9 Jeem 2023 April 12 First Shift Paper
9 Jeem 2023 April 12 First Shift Paper
9 Jeem 2023 April 12 First Shift Paper
Please read the instructions carefully. You are allotted 5 minutes specifically for this
purpose.
Important Instructions:
1. The test is of 3 hours duration.
2. This test paper consists of 90 questions. Each subject (PCM) has 30 questions. The
maximum marks are 300.
3. This question paper contains Three Parts. Part-A is Physics, Part-B is Chemistry and
Part-C is Mathematics. Each part has only two sections: Section-A and Section-B.
4. Section – A : Attempt all questions.
6. Section-A (01 – 20) contains 20 multiple choice questions which have only one correct
answer. Each question carries +4 marks for correct answer and –1 mark for wrong
answer.
7. Section-B (1 – 10) contains 10 Numerical based questions. The answer to each question
is rounded off to the nearest integer value. Each question carries +4 marks for correct
answer and –1 mark for wrong answer.
JEE-MAIN-2023 (12th April-First Shift)-PCM-2
PART – A (PHYSICS)
SECTION - A
(One Options Correct Type)
This section contains 20 multiple choice questions. Each question has four choices (A), (B), (C) and
(D), out of which ONLY ONE option is correct.
Q1. An engine operating between the boiling and freezing points of water will have
A. efficiency more than 27%.
B. efficiency less than the efficiency of a Carnot engine operating between the same two
temperatures.
C. efficiency equal to 27%
D. efficiency less than 27%
Q2. Given below are two statements : one is labelled as Assertion A and the other is labelled as
Reason R
Assertion A : EM waves used for optical communication have longer wavelengths than that of
microwave, employed in Radar technology.
Reason R : Infrared EM waves are more energetic than microwaves, (used in Radar) In the light
of given statements, choose the correct answer from the options given below.
(A) A is true but R is false
(B) Both A and R are true but R is NOT the correct explanation of A
(C) A is false but R is true
(D) Both A and R are true and R is the correct explanation of A
Q3. A wire of resistance160 is melted and drawn in a wire of one-fourth of its length. The new
resistance of the wire will be
(A) 10 (B) 40
(C) 640 (D) 16
Q5. Two satellites A and B move round the earth in the same orbit. The mass of A is twice the mass
of B. The quantity which is same for the satellites will be
(A) Potential energy (B) Total energy
(C) Speed (D) Kinetic energy
JEE-MAIN-2023 (12th April-First Shift)-PCM-3
Q6. If the r. m. s speed of chlorine molecule is 490m/s at 27 C, the r.m.s speed of argon molecules at
the same temperature will be (Atomic mass of argon = 39.9u, molecular mass of chlorine = 70.9
u)
(A) 751.7m/s (B) 551.7m/s
(C) 651.7m/s (D) 451.7m/s
Q7. The ratio of escape velocity of a planet to the escape velocity of earth will be :-
Given : Mass of the planet is 16 times mass of earth and radius of the planet is 4 times the radius
of earth.
(A) 1: 2 (B) 1 : 4
(C) 4 : 1 (D) 2 : 1
Q8. A ball is thrown vertically upward with an initial velocity of 150m/s. The ratio of velocity after 3s
x 1 2
and 5s is . The value of x is ________. { take, g = 10 m/s }
x
(A) 10 (B) 6
(C) 5 (D) – 5
Q10. A proton and an - particle are accelerated from rest by 2V and 4V potentials,respectively. The
ratio of their de-Broglie wavelength is :
(A) 8 : 1 (B) 4 : 1
(C) 16 : 1 (D) 2 : 1
Q11. A body cools from 80 C to 60 C in 5 minutes. The temperature of the surrounding is 20 C. The
time it takes to cool from 60 C to 40 C is :
(A) 450s (B) 500s
25
(C) 420s (D) s
3
Q12. An ice cube has a bubble inside. When viewed from one side the apparent distance of the bubble
is 12cm. When viewed from the opposite side, the apparent distance of the bubble is observed as
4cm. If the side of the ice cube is 24cm, the refractive index of the ice cube is
4 3
(A) (B)
3 2
6 2
(C) (D)
5 3
JEE-MAIN-2023 (12th April-First Shift)-PCM-4
Q14. A 12.5 eV electron beam is used to bombard gaseous hydrogen at room temperature. The
number of spectral lines emitted will be :
(A) 1 (B) 4
(C) 3 (D) 2
Q15. A particle is executing simple harmonic motion (SHM). The ratio of potential energy and kinetic
energy of the particle when its displacement is half of its amplitude will be
(A) 1 : 1 (B) 1 : 4
(C) 1 : 3 (D) 2 : 1
Q17. Given below are two statements : one is labelled as Assertion A and the other is labelled
as Reason R
Assertion A : If an electric dipole of dipole moment 30 105 C m is enclosed by a closed surface,
the net flux coming out of the surface will be zero.
Reason R : Electric dipole consists of two equal and opposite charges.
In the light of above, statements, choose the correct answer from the options given below.
