FINAL JEE–MAIN EXAMINATION – APRIL, 2024

(Held On Thursday 04th April, 2024) TIME : 9 : 00 AM to 12 : 00 NOON

MATHEMATICS TEST PAPER WITH SOLUTION

SECTION-A 3. The vertices of a triangle are A(–1, 3), B(–2, 2) and
1. Let ƒ : R  R be a function given by C(3, –1). A new triangle is formed by shifting the sides
 1  cos2x of the triangle by one unit inwards. Then the equation
 , x0 of the side of the new triangle nearest to origin is :
 x2
ƒ x    , x  0 , where ,   R. If 
(1) x – y – 2  2 = 0 

  1  cos x
 x
, x0 
(2) –x + y – 2  2 = 0 
ƒ is continuous at x = 0, then 2 + 2 is equal to :  
(3) x + y – 2  2 = 0
(1) 48 (2) 12
(3) 3 (4) 6 (4) x + y +  2  2  = 0
Ans. (2) Ans. (3)
2
2 sin x (–1,3)
Sol. ƒ(0–) = lim =2=
x 0 x2 A
(–2,2)
x B
sin m = –1
+
ƒ(0 ) = lim   2 2   2 Sol.
x 0  x 2
2
2 C
(3, –1)
= 2 2
2 + 2 = 4 + 8 = 12
2. Three urns A, B and C contain 7 red, 5 black; equation of AC  x + y = 2
5 red, 7 black and 6 red, 6 black balls, respectively. equation of line parallel to AC x + y = d
One of the urn is selected at random and a ball is
d 2
drawn from it. If the ball drawn is black, then the 1
probability that it is drawn from urn A is : 2
4 5 d 2 2
(1) (2)
17 18 eqn of new required line
7 5
(3) (4) xy2 2
18 16
Ans. (2) 4. If the solution y = y(x) of the differential equation
A B C (x4 + 2x3 + 3x2 + 2x + 2)dy – (2x2 + 2x + 3)dx = 0
Sol. 
7R, 5B 5R, 7B 6R, 6B satisfies y(–1) =  , then y(0) is equal to :
4
1 5 1 7 1 6
P(B) = .  .  . 
3 12 3 12 3 12 (1)  (2) 0
12
1 5
.
5  
3 12 
(3) (4)
required probability = 4 2
1 5 7 6  18
.    Ans. (3)
3  12 12 12 
  2x2  2x  3
Sol.  dy   x 4  2x3  3x 2  2x  2
dx

 2x2  2x  3
y dx Sol.
 x2  1 x2  2x  2 
dx dx
y 2
 2
x  2x  2 x 1
y = tan (x + 1) + tan–1x + C
–1
1 5
2
  1
1
2
y(–1) = A  1  3x  2x   dx
4  x
  2
0 C C=0
4 4 1 5
–1
 y = tan (x + 1) + tan x –1  3x 2 2x3  2
A  x    n x
  2 3 1
y(0) = tan–11 = 2
4 2 3
1 5 3 1 5  2 1 5  1 5 
5. Let the sum of the maximum and the minimum A        n 
2 2 2  3 2   2 
2x 2  3x  8 m
values of the function f(x) = be , 1 31 21
2
2x  3x  8 n 1
        n 
where gcd(m, n) = 1. Then m + n is equal to : 2 2 4 38 2
(1) 182 (2) 217 1 5 3 3 15 4 2
A    5   5
(3) 195 (4) 201 2 2 8 4 8 3 3
Ans. (4)
1 3 1
    n 1  5 
2x 2  3x  8 2 8 12
Sol. y 2
2x  3x  8
 1 3 2  15 4 1
x2(2y – 2) + x(3y + 3) + 8y – 8 = 0  5         n 1  5 
 2 4 3  8 3 12
use D  0
(3y + 3)2 – 4(2y – 2) (8y – 8)  0 
14
24
5
15
24
 n 1 5  
(11y – 5) (5y – 11)  0
7. If the system of equations
 5 11 
 y , 
 11 5  x   
2 sin  y  
2 cos  z  0
y = 1 is also included
x + (cos )y + (sin )z = 0
6. One of the points of intersection of the curves
x + (sin )y – (cos )z = 0
1 1 
y = 1 + 3x – 2x2 and y = is  ,2  . Let the area
x 2   
has a non-trivial solution, then    0,  is equal to :
of the region enclosed by these curves be  2
1
24
   
5  m – nloge 1  5 , where , m, n  (1)
3
4
(2)
7
24
N. Then  + m + n is equal to 5 11
(3) (4)
(1) 32 (2) 30 24 24
(3) 29 (4) 31 Ans. (3)
Ans. (2)
 1 2 sin  2 cos  y=f(x
Sol. 1 sin   cos   0
1 cos  sin 
Sol. x
–2 2
 1 2 sin   sin   cos   2 cos   cos   sin    0 x–2
–2
 1  2 cos2  2 sin 2  0
1 f(|x|)  |f(x)|
cos2  sin 2  
2
  1 (–2,0) (2,0)
cos  2     0 2
 4 2 x
–x–2 x–2 0 x
 2 2
2   2n  (0,–2) –2
4 3
 
  n  x  2  2  x  0, 0  x  2
8 3 h(x)  
n = 0,   x  2  2   x 2  x  0

  5
x  
3 8 24
8. There are 5 points P1, P2, P3, P4, P5 on the side AB, –2 0 2
excluding A and B, of a triangle ABC. Similarly
there are 6 points P6, P7, …, P11 on the side BC and 7 2 0

points P12, P13, …, P18 on the side CA of the triangle.   h(x)dx  0 and  h  x  dx  2
0 2
The number of triangles, that can be formed using the
points P1, P2, …, P18 as vertices, is : 10. The sum of all rational terms in the expansion of

2 
15
1 1
(1) 776 (2) 751 5  53 is equal to :
(3) 796 (4) 771
(1) 3133 (2) 633
Ans. (2)
18 (3) 931 (4) 6131
Sol. C3 – 5C3 – 6C3 – 7C3
Ans. (1)
= 751

9.
 2, 2  x  0
Let ƒ(x) =  and h(x) = f(|x|) + |f(x)|. Sol. Tr + 1 = Cr 15   
1 r
53
1 15 r
25
x  2, 0  x  2 r 15 r
2  15C r 5 3 . 2 5
Then  h  x  dx is equal to :
R = 3, 15µ
2

(1) 2 (2) 4  r = 0, 15
(3) 1 (4) 6 2 rational terms
Ans. (1)  15C0 23  15C15  5
5

