Weekly Test-10 Sankalp2325 m1 Paper & Answer Key (Xii)
Weekly Test-10 Sankalp2325 m1 Paper & Answer Key (Xii)
Weekly Test-10 Sankalp2325 m1 Paper & Answer Key (Xii)
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WT-SANKALP2325M1-PCM-(101263)-2
PART I : PHYSICS
SECTION – 1 : (Only One Option Correct Type)
This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE option is correct.
1. A hollow cylindrical conductor (inner radius = a, outer radius = b) carries a current i uniformly
spread over its cross section. Which graph below correctly gives B as a function of the distance r
from the center of the cylinder?
(A) B (B) B
a r a r
b b
(C) B (D) B
a r a r
b b
0I Z
(C) 2 3 2
(D) zero A
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WT-SANKALP2325M1-PCM-(101263)-3
5. Two infinitely long wires Q & R, each carrying current I are placed
along y and parallel to z axis respectively as shown in the figure. A
y
point charge +q having mass M is projected from the point P(a, a, 0)
a
with velocity v ˆi vjˆ as shown. The instantaneous acceleration of Q P
I a
the particle just after projection is [v = 107 m/s, I = 10/3 A, q = 100
C, M = 1 gm, a = 0.25 m) I x
R
(A) 4 m/s2 (B) 8 m/s2
2
(C) 12 m/s (D) 16 m/s2
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WT-SANKALP2325M1-PCM-(101263)-4
This section contains 3 multiple choice type questions. Each question has four choices (A), (B), (C)
and (D) out of which ONE or MORE THAN ONE are correct.
7. Two concentric coil of radii r1 and r2 (r1 < r2) carry currents i1 and i2 respectively. If the smaller coil
is rotated slightly about one of its diameter it starts oscillating. Then choose the correct
statements.
(A) The oscillations are simple harmonic in nature
(B) The frequency of oscillation is proportional to product i1i2.
(C) The frequency of oscillation is proportional to square root of r2
(D) The frequency of oscillation is independent of radius r1.
ˆ and a uniform Y
8. There is a uniform horizontal magnetic field along (k)
B
gravitational field g(ˆj) . A particle with charge q is projected from the
origin along positive x-axis with speed V0, and is found to cross
O V0 X
P(a, –b) after some time. Which of the following is true?
(A) The speed while crossing P is more than V0
g
(B) The speed while crossing P is less than V0
(C) Both magnetic field and gravitational field do work on particle P
(D) Only gravitational field does work on particle.
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WT-SANKALP2325M1-PCM-(101263)-5
This section contains THREE questions. The answer to each question is a NUMERICAL VALUE. For
each question, enter the correct numerical value (in decimal notation, truncated/rounded off to the
second decimal place; e.g. XXXXX.XX).
10. A charge particle of mass ‘m’ and charge –q is released from rest m k
from the given position. In the presence and absence of the x x x x x xx
magnetic field normal reaction acting on the charge at P are N1 x x x x x x Rx
and N2 respectively. Neglecting friction and assuming gravity x x xB x
5Bq 2gR
presence. The value of N1 – N2 is given by . Find k.
k P
12. A coil carrying a current I = 10 mA is placed in a uniform magnetic field so that its axis coincides
with the field direction. The coil consist of only one turn and made up of copper. The diameter of
the wire is 0.1 mm, the radius of the coil is R = 3 cm. The value of external induction field will the
coil rupture is K. Breaking stress of copper = 3 108 N/m2. Then find the value of K.
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WT-SANKALP2325M1-PCM-(101263)-6
This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE option is correct.
1. NH2
O
P Product . P is
O
H2C
CH3
(A) O O (B) O
HN C CH2 C CH3 HN C CH3
CH 3
CH3
(C) NH2 O O (D) NH2 O
C CH2 C CH3
CH3 CH3 O
2. O
H2 C C NH2 IV O
HC C6 H4 NH C CH3
III
H2 C NH CH CH2 NH2 I
II CH3
Arrange the above mentioned nitrogen atoms of the compound in decreasing order of basic
nature?