(A) Both A and R are true and R is the correct explanation of A
(B) A is true but R is false
(C) A is false but R is true
(D) Both A and R true but R is NOT the correct explanation of A
Q18. The amplitude of 15 sin (1000 t ) is modulated by 10 sin (4 t ) signal. The amplitude modulated
signal contains frequencies of
A. 500 Hz
B. 2 Hz
C. 250 Hz
D. 498 Hz
E. 502 Hz
Choose the correct answer from the options given below :
(A) A, D and E only (B) A and C only
(C) A and B only (D) A and D only
JEE-MAIN-2023 (12th April-First Shift)-PCM-5
Q19. In an n-p-n common emitter (CE) transistor the collector current changes from 5 mA to 16
mA for the change in base current from 100 A and 200 A, respectively. The current gain
of transistor is _________.
(A) 9 (B) 0.9
(C) 110 (D) 210
Q20. Three forces F1 = 10 N, F2 = 8 N, F3 = 6 N are acting on a particle of mass 5 kg. The forces F2
and F3 are applied perpendicularly so that particle remains at rest. If the force F1 is removed, then
the acceleration of the particle is :
-2 -2
(A) 4.8 ms (B) 2 ms
-2
(C) 0.5 ms (D) 7 ms-2
JEE-MAIN-2023 (12th April-First Shift)-PCM-6
SECTION - B
(Numerical Answer Type)
This section contains 10 Numerical based questions. The answer to each question is rounded off to the
nearest integer value.
Q1. Glycerin of density 1.25 103 kg m 3 is flowing through the conical section of pipe. The area of
cross-section of the pipe at its ends are 10cm 2 and 5 cm 2 and pressure drop across its length is 3
Nm-2. The rate of flow of glycerin through the pipe is x 10 5 m3 s 1. The value of x is _______.
Q2. To maintain a speed of 80km/h by a bus of mass 500 kg on a plane rough road for 4 km distance,
the work done by the engine of the will be ______KJ. [ The coefficient of friction between type of
bus and road is 0.04. ]
Q3. A conducting circular loop is placed in a uniform magnetic field of 0.4 T with its plane
perpendicular to the field. Somehow, the radius of the loop starts expanding at a constant rate of
1 mm/s. The magnitude of induced emf in the loop at an instant when the radius of the loop is 2
cm will be ________ V.
Q4. A compass needle oscillates 20 times per minute at a place where the dip is 30 and 30 times per
minute where the dip is 60 . The ratio of total magnetic field due to the earth at two places
4
respectively is . The value of x is :
x
Q5. For a certain organ pipe, the first three resonance frequencies are in the ratio of 1 : 3 : 5
respectively. If the frequency of fifth harmonic is 405 Hz and the speed of sound in air is 324 ms-1
the length of the organ pipe is _______m
Q6. Two convex lenses of focal length 20cm each are placed coaxially with a sepration of 60cm
between them. The image of the distant object by the combination is at ______ cm from the first
lens.
Q7. The current flowing through a conductor connected across a source is 2 A and 1.2 A at 0 C and
100 C respectively. The current flowing through the conductor at 50 C will be ________
102 mA .
Q9. 64 identical drops each charged upto potential of 10 mV are combined to from a bigger drop. The
potential of the bigger drop will be _______mV.
x
Q10. For a rolling spherical shell, the ratio of rotational kinetic energy and total kinetic energy is . The
5
value of x is _______.
JEE-MAIN-2023 (12th April-First Shift)-PCM-7
PART – B (CHEMISTRY)
SECTION - A
(One Options Correct Type)
This section contains 20 multiple choice questions. Each question has four choices (A), (B), (C) and
(D), out of which ONLY ONE option is correct.
Q4. The bond order and magnetic property of acetylide ion are same as that of
(A) NO (B) O 2
(C) O 2 (D) N2
Q5. Four gases A,B,C and D have critical temperature 5.3, 33.2, 126.0 and 154.3K respectively. For
their adsorption on a fixed amount of charcoal, the correct order is
(A) C > D > B > A (B) D > C > A > B
(C) C > B > D> A (D) D> C> B > A
Q6. A metal chloride contains 55.0% of chlorine by weight. 100mL vapours of the metal chloride at
STP weigh 0.57g. The molecular formula of the metal chloride is (Given: Atomic mass of chlorine
is 35.5u)
(A) MCl (B) MCl2
(C) MCl4 (D) MCl3
JEE-MAIN-2023 (12th April-First Shift)-PCM-8
(i) O3
Q9. 2 hexene
(ii) H2 O
Pr oduct
The two products formed in above reaction are
(A) Butannoic acid and acetic acid (B) Butanoic acid and acetaldehyde
(C) Butanal and acetic acid (D) Butanal and acetaldehyde
B. Ti H2 O 6
3 II. 2.0
C. Fe CN6
3 III. 1.2
D. NiF
4 IV. 0.4
6
Q12. Given below are two statements: One is labelled as Assertion A and the other is labelled
as Reason R.
Assertion A: In the Ellingham diagram, a sharp change in slope of the line is observed for
o
MgMgO at 1120 C
Reason R: There is a large change of entropy associated with the change of state.
