
1008 125 Boron trifluoride 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.4 mi) 300 m (1000 ft) 1.7 km (1.1 mi) 4.8 km (3.0 mi)
1008 125 Boron trifluoride, compressed
1016 119 Carbon monoxide 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 200 m (600 ft) 1.2 km (0.8 mi) 4.8 km (3.0 mi)
1016 119 Carbon monoxide, compressed
1017 * 124 Chlorine 60 m (200 ft) 0.4 km (0.2 mi) 1.5 km (1.0 mi) 500 m (1500 ft) 3.0 km (1.9 mi) 7.9 km (4.9 mi)
1023 119 Coal gas 60 m (200 ft) 0.2 km (0.1 mi) 0.2 km (0.1 mi) 100 m (300 ft) 0.4 km (0.2 mi) 0.5 km (0.3 mi)
1023 119 Coal gas, compressed
1026 119 Cyanogen 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 60 m (200 ft) 0.4 km (0.2 mi) 1.7 km (1.0 mi)
1026 119 Cyanogen gas
1040 * 119P Ethylene oxide 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 150 m (500 ft) 0.9 km (0.5 mi) 2.0 km (1.3 mi)
1040 * 119P Ethylene oxide with Nitrogen
1045 124 Fluorine 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 100 m (300 ft) 0.5 km (0.3 mi) 2.3 km (1.4 mi)
1045 124 Fluorine, compressed
1048 125 Hydrogen bromide, anhydrous 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 200 m (600 ft) 1.2 km (0.8 mi) 3.9 km (2.4 mi)
1050 * 125 Hydrogen chloride, anhydrous 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 60 m (200 ft) 0.3 km (0.2 mi) 1.3 km (0.8 mi)
1051 117 AC (when used as a weapon) 60 m (200 ft) 0.3 km (0.2 mi) 1.0 km (0.6 mi) 1000 m (3000 ft) 3.7 km (2.3 mi) 8.4 km (5.3 mi)
1051 117 Hydrocyanic acid, aqueous 60 m (200 ft) 0.2 km (0.1 mi) 0.6 km (0.4 mi) 400 m (1250 ft) 1.4 km (0.9 mi) 3.8 km (2.4 mi)
solutions, with more than 20%
Hydrogen cyanide
1051 117 Hydrogen cyanide, anhydrous,
stabilized
1051 117 Hydrogen cyanide, stabilized
1052 * 125 Hydrogen fluoride, anhydrous 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 300 m (1000 ft) 1.5 km (0.9 mi) 3.2 km (2.0 mi)
1053 117 Hydrogen sulfide 30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.3 mi) 300 m (1000 ft) 1.7 km (1.0 mi) 5.6 km (3.5 mi)
1053 117 Hydrogen sulphide
1062 123 Methyl bromide 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.2 mi) 100 m (300 ft) 0.6 km (0.4 mi) 1.9 km (1.2 mi)
1064 117 Methyl mercaptan 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 150 m (500 ft) 1.0 km (0.7 mi) 3.2 km (2.0 mi)
1067 124 Dinitrogen tetroxide 30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.2 mi) 300 m (1000 ft) 1.1 km (0.7 mi) 2.7 km (1.7 mi)
1067 124 Nitrogen dioxide
1069 125 Nitrosyl chloride 30 m (100 ft) 0.2 km (0.2 mi) 1.1 km (0.7 mi) 600 m (2000 ft) 3.6 km (2.3 mi) 9.5 km (5.9 mi)
1071 119 Oil gas 60 m (200 ft) 0.2 km (0.1 mi) 0.2 km (0.1 mi) 100 m (300 ft) 0.4 km (0.2 mi) 0.5 km (0.3 mi)
1071 119 Oil gas, compressed
1076 125 CG (when used as a weapon) 150 m (500 ft) 0.8 km (0.5 mi) 3.2 km (2.0 mi) 1000 m (3000 ft) 7.5 km (4.7 mi) 11.0+ km (7.0+ mi)
1076 125 Diphosgene 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.5 km 0.3 mi)
1076 125 DP (when used as a weapon) 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 200 m (600 ft) 1.0 km (0.7 mi) 2.4 km (1.5 mi)
1076 125 Phosgene 100 m (300 ft) 0.6 km (0.4 mi) 2.7 km (1.7 mi) 500 m (1500 ft) 3.1 km (1.9 mi) 10.8 km (6.7 mi)
1079 * 125 Sulfur dioxide 100 m (300 ft) 0.7 km (0.4 mi) 2.8 km (1.7 mi) 1000 m (3000 ft) 5.6 km (3.5 mi) 11.0+ km (7.0+ mi)
1079 * 125 Sulphur dioxide
1082 119P Trifluorochloroethylene, 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.4 km (0.3 mi) 0.9 km (0.6 mi)
stabilized
1092 131P Acrolein, stabilized 150 m (500 ft) 1.4 km (0.9 mi) 4.0 km (2.5 mi) 800 m (2500 ft) 9.3 km (5.8 mi) 11.0+ km (7.0+ mi)
1098 131 Allyl alcohol 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 60 m (200 ft) 0.3 km (0.2 mi) 0.5 km (0.3 mi)
Page 295
"+" means distance can be larger in certain atmospheric conditions * PLEASE ALSO CONSULT TABLE 3 FOR THIS MATERIAL