(A) I > II > IV > III (B) II > I > IV > III
(C) II > I > III > IV (D) I > IV > III > II
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WT-SANKALP2325M1-PCM-(101263)-7
3. N2Cl
O O
K L M
4. NH2
A C NaNO /HCl
B D
2
yellow oily liquid
MW 113
5. In the reaction:
Cl
P,
N
H
Product P, should be:
(A) (B)
N N Cl
H H
(C) (D) Cl
Cl
N
H N
H
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WT-SANKALP2325M1-PCM-(101263)-8
6. The decreasing order of reactivity of the following compounds towards Hoffmann Bromamide
reaction is
CONH 2 CONH 2 CONH 2 CONH 2
Me NO 2 OMe
Me Me
(A) III > I > IV > II (B) III > IV > I > II
(C) II > I > IV > III (D) IV > I > III > II
This section contains 3 multiple choice type questions. Each question has four choices (A), (B), (C)
and (D) out of which ONE or MORE THAN ONE are correct.
(B)
NH3
Br NH2
(C)
NaN3 LAH
Br N3 NH2
(D) O
Br NH2
OH/H O
N K 2
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WT-SANKALP2325M1-PCM-(101263)-9
9. Which of the following compounds react with benzene sulphonyl chloride in aqueous potassium
hydroxide to give a clear solution which on acidification gives a precipitate?
Me NH
Me
(A) N (B)
Me
NH2
NH2
(C)
(D)
Me
This section contains THREE questions. The answer to each question is a NUMERICAL VALUE. For
each question, enter the correct numerical value (in decimal notation, truncated/rounded‐off to the
second decimal place; e.g. xxxxx.xx).
10.
AgOH
N I
A tertiary amine
Major hydrocarbon
H / H2O
I /NaOH
D C
2
B
M3
N2
X CO2 N2
11.
COO
The degree of unsaturation in X is.
12. A hydrocarbon ‘P’ having molecular formula C8H10 can form only three monochloroderivative. ‘P’
on oxidation with KMnO4 yields a compound, which on heating with aq. NH3 yields ‘Q’. ‘Q’ on
treatment with NaOH followed by NaOCl yields a salt which on acidification yields a compound ‘R’
having molecular formula C7H7O2N. The compound ‘R’ is further treated with (NaNO2 + HCl) and
then with base to give dipolar ion ‘S’ which readily losses two gases to give an intermediate ‘T’ is
finally converted into hydrocarbon ‘U’ on dimerisation. Degree of unsaturation in the hydrocarbon
‘U’ will be:
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WT-SANKALP2325M1-PCM-(101263)-10
This section contains 6 multiple choice type questions. Each question has four choices (A), (B), (C)
and (D) out of which ONE is correct.
1. If f(x) is a polynomial function with positive integral coefficients (degree of f(x) 1) and for
f f x 1
x1 is an integer, then (where [.] denotes the greatest integer function)
f x
(A) x [1, 2) (B) x [2, 3)
(C) x [3, 4) (D) none of these
3
m
2. Let x1, x2, x3 be roots of equation (x – 1) (x – 8) (x – 31) = 1. Then lim
i1
lim cos n! xi
m n
is
equal to
(A) 0 (B) 1
(C) 3 (D) none of these
3. Let C1 (x – 1)2 + y2 = 1 and C2: x2 + y2 = r2 intersect at P in 1st quadrant and let R be the point
where the line passing through the points Q (0, r) and P intersects the x-axis. If radius of C2
decreases indefinitely then limiting position of R is given by (, 0) then ‘’ is equal to
(A) 1 (B) 2
(C) 3 (D) 4
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WT-SANKALP2325M1-PCM-(101263)-11
/2 /2
dx dx
5. If
0
2 2 2 2
a cos x b sin x 2ab
, then the value of 0 4 cos2 x 9 sin2 x 2
is equal to
11 13
(A) (B)
864 864
17
(C) (D) none of these
864
3
1 x x2 1
6.