In the light of the above statements, choose the correct answer from the options given below:
(A) A is true but R is false
(B) A is false but R is true
(C) Both A and R are true and R is the correct explanation of A
(D) Both A and R are true but R is NOT the correct explanation of A
Q13. Match List I with List II
List I- Example List II - Type
A. 2-chloro-1,3-butadiene I. Biodegradable polymer
B. Nylon2-nylon6 II. Synthetic Rubber
C. Polyacrylonitrile III. Polyester
D. Dacron IV. Addition polymer
Choose the correct answer from the option given below :
(A) A-II, B- I, C-IV, D-III (B) A-IV, B-III, C-I, D-II
(C) A-II, B-IV, C-I, D-III (D) A-IV, B-I, C-III, D-II
Q14. Given below are two statements: One is labelled as Assertion A and the other is labelled
as Reason R.
Assertion A 5f electrons can participate in bonding to a far greater extent than 4f electrons
Reason R: 5f orbitals are not as buried as 4f orbitals
In the light of the above statements, choose the correct answer from the options given below:
(A) A is false but R is true
(B) A is true but R is false
(C) Both A and R are true but R is NOT the correct explanation of A
(D) Both A and R are true and R is the correct explanation of A
Q15.
O
Me C
OEt
C CH3 'A'
O major Product
O O
(A) Me C C CH3
C CH C
Me O
Me
O
(B) C CH3
Me
(C)
O
JEE-MAIN-2023 (12th April-First Shift)-PCM-10
O
O
C CH3
(D) Me C
C C
C CH3
Me
O
z
X, Y and Z respectively are
(A) X Y Z
CaCO3 NaCl HCl
(B) X Y Z
CaO NaCl+ CO2 KCl
(C) X Y Z
CaO NaCl+CO2 NaCl
(D) X Y Z
CaCO3 NaCl KCl
(A) (B)
Br
OH
OH O
Q19. The major product ‘P’ formed in the following sequence of reaction is
OH (i) SOCl2
(ii) R-NH2
O (iii) LiAlH4
(iv) H3O+
H H
N R N R
(A) (B)
OH
H N R
H
OH N R
(C) (D)
Cl O
+ NaNO 2 + HX 'B'
(A) The product ‘B’ formed in the above reaction is p-nitroso compound at low temperature
(B) ‘B’ is N- nitroso ammonium compound
(C) The electrophile involved in the reaction NO+
(D) The reaction occurs at low temperature
JEE-MAIN-2023 (12th April-First Shift)-PCM-12
SECTION - B
(Numerical Answer Type)
This section contains 10 Numerical based questions. The answer to each question is rounded off to the
nearest integer value.
Q1. An analyst wants to convert 1L HCl of pH = 1 to a solution of HCl of pH 2. the volume of water
needed to do this dilution is______ mL. (Nearest integer)
2
Q2. In an oligopeptide named Alanylglycylphenyl alanyl isoeucine, the number of sp hybridised
arbons is__________.
Q3. 80 mole percent of MgCl2 is dissociated in aqueous solution. The vapour pressure of 1.0 molal
aqueous solution of MgCl2 is ___________. mm Hg (Nearest integer)
Given: Vapour pressure of water at 38oC is 50 mm Hg.
Q4. Value of work function (W 0) for a few metals are given below.
Metal Li Na K Mg Cu Ag
W 0 / eV 2.42 2.3 2.25 3.7 4.8 4.3
The number of metals which will show photoelectric effect when light of wavelength 400 nm falls
on it is____________.
Given: h = 6.6 1034Js
c = 3108m s1
e = 1.6 1019C
Q5.
(i) NH4Cl / KCN Conc. HNO3-H2SO4
H5 C2 O CH2CHO 'A' 'B'
+
(ii) H2SO4 / H 2eq
(i) (CH3CO)2O
(ii) EtOH,
(iii) H2, Pd / C
(iv) HNO2
(v) NaI
'D'
(C xH19 NO4I 2)
The value of x in compound ‘D’ is______________.
Q7. At 600K, the root mean square (rms) speed of X (molar mass = 40) is equal to the most
probable speed of gas Y at 90K. The molar mass of the gas Y is ___________ g mol 1.
(Nearest integer)
Q8. One mole of an ideal gas at 350K is in a 2.0 L vessel of thermally conducting walls, which are in
contact with the surrounding. It undergoes isothermal reversible expansion from 2.0L to 3.0 L
against constant pressure of 4 atm. The change in entropy of the surrounding (S)
is____________ JK1) (Nearest integer)
JEE-MAIN-2023 (12th April-First Shift)-PCM-13
Q10. The mass of NH3 produced when 131.8 kg of cyclohexanecarbaldehyde undergoes Tollen’s test
is _________kg. (Nearest integer)
Molar mass of C = 12g/mol
N = 14g/mol
O = 16 g / mol
JEE-MAIN-2023 (12th April-First Shift)-PCM-14
PART – C (MATHEMATICS)
SECTION - A
(One Options Correct Type)
This section contains 20 multiple choice questions. Each question has four choices (A), (B), (C) and
(D), out of which ONLY ONE option is correct.