= 8 + 3125 = 3133
11. Let a unit vector which makes an angle of 60° with 2 = a + 6d ...(i)
2iˆ  2ˆj  kˆ and an angle of 45° with ˆi  kˆ be C . p = a + 7d ...(ii)

 1 q = a + 12d ...(iii)
1 ˆ 2 ˆ
Then C    ˆi  j k  is :
 2 3 2 3  p–2=d ((ii) – (i))
q – p = 5d ((iii) – (ii))
2ˆ 2 ˆ 1 2 2 ˆ
(1)  i j  k q – p = 5(p – 2)
3 3 2 3 
q = 6p – 10
2ˆ 1 ˆ 1ˆ
(2) i j k p2 = 2(6p – 10)
3 3 2 2
p2 – 12p + 20 = 0
 1 1 ˆ  1 1 ˆ  1 2 ˆ p = 10, 2
(3)   i    j  k
 3 2  3 3 2   3 3 
p = 10 ; q = 50
2ˆ 1ˆ d=8
(4) i k
3 2 a = –46
Ans. (4) 2, 10, 50, 250, 1250
Sol. C  C1ˆi  C2 ˆj  C3 kˆ ar4 = a + (n – 1)d
C12 + C22 + C32 = 1 1250 = –46 + (n – 1)8

 
C. 2iˆ  2ˆj  kˆ  C 9 cos60
n = 163
13. Let a, b  R. Let the mean and the variance of 6
3 observations –3, 4, 7, –6, a, b be 2 and 23,
2C1 + 2C2 – C3 =
2
respectively. The mean deviation about the mean
C1 – C3 = 1 of these 6 observations is :
1 13 16
C1 + 2C2 = (1) (2)
2 3 3
2 1 11 14
C1 =  (3) (4)
3 2 3 3
1 Ans. (1)
C2 =
3 2  xi  x 2i
Sol.  2 and  2  23
2 1 6 N
C3 = 
3 2  +  = 10
12. Let the first three terms 2, p and q, with q  2, of a 2 + 2 = 52
G.P. be respectively the 7th, 8th and 13th terms of an solving we get  = 4,  = 6
A.P. If the 5th term of the G.P. is the nth term of the
 xi  x 5  2  5  8  2  4 13
A.P., then n is equal to  
6 6 3
(1) 151 (2) 169
(3) 177 (4) 163
Ans. (4)
Sol. p2 = 2q
14. If 2 and 6 are the roots of the equation ax2 + bx + 1 = 0, 16. Let the point, on the line passing through the points
then the quadratic equation, whose roots are P(1, –2, 3) and Q(5, –4, 7), farther from the origin
1 1 and at a distance of 9 units from the point P, be
and , is :
2a  b 6a  b (, , ). Then 2 + 2 + 2 is equal to :
2 2
(1) 2x + 11x + 12 = 0 (2) 4x + 14x + 12 = 0 (1) 155 (2) 150
2 2
(3) x + 10x + 16 = 0 (4) x + 8x + 12 = 0 (3) 160 (4) 165
Ans. (4) Ans. (1)
b Sol. PQ line
Sol. Sum = 8 = 
a
x 1 y  2 z  3
1 1  
Product = 12 = a= 4 2 4
a 12
pt (4t + 1, –2t – 2, 4t + 3)
2
b=  distance2 = 16t2 + 4t2 + 16t2 = 81
3
3
2 2 1 t
2a + b =   2
12 3 2
pt (7, –5, 9)
6 2 1
6a + b =   2 + 2 + 2 = 155
12 3 6
sum = –8 option (1)
P = 12 17. A square is inscribed in the circle
2
x + 8x + 12 = 0 x2 + y2 – 10x – 6y + 30 = 0. One side of this square
is parallel to y = x + 3. If (xi, yi) are the vertices of
15. Let  and  be the sum and the product of all the
non-zero solutions of the equation  z   z  0 , z  C.
2 the square, then   x2i  y2i  is equal to :
Then 4(2 + 2) is equal to : (1) 148 (2) 156
(1) 6 (2) 4 (3) 160 (4) 152
(3) 8 (4) 2 Ans. (4)
Ans. (2)
Sol.
(5,3)
Sol. z = x + iy 2
z  x  iy

z 2  x2  y2  2ixy
y=x+c & x+y+d=0
2 2 2 2
 x  y  2ixy  x  y  0 53c 8d
 2  2
x=0 or y=0 2 2
2
–y + |y| = 0 x2 + |x| = 0 |c + 2| = 2 8 + d = ±2
2
|y| = |y| x=0 c = 0, – 4 d = –10, –6
y = 0, ±1 pts (5, 5), (3, 3), (7, 3), (5, 1)
 i, –i =i–i=0  x2i  y12   25  25  9  9  49  9  25  1
are roots  = i(–i) = 1
= 152
4(0 + 1) = 4
Option (4)
18. If the domain of the function Sol. |adj(A – 2AT) (2A – AT)| = 28
 3x  22   3x 2  8x  5  |(A – 2AT) (2A – AT)| = 24
sin 1    log e 2  is (, ],
 2x  19   x  3x  10  |A – 2AT| |2A – AT| = ±16
then 3 + 10 is equal to :
(A – 2AT)T = AT – 2A
(1) 97 (2) 100
|A – 2AT| = |AT – 2A|
(3) 95 (4) 98
Ans. (1)  |A – 2AT|2 = 16

3x  22 3x 2  8x  5 |A – 2AT| = ±4
Sol. 1  1 0
2x  19 x 2  3x  10 1 2    2 2 0 
1 0 1    4 0 2 
 41     
x   5, 
 5 0 1 2  2 2 4 

3 + 10 = 97 1 0 
Option (1) 3 0 1
19. Let ƒ(x) = x5 + 2ex/4 for all x  R. Consider a 2  1 2
function g(x) such that (gof) (x) = x for all x  R.
1 + 3 = 4
Then the value of 8g(2) is :
3 = 3
(1) 16 (2) 4
(3) 8 (4) 2 =1
Ans. (1) 1 2 1
Sol. f(x) = 2 A  1 0 1  1  3  4
when x = 0 0 1 2

 g(f(x)) f(x) = 1 |A|2 = 16

1 SECTION-B
g  2  
f 0

 5x  11/3   x  5 1/3 m 5
21. If lim  , where
2 x/4 x 1  2x  3 1/2
 x  4
1/2
n  2n 
2/3
 f(x) = 5x4 + e
4
gcd(m, n) = 1, then 8m + 12n is equal to _____
g(2) = 2
Ans. (100)
Ans = 16
1 1
Option (1) (5x  1)2/3 5  (x  5) 2/3
1 2  
Sol. lim 3 3
x 1 1 1
(2x  3) .2  (x  4) 1/2
1/2
20. Let   (0, ) and A = 1 0 1  . 2 2
0 1 2 
8 5 m 8

