SAFETY DATA SHEET

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SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE

COMPANY/UNDERTAKING

Product identifier
Trade name DECIS® 100 EC INSECTICIDE
Product code (UVP) 05943388
SDS Number 102000002876
PCP Registration No. 33700

Relevant identified uses of the substance or mixture and uses advised against
Use Insecticide
Restrictions on use See product label for restrictions.
Information on supplier
Supplier Bayer CropScience Inc
#200, 160 Quarry Park Blvd, SE
Calgary, Alberta T2C 3G3
Canada
Responsible Department Email: SDSINFO.BCS-NA@bayer.com
Emergency telephone no.
<strong>Emergency Telephone Number (24hr/
Emergency Telephone 7 days) </strong> 1-800-334-7577
1-800-334-7577
Number (24hr/ 7 days)
<strong>Product Information Telephone
Product Information Number </strong>
1-888-283-6847
1-888-283-6847
Telephone Number

SECTION 2: HAZARDS IDENTIFICATION

Classified in accordance with Part 2 of the Hazardous Products Regulations

Aspiration hazard, Serious eye damage: Category 1
Acute toxicity(Oral, Inhalation): Category 4
Specific target organ toxicity - single exposure: Category 3
Flammable liquids: Category 3

Labelling in accordance with Part 3 of the Hazardous Products Regulations

Signal word: Danger

Hazard statements
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May be fatal if swallowed and enters airways.

Causes serious eye damage.
Harmful if swallowed or if inhaled.
May cause respiratory irritation.
May cause drowsiness or dizziness.
Flammable liquid and vapour.
Precautionary statements
Wear protective gloves/ eye protection/ face protection.
Wash thoroughly after handling.
Do not eat, drink or smoke when using this product.
Avoid breathing mist/ spray.
Use only outdoors or in a well-ventilated area.
Keep away from open flames/hot surfaces. - No smoking.
Keep container tightly closed.
Ground/bond container and receiving equipment.
Use explosion-proof electrical/ ventilating/ lighting/ equipment.
Use only non-sparking tools.
Take precautionary measures against static discharge.
IF SWALLOWED: Immediately call a POISON CENTER/doctor/ physician.
Do NOT induce vomiting.
Rinse mouth.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
Immediately call a POISON CENTER/doctor/ physician.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/
shower.
In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.
Store locked up.
Store in a well-ventilated place. Keep container tightly closed.
Keep cool.
Dispose of contents/container in accordance with local regulation.

Hazards Not Otherwise Classified (HNOC)

No physical hazards not otherwise classified.
No health hazards not otherwise classified.

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

Hazardous Component Name CAS-No. Concentration % by weight

Deltamethrin 52918-63-5 10.50
2-Methylpropan-1-ol 78-83-1 1.3
Cyclohexanone 108-94-1 36.8
Hydrocarbons, C9, aromatics 64742-95-6 44.0
Benzenesulfonic acid, mono-C11-13-branched alkyl 68953-96-8 2.9
derivs., calcium salts
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SECTION 4: FIRST AID MEASURES