Q1. Two dices A and B are rolled. Let the numbers obtained on A and B be and respectively. If
p
the variance of is , where p and q are co-prime, then the sum of the positive divisors of p
q
is equal to
(A) 72 (B) 31
(C) 48 (D) 36
1 n 1 1 1023
Q2. If Cn n Cn 1 .... n C1 n C0 then n is equal to
n1 n 2 10
(A) 7 (B) 9
(C) 6 (D) 8
Q3. Let the plane P : 4x y z 10 be rotated by an angle about its line of intersection with the
2
plane x y z 4 . If is the distance of the point 2, 3, 4 from the new position of the plane
P, then 35 is equal to
(A) 85 (B) 126
(C) 90 (D) 105
Q4. In a triangle ABC, if cos A 2cosB cos C 2 and the lengths of the sides opposite to the angles
A and C are 3 and 7 respectively, then cos A cosC is equal to
5 3
(A) (B)
7 7
10 9
(C) (D)
7 7
Q7. Let a, b, c be three distinct real numbers, none equal to one. If the vectors a ˆi ˆj kˆ ,
ˆi bjˆ kˆ and ˆi ˆj ckˆ are coplanar, then 1 1 1
is equal to
1 a 1 b 1 c
(A) 2 (B) 1
(C) 2 (D) 1
Q8. Let , a ˆi ˆj kˆ and b 3iˆ ˆj 2kˆ . Let c be a vector such that
2
a b c c 0, a c 17 and b c 20 . Then c ˆi ˆj kˆ is equal to
(A) 53 (B) 62
(C) 49 (D) 46
1
1 1 2 1 2
Q9. Let A 51 . If B A , then the sum of all the elements of the matrix
1 1 1 1
0 1
50
n
B
n 1
is equal to
(A) 50 (B) 75
(C) 100 (D) 125
Q11. The area of the region enclosed by the curve y x 3 and its tangent at the point 1, 1 is
23 19
(A) (B)
4 4
31 27
(C) (D)
4 4
2 3 6 2 2
Q12. Let P , , Q, R and S be four points on the ellipse 9x 4y 36 . Let PQ and RS be
7 7
1 1 p
mutually perpendicular and pass through the origin. If 2
2
, where p and q are
PQ RS q
coprime, then p q is equal to
(A) 143 (B) 137
(C) 147 (D) 157
sin2 x
3e k
Q13. If the local maximum value of the function f x , x 0, , is , then
2sin x 2 e
8
k k8
k 8 is equal to
e e5
(A) e3 e6 e11 (B) e3 e5 e11
(C) e3 e6 e10 (D) e5 e6 e11
JEE-MAIN-2023 (12th April-First Shift)-PCM-16
n2 3n 10
1
Q15. Let an be a sequence such that a1 a2 ... an . If 28 p1 p2 p3 ....pm ,
n 1n 2 a
k 1 k
where p1, p2 ,....,pm are the first m prime numbers, then m is equal to
(A) 7 (B) 8
(C) 5 (D) 6
7 3
Q16. If the point , lies on the curve traced by the mid-points of the line segments of the lines
3
x cos y sin 7 , 0, between the co-ordinates axes, then is equal to
2
(A) 7 (B) 7
(C) 7 3 (D) 7 3
Q17.
Let y y x , y 0 , be a solution curve of the differential equation 1 x2 dy y x y dx . If
y 0 1 and y 2 2 , then
1
(A) e3 e 5 2 1
(B) e3 e 3 2 2
1
(C) e e2 3 2 2 1
(D) e e2 5 2
Q18. The number of five digit numbers, greater than 40000 and divisible by 5, which can be formed
using the digits 0, 1, 3, 5, 7 and 9 without repetition, is equal to
(A) 72 (B) 96
(C) 132 (D) 120
1
Q19. Let C be the circle in the complex plane with centre z0
2
1 3i and radius r = 1. Let
z1 1 i and the complex number z2 be the outside the circle C such that z1 z0 z 2 z0 1 . If
2
z0 , z1 and z2 are collinear, then the smaller value of z 2 is equal to
5 3
(A) (B)
2 2
7 13
(C) (D)
2 2
6 2log3 x
Q20. Let D be the domain of the function f x sin1 log3 x . If the range of the function
5x
g : D defined by
g x x x , x is the greatest int eger function , is , , then
5
2 is equal to
(A) 45 (B) 135
(C) 46 (D) 136
JEE-MAIN-2023 (12th April-First Shift)-PCM-17
SECTION - B
(Numerical Answer Type)
This section contains 10 Numerical based questions. The answer to each question is rounded off to the
nearest integer value.
x7
Q1. Let I x
x
dx and I 9 12 7loge 7 . If I 1 7loge 1 2 2 then 4 is equal
to……….
0.15
k
Q2. If 100x 2 1 dx , then k is equal to………
0.15
3000
Q3. Let the digits a, b, c be in A.P. Nine-digit numbers are to be formed using each of these three
digits thrice such that three consecutive digits are in A.P. at least once. How many such numbers
can be formed?
