FINAL JEE–MAIN EXAMINATION – APRIL, 2024

(Held On Friday 05th April, 2024) TIME : 3 : 00 PM to 6 : 00 PM

MATHEMATICS TEST PAPER WITH SOLUTION

SECTION-A Sol. C  x2 + y2 + gx + gy = 0 .....(1)
1. Let ƒ: [–1, 2]  R be given by 2x + 2yy' + g + gy' = 0
ƒ(x) = 2x2 + x + [x2] – [x], where [t] denotes the
 2x  2yy ' 
greatest integer less than or equal to t. The number g   
 1 y' 
of points, where ƒ is not continuous, is :
(1) 6 (2) 3 Put in (1)
(3) 4 (4) 5  2x  2yy ' 
x2  y2    (x  y)  0
Ans. (3)  1 y' 
Sol. Doubtful points : –1, 0, 1, 2, 3,2 (x2 – y2 – 2xy)y' = x2 – y2 + 2xy
at x = 2, 3 3. Let S1 = {z  C : |z|  5},

 
f(x)  2x 2  x  [x]   x 2   Discount   z  1  3 i  
S2  z  C : Im  0
   1  3 i   and
Cont. Cont.    
at x = –1 : S3 = {z  C : Re (z) }. Then
RHL  f(x)  (2  1  ( 1))  0  2  125 125
 Dis. (1) (2)
f(1)  2  1  ( 1)  1  3  6 24
at x = 2 : 125 125
(3) (4)
LHL  f(x)  8  2  1  3  12  4 12
 Cont. Ans. (4)
f(2)  8  2  2  4  12 
at x = 0 : Sol. S1 : x2 + y2  25 .....(1)
LHL  0  0  (1)  0  1
 Dis. S2 : lm of

z  1 3 i 0
f(0)  0 
1  3i 
at x = 1
LHL  2  1  0  0  3   x  iy 
lm of   1   0
 1 3 i 
f(1)  3  1  1  3 Cont.
RHL  2  1  1  1  3 

  x  iy  1  3 i
lm of 
   0
2. The differential equation of the family of circles  4 
passing the origin and having center at the line  
y = x is :  3xy 0 ......(2)
(1) (x2 – y2 + 2xy)dx = (x2 – y2 + 2xy)dy
S3 : x  0 ......(3)
(2) (x2 + y2 + 2xy)dx = (x2 + y2 – 2xy)dy
(3) (x2 – y2 + 2xy)dx = (x2 – y2 – 2xy)dy Area =
5
12

(5)2 
(4) (x2 + y2 – 2xy)dx = (x2 + y2 + 2xy)dy
Ans. (3)
 6. Let a  2iˆ  5jˆ  kˆ , b  2iˆ  2ˆj  2kˆ
and c be three vectors such that

 c  ˆi   a  b  ˆi   a   c  ˆi  . a.c  29 ,
60°
then c.  2iˆ  ˆj  kˆ  is equal to :

(1) 10 (2) 5
4. The area enclosed between the curves y = x|x| and (3) 15 (4) 12
y = x – |x| is : Ans. (2)
8 2
(1) (2) Sol. Let's assume v  a  b  ˆi
3 3

(3) 1 (4)
4  5iˆ  3jˆ  kˆ
3
Ans. (4) and c  ˆi  p
Sol. So,
pv  a p
y = x2
pv  pa  0

p  v  a   0
y=0
(0,0)  p   v  a 
y = 2x
(–2,–4) 
c  i   7iˆ  8jˆ 
y = –x2

a.c  a.iˆ  a. 7iˆ  8jˆ 
29  2   14  40 
0
4
 x
2
A  2x 
2
3
1

5. 60 words can be made using all the letters of the 2
word BHBJO, with or without meaning. If these
words are written as in a dictionary, then the 50th      
c. 2iˆ  ˆj  kˆ  ˆi. 2iˆ  ˆj  kˆ   7iˆ  8jˆ . 2iˆ  ˆj  kˆ 
word is : 1
(1) OBBHJ (2) HBBJO   14  8  2  5
2
(3) OBBJH (4) JBBOH
Ans. (3) 7. Consider three vectors a, b,c . Let a  2, b  3
Sol. B B H J O
 