Page 296
1135 131 Ethylene chlorohydrin 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 60 m (200 ft) 0.3 km (0.2 mi) 0.4 km (0.3 mi)
1143 131P Crotonaldehyde 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 1.0 km (0.6 mi)
1143 131P Crotonaldehyde, stabilized
1162 155 Dimethyldichlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.2 mi) 60 m (200 ft) 0.6 km (0.4 mi) 1.9 km (1.2 mi)
(when spilled in water)
1163 131 1,1-Dimethylhydrazine 30 m (100 ft) 0.2 km (0.1 mi) 0.5 km (0.4 mi) 100 m (300 ft) 1.1 km (0.7 mi) 2.2 km (1.4 mi)
1163 131 Dimethylhydrazine,
unsymmetrical
1182 155 Ethyl chloroformate 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.4 km (0.2 mi) 0.6 km (0.4 mi)
1183 139 Ethyldichlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 60 m (200 ft) 0.7 km (0.5 mi) 2.2 km (1.4 mi)
1185 131P Ethyleneimine, stabilized 30 m (100 ft) 0.2 km (0.1 mi) 0.5 km (0.3 mi) 100 m (300 ft) 1.0 km (0.6 mi) 2.0 km (1.3 mi)
1196 155 Ethyltrichlorosilane 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.5 mi) 200 m (600 ft) 2.1 km (1.3 mi) 6.3 km (3.9 mi)
1238 155 Methyl chloroformate 30 m (100 ft) 0.2 km (0.2 mi) 0.6 km (0.4 mi) 150 m (500 ft) 1.1 km (0.7 mi) 2.3 km (1.4 mi)
1239 131 Methyl chloromethyl ether 30 m (100 ft) 0.3 km (0.2 mi) 1.1 km (0.7 mi) 200 m (600 ft) 2.2 km (1.4 mi) 4.6 km (2.9 mi)
1242 139 Methyldichlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 60 m (200 ft) 0.8 km (0.5 mi) 2.5 km (1.6 mi)
1244 131 Methylhydrazine 30 m (100 ft) 0.3 km (0.2 mi) 0.6 km (0.4 mi) 100 m (300 ft) 1.4 km (0.9 mi) 2.3 km (1.4 mi)
1250 155 Methyltrichlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 100 m (300 ft) 0.9 km (0.6 mi) 2.6 km (1.7 mi)
1251 131P Methyl vinyl ketone, stabilized 100 m (300 ft) 0.3 km (0.2 mi) 0.8 km (0.5 mi) 800 m (2500 ft) 1.5 km (1.0 mi) 3.0 km (1.9 mi)
1259 131 Nickel carbonyl 100 m (300 ft) 1.4 km (0.9 mi) 5.4 km (3.4 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)
1295 139 Trichlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 60 m (200 ft) 0.7 km (0.4 mi) 2.2 km (1.4 mi)
1298 155 Trimethylchlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.6 km (0.4 mi) 1.6 km (1.0 mi)
1305 155P Vinyltrichlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.2 mi) 60 m (200 ft) 0.6 km (0.4 mi) 2.0 km (1.3 mi)
1305 155P Vinyltrichlorosilane, stabilized
1340 139 Phosphorus pentasulfide, 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.4 km (0.2 mi) 1.4 km (0.9 mi)
free from yellow and
white Phosphorus
1340 139 Phosphorus pentasulphide,
free from yellow and
white Phosphorus
1360 139 Calcium phosphide 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 300 m (1000 ft) 1.1 km (0.7 mi) 3.8 km (2.4 mi)
1380 135 Pentaborane 60 m (200 ft) 0.6 km (0.4 mi) 2.0 km (1.2 mi) 200 m (600 ft) 2.7 km (1.7 mi) 8.2 km (5.1 mi)
1384 135 Sodium dithionite 30 m (100 ft) 0.2 km (0.1 mi) 0.6 km (0.4 mi) 60 m (200 ft) 0.8 km (0.5 mi) 2.7 km (1.7 mi)
1384 135 Sodium hydrosulfite
1384 135 Sodium hydrosulphite
1397 139 Aluminum phosphide 60 m (200 ft) 0.2 km (0.2 mi) 0.9 km (0.6 mi) 500 m (1500 ft) 2.1 km (1.3 mi) 7.5 km (4.7 mi)
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Page 298
1419 139 Magnesium aluminum 60 m (200 ft) 0.2 km (0.1 mi) 0.9 km (0.5 mi) 500 m (1500 ft) 1.9 km (1.2 mi) 6.5 km (4.1 mi)
phosphide
1432 139 Sodium phosphide 30 m (100 ft) 0.2 km (0.1 mi) 0.6 km (0.4 mi) 400 m (1250 ft) 1.4 km (0.9 mi) 4.2 km (2.6 mi)
1510 143 Tetranitromethane 30 m (100 ft) 0.2 km (0.2 mi) 0.4 km (0.2 mi) 60 m (200 ft) 0.5 km (0.4 mi) 1.0 km (0.6 mi)
1541 155 Acetone cyanohydrin, stabilized 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 100 m (300 ft) 0.3 km (0.2 mi) 1.0 km (0.7 mi)
1556 152 MD (when used as a weapon) 300 m (1000 ft) 1.6 km (1.0 mi) 4.3 km (2.7 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)
1556 152 Methyldichloroarsine 100 m (300 ft) 1.4 km (0.9 mi) 2.2 km (1.4 mi) 300 m (1000 ft) 3.8 km (2.4 mi) 6.9 km (4.3 mi)
1556 152 PD (when used as a weapon) 60 m (200 ft) 0.4 km (0.3 mi) 0.4 km (0.3 mi) 300 m (1000 ft) 1.6 km (1.0 mi) 1.6 km (1.0 mi)
1560 157 Arsenic chloride 30 m (100 ft) 0.2 km (0.1 mi) 0.3 km (0.2 mi) 100 m (300 ft) 1.0 km (0.6 mi) 1.6 km (1.0 mi)
1560 157 Arsenic trichloride
1569 131 Bromoacetone 30 m (100 ft) 0.4 km (0.3 mi) 1.2 km (0.8 mi) 150 m (500 ft) 1.9 km (1.2 mi) 3.6 km (2.3 mi)
1580 154 Chloropicrin 30 m (100 ft) 0.4 km (0.3 mi) 1.0 km (0.6 mi) 150 m (500 ft) 1.6 km (1.0 mi) 3.1 km (1.9 mi)
1581 123 Chloropicrin and Methyl 30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 300 m (1000 ft) 2.1 km (1.3 mi) 5.9 km (3.7 mi)
1581 123 bromide mixture
Methyl bromide and
Chloropicrin mixture
1582 119 Chloropicrin and Methyl 30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.3 mi) 60 m (200 ft) 0.4 km (0.2 mi) 1.7 km (1.1 mi)
chloride mixture
1582 119 Methyl chloride and
Chloropicrin mixture
1583 154 Chloropicrin mixture, n.o.s. 30 m (100 ft) 0.4 km (0.3 mi) 1.0 km (0.6 mi) 150 m (500 ft) 1.6 km (1.0 mi) 3.1 km (1.9 mi)
1589 125 CK (when used as a weapon) 150 m (500 ft) 1.0 km (0.6 mi) 3.8 km (2.4 mi) 800 m (2500 ft) 5.7 km (3.6 mi) 11.0+ km (7.0+ mi)
1589 125 Cyanogen chloride, stabilized 100 m (300 ft) 0.5 km (0.3 mi) 2.2 km (1.4 mi) 400 m (1250 ft) 2.6 km (1.7 mi) 8.6 km (5.4 mi)
1595 156 Dimethyl sulfate 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 0.8 km (0.5 mi)
1595 156 Dimethyl sulphate
1605 154 Ethylene dibromide 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.1 mi)
1612 123 Hexaethyl tetraphosphate and 100 m (300 ft) 0.8 km (0.5 mi) 2.7 km (1.7 mi) 400 m (1250 ft) 3.5 km (2.2 mi) 8.1 km (5.1 mi)
compressed gas mixture
1613 154 Hydrocyanic acid, aqueous 60 m (200 ft) 0.2 km (0.1 mi) 0.2 km (0.1 mi) 150 m (500 ft) 0.5 km (0.3 mi) 1.3 km (0.8 mi)
1613 154 Hydrogen cyanide, aqueous
1614 152 Hydrogen cyanide, stabilized 60 m (200 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 150 m (500 ft) 0.5 km (0.4 mi) 1.7 km (1.1 mi)
(absorbed)
1647 151 Ethylene dibromide and Methyl 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.2 mi) 100 m (300 ft) 0.6 km (0.4 mi) 1.9 km (1.2 mi)
bromide mixture, liquid
1647 151 Methyl bromide and Ethylene
dibromide mixture, liquid
1660 124 Nitric oxide 30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 100 m (300 ft) 0.6 km (0.4 mi) 2.3 km (1.5 mi)
1660 124 Nitric oxide, compressed
1670 157 Perchloromethyl mercaptan 30 m (100 ft) 0.2 km (0.2 mi) 0.4 km (0.2 mi) 100 m (300 ft) 0.7 km (0.5 mi) 1.3 km (0.8 mi)
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Page 300
1680 157 Potassium cyanide 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 100 m (300 ft) 0.3 km (0.2 mi) 1.2 km (0.8 mi)
1680 157 Potassium cyanide, solid
1689 157 Sodium cyanide 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 100 m (300 ft) 0.4 km (0.2 mi) 1.4 km (0.9 mi)
1689 157 Sodium cyanide, solid
1694 159 CA (when used as a weapon) 30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.3 mi) 100 m (300 ft) 0.5 km (0.4 mi) 2.6 km (1.6 mi)
1695 131 Chloroacetone, stabilized 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.4 km (0.3 mi) 0.8 km (0.5 mi)
1697 153 CN (when used as a weapon) 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.3 km (0.2 mi) 1.2 km (0.8 mi)
1698 154 Adamsite 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 60 m (200 ft) 0.3 km (0.2 mi) 1.4 km (0.9 mi)
(when used as a weapon)
1698 154 DM (when used as a weapon)
1699 151 DA (when used as a weapon) 30 m (100 ft) 0.2 km (0.1 mi) 0.8 km (0.5 mi) 300 m (1000 ft) 1.9 km (1.2 mi) 7.5 km (4.7 mi)
1716 156 Acetyl bromide 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 1.3 km (0.8 mi)
1717 155 Acetyl chloride 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 100 m (300 ft) 1.0 km (0.6 mi) 2.8 km (1.7 mi)
1722 155 Allyl chlorocarbonate 100 m (300 ft) 0.4 km (0.2 mi) 0.9 km (0.6 mi) 400 m (1250 ft) 1.5 km (1.0 mi) 3.0 km (1.9 mi)
1722 155 Allyl chloroformate
1724 155 Allyltrichlorosilane, stabilized 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.2 mi) 60 m (200 ft) 0.6 km (0.4 mi) 1.9 km (1.2 mi)
1725 137 Aluminum bromide, anhydrous 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.2 km (0.1 mi) 0.6 km (0.4 mi)
1726 137 Aluminum chloride, anhydrous 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 60 m (200 ft) 0.6 km (0.4 mi) 2.2 km (1.4 mi)
1728 155 Amyltrichlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.2 mi) 60 m (200 ft) 0.6 km (0.4 mi) 1.9 km (1.2 mi)
1732 157 Antimony pentafluoride 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 150 m (500 ft) 1.2 km (0.7 mi) 4.2 km (2.6 mi)
1741 125 Boron trichloride 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 100 m (300 ft) 0.6 km (0.4 mi) 1.4 km (0.9 mi)
(when spilled on land)
1741 125 Boron trichloride 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 100 m (300 ft) 1.3 km (0.8 mi) 3.8 km (2.4 mi)
1744 154 Bromine 60 m (200 ft) 0.6 km (0.4 mi) 1.9 km (1.2 mi) 300 m (1000 ft) 2.8 km (1.8 mi) 6.5 km (4.0 mi)
1744 154 Bromine, solution
1744 154 Bromine, solution
1744 154 Bromine, solution 60 m (200 ft) 0.5 km (0.3 mi) 1.3 km (0.8 mi) 150 m (500 ft) 1.8 km (1.1 mi) 4.2 km (2.6 mi)
1745 144 Bromine pentafluoride 30 m (100 ft) 0.4 km (0.2 mi) 1.4 km (0.9 mi) 200 m (600 ft) 2.3 km (1.4 mi) 5.1 km (3.2 mi)
1745 144 Bromine pentafluoride 30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 150 m (500 ft) 1.2 km (0.8 mi) 4.4 km (2.7 mi)
1746 144 Bromine trifluoride 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.5 km (0.4 mi)
1746 144 Bromine trifluoride 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 100 m (300 ft) 1.1 km (0.7 mi) 4.1 km (2.5 mi)
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1747 155 Butyltrichlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.2 mi) 60 m (200 ft) 0.6 km (0.4 mi) 1.8 km (1.1 mi)
1749 124 Chlorine trifluoride 60 m (200 ft) 0.3 km (0.2 mi) 1.2 km (0.8 mi) 300 m (1000 ft) 1.5 km (0.9 mi) 4.6 km (2.9 mi)
1752 156 Chloroacetyl chloride 30 m (100 ft) 0.3 km (0.2 mi) 0.6 km (0.4 mi) 100 m (300 ft) 1.2 km (0.8 mi) 2.3 km (1.4 mi)
1752 156 Chloroacetyl chloride 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.9 km (0.6 mi)
1753 156 Chlorophenyltrichlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 1.0 km (0.7 mi)
1754 137 Chlorosulfonic acid 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.4 km (0.2 mi)
1754 137 Chlorosulfonic acid 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 60 m (200 ft) 0.7 km (0.5 mi) 2.5 km (1.5 mi)
1754 137 Chlorosulfonic acid and 100 m (300 ft) 0.4 km (0.2 mi) 0.9 km (0.5 mi) 400 m (1250 ft) 2.9 km (1.8 mi) 5.7 km (3.5 mi)
Sulfur trioxide mixture
1754 137 Chlorosulfonic acid and 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 60 m (200 ft) 0.7 km (0.5 mi) 2.5 km (1.5 mi)
Sulfur trioxide mixture
1754 137 Chlorosulphonic acid 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.4 km (0.2 mi)
1754 137 Chlorosulphonic acid 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 60 m (200 ft) 0.7 km (0.5 mi) 2.5 km (1.5 mi)
1754 137 Chlorosulphonic acid and 100 m (300 ft) 0.4 km (0.2 mi) 0.9 km (0.5 mi) 400 m (1250 ft) 2.9 km (1.8 mi) 5.7 km (3.5 mi)
Sulphur trioxide mixture
1754 137 Chlorosulphonic acid and 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 60 m (200 ft) 0.7 km (0.5 mi) 2.5 km (1.5 mi)
Sulphur trioxide mixture
1754 137 Sulfur trioxide and 100 m (300 ft) 0.4 km (0.2 mi) 0.9 km (0.5 mi) 400 m (1250 ft) 2.9 km (1.8 mi) 5.7 km (3.5 mi)
Chlorosulfonic acid mixture
1754 137 Sulfur trioxide and 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 60 m (200 ft) 0.7 km (0.5 mi) 2.5 km (1.5 mi)
Chlorosulfonic acid mixture
1754 137 Sulphur trioxide and 100 m (300 ft) 0.4 km (0.2 mi) 0.9 km (0.5 mi) 400 m (1250 ft) 2.9 km (1.8 mi) 5.7 km (3.5 mi)
Chlorosulphonic acid mixture
1754 137 Sulphur trioxide and 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 60 m (200 ft) 0.7 km (0.5 mi) 2.5 km (1.5 mi)
Chlorosulphonic acid mixture
1758 137 Chromium oxychloride 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.2 km (0.2 mi) 0.8 km (0.5 mi)
1762 156 Cyclohexenyltrichlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 30 m (100 ft) 0.4 km (0.3 mi) 1.4 km (0.9 mi)
1763 156 Cyclohexyltrichlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 30 m (100 ft) 0.4 km (0.3 mi) 1.4 km (0.9 mi)
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1765 156 Dichloroacetyl chloride 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 1.0 km (0.6 mi)
1766 156 Dichlorophenyltrichlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.2 mi) 60 m (200 ft) 0.6 km (0.4 mi) 2.1 km (1.3 mi)
1767 155 Diethyldichlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.4 km (0.3 mi) 1.1 km (0.7 mi)
1769 156 Diphenyldichlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 30 m (100 ft) 0.4 km (0.3 mi) 1.3 km (0.8 mi)
1771 156 Dodecyltrichlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 1.4 km (0.9 mi)
1777 137 Fluorosulfonic acid 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.2 km (0.2 mi) 0.8 km (0.5 mi)
1777 137 Fluorosulphonic acid
1781 156 Hexadecyltrichlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.2 km (0.2 mi) 0.7 km (0.4 mi)
1784 156 Hexyltrichlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 1.5 km (0.9 mi)
1799 156 Nonyltrichlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 1.6 km (1.0 mi)
1800 156 Octadecyltrichlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 1.5 km (1.0 mi)
1801 156 Octyltrichlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 1.6 km (1.0 mi)
1804 156 Phenyltrichlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 1.5 km (1.0 mi)
1806 137 Phosphorus pentachloride 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.2 mi) 30 m (100 ft) 0.4 km (0.3 mi) 1.5 km (0.9 mi)
1808 137 Phosphorus tribromide 30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.2 mi) 60 m (200 ft) 0.6 km (0.4 mi) 2.0 km (1.2 mi)
1809 137 Phosphorus trichloride 30 m (100 ft) 0.2 km (0.1 mi) 0.5 km (0.3 mi) 100 m (300 ft) 1.0 km (0.6 mi) 2.2 km (1.4 mi)
1809 137 Phosphorus trichloride 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 60 m (200 ft) 0.8 km (0.5 mi) 2.5 km (1.6 mi)
1810 137 Phosphorus oxychloride 30 m (100 ft) 0.3 km (0.2 mi) 0.7 km (0.4 mi) 100 m (300 ft) 1.2 km (0.7 mi) 2.2 km (1.4 mi)
1810 137 Phosphorus oxychloride 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 60 m (200 ft) 0.7 km (0.4 mi) 2.3 km (1.4 mi)
1815 132 Propionyl chloride 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.8 km (0.5 mi)
1816 155 Propyltrichlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 60 m (200 ft) 0.6 km (0.4 mi) 2.0 km (1.3 mi)
1818 157 Silicon tetrachloride 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 100 m (300 ft) 0.9 km (0.6 mi) 2.8 km (1.7 mi)
1828 137 Sulfur chlorides 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 60 m (200 ft) 0.3 km (0.2 mi) 0.5 km (0.3 mi)
1828 137 Sulfur chlorides 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 30 m (100 ft) 0.4 km (0.2 mi) 1.2 km (0.8 mi)
1828 137 Sulphur chlorides 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 60 m (200 ft) 0.3 km (0.2 mi) 0.5 km (0.3 mi)
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1828 137 Sulphur chlorides 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 30 m (100 ft) 0.4 km (0.2 mi) 1.2 km (0.8 mi)
1829 137 Sulfur trioxide, stabilized 100 m (300 ft) 0.4 km (0.2 mi) 0.9 km (0.5 mi) 400 m (1250 ft) 2.9 km (1.8 mi) 5.7 km (3.5 mi)
1829 137 Sulphur trioxide, stabilized
1831 137 Sulfuric acid, fuming 100 m (300 ft) 0.4 km (0.2 mi) 0.9 km (0.5 mi) 400 m (1250 ft) 2.9 km (1.8 mi) 5.7 km (3.5 mi)
1831 137 Sulfuric acid, fuming,
with not less than 30% free
Sulfur trioxide
1831 137 Sulphuric acid, fuming
1831 137 Sulphuric acid, fuming,
with not less than 30% free
Sulphur trioxide
1834 137 Sulfuryl chloride 30 m (100 ft) 0.2 km (0.1 mi) 0.5 km (0.4 mi) 100 m (300 ft) 0.9 km (0.6 mi) 2.0 km (1.3 mi)
1834 137 Sulfuryl chloride 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 1.8 km (1.1 mi)
1834 137 Sulphuryl chloride 30 m (100 ft) 0.2 km (0.1 mi) 0.5 km (0.4 mi) 100 m (300 ft) 0.9 km (0.6 mi) 2.0 km (1.3 mi)
1834 137 Sulphuryl chloride 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 1.8 km (1.1 mi)
1836 137 Thionyl chloride 30 m (100 ft) 0.2 km (0.2 mi) 0.7 km (0.5 mi) 100 m (300 ft) 0.9 km (0.6 mi) 1.9 km (1.2 mi)
1836 137 Thionyl chloride 100 m (300 ft) 1.1 km (0.7 mi) 3.0 km (1.9 mi) 800 m (2500 ft) 9.9 km (6.2 mi) 11.0+ km (7.0+ mi)
1838 137 Titanium tetrachloride 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 30 m (100 ft) 0.4 km (0.3 mi) 0.7 km (0.4 mi)
1838 137 Titanium tetrachloride 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 1.8 km (1.1 mi)
1859 157 Silicon tetrafluoride 30 m (100 ft) 0.2 km (0.1 mi) 0.8 km (0.5 mi) 100 m (300 ft) 0.6 km (0.4 mi) 2.5 km (1.6 mi)
1859 157 Silicon tetrafluoride,
compressed
1892 151 ED (when used as a weapon) 150 m (500 ft) 2.0 km (1.2 mi) 2.9 km (1.8 mi) 1000 m (3000 ft) 10.4 km (6.5 mi) 11.0+ km (7.0+ mi)
1892 151 Ethyldichloroarsine 150 m (500 ft) 1.5 km (1.0 mi) 2.4 km (1.5 mi) 500 m (1500 ft) 5.2 km (3.3 mi) 10.2 km (6.1 mi)
1898 156 Acetyl iodide 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.2 mi) 60 m (200 ft) 0.5 km (0.3 mi) 1.1 km (0.7 mi)
1911 119 Diborane 60 m (200 ft) 0.3 km (0.2 mi) 1.0 km (0.7 mi) 200 m (600 ft) 1.3 km (0.8 mi) 3.9 km (2.5 mi)
1911 119 Diborane, compressed
1923 135 Calcium dithionite 30 m (100 ft) 0.2 km (0.1 mi) 0.7 km (0.4 mi) 60 m (200 ft) 0.8 km (0.5 mi) 2.8 km (1.7 mi)
1923 135 Calcium hydrosulfite
1923 135 Calcium hydrosulphite
1929 135 Potassium dithionite 30 m (100 ft) 0.2 km (0.1 mi) 0.6 km (0.4 mi) 60 m (200 ft) 0.7 km (0.4 mi) 2.5 km (1.5 mi)
1929 135 Potassium hydrosulfite
1929 135 Potassium hydrosulphite
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1931 171 Zinc dithionite 30 m (100 ft) 0.2 km (0.1 mi) 0.6 km (0.4 mi) 60 m (200 ft) 0.7 km (0.5 mi) 2.5 km (1.6 mi)
1931 171 Zinc hydrosulfite
1931 171 Zinc hydrosulphite
1953 119 Compressed gas, flammable, 100 m (300 ft) 0.5 km (0.3 mi) 2.2 km (1.4 mi) 600 m (2000 ft) 2.6 km (1.7 mi) 8.6 km (5.4 mi)
poisonous, n.o.s.
poisonous, n.o.s.
poisonous, n.o.s.
(Inhalation Hazard Zone C)
poisonous, n.o.s.
1953 119 Compressed gas, 100 m (300 ft) 0.5 km (0.3 mi) 2.2 km (1.4 mi) 600 m (2000 ft) 2.6 km (1.7 mi) 8.6 km (5.4 mi)
flammable, toxic, n.o.s.
toxic, n.o.s.
1953 119 Compressed gas, poisonous, 100 m (300 ft) 0.5 km (0.3 mi) 2.2 km (1.4 mi) 600 m (2000 ft) 2.6 km (1.7 mi) 8.6 km (5.4 mi)
flammable, n.o.s.
flammable, n.o.s.
flammable, n.o.s.
flammable, n.o.s.
flammable, n.o.s.
1953 119 Compressed gas, toxic, 100 m (300 ft) 0.5 km (0.3 mi) 2.2 km (1.4 mi) 600 m (2000 ft) 2.6 km (1.7 mi) 8.6 km (5.4 mi)
flammable, n.o.s.
1953 119 Compressed gas, toxic,
flammable, n.o.s.
flammable, n.o.s.
flammable, n.o.s.
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Page 310
flammable, n.o.s.
poisonous, n.o.s.
1955 123 Compressed gas,
poisonous, n.o.s.
poisonous, n.o.s.
poisonous, n.o.s.
poisonous, n.o.s.
1955 123 Compressed gas, toxic, n.o.s. 100 m (300 ft) 0.5 km (0.3 mi) 2.2 km (1.4 mi) 600 m (2000 ft) 3.5 km (2.2 mi) 9.4 km (5.9 mi)
1955 123 Compressed gas, toxic, n.o.s.
1955 123 Organic phosphate compound 100 m (300 ft) 0.9 km (0.6 mi) 2.6 km (1.6 mi) 500 m (1500 ft) 3.9 km (2.4 mi) 9.4 km (5.9 mi)
mixed with compressed gas
1955 123 Organic phosphate mixed with
compressed gas
1955 123 Organic phosphorus compound
mixed with compressed gas
1967 123 Insecticide gas, poisonous, 100 m (300 ft) 0.9 km (0.6 mi) 2.6 km (1.6 mi) 500 m (1500 ft) 3.9 km (2.4 mi) 9.4 km (5.9 mi)
n.o.s.
1967 123 Insecticide gas, toxic, n.o.s.
1967 123 Parathion and compressed gas 30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 100 m (300 ft) 0.6 km (0.4 mi) 2.3 km (1.5 mi)
mixture
1975 124 Dinitrogen tetroxide and Nitric
oxide mixture
1975 124 Nitric oxide and Dinitrogen
tetroxide mixture
1975 124 Nitric oxide and Nitrogen
dioxide mixture
1975 124 Nitric oxide and Nitrogen
tetroxide mixture
1975 124 Nitrogen dioxide and Nitric
oxide mixture
1975 124 Nitrogen tetroxide and Nitric
oxide mixture
1994 131 Iron pentacarbonyl 100 m (300 ft) 0.9 km (0.6 mi) 2.1 km (1.3 mi) 400 m (1250 ft) 4.8 km (3.0 mi) 8.3 km (5.2 mi)
2004 135 Magnesium diamide 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 100 m (300 ft) 0.7 km (0.5 mi) 2.4 km (1.5 mi)
2011 139 Magnesium phosphide 60 m (200 ft) 0.2 km (0.1 mi) 0.8 km (0.5 mi) 500 m (1500 ft) 1.8 km (1.1 mi) 6.0 km (3.8 mi)
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2012 139 Potassium phosphide 30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 300 m (1000 ft) 1.2 km (0.8 mi) 4.0 km (2.5 mi)
2013 139 Strontium phosphide 30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 300 m (1000 ft) 1.2 km (0.7 mi) 3.8 km (2.4 mi)
2032 157 Nitric acid, fuming 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 150 m (500 ft) 0.5 km (0.3 mi) 1.1 km (0.7 mi)
2032 157 Nitric acid, red fuming
2186 * 125 Hydrogen chloride, 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 300 m (1000 ft) 2.0 km (1.3 mi) 7.6 km (4.7 mi)
refrigerated liquid
2188 119 Arsine 150 m (500 ft) 1.0 km (0.6 mi) 4.0 km (2.5 mi) 1000 m (3000 ft) 5.8 km (3.6 mi) 11.0+ km (7.0+ mi)
2188 119 SA (when used as a weapon) 300 m (1000 ft) 1.9 km (1.2 mi) 5.7 km (3.6 mi) 1000 m (3000 ft) 8.9 km (5.6 mi) 11.0+ km (7.0+ mi)
2189 119 Dichlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.2 mi) 200 m (600 ft) 1.2 km (0.8 mi) 2.9 km (1.8 mi)
2190 124 Oxygen difluoride 200 m (600 ft) 0.4 km (0.3 mi) 2.1 km (1.3 mi) 1000 m (3000 ft) 2.2 km (1.4 mi) 8.6 km (5.4 mi)
2190 124 Oxygen difluoride, compressed
2191 123 Sulfuryl fluoride 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 300 m (1000 ft) 1.9 km (1.2 mi) 5.1 km (3.2 mi)
2191 123 Sulphuryl fluoride
2192 119 Germane 150 m (500 ft) 0.8 km (0.5 mi) 3.2 km (2.0 mi) 800 m (2500 ft) 4.4 km (2.7 mi) 10.6 km (6.6 mi)
2194 125 Selenium hexafluoride 200 m (600 ft) 1.1 km (0.7 mi) 3.7 km (2.3 mi) 800 m (2500 ft) 5.0 km (3.1 mi) 11.0+ km (7.0+ mi)
2195 125 Tellurium hexafluoride 200 m (600 ft) 1.2 km (0.7 mi) 4.4 km (2.8 mi) 1000 m (3000 ft) 6.7 km (4.2 mi) 11.0+ km (7.0+ mi)
2196 125 Tungsten hexafluoride 30 m (100 ft) 0.2 km (0.1 mi) 0.8 km (0.5 mi) 150 m (500 ft) 0.9 km (0.6 mi) 3.1 km (2.0 mi)
2197 125 Hydrogen iodide, anhydrous 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 150 m (500 ft) 0.9 km (0.6 mi) 2.8 km (1.7 mi)
2198 125 Phosphorus pentafluoride 30 m (100 ft) 0.2 km (0.1 mi) 0.8 km (0.5 mi) 150 m (500 ft) 0.9 km (0.5 mi) 3.3 km (2.0 mi)
2198 125 Phosphorus pentafluoride,
compressed
2199 119 Phosphine 60 m (200 ft) 0.2 km (0.2 mi) 1.0 km (0.7 mi) 400 m (1250 ft) 1.3 km (0.8 mi) 4.1 km (2.5 mi)
2202 117 Hydrogen selenide, anhydrous 200 m (600 ft) 1.1 km (0.7 mi) 4.9 km (3.1 mi) 1000 m (3000 ft) 8.5 km (5.3 mi) 11.0+ km (7.0+ mi)
2204 119 Carbonyl sulfide 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 300 m (1000 ft) 1.3 km (0.8 mi) 3.5 km (2.2 mi)
2204 119 Carbonyl sulphide
2232 153 Chloroacetaldehyde 30 m (100 ft) 0.2 km (0.1 mi) 0.4 km (0.2 mi) 60 m (200 ft) 0.7 km (0.5 mi) 1.3 km (0.8 mi)
2232 153 2-Chloroethanal
2308 157 Nitrosylsulfuric acic 30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.3 mi) 300 m (1000 ft) 0.9 km (0.6 mi) 2.5 km (1.6 mi)
2308 157 Nitrosylsulfuric acic, liquid
2308 157 Nitrosylsulfuric acic, solid
2308 157 Nitrosylsulphuric acic
2308 157 Nitrosylsulphuric acic, liquid
2308 157 Nitrosylsulphuric acic, solid
2334 131 Allylamine 30 m (100 ft) 0.2 km (0.1 mi) 0.6 km (0.4 mi) 150 m (500 ft) 1.5 km (0.9 mi) 2.8 km (1.7 mi)
2337 131 Phenyl mercaptan 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.5 km (0.3 mi)
2353 132 Butyryl chloride 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.4 km (0.2 mi) 1.0 km (0.6 mi)
2382 131 1,2-Dimethylhydrazine 30 m (100 ft) 0.2 km (0.1 mi) 0.4 km (0.2 mi) 60 m (200 ft) 0.8 km (0.5 mi) 1.5 km (1.0 mi)
2382 131 Dimethylhydrazine,
symmetrical
Page 313
"+" means distance can be larger in certain atmospheric conditions * PLEASE ALSO CONSULT TABLE 3 FOR THIS MATERIAL