Q4. Let the plane x 3y 2z 6 0 meet the co-ordinate axes at the points A, B, C. If the orthocenter
2
of the triangle ABC is , , , then 98 is equal to……….
7
31
Q5. Let the positive numbers a1, a2 , a3 , a4 and a5 be in a G.P. Let their mean and variance be
and
10
m 31
respectively, where m and n are co-prime. If the mean of their reciprocals is and
n 40
a3 a4 a5 14 , then m + n is equal to………
Q6. Two circles in the first quadrant of radii r1 and r2 touch the coordinate axes. Each of them cuts off
an intercept of 2 units with the line x y 2 . Then r12 r22 r1r2 is equal to…………
Q7. A fair n n 1 faces die is rolled repeatedly unit a number less than n appears. If the mean of the
n
number of tosses required is , then n is equal to…………
9
Q8. The number of relations, on the set 1, 2, 3 containing 1, 2 and 2, 3 , which are reflexive and
transitive but not symmetric, is …………
Q9. Let x be the greatest integer x . Then the number of points in the interval 2, 1 , where the
function f x x x x is discontinuous, is………….
1 2k 2k 1 n
2
Q10. Let Dk n n n 2 n2 . If D k 96 , then n is equal to………..
2 2 k 1
n n n n n2
JEE-MAIN-2023 (12th April-First Shift)-PCM-18
SECTION – B
1. 4 2. 784 3. 50 4. 243
5. 1 6. 100 7. 15 8. 4
9. 160 10. 2
PART – B (CHEMISTRY)
SECTION - A
1. A 2. C 3. B 4. A
5. D 6. B 7. B 8. B
9. A 10. B 11. B 12. C
13. A 14. D 15. B 16. A
17. A 18 A 19. A 20. B
SECTION - B
1. 9000 2. 10 3. 48 4. 3
5. 15 6. 3 7. 4 8. 3
9. 25 10. 10
JEE-MAIN-2023 (12th April-First Shift)-PCM-19
PART – C (MATHEMATICS)
SECTION - A
1. C 2. B 3. B 4. C
5. A 6. B 7. D 8. D
9. C 10. B 11. D 12. D
13. A 14. D 15. D 16. A
17. B 18 D 19. A 20. DROP
SECTION - B
1. 64 2. 575 3. 944 4. 288
5. 211 6. 7 7. 10 8. 3
9. 2 10. 6
JEE-MAIN-2023 (12th April-First Shift)-PCM-20
Sol2. Infrared rays are used in optical communication and they have shorter wavelength
than microwave.
hc
E
Sol3. R 160
A
/ 4 1
R' 10
4A 16 A
Sol4. Curie’s law is not valid for diamagnetic materials. Magnetic susceptibility of a
diamagnetic material does not depend on temperature.
Diamagnetic materials oppose external mag field by inducing magnetic dipole moment
opposite to magnetizing field.
GM
Sol5. Vorbital
R
M is mass of planet
Vorbital = Vorbital
(A) (B)
1
Sol6. Vrms
M
Vrms of Ar 70.9
490 39.9
Vrms of Argon 490 1.3 651.7m / s
2 G 16Me 2GMe
Sol7. Vescape = 2x
4Re Re
planet
Vescape = 2 Vescape
(planet) (Earth)
JEE-MAIN-2023 (12th April-First Shift)-PCM-21
Vt 3 s 150 10 3 120 6
Sol8.
Vt 5 s 150 10 5 100 5
x 1 6
x 5
x5
h
Sol10. proton - (i)
2mq 2v
h
particle - (ii)
2 4m 2q 4v
proton 4
particle 1
d1
Sol12. 12
d2
d1
d2
4
d1 d2 16 24
3
2 24cm
Sol13. At resonance cos 1 I
0 Imax
1
L
c
fresconace f
JEE-MAIN-2023 (12th April-First Shift)-PCM-22
1 1
Sol14. 12.5 13.6 2 2
1 n
4 3
No. of spectral lines emitted
n n 1
3
2
2
1 A
Sol15. At m 2 A 2
2 4
3
kE m 2 A 2
8
1 A 2 m 2 A 2
PE m 2
2 4 8
PE 1
kE 3
F
Sol16. k 2
MT
x
2
w T1
T
L ML2 T 1
t
I mr 2
ML2
IC 11 10 3
Sol19. 110
IB 100 10 6
F 10
Sol20. a 1 2m / s 2
m 5
F2 = 10N
F1 F2 F3 0 F3 = 6N
m = 5kg 8N = F2
JEE-MAIN-2023 (12th April-First Shift)-PCM-23
SECTION - B
Sol1. Using Bernowlli’s theorem
1 1
P1 v12 P2 v 22
2 2
1
P1 P2 v 2 v12
2
Sol3. BA B r 2
d dr
Emf B 2r
dt dt
Emf 0.4 2 2 102 10 3
16 10 6 volts
50.24 10 6 volts
50.24 v
I I
Sol4. T 2 2
MBH M B cos
T1 B 2 1/ 2
T2 B1 3 / 2
20 / 60 B2
30 / 60 B1 3
4 B2
9 B1 3
B1 9 4
B2 4 3 x
256
x 3
81
x 9.48
st 405
Sol5. 1 Harmonic 1 81Hz
5
V
81
4L
324
81
42
324
L 1m
4 81
JEE-MAIN-2023 (12th April-First Shift)-PCM-24
V
Sol7. Using I
R
V
2 - (i)
R0
V
1.2 - (ii)
R 0 1 100
1
150
At 80 C
V 2 R0
I
R0 1 50 1
R0 1 50
150
2 6
I 1.5 A
4/3 4
I 1500 mA 15 10 2 mA
1 2 1
Sol10. KErotational MR 2 2 m 2 R 3
2 3 3
1 2 1
KE Total mR 3 3 mV 2
2 3 2
V R
5
KE total m 2 R 2
6
KE rotational 2 x
KE total 5 5
x2
PART – B (CHEMISTRY)
SECTION – A
Sol1. On moving down the group, mass increases more as compared to size therefore, density
increases. But in case of K, increase in size is more due to 3d orbital hence, density is less than
Na.