B _____ 4!  24 and a  b  c . If   0,  is the angle between
 3
4!
H _____  12 the vectors b and c , then the minimum value of
2!
2
4! 27 c  a is equal to :
J _____  12
2!
(1) 110 (2) 105
O B B H J
(3) 124 (4) 121
O B B J H  50th rank
Ans. (3)
Sol.
2 2
c  a  c  a  2a.c 9. Let (, , ) be the point (8, 5, 7) in the line
x 1 y 1 z  2
2   . Then  +  +  is equal to
 c 40 2 3 5
(1) 16 (2) 18
 a  bc
(3) 14 (4) 20
a  bc Ans. (3)
Sol.
2  3 c sin 
A (8, 5, 7)
2  
c  cosec    0, 
3  3
2 2  2  M
c min   cosec  , 
3 3  3  (2 +1, 3 – 1, 5 + 2)

2  16 
 27 c  a min  27   4   124
 27  A'
8. Let A(–1, 1) and B(2, 3) be two points and P be a
variable point above the line AB such that the area 
AM. 2iˆ  3jˆ  5kˆ  0 
of PAB is 10. If the locus of P is ax + by = 15,
(2 – 7)(2) + (3 – 6)(3) + (5 – 5)(5) = 0
then 5a + 2b is :
12 6 38 = 57
(1)  (2)  3
5 5 
(3) 4 (4) 6 2
Ans. (1)  7 19 
M  4, , 
Sol.  2 2 
P(h,k) A'(0,2,12)
10. If the constant term in the expansion of
12
B(2,3)  5 3 2x 
  3  , x  0, is ×28× 5 3 , then 25 is
A(–1,1)  x 5 
equal to :
(1) 639 (2) 724
(3) 693 (4) 742
Ans. (3)
12  r r
h k 1  31/5 
12  2x 
1 Sol. Tr 1  Cr    1/3 
1 1 1  10  x  5 
2
2 3 1 12  r
C r  3 2 x
12 r 2r 12
5
–2x + 3y = 25 Tr 1 
 5
r /3

6 9
 x  y  15 r=6
5 5
C6  3 2
12 6/5 6
6 9  9  11  7  8 1/5
a=  ,b= T7  2
  2 .3
5 5 5  25 
18 25 = 693
5a = –6, 2b =
5
11. Let ƒ, g : R  R be defined as : ƒ(x) = |x – 1| and 13. Let the set S = {2, 4, 8, 16, ....., 512} be partitioned
into 3 sets A, B, C with equal number of elements such
 e x , x  0
g(x)   . Then the function ƒ(g(x)) is that A  B  C = S and A  B = B  C = A  C = .
x  1, x  0 The maximum number of such possible partitions of S
(1) neither one-one nor onto. is equal to :
(2) one-one but not onto. (1) 1680 (2) 1520
(3) 1710 (4) 1640
(3) both one-one and onto.
Ans. (1)
(4) onto but not one-one.
Sol.
Ans. (1)
A B
Sol. f(g(x)) = |g(x) – 1|

 ex  1 x0
fog 
 x  1  1 x0 C

e x  1 x  0
fog  9!
 x x0  3!
 3!3!3! 3!
14. The values of m, n, for which the system of
equations
x + y + z = 4,
2x + 5y + 5z = 17,
x + 2y + mz = n
has infinitely many solutions, satisfy the equation :
(1) m2 + n2 – m – n = 46
12. Let the circle C1 : x2 + y2 – 2(x + y) + 1 = 0 and C2
(2) m2 + n2 + m + n = 64
be a circle having centre at (–1, 0) and radius 2. If (3) m2 + n2 + mn = 68
the line of the common chord of C1 and C2 (4) m2 + n2 – mn = 39
intersects the y-axis at the point P, then the square Ans. (4)
of the distance of P from the centre of C1 is : 1 1 1
Sol. D 2 5 5 0 m=2
(1) 2 (2) 1
1 2 m
(3) 6 (4) 4
Ans. (1) 1 1 4
D3  2 5 17  0  n = 7
Sol. S1 : x2 + y2 – 2x – 2y + 1 = 0
1 2 n
S2 : x2 + y2 + 2x – 3 = 0
Common chord = S1 – S2 = 0 15. The coefficients a, b, c in the quadratic equation
–4x – 2y + 4 = 0 ax2 + bx + c = 0 are from the set {1, 2, 3, 4, 5, 6}.
If the probability of this equation having one real
2x + y = 2  P(0, 2)
root bigger than the other is p, then 216p equals :
2
d (c,p) = (1 – 0)2 + (2 – 1)2 = 2 (1) 57 (2) 38
(3) 19 (4) 76
Ans. (2)
Sol. D > 0 1

x
m 1
17. Let (m, n) = (1  x) n 1 dx , m, n > 0. If
b2 > 4ac
0
b = 3 : (a, c) = (1, 1)(1, 2)(2,1) 1