3 6 2/3 n  3
T T 8
If det(adj(2A – A ).adj(A – 2A )) = 2 , then
(det(A))2 is equal to :
8m + 12n = 100
(1) 1 (2) 49
(3) 16 (4) 36
Ans. (3)
22. In a survey of 220 students of a higher secondary 24. If the shortest distance between the lines
school, it was found that at least 125 and at most x2 y3 z5 x 3 y 2 z 4
  and   is
130 students studied Mathematics; at least 85 and 2 3 4 1 3 2
at most 95 studied Physics; at least 75 and at most 38
k

  x  dx   
2
90 studied Chemistry; 30 studied both Physics and k and , where [x]
3 5 0
Chemistry; 50 studied both Chemistry and
Mathematics; 40 studied both Mathematics and denotes the greatest integer function, then 63
Physics and 10 studied none of these subjects. Let is equal to _____
m and n respectively be the least and the most Ans. (48)
number of students who studied all the three
38 ˆ ˆi ˆj
(5iˆ  5jˆ  9k) kˆ
subjects. Then m + n is equal to _____ Sol. k̂  .2 3 4
Ans. (45) 3 5 5 1 3 2
M 38 19
P k̂ 
3 5 5
Sol. m 40–x P 19
k
x 5
50–x 30–x 3
k
2

 x    0  
3/2 1 2 3/2
C
2
1  2
0 0 1 2

3 
C  2 1  2  2 
2 
125 m + 90 – x 130
2 2
85 P + 70 – x 95
=2
75  C + 80 – x 90
 63 = 48
m + P + C + 120 – 2x = 210
25. Let A be a square matrix of order 2 such that
15  x  45 & 30 – x  0
|A| = 2 and the sum of its diagonal elements is –3.
 15 x 30 If the points (x, y) satisfying A2 + xA + yI = 0 lie
30 + 15 = 45 on a hyperbola, whose transverse axis is parallel to
23. Let the solution y = y(x) of the differential the x-axis, eccentricity is e and the length of the
dy latus rectum is , then e4 + 4 is equal to ______
equation – y = 1 + 4sinx satisfy y() = 1. Then
dx
Ans. (Bouns)

y   + 10 is equal to _____ NTA Ans. (25)
2
Sol. Given |A| = 2
Ans. (7)
trace A = –3
Sol. ye x    e x  4e x sin x  dx and A2 + xA + yI = 0
ye–x = –e–x – 2(e–xsinx e–xcosx) + C  x = 3, y = 2
y = – 1 – 2(sinx + cosx) + cex so, information is incomplete to determine
y() = 1 c = 0 eccentricity of hyperbola (e) and length of latus
rectum of hyperbola ()
y( /2) = –1 – 2 = –3
Ans = 10 – 3 = 7
 2
C2 3 C2 4 C2 28. Let the length of the focal chord PQ of the
26. Let a  1     ..., parabola y2 = 12x be 15 units. If the distance of PQ
3! 4! 5!
1
C0  1C1 2 C0  2 C1  2 C2 3 C0  3C1  3C2  3C3 from the origin is p, then 10p2 is equal to ____
b  1    ...
1! 2! 3! Ans. (72)
2b Sol.
Then 2 is equal to ______
a
P y2=12x
Ans. (8)
(1  x) (1  x)2 (1  x)3 15
Sol. f(x) = 1 +    .....
1! 2! 3!
(3,0)
e(1 x) 1 (1  x) (1  x)2 (1  x)2 P
 1  
1 x 1 x 2! 3! 4! Q
2 3
C2 C
coef x2 in RHS : 1 +  2  ....  a length of focal chord = 4a cosec2 = 15
3 4
coeff. x2 in L.H.S. 12cosec2 = 15

 x2   x2  4
sin2 =
e  1  x   ....  1  x  ......  5
 2!   2! 
tan2 = 4
e
is e  e   a tan = 2
2!
2 2 2 23 y0
b = 1    ......  e2 equation 2
1! 2! 3! x3
2b y = 2x – 6
8
a2 2x – y –6 = 0
27. Let A be a 3 × 3 matrix of non-negative real 6
P=
1 1 5
elements such that A 1  3 1 . Then the
 
36
1 1 10p2 = 10.  72
5
maximum value of det(A) is _____
Ans. (27) 29. Let ABC be a triangle of area 15 2 and the
 a1 a 2 a 3  vectors AB  ˆi  2ˆj  7kˆ , BC  aiˆ  bjˆ  ckˆ and
Sol. Let A =  b1 b 2 b3  AC  6iˆ  djˆ  2kˆ , d > 0. Then the square of the
 
 c1 c 2 c 3 
length of the largest side of the triangle ABC is
1 1
Ans. (54)
A 1  3 1
1 1 Sol.
   
 a1 + a2 + a 3 = 3 …..(1) A
 b1 + b2 + b3 = 3 …..(2)
 c1 +ca2 + c3 = 3 …..(3)
Now,
|A| = (a1b2c3 + a2b3c1 + a3b1c2)
– (a3b2c1 + a2b1c3 + a1b3c2) B C
 From above in formation, clearly |A|max = 27,
when a1 = 3, b2 = 3, c3 = 3
 ˆi ˆj kˆ tanx = t
1
Area = 1 2 7  15 2 1
2 6 d 2 1 dt 

20 1 3 2
=
6 3
t  2   4
(–4 + 7d) î – ĵ (–2 + 42) + k̂ (d – 12)  
 /4
(7d – 4)2 + (40)2 + (d – 12)2 = 1800 cos2x 1 3
2
50d – 80d – 40 = 0
I2 =  2  sin 2x
dx =  n 
2 2
0
2
5d – 8d – 4 = 0 1  1 2
2 I1  I 2   n
5d – 10d – 2d – 4 36 2 3
5d(d – 2) + 2(d – 2) = 0  a  2, b  6
2 Ans. 8
d = 2 or d = 
5
 d > 0, d = 2

(a + 1) î + (b + 2) ĵ + (c – 7) k̂ = 6 î + 2 ĵ – 2 k̂
a + 1 = 6 & b + 2 = 2, c – 7 = –2
a=5 b=0 c=5
|AB| = 1  4  49  54

|BC| = 25  25  50

|AC| = 86  4  4  44
Ans. 54

4
sin 2 x 1 a 
30. If  1  sin x cos x dx  a loge  3   b 3
, where a,
0

b  N, then a + b is equal to _____

Ans. (8)
 