Sol2. Lead storage battery consists of lead anode and a grid of lead packed with lead oxide (PbO2) as
cathode, a 38% solution of H2SO4 is used as are electrolyte. On charging the battery the reaction
is reversed and PbSO4(s) on anode and cathode is converted into Pb and PbO2 respectively.
Sol3.
HO O O O O O
OH
= 2+
2eq
HO O O O O O
(B)
(Squaric acid)
‘B’ is an aromatic compound while ‘A’ shows tautomerism and bond length of C-C are equal in
compound ‘B’
100
Sol6. Number of moles
22700
0.57 gm
Number of moles
M
0.57 22700
M 129.39
100
55
Weight of Cl 129.39 71.164 71
100
JEE-MAIN-2023 (12th April-First Shift)-PCM-26
71
moles of Cl 2
35.5
Hence, formula will be MCl2
Sol7. According to Fajan’s rule cation having greater +ve charge will have more covalent
character. Oxides of halogens also more stable than lower one. Due to
(a) More EN
(b) Higher O.S
(c) Resonance stablisation
Sol10. (a) 4NO2 (g) O2 (g) 2H2 O() 4HNO3 (aq)
SO2 and NO2 gas have major contribution in acid rain.
(b) CH4,CH2, CFC & O3 are responsible for global warming
(c)
H2 O( ) CO2 (g)
H2 CO3
H2 CO3 aq
H aq HCO3 aq
Rain water has pH of 5.6 due to the presence of H+ ions formed by the reaction of rain water with
CO2.
(d) Phosphate present in fertilizers contribution for Eutrophication. Eutrophication is the process
in which nutrient enriched water bodies support a dense plant population, which kills animal life
by depriving it of oxygen and result in subsequent loss of biodiversity.
o
Sol12. For line II, S is more –ve than G
II
line I, hence higher slope.
For I SI Ssolid Ssolid Sgas
For II SII S solid Sliq Sgas 2Mg(s)+O2(g)2MgO(s)
Hence SII more –ve SI 2Mg(l)+O2(g)2MgO(s)
M.P. of metal
o T
T=1120 C
Sol14. 5f orbital not buried as 4f orbitals, so electrons present in 5f orbital experience less nuclear
attraction than electron present in 4f orbital. Hence electrons of 5f orbital can take part in bonding
to a far greater extent.
Sol15.
O O
CH3 C CH2 CH 2 CH2 CH 2 C CH3
EtO
O O
CH3 C CH2 CH2 CH2 CH C CH3
OH
O O O
CH3 O +
H C CH3 C CH3
C CH3
Sol16.
CaCl 2 + Na2CO3 CaCO3 + NaCl
(X) (Y)
HCl (Z)
Sol17. Boron is non- metallic in nature. It is extremely hard and black coloured solid. It exits in many
allotropic forms. Due to very strong crystalline lattice boron has normally high M.P & B.P
JEE-MAIN-2023 (12th April-First Shift)-PCM-28
Sol18.
Mg O
O
+MgBr
Br
O Br
O
O
Br
Br H2O
O
OH
Sol19.
OH Cl
SOCl2
O O
R NH2
NH R
NHR LiAlH4
H3O+ O
Sol20.
N Me2 N Me2
NaNO2 + HX
NO
NaNO2 HX HNO 2 Nax
H
HNO2 NO [Electrophile)
JEE-MAIN-2023 (12th April-First Shift)-PCM-29
SECTION – B
Sol1. H 10 1 &VHcl 1L
2
H 10 VHCl 4
M1V1 M2 V2
10 1 1000 102 V1
V 1 10 4 ml 10L
Volume added is 9L or 9000 ml
Sol2.
O O O O
CH3 CH C NH CH2 C NH CH C NH CH C OH
NH2 CH2 HC CH3
Ph CH2
CH3
1240
Sol4. E 3.1eV
400
Mg, Cu, Ag will be the answer
JEE-MAIN-2023 (12th April-First Shift)-PCM-30
Sol5.