Description of first aid measures

General advice When possible, have the product container or label with you when
calling a poison control center or doctor or going for treatment.
Inhalation Move to fresh air. If person is not breathing, call 911 or an ambulance,
then give artificial respiration, preferably mouth-to-mouth if possible.
Call a physician or poison control center immediately.
Skin contact Take off contaminated clothing and shoes immediately. Wash off
immediately with plenty of water for at least 15 minutes. Call a
physician or poison control center immediately.
Eye contact Hold eye open and rinse slowly and gently with water for 15-20
minutes. Remove contact lenses, if present, after the first 5 minutes,
then continue rinsing eye. Call a physician or poison control center
immediately.
Ingestion Call a physician or poison control center immediately. Rinse out mouth
and give water in small sips to drink. DO NOT induce vomiting unless
directed to do so by a physician or poison control center. Never give
anything by mouth to an unconscious person. Do not leave victim
unattended.
Most important symptoms and effects, both acute and delayed
Symptoms Local:, Skin and eye paraesthesia which may be severe, Usually
transient with resolution within 24 hours, Skin, eye and mucous
membrane irritation, Cough, Sneezing
Systemic:, discomfort in the chest, tachycardia, Hypotension, Nausea,
Abdominal pain, Diarrhoea, Vomiting, Blurred vision, Headache,
Anorexia, Somnolence, Coma, Convulsions, Tremors, Prostration,
Airway hyperreaction, Pulmonary oedema, Palpitation, Muscular
fasciculation, Apathy, Dizziness
Indication of any immediate medical attention and special treatment needed
Risks This product contains a pyrethroid. Pyrethroid poisoning should not be
confused with carbamate or organophosphate poisoning.
Treatment Systemic treatment: Initial treatment: symptomatic. Monitor: respiratory
and cardiac functions. In case of ingestion gastric lavage should be
considered in cases of significant ingestions only within the first 2
hours. However, the application of activated charcoal and sodium
sulphate is always advisable. Keep respiratory tract clear. Oxygen or
artificial respiration if needed. In case of convulsions, a
benzodiazepine (e.g. diazepam) should be given according to standard
regimens. If not effective, phenobarbital may be used.
Contraindication: atropine. Contraindication: derivatives of adrenaline.
There is no specific antidote. Recovery is spontaneous and without
sequelae.
In case of skin irritation, application of oils or lotions containing vitamin
E may be considered.
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SECTION 5: FIREFIGHTING MEASURES

Extinguishing media
Suitable Use water spray, alcohol-resistant foam, dry chemical or carbon
dioxide.
Unsuitable High volume water jet

<strong>Special
Special hazards arisinghazards arising
Dangerous gasesfrom the substance
are evolved in the event of aor
fire.mixture </strong>
from the substance or
Dangerous
mixture gases are evolved in the event of a fire.
Advice for firefighters
<strong>Special protective equipment for firefighters</strong> Firefighters
Special protective Firefighters should wearshould
NIOSHwearapproved
NIOSH approved self-contained breathing
self-contained breathing apparatus
and full protective clothing.
equipment for firefighters apparatus and full protective clothing.
Further information Keep out of smoke. Fight fire from upwind position. Cool closed
containers exposed to fire with water spray. Do not allow run-off from
fire fighting to enter drains or water courses.
Flash point 40 °C
Auto-ignition temperature No data available
Lower explosion limit No data available
Upper explosion limit No data available
Explosivity Not applicable

SECTION 6: ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Precautions Avoid contact with spilled product or contaminated surfaces. Remove
all sources of ignition. Keep unauthorized people away. Isolate hazard
area.
Methods and materials for containment and cleaning up
Methods for cleaning up Soak up with inert absorbent material (e.g. sand, silica gel, acid
binder, universal binder, sawdust). Clean contaminated floors and
objects thoroughly, observing environmental regulations. Keep in
suitable, closed containers for disposal.
Additional advice Use personal protective equipment. If the product is accidentally
spilled, do not allow to enter soil, waterways or waste water canal.
Reference to other sections Information regarding safe handling, see section 7.
Information regarding personal protective equipment, see section 8.
Information regarding waste disposal, see section 13.
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SECTION 7: HANDLING AND STORAGE

Precautions for safe handling

Advice on safe handling Use only in area provided with appropriate exhaust ventilation.
<strong>Advice on protection against fire and explosion</strong> Keep away from heat and sources of ignition. Take measures
Advice on protection Keep away from heat and sources of ignition. Take measures to prevent
to prevent fire
against the build
and up of electrostatic
explosion charge.
the build Vapours may form explosive
up of electrostatic charge. mixture
Vapours with
mayair. form explosive mixture
with air.
Hygiene measures Wash hands thoroughly with soap and water after handling and before
eating, drinking, chewing gum, using tobacco, using the toilet or
applying cosmetics.
Remove Personal Protective Equipment (PPE) immediately after
handling this product. Before removing gloves clean them with soap and
water. Remove soiled clothing immediately and clean thoroughly before
using again. Wash thoroughly and put on clean clothing.
Conditions for safe storage, including any incompatibilities
<strong>Requirements
Requirements for for storage
storage areas and containers</strong>
Keep Keep containers
containers tightly closedtightly
in a closed in a dry,
dry, cool and cool and well-ventilatedplace.
well-ventilated place. Store
inareas
a placeand
accessible by authorized personsStore
containers only. Store
in ainplace
originalaccessible
container. Keep
byaway from directpersons
authorized sunlight. only. Store in original
container. Keep away from direct sunlight.
Advice on common storage Keep away from food, drink and animal feedingstuffs.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters
Components CAS-No. Control parameters Update Basis
Deltamethrin 52918-63-5 0.01 mg/m3 OES BCS*
(TWA)
2-Methylpropan-1-ol 78-83-1 152 mg/m3/50 ppm 07 2009 CAD AB
(TWA) OEL