2
sin 2 x 4
1  cos2x
Sol.  1 dx   2  sin 2x dx
0 1  sin 2x 0
2
1 cos2x
 2  sin 2x   2  sin 2x
(I1) – (I2)
dx
(I1) =  2 tan x
2
1  tan 2 x

4
sec2 x dx
 2 tan 2 x  2 tan x  2
0
 PHYSICS TEST PAPER WITH SOLUTION
SECTION-A  z
Sol. E  ˆi40 cos   t  
31. An electron is projected with uniform velocity  c
along the axis inside a current carrying long
E is along +x direction
solenoid. Then : v is along +z direction
(1) the electron will be accelerated along the axis.
So direction of B will be along +y and magnitude
(2) the electron will continue to move with uniform
E
velocity along the axis of the solenoid. of B will be
c
(3) the electron path will be circular about the axis.
40  z
(4) the electron will experience a force at 45° to the So answer is cos   t   ˆj
axis and execute a helical path.
c  c
33. Which of the following nuclear fragments
Ans. (2)
corresponding to nuclear fission between neutron
 10 n  and uranium isotope  235
92 U 
is correct:
Sol. e  (1) 144
56 Ba 89
36 Kr  4 0 n (2)
1 140
56 Xe  38
94
Sr  310 n
(3) 153
51 Sb  99
41 Nb  30 n (4)
1 144
56 Ba 89
36 Kr  30 n
1

B
Ans. (4)
Since v || B so force on electron due to magnetic Sol. Balancing mass number and atomic number
field is zero. So it will move along axis with
235
92 U 10 n 144
56 Ba  36 Kr  30 n
89 1

uniform velocity. 34. In an experiment to measure focal length (f) of

32. The electric field in an electromagnetic wave is convex lens, the least counts of the measuring
scales for the position of object (u) and for the
 z
given by E  ˆi40 cos   t   NC 1 . The position of image (v) are u and v, respectively.
 c
The error in the measurement of the focal length of
magnetic field induction of this wave is (in SI
the convex lens will be :
unit):
u v  u v 
40  z (1)  (2) f 2  2  2 
(1) B  ˆi cos   t   u v u v 
c  c
 u v   u v 
(3) 2f    (4) f  
 z
(2) B  ˆj40 cos   t    u v   u v 
 c Ans. (2)
40  z Sol. f–1 = v–1 – u–1
(3) B  kˆ cos   t  
c  c –f–2 df = – v–2dv – u–2du
df dv du
40  z  
(4) B  ˆj cos   t   f 2 v2 u 2
c  c
 dv du 
Ans. (4) df  f 2  2  2 
v u 
35. Given below are two statements : P1 – P2 = gh
Statement I : When speed of liquid is zero 1 1
everywhere, pressure difference at any two points P1  P2  v 22  v12
2 2
depends on equation P1 – P2 = g (h2 – h1)
1 1
Statement II : In ventury tube shown gh  v 22  v12
2 2
2gh  12  22
2gh  v 22  v12
Hence answer (4)
h 36. The resistances of the platinum wire of a platinum
resistance thermometer at the ice point and steam

1 point are 8  and 10  respectively. After

2 inserting in a hot bath of temperature 400°C, the
P1, A1 P2, A2 resistance of platinum wire is :

In the light of the above statements, choose the (1) 2 (2) 16  (3) 8  (4) 10 
most appropriate answer from the options given Ans. (2)
below. Sol. Given R0 = 8, R100 = 10
(1) Both Statement I and Statement II are correct.
 R100 = R0 (1 + T)
(2) Statement I is incorrect but Statement II is
Also, R400 = R0 (1 + T1)
correct.
(3) Both Statement I and Statement II are incorrect. 1
 10 = 8 (1 +  × 100)  100 =
(4) Statement I is correct but Statement II is 4
incorrect.  R400 = 8 (1 + 400) = 8 (1 + 1) = 16
Ans. (4) Hence option (2)
h 37. A metal wire of uniform mass density having
length L and mass M is bent to form a semicircular
Sol.
P1 arc and a particle of mass m is placed at the centre
1 2
A1
P2, A2 of the arc. The gravitational force on the particle
by the wire is:
Applying Bernoulli's equation
GMm
1 1 (1) (2) 0
P1  gh 1  v12 = P2  gh 2  v 22 2L2
2 2
[h1 & h2 are height of point from any reference GmM2 2GmM
(3) (4)
level] L2 L2
Given V1 = V2 = 0 (for statement-1) Ans. (4)
 P1 – P2 = g(h2 – h2) Sol. M,L
For statement-2
1 1 R
P1  v12  P2  v 22 O
2 2
 L 40. Which figure shows the correct variation of
We have R 
 applied potential difference (V) with photoelectric
M
2G current (I) at two different intensities of light (I 1 <
g0  L  2GM
R L2 I2) of same wavelengths :
2GMm
 Fm  mg 0  i
L2
Hence option (4) I2
38. On celcius scale the temperature of body increases I1
by 40°C. The increase in temperature on (1)
Fahrenheit scale is: –V0 V
(1) 70°F
i
(2) 68°F I2
(3) 72°F I1
(4) 75°F
(2)
Ans. (3)
–V0 V
Sol. We know that per °C change is equivalent to 1.8°
change in °F.
i
 40° change on celcius scale will corresponds to I2
I1
72° change on Fahrenheit scale.
Hence option (3) (3)
39. An effective power of a combination of 5 identical V
–V0
convex lenses which are kept in contact along the
principal axis is 25 D. Focal length of each of the i
I2
convex lens is :
I1
(1) 20 cm
(2) 50 cm (4)
(3) 500 cm –V0
V
(4) 25 cm
Ans. (1) Ans. (3)
Sol. We know that Peq = Pi Sol. Given lights are of same wavelength.
 given all lenses are identical Hence stopping potential will remain same.
 5P = 25D
Since I2 > I1, hence saturation current
 P = 5D
corresponding to I2 will be greater than that
1 1
  5  f  m  20cm corresponding to I1.
f 5
Hence option (1) Hence option (3)
41. A wooden block, initially at rest on the ground, is Sol. Velocity just before collision = 2gh
pushed by a force which increases linearly with
time t. Which of the following curve best describes h
acceleration of the block with time : Velocity just after collision = 2g  
2
a
1 1
KE  m  2gh   mgh
(1) 2 2
1
(0,0) t  mgh
2
a  % loss in energy