Page 314
2395 132 Isobutyryl chloride 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.2 km (0.2 mi) 0.6 km (0.4 mi)
2407 155 Isopropyl chloroformate 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.2 mi) 60 m (200 ft) 0.5 km (0.3 mi) 1.0 km (0.6 mi)
2417 125 Carbonyl fluoride 100 m (300 ft) 0.6 km (0.4 mi) 2.3 km (1.4 mi) 600 m (2000 ft) 3.7 km (2.3 mi) 8.0 km (5.0 mi)
2417 125 Carbonyl fluoride, compressed
2418 125 Sulfur tetrafluoride 100 m (300 ft) 0.5 km (0.4 mi) 2.6 km (1.6 mi) 600 m (2000 ft) 3.5 km (2.2 mi) 9.4 km (5.9 mi)
2418 125 Sulphur tetrafluoride
2420 125 Hexafluoroacetone 60 m (200 ft) 0.3 km (0.2 mi) 1.4 km (0.9 mi) 1000 m (3000 ft) 7.6 km (4.7 mi) 11.0+ km (7.0+ mi)
2421 124 Nitrogen trioxide 60 m (200 ft) 0.4 km (0.3 mi) 1.8 km (1.1 mi) 300 m (1000 ft) 1.9 km (1.2 mi) 6.7 km (4.2 mi)
2434 156 Dibenzyldichlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.2 km (0.1 mi) 0.6 km (0.4 mi)
2435 156 Ethylphenyldichlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.4 km (0.2 mi) 1.1 km (0.7 mi)
2437 156 Methylphenyldichlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 30 m (100 ft) 0.4 km (0.3 mi) 1.4 km (0.9 mi)
2438 132 Trimethylacetyl chloride 30 m (100 ft) 0.3 km (0.2 mi) 0.6 km (0.4 mi) 100 m (300 ft) 1.2 km (0.8 mi) 2.1 km (1.3 mi)
2442 156 Trichloroacetyl chloride 30 m (100 ft) 0.2 km (0.1 mi) 0.3 km (0.2 mi) 60 m (200 ft) 0.6 km (0.4 mi) 1.2 km (0.8 mi)
2474 157 Thiophosgene 60 m (200 ft) 0.7 km (0.4 mi) 2.0 km (1.2 mi) 300 m (1000 ft) 2.7 km (1.7 mi) 5.5 km (3.4 mi)
2477 131 Methyl isothiocyanate 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.2 km (0.2 mi) 0.4 km (0.2 mi)
2480 155 Methyl isocyanate 150 m (500 ft) 1.7 km (1.1 mi) 5.8 km (3.6 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)
2481 155 Ethyl isocyanate 150 m (500 ft) 1.8 km (1.2 mi) 5.9 km (3.7 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)
2482 155 n-Propyl isocyanate 100 m (300 ft) 1.1 km (0.7 mi) 2.8 km (1.7 mi) 600 m (2000 ft) 7.8 km (4.9 mi) 11.0+ km (7.0+ mi)
2483 155 Isopropyl isocyanate 100 m (300 ft) 1.2 km (0.8 mi) 3.1 km (1.9 mi) 800 m (2500 ft) 10.1 km (6.3 mi) 11.0+ km (7.0+ mi)
2484 155 tert-Butyl isocyanate 100 m (300 ft) 1.1 km (0.7 mi) 2.7 km (1.7 mi) 600 m (2000 ft) 7.2 km (4.5 mi) 11.0+ km (7.0+ mi)
2485 155 n-Butyl isocyanate 60 m (200 ft) 0.8 km (0.5 mi) 1.7 km (1.1 mi) 300 m (1000 ft) 4.0 km (2.5 mi) 6.7 km (4.2 mi)
2486 155 Isobutyl isocyanate 60 m (200 ft) 0.8 km (0.5 mi) 1.7 km (1.1 mi) 300 m (1000 ft) 4.0 km (2.5 mi) 6.5 km (4.1 mi)
2487 155 Phenyl isocyanate 30 m (100 ft) 0.2 km (0.2 mi) 0.3 km (0.2 mi) 60 m (200 ft) 0.8 km (0.5 mi) 1.2 km (0.8 mi)
2488 155 Cyclohexyl isocyanate 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 0.7 km (0.5 mi)
2495 144 Iodine pentafluoride 30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 150 m (500 ft) 1.2 km (0.8 mi) 4.6 km (2.9 mi)
2521 131P Diketene, stabilized 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.5 km (0.3 mi)
2534 119 Methylchlorosilane 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 100 m (300 ft) 0.7 km (0.4 mi) 1.8 km (1.1 mi)
2548 124 Chlorine pentafluoride 30 m (100 ft) 0.2 km (0.2 mi) 1.2 km (0.7 mi) 300 m (1000 ft) 1.8 km (1.1 mi) 7.3 km (4.6 mi)
2600 119 Carbon monoxide and 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 200 m (600 ft) 1.2 km (0.8 mi) 4.8 km (3.0 mi)
Hydrogen mixture,
compressed
2600 119 Hydrogen and Carbon
monoxide mixture,
compressed
2605 155 Methoxymethyl isocyanate 30 m (100 ft) 0.4 km (0.2 mi) 0.5 km (0.4 mi) 100 m (300 ft) 1.2 km (0.8 mi) 1.8 km (1.2 mi)
2606 155 Methyl orthosilicate 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.2 km (0.1 mi) 0.3 km (0.2 mi)
2644 151 Methyl iodide 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 100 m (300 ft) 0.3 km (0.2 mi) 0.7 km (0.5 mi)
2646 151 Hexachlorocyclopentadiene 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.4 km (0.3 mi)
2668 131 Chloroacetonitrile 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi)
2676 119 Stibine 60 m (200 ft) 0.4 km (0.2 mi) 1.7 km (1.1 mi) 300 m (1000 ft) 1.9 km (1.2 mi) 6.5 km (4.0 mi)
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2691 137 Phosphorus pentabromide 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 1.0 km (0.6 mi)
2692 157 Boron tribromide 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.7 km (0.4 mi)
2692 157 Boron tribromide 30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.3 mi) 60 m (200 ft) 0.8 km (0.5 mi) 2.5 km (1.6 mi)
2740 155 n-Propyl chloroformate 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 60 m (200 ft) 0.6 km (0.4 mi) 1.1 km (0.7 mi)
2742 155 sec-Butyl chloroformate 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 30 m (100 ft) 0.4 km (0.3 mi) 0.6 km (0.4 mi)
2742 155 Isobutyl chloroformate 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.5 km (0.3 mi)
2743 155 n-Butyl chloroformate 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 30 m (100 ft) 0.4 km (0.2 mi) 0.5 km (0.4 mi)
2806 138 Lithium nitride 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 60 m (200 ft) 0.6 km (0.4 mi) 2.1 km (1.3 mi)
2810 153 Buzz 60 m (200 ft) 0.4 km (0.2 mi) 1.7 km (1.1 mi) 400 m (1250 ft) 2.2 km (1.4 mi) 8.1 km (5.0 mi)
2810 153 BZ (when used as a weapon)
2810 153 CS (when used as a weapon) 30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 100 m (300 ft) 0.4 km (0.3 mi) 1.9 km (1.2 mi)
2810 153 DC (when used as a weapon) 30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 60 m (200 ft) 0.4 km (0.3 mi) 1.8 km (1.1 mi)
2810 153 GA (when used as a weapon) 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.1 mi) 100 m (300 ft) 0.5 km (0.4 mi) 0.6 km (0.4 mi)
2810 153 GB (when used as a weapon) 60 m (200 ft) 0.4 km (0.3 mi) 1.1 km (0.7 mi) 400 m (1250 ft) 2.1 km (1.3 mi) 4.9 km (3.0 mi)
2810 153 GD (when used as a weapon) 60 m (200 ft) 0.4 km (0.3 mi) 0.7 km (0.5 mi) 300 m (1000 ft) 1.8 km (1.1 mi) 2.7 km (1.7 mi)
2810 153 GF (when used as a weapon) 30 m (100 ft) 0.2 km (0.2 mi) 0.3 km (0.2 mi) 150 m (500 ft) 0.8 km (0.5 mi) 1.0 km (0.6 mi)
2810 153 H (when used as a weapon) 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 60 m (200 ft) 0.3 km (0.2 mi) 0.4 km (0.3 mi)
2810 153 HD (when used as a weapon)
2810 153 HL (when used as a weapon) 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 100 m (300 ft) 0.5 km (0.3 mi) 1.0 km (0.6 mi)
2810 153 HN-1 60 m (200 ft) 0.3 km (0.2 mi) 0.5 km (0.3 mi) 200 m (600 ft) 1.1 km (0.7 mi) 1.8 km (1.1 mi)
2810 153 L (Lewisite)
2810 153 Lewisite 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 100 m (300 ft) 0.5 km (0.3 mi) 1.0 km (0.6 mi)
2810 153 Mustard 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 60 m (200 ft) 0.3 km (0.2 mi) 0.4 km (0.3 mi)
2810 153 Mustard Lewisite 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 100 m (300 ft) 0.5 km (0.3 mi) 1.0 km (0.6 mi)
2810 153 Poisonous liquid, n.o.s. 60 m (200 ft) 0.4 km (0.3 mi) 1.3 km (0.8 mi) 200 m (600 ft) 2.3 km (1.4 mi) 5.1 km (3.2 mi)
2810 153 Poisonous liquid, n.o.s.
2810 153 Poisonous liquid, n.o.s. 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 0.7 km (0.5 mi)
2810 153 Poisonous liquid, organic, n.o.s. 30 m (100 ft) 0.3 km (0.2 mi) 1.1 km (0.7 mi) 300 m (1000 ft) 1.8 km (1.1 mi) 4.5 km (2.8 mi)
2810 153 Poisonous liquid, organic, n.o.s.
2810 153 Poisonous liquid, organic, n.o.s. 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 0.7 km (0.5 mi)
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2810 153 Sarin 60 m (200 ft) 0.4 km (0.3 mi) 1.1 km (0.7 mi) 400 m (1250 ft) 2.1 km (1.3 mi) 4.9 km (3.0 mi)
2810 153 Soman
2810 153 Tabun 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.1 mi) 100 m (300 ft) 0.5 km (0.4 mi) 0.6 km (0.4 mi)
2810 153 Thickened GD 60 m (200 ft) 0.4 km (0.3 mI) 0.7 km (0.5 mi) 300 m (1000 ft) 1.8 km (1.1 mi) 2.7 km (1.7 mi)
2810 153 Toxic liquid, n.o.s. 60 m (200 ft) 0.4 km (0.3 mi) 1.3 km (0.8 mi) 200 m (600 ft) 2.3 km (1.4 mi) 5.1 km (3.2 mi)
2810 153 Toxic liquid, n.o.s.
2810 153 Toxic liquid, n.o.s. 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 0.7 km (0.5 mi)
2810 153 Toxic liquid, organic, n.o.s. 30 m (100 ft) 0.3 km (0.2mi) 1.1 km (0.7 mi) 300 m (1000 ft) 1.8 km (1.1 mi) 4.5 km (2.8 mi)
2810 153 Toxic liquid, organic, n.o.s.
2810 153 Toxic liquid, organic, n.o.s. 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 0.7 km (0.5 mi)
2810 153 VX (when used as a weapon) 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 60 m (200 ft) 0.4 km (0.2 mi) 0.3 km (0.2 mi)
2811 154 CX (when used as a weapon) 60 m (200 ft) 0.2 km (0.2 mi) 1.1 km (0.7 mi) 200 m (600 ft) 1.2 km (0.7 mi) 5.1 km (3.2 mi)
2826 155 Ethyl chlorothioformate 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 30 m (100 ft) 0.4 km (0.3 mi) 0.7 km (0.4 mi)
2845 135 Ethyl phosphonous dichloride, 30 m (100 ft) 0.3 km (0.2 mi) 0.8 km (0.5 mi) 150 m (500 ft) 1.5 km (0.9 mi) 2.8 km (1.7 mi)
anhydrous
2845 135 Methyl phosphonous dichloride 30 m (100 ft) 0.4 km (0.3 mi) 1.2 km (0.8 mi) 200 m (600 ft) 2.3 km (1.4 mi) 4.3 km (2.7 mi)
2901 124 Bromine chloride 60 m (200 ft) 0.3 km (0.2 mi) 1.1 km (0.7 mi) 400 m (1250 ft) 2.5 km (1.5 mi) 6.7 km (4.2 mi)
2927 154 Ethyl phosphonothioic 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.1 mi)
dichloride, anhydrous
2927 154 Ethyl phosphorodichloridate 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.1 mi)
2927 154 Poisonous liquid, 60 m (200 ft) 0.4 km (0.2 mi) 0.9 km (0.6 mi) 200 m (600 ft) 1.5 km (1.0 mi) 3.0 km (1.9 mi)
corrosive, n.o.s.
2927 154 Poisonous liquid,
corrosive, n.o.s.
corrosive, n.o.s.
2927 154 Poisonous liquid, corrosive, 60 m (200 ft) 0.3 km (0.2 mi) 0.8 km (0.5 mi) 300 m (1000 ft) 1.5 km (1.0 mi) 3.0 km (1.9 mi)
organic, n.o.s.
corrosive, organic, n.o.s.
corrosive, organic, n.o.s.
2927 154 Toxic liquid, corrosive, n.o.s. 60 m (200 ft) 0.4 km (0.2 mi) 0.9 km (0.6 mi) 200 m (600 ft) 1.5 km (1.0 mi) 3.0 km (1.9 mi)
2927 154 Toxic liquid, corrosive, n.o.s.
2927 154 Toxic liquid, corrosive, n.o.s. 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.1 mi) 30 m (100 ft) 0.4 km (0.3 mi) 0.7 km (0.4 mi)
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2927 154 Toxic liquid, corrosive, 60 m (200 ft) 0.3 km (0.2 mi) 0.8 km (0.5 mi) 300 m (1000 ft) 1.5 km (1.0 mi) 3.0 km (1.9 mi)
organic, n.o.s.
2927 154 Toxic liquid, corrosive,
organic, n.o.s.
organic, n.o.s.
flammable, n.o.s.
flammable, n.o.s.
flammable, n.o.s.
flammable, organic, n.o.s.
2929 131 Toxic liquid, flammable, n.o.s. 60 m (200 ft) 0.8 km (0.5 mi) 1.7 km (1.1 mi) 300 m (1000 ft) 4.0 km (2.5 mi) 6.5 km (4.1 mi)
2929 131 Toxic liquid, flammable, n.o.s.
2929 131 Toxic liquid, flammable, n.o.s. 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 0.7 km (0.5 mi)
2929 131 Toxic liquid, flammable, 30 m (100 ft) 0.4 km (0.3 mi) 1.2 km (0.8 mi) 200 m (600 ft) 2.2 km (1.4 mi) 4.6 km (2.9 mi)
organic, n.o.s.
2929 131 Toxic liquid, flammable,
organic, n.o.s.
2929 131 Toxic liquid, flammable, 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 0.7 km (0.5 mi)
organic, n.o.s.
2977 166 Radioactive material, 30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.3 mi) 60 m (200 ft) 0.5 km (0.3 mi) 2.4 km (1.5 mi)
Uranium hexafluoride, fissile
2977 166 Uranium hexafluoride,
fissile containing more
than 1% Uranium-235
2978 166 Radioactive material, 30 m (100 ft) 0.1 km (0.1 mi) 0.4 km (0.3 mi) 60 m (200 ft) 0.5 km (0.3 mi) 2.3 km (1.5 mi)
Uranium hexafluoride
2978 166 Uranium hexafluoride
2978 166 Uranium hexafluoride,
non-fissile or fissile-excepted
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2985 155 Chlorosilanes, flammable, 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 1.6 km (1.0 mi)
corrosive, n.o.s.
2985 155 Chlorosilanes, n.o.s.
2986 155 Chlorosilanes, corrosive, 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 1.6 km (1.0 mi)
flammable, n.o.s.
2987 156 Chlorosilanes, corrosive, n.o.s. 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 1.6 km (1.0 mi)
2988 139 Chlorosilanes, n.o.s. 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 1.6 km (1.0 mi)
2988 139 Chlorosilanes, water-reactive,
3023 131 2-Methyl-2-heptanethiol 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.2 mi) 60 m (200 ft) 0.5 km (0.3 mi) 0.9 km (0.5 mi)
3023 131 tert-Octyl mercaptan
3048 157 Aluminum phosphide pesticide 60 m (200 ft) 0.2 km (0.2 mi) 0.9 km (0.6 mi) 500 m (1500 ft) 2.1 km (1.3 mi) 7.4 km (4.6 mi)
3049 138 Metal alkyl halides, 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.4 km (0.3 mi) 1.3 km (0.8 mi)
water-reactive, n.o.s.
3049 138 Metal aryl halides,
3052 135 Aluminum alkyl halides 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.4 km (0.3 mi) 1.3 km (0.8 mi)
3052 135 Aluminum alkyl halides, liquid
3052 135 Aluminum alkyl halides, solid
3057 125 Trifluoroacetyl chloride 30 m (100 ft) 0.2 km (0.1 mi) 1.0 km (0.6 mi) 800 m (2500 ft) 4.2 km (2.7 mi) 11.0+ km (7.0+ mi)
3079 131P Methacrylonitrile, stabilized 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.4 km (0.3 mi) 0.8 km (0.5 mi)
3083 124 Perchloryl fluoride 30 m (100 ft) 0.1 km (0.1 mi) 0.6 km (0.4 mi) 400 m (1250 ft) 2.5 km (1.6 mi) 7.7 km (4.8 mi)
3122 142 Poisonous liquid, oxidizing, 30 m (100 ft) 0.4 km (0.2 mi) 1.4 km (0.9 mi) 200 m (600 ft) 2.3 km (1.4 mi) 5.1 km (3.2 mi)
n.o.s.
oxidizing, n.o.s.
oxidizing, n.o.s.
3122 142 Toxic liquid, oxidizing, n.o.s. 30 m (100 ft) 0.4 km (0.2 mi) 1.4 km (0.9 mi) 200 m (600 ft) 2.3 km (1.4 mi) 5.1 km (3.2 mi)
3122 142 Toxic liquid, oxidizing, n.o.s.
3122 142 Toxic liquid, oxidizing, n.o.s. 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mi) 60 m (200 ft) 0.5 km (0.4 mi) 1.0 km (0.6 mi)
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3123 139 Poisonous liquid, which in 60 m (200 ft) 0.4 km (0.3 mi) 1.3 km (0.8 mi) 200 m (600 ft) 2.3 km (1.4 mi) 5.1 km (3.2 mi)
3123 139 Poisonous liquid, which in 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 0.7 km (0.5 mi)
3123 139 Poisonous liquid, which in
3123 139 Toxic liquid, 60 m (200 ft) 0.4 km (0.3 mi) 1.3 km (0.8 mi) 200 m (600 ft) 2.3 km (1.4 mi) 5.1 km (3.2 mi)
3123 139 Toxic liquid,
3123 139 Toxic liquid, 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 0.7 km (0.5 mi)
3123 139 Toxic liquid, which in contact 60 m (200 ft) 0.4 km (0.3 mi) 1.3 km (0.8 mi) 200 m (600 ft) 2.3 km (1.4 mi) 5.1 km (3.2 mi)
with water emits flammable
gases, n.o.s.
3123 139 Toxic liquid, which in
3123 139 Toxic liquid, which in 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 0.7 km (0.5 mi)
3160 119 Liquefied gas, poisonous, 100 m (300 ft) 0.5 km (0.3 mi) 2.2 km (1.4 mi) 600 m (2000 ft) 2.6 km (1.7 mi) 8.6 km (5.4 mi)
flammable, n.o.s.
flammable, n.o.s.
flammable, n.o.s.
flammable, n.o.s.
flammable, n.o.s.
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3160 119 Liquefied gas, toxic, 100 m (300 ft) 0.5 km (0.3 mi) 2.2 km (1.4 mi) 600 m (2000 ft) 2.6 km (1.7 mi) 8.6 km (5.4 mi)
flammable, n.o.s.
3160 119 Liquefied gas, toxic,
flammable, n.o.s.
flammable, n.o.s.
flammable, n.o.s.
flammable, n.o.s.
3162 123 Liquefied gas, poisonous, n.o.s. 100 m (300 ft) 0.5 km (0.3 mi) 2.2 km (1.4 mi) 600 m (2000 ft) 3.5 km (2.2 mi) 9.4 km (5.9 mi)
3162 123 Liquefied gas, poisonous, n.o.s.
3162 123 Liquefied gas, toxic, n.o.s. 100 m (300 ft) 0.5 km (0.3 mi) 2.2 km (1.4 mi) 600 m (2000 ft) 3.5 km (2.2 mi) 9.4 km (5.9 mi)
3162 123 Liquefied gas, toxic, n.o.s.
3246 156 Methanesulfonyl chloride 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.2 km (0.1 mi) 0.3 km (0.2 mi)
3246 156 Methanesulphonyl chloride
3275 131 Nitriles, poisonous, 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.4 km (0.3 mi) 0.8 km (0.5 mi)
flammable, n.o.s.
3275 131 Nitriles, toxic,
flammable, n.o.s.
3276 151 Nitriles, liquid, poisonous, n.o.s. 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.4 km (0.3 mi) 0.8 km (0.5 mi)
3276 151 Nitriles, liquid, toxic, n.o.s.
3276 151 Nitriles, poisonous, liquid, n.o.s.
3276 151 Nitriles, poisonous, n.o.s.
3276 151 Nitriles, toxic, liquid, n.o.s.
3276 151 Nitriles, toxic, n.o.s.
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3278 151 Organophosphorus compound, 30 m (100 ft) 0.4 km (0.3 mi) 1.2 km (0.8 mi) 200 m (600 ft) 2.3 km (1.4 mi) 4.3 km (2.7 mi)
liquid, poisonous, n.o.s.
liquid, toxic, n.o.s.
poisonous, liquid, n.o.s.
poisonous, n.o.s.
toxic, liquid, n.o.s.
toxic, n.o.s.
poisonous, flammable, n.o.s.
toxic, flammable, n.o.s.
3280 151 Organoarsenic compound, 30 m (100 ft) 0.2 km (0.1 mi) 0.8 km (0.5 mi) 150 m (500 ft) 1.8 km (1.1 mi) 4.5 km (2.8 mi)
liquid, n.o.s.
3280 151 Organoarsenic compound,
n.o.s.
3281 151 Metal carbonyls, liquid, n.o.s. 100 m (300 ft) 1.4 km (0.9 mi) 5.4 km (3.4 mi) 1000 m (3000 ft) 11.0+ km (7.0+ mi) 11.0+ km (7.0+ mi)
3281 151 Metal carbonyls, n.o.s.
3287 151 Poisonous liquid, inorganic, 60 m (200 ft) 0.6 km (0.4 mi) 2.0 km (1.2 mi) 300 m (1000 ft) 2.8 km (1.8 mi) 6.5 km (4.0 mi)
n.o.s.
inorganic, n.o.s.
inorganic, n.o.s.
3287 151 Toxic liquid, inorganic, n.o.s. 60 m (200 ft) 0.6 km (0.4 mi) 2.0 km (1.2 mi) 300 m (1000 ft) 2.8 km (1.8 mi) 6.5 km (4.0 mi)
3287 151 Toxic liquid, inorganic, n.o.s.
3287 151 Toxic liquid, inorganic, n.o.s. 30 m (100 ft) 0.2 km (0.1 mi) 0.3 km (0.2 mi) 100 m (300 ft) 1.0 km (0.6 mi) 1.6 km (1.0 mi)
inorganic, n.o.s.
3289 154 Poisonous liquid, corrosive,
inorganic, n.o.s.
inorganic, n.o.s.
inorganic, n.o.s.
3289 154 Toxic liquid, corrosive,
inorganic, n.o.s.
inorganic, n.o.s.
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3294 131 Hydrogen cyanide, solution in 60 m (200 ft) 0.2 km (0.1 mi) 0.4 km (0.2 mi) 200 m (600 ft) 0.7 km (0.4 mi) 2.0 km (1.2 mi)
alcohol, with not more than
3300 119P Carbon dioxide and Ethylene 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 150 m (500 ft) 0.9 km (0.5 mi) 2.0 km (1.3 mi)
oxide mixture, with more than
87% Ethylene oxide
3300 119P Ethylene oxide and Carbon
dioxide mixture, with more
poisonous, oxidizing, n.o.s.
toxic, oxidizing, n.o.s.
poisonous, corrosive, n.o.s.
Page 331