NH4Cl
EtO CH2 CHO EtO CH2 CH NH
(NH3 /H+)
KCN
O2N
NH2 NH
H2SO4 / H+
EtO CH2 CH COOH EtO CH2 CH CN
O
O 2N O 2N
NH2 HN C CH3
EtO CH2 CH COOH EtO CH2 CH COOH
(CH3CO)2O
EtOH
O 2N O 2N
O O
H2N O 2N
HN C
CH3 HN C CH3
H2 / Pd / C
EtO CH2 CH COOEt EtO CH2 CH COOEt
H2N HNO 2 O 2N
+ O O
N2 I
HN C CH3 HN C CH3
NaI
EtO CH2 CH COOEt EtO CH2 CH COOEt
+
N2 I
X = 15
Sol6.
NO Br2
K
1
NOBr2 (fast)
K 2
K3
NOBr2 NO 2NOBr
Rate K 3 NOBr2 NO from RDS
K eq
NOBr2 from reaction (I)
NOBr2
NOBr2 K eq NOBr2
2
Rate = K 3K eq NO Br2
Order = 3
JEE-MAIN-2023 (12th April-First Shift)-PCM-31
V2
Sol8. S system nRln
V1
3
1 8.314 ln
2
S system 3.37
S surr 3.37
Sol10.
2[Ag(NH3)2]OH
CHO COO +3NH3 +2Ag + H2O
131.8 1000
WNH3 3 17 60kg
112
PART – C (MATHEMATICS)
SECTION – A
Sol1. We’ve, 1,2,3,4,5,6
1, 2, 3, 4, 5, 6 .
Frequency
-5 1
-4 2
-3 3
-2 4
-1 5
0 6
1 5
2 4
3 3
4 2
5 1
JEE-MAIN-2023 (12th April-First Shift)-PCM-32
5 1 4 2 3 3.....
Mean 0
36
2 25 1 16 2 9 3 4 4 1 5
2 02
36
35
6
Now, 35 = 51. 71
Sum of positive divisors 50 51 70 71
48
n n
C 1023
Sol2. r 1r 10
r 0
n n 1 C
r 1 1023
n1
10
r 0
n 1
2
1 1023
n 1 10
n 9.
A C 1
tan tan
2 2 3
s b s c s a s b 1
.
s s a s s C 3
sb 1
s 3
abc
b
2 1
abc 3
2
b 5 a 3, c 7
b2 c 2 a2 a2 b2 c 2
Now, cos A cos C
2bc 2ab
10
7
Sol5.
p q ~p ~q pq p ~ q Si pq ~pq p ~ q ~ p ~ q S2
F F T T T F F F F F T T
F T T F T F F F T F F T
T F F T F T F F F T F T
T T F F T F F T F F F T
Sol8. We’ve a b c t c
t 1 c a b
3,0,1
c
t 1
3 1
,0,
t 1 t 1
3 1
a.c 17 17
t 1 t 1
3 1 17 t 1 18 7t - (i)
Again, b.c 20
3 3 2
20
t 1 t 1
3 9 20t -(ii)
1
1 2 1 1 2
Sol9. B 51
1 1 0 1 1 1
1 52 1 1 0 1 1 1
51 1 50 0 1 51 1 1
1
I C say .
51
n
1 n
Now, Bn I C I C 0 0.....
51 51
2 1 1 1 1 0 0
C .
1 1 1 1 0 0
50 50
n
Bn I 51C 50I 25C
n 1 n 1
50 0 25 25
0 50 25 25
75 25
25 25
A point on 1 5 3t, 4 t, 2t ,
lies on 2
3 5 3t 2 4 t 2t 2
9t 25 -(i)
Also, 5 3t 3 4 t 2 2t 13
2t 3 -(ii)
Solve (i) and (ii) to get 7,t 2
x 5 y 4 z7
1 : say
3 1 2
Let P 3 5, 4, 2 7
If P is nearest to Q, then PQ. 3,1, 2 0
3 1, 1, 5 2 . 3,1, 2 0
1
P 2, 3,5 a b c 10
Sol11. Given y x3
(2,8)
dy
3x 2 3
dx y=x
dy
3
dx x 1
(-1,-1)
Equation of tangent at 1, 1
is y 1 3 x 1
y 3x 2
It intersects the curve y x 3 at 2,8
Required Area =
2 4 2
3x 2
3 x 27
3x 2 x dx 2x .
1 2 4
1
4
144
PQ2 4r 2 .
9 cos 4 sin2
2
144
Similarly RS2
9 sin 4 cos2
2
1 1 13cos2 13 sin 2
PQ2 RS2 144
13 p
144 q
p q 157
JEE-MAIN-2023 (12th April-First Shift)-PCM-36
sin2 x
3e
Sol13. y , 0x
2 sin x 2
sin2 x
dy 3e 3e
2 n 1 sin x cos x
dx 2sin x
2sin x
dy 3e
Now, 0 sin x cos x 2n 1 0
dx 2sin x
3e 3
2 n 1 sin x
2sin x 2
x
3
Again, f ' x 0 for x
3
and f ' x 0 for x
3
f x has maximum at x .