(2) 1
mgh
KE 2
=  100   100  50%
(0,0) t KE i 1
mg2h
2
a
Hence option (4)

(3) 43. The equation of stationary wave is :

 2nt   2x 
(0,0) t y  2a sin   cos  
     
a Which of the following is NOT correct

(4) (1) The dimensions of nt is [L]

(2) The dimensions of n is [LT–1]
(0,0) t
(3) The dimensions of n/ is [T]
Ans. (2) (4) The dimensions of x is [L]
F
Sol. m Ans. (3)

F kt Sol. Comparing the given equation with standard

F  ma  a  
m m 2 n 2
equation of standing  & k
a vs t will be straight line passing through origin.  
Since option (2).
42. If a rubber ball falls from a height h and rebounds n
       T
1

upto the height of h/2. The percentage loss of total

energy of the initial system as well as velocity ball
[nt] = [] = L
before it strikes the ground, respectively, are :
gh [n] = [] = LT–1
(1) 50%, (2) 50%, gh
2 [x] = [] = L
(3) 40%, 2gh (4) 50%, 2gh Hence option (3)
Ans. (4)
44. A body travels 102.5 m in nth second and 115.0 m 46. An infinitely long positively charged straight
th
in (n + 2) second. The acceleration is : thread has a linear charge density  Cm–1. An
(1) 9 m/s2 (2) 6.25 m/s2 electron revolves along a circular path having axis
along the length of the wire. The graph that
(3) 12.5 m/s2 (4) 5 m/s2
correctly represents the variation of the kinetic
Ans. (2) energy of electron as a function of radius of
a circular path from the wire is :
Sol. Given, 102.5  u   2n  1 &
2
KE
a
115  u   2n  3 
2
a (1)
 102.5  u  an  &
2 O r
3a
115  u  an  KE
2
12.5 = 2a  a = 6.25 m/s2
Hence option (2) (2)

45. To measure the internal resistance of a battery, O r

potentiometer is used. For R = 10 , the balance
KE
point is observed at  = 500 cm and for R = l  the

balance point is observed at  = 400 cm. The (3)

internal resistance of the battery is approximately : O r

(1) 0.2  (2) 0.4  KE
(3) 0.1  (4) 0.3  (4)
Ans. (4)
Sol. Let potential gradient be . O r
 i × 10 =  × 500 =  – irs Ans. (2)
 500 =  – 50rs +
+
Also, +
+
i' × 1 =  × 400 =  – i'rs +
r
Sol. + –e
 400 =  – 400 rs +
+
+
10
 100 = 350 rs  rs =  0.3 +
35
Electric field E at a distance r due to infinite long
Hence option (4)
2k
wire is E 
r
 Force of electron  F = eE 15
 2k  –6V –8V
F  e 
 r  10
2ke
F 15  10 15  10
r R eq    6
15  10 25
This force will provide required centripetal force
Correct answer (3)
mv 2 2ke
F  48. P-T diagram of an ideal gas having three different
r r
densities 1, 2, 3 (in three different cases) is
2ke
v shown in the figure. Which of the following is
m
correct :
1 1  2ke  1
KE  mv 2  m  
2 2  m  2
= ke P
3
This is constant so option (2) is correct.
47. The value of net resistance of the network as
T
shown in the given figure is :
15 (1) 2 < 3 (2) 1 > 2
(3) 1 < 2 (4) 1 = 2 = 3
10 Ans. (2)
–8V
–6V Sol. For ideal gas
5
PV = nRT
m
PV  RT
5  15  M
(1)    (2)  
2  4  M  RT
P 
 30  V M
(3) 6 (4)   RT
 11  P
Ans. (3) M
15 (Where m is mass of gas and M is molecular mass
of gas)
10 1
–8V P 1
Sol. –6V 2
5 2 P1
P2 3
Diode 2 is in reverse bias P3
So current will not flow in branch of 2nd diode, So T
we can assume it to be broken wire. for same temperature P1 > P2 > P3
Diode 1 is in forward bias
So 1 > 2 > 3
So it will behave like conducting wire. So new
So correct answer is (2)
circuit will be
49. The co-ordinates of a particle moving in x-y plane 50. In an ac circuit, the instantaneous current is zero,
when the instantaneous voltage is maximum. In
are given by :
this case, the source may be connected to :
x = 2 + 4t, y= 3t + 8t2. A. pure inductor.
The motion of the particle is : B. pure capacitor.
C. pure resistor.
(1) non-uniformly accelerated.
D. combination of an inductor and capacitor.
(2) uniformly accelerated having motion along a Choose the correct answer from the options given
straight line. below :
(1) A, B and C only (2) B, C and D only
(3) uniform motion along a straight line. (3) A and B only (4) A, B and D only
(4) uniformly accelerated having motion along a Ans. (4)

parabolic path. Sol. This is possible when phase difference is
2
Ans. (4) between current and voltage so correct answer will
Sol. x = 2 + 4t be (4)
dx SECTION-B
 vx  4 51. An infinite plane sheet of charge having uniform
dt
surface charge density +s C/m2 is placed on x-y
dv x plane. Another infinitely long line charge having
 ax  0
dt uniform linear charge density +e C/m is placed at
z = 4m plane and parallel to y-axis. If the
y = 3t + 8t2
magnitude values |s| = 2 |e| then at point (0, 0, 2),
dy the ratio of magnitudes of electric field values due
 v y  3  16t
dt to sheet charge to that of line charge is  n :1 .
dv y The value of n is________.
 a y  16 Ans. (16)
dt
the motion will be uniformly accelerated motion. y

For path +s

e
x = 2 + 4t
x
x  2 (0, 0, 2)
t Sol.
4 z=4
z
Put this value of t is equation of y
2
 x2  x2 ES  2 0 r
y  3   8   
 4   4  E 2 0 
this is a quadratic equation so path will be   r

parabola. 
 2  2 4 
Correct answer (4)  
 1
 n = 16
52. A hydrogen atom changes its state from n = 3 to 1
2E  2
n = 2. Due to recoil, the percentage change in the 1   1  
E
11 2
' 2
wave length of emitted light is approximately   mc   mc
 2 2
1 × 10–n. The value of n is__________.
[Given Rhc = 13.6 eV, hc = 1242 eV nm, ' E
1
h = 6.6 × 10–34 J s, mass of the hydrogen atom  2mc 2
= 1.6 × 10–27 kg]
 '  E 1.9  1.6  10 19
Ans. (7)   27
= 10–9
 2mc 2
2 1.67 10  9 10 16

1 1
Sol. E  13.6  2  2  = 1.9 eV
2 3   % change  10–7
hc Correct answer 7
E 

53. The magnetic field existing in a region is given by
hc
 ˆ . A square loop of edge 50 cm
E B  0.2 1  2x  kT
Pi = Pf carrying 0.5 A current is placed in x-y plane with
h its edges parallel to the x-y axes, as shown in
0   mv 
'
figure. The magnitude of the net magnetic force
h
v experienced by the loop is______ mN.
m '
1 hc y
E  mv 2 
2 ' 2m
2
1  h  hc
 m  
2  m '   '
(0,0) x
2m
Now
Ans. (50)
h2 hc
E  
2m '2
' Sol. Force on segment parallel to x-axis will cancel

h2 each other. Hence Fnet will be due to portion

 '2 E  hc ' 0
2m parallel to y-axis.