Page 332
toxic, corrosive, n.o.s.
oxidizing, corrosive, n.o.s.
Page 333


Page 334
oxidizing, n.o.s.
oxidizing, n.o.s.
oxidizing, n.o.s.
oxidizing, n.o.s.
oxidizing, n.o.s.
3307 124 Liquefied gas, toxic, oxidizing, 60 m (200 ft) 0.4 km (0.3 mi) 2.1 km (1.3 mi) 600 m (2000 ft) 2.6 km (1.7 mi) 8.6 km (5.4 mi)
n.o.s.
oxidizing, n.o.s.
oxidizing, n.o.s.
oxidizing, n.o.s.
oxidizing, n.o.s.
corrosive, n.o.s.
corrosive, n.o.s.
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Page 336
corrosive, n.o.s.
corrosive, n.o.s.
corrosive, n.o.s.
3308 123 Liquefied gas, toxic, corrosive, 100 m (300 ft) 0.5 km (0.4 mi) 2.6 km (1.6 mi) 600 m (2000 ft) 3.5 km (2.2 mi) 9.4 km (5.9 mi)
n.o.s.
corrosive, n.o.s.
corrosive, n.o.s.
corrosive, n.o.s.
corrosive, n.o.s.
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Page 338
3310 124 Liquefied gas, poisonous, 30 m (100 ft) 0.1 km (0.1 mi) 0.3 km (0.2 mI) 200 m (600 ft) 0.9 km (0.6 mi) 2.8 km (1.7 mi)
3318 125 Ammonia solution, with more 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 150 m (500 ft) 0.8 km (0.5 mi) 2.0 km (1.3 mi)
than 50% Ammonia
flammable, n.o.s.
3355 119 Insecticide gas, poisonous,
flammable, n.o.s.
flammable, n.o.s.
flammable, n.o.s.
flammable, n.o.s.
3355 119 Insecticide gas, toxic, 100 m (300 ft) 0.5 km (0.3 mi) 2.2 km (1.4 mi) 600 m (2000 ft) 2.6 km (1.7 mi) 8.6 km (5.4 mi)
flammable, n.o.s.
3355 119 Insecticide gas, toxic,
flammable, n.o.s.
flammable, n.o.s.
Page 339


Page 340
flammable, n.o.s.
flammable, n.o.s.
3361 156 Chlorosilanes, poisonous, 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 1.6 km (1.0 mi)
corrosive, n.o.s.
3361 156 Chlorosilanes, toxic, corrosive,
n.o.s. (when spilled in water)
3362 155 Chlorosilanes, poisonous, 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 1.6 km (1.0 mi)
corrosive, flammable, n.o.s.
3362 155 Chlorosilanes, toxic,
3381 151 Poisonous by inhalation 60 m (200 ft) 0.4 km (0.3 mi) 1.3 km (0.8 mi) 200 m (600 ft) 2.3 km (1.4 mi) 5.1 km (3.2 mi)
liquid, n.o.s.
3381 151 Toxic by inhalation liquid, n.o.s.
liquid, n.o.s.
3382 151 Toxic by inhalation liquid, n.o.s.
liquid, flammable, n.o.s.
3383 131 Toxic by inhalation liquid,
flammable, n.o.s.
liquid, flammable, n.o.s.
flammable, n.o.s.
liquid, water-reactive, n.o.s.
liquid, water-reactive, n.o.s.
Page 341


Page 342
liquid, oxidizing, n.o.s.
3387 142 Toxic by inhalation
liquid, corrosive, n.o.s.
3456 157 Nitrosylsulfuric acid, solid 30 m (100 ft) 0.1 km (0.1 mi) 0.5 km (0.3 mi) 200 m (600 ft) 0.7 km (0.5 mi) 2.5 km (1.6 mi)
3456 157 Nitrosylsulphuric acid, solid
3461 135 Aluminum alkyl halides, solid 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.4 km (0.3 mi) 1.3 km (0.8 mi)
3488 131 Poisonous by inhalation liquid, 60 m (200 ft) 0.8 km (0.5 mi) 1.7 km (1.1 mi) 300 m (1000 ft) 4.0 km (2.5 mi) 6.5 km (4.1 mi)
water-reactive, flammable,
n.o.s. (Inhalation Hazard
Zone A)
3490 155 Toxic by inhalation liquid, water
reactive, flammable, n.o.s.
water-reactive, flammable,
n.o.s. (Inhalation Hazard
Zone B)
3491 155 Toxic by inhalation liquid, water
reactive, flammable, n.o.s.
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Page 344
3494 131 Petroleum sour crude oil, 30 m (100 ft) 0.2 km (0.1 mi) 0.2 km (0.1 mi) 60 m (200 ft) 0.5 km (0.3 mi) 0.7 km (0.5 mi)
flammable, toxic
9191 143 Chlorine dioxide, 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.2 km (0.2 mi) 0.6 km (0.4 mi)
hydrate, frozen
9202 168 Carbon monoxide, refrigerated 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 200 m (600 ft) 1.2 km (0.8 mi) 4.8 km (3.0 mi)
liquid (cryogenic liquid)
9206 137 Methyl phosphonic dichloride 30 m (100 ft) 0.1 km (0.1 mi) 0.2 km (0.1 mi) 30 m (100 ft) 0.4 km (0.3 mi) 0.6 km (0.4 mi)
9263 156 Chloropivaloyl chloride 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.3 km (0.2 mi)
9264 151 3,5-Dichloro-2,4,6- 30 m (100 ft) 0.1 km (0.1 mi) 0.1 km (0.1 mi) 30 m (100 ft) 0.3 km (0.2 mi) 0.3 km (0.2 mi)
trifluoropyridine
9269 132 Trimethoxysilane 30 m (100 ft) 0.2 km (0.1 mi) 0.5 km (0.3 mi) 100 m (300 ft) 0.9 km (0.6 mi) 1.9 km (1.2 mi)
See Next Page for Table of Water-Reactive Materials Which Produce Toxic Gases
Page 345

TABLE 2 - WATER-REACTIVE MATERIALS WHICH PRODUCE TOXIC GASES
HOW TO USE TABLE 2 – WATER-REACTIVE MATERIALS Materials Which Produce Large Amounts of Toxic-by-Inhalation (TIH) Gas(es)
When Spilled in Water
WHICH PRODUCE TOXIC GASES
ID Guide TIH Gas(es)
Table 2 lists materials which produce large amounts of Toxic Inhalation Hazard (TIH) gases when No. No. Name of Material Produced
spilled in water and identifies the TIH gases produced.
1162 155 Dimethyldichlorosilane HCl
The materials are listed by ID number order.
1183 139 Ethyldichlorosilane HCl
These Water Reactive materials are easily identified in Table 1 as their name is immediately 1196 155 Ethyltrichlorosilane HCl
followed by (when spilled in water). 1242 139 Methyldichlorosilane HCl
Note : Some Water Reactive materials are also TIH materials themselves (e.g., Bromine 1250 155 Methyltrichlorosilane HCl
trifluoride (1746), Thionyl chloride (1836), etc.). In these instances, two entries are 1295 139 Trichlorosilane HCl
provided in Table 1 for land-based and water-based spills. If the Water Reactive 1298 155 Trimethylchlorosilane HCl
material is NOT a TIH and this material is NOT spilled in water, Table 1 and Table 2 do not 1305 155P Vinyltrichlorosilane HCl
apply and safety distances will be found within the appropriate orange guide. 1305 155P Vinyltrichlorosilane, stabilized HCl
1340 139 Phosphorus pentasulfide, free from yellow and white Phosphorus H2S
1340 139 Phosphorus pentasulphide, free from yellow and white Phosphorus H2S
1360 139 Calcium phosphide PH3
1384 135 Sodium dithionite H2S SO2
1384 135 Sodium hydrosulfite H2S SO2
1384 135 Sodium hydrosulphite H2S SO2
1397 139 Aluminum phosphide PH3
1419 139 Magnesium aluminum phosphide PH3
1432 139 Sodium phosphide PH3
1541 155 Acetone cyanohydrin, stabilized HCN
1680 157 Potassium cyanide HCN
1680 157 Potassium cyanide, solid HCN
1689 157 Sodium cyanide HCN
1689 157 Sodium cyanide, solid HCN
Chemical Symbols for TIH Gases:

Br2 Bromine HF Hydrogen fluoride NO2 Nitrogen dioxide
Cl2 Chlorine HI Hydrogen iodide PH3 Phosphine
Hbr Hydrogen bromide H2S Hydrogen sulfide SO2 Sulfur dioxide
Hcl Hydrogen chloride H2S Hydrogen sulphide So2 Sulphur dioxide
HCN Hydrogen cyanide NH3 Ammonia
Page 346 Use this list only when material is spilled in water. Page 347
TABLE 2 - WATER-REACTIVE MATERIALS WHICH PRODUCE TOXIC GASES TABLE 2 - WATER-REACTIVE MATERIALS WHICH PRODUCE TOXIC GASES
Materials Which Produce Large Amounts of Toxic-by-Inhalation (TIH) Gas(es) Materials Which Produce Large Amounts of Toxic-by-Inhalation (TIH) Gas(es)
When Spilled in Water When Spilled in Water
ID Guide TIH Gas(es) ID Guide TIH Gas(es)

No. No. Name of Material Produced No. No. Name of Material Produced
1716 156 Acetyl bromide HBr 1766 156 Dichlorophenyltrichlorosilane HCl

