Revision date: 05/12/2018 Revision: 2 Supersedes date: 03/05/2018

SAFETY DATA SHEET

Gallup Home and Garden

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name Gallup Home and Garden

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Herbicide

1.3. Details of the supplier of the safety data sheet

Supplier Barclay Chemicals Manufacturing Ltd.
Damastown Industrial Park
Damastown Way
Mulhuddart
Dublin 15
+353 1 811 29 00
+353 1 822 46 78
info@barclay.ie

Manufacturer Barclay Chemicals Manufacturing Ltd.

Damastown Industrial Park
Damastown Way
Mulhuddart
Dublin 15
+353 1 811 29 00
+353 1 822 46 78
info@barclay.ie

1.4. Emergency telephone number

Emergency telephone +353 86 385 77 69

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification (EC 1272/2008)
Physical hazards Not Classified

Health hazards Not Classified

Environmental hazards Not Classified

2.2. Label elements

Hazard statements NC Not Classified

Precautionary statements P102 Keep out of reach of children.

P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.

1/7
Revision date: 05/12/2018 Revision: 2 Supersedes date: 03/05/2018

Gallup Home and Garden

Supplemental label EUH401 To avoid risks to human health and the environment, comply with the instructions for
information use.

2.3. Other hazards

SECTION 3: Composition/information on ingredients

3.2. Mixtures

Glyphosate Isopropylamine Salt 30-60%

CAS number: 38641-94-0 EC number: 254-056-8

Classification
Aquatic Chronic 2 - H411

Poly(oxy-1,2-ethanediyl),.alpha.- phosphono-. omega, - 1-5%

butoxy, isopropylamine salt
CAS number: 431040-31-2

Classification
Skin Corr. 1C - H314
Eye Dam. 1 - H318

(2-hydroxypropyl)ammonium phosphate 1-5%

CAS number: 67952-32-3 EC number: 267-885-5

Classification
Met. Corr. 1 - H290
Acute Tox. 4 - H312
Skin Corr. 1B - H314
Eye Dam. 1 - H318

Alcohols, C8-10, ethoxylated 1-5%

CAS number: 71060-57-6

Classification
Acute Tox. 4 - H302
Eye Dam. 1 - H318

2-[2-(2-butoxyethoxy)ethoxy]ethanol 1-5%
CAS number: 143-22-6 EC number: 205-592-6

Classification
Eye Dam. 1 - H318

The full text for all hazard statements is displayed in Section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures

Inhalation Remove person to fresh air and keep comfortable for breathing. Get medical attention if any
discomfort continues.

2/7
Revision date: 05/12/2018 Revision: 2 Supersedes date: 03/05/2018

Gallup Home and Garden

Ingestion Remove affected person from source of contamination. Remove person to fresh air and keep
comfortable for breathing. Rinse mouth thoroughly with water. Get medical attention. Do not
induce vomiting.

Skin contact Remove affected person from source of contamination. Remove contaminated clothing and
rinse skin thoroughly with water. Get medical attention if irritation persists after washing.

Eye contact Remove affected person from source of contamination. Remove any contact lenses and open
eyelids wide apart. Rinse immediately with plenty of water. Get medical attention if irritation
persists after washing. Show this Safety Data Sheet to the medical personnel.

4.2. Most important symptoms and effects, both acute and delayed
General information Treat symptomatically.

Inhalation This is unlikely to occur but symptoms similar to those of ingestion may develop.

Ingestion May cause stomach pain or vomiting.

Skin contact May be slightly irritating to skin.

Eye contact May be slightly irritating to eyes.

4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media Extinguish with alcohol-resistant foam, carbon dioxide, dry powder or water fog.

Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media

5.2. Special hazards arising from the substance or mixture

Specific hazards None known.

Hazardous combustion None known.

products

5.3. Advice for firefighters

Protective actions during Do not use water jet as an extinguisher, as this will spread the fire. Avoid breathing fire gases
firefighting or vapours. Contain and collect extinguishing water. Fight fire from safe distance or protected
location. If risk of water pollution occurs, notify appropriate authorities. Move containers from
fire area if it can be done without risk.

Special protective equipment Use air-supplied respirator, gloves and protective goggles.
for firefighters

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions For personal protection, see Section 8. Keep unnecessary and unprotected personnel away
from the spillage.

6.2. Environmental precautions

Environmental precautions Do not discharge into drains or watercourses or onto the ground. Contain spillage with sand,
earth or other suitable non-combustible material. Environmental Manager must be informed of
all major spillages.

6.3. Methods and material for containment and cleaning up

3/7
Revision date: 05/12/2018 Revision: 2 Supersedes date: 03/05/2018

Gallup Home and Garden

Methods for cleaning up Contain spillage with sand, earth or other suitable non-combustible material. Collect spillage.
Place waste in labelled, sealed containers. Dispose of waste to licensed waste disposal site in
accordance with the requirements of the local Waste Disposal Authority.