 (1  x
10 20
b = 4 : (a, c) = (1, 1)(1, 2)(2,1)(1,3)(3,1) ) dx  a  (b,c) , then 100(a + b + x)
0
b = 5 : (a, c) = (1,1)(1,2)(2,1) (1,3)(3,1)(1,4)(4,1) equals ______.
(1,5)(5,1)(1,6)(6,1)(2,3)(3,2)(2,2) (1) 1021 (2) 1120
b = 6 : (a, c) = (1,1)(1,2)(2,1) (1,3)(3,1)(1,4)(4,1) (3) 2012 (4) 2120
Ans. (4)
(1,5)(5,1)(1,6)(6,1)(2,3)(3,2)(2,4)(4,2)(2,2) 1

 
20
fav. cases = 38 Sol. I   1. 1  x10 dx
0
38
Prob. : x10 = t
666
x = t1/10
16. Let ABCD and AEFG be squares of side 4 and
1
dx   t 
9/10
dt
2 units, respectively. The point E is on the line 10
1
segment AB and the point F is on the diagonal AC. 1
 t  dt
9/10
I   (1  t)20
Then the radius r of the circle passing through the 0
10
point F and touching the line segments BC and CD 1
1 9/10
1  t  dt
20

satisfies :
I 
10 0
t

(1) r = 1 (2) r2 – 8r + 8 = 0 1 1
a= b= c = 21
(3) 2r2 – 4r + 1 = 0 (4) 2r2 – 8r + 7 = 0 10 10
  3
Ans. (2) 
18. Let   0 and A       .
Sol.    2 
(0, 4) (4, 4)
 3 9 3 
D C  
If B    7 2  is the matrix of cofactors
 2 5 2 
of the elements of A, then det(AB) is equal to :
F(2,2) (1) 343 (2) 125
(3) 64 (4) 216
Ans. (4)
Sol. Equating co-factor fo A21
A E B (4, 0)
(22 – 3) = 
(0, 0) (2, 0)  = 0, 2 (accept)
y=4 Now, 22 –  = 3
=2 =1
r
o |AB| = |A cof (A)| = |A|3
(4–r, 4–r ) r 1 2 3
r
x=4 A  2 2 1  6  2(9)  3(6)  6
F
(2,2) 1 2 4
OF2 = r2
(2 – r)2 + (2 – r)2 = r2
r2 – 8r + 8 = 0
 2cos  cos2 SECTION-B
19. If y()  ,
cos3  4 cos2  5cos   2 21. Let the mean and the standard deviation of the
 probability distribution
then at   , y" + y' + y is equal to:
2 X  1 0 –3
 P(X) 1 K 1 1
(1) (2) 1 
2 3 6 4
1
(3) (4) 2 be  and , respectively. If  –  = 2, then  +  is
2
equal to _____.
Ans. (4)
Ans. (5)
2cos  2 cos2   1 1 1 1 1
Sol. y Sol.  k   1  k
4 cos3   3cos   8cos2   4  5cos   2 3 6 4 4

y
 2 cos 2
  2 cos   1  
 1 3
 –
 2 cos 2

  2 cos   1  2 cos   2  3 4 4
 1
1 1   –
y  3 2
2  1  cos  
2
 1  1 1 1  1
  y=    2   9  –  – 
2 2  3 4 4  3 2

1 1  2 2  9
y'      sin      
2  1  cos  2  9 3 4
 
=+2
 1
  y= 2 2  9  2 9
2     2  
2
2 2     
9 3 4 9 4
1  cos  1  cos   sin (2)(1  cos)( sin ) 
2

y"     2 2
– 0
2 (1  cos )4  9 3

  = 0, (reject) or  = 6
  y=1
2 ( x  0 is already given)
20. For x 0, the least value of K, for which 41+x + 41–x,   +  = 2 + 2
K =5
, 16x + 16–x are three consecutive terms of an
2
A.P. is equal to :
(1) 10 (2) 4 22. Let y = y(x) be the solution of the differential
(3) 8 (4) 16 1

Ans. (1) equation

dy

2x
y  xe
1 x2  ; y(0) = 0.
 