1717 155 Acetyl chloride HCl 1767 155 Diethyldichlorosilane HCl
1724 155 Allyltrichlorosilane, stabilized HCl 1769 156 Diphenyldichlorosilane Hcl
1725 137 Aluminum bromide, anhydrous HBr 1771 156 Dodecyltrichlorosilane HCl
1726 137 Aluminum chloride, anhydrous HCl 1777 137 Fluorosulfonic acid HF
1728 155 Amyltrichlorosilane HCl 1777 137 Fluorosulphonic acid HF
1732 157 Antimony pentafluoride HF 1781 156 Hexadecyltrichlorosilane HCl
1741 125 Boron trichloride HCl 1784 156 Hexyltrichlorosilane HCl
1745 144 Bromine pentafluoride HF Br2 1799 156 Nonyltrichlorosilane HCl
1746 144 Bromine trifluoride HF Br2 1800 156 Octadecyltrichlorosilane HCl
1747 155 Butyltrichlorosilane HCl 1801 156 Octyltrichlorosilane HCl
1752 156 Chloroacetyl chloride HCl 1804 156 Phenyltrichlorosilane HCl
1753 156 Chlorophenyltrichlorosilane HCl 1806 137 Phosphorus pentachloride HCl
1754 137 Chlorosulfonic acid HCl 1808 137 Phosphorus tribromide HBr
1754 137 Chlorosulfonic acid and Sulfur trioxide mixture HCl 1809 137 Phosphorus trichloride HCl
1754 137 Chlorosulphonic acid HCl 1810 137 Phosphorus oxychloride HCl
1754 137 Chlorosulphonic acid and Sulphur trioxide mixture HCl 1815 132 Propionyl chloride HCl
1754 137 Sulfur trioxide and Chlorosulfonic acid HCl 1816 155 Propyltrichlorosilane HCl
1754 137 Sulphur trioxide and Chlorosulphonic acid HCl 1818 157 Silicon tetrachloride HCl
1758 137 Chromium oxychloride HCl 1828 137 Sulfur chlorides HCl SO2 H2S
1762 156 Cyclohexenyltrichlorosilane HCl 1828 137 Sulphur chlorides HCl SO2 H2S
1763 156 Cyclohexyltrichlorosilane HCl 1834 137 Sulfuryl chloride HCl
1765 156 Dichloroacetyl chloride HCl 1834 137 Sulphuryl chloride HCl
Chemical Symbols for TIH Gases: Chemical Symbols for TIH Gases:
Br2 Bromine HF Hydrogen fluoride NO2 Nitrogen dioxide Br2 Bromine HF Hydrogen fluoride NO2 Nitrogen dioxide
Cl2 Chlorine HI Hydrogen iodide PH3 Phosphine Cl2 Chlorine HI Hydrogen iodide PH3 Phosphine
Hbr Hydrogen bromide H2S Hydrogen sulfide SO2 Sulfur dioxide Hbr Hydrogen bromide H2S Hydrogen sulfide SO2 Sulfur dioxide
Hcl Hydrogen chloride H2S Hydrogen sulphide So2 Sulphur dioxide Hcl Hydrogen chloride H2S Hydrogen sulphide So2 Sulphur dioxide
HCN Hydrogen cyanide NH3 Ammonia HCN Hydrogen cyanide NH3 Ammonia
Page 348 Use this list only when material is spilled in water. Use this list only when material is spilled in water. Page 349
TABLE 2 - WATER-REACTIVE MATERIALS WHICH PRODUCE TOXIC GASES TABLE 2 - WATER-REACTIVE MATERIALS WHICH PRODUCE TOXIC GASES
Materials Which Produce Large Amounts of Toxic-by-Inhalation (TIH) Gas(es) Materials Which Produce Large Amounts of Toxic-by-Inhalation (TIH) Gas(es)
When Spilled in Water When Spilled in Water
ID Guide TIH Gas(es) ID Guide TIH Gas(es)

No. No. Name of Material Produced No. No. Name of Material Produced
1836 137 Thionyl chloride HCl SO2 2395 132 Isobutyryl chloride HCl
1838 137 Titanium tetrachloride HCl 2434 156 Dibenzyldichlorosilane Hcl
1898 156 Acetyl iodide HI 2435 156 Ethylphenyldichlorosilane HCl
1923 135 Calcium dithionite H2S SO2 2437 156 Methylphenyldichlorosilane HCI
1923 135 Calcium hydrosulfite H2S SO2 2495 144 Iodine pentafluoride HF
1923 135 Calcium hydrosulphite H2S SO2 2691 137 Phosphorus pentabromide HBr
1929 135 Potassium dithionite H2S SO2 2692 157 Boron tribromide HBr
1929 135 Potassium hydrosulfite H2S SO2 2806 138 Lithium nitride NH3
1929 135 Potassium hydrosulphite H2S SO2 2977 166 Radioactive material, Uranium hexafluoride, fissile HF
1931 171 Zinc dithionite H2S SO2 2977 166 Uranium hexafluoride, fissile containing more than 1% HF
Uranium-235
1931 171 Zinc hydrosulfite H2S SO2 2978 166 Radioactive material, Uranium hexafluoride HF
1931 171 Zinc hydrosulphite H2S SO2 2978 166 Uranium hexafluoride HF
2004 135 Magnesium diamide NH3 2978 166 Uranium hexafluoride, non fissile or fissile-excepted HF
2011 139 Magnesium phosphide PH3 2985 155 Chlorosilanes, flammable, corrosive, n.o.s HCl
2012 139 Potassium phosphide PH3 2985 155 Chlorosilanes, n.o.s HCl
2013 139 Strontium phosphide PH3 2986 155 Chlorosilanes, corrosive, flammable, n.o.s HCl
2308 157 Nitrosylsulfuric acid NO2 2986 155 Chlorosilanes, n.o.s HCl
2308 157 Nitrosylsulfuric acid, liquid NO2 2987 156 Chlorosilanes, corrosive, n.o.s HCl
2308 157 Nitrosylsulfuric acid, solid NO2 2987 156 Chlorosilanes, n.o.s HCl
2308 157 Nitrosylsulphuric acid NO2 2988 139 Chlorosilanes, n.o.s HCl
2308 157 Nitrosylsulphuric acid, liquid NO2 2988 139 Chlorosilanes, water-reactive, flammable, corrosive, n.o.s. HCl
2308 157 Nitrosylsulphuric acid, solid NO2 3048 157 Aluminum phosphide pesticide PH3
2353 132 Butyryl chloride HCl
Chemical Symbols for TIH Gases: Chemical Symbols for TIH Gases:
Br2 Bromine HF Hydrogen fluoride NO2 Nitrogen dioxide Br2 Bromine HF Hydrogen fluoride NO2 Nitrogen dioxide
Cl2 Chlorine HI Hydrogen iodide PH3 Phosphine Cl2 Chlorine HI Hydrogen iodide PH3 Phosphine
Hbr Hydrogen bromide H2S Hydrogen sulfide SO2 Sulfur dioxide Hbr Hydrogen bromide H2S Hydrogen sulfide SO2 Sulfur dioxide
Hcl Hydrogen chloride H2S Hydrogen sulphide So2 Sulphur dioxide Hcl Hydrogen chloride H2S Hydrogen sulphide So2 Sulphur dioxide
HCN Hydrogen cyanide NH3 Ammonia HCN Hydrogen cyanide NH3 Ammonia
Page 350 Use this list only when material is spilled in water. Use this list only when material is spilled in water. Page 351
TABLE 2 - WATER-REACTIVE MATERIALS WHICH PRODUCE TOXIC GASES
Materials Which Produce Large Amounts of Toxic-by-Inhalation (TIH) Gas(es)

When Spilled in Water
ID Guide TIH Gas(es)

NOTES
No. No. Name of Material Produced
3049 138 Metal alkyl halides, water-reactive, n.o.s HCl

3049 138 Metal aryl halides, water-reactive, n.o.s HCl
3052 135 Aluminum alkyl halide HCl
3052 135 Aluminum alkyl halides, liquid HCl
3052 135 Aluminum alkyl halides, solid HCl
3361 156 Chlorosilanes, poisonous, corrosive, n.o.s. HCl
3361 156 Chlorosilanes, toxic, corrosive, n.o.s. HCl
3362 155 Chlorosilanes, poisonous, corrosive, flammable, n.o.s. HCl
3362 155 Chlorosilanes, toxic, corrosive, flammable, n.o.s. HCl
3456 157 Nitrosylsulfuric acid, solid NO2
3456 157 Nitrosylsulphuric acid, solid NO2
3461 135 Aluminum alkyl halides, solid HCl
9191 143 Chlorine dioxide, hydrate, frozen Cl2
Chemical Symbols for TIH Gases:

Br2 Bromine HF Hydrogen fluoride NO2 Nitrogen dioxide
Cl2 Chlorine HI Hydrogen iodide PH3 Phosphine
Hbr Hydrogen bromide H2S Hydrogen sulfide SO2 Sulfur dioxide
Hcl Hydrogen chloride H2S Hydrogen sulphide So2 Sulphur dioxide
HCN Hydrogen cyanide NH3 Ammonia
Page 352 Use this list only when material is spilled in water. Page 353
•
•
•
•
•
•
Page 354
speeds.
The selected materials are:
Chlorine (UN1017)
Ammonia (UN1005)
Ethylene oxide (UN1040)
Hydrogen fluoride (UN1052)

Sulfur dioxide/Sulphur dioxide (UN1079)
Table 3 lists Toxic Inhalation Hazard materials that may be more commonly encountered.
Hydrogen chloride (UN1050) and Hydrogen chloride, refrigerated liquid (UN2186)

DISTANCES FOR DIFFERENT QUANTITIES OF SIX COMMON TIH GASES
HOW TO USE TABLE 3 – INITIAL ISOLATION AND PROTECTIVE ACTION
(therefore different volume capacities) for day time and night time situations and different wind
Action Distances for large spills (more than 208 liters) involving different container types
The materials are presented in alphabetical order and provide Initial Isolation and Protective
TABLE 3 - INITIAL ISOLATION AND PROTECTIVE ACTION DISTANCES FOR DIFFERENT QUANTITIES
OF SIX COMMON TIH GASES
UN1005 Ammonia, anhydrous: Large Spills
First Then PROTECT persons Downwind during

TRANSPORT ISOLATE
CONTAINER in all DAY NIGHT
Directions Low wind Moderate wind High wind Low wind Moderate wind High wind
(< 6 mph = (6-12 mph = (> 12 mph = (< 6 mph = (6-12 mph = (> 12 mph =
< 10 km/h) 10 - 20 km/h) > 20 km/h) < 10 km/h) 10 - 20 km/h) > 20 km/h)
Meters (Feet) Km (Miles) Km (Miles) Km (Miles) Km (Miles) Km (Miles) Km (Miles)
Rail tank car 300 (1000) 2.3 (1.4) 1.3 (0.8) 1.0 (0.6) 6.3 (3.9) 2.6 (1.6) 1.3 (0.8)
Highway tank truck 125 (400) 1.0 (0.6) 0.5 (0.3) 0.3 (0.2) 2.6 (1.6) 0.8 (0.5) 0.5 (0.3)
or trailer
Agricultural nurse tank 60 (200) 0.6 (0.4) 0.3 (0.2) 0.3 (0.2) 1.5 (0.9) 0.5 (0.3) 0.3 (0.2)
Multiple small cylinders 30 (100) 0.3 (0.2) 0.2 (0.1) 0.2 (0.1) 0.8 (0.5) 0.3 (0.2) 0.2 (0.1)
TRANSPORT
CONTAINER UN1017 Chlorine: Large Spills
Rail tank car 1000 (3000) 11+ (7+) 9.0 (5.6) 5.5 (3.4) 11+ (7+) 11+ (7+) 7.1 (4.4)
Highway tank truck 1000 (3000) 10.6 (6.6) 3.5 (2.2) 2.9 (1.8) 11+ (7+) 5.5 (3.4) 4.2 (2.6)
or trailer
Multiple ton cylinders 400 (1250) 4.0 (2.5) 1.5 (0.9) 1.1 (0.7) 7.9 (4.9) 2.7 (1.7) 1.5 (0.9)
or single ton cylinder
Page 355
Page 356
UN1005 Ammonia, anhydrous: Large Spills

TRANSPORT ISOLATE
Rail tank car 200 (600) 1.4 (0.9) 0.8 (0.5) 0.6 (0.4) 4.0 (2.5) 1.4 (0.9) 0.8 (0.5)
or tra
TRANSPORT Un1050 Hydrogen Chlorine: Large Spills

CONTAINER Un2186 Hydrogen Chlorine, refrigerated: Large Spills
Rail tank car 600 (2000) 6.1 (3.8) 2.3 (1.4) 1.8 (1.1) 11+ (7+) 4.0 (2.5) 2.6 (1.6)
or trailer
Un1052 Hydrogen fluoride: Large Spills

TRANSPORT ISOLATE
Rail tank car 400 (1250) 3.2 (2.0) 1.9 (1.2) 1.6 (1.0) 7.9 (4.9) 3.1 (1.9) 1.9 (1.2)
or tra
TRANSPORT
CONTAINER Un1079 Sulfur dioxide/Sulphur dioxide: Large Spills
Rail tank car 1000 (3000) 11+ (7+) 11+ (7+) 7.6 (4.7) 11+ (7+) 11+ (7+) 10.8 (6.7)
Highway tank truck 1000 (3000) 11+ (7+) 7.6 (4.7) 5.1 (3.2) 11+ (7+) 10 (6.2) 6.1 (3.8)
or trailer
Page 357
ERG2012 USER’S GUIDE GUIDEBOOK CONTENTS
This guidebook has been redeveloped by GSDMA as per the Gujarat context on the basis of The 1-Yellow-bordered pages: Index list of dangerous goods in numerical order of ID number. This
2012 Emergency Response Guidebook (ERG2012) . Originally, the ERG2012 was developed jointly section quickly identifies the guide to be consulted from the ID Number of the material involved.
by Transport Canada (TC), the U.S. Department of Transportation (DOT), the Secretariat of This list displays the 4-digit ID number of the material followed by its assigned emergency
Transport and Communications of Mexico (SCT) and with the collaboration of CIQUIME (Centro response guide and the material name.
de Información Química para Emergencias) of Argentina, for use by fire fighters, police, and other For example: ID No. GUIDE No. Name of Material
emergency services personnel who may be the first to arrive at the scene of a transportation 1090 127 Acetone
incident involving dangerous goods. It is primarily a guide to aid first responders in quickly
identifying the specific or generic hazards of the material(s) involved in the incident, and 2-Blue-bordered pages: Index list of dangerous goods in alphabetical order of material name.
protecting themselves and the general public during the initial response phase of the incident. This section quickly identifies the guide to be consulted from the name of the material involved.
For the purposes of this guidebook, the “initial response phase” is that period following arrival at This list displays the name of the material followed by its assigned emergency response guide and
the scene of an incident during which the presence and/or identification of dangerous goods is 4-digit ID number.
confirmed, protective actions and area securement are initiated, and assistance of qualified For example: Name of Material GUIDE No. ID No.
personnel is requested. It is not intended to provide information on the physical or chemical Sulfuric acid 137 1830
properties of dangerous goods.
3-Orange-bordered pages: This section is the most important section of the guidebook because it
This guidebook will assist responders in making initial decisions upon arriving at the scene of a is where all safety recommendations are provided. It comprises a total of 62 individual guides,
dangerous goods incident. It should not be considered as a substitute for emergency response presented in a two-page format. Each guide provides safety recommendations and emergency
training, knowledge or sound judgment. ERG2012 does not address all possible circumstances response information to protect yourself and the public. The left hand page provides safety
that may be associated with a dangerous goods incident. It is primarily designed for use at a related information whereas the right hand page provides emergency response guidance and
dangerous goods incident occurring on a highway or railroad. Be mindful that there may be activities for fire situations, spill or leak incidents and first aid. Each guide is designed to cover a
limited value in its application at fixed facility locations. group of materials which possess similar chemical and toxicological characteristics.
ERG2012 incorporates dangerous goods lists from the most recent United Nations The guide title identifies the general hazards of the dangerous goods covered.
Recommendations as well as from other international and national regulations. Explosives are
not listed individually by either proper shipping name or ID Number. They do, however, appear For example: GUIDE 124 - Gases-Toxic and/or Corrosive-Oxidizing.
under the general heading “Explosives” on the first page of the ID Number index (yellow- Each guide is divided into three main sections: the first section describes potential hazards that
bordered pages) and alphabetically in the Name of Material index (blue-bordered pages). Also, the material may display in terms of fire/explosion and health effects upon exposure. The highest
the letter (P) following the guide number in the yellow-bordered and bluebordered pages potential is listed first. The emergency responder should consult this section first. This allows the
identifies those materials which present a polymerization hazard under certain conditions, for responder to make decisions regarding the protection of the emergency response team as well as
example: Acrolein, stabilized 131P. the surrounding population.
First responders at the scene of a dangerous goods incident should seek additional specific The second section outlines suggested public safety measures based on the situation at hand. It
information about any material in question as soon as possible. The information received by provides general information regarding immediate isolation of the incident site, recommended
contacting the appropriate emergency response agency, by calling the emergency response type of protective clothing and respiratory protection. Suggested evacuation distances are listed
telephone number on the shipping document, or by consulting the information on or for small and large spills and for fire situations (fragmentation hazard). It also directs the reader to
accompanying the shipping document, may be more specific and accurate than this guidebook in consult the tables listing Toxic Inhalation Hazard (TIH) materials, chemical warfare agents and
providing guidance for the materials involved. water-reactive materials (green-bordered pages) when the material is highlighted in the yellow-
BEFORE AN EMERGENCY – BECOME FAMILIAR WITH THIS GUIDEBOOK! bordered and blue-bordered pages.
The third section covers emergency response actions, including first aid. It outlines special
precautions for incidents which involve fire, spill or chemical exposure. Several recommendations
are listed under each part which will further assist in the decision making process. The
information on first aid is general guidance prior to seeking medical care.
Page 358 Page 359

