Product name: Kuraray Poval SDS TURKEY

Version No.: 01 Issue date: 11-June-2014 Revision date: - 1/5

SAFETY DATA SHEET

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

Identification of the Kuraray Poval
substance/preparation
Use of the For industrial use only. Additive. Adhesive. Auxiliary. Binder. Coatings. Protective
substance/preparation colloid/dispersing agent. Raw material.
Version No. 01
Issue date 11-June-2014
Revision date -
Synonym(s) Product grades covered by this safety data sheet see below:
22-88 MB
Chemical name Polyvinyl alcohol, partially saponified
Manufacturer
Supplier: Kuraray Europe GmbH
Philipp-Reis-Str. 4
D-65795 Hattersheim
+49-69-305-85300
Technical Contact: +49-69-305-6201
Emergency telephone: +49-69-305-6418
E-mail address: product-safety@kuraray.eu

2. HAZARDS IDENTIFICATION
Physical hazards Not classified as a physical hazard.
Health hazards Not classified for health hazards. However, occupational exposure to the mixture or substance(s)
may cause adverse health effects.
Environmental hazards Not classified as an environmental hazard.
Specific hazards Dusts may irritate the respiratory tract, skin and eyes. Exposed may experience eye tearing,
redness, and discomfort. Liberated dust may irritate throat and respiratory system and cause
coughing. Prolonged contact may cause dryness of the skin. Fine particles may form explosive
mixtures with air.
Main symptoms Coughing.

3. COMPOSITION/INFORMATION ON INGREDIENTS
Components CAS No. Percent EC-No. Classification
Polyvinyl alcohol, partially 25213-24-5 >93
saponified
Methanol (impurity) 67-56-1 <3 200-659-6 F;R11, T;R23/24/25-39/23/24/25

Composition comments All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in
percent by volume. This product contains additives in low concentrations with no impact on the
evaluation of its hazard properties.

4. FIRST-AID MEASURES
Inhalation If dust from the material is inhaled, remove the affected person immediately to fresh air. Call a
physician if symptoms develop or persist.
Skin contact Rinse skin with water. Get medical attention if irritation develops and persists.
Eye contact Do not rub eye. Rinse with water. Get medical attention if irritation develops and persists.
Notes to physician Provide general supportive measures and treat symptomatically.

5. FIRE-FIGHTING MEASURES
Suitable extinguishing media Use fire-extinguishing media appropriate for surrounding materials.
Extinguishing media which Do not use a solid water stream as it may scatter and spread fire.
must not be used for safety
reasons
Unusual fire & explosion The product is not flammable. The product may form dust and can accumulate electrostatic
hazards charges, which may cause an electrical spark (ignition source). Use proper grounding procedures.
Specific hazards During fire, gases hazardous to health may be formed.
Product name: Kuraray Poval SDS TURKEY
Version No.: 01 Issue date: 11-June-2014 Revision date: - 2/5

Special protective equipment Selection of respiratory protection for firefighting: follow the general fire precautions indicated in
for fire-fighters the workplace. Self-contained breathing apparatus and full protective clothing must be worn in
case of fire.
Fire fighting Use standard firefighting procedures and consider the hazards of other involved materials.
equipment/instructions
Hazardous combustion Carbon oxides.
products

6. ACCIDENTAL RELEASE MEASURES

Personal precautions Avoid inhalation of dust and contact with skin and eyes. Wear appropriate personal protective
equipment.
Environmental precautions Environmental manager must be informed of all major spillages.
Methods for cleaning up Avoid dust formation. Collect dust or particulates using a vacuum cleaner with a HEPA filter. Do
not use compressed air when cleaning. For waste disposal, see section 13 of the SDS.

7. HANDLING AND STORAGE

Handling Avoid inhalation of dust and contact with skin and eyes. Wear appropriate personal protective
equipment. Wash hands after handling. Observe good industrial hygiene practices. Maintenance:
Use work methods which minimise dust production. Use only in well-ventilated areas. Take
precautionary measures against static discharges when there is a risk of dust explosion.
Storage Keep in original container. Store in a cool, dry, well-ventilated place. Store away from incompatible
materials. Read and follow manufacturer's recommendations.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Occupational exposure limits
US. ACGIH Threshold Limit Values

Components Type Value Form

Dust (CAS -) TWA 3 mg/m3 Respirable particles.
10 mg/m3 Inhalable particles.
Methanol (impurity) (CAS STEL 250 ppm
67-56-1)
TWA 200 ppm
Turkey. MAK (Ordinance No. 1475 on Precautions Required in Workplaces Working with Flammable, Explosive,
Dangerous and Harmful Substances, Annexes 1-3 (1973))

Components Type Value

Methanol (impurity) (CAS MAK 260 mg/m3
67-56-1)
200 ppm
Turkey. OELs. Regulation on Protection of Health & Safety Measures from Risks related to Chemical Agents at Work,
Annex I, Indicative Occupational Exposure Limit Values

Components Type Value

Methanol (impurity) (CAS TWA 260 mg/m3
67-56-1)
200 ppm
Biological limit values
ACGIH Biological Exposure Indices

Components Value Determinant Specimen Sampling time

Methanol (impurity) (CAS 15 mg/l Methanol Urine *
67-56-1)
* - For sampling details, please see the source document.
Recommended monitoring procedures
Additional exposure data Not available.
US ACGIH Threshold Limit Values: Skin designation
Methanol (impurity) (CAS 67-56-1) Can be absorbed through the skin.
Engineering measures Provide sufficient ventilation for operations causing dust formation. Follow above occupational
exposure limit values for dusts. Ventilate as needed to control airborne dust. Use explosion-proof
electrical equipment if airborne dust levels are high.
Personal protective equipment
Respiratory protection In case of inadequate ventilation or risk of inhalation of dust, use suitable respiratory equipment
with particle filter (type P2).
Product name: Kuraray Poval SDS TURKEY
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Hand protection It is a good industrial hygiene practice to minimise skin contact. For prolonged or repeated skin
contact use suitable protective gloves.
Eye protection Risk of contact: Wear approved safety goggles.
Skin and body protection Wear suitable protective clothing. It is a good industrial hygiene practice to minimise skin contact.
Environmental exposure Contain spills and prevent releases and observe national regulations on emissions.
controls
Hygiene measures Handle in accordance with good industrial hygiene and safety practices. Routinely wash work
clothing and protective equipment to remove contaminants.
Control parameters Follow standard monitoring procedures.