2
dx 1  x 2
 1   1 
4  4 x  x    42x  2x 
Sol. k  4   4  Then the area enclosed by the curve
2 2 
1

ƒ(x)  y(x)e
1 x2  and the line y – x = 4 is ____.
k  10
Ans. (18)
 
2x
dx –1 24. Let the point (–1, , ) lie on the line of the
1 x2 2 2
Sol. IF = e  e 1 x shortest distance between the lines
–1 1 –1 x2 y2 z5 x  2 y  6 z 1
dx
  and   .
y  e 1 x   x  e 1 x  e 1 x
2 2 2
3 4 2 1 2 0
–1 Then ( – )2 is equal to _____.
2 x2
y  e 1 x  c Ans. (25)
2
Sol.
(0, 0)  C  0
1 (–2,–6,1)
x2 2 Q
y(x)  e 1 x
2
x2 (–1,,)
f(x) 
2
y = x2/2 (–2,2,5)

(4, 8)
(–2, 2)
P(–3– 2, 4+ 2, 2+ 5)
y = x/4 Q(– – 2, 2 – 6, 1)
DRS of PQ = (3 – , 2 – 4 – 8, –2 – 4)
4
x2 ˆi ˆj kˆ
A   (x  4)  dx  18
–2
2 DRS of PQ = –1 2 0
23. The number of solutions of –3 4 2
sin2x + (2 + 2x – x2)sinx – 3(x – 1)2 = 0, where
–  x  , is   4iˆ  2 ˆj  2kˆ 
Ans. (2) OR
Sol. sin2x – (x2 – 2x – 2)sinx – 3(x – 1) 2 = 0 (2, 1, 1)
2 2 2
sin x – (x – 1) )sinx – 3(x–1) = 0     – 4 – 8 –2 – 4
 
2 1 1
roots :   =  + 2 & 7 =  – 8
2
–3 (x–1)   –1  1
sinx = –3 (reject) or (x – 1)2 Q : (–3, –4, 1)
sinx = (x – 1)2
x  3 y  4 z 1
LPQ =  
2 1 1
  4  1
(–1, , )  1 = 
1 1
  = –3,  = 2
(1,0) ( – )2 = 25
25. If 26. Let a > 0 be a root of the equation 2x2 + x – 2 = 0.

1
3 2

5  2 6 9 3  11 2 49  20 6
18
 
180
 ....
If lim

16 1  cos(2  x  2x2 )    17 , where
2 3 36 3
x
1 (1  ax2 )
a
 b  a
upto  = 2   1  loge   , where a and b are ,   Z then  +  is equal to ______.
 a  b
 
Ans. (170)
integers with gcd(a, b) = 1, then 11a + 18b is equal
a
to ______.
Sol. 2x2 + x – 2 = 0
b
Ans. (76)

x x2 x3 x4
Sol. S 1     ....
2 3 18 36 3 180 2x2 – x – 2 = 0
x
Put  t, where x  3 – 2
3 2
  1  1   1
t t t t 2 3 4  1 – cos2  x –  x –   4 x – 
  a  b   b
S 1     .... lim 16  2
 2
2 6 12 20 x
1
a
 1
4 x  
 1
a2  x – 
 b  a
 1 1 1 1 1 1 1
S  1  t 1 –   t 2  –   t 3  –   t 4  – 
 2 2 3 3 4  4 5 2 1 1
2
 16  2  – 
 t2 t3 t3   t t2 t3 t 4  a a b
S   1  t     ...  –      ... 
 2 3 4  2 3 4 5  32  17  17.8 17  8  16
 2   2 
a  4 a  –1  117 
2
 t2  1  t2 t3 
S   t   ...  –  t    ...   2
 2  t 2 3 
136.16 18  2 7
 
 1 1 
S  2   1 –   – log 1 – t     – 1  log 1 – t   2 18.2 7 18  2 7
 t t 
136
    18  2 7   16
3 3– 2 256
S2 – 1  log  1 – 
 3– 2   3 
 153  17 17     17
 2  2
S2  loge  +  = 153 + 17 = 170
 3– 2 3