4-Green-bordered pages: This section contains three tables. Table 2 lists, by ID number order, materials that produce large amounts of Toxic Inhalation Hazard
(TIH) gases when spilled in water and identifies the TIH gases produced. These Water Reactive
Table 1 lists, by ID number order, TIH materials, including certain chemical warfare agents, and materials are easily identified in Table 1 as their name is immediately followed by (when spilled in
water-reactive materials which produce toxic gases upon contact with water. This table provides water). Some Water Reactive materials are also TIH materials themselves (e.g., Bromine
two different types of recommended safe distances which are "Initial isolation distances" and trifluoride (1746), Thionyl chloride (1836), etc.). In these instances, two entries are provided in
"Protective action distances". The materials are highlighted in green for easy identification in Table 1 for land-based and water-based spills. If the Water Reactive material is NOT a TIH and this
both numeric (yellow-bordered pages) and alphabetic (blue-bordered pages) lists of the material is NOT spilled in water, Table 1 and Table 2 do not apply and safety distances will be found
guidebook. This table provides distances for both small (approximately 208 liters or less for liquids within the appropriate orange-bordered guide.
and 300 kilograms (660 pounds) or less for solids when spilled in water) and large spills (more than
208 liters for liquids and more than 300 kilograms (660 pounds) for solids when spilled in water) Table 3 provides, by alphabetical order of material name, initial isolation and protective action
for all highlighted materials. The list is further subdivided into daytime and nighttime situations. distances for six Toxic Inhalation Hazard materials that may be more commonly encountered.
This is necessary due to varying atmospheric conditions which greatly affect the size of the The selected materials are:
hazardous area. The distances change from daytime to nighttime due to different mixing and --Ammonia, anhydrous (UN1005)
dispersion conditions in the air. During the night, the air is generally calmer and this causes the
material to disperse less and therefore create a toxic zone which is greater than would usually --Chlorine (UN1017)
occur during the day. During the day, a more active atmosphere will cause a greater dispersion of --Ethylene oxide (UN1040)
the material resulting in a lower concentration of the material in the surrounding air. The actual --Hydrogen chloride (UN1050) and Hydrogen chloride, refrigerated liquid (UN2186)
area where toxic levels are reached will be smaller (due to increased dispersion). In fact, it is the --Hydrogen fluoride (UN1052)
quantity or concentration of the material Vapour that poses problems not its mere presence. The --Sulfur dioxide/Sulphur dioxide (UN1079)
"Initial Isolation Distance" is a distance within which all persons should be considered for
evacuation in all directions from the actual spill/leak source. It is a distance (radius) which defines The table provides Initial Isolation and Protective Action Distances for large spills (more than 208
a circle (Initial Isolation Zone) within which persons may be exposed to dangerous concentrations liters) involving different container types (therefore different volume capacities) for day time and
upwind of the source and may be exposed to life threatening concentrations downwind of the night time situations and different wind speeds.
source. For example, in the case of Compressed gas, toxic, n.o.s., ID No. 1955, Inhalation Hazard
Zone A, the isolation distance for small spills is 100 meters (300 feet), therefore, representing an
evacuation circle of 200 meters (600 feet) in diameter. For the same material, the "Protective
ISOLATION AND EVACUATION DISTANCES
Action Distance" for a small spill is 0.5 kilometers (0.3 mile) for a daytime incident and 2.2
kilometers (1.4 miles) for a nighttime incident, these distances represent a downwind distance
from the spill/leak source within which Protective Actions could be implemented. Protective
Isolation or evacuation distances are shown in the guides (orange-bordered pages) and in the
Actions are those steps taken to preserve the health and safety of emergency responders and the
Table 1 - Initial Isolation and Protective Action Distances (green-bordered pages). This may
public. People in this area could be evacuated and/or sheltered in-place. For more information,
confuse users not thoroughly familiar with ERG2012. It is important to note that some guides
consult pages 285 to 291.
refer only to non-TIH materials (36 guides), some refer to both TIH and non-TIH materials (21
What is a TIH? It is a gas or volatile liquid which is known to be so toxic to humans as to pose a guides) and some (5 guides) refer only to TIH or Water-reactive materials (WRM). A guide refers to
hazard to health during transportation, or in the absence of adequate data on human toxicity, is both TIH and non-TIH materials (for example see GUIDE 131) when the following sentence
presumed to be toxic to humans because when tested on laboratory animals it has a Lethal appears under the title EVACUATIONSpill: “See Table 1 - Initial Isolation and Protective Action
Concentration 50 (LC50) value of not more than 5000 ppm. Distances for highlighted materials. For non-highlighted materials, increase, in the downwind
direction, as necessary, the isolation distance shown under ‘PUBLIC SAFETY.’” A guide refers only
It is important to note that even though the term zone is used, the hazard zones do not represent to TIH or WRM materials (for example see GUIDE 124) when the following sentence appears
any actual area or distance. The assignment of the zones is strictly a function of their Lethal under the title EVACUATION-Spill: “See Table 1 - Initial Isolation and Protective Action Distances”.
Concentration 50 (LC50); for example, TIH Zone A is more toxic than Zone D. All distances which If the previous sentences do not appear in a guide, then this particular guide refers only to non-
are listed in the green-bordered pages are calculated by the use of mathematical models for each TIH materials (for example see GUIDE 128).
TIH material. For the assignment of hazard zones refer to the glossary.
Page 360 Page 361

In order to identify appropriate isolation and protective action distances, use the following: If you PROTECTIVE CLOTHING
are dealing with a TIH/WRM/Chemical warfare material (highlighted entries in the index lists),
the isolation and evacuation distances are found directly in the green-bordered pages. The guides
Street Clothing and Work Uniforms. These garments, such as uniforms worn by police and
(orange-bordered pages) also remind the user to refer to the green-bordered pages for
emergency medical services personnel, provide almost no protection from the harmful effects of
evacuation specific information involving highlighted materials.
dangerous goods.
If you are dealing with a non-TIH material but the guide refers to both TIH and non-TIH
Structural Fire Fighters’ Protective Clothing (SFPC). This category of clothing, often called
materials, an immediate isolation distance is provided under the heading PUBLIC SAFETY as a
turnout or bunker gear, means the protective clothing normally worn by fire fighters during
precautionary measure to prevent injuries. It applies to the non-TIH materials only. In addition,
structural fire fighting operations. It includes a helmet, coat, pants, boots, gloves and a hood to
for evacuation purposes, the guide informs the user under the title EVACUATIONSpill to increase,
cover parts of the head not protected by the helmet and facepiece. This clothing must be used
for non-highlighted materials, in the downwind direction, if necessary, the immediate isolation
with full-facepiece positive pressure self-contained breathing apparatus (SCBA). This protective
distance listed under “PUBLIC SAFETY”. For example, GUIDE 131 – Flammable Liquids-Toxic,
clothing should, at a minimum, meet the OSHA Fire Brigades Standard (29 CFR 1910.156).
instructs the user to: "As an immediate precautionary measure, isolate spill or leak area for at
Structural fire fighters’ protective clothing provides limited protection from heat and cold, but
least 50 meters (150 feet) in all directions." In case of a large spill, the isolation area could be
may not provide adequate protection from the harmful Vapours or liquids that are encountered
expanded from 50 meters (150 feet) to a distance deemed as safe by the On-scene commander
during dangerous goods incidents. Each guide includes a statement about the use of SFPC in
and emergency responders.
incidents involving those materials referenced by that guide. Some guides state that SFPC
If you are dealing with a non-TIH material and the guide refers only to non-TIH materials, the provides limited protection. In those cases, the responder wearing SFPC and SCBA may be able to
immediate isolation and evacuation distances are specified as actual distances in the guide perform an expedient, that is quick “in-and-out”, operation. However, this type of operation can
(orange-bordered pages) and are not referenced in the green-bordered pages. place the responder at risk of exposure, injury or death. The incident commander makes the
decision to perform this operation only if an overriding benefit can be gained (i.e., perform an
Note 1: If an entry is highlighted in green in either the yellow-bordered or blue-bordered pages immediate rescue, turn off a valve to control a leak, etc.). The coverall-type protective clothing
AND THERE IS NO FIRE, go directly to Table 1 - Initial Isolation and Protective Action Distances customarily worn to fight fires in forests or wildlands is not SFPC and is not recommended nor
(green-bordered pages) and look up the ID number and name of material to obtain initial isolation referred to elsewhere in this guidebook.
and protective action distances. IF THERE IS A FIRE, or IF A FIRE IS INVOLVED, ALSO CONSULT the
assigned guide (orange-bordered pages) and apply as appropriate the evacuation information Positive Pressure Self-Contained Breathing Apparatus (SCBA). This apparatus provides a
shown under PUBLIC SAFETY. constant, positive pressure flow of air within the facepiece, even if one inhales deeply while doing
heavy work. Chemical-cartridge respirators or other filtering masks are not acceptable
Note 2: If the name in Table 1 is shown with “When Spilled In Water”, these materials produce substitutes for positive pressure self-contained breathing apparatus. Demand-type SCBA does
large amounts of Toxic Inhalation Hazard (TIH) gases when spilled in water. Some Water Reactive not meet the OSHA 29 CFR 1910.156 (f)(1)(i) of the Fire Brigades Standard. If it is suspected that a
materials are also TIH materials themselves (e.g., Bromine trifluoride (1746), Thionyl chloride Chemical Warfare Agent (CW) is involved, the use of NIOSH-certified respirators with CBRN
(1836), etc.). In these instances, two entries are provided in Table 1 for land-based and water- protection are highly recommended.
based spills. If the Water Reactive material is NOT a TIH and this material is NOT spilled in water,
Table 1 and Table 2 do not apply and safety distances will be found within the appropriate orange- Chemical Protective Clothing and Equipment. Safe use of this type of protective clothing and
bordered guide. equipment requires specific skills developed through training and experience. It is generally not
available to, or used by, first responders. This type of special clothing may protect against one
chemical, yet be readily permeated by chemicals for which it was not designed. Therefore,
protective clothing should not be used unless it is compatible with the released material. This
type of special clothing offers little or no protection against heat and/ or cold. Examples of this
type of equipment have been described as (1) Vapour Protective Suits (NFPA 1991), also known as
Totally-Encapsulating Chemical Protective (TECP) Suits or Level A* protection (OSHA 29 CFR
1910.120, Appendix A & B), and (2) Liquid-Splash
Page 362 Page 363

Protective Suits (NFPA 1992 & 1993), also known as Level B* or C* protection (OSHA 29 CFR FIRE AND SPILL CONTROL
1910.120, Appendix A & B) or suits for chemical/biological terrorism incidents (NFPA 1994), class
1, 2 or 3 Ensembles and Standard CAN/CGSB/CSA-Z1610-11 – Protection of first responders from
chemical, biological, radiological, and nuclear (CBRN) events (2011). No single protective clothing
FIRE CONTROL
material will protect you from all dangerous goods. Do not assume any protective clothing is
resistant to cold and/or heat or flame exposure unless it is so certified by the manufacturer (NFPA Water is the most common and generally most available fire extinguishing agent. Exercise caution
1991 5-3 Flammability Resistance Test and 5-6 Cold Temperature Performance Test). in selecting a fire extinguishing method since there are many factors to be considered in an
incident. Water may be ineffective in fighting fires involving some materials; its effectiveness
* Consult glossary for additional protection levels under the heading “Protective Clothing”.
depends greatly on the method of application. Fires involving a spill of flammable liquids are
generally controlled by applying a fire fighting foam to the surface of the burning material.
Fighting flammable liquid fires requires foam concentrate which is chemically compatible with
the burning material, correct mixing of the foam concentrate with water and air, and careful
application and maintenance of the foam blanket. There are two general types of fire fighting
foam: regular and alcohol-resistant. Examples of regular foam are protein-base, fluoroprotein,
and aqueous film forming foam (AFFF). Some flammable liquids, including many petroleum
products, can be controlled by applying regular foam. Other flammable liquids, including polar
solvents (flammable liquids which are water soluble) such as alcohols and ketones, have different
chemical properties. A fire involving these materials cannot be easily controlled with regular
foam and requires application of alcohol-resistant foam. Polar-solvent fires may be difficult to
control and require a higher foam application rate than other flammable liquid fires (see
NFPA/ANSI Standards 11 and 11A for further information). Refer to the appropriate guide to
determine which type of foam is recommended. Although it is impossible to make specific
recommendations for flammable liquids which have subsidiary corrosive or toxic hazards,
alcohol-resistant foam may be effective for many of these materials. The emergency response
telephone number on the shipping document, or the appropriate emergency response agency,
should be contacted as soon as possible for guidance on the proper fire extinguishing agent to
use. The final selection of the agent and method depends on many factors such as incident
location, exposure hazards, size of the fire, environmental concerns, as well as the availability of
extinguishing agents and equipment at the scene.
WATER REACTIVE MATERIALS

Water is sometimes used to flush spills and to reduce or direct Vapours in spill situations. Some of
the materials covered by the guidebook can react violently or even explosively with water. In
these cases, consider letting the fire burn or leaving the spill alone (except to prevent its
spreading by diking) until additional technical advice can be obtained. The applicable guides
clearly warn you of these potentially dangerous reactions. These materials require technical
advice since
(1) water getting inside a ruptured or leaking container may cause an explosion;
(2) water may be needed to cool adjoining containers to prevent their rupturing
(exploding) or further spread of the fires;
Page 364 Page 365

(3) water may be effective in mitigating an incident involving a water-reactive material only What are the main hazards from a BLEVE?
if it can be applied at a sufficient flooding rate for an extended period; and
The main hazards from a propane or LPG BLEVE are:
(4) the products from the reaction with water may be more toxic, corrosive, or otherwise --fire
more undesirable than the product of the fire without water applied. --thermal radiation from the fire
When responding to an incident involving water-reactive materials, take into account the existing --blast
conditions such as wind, precipitation, location and accessibility to the incident, as well as the --projectiles
availability of the agents to control the fire or spill. Because there are variables to consider, the
decision to use water on fires or spills involving water-reactive materials should be based on The danger from these decreases as you move away from the BLEVE centre. The furthest reaching
information from an authoritative source; for example, a producer of the material, who can be hazard is projectiles.
contacted through the emergency response telephone number or the appropriate emergency This information was prepared for Transport Canada, the Canadian Association of Fire Chiefs and
response agency. the Propane Gas Association of Canada Inc. by Dr. A. M. Birk, Queen’s University, Kingston
(Ontario) Canada.
Vapour CONTROL
For a free download or to order a DVD of the video BLEVE Response and Prevention, please visit
Limiting the amount of Vapour released from a pool of flammable or corrosive liquids is an <http://www.tc.gc.ca/eng/tdg/bleve-1119.htm> or contact us at 1-888-830-4911, or by Email:
operational concern. It requires the use of proper protective clothing, specialized equipment, MPS@tc.gc.ca.
appropriate chemical agents, and skilled personnel. Before engaging in Vapour control, get advice
from an authoritative source as to the proper tactics. To download a free copy, first click on the green "View/Download" button and then left-click the
video link to view the video or right-click to download a copy by selecting "Save target as" to save
There are several ways to minimize the amount of Vapours escaping from pools of spilled liquids, to your computer.
such as special foams, adsorbing agents, absorbing agents, and neutralizing agents. To be
effective, these Vapour control methods must be selected for the specific material involved and
performed in a manner that will mitigate, not worsen, the incident.
Where specific materials are known, such as at manufacturing or storage facilities, it is desirable
for the dangerous goods response team to prearrange with the facility operators to select and
stockpile these control agents in advance of a spill. In the field, first responders may not have the
most effective Vapour control agent for the material available. They are likely to have only water
and only one type of fire fighting foam on their vehicles. If the available foam is inappropriate for
use, they are likely to use water spray. Because the water is being used to form a Vapour seal, care
must be taken not to churn or further spread the spill during application. Vapours that do not
react with water may be directed away from the site using the air currents surrounding the water
spray. Before using water spray or other methods to safely control Vapour emission or to suppress
ignition, obtain technical advice, based on specific chemical name identification.
BLEVE (Boiling Liquid Expanding Vapour Explosion)

The following section presents, in a two-page format, background information on BLEVEs and
includes a chart that provides important safety-related information to consider when confronted
with this type of situation involving Liquefied Petroleum Gases (LPG), UN1075. LPGs include the
following flammable gases; Butane, UN1011; Butylene, Un1012; Isobutylene, UN1055;
Propylene, UN2077; Isobutane, UN1969; and Propane, UN1978.
Page 366 Page 367

BLEVE – SAFETY PRECAUTIONS
Meters (Feet) Meters (Feet) Meters (Feet) Meters (Feet) Litres/min USgal/min
112
158
224
371
512
716
935
25
50
Cooling water
?ow rate
Use with caution. The following table gives a summary of tank properties, critical times, critical
189.3
1404
1938
2710
3539
distances and cooling water flow rates for various tank sizes. This table is provided to give
94.6
424
598
848
responders some guidance but it should be used with caution.
(1007)
(1601)
(2736)
1050 (3445)
1323 (4341)
1852 (6076)
2200 (7218)
2200 (7218)
2200 (7218)
Tank dimensions are approximate and can vary depending on the tank design and application.
evacuation
Preferred
distance
307
488
834
Minimum time to failure is based on severe torch fire impingement on the vapour space of a tank
in good condition, and is approximate. Tanks may fail earlier if they are damaged or corroded.
417 (1368)
525 (1722)
661 (2169)
926 (3038)
(1004) 1149 (3770)
(1257) 1435 (4708)
(1499) 1715 (5627)

(505)
(801)
Tanks may fail minutes or hours later than these minimum times depending on the conditions. It
evacuation
Minimum
distance
has been assumed here that the tanks are not equipped with thermal barriers or water spray
154
244
cooling.
(364)
(459)
(577)
(810)
(295)
(295)
Minimum time to empty is based on an engulfing fire with a properly sized pressure relief valve. If
Emergency
response
distance
the tank is only partially engulfed then time to empty will increase (i.e., if tank is 50% engulfed
111
140
176
247
306
383
457
90
90
then the tanks will take twice as long to empty). Once again, it has been assumed that the tank is
not equipped with a thermal barrier or water spray.
(92)
(115)
(144)
(203)
(253)
(315)
(374)
(33)
(53)
Fireball
radius
(USE WITH CAUTION)
Tanks equipped with thermal barriers or water spray cooling significantly increase the times to
28
35
44
62
77
96
114
10
16
failure and the times to empty. A thermal barrier can reduce the heat input to a tank by a factor of
ten or more. This means it could take ten times as long to empty the tank through the Pressure
BLEVE
Minutes
Approximate
Relief Valve (PRV).
engul?ng
empty for
time to
?re
12
18
20
22
28
32
40
45
8
Fireball radius and emergency response distance is based on mathematical equations and is
approximate. They assume spherical fireballs and this is not always the case.
Minutes
Minimum
failure for
severe
time to
torch
Two safety distances for public evacuation. The minimum distance is based on tanks that are
9
4
4
launched with a small elevation angle (i.e., a few degrees above horizontal). This is most common
for horizontal cylinders. The preferred evacuation distance has more margin of safety since it
Litres (Gallons) Meters (Feet) Meters (Feet) Kilograms (Lbs)
(1764)
(3527)
(7055)
8800 (19400)
11.8 (38.7) 16800 (37037)
(45) 32800 (72310)