1/ 3
ln dx is equal to
x x x2 1
8
(A) (B) 0
3
8
(C) – (D) 3
3
This section contains 3 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONE OR MORE may be correct.
n2 1! 2! ..... n!
7. If lim , where is a non-zero real number, then
n n
3 1
(A) (B)
4 2
(C) e3/4 (D) e1/2
8. P(x) is polynomial of degree n (n > m) such that P(x) = Q(x) P(x) where Q(x) is a quadratic
polynomial and P(x) is second derivative of P(x),
(A) if P(x) has atleast two distinct roots then it must have n distinct roots
(B) if P(x) has a root of multiplicity at least 2 then it has all identical roots
(C) P(x) and P(x) must have n – 2 roots common
(D) P(x) and P(x) may have n – 2 roots common
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WT-SANKALP2325M1-PCM-(101263)-12
2
9. The values of a for which the integral x adx 1 is satisfied are
0
(A) [2, ) (B) (–, 0]
(C) (0, 2) (D) none of these
This section contains THREE questions. The answer to each question is a NUMERICAL VALUE. For
each question, enter the correct numerical value (in decimal notation, truncated/rounded‐off to the
second decimal place; e.g. XXXXX.XX).
1
n 1
10. If lim nk x x k 1dx exists and is equal to f(k), k N, then the value of is
n
0 f 5
(Where [.] denotes the greatest integer function)
11. Let A n denotes the area of rectangle formed by taking two of its vertices on x-axis and remaining
4n 2
x4
two on curve f(x) e 2 and Bn denotes the maximum value of A n for x R. If Bn P ,
n 1
2
then 16loge is equal to
p
I1 3 1
1 3 1 3 1 0.2
2 2 I 2 2
12.
If I1 1 1 x 3 2
x dx and I2 1 1 x
3
2
x dx , then 2
10
is equal to
0 0
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WT-SANKALP2325M1-PCM-(101263)-13
(Batches: SANKALP2325M1)
IIT – JEE, 2325 Paper Code
101263
ANSWERS
PHYSICS (PART-I)
1. C 2. C 3. B 4. B
5. B 6. B 7. A, D 8. A, D
CHEMISTRY (PART-II)
1. A 2. B 3. C 4. D
5. D 6. A 7. B, C 8. A, B, C
9. C, D 10. 5 11. 9 12. 9
MATHEMATICS (PART-III)
1. A 2. A 3. D 4. B
5. B 6. B 7. B, C 8. A, B, D
9. A, B, C 10. 5.00 11. 4.00 12. 0.12
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WT-SANKALP2325M1-PCM-(101263)-14
2. C
If the loop is completed by wire of length 2R along y-axis i.e. the diametre of the semicircle
then B.d I [Ampere’s law]. And due to the diameter wire only,
0
0I 0I 30I
B at all point on the circle 3x 2 + 3z2 = R2, is sin 1 sin 2 sin60o sin60o
4r R 4R
4
3
3 0I R 3
B.d (due to diameter wire only) = 4R
2
3
2
0I
30I
2 3 0I
Hence, B.d due to semicircle = I 0
2
2
3. B
Total angle P1OP2 = 150
P4 150 5
So, B d 0i 0i
P1 360 2
4. B
5. B
qv B
a= = 8 m/s2
M
6. B
= MB = 5 N m
= 10 rad/s2
I
4
a = R 8 m/s2
5
7. A, D
= MB sin
ii
f 12
r2
8. A, D
Magnetic field force always being perpendicular to velocity does not work on charge, positive
work is done by gravitational field for the motion from A to P.