2-Methylpropan-1-ol 78-83-1 50 ppm 09 2011 CAD BC

(TWA) OEL

2-Methylpropan-1-ol 78-83-1 50 ppm 03 2011 CAD MB

(TWA) OEL

2-Methylpropan-1-ol 78-83-1 50 ppm 11 2010 CAD ON

(TWA) OEL

2-Methylpropan-1-ol 78-83-1 60 ppm 05 2009 CAD SK

(15 MIN ACL) OEL

2-Methylpropan-1-ol 78-83-1 50 ppm (8 HR50

ACL)
ppm 05 2009 CAD
CADSKSK
OEL
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152 mg/m3/50 ppmACL)

(8 HR (TWA) OEL
OEL(QUE)

2-Methylpropan-1-ol 78-83-1 152 mg/m3/50 ppm 11 2011 OEL (QUE)

(TWA)
Cyclohexanone 108-94-1 80 mg/m3/20 ppm 07 2009 CAD AB
(TWA) OEL

Cyclohexanone 108-94-1 200 mg/m3/50 ppm 07 2009 CAD AB

(STEL) OEL

Cyclohexanone 108-94-1 20 ppm 09 2011 CAD BC

(TWA) OEL

Cyclohexanone 108-94-1 50 ppm 09 2011 CAD BC

(STEL) OEL

Cyclohexanone 108-94-1 20 ppm 03 2011 CAD MB

(TWA) OEL

Cyclohexanone 108-94-1 50 ppm 03 2011 CAD MB

(STEL) OEL

Cyclohexanone 108-94-1 20 ppm 11 2010 CAD ON

(TWA) OEL

Cyclohexanone 108-94-1 50 ppm 11 2010 CAD ON

(STEL) OEL

Cyclohexanone 108-94-1 20 ppm 05 2009 CAD SK

(8 HR ACL) OEL

Cyclohexanone 108-94-1 50 ppm 05 2009 CAD SK

(15 MIN ACL) OEL

Cyclohexanone 108-94-1 100 mg/m3/25 ppm 11 2011 OEL (QUE)

(TWA)
*OES BCS: Internal Bayer AG, Crop Science Division "Occupational Exposure Standard"
Exposure controls
Personal protective equipment
In normal use and handling conditions please refer to the label and/or leaflet. In all other cases the
following recommendations would apply.
Respiratory protection When respirators are required, select NIOSH approved equipment
based on actual or potential airborne concentrations and in
accordance with the appropriate regulatory standards and/or industry
recommendations.

Hand protection Chemical-resistant gloves (barrier laminate, butyl rubber, nitrile

rubber or Viton)
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Eye protection Use tightly sealed goggles and face protection.

Skin and body protection Wear long-sleeved shirt and long pants and shoes plus socks.
General protective measures Follow manufacturer's instructions for cleaning/maintaining PPE. If
no such instructions for washables, use detergent and warm/tepid
water.
Keep and wash PPE separately from other laundry.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Form Liquid, clear
Colour light yellow to brown
Odour aromatic
Odour Threshold No data available
pH 4.5 - 7.0 (1 %) (23 °C) (deionized water)
Melting point/range No data available
Boiling Point
No data available
Flash point 40 °C
Flammability No data available
Auto-ignition temperature No data available

Minimum ignition energy Not applicable

<strong>Self-accelarating
Self-accelarating No decomposition
data available temperature (SADT)
</strong> No data available
decomposition temperature
(SADT)
Upper explosion limit No data available
Lower explosion limit No data available
Vapour pressure No data available
Evaporation rate No data available
Relative vapour density No data available
Relative density No data available
Density ca. 0.95 g/cm³ (20 °C)