(88)
(353)
17.2 (56.4) 56000 (123457)

assumes the tanks are launched at a 45 degree angle to the horizontal. This might be more
Propane
Mass
appropriate if a vertical cylinder is involved. It is understood that these distances are very large
800
1600
3200
40
160
and may not be practical in a highly populated area. However, it should be understood that the
risks increase rapidly the closer you are to a BLEVE. Keep in mind that the furthest reaching
(9.8)
4.9 (16.1)
6.5 (21.3)
(22)
(4.9)
(4.9)
projectiles tend to come off in the zones 45 degrees on each side of the tank ends.
Length
6.7
13.7
1.5
1.5
Water flow rate is based on 5√capacity (USgal) = usgal/min needed to cool tank metal.
(3.2)
(3.3)
(4.1)
(6.9)
(6.9)
(9)
3.3 (10.8)
(1)
(2)
Warning: the data given are approximate and should only be used with extreme caution. For
Diameter
example, where times are given for tank failure or tank emptying through the pressure relief valve
1.25
2.1
2.1
2.75
0.3
0.61
0.96
– these times are typical but they can vary from situation to situation. Therefore, never risk life
based on these times.
(1544)
(3088)
(8492)
(16212)
(31652)
(54040)
(38.6)
(154.4)
(772)
Capacity
400
2000
4000
8000
22000
42000
82000
140000
100
Page 368 Page 369
CRIMINAL/TERRORIST USE OF CHEMICAL/BIOLOGICAL/RADIOLOGICAL AGENTS INDICATORS OF A POSSIBLE CHEMICAL INCIDENT (Continued)
Unexplained odors Smells may range from fruity to flowery to sharp/pungent to
The following is intended to supply information to first responders for use in making a preliminary garlic/ horseradish-like to bitter almonds/peach kernels to new
assessment of a situation that they suspect involves criminal/terrorist use of chemical, biological mown hay. It is important to note that the particular odor is
agents and/or radioactive materials (CBRN). To aid in the assessment, a list of observable completely out of character with its surroundings.
indicators of the use and/or presence of a CB agent or radioactive material is provided in the
following paragraphs. This section ends with a Safe Standoff Distance Chart for various threats Unusual numbers of dying or Health problems including nausea, disorientation, difficulty
when Improvised Explosive Devices are involved. sick people (mass casualties) in breathing, convulsions, localized sweating, conjunctivitis
(reddening of eyes/nerve agent symptoms), erythema
DIFFERENCES BETWEEN A CHEMICAL, BIOLOGICAL AND RADIOLOGICAL AGENT (reddening of skin/vesicant symptoms) and death.
Chemical and biological agents as well as radioactive materials can be dispersed in the air we Pattern of casualties Casualties will likely be distributed downwind, or if indoors, by
breathe, the water we drink, or on surfaces we physically contact. Dispersion methods may be as the air ventilation system.
simple as opening a container, using conventional (garden) spray devices, or as elaborate as
detonating an improvised explosive device. Blisters/rashes Numerous individuals experiencing unexplained water-like
blisters, weals (like bee stings), and/or rashes.
Chemical Incidents are characterized by the rapid onset of medical symptoms (minutes to hours)
and easily observed signatures (colored residue, dead foliage, pungent odor, dead insects and Illness in confined area Different casualty rates for people working indoors versus
animals). outdoors dependent on where the agent was released.
Biological Incidents are characterized by the onset of symptoms in hours to days. Typically, there Unusual liquid droplets Numerous surfaces exhibit oily droplets/film; numerous water
will be no characteristic signatures because biological agents are usually odorless and colorless. surfaces have an oily film. (No recent rain.)
Because of the delayed onset of symptoms in a biological incident, the area affected may be Different looking areas Not just a patch of dead weeds, but trees, shrubs, bushes, food
greater due to the movement of infected individuals. crops, and/or lawns that are dead, discolored, or withered. (No
Radiological Incidents are characterized by the onset of symptoms, if any, in days to weeks or current drought.)
longer. Typically, there will be no characteristic signatures because radioactive materials are Low-lying clouds Low-lying cloud/fog-like condition that is not consistent with its
usually odorless and colorless. Specialized equipment is required to determine the size of the surroundings.
affected area, and whether the level of radioactivity presents an immediate or longterm health
hazard. Because radioactivity is not detectable without special equipment, the affected area may Unusual metal debris Unexplained bomb/munitions-like material, especially if it
be greater due to the migration of contaminated individuals. contains a liquid.
At the levels created by most probable sources, not enough radiation would be generated to kill INDICATORS OF A POSSIBLE BIOLOGI.CAL INCIDENT
people or cause severe illness. In a radiological incident generated by a “dirty bomb”, or
Radiological Dispersal Device (RDD), in which a conventional explosive is detonated to spread Unusual numbers of sick or Any number of symptoms may occur. Casualties may
radioactive contamination, the primary hazard is from the explosion. However, certain dying people or animals occur hours to days after an incident has occurred. The time
radioactive materials dispersed in the air could contaminate up to several city blocks, creating required before symptoms are observed is dependent on the
fear and possibly panic, and requiring potentially costly cleanup. agent used.
INDICATORS OF A POSSIBLE CHEMICAL INCIDENT Unscheduled and unusual Especially if outdoors during periods of darkness.
spray being disseminated
Dead animals/birds/fish Not just an occasional road kill, but numerous animals Abandoned spray devices Devices may not have distinct odors.
(wild and domestic, small and large), birds, and fish in
the same area.
Lack of insect life If normal insect activity (ground, air, and/or water) is INDICATORS OF A POSSIBLE RADIOLOGICAL INCIDENT
missing, check the ground/water surface/shore line for Radiation Symbols Containers may display a “propeller” radiation symbol.
dead insects. If near water, check for dead fish/aquatic
birds. Unusual metal debris Unexplained bomb/munitions-like material.
Page 370 Page 371

INDICATORS OF A POSSIBLE RADIOLOGICAL INCIDENT (continued) Initial actions to consider in a potential CBRN/Hazmat Terrorism Event:
Heat-emitting material Material that is hot or seems to emit heat without any sign • Avoid using cell phones, radios, etc. within 100 meters (300 feet) of a suspect device
of an external heat source. • NOTIFY your local police by calling 108/100.
Glowing material Strongly radioactive material may emit or cause • Set up Incident command upwind and uphill of the area.
radioluminescence. • Do NOT touch or move suspicious packages/containers.
• Be cautious regarding potential presence of secondary devices (e.g. Improvised Explosive
Sick people/animals In very improbable scenarios there may be unusual
Devices, IEDs).
numbers of sick or dying people or animals. Casualties
may occur hours to days or weeks after an incident has • Avoid contamination.
occurred. The time required before symptoms are • Limit access to only those responsible for rescue of victims or assessment of unknown
observed is dependent on the radioactive material used, materials or devices.
and the dose received. Possible symptoms include skin • Evacuate and isolate individuals potentially exposed to dangerous goods/hazardous
reddening or vomiting. materials.
• Isolate contaminated areas and secure the scene for analysis of material.
PERSONAL SAFETY CONSIDERATIONS

When approaching a scene that may involve CB agents or radioactive materials, the most critical Decontamination measures. Emergency responders should follow standard decontamination
consideration is the safety of oneself and other responders. Protective clothing and respiratory procedures (flush-strip-flush). Mass casualty decontamination should begin as soon as possible
protection of appropriate level of safety must be used. In incidents where it is suspected that by stripping (all clothing) and flushing (soap and water). If biological agents are involved or
CBRN materials have been used as weapons, NIOSH-certified respirators with CBRN protection suspected, careful washing and use of a brush are more effective. If chemical agents are
are highly recommended. Be aware that the presence and identification of CB agents or suspected, the most important and effective decontamination will be the one done within the
radioactive materials may not be verifiable, especially in the case of biological or radiological first one or two minutes. If possible, further decontamination should be performed using a 0.5%
agents. The following actions/measures to be considered are applicable to either a chemical, hypochlorite solution (1 part household bleach mixed with 9 parts water). If biological agents are
biological or radiological incident. The guidance is general in nature, not all encompassing, and its suspected, a contact time of 10 to 15 minutes should be allowed before rinsing. The solution can
applicability should be evaluated on a case-by-case basis. be used on soft tissue wounds, but must not be used in eyes or open wounds of the abdomen,
chest, head, or spine. For further information contact the agencies listed in this guidebook.
Approach and response strategies. Protect yourself and use a safe approach (minimize any
exposure time, maximize the distance between you and the item that is likely to harm you, use For persons contaminated with radioactive material, remove them to a low radiation area if
cover as protection and wear appropriate personal protective equipment and respiratory necessary. Remove their clothing and place it in a clearly marked sealed receptacle, such as a
protection). Identify and estimate the hazard by using indicators as provided above. Isolate the plastic bag, for later testing. Use decontamination methods described above, but avoid breaking
area and secure the scene; potentially contaminated people should be isolated and the skin, e.g., from shaving, or overly vigorous brushing. External radiological contamination on
decontaminated as soon as possible. To the extent possible, take measures to limit the spread of intact skin surface rarely causes a high enough dose to be a hazard to either the contaminated
contamination. In the event of a chemical incident, the fading of chemical odors is not necessarily person or the first responders. For this reason, except in very unusual circumstances, an injured
an indication of reduced Vapour concentrations. Some chemicals deaden the senses giving the person who is also radiologically contaminated should be medically stabilized, taking care to
false perception that the chemical is no longer present. minimize the spread of the contamination to the extent possible, before decontamination
measures are initiated.
If there is any indication that an area may be contaminated with radioactive materials, including
the site of any non-accidental explosion, responder personnel should be equipped with radiation
detection equipment that would alert them if they are entering a radiologically compromised Note : The above information was developed in part by the Department of National Defence
environment, and should have received adequate training in its use. This equipment should be (Canada), the U.S. Department of the Army, Aberdeen Proving Ground and the Federal
designed in such a way that it can also alert the responders when an unacceptable ambient dose Bureau of Investigation (FBI).
rate or ambient dose has been reached.
Page 372 Page 373

Improvised Explosive Device (IED)
SAFE STAND OFF DISTANCE
Threat Description Explosives Building Outdoor NOTES
Mass (TNT Evacuation Evacuation
equivalent)1 Distance2 Distance3
Pipe Bomb 5 lbs 2.3 kg 70 ft 21 m 850 ft 259 m
Suicide Belt 10 lbs 4.5 kg 90 ft 27 m 1,080 ft 330 m

High Explosives (TNT Equivalent)
Suicide Vest 20 lbs 9 kg 110 ft 34 m 1,360 ft 415 m

Briefcase/Suitcase
50 lbs 23 kg 150 ft 46 m 1,850 ft 564 m
Bomb
Compact Sedan 500 lbs 227 kg 320 ft 98 m 1,500 ft 457 m
Sedan 1,000 lbs 454 kg 400 ft 122 m 1,750 ft 534 m
Passenger/Cargo Van 4,000 lbs 1 814 kg 640 ft 195 m 2,750 ft 838 m

Small Moving Van/
10,000 lbs 4 536 kg 860 ft 263 m 3,750 ft 1 143 m
Delivery Truck
Moving Van/Water Truck 30,000 lbs 13 608 kg 1,240 ft 375 m 6,500 ft 1 982 m
Semitrailer 60,000 lbs 27 216 kg 1,570 ft 475 m 7,000 ft 2 134 m
Threat Description LPG Mass/ Fireball Safe

Volume1 Diameter4 Distance5
(LPG - Butane or Propane)
Lique?ed Petroleum Gas
Small LPG Tank 20 lbs/5 gal 9 kg/19 L 40 ft 12 m 160 ft 48 m
Large LPG Tank 100 lbs/25 gal 45 kg/95 L 69 ft 21 m 276 ft 84 m
Commercial/
2,000 lbs/500 gal 907 kg/1 893 L 184 ft 56 m 736 ft 224 m
Residential LPG Tank
Small LPG Truck 8,000 lbs/2,000 gal 3 630 kg/7 570 L 292 ft 89 m 1,168 ft 356 m
Semitanker LPG 40,000 lbs/10,000 gal 18 144 kg/37 850 L 499 ft 152 m 1,996 ft 608 m
1 Based on the maximum amount of material that could reasonably fit into a container or vehicle. Variations
possible.
2 Governed by the ability of an unreinforced building to withstand severe damage or collapse.
3 Governed by the greater of fragment throw distance or glass breakage/falling glass hazard distance. These
distances can be reduced for personnel wearing ballistic protection. Note that the pipe bomb, suicide
belt/vest, and briefcase/ suitcase bomb are assumed to have a fragmentation characteristic that requires
greater standoff distances than an equal amount of explosives in a vehicle.
4 Assuming efficient mixing of the flammable gas with ambient air.
5 Determined by U.S. firefighting practices wherein safe distances are approximately 4 times the flame height.
Note that an LPG tank filled with high explosives would require a significantly greater standoff distance than
if it were filled with LPG.
Page 374 Page 375
Glossary Glossary
AEGL(s) Acute Exposure Guideline Level(s), AEGLs represent threshold Blood agents Substances that injure a person by interfering with cell respiration (the
exposure limits for the general public after a once-in-alifetime, or exchange of oxygen and carbon dioxide between blood and tissues).
rare, exposure and are applicable to emergency exposure periods Hydrogen cyanide (AC) and Cyanogen chloride (CK) are blood agents.
ranging from 10 minutes to 8 hours. Three levels AEGL-1, AEGL-2 and
AEGL-3 are developed for each of five exposure periods (10 and 30 Symptoms: Respiratory distress, headache, unresponsiveness, seizures,
minutes, 1 hour, 4 hours, and 8 hours) and are distinguished by coma.
varying degrees of severity of toxic effects; see AEGL-1, AEGL-2 and
AEGL-3. Burn Refers to either a chemical or thermal burn, the former may be caused by
corrosive substances and the latter by liquefied cryogenic gases, hot
AEGL-1 AEGL-1 is the airborne concentration (expressed as parts per million molten substances, or flames.
or milligrams per cubic meter [ppm or mg/m3]) of a substance above
which it is predicted that the general population, including CBRN Chemical, biological, radiological or nuclear warfare agent.
susceptible individuals, could experience notable discomfort,
Choking agents Substances that cause physical injury to the lungs. Exposure is through
irritation, or certain asymptomatic, non-sensory effects. However,
inhalation. In extreme cases, membranes swell and lungs become filled
the effects are not disabling and are transient and reversible upon
with liquid (pulmonary edema). Death results from lack of oxygen; hence,
cessation of exposure.
the victim is “choked”. Phosgene (CG) is a choking agent.
AEGL-2 AEGL-2 is the airborne concentration (expressed as ppm or mg/m3)
Symptoms: Irritation to eyes/nose/throat, respiratory distress, nausea
of a substance above which it is predicted that the general
and vomiting, burning of exposed skin.
population, including susceptible individuals, could experience
irreversible or other serious, long-lasting adverse health effects or an CO2 Carbon dioxide gas.
impaired ability to escape.
Cold zone Area where the command post and support functions that are necessary
AEGL-3 AEGL-3 is the airborne concentration (expressed as ppm or mg/m3) to control the incident are located. This is also referred to as the clean
of a substance above which it is predicted that the general zone, green zone or support zone in other documents. (EPA Standard
population, including susceptible individuals, could experience life- Operating Safety Guidelines, OSHA 29 CFR 1910.120, NFPA 472)
threatening health effects or death.
Combustible liquid Liquids which have a flash point greater than 60oC (140oF) and below
Alcohol resistant foam A foam that is resistant to “polar” chemicals such as ketones and 93oC (200oF). U.S. regulations permit a flammable liquid with a flash
esters which may break down other types of foam. Biological agents point between 38oC (100oF) and 60oC (140oF) to be reclassed as a
Living organisms that cause disease, sickness and mortality in combustible liquid.
humans. Anthrax and Ebola are examples of biological agents. Refer
to GUIDE 158. Compatibility Group Letters identify explosives that are deemed to be compatible. The
definition of these Compatibility Groups in this Glossary are intended to
Blister agents (vesicants) Substances that cause blistering of the skin. Exposure is through be descriptive. Please consult the transportation of dangerous
liquid or Vapour contact with any exposed tissue (eyes, skin, lungs). goods/hazardous materials or explosives regulations of your jurisdiction
Mustard (H), Distilled Mustard (HD), Nitrogen Mustard (HN) and for the exact wording of the definitions. Class 1 materials are considered
Lewisite (L) are blister agents. Symptoms: Red eyes, skin irritation, to be “compatible” if they can be transported together without
burning of skin, blisters, upper respiratory damage, cough, significantly increasing either the probability of an incident or, for a given
hoarseness. quantity, the magnitude of the effects of such an incident.
A Substances which are expected to mass detonate very soon after

fire reaches them.
Page 376 Page 377
Glossary Glossary
B Articles which are expected to mass detonate very soon after Decontamination The removal of dangerous goods from personnel and equipment to the
fire reaches them. extent necessary to prevent potential adverse health effects. Always
avoid direct or indirect contact with dangerous goods; however, if contact
C Substances or articles which may be readily ignited and burn occurs, personnel should be decontaminated as soon as possible. Since
violently without necessarily exploding. the methods used to decontaminate personnel and equipment differ
D Substances or articles which may mass detonate (with blast from one chemical to another, contact the chemical manufacturer,
and/or fragment hazard) when exposed to fire. through the agencies listed on the inside back cover, to determine the
appropriate procedure. Contaminated clothing and equipment should be
E&F Articles which may mass detonate in a fire. removed after use and stored in a controlled area (warm/contamination
G Substances and articles which may mass explode and give off reduction/yellow/limited access zone) until cleanup procedures can be
smoke or toxic gases. initiated. In some cases, protective clothing and equipment cannot be
decontaminated and must be disposed of in a proper manner.
H Articles which in a fire may eject hazardous projectiles and
dense white smoke. Dry chemical A preparation designed for fighting fires involving flammable liquids,
pyrophoric substances and electrical equipment. Common types contain
J Articles which may mass explode.
sodium bicarbonate or potassium bicarbonate.
K Articles which in a fire may eject hazardous projectiles and
toxic gases. Edema The accumulation of an excessive amount of watery fluid in cells and
tissues. Pulmonary edema is an excessive buildup of water in the lungs,
L Substances and articles which present a special risk and could for instance, after inhalation of a gas that is corrosive to lung tissue.
be activated by exposure to air or water.
N Articles which contain only extremely insensitive detonating ERPG(s) Emergency Response Planning Guideline(s). Values intended to provide
substances and demonstrate a negligible probability of estimates of concentration ranges above which one could reasonably
accidental ignition or propagation. anticipate observing adverse health effects; see ERPG-1, ERPG-2 and
ERPG-3.
S Packaged substances or articles which, if accidentally
initiated, produce effects that are usually confined to the ERPG-1 The maximum airborne concentration below which it is believed nearly
immediate vicinity. all individuals could be exposed for up to 1 hour without experiencing
more than mild, transient adverse health effects or without perceiving a
Control zones Designated areas at dangerous goods incidents, based on safety and
clearly defined objectionable odor.
the degree of hazard. Many terms are used to describe control zones;
however, in this guidebook, these zones are defined as the ERPG-2 The maximum airborne concentration below which it is believed nearly
hot/exclusion/red/restricted zone, warm/ contamination all individuals could be exposed for up to 1 hour without experiencing or
reduction/yellow/limited access zone, and cold/ developing irreversible or other serious health effects or symptoms that
support/green/clean zone. (EPA Standard Operating Safety could impair an individual’s ability to take protective action.
Guidelines, OSHA 29 CFR 1910.120, NFPA 472)
ERPG-3 The maximum airborne concentration below which it is believed nearly
Cryogenic liquid A refrigerated, liquefied gas that has a boiling point colder than -90oC
all individuals could be exposed for up to 1 hour without experiencing or
(-130oF) at atmospheric pressure.
developing life-threatening health effects.
Dangerous Water Produces significant toxic gas when it comes in contact with
Flammable liquid A liquid that has a flash point of 60oC (140oF) or lower.
Reactive Material water.
Decomposition products Products of a chemical or thermal break-down of a substance.
Page 378 Page 379