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WT-SANKALP2325M1-PCM-(101263)-15
9. A, B, C, D
( ˆj k)
ˆ k ˆj
Direction of magnetic field at P due to CD = îx
2
2
ˆ ˆ
( j k) k ˆj
Direction of magnetic field at P due to EF = îx
2
2
Hence direction will be along ĵ
Direction of magnetic field at ‘O’ due to upper frame along î
Direction of magnetic field at O due to horizontal frame will be along ĵ .
10. 5.00
absence of magnetic field
mv12
N2 – mg =
R
In the presence of magnetic field
mv 22
N1 – mg – qvB = 2gR
R
N2
v1 = v2 = 2gR
So N1 – N2 = B2 2gR v
So k = 5. mg
N1
v
qvB
mg
11. 0.25
sin
for equation iB(cos ) = mg sin + 2mg
2
iB iB iB
So, tan
2mg 2g 2g
tan = 1
= /4
12. 2500.00
Fm
2T sin = Bi (R)
2
T = IRB
2
also, T = r
r 2 T T
B=
IR
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WT-SANKALP2325M1-PCM-(101263)-16
CHEMISTRY (PART-II)
1. A
O OH
HN C CH2 C CH 2
O
H 3C NH2
O
H2 C Tautomerise
CH 3
O O
HN C CH2 C CH3
CH3
2. B
3. C
N 2 Cl OH OH
O O
CHO
steam (i)CHCl3 / NaOH / (CH 3 CO ) 2 O
CH 3 COONa
(ii) H O
3
Perkin's reaction
4. D
NH2 NC NHCH3 ON NH CH3
CHCl /OH
3 H /Ni or LiAlH
2 4
NaNO /HCl
2
5. D
Cl
Cl
N
Cl
Cl
H +
N
CH2 N
H
H
6. A
Electron releasing group increases reactivity and electron withdrawing group decreases reactivity
for Hoffmann Bromamide reaction.
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WT-SANKALP2325M1-PCM-(101263)-17
7. B, C
Cl
NH3 Cl
NaHCO3
CO 2
AgNO3 NaHCO3
NH2 AgNO3
no reaction no reaction
AgCl
white
8. A, B, C
o
(D) is incorrect, since Gabriel method is used to prepare 1 aliphatic amines.
9. C, D
Primary amines react with benzene sulphonyl chloride to form N-substituted benzene
sulphonamide which react with aqueous KOH to form a soluble salt. The solution on acidification
give a precipitate.
O O
R NH2 Cl S R NH S
O O
O O
K
KOH HCl
R N
S
R NH S
O O ppt.
10. 5
OH
CH3CH CH2 H3C CH CH3 CH3 COO CHI3
A
B C D
3
Fe
3CH3 COO Fe CH3 COO 3
Blood red colour
11. 9
' X' is
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WT-SANKALP2325M1-PCM-(101263)-18
12. 9
O
CH3 COOH C
KMnO4
aq. NH3
NH
H2O
CH3 COOH C
P
O
'Q '
NaOH
CO 2Na COOH
NaOCl
NH2 CONH2
HCl
CO 2H CO 2H
CO 2
NaNO2 HCl
OH
NH2 N2 +
N2
R S
CO 2 N2
Benzyne
T
Dimerisation
Biphenylene
U
MATHEMATICS (PART-III)
1. A
f x an xn an1xn 1..... a0 , [x] = m then f m anmn an1mn1..... a0
n n1
f f m 1 an f m 1 an1 f m 1 ..... a0
= k f(m) + an + an – 1 + ….. a0 = k f(m) + f(1)
f f m 1 f 1
Since k = integer
f m f m
m = 1 hence x [1, 2)
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WT-SANKALP2325M1-PCM-(101263)-19