Water solubility miscible

<strong>Partition coefficient: n- octanol/water</strong> Deltamethrin: log Pow:
Partition coefficient: n- Deltamethrin: log Pow: 6.4 (25 °C)
6.4 (25 °C)Solvent Naphtha (petroleum), light aromatic:Not applicable
octanol/water
Solvent Naphtha (petroleum), light aromatic:
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<strong>Viscosity, dynamic </strong> No data available

Not applicable

Viscosity, dynamic No data available

Viscosity, kinematic ca. 1.77 mm²/s (40 °C)

Surface tension ca. 29.8 mN/m (40 °C)
Oxidizing properties No data available
Explosivity Not applicable
Other information Further safety related physical-chemical data are not known.

SECTION 10: STABILITY AND REACTIVITY

Reactivity Stable under normal conditions.

Thermal decomposition Stable under normal conditions.
Chemical stability Stable under recommended storage conditions.

<strong>Possibility of hazardous
Possibility of hazardous reactions
No hazardous </strong>
reactions No hazardous
when stored reactions
and handled accordingwhen
to stored
and handled according toprescribed
reactions prescribed instructions.
instructions.

Conditions to avoid Extremes of temperature and direct sunlight.

Incompatible materials No incompatible materials known.

<strong>Hazardous decomposition
Hazardous decomposition products</strong>
No decomposition No expected
products decomposition products
under normal expected
conditions of under
use.
normal conditions of use.
products

SECTION 11: TOXICOLOGICAL INFORMATION

Exposure routes Eye contact, Skin contact, Inhalation, Ingestion

Immediate Effects
Eye Corrosive to eyes.
Skin May cause irritation.
Ingestion Harmful or fatal if swallowed.
Inhalation Harmful if inhaled.
Information on toxicological effects
Acute oral toxicity LD50 (Rat) 633 mg/kg
Acute inhalation toxicity ATE (Mix) 2.4 mg/l
Calculation method
Acute dermal toxicity LD50 (Rat) > 4,000 mg/kg
Skin corrosion/irritation No skin irritation (Rabbit)
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<strong>Serious
Serious eyeeye damage/eye irritation </strong>
damage/eye Severe Severe eye irritation.
eye irritation. (Rabbit)
(Rabbit)
irritation
Respiratory or skin Skin: Non-sensitizing. (Guinea pig)
sensitisation OECD Test Guideline 406, Buehler test
Assessment STOT Specific target organ toxicity – single exposure
Deltamethrin: Based on available data, the classification criteria are not met.
Solvent Naphtha (petroleum), light aromatic: May cause respiratory irritation., Solvent Naphtha
(petroleum), light aromatic: May cause drowsiness or dizziness.
Assessment STOT Specific target organ toxicity – repeated exposure
Deltamethrin caused neurobehavioral effects and/or neuropathological changes in animal studies. The
toxic effects of Deltamethrin are related to transient neurobehavioral effects typical for pyrethroid
neurotoxicity.
Solvent Naphtha (petroleum), light aromatic: Based on available data, the classification criteria are not
met.
Assessment mutagenicity
Deltamethrin was not mutagenic or genotoxic in a battery of in vitro and in vivo tests.
Solvent Naphtha (petroleum), light aromatic is not considered mutagenic.
Assessment carcinogenicity
Deltamethrin was not carcinogenic in lifetime feeding studies in rats and mice.
Solvent Naphtha (petroleum), light aromatic: Based on available data, the classification criteria are not
met.

<strong>ACGIH</strong>
ACGIH <br>Cyclohexanone <br>108-94-1
<br>Group A3 <p> <strong>NTP</strong>
Cyclohexanone 108-94-1 Group A3
NTP
<br>None. <p> <strong>IARC</strong>
None.
<br>Deltamethrin <br>52918-63-5
IARC
<br>Overall evaluation: 3 <br>Cyclohexanone
Deltamethrin 52918-63-5 Overall evaluation: 3
Cyclohexanone 108-94-1 Overall evaluation: 3
<br>108-94-1
OSHA
<br>Overall evaluation:
3None.<p> <strong>OSHA</strong> <br>None.