6.4. Reference to other sections

Reference to other sections For personal protection, see Section 8.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Usage precautions Avoid contact with eyes. Do not empty into drains. Do not eat, drink or smoke when using this
product. Protect from freezing and direct sunlight.

7.2. Conditions for safe storage, including any incompatibilities

Storage precautions Keep away from food, drink and animal feeding stuffs. Keep only in the original container.
Protect from freezing and direct sunlight.

7.3. Specific end use(s)

Specific end use(s) The identified uses for this product are detailed in Section 1.2.

SECTION 8: Exposure Controls/personal protection

8.1. Control parameters

8.2. Exposure controls

Protective equipment

Eye/face protection Wear eye protection.

Hand protection Wear protective gloves made of the following material: Nitrile rubber.

Hygiene measures Do not eat, drink or smoke when using this product. Promptly remove any clothing that
becomes wet or contaminated. Provide eyewash station. Wash hands thoroughly after
handling.

SECTION 9: Physical and Chemical Properties

9.1. Information on basic physical and chemical properties

Appearance Clear liquid.

Colour Yellow. Orange.

Odour Characteristic.

pH pH (concentrated solution): 4.5 - 5.5

Relative density 1.155 - 1.175 @ 20°C

Solubility(ies) Miscible with water.

Comments Information given is applicable to the product as supplied.

9.2. Other information

Other information None.

SECTION 10: Stability and reactivity

10.1. Reactivity

4/7
Revision date: 05/12/2018 Revision: 2 Supersedes date: 03/05/2018

Gallup Home and Garden

Reactivity There are no known reactivity hazards associated with this product.

10.2. Chemical stability

Stability Stable at normal ambient temperatures and when used as recommended.

10.3. Possibility of hazardous reactions

Possibility of hazardous No potentially hazardous reactions known.
reactions

10.4. Conditions to avoid

Conditions to avoid Avoid freezing. There are no known conditions that are likely to result in a hazardous
situation.

10.5. Incompatible materials

Materials to avoid None known.

10.6. Hazardous decomposition products

Hazardous decomposition Does not decompose when used and stored as recommended.
products

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity - oral
ATE oral (mg/kg) 43,917.44

Acute toxicity - dermal

ATE dermal (mg/kg) 64,196.09

General information No specific health hazards known.

SECTION 12: Ecological Information

Ecotoxicity Not regarded as dangerous for the environment.

12.1. Toxicity
Acute aquatic toxicity
Acute toxicity - fish LC₅₀, 96 hours: >100 mg/l, Fish

Acute toxicity - aquatic EC₅₀, 48 hours: >100 mg/l, Daphnia magna

invertebrates

Acute toxicity - aquatic plants LC₅₀, 96 hours: >100 mg/l, Algae

12.2. Persistence and degradability

Persistence and degradability The degradability of the product is not known.

12.3. Bioaccumulative potential

Bioaccumulative potential No data available on bioaccumulation.

12.4. Mobility in soil

Mobility The product is miscible with water and may spread in water systems.

12.5. Results of PBT and vPvB assessment

Results of PBT and vPvB This product does not contain any substances classified as PBT or vPvB.
assessment

5/7
Revision date: 05/12/2018 Revision: 2 Supersedes date: 03/05/2018

Gallup Home and Garden

12.6. Other adverse effects

Other adverse effects Not applicable.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

General information Dispose of waste product or used containers in accordance with local regulations

SECTION 14: Transport information

General The product is not covered by international regulations on the transport of dangerous goods
(IMDG, IATA, ADR/RID).

14.1. UN number
Not applicable.

14.2. UN proper shipping name

Not applicable.

14.3. Transport hazard class(es)

No transport warning sign required.

14.4. Packing group

Not applicable.

14.5. Environmental hazards

Environmentally hazardous substance/marine pollutant

No.

14.6. Special precautions for user

Not applicable.

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78
and the IBC Code

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU legislation Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16
December 2008 on classification, labelling and packaging of substances and mixtures (as
amended).
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18
December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals (REACH) (as amended).

15.2. Chemical safety assessment

An Exposure Scenario has not been prepared as a CSR was not required for registration.

SECTION 16: Other information

Revision date 05/12/2018

Revision 2

6/7
Revision date: 05/12/2018 Revision: 2 Supersedes date: 03/05/2018

Gallup Home and Garden

Supersedes date 03/05/2018

SDS number 4892

Hazard statements in full H290 May be corrosive to metals.

H302 Harmful if swallowed.
H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H318 Causes serious eye damage.
H411 Toxic to aquatic life with long lasting effects.

This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate
and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or
completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.

7/7