Glossary Glossary
Flash point Lowest temperature at which a liquid or solid gives off Vapour in such Mass explosion Explosion which affects almost the entire load virtually instantaneously.
a concentration that, when the Vapour combines with air near the
mg/m3 Milligrams of a material per cubic meter of air.
surface of the liquid or solid, a flammable mixture is formed. Hence,
the lower the flash point, the more flammable the material. Miscible In this guidebook, means that a material mixes readily with water.
Hazard zones HAZARD ZONE A: Gases: LC50 of less than or equal to mL/m3 Milliliters of a material per cubic meter of air. (1 mL/m3 equals 1 ppm)
(Inhalation Hazard 200 ppm,
Nerve agents Substances that interfere with the central nervous system. Exposure is
Zones) Liquids: V equal to or greater than 500 LC50
primarily through contact with the liquid (via skin and eyes) and
and LC50 less than or equal to 200 ppm,
secondarily through inhalation of the Vapour. Tabun (GA), Sarin (GB),
HAZARD ZONE B: Gases: LC50 greater than 200 ppm and less Soman (GD) and VX are nerve agents.
than or equal to 1000 ppm, Liquids: V equal to
Symptoms: Pinpoint pupils, extreme headache, severe tightness in the
or greater than 10 LC50; LC50 less than or
chest, dyspnea, runny nose, coughing, salivation, unresponsiveness,
equal to 1000 ppm and criteria for Hazard
seizures.
Zone A are not met.
Non-polar See “Immiscible”.
HAZARD ZONE C: LC50 greater than 1000 ppm and less than or
equal to 3000 ppm, n.o.s. These letters refer to “not otherwise specified”. The entries which use
this description are generic names such as “Corrosive liquid, n.o.s.” This
HAZARD ZONE D: LC50 greater than 3000 ppm and less than or
means that the actual chemical name for that corrosive liquid is not listed
equal to 5000 ppm.
in the regulations; therefore, a generic name must be used to describe it
Hot zone Area immediately surrounding a dangerous goods incident which on shipping papers.
extends far enough to prevent adverse effects from released
Noxious In this guidebook, means that a material may be harmful or injurious to
dangerous goods to personnel outside the zone. This zone is also
health or physical well-being.
referred to as exclusion zone, red zone or restricted zone in other
documents. (EPA Standard Operating Safety Guidelines, OSHA 29 CFR Oxidizer A chemical which supplies its own oxygen and which helps other
1910.120, NFPA 472) combustible material burn more readily.
IED See “Improvised Explosive Device”. P The letter (P) following a guide number in the yellow-bordered and blue-
bordered pages identifies a material which may polymerize violently
Immiscible In this guidebook, means that a material does not mix readily with
under high temperature conditions or contamination with other
water.
products. It is used to identify materials that have a strong potential for
Improvised Explosive A bomb that is manufactured from commercial, military or polymerization in the absence of an inhibitor or due to the inhibitor
depletion caused by the accident conditions. This polymerization will
Device homemade explosives.
produce heat and high pressure buildup in containers which may explode
Large spill A spill that involves quantities that are greater than 208 liters for or rupture. (See polymerization below)
liquids and greater than 300 kilograms (660 pounds) for solids.
Packing Group The Packing Group (PG) is assigned based on the degree of danger
Lc50 Lethal concentration 50. The concentration of a material presented by the hazardous material:
administered by inhalation that is expected to cause the death of 50%
PG I : Great danger
of an experimental animal population within a specified time.
(Concentration is reported in either ppm or mg/m3) PG II : Medium danger
PG III : Minor danger
Page 380 Page 381

Glossary Glossary
PG See Packing Group Radiation Authority As referred to in GUIDES 161 through 166 for radioactive materials, the
Radiation Authority is either a Federal, state/provincial agency or
pH pH is a value that represents the acidity or alkalinity of a water solution. state/province designated official. The responsibilities of this authority
Pure water has a pH of 7. A pH value below 7 indicates an acid solution (a include evaluating radiological hazard conditions during normal
pH of 1 is extremely acidic). A pH above 7 indicates an alkaline solution (a operations and during emergencies. If the identity and telephone
pH of 14 is extremely alkaline). Acids and alkalies (bases) are commonly number of the authority are not known by emergency responders, or
referred to as corrosive materials. included in the local response plan, the information can be obtained from
the agencies listed on the inside back cover. They maintain a periodically
PIH Poison Inhalation Hazard. Term used to describe gases and volatile liquids updated list of radiation authorities.
that are toxic when inhaled. (Same as TIH)
Radioactivity The property of some substances to emit invisible and potentially harmful
Polar See “Miscible”. radiation.
Polymerization This term describes a chemical reaction which is generally associated with Refrigerated liquid See “Cryogenic liquid”.
the production of plastic substances. Basically, the individual molecules
of the chemical (liquid or gas) react with each other to produce what can Small spill A spill that involves quantities that are less than 208 liters for liquids and
be described as a long chain. These chains can be formed in many useful less than 300 kilograms (660 pounds) for solids.
applications. A well known example is the styrofoam (polystyrene) coffee
cup which is formed when liquid molecules of styrene react with each Straight (solid) stream Method used to apply or distribute water from the end of a hose. The
other or polymerize forming a solid, therefore changing the name from water is delivered under pressure for penetration. In an efficient straight
styrene to polystyrene (poly means many). (solid) stream, approximately 90% of the water passes through an
imaginary circle 38 cm (15 inches) in diameter at the breaking point. Hose
ppm Parts per million. (1 ppm equals 1 mL/m3) (solid or straight) streams are frequently used to cool tanks and other
equipment exposed to flammable liquid fires, or for washing burning
Protective clothing Includes both respiratory and physical protection. One cannot assign a spills away from danger points. However, straight streams will cause a
level of protection to clothing or respiratory devices separately. These spill fire to spread if improperly used or when directed into open
levels were accepted and defined by response organizations such as U.S. containers of flammable and combustible liquids.
Coast Guard, NIOSH, and U.S. EPA.
TIH Toxic Inhalation Hazard. Term used to describe gases and volatile liquids
Level A: SCBA plus totally encapsulating chemical resistant clothing that are toxic when inhaled. (Same as PIH)
(permeation resistant).
V Saturated Vapour concentration in air of a material in mL/m3 (volatility)
Level B: SCBA plus hooded chemical resistant clothing (splash suit). at 20oC and standard atmospheric pressure.
Level C: Full or half-face respirator plus hooded chemical resistant Vapour density Weight of a volume of pure Vapour or gas (with no air present) compared
clothing (splash suit). to the weight of an equal volume of dry air at the same temperature and
Level D: Coverall with no respiratory protection. pressure. A Vapour density less than 1 (one) indicates that the Vapour is
lighter than air and will tend to rise. A Vapour density greater than 1 (one)
Pyrophoric A material which ignites spontaneously upon exposure to air (or oxygen). indicates that the Vapour is heavier than air and may travel along the
ground.
Vapour pressure Pressure at which a liquid and its Vapour are in equilibrium at a given
temperature. Liquids with high Vapour pressures eVapourate rapidly.
Page 382 Page 383

Glossary
The Emergency Response Guidebook is normally revised and reissued regularly.
Viscosity Measure of a liquid’s internal resistance to flow. This property is However, in the event of a significant mistake, omission or change in the state of
important because it indicates how fast a material will leak out through knowledge, special instructions to change the guidebook (in pen-and-ink, with
holes in containers or tanks. paste-over stickers, or with a supplement) may be issued.
Warm zone Area between Hot and Cold zones where personnel and equipment Users of this guidebook should check periodically to make sure their version is
decontamination and hot zone support take place. It includes control current. Changes should be annotated below. Contact:
points for the access corridor and thus assists in reducing the spread of
contamination. Also referred to as the contamination reduction corridor
(CRC), contamination reduction zone (CRZ), yellow zone or limited access GSDMA
zone in other documents. (EPA Standard Operating Safety Guidelines, http://gsdma.org/
OSHA 29 CFR 1910.120, NFPA 472)
Water-sensitive Substances which may produce flammable and/or toxic decomposition
products upon contact with water. This guidebook incorporates changes dated:
Water spray (fog) Method or way to apply or distribute water. The water is finely divided to _______________________________________________
provide for high heat absorption. Water spray patterns can range from
_______________________________________________
about 10 to 90 degrees. Water spray streams can be used to extinguish or
control the burning of a fire or to provide exposure protection for _______________________________________________
personnel, equipment, buildings, etc. (This method can be used to
absorb Vapours, knockdown Vapours or disperse Vapours. Direct a
water spray (fog), rather than a straight (solid) stream, into the Vapour
cloud to accomplish any of the above).
Water spray is particularly effective on fires of flammable liquids and
volatile solids having flash points above 37.8oC (100oF).
Regardless of the above, water spray can be used successfully on
flammable liquids with low flash points. The effectiveness depends
particularly on the method of application. With proper nozzles, even
gasoline spill fires of some types have been extinguished when
coordinated hose lines were used to sweep the flames off the surface of
the liquid. Furthermore, water spray carefully applied hasfrequently
been used with success in extinguishing fires involving flammable liquids
with high flash points (or any viscous liquids) by causing frothing to occur
only on the surface, and this foaming action blankets and extinguishes
the fire.
Page 384 Page 385

Emergency Response Telephone Numbers Emergency Response Telephone Numbers - District level
Agency Phone No. Fax No. Collector DDO Police

Emergency Services (Medical, Police & Fire) 108 Sr.
No. District Code Control Room (O) (O) Control Room (O)
Police 100
01 Ahmedabad 079 27560511 27551681 25506487 2686091 22686398
Fire & Emergency Services 101
02 Amreli 02792 230735 222307 222313 223498 222333
District Emergency Operation Centre (Dist. Code) + 1077 03 Anand 02692 243222 242871 241110 261033 260027
(from landline)
04 Banaskantha 02742 250627 257171 254060 252600 257015
State Emergency Operation Centre (079) 1070 (from landline) (079) 23251912
05 Bharuch 02642 242300 240600 240603 269303 223633
Block No. 2, Ground Floor, Sachivalaya (079 ) 23251900 (079) 23251916
Gandhinagar. (079) 23251902 06 Bhavnagar 0278 2521554-55 2428822 2426810 223499 2520050
07 Dahod 02673 239277 239001 239066 222400 222300
Regional Emergency Response Centre (Ahmedabad) (079) 22148598 (079) 22148598
(079) 22148465 08 Dang 02631 220347 220201 220254 220322 220248
9327038754 09 Gandhinagar 079 23256720 23259029 23256983 23210914 23210901
23256639 23259030
Regional Emergency Response Centre (Vadodara) (0265) 2413753 (0265) 2420881
(0265) 2413635 10 Jamnagar 0288 2553404 2555869 2553901 2550200 2554203
9879615020 11 Junagadh 0285 2633446-7-8 2650201 2651001 2620603 2655633
2650202
Regional Emergency Response Centre (Rajkot) 9624703444 (0281) 2226185
12 Kheda 0268 2562799 2550856 2557262 25611800 2550150
(0281) 2227222
9714503715 13 Kutch 02832 252347 250020 250080 253593 250444
Regional Emergency Response Centre (Surat) (0261) 2414139 (0261) 2451935 14 Mehsana 02762 222220 222200 222301-2 222133 222122
222211
(0261) 2414195
9724345234 15 Narmada 02640 224001 224911 222161 224820 222115 222167
16 Navsari 02637 259401 244999 244299 245333
Regional Emergency Response Centre (Gandhidham) (02832) 252347 (02832) 224150 256556 248120 246070 245334
Central Control Room (0265) 2232327 17 Panchmahals 02672 242536 242800 253377 242504 242200
Material Bhavan, Ground Floor, RILVMD, (0265) 2230342
18 Patan 02766 224830 233303 223440 230502 223555
Po. Petrochemicals, Dist. Vadodara- 391346 (0265) 2230556
19 Porbandar 0286 2245800 2243800 2243804 2240922 2211222
Relief Commissioner (079) 23251900 (079) 23251912
20 Rajkot 0281 2471573 2473900 2477008 2445975 2446333
Block No. 2, Ground Floor, Sachivalaya Gandhinagar. (079) 23251916 2479351
Gujarat State Disaster Management Authority (079) 23259283 (079) 23259302 21 Sabarkantha 02772 230100249039 241001 242350 241303 247333
Block No. 11, 5th Floor, Udyog Bhavan, (079) 23259246 (079) 23259275 240600
Sector – 11, Gandhinagar – 382011. (079) 23259303 22 Surat 0261 2465112 2471121 2422160 2463976 2463976
Disaster Prevention & Management Centre (02646) 220229 2472471 2463978
GIDC - Ankleshwar (02646) 653101 23 Surendranagar 02752 284300 283400 282200 283752 230452 282100
Vapi Emergency Control Centre (0260) 2433950 24 Tapi 02626 224401 223332 224400 222141 222700
Kakrapar Atomic Power Station (02626) 230328 (02626) 234266 25 Vadodara 0265 2427592 2423100 2432027 2419777 2412255
Kakarapar Gujarat Site (02626) 234245 (02626) 234268 26 Valsad 02632 243238 253613 253184 253333 254222
PO. Anumala, Via: Vyara Dist. Surat – 394651 243417 248053
Page 386 Page 387

Emergency Response Telephone Numbers
Agency Phone No. Fax. No.

NOTES
National Disaster Management Authority (NDMA) (011) 26701700 (011) 26701729
NDMA Bhawan,A-1, Safdarjung Enclave, New Delhi (011) 26701728
Director General Factory Advice Service & Labour Institutes (022) 24092203 (022) 24071986
Ministry of Labour, Government of India, Sion, Mumbai -400 022
National Institute of Occupational Health (079) 22686351
Meghani Nagar, Ahmedabad – 380 016 (079) 22686352
Director Industrial safety & Health, Gujarat (079) 25502349 (079) 2550 2357
3rd & 5th Floor, Shram Bhavan, (079) 25502346
Nr. Gun House, Khanpur, Ahmedabad (079) 25502356
Gujarat Pollution Control Board (079) 2323 2152 (079) 2323 2156
Paryavaran Bhavan, Sector – 10 A Gandhinagar - 382010 (079) 2322 2784
Gujarat Industrial Development Corporation (079) 23250581 (079) 2325 0582
Udyog Bhavan, Gandhinagar (079) 23250636
(079) 23250637
Petroleum & Explosive Safety Organization (0265) 2225159
8th Floor, Yash Kamal Building, Sayajigunj Vadodara -390001 (0265) 2361035
Ministry of Chemicals & Fertilizers (011) 23715370 (011) 23725114
Janpath Bhawan, 3rd Floor, B-Wing, Janpath, New Delhi-110001
Ministry of Petroleum & Natuarl Gas (011) 23386965 (011) 23383100
Shastri Bhavan, New Delhi - 110001
Ministry of Environment & Forests (011) 24361669
Paryavaran Bhavan CGO Complex, Lodhi Road (011) 24362064
New Delhi - 110 003
Council of Scientific and Industrial Research (011) 23710138
Anusandhan Bhawan, 2 Rafi Marg, (011) 23710144
New Delhi-110001, India (011) 23710158
National Safety Council (022) 2757 9924 (022) 27577351
Plot No.98-A, Institutional Area, Sector 15,
CBD Belapur, Navi Mumbai - 400 614
Disaster Management Institute (0755) 2466715
Paryavaran Parisar, E-5, Arera Colony, (0755) 2461348 (0755) 2466653
PB No. 563 Bhopal-462016, MP (India)
Gujarat Safety Council (0265) 2429589 (0265) 2425202
Midway Height, 4th Floor, Beside Panchmukhi Hanuman Temple, (0265) 6596727
Tilak Road, Kalaghoda, Vadodara- 390 001
Indian Institute of Chemical Technology (040) 27193030 (040) 27160387
Uppal Road, Tarnaka, Hyderabad - 500 007
Industrial Toxicology Research Centre (0522) 2621856 (0522) 2628227
Post Box No. 80, Mahatma Gandhi Marg (0522) 2628227 (0522) 2611547
Lucknow - 226 001, India
Page 388 Page 389

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Gujarat State Disaster Management Authority

* BEFORE AN EMERGENCY – BECOME FAMILIAR WITH THIS GUIDEBOOK!

(Having Subsidiary hazard class label)

1 = Water Jet 2 = Fog 3 = Foam 4 = Dry Agent

Natural Gas Transmission Pipelines

Considerations For Establishing Protective Action Distance:

PUBLIC SAFETY (cryogenic liquid), non - 1021 126 1-Chloro-1,2,2,2

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Guide No. Type of Substance Page No.

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