Assessment toxicity to reproduction

Deltamethrin did not cause reproductive toxicity in a two-generation study in rats.
Solvent Naphtha (petroleum), light aromatic: Based on available data, the classification criteria are not
met.
Assessment developmental toxicity
Deltamethrin caused developmental toxicity only at dose levels toxic to the dams. The developmental
effects seen with Deltamethrin are related to maternal toxicity.
Solvent Naphtha (petroleum), light aromatic: This information is not available.
Aspiration hazard
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May be fatal if swallowed and enters airways.

Further information
Cutaneous sensations may occur, such as burning or stinging on the face and mucosae. However,
these sensations cause no lesions and are of a transitory nature (max. 24 hours).
Acute toxicity studies have been bridged from a similar formulation(s).
The non-acute information pertains to the active ingredient(s).

SECTION 12: ECOLOGICAL INFORMATION

Toxicity to fish LC50 (Oncorhynchus mykiss (rainbow trout)) 0.0051 mg/l

Exposure time: 96 h
<strong>Toxicity
Toxicity to aquatic to aquatic invertebrates
EC50 (Daphnia </strong>
magna (Water EC50
flea)) 0.00078 mg/l (Daphnia magna
invertebrates Exposure time: 48 h
(Water flea)) 0.00078 mg/l Exposure time: 48 h

Toxicity to aquatic plants EC50 (Raphidocelis subcapitata (freshwater green alga)) 29.5 mg/l
Biomass; Exposure time: 72 h
EC50 (Raphidocelis subcapitata (freshwater green alga)) > 72.6 mg/l
Growth rate; Exposure time: 72 h
Biodegradability Deltamethrin:
Not rapidly biodegradable
Solvent Naphtha (petroleum), light aromatic:
rapidly biodegradable
Koc Deltamethrin: Koc: 10240000
Bioaccumulation Deltamethrin: Bioconcentration factor (BCF) 1,400
Does not bioaccumulate.
Solvent Naphtha (petroleum), light aromatic:
No data available
Mobility in soil Deltamethrin: Immobile in soil
Solvent Naphtha (petroleum), light aromatic: Slightly mobile in soils
Results of PBT and vPvB assessment
PBT and vPvB assessment Deltamethrin: This substance is not considered to be persistent,
bioaccumulative and toxic (PBT). This substance is not considered to be
very persistent and very bioaccumulative (vPvB).
Solvent Naphtha (petroleum), light aromatic: This substance is not
considered to be persistent, bioaccumulative and toxic (PBT). This
substance is not considered to be very persistent and very
bioaccumulative (vPvB).
<strong>Additional
Additional ecologicalecological
Noinformation</strong> No other effects to be mentioned.
other effects to be mentioned.
information
Environmental
Environmental precautions Do not
precautions Do apply directly
not apply to water,
directly to areas
to water, where
to areas wheresurface
surfacewater
waterisispresent
presentor to
intertidal areas below the meanor
high water mark.
to intertidal areasDo not contaminate
below the mean high surface or ground water by cleaning
water mark.
equipment or disposal of wastes,
Doincluding equipment
not contaminate wash
surface orwater.
ground water by cleaning equipment or
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Drift and runoff

disposal from
of wastes, treated
including areas may
equipment washbe hazardous to aquatic
water.
Drift and runoff from treated areas may be hazardous to aquatic
organisms
organisms in adjacent
in adjacent sites.
sites.
Do not apply when weather conditions favor runoff or drift.
Do not apply this product or allow it to drift to blooming crops or weeds if
bees are visiting the treatment area.
Notify state/provincial or local authorities and Bayer immediately if you
observe any adverse environmental effects due to the use of this
product.
Apply this product as specified on the label.

SECTION 13: DISPOSAL CONSIDERATIONS

Waste treatment methods

Product Follow container label instructions for disposal of wastes generated
during use in compliance with the product label.
Dispose in accordance with all local, state/provincial and federal
regulations.
Contaminated packaging Do not re-use empty containers.
Completely empty container into application equipment, then dispose of
empty container in a sanitary landfill, by incineration or by other
procedures approved by state/provincial and local authorities.
If burned, stay out of smoke.
Consult state and local regulations regarding the proper disposal of
container.
Follow advice on product label and/or leaflet.