4Eh 2 F = 0.5 × 0.5 × 6 × 0.2 – 0.5 × 0.5 × 0.2 × 5

hc  h 2 c2 
'  2m = 0.5 × 0.5 × 0.2
2E
= 0.25 × 0.2
2E
hc  hc 1  = 50 × 10–3 N
'  mc2
2E = 50 mN
54. A alternating current at any instant is given by 56. A soap bubble is blown to a diameter of 7 cm.
    36960 erg of work is done in blowing it further. If
i  6  56 sin  100 t    A . The rms value
  3  surface tension of soap solution is 40 dyne/cm then
of the current is___________ A.  22 
the new radius is ______ cm. Take :    .
Ans. (8)  7 
2
 i dt Ans. (7)
Sol. I rms 
 dt Sol.  = U = SA
40dyne  2  7 2  2
 56 
2
36960 erg = 8  r      cm
I rms   6  2
 cm  2 
2
r = 7 cm
 36  28
57. Two wavelengths 1 and 2 are used in Young's
 64
double slit experiment 1 = 450 nm and
= 8A
2 = 650 nm. The minimum order of fringe
55. Twelve wires each having resistance 2 are joined
to form a cube. A battery of 6 V emf is joined produced by 2 which overlaps with the fringe
across point a and c. The voltage difference produced by 1 is n. The value of n is ____.
between e and f is_____ V. Ans. (9)
6V Sol. n22 = n11
b c n 2 1 450 9
  
a d n1  2 650 13
e f n2 = 9
h 58. An elastic spring under tension of 3 N has a length
g
a. Its length is b under tension 2 N. For its length
Ans. (1)
6V (3a – 2b), the value of tension will be_____ N.
Ans. (5)
i1 b c
a d Sol. 3 = K (a – )
i1
i2 e f
Sol. i2/2 2 = K (b – )
h g
i2/2
T = K (3a – 2b – )
From symmetry, current through e-b & g-d = 0
3 3 T = K (3(a – ) – 2 (b – )
 R eq  R  
4 2
62  3 2 
 Current through battery 
3
 4A  K 3    2   
  K   K 
4
i2   2  1A =9–4
8
i2 1 =5N
 V across e-f =  R   2  1V
2 2
59. Two forces F1 and F2 are acting on a body. One 60. A solid sphere and a hollow cylinder roll up
without slipping on same inclined plane with same
force has magnitude thrice that of the other force
initial speed v. The sphere and the cylinder reaches
and the resultant of the two forces is equal to the upto maximum heights h1 and h2, respectively,
force of larger magnitude. The angle between F1 n
above the initial level. The ratio h1 : h2 is . The
10
and F2 is cos1 
 1  . The value of |n| is ____. value of n is_____.

n Ans. (7)
Ans. (6) Sol Gain in P.E. = Loss in K.E.
1  K2 
Sol. F1  F mgh  mv 2  1  2 
2  R 
FR  F2  3F K2
h 1
FR2  F12  F22  2F1 F2 cos  R2
2
9F2 = F2 + 9F2 + 6F2cos 1
h1 5 7  7

1 h 2 1  1 5  2 10
cos   
6 n=7

 1 
  cos1  
 6 
n = –6
|n| = 6
 CHEMISTRY TEST PAPER WITH SOLUTION
SECTION-A 63. Match List -I with List II:
61. What pressure (bar) of H2 would be required to
List - I List - II
make emf of hydrogen electrode zero in pure water
Mechanism steps Effect
at 25ºC ?
 +
(1) 10–14 (2) 10–7 (3) 1 (4) 0.5 NH2 NH2
 (I) – E effect

NTA Ans. (3) (A)

Sol. 2e– + 2H+(aq)  H2(g) H

(II) – R effect
0.059 PH
(B) +H+
E  Eo  log 2 2 +
n [H ]

0.059 PH –
00 log 72 2 + CN
2 (10 ) (C) (III) + E effect
CN

PH2
log 0  
(107 ) 2 
 O
ON=O –  
N O
(D) (IV) + R effect
PH2 +
1
1014

PH2  1014 bar

Choose the correct answer from the options given
62. The correct sequence of ligands in the order of
below :
decreasing field strength is :
(1) (A) – (IV), (B) – (III), (C) – (I), (D) – (II)
(1) CO  H 2 O  F   S2 
(2) (A) – (III), (B) – (I), (C) – (II), (D) – (IV)
  
(2) OH  F  NH 3  CN
(3) (A) – (II), (B) – (IV), (C) – (III), (D) – (I)
– 4– –
(3) NCS > EDTA > CN > CO
(4) (A) – (I), (B) – (II), (C) – (IV), (D) – (III)
(4) S2– > –OH > EDTA4– > CO
Ans. (1)
Ans. (1)

Sol. According to spectrochemical series ligand field

strength is CO > H2O > F– > S2–

 .. +
Sol. NH2 CH2Br NaOH(alc)
NH2 HBr
 66. B C
.. Ether
+ R effect (NH2 electron Br
donating)
Identify B and C and how are A and C related ?
O O O O–
N N
(B) (C)
+ – R effect (NO2 electron
withdrawing) Br OH functional
(1) group
H
+
+E Effect H electron OH OH isomers
+ H+ deficient
+
species)
Br Derivative
Br