3
3/4 k
f
3
e e3/8
e
(given)
k e11/8
8
k k8
5 k 8 e3 e6 e11
e e
6 6 6 6
Sol14. i and i
2 2 2 2
3 3
i i
re 4 , re 4 , where r = 3.
14 14 10 10
0, 0
69
r 23 .cos
23 23 14 14 4
15 15 10 10 15
r .cos
45
4
8
r 81.
n n 3
Sol15. Sn
n 1 n 2
n n 3 n 1n 2
an Sn Sn1
n 1n 2 n n 1
4
.
n n 1 n 2
1 n n 1n 2 n 3 n 1
.n n 1 n 2
an 4 16
JEE-MAIN-2023 (12th April-First Shift)-PCM-37
1
n n 1 n 2 n 3 n 1 n n 1n 2
16
Vn Vn 1
10
1 28
28 28 V10 V0 10 11 12 13
n 1 an 16
2 3 5 7 11 13.
m 6.
1 dy x 1 1
Sol17. We’ve, 2 dx
.
2 y
-(i)
y 1 x 1 x2
1 1 dy dz
Let z 2
y y dx dx
dz x 1
equation (i) becomes 2
z .
dx 1 x 1 x2
x 1
Integrating factor e
1 x2
dx
e2
n 1 x2
1 x2 .
Solution is given by
1
z 1 x 2 dx
1 x2
z 1 x 2 n x 1 x 2 c.
1 x2
n 1 x2 x c
y
y 0 1 1 0 c c 1
JEE-MAIN-2023 (12th April-First Shift)-PCM-38
3 32 2 3
Now, x 2 2 n y
y e 32 2
n
e
3 2 2 e 3 1
e3/
e
e 32 2 .
Sol18. Form
Number
0 3 4! 72
(First digit can be 5, 7 or 9)
2 4! 48
5 (First digit can be 7 or 9)
Total possibilities
72 48 120
1 1 1
Sol19. We’ve, z1 z0 i
2 2 2
z2 z0 2
z0
Slope of the line segment joining
z0 ,z1 and z2 is -1 z1
3
i
2e
i /4 z2
z 2 z0 2e 4 or
1 5 3 1
z2 i or i
2 2 2 2
2 10 5
smaller of z2
4 2
SECTION – B
x7 7 14 t dt
Sol1. Let t2 x 2 dx 2
x t 1 t2 1
t2 t 2t
I 14 dt 14 .
2
dt
2 t2 1 2
t2 1
7t dt
2
7 2
t 1 t 1
7t 7 t 1
2 n c
t 1 2 t 1
4
Now, x 9 t and x 1 t 2 2
3
JEE-MAIN-2023 (12th April-First Shift)-PCM-39
Given, I 9 12 7log e 7
7 1
12 n c 12 7n7
2 7
7
c n7
2
14 2 7 2 2 1 7
Now, I 1 n n7
7 2 2 2 1 2
2 2 7n 1 2 2
2 2 4 64
0.15
Sol2. 100 x2 1 dx
0.15
0.1 0.15
2 1 100x 2 dx 1 100 x 2 dx
0
0.1
(Using Symmetry) -0.15 -0.1 0.1 0.15
100x 3 0.1 100x 3 0.15
2 x x
3 0
3 0.1
115 k
(given)
600 3000
k 575
31 1 1 r 5 1
-(ii)
8 a r4 r 1
31 31r 4 a
From (i) and (ii),
2a 8
a2r 4 4
2
ar 2 2 a
r2
5 2
r 1 31r 31 1 1
From equation (i), 1 r r2
r 1 4 4 r2 r
2
1 1 35
r r 0
r r 4
1 5 7
r or
r 2 2
1 5 1
r 0, We’ve r r 2 or
r 2 2
1
a or 8
2
1
So, the numbers are ,1, 2,4,8.
2
1
1 4 16 64 2
31
2 4
5 10
JEE-MAIN-2023 (12th April-First Shift)-PCM-40
186 m
25 n
m n 212
Sol3. ----
Sol5. Let ak ar k 1
31 a ar .... ar 4 31 1 r 5
Now, -(i)
10 5 2a 1 r
5
1 1 1
1 / 1
31 a r r
Again,
40 5
2 2
Sol6. Let the circle be x r y r r 2
Intercept on the line x y 2 is given by
2
2 2r 2
2 r 2
2
r 2 4r 3 0
r1 1, r2 3
r12 r22 r1 r2 9 1 3 7.
1 1 n 1
3 . . .
. n n n .
. .
. .
r 1
1 n 1
r .
n n
r 1
1 n 1
Mean = XP X r. n .
r 1 n
r 1
n 1 1 n 1 1
n
r. n .
n 2
r 1 1
1
n
n n
(given)
n 1 9
n 10.
2 x 2, 2 x 1
Sol9. f x 1 x 1, 1 x 0
x ,0 x 1
points of discontinuity are x 1,0
n n n 1 n2
n
Sol10. Dk n n2 n 2 n2
k 1
n n2 n n2 n 2
n n n 1 n2
0 2 0
0 0 n2
n 2 .2n 96
n n 2 48
n6