SECTION 14: TRANSPORT INFORMATION

TDG
UN number 1993
Labels 3
Packaging group III
Marine pollutant Marine pollutant
Proper shipping name FLAMMABLE LIQUID, N.O.S.
(DELTAMETHRIN, SOLVENT NAPHTHA (PETROLEUM)
LIGHT AROMATIC)

49CFR
UN number 1993
Class 3
Packaging group III
Proper shipping name FLAMMABLE LIQUIDS, N.O.S.
(SOLVENT NAPHTHA (PETROLEUM) LIGHT AROMATIC,
CYCLOHEXANONE)
RQ Reportable Quantity is reached with 13,586 lb of product.
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IMDG
UN number 1993
Class 3
Packaging group III
Marine pollutant YES
Proper shipping name FLAMMABLE LIQUID, N.O.S.
(DELTAMETHRIN, SOLVENT NAPHTHA (PETROLEUM)
LIGHT AROMATIC SOLUTION)

IATA
UN number 1993
Class 3
Packaging group III
Environm. Hazardous Mark NO
Proper shipping name FLAMMABLE LIQUID, N.O.S.
(DELTAMETHRIN, SOLVENT NAPHTHA (PETROLEUM)
LIGHT AROMATIC SOLUTION )

This transportation information is not intended to convey all specific regulatory information relating to this
product. It does not address regulatory variations due to package size or special transportation
requirements.

Further Information In accordance with TDG regulations 3.6(3) and 4.22 this
product does not require marine pollutant safety marks or
shipping documentation reference when transported on land by
road or rail.

SECTION 15: REGULATORY INFORMATION

PCP Registration No. 33700

PMRA Information:
Read the label, authorized under the Pest Control Products Act, prior to using or handling the pest control
product.

This chemical is a pest control product regulated by Health Canada Pest Management Regulatory Agency
and is subject to certain labelling requirements under the Pest Control Products Act. These requirements
differ from the classification criteria and hazard information required for GHS-consistent safety data
sheets. The following is the hazard information required on the pest control product label:
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Signal word: Danger!

Hazard statements: Poison.

Corrosive to eyes.
Harmful or fatal if swallowed.
Harmful if inhaled.
May cause skin irritation.

There are Canada-specific environmental requirements for handling, use, and disposal of this pest control
product that are indicated on the label.

SECTION 16: OTHER INFORMATION

Abbreviations and acronyms

49CFR Code of Federal Regulations, Title 49
ACGIH US. ACGIH Threshold Limit Values
ATE Acute toxicity estimate
CAS-Nr. Chemical Abstracts Service number
CERCLA Comprehensive Environmental Response, Compensation, and Liability Act
EINECS European inventory of existing commercial substances
ELINCS European list of notified chemical substances
IARC International Agency for Research on Cancer
IATA International Air Transport Association
IMDG International Maritime Dangerous Goods
N.O.S. Not otherwise specified
NTP US. National Toxicology Program (NTP) Report on Carcinogens
OECD Organization for Economic Co-operation and Development
TDG Transportation of Dangerous Goods
TWA Time weighted average
UN United Nations
WHO World health organisation
NFPA 704 (National Fire Protection Association):
Health - 2 Flammability - 2 Instability - 1 Others - none
HMIS (Hazardous Materials Identification System, based on the Third Edition Ratings Guide)
Health - 2 Flammability - 2 Physical Hazard - 1 PPE -
0 = minimal hazard, 1 = slight hazard, 2 = moderate hazard, 3 = severe hazard, 4 = extreme hazard

Reason for Revision: The following sections have been revised: Section 12. Ecological information.
Section 15: Regulatory information. Reviewed and updated for general editorial purposes.

Revision Date: 04/27/2021

This information is provided in good faith but without express or implied warranty. The customer assumes
all responsibility for safety and use not in accordance with label instructions. The product names are
registered trademarks of Bayer.