2. A
x1 x2 x3 are all irrational hence cos ( n! xi) (–1, 1)
m
Hence lim lim cos n! x i 0
m n
3. D
r2 r4
Solving C1 and C2 we get P as , r 2
2 4
r3
Solving the line PQ with x-axis we get x co-ordinate as 2
r4
r r2
4
r3
lim lim 2 4 R approaches the point (4, 0) as r 0
+
r 0 4
r
r r2
4
4. B
cosm x sinnx m
Im, n = cosm xcosnxdx = cosm1 x sin x sinnxdx
n n
cosm x sinnx m
= cosm 1 x cos n 1 x cosnx cos x dx
n n
cosm x sinnx m m
Im, n = cosm 1 x cos n 1 xdx Im, n
n n n
mn cosm x sinnx m
Im, n Im1, n1 c1
n n n
or (m + n) Im, n = mIm – 1, n – 1 + cosm x sin nx + c
5. B
/2
dx
Let I =
0
2 2
a cos x b sin x 2 2
2ab
Differentiating w.r.t. a
/2
dx2acos2 x
0 a 2
cos x b sin x
2 2 2
2
2a2b
/2
cos2 xdx
0 a2 cos2 x b2 sin2 x 2
4a3b
Similarly diff. w.r.t. b
/2
sin2 xdx
0 a2 cos2 x b2 sin2 x 2
4ab3
/2
dx 1 1
0 a2 cos2 x b2 sin2 x 2
4ab a 2
2
b
1 1 13
=
24 4 9 864
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WT-SANKALP2325M1-PCM-(101263)-20
6. B
3
1 x x2 1
I=
1/ 3
ln dx
x x x2 1
1 1
1/ 3 2 1
1 1 t t 1
t ln dt
Let x =
t
dx = – 2 dt I =
t
3
1 1
2 1 t
2
t t
3
1 t t2 1
=
1/ 3
ln dt I = – I I = 0
t t t 2 1
7. B, C
1
ln = lim [ln 1 + (ln 1 + ln 2) + (ln 1 + ln 2 + ln 3) + .....] – ln n
n n2
1 2 n n n 1
nln n 1 ln ..... ln lnn
n n n 2 n 1 2n 1 n n 1 r r
= lim 2
lnn = lim lnn + ln
n n n 2n n r 1 n n
1
1 3
2
and ln = 1 x ln x dx 4
0
8. A, B, D
Suppose P(x) does not have n distinct roots then it has a root of multiplicity at least 2 let it be
x = 0. Then P(x) = xk R(x), k 2.
P(x) = k(k – 1)xk – 2 R(x) + 2kxk – 1 R(x) + xk R(x)
Where R(0) 0 highest power of x dividing P(x) is xk – 2 and also
1
P(x) = Q(x) P(x) hence Q(x) = Cx 2 C
n n 1
Comparing coefficients P(x) = Cx2 P(x) if P(x) = ajx j
a j Cj j 1 a j j aj = 0 (j < n)
P(x) = anxn all roots identical.
9. A, B, C
For a 0
given inequation becomes
2
1
x a dx 1 a 2
0
a0
0
x adx 1 a x dx 1
0
3
2a – 2 1 a a2
2
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WT-SANKALP2325M1-PCM-(101263)-21
10. 5
1
n t
x k 1 x k 1
x x dx
0 0
lim k
dx lim
n
1 t 0 tk
n
Taking t as continuous variable (as t 0)
t t k 1 1 1
lim k 1 lim t t
t0 k t t 0 k k
11. 4
4n 2 x 4
A x 2x.e 2 let area be A(x)
2
4n 2
A ' x 2e 1 2 4n
x4
1 2 1 2 1 2
Maxima occurs at x n
and f x max 1/4 n
, 1/4 x 1/4
2 e 2 x 1 e 2 e
12. 0.12
Let 1 – x3 = t
1 3 1 3 1
1 t
2 2
3I1 1 t dt and 3I2 1 dt
0 0
1 3
3I2 = 2 1 t 1 t 1 dt (Using integration by parts)
3 1 2 2
3I2 3 1 2 3I 3 1 2 3I 2 1
I1 3 1 3 1 3 1
So, 0.2 1 0.2 1.2
I2 2 2 2 2 2 2
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