 –
+ CN – E Effect (CN electron (2)
CN deficient OH OH
species)
64. What will be the decreasing order of basic strength Br position
of the following conjugate bases ?
 (3) isomers
OH, RO, CH 3COO, C l
Br
(1) C l > OH > R O > CH3CO O Br
(2) R O >–OH > CH3CO O > C l Br chain
(3) –OH > R O > CH3 CO O > C l
(4) isomers
(4) C l > R O > –OH > CH3CO O Br Br
Ans. (2)
Sol. Strong acid have weak conjugate base Ans. (3)
Acidic strength :
H–Cl > CH3COOH > H2O > R–OH Sol.
Conjugate base strength : H
Br
Cl– < CH3COO– < OH < RO–
65. In the precipitation of the iron group (III) in CH2 NaOH
qualitative analysis, ammonium chloride is added alc.
before adding ammonium hydroxide to : Br (E2) Br
(B)
(1) prevent interference by phosphate ions (A)
(2) decrease concentration of –OH ions HBr ether
(3) increase concentration of Cl– ions (Electrophilic
Addition
(4) increase concentration of NH4+ ions
Reaction)
Ans. (2)
Br
Sol. NH4OH NH4  OH
NH 4 Cl  NH 4  Cl

Due to common ion effect of NH 4 , B (C)
[OH–] decreases in such extent that only group-III r
cation can be precipitated , due to their very low
Ksp in the range of 10–38. A and C are position isomer.
67. One of the commonly used electrode is calomel 69. Which one of the following molecules has
electrode. Under which of the following categories maximum dipole moment ?
calomel electrode comes ? (1) NF3 (2) CH4
(1) Metal – Insoluble Salt – Anion electrodes
(3) NH3 (4) PF5
(2) Oxidation – Reduction electrodes
Ans. (3)
(3) Gas – Ion electrodes
Sol. CH4 & PF5 , µnet = 0 (non polar)
(4) Metal ion – Metal electrodes
Ans. (1) µNH3  µNF3
Vector addition of bond Vector subtraction of bond
Sol. Theory based moment & lone pair moment moment & lone pair moment

68. Number of complexes from the following with 70. Number of molecules/ions from the following in
even number of unpaired "d" electrons is____. which the central atom is involved in sp3
[V(H2O)6]3+, [Cr(H2O)6]2+, [Fe(H2O)6]3+, hybridization is ________.
3+ 2+
[Ni(H2O)6] , [Cu(H2O)6]
NO3–, BCl3, ClO2–, ClO3
[Given atomic numbers : V = 23, Cr = 24, Fe = 26,
(1) 2 (2) 4
Ni = 28, Cu = 29]
(3) 3 (4) 1
(1) 2 (2) 4
Ans. (1)
(3) 5 (4) 1
Ans. (1) O– Cl
Cl B
Sol. [V(H2O)6]3+  d2sp3 Sol. O = N Cl Cl
O
3 2
23V :- [Ar]3d 4s
2 sp2 O O–
sp sp 3

V+3 :- [Ar]3d2 , n = 2 (even number of unpaired e–)

[Cr(H2O)6]2+  sp3d2
·
Cl
O O
5 1
24Cr :- [Ar]3d 4s
O
sp3
Cr+2 :- [Ar]3d4 , n = 4 (even number of unpaired e–)
eg 71. Which among the following is incorrect statement?
(1) Electromeric effect dominates over inductive
t2g
effect
[Fe(H2O)6]3+  sp3d2
(2) The electromeric effect is, temporary effect
Fe3+  [Ar]3d54s0
(3) The organic compound shows electromeric
n = 5 (odd number of unpaired e–)
effect in the presence of the reagent only
[Ni(H2O)6] 3+  sp3d2
(4) Hydrogen ion (H+) shows negative electromeric
Ni :- [Ar]3d84s2
effect
Ni+3 :- [Ar]3d7 , n = 3 (odd number of unpaired e–)
[Cu(H2O)6]2+  sp3d2 Ans. (4)

Cu :- [Ar]3d94s0 Sol. Hydrogen ion (H+) shows positive electromeric

n = 1 (odd number of unpaired e–) effect.
72. Given below are two statements : 74. Which of the following is the correct structure of
L-Glucose ?
Statement I : Acidity of -hydrogens of aldehydes CHO
CHO
and ketones is responsible for Aldol reaction. OH
HO
Statement II : Reaction between benzaldehyde OH HO
(1) HO (2)
OH
and ethanal will NOT give Cross – Aldol product. HO HO
In the light of above statements, choose the most CH2OH CH2OH

appropriate answer from the options given below. CHO CHO

(1) Both Statement I and Statement II are HO HO
HO HO
correct. (3) OH (4) HO

(2) Both Statement I and Statement II are OH HO

incorrect. CH2OH CH2OH

Ans. (1)
(3) Statement I is incorrect but Statement II is Sol. Structure of L-Glucose is
CHO
correct.
HO
(4) Statement I is correct but Statement II is
OH
incorrect. HO
HO
Ans. (4)
CH2OH
Sol. Aldehyde and ketones having acidic
75. The element which shows only one oxidation state
-hydrogen show aldol reaction other than its elemental form is :
(1) Cobalt (2) Scandium
O
(3) Titanium (4) Nickel
H–C=O H–C=CH–C–H Ans. (2)
O Sol. Co, Ti, Ni can show +2, +3 and +4 oxidation state,
+ CH3–C–H
Base But 'Sc' only shows +3 stable oxidation state.

(Acidic H) 76. Identify the product in the following reaction :
Benzaldehyde Ethanal Cross aldol product O
Zn – Hg
H Product
73. Which of the following nitrogen containing HCl
compound does not give Lassaigne’s test ?
O
(1) Phenyl hydrazine (2) Glycene OH
(1) (2)
(3) Urea (4) Hydrazine

Ans. (4) OH O
OH
Sol. Hydrazine (NH2–NH2) have no carbon so does not (3) (4)

show Lassaigne’s test.