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance Granules.
Physical state Solid.
Form Granules.
Colour White.
Odour Odourless.
Odour threshold Not available.
pH 4,5 - 7
Boiling point Not applicable
Flash point > 93,0 °C (> 199,4 °F)
Flammability limits in air, Not available.
upper, % by volume
Flammability limits in air, Not available.
lower, % by volume
Vapour pressure Not available.
Solubility (water) Not available.
Partition coefficient No data available.
(n-octanol/water)
Viscosity Not available.
Vapour density Not available.
Evaporation rate Not available.
Melting point/freezing point Not available.
Auto-ignition temperature Not available.
VOC Not available.
Bulk density 400 - 600 kg/m3
Percent volatile < 5 % w/w
Molecular formula (C4H6O2.C2H4O)x

10. STABILITY AND REACTIVITY

Conditions to avoid Contact with incompatible materials. Avoid dust close to ignition sources.
Hazardous decomposition Carbon oxides.
products
Stability Material is stable under normal conditions.
Materials to avoid Strong oxidising agents. Strong acids.
Hazardous polymerisation Hazardous polymerisation does not occur.

11. TOXICOLOGICAL INFORMATION

Toxicological data
Components Species Test results
Methanol (impurity) (CAS 67-56-1)
Acute
Dermal
LD50 Rabbit 17100 mg/kg
Inhalation
LC50 Rat 128200 mg/m³, 4 Hours
Oral
LD50 Rat 1187 - 2769 mg/kg
Product name: Kuraray Poval SDS TURKEY
Version No.: 01 Issue date: 11-June-2014 Revision date: - 4/5

Acute toxicity Dusts may irritate the respiratory tract, skin and eyes.
Routes of exposure Eye contact. Inhalation. Skin contact.
Toxicological information Dusts or powder may irritate the respiratory tract, skin and eyes. May be harmful if swallowed.
May be harmful if inhaled. Components of the product may be absorbed into the body through the
skin.
Chronic toxicity Frequent inhalation of dust over a long period of time increases the risk of developing lung
diseases. Prolonged and repeated overexposure to dust can lead to pneumoconiosis. Pre-existing
skin and respiratory conditions including dermatitis, asthma and chronic lung disease might be
aggravated by exposure to this product.
Sensitisation Not a skin sensitiser.
Carcinogenicity Not classified.
Mutagenicity Not expected to be mutagenic.
Reproductivity Not classified.
Epidemiology Frequent inhalation of dust over a long period of time increases the risk of developing lung
diseases.
Local effects Dust may irritate the eyes. Inhalation of dusts may cause respiratory irritation.
Symptoms and target organs Dust may irritate throat and respiratory system and cause coughing. Direct contact with eyes may
cause temporary irritation.
Further information Pre-existing skin and respiratory conditions including dermatitis, asthma and chronic lung disease
might be aggravated by exposure.

12. ECOLOGICAL INFORMATION

Ecotoxicological data
Components Species Test results
Methanol (impurity) (CAS 67-56-1)
Aquatic
Algae EC50 Algae 22000 mg/l, 96 hours
Crustacea EC50 Daphnia magna > 10000 mg/l, 48 hours
Fish LC50 Lepomis macrochirus 15400 mg/l, 96 hours

Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Persistence and degradability No data available.
Bioaccumulation No data available.
Mobility No data available.

13. DISPOSAL CONSIDERATIONS

Disposal instructions Dispose of in accordance with local regulations.
Waste from residues / unused Dispose of in accordance with local regulations.
products
Contaminated packaging Dispose of in accordance with local regulations.
EU wastecodes 07 02 13
Waste codes should be assigned by the user based on the application for which the product was
used.

14. TRANSPORT INFORMATION

ADR
Not regulated as dangerous goods.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
Transport in bulk according to Not available.
Annex II of MARPOL73/78 and
the IBC Code

15. REGULATORY INFORMATION

Labelling
R-phrase(s) None.
S-phrase(s) None.
This preparation is not classified as dangerous, although it contains dangerous components below regulatory thresholds.
Product name: Kuraray Poval SDS TURKEY
Version No.: 01 Issue date: 11-June-2014 Revision date: - 5/5

16. OTHER INFORMATION

Wording of the R-phrases in R11 Highly flammable.
sections 2 and 3 R23/24/25 Toxic by inhalation, in contact with skin and if swallowed.
R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with
skin and if swallowed.
Recommended use For industrial use only. Additive. Adhesive. Auxiliary. Binder. Coatings. Protective
colloid/dispersing agent. Raw material.
Further information The substance is classified based on test data for physical hazards. The classification for health
and environmental hazards is derived by a combination of calculation methods and test data, if
available. For details, refer to Sections 9, 11 and 12.

Disclaimer This information is provided without warranty. The information is believed to be correct. This
information should be used to make an independent determination of the methods to safeguard
workers and the environment.