O
Ans. (4)
 O 80. The correct order of first ionization enthalpy
Sol.
values of the following elements is :
H (A) O (B) N
Zn –Hg (Clemmensen (C) Be (D) F
HCl reduction) (E) B
Choose the correct answer from the options given
O below :
(1) B < D < C < E < A (2) E < C < A < B < D
77. Number of elements from the following that (3) C < E < A < B < D (4) A < B < D < C < E
CANNOT form compounds with valencies which Ans. (2)
match with their respective group valencies is Sol. Correct order of Ist IE
______. Li < B < Be < C < O < N < F < Ne
B, C, N, S, O, F, P, Al, Si     
E<C < A<B<D
(1) 7 (2) 5 (3) 6 (4) 3
Ans. (4) SECTION-B
Sol. N,O, F can’t extend their valencies upto their
81. The enthalpy of formation of ethane (C2H6) from
group number due to the non-availability of vacant
2d like orbital. ethylene by addition of hydrogen where the bond-
78. The Molarity (M) of an aqueous solution energies of C – H, C – C, H – H are 414 kJ, 347 kJ,
containing 5.85 g of NaCl in 500 mL water is : 615 kJ and 435 kJ respectively is - __________ kJ.
(Given : Molar Mass Na : 23 and Cl : 35.5 gmol–1)
Ans. (125)
(1) 20 (2) 0.2
(3) 2 (4) 4 Sol. C2H4(g) + H2(g)  C2H6(g)
Ans. (2) H = BE(C = C) + 4BE (C – H) + BE (H – H)
n NaCl – BE(C – C) – 6BE (C – H)
Sol. M
Vsol (in L) H = BE(C = C) + BE(H – H) – BE(C – C)
5.85 – 2BE(C – H)
M  58.5  0.2M = 615 + 435 – 347 – 2 × 414
0.5 = – 125 kJ
79. Identify the correct set of reagents or reaction
82. The number of correct reaction(s) among the
conditions ‘X’ and ‘Y’ in the following set of
transformation. following is ________.
‘X’ ‘Y’ O
CH3 – CH2 – CH2 – Br Product CH3 – CH – CH3
C CH2
Cl Anhyd.AlCl3
Br (A) +

(1) X = conc.alc. NaOH, 80°C, Y = Br2/CHCl3

O
(2) X = dil.aq. NaOH, 20°C, Y = HBr/acetic acid
C COOH
(3) X = conc.alc. NaOH, 80°C, Y = HBr/acetic Cl H2
(B)
Pd – BaSO4
acid
CHO
(4) X = dil.aq. NaOH, 20°C, Y = Br2/CHCl3 (C)
CO, HCl
Anhyd.AlCl3/CuCl
Ans. (3)
X conc.alc.NaOH CONH2 NH2
Sol. CH3–CH2–CH2–Br  H3O+
o
80 C (D) 
Y  HBr /Acetic acid
CH3–CH=CH2  CH3–CHBr – CH3
Ans. (1)
Sol. 85. Only 2 mL of KMnO4 solution of unknown
O molarity is required to reach the end point of a
C CH2
(A) Cl Anhy. AlCl3
+ (Incorrect) titration of 20 mL of oxalic acid (2 M) in acidic

O medium. The molarity of KMnO4 solution should

C Cl H2 COOH
(B) Pd –BaSO4
(Incorrect) be ________ M.

CO, HCl CHO

(C) Anhy. AlCl3 / CuCl (Correct) NTA Ans. (50)

CONH2 H3O+ NH2 Sol. eq.(KMnO4) = eq.(H2C2O4)

(D) (Incorrect)

M × 2 × 5 = 2 × 20 × 2
83. X g of ethylamine is subjected to reaction with M = 8M
NaNO2/HCl followed by water; evolved dinitrogen
86. Consider the following reaction
gas which occupied 2.24 L volume at STP.
MnO2 + KOH + O2  A + H2O.
X is ______ × 10–1 g.
Ans. (45) Product ‘A’ in neutral or acidic medium

Sol. disproportionate to give products ‘B’ and ‘C’ along

NaNO  HCl HO
CH3CH 2 NH 2 
2
 
2
 CH3CH2–OH + N 2 with water. The sum of spin-only magnetic
Mol.wt.45g 14 g

moment values of B and C is __________ BM.

given : N2 evolved is 2.24 L i.e. 0.1 mole.
i.e. CH3CH2NH2 (ethyl amine) will be 4.5 g (nearest integer)

(=0.1 mole) (Given atomic number of Mn is 25)

Hence the answer = 45 × 10–1 g Ans. (4)
84. The de-Broglie’s wavelength of an electron in the
Sol. MnO2 + KOH + O2  K2MnO4 + H2O
4th orbit is _______ a0. (a0 = Bohr’s radius)

Ans. (8) (A)

Sol. 2rn = nd Neutral/acidic solution

K2MnO4   KMnO4 + MnO2
n2
2a 0  n d
Z Mn+4 :- [Ar]3d3

42
2a 0  4d n = 3,  = 3(3  2) = 3.87 B.M.
1
d  8a 0 Nearest integer is (4)
87. Consider the following transformation involving Sol. 2 = 0.52 × m
first order elementary reaction in each step at 2
m
constant temperature as shown below. 0.52
AB
Step 1
C 
Step 2
P According to question, solution is much diluted
Step 3
P n
Some details of the above reaction are listed so o  solute
P n solvent
below.
P m
Step Rate constant Activation o
  M solvent
–1 P 1000
(sec ) energy (kJ mol–1)
m
1 k1 300 P  P o   M solvent
1000
2 k2 200
2
3 k3 Ea3
If the overall rate constant of the above  760  0.52  18 = 52.615
1000
kk
transformation (k) is given as k  1 2 and the P5 = 760 – 52.615 = 707.385 mm of Hg
k3
89. The number of different chain isomers for C7H16 is
overall activation energy (Ea) is 400 kJ mol–1, then
__________.
the value of Ea3 is ______ kJ mol–1 (nearest
integer) Ans. (9)
Ans. (100) Sol. (i) (ii)
KK
Sol. K  1 2
K3
 E a1  Ea2 (iii) (iv)
 Ea RT RT
A1e A 2e
Ae RT
  E a3

A3 e RT (v) (vi)

 Ea  (Ea1  Ea 2  Ea3 )
A1A 2
Ae RT  e RT (vii) (viii)
A3
Ea  Ea1  Ea2  Ea3 (ix)
400 = 300 + 200 – Ea3
Ea3 = 100 kJ/mole 90. Number of molecules/species from the following

88. 2.5 g of a non-volatile, non-electrolyte is dissolved having one unpaired electron is ________.
in 100 g of water at 25°C. The solution showed a O2 ,O21 , NO, CN 1 , O22 
boiling point elevation by 2°C. Assuming the
solute concentration in negligible with respect to Ans. (2)
the solvent concentration, the vapour pressure of
Sol. According to M.O.T.
the resulting aqueous solution is _______ mm
of Hg (nearest integer) O2  no. of unpaired electrons = 2
[Given : Molal boiling point elevation constant of O2–  no. of unpaired electron = 1
water (Kb) = 0.52 K. kg mol–1, NO  no. of unpaired electron = 1
1 atm pressure = 760 mm of Hg, molar mass of
CN–  no. of unpaired electron = 0
water = 18 g mol–1]
Ans. (707) O22  no. of unpaired electron = 0