 6  2 2  3  2 27. If ƒ(t)  
2xdx
, 0 < t < , then the value
S2 log e  2    1  log e 2 2
2 3  2  3 0 1  cos t sin x


a = 2, b = 3 2
2 dt
11a + 18b = 11 × 2 +18 × 3 = 76 of  ƒ(t) equals _____.
0

Ans. (1)

2x
Sol. f(t)   2 2
dx .....(1)
0 1 – cos t sin x
 
( – x)dx P(7,4)
 2 2 2
....(2)
0 1 – cos t sin x
A

 2
2f(t)  2  22
dx B
0 1 – cos t sin x (2, 0) C(4, 0) (6, 0)


f(t)   2
dx
2
m=9
0 1 – cos t sin x
M = 41
divide & by cos2x

M2 – m2 = 412 – 92 = 1600
2
sec xdx
f(t)    2 2 2 29. Let a line perpendicular to the line 2x – y = 10
0 sec x – cos t tan x
touch the parabola y2 = 4(x – 9) at the point P. The
 /2
sec 2 xdx distance of the point P from the centre of the circle
f(t)  2  
sec 2 x – cos2 t tan 2 x
0 x2 + y2 – 14x – 8y + 56 = 0 is ______.
tanx = z Ans. (10)
2
sec xdx = dz
Sol. y2 = 4(x – 9)

dz –1
f(t)  2   2 2 slope of tangent =
0 1  sin t  z 2
2  1 2 1 
 Point of contact P  9  , 
 1  –1 
2
sin t 
  –  2 
 /2   2
2
Then  f(t)
dt P(13, –4)
0
center of circle C(7, 4)
 /2
  sin t dt distance CP  13 – 7    –4 – 4 
2 2

0
= 10
=1
30. The number of real solutions of the equation
28. Let the maximum and minimum values of
x |x + 5| + 2|x + 7| – 2 = 0 is _____.

    x  7 , x  R be M and m
2
2 2
8x  x  12  4 Ans. (3)
30. The number of real solutions of the equation
respectively. Then M2 – m2 is equal to _____.
x |x + 5| + 2|x + 7| – 2 = 0 is _____.
Ans. (1600)
Allen Ans. (3)
2 2
Sol. (x – 7) + (y – 4)
Sol. Case I : x  –5
y  8x – x 2 – 12 x2 + 5x + 2x + 12 = 0

2 2
x2 + 7x + 12 = 0
y  –(x – 4)  16 –12
x = –3, –4
 x – 4   y2  4
2
Case II : –7 < x < –5
–x2 – 5x + 2x + 14 – 2 = 0
–x2 – 3x + 12 = 0
–3  9  48
x
2
–3  57

2
–3 – 57 –3  57
x , (rejected)
2 2
Case III : x  –7
–x2 – 5x – 2x – 14 – 2 = 0
x2 + 7x + 16 = 0
D = 49 – 64 < 0
No solutions
No. of solutions = 3
 PHYSICS TEST PAPER WITH SOLUTION
SECTION-A mv 2
Sol. FC 
31. Given below are two statements : r
Statement I : When the white light passed through
Kq1q 2 mv2
a prism, the red light bends lesser than yellow and 
r2 r
violet. mv2r2 = Kq1q2r
Statement II : The refractive indices are different
L2
for different wavelengths in dispersive medium. In  Kq1q 2 r
m
the light of the above statements, choose the
L r
correct answer from the options given below :
(1) Both Statement I and Statement II are true. 34. A galvanometer of resistance 100 when

(2) Statement I is true but Statement II is false. connected in series with 400 measures a voltage
(3) Both Statement I and Statement II are false. of upto 10 V. The value of resistance required to
convert the galvanometer into ammeter to read
(4) Statement I is false but Statement II is true.
upto 10 A is x × 10–2 . The value of x is :
Ans. (1)
(1) 2 (2) 800
Sol. As red > yellow > violet
(3) 20 (4) 200
Light ray with longer wavelength bends less.
Ans. (3)
32. Which of the following statement is not true about
10
stopping potential (V0)? Sol. ig   20  10 3 A
400  100
(1) It depends on the nature of emitter material.
For ammeter
(2) It depends upon frequency of the incident light.
Let shunt resistance = S
(3) It increases with increase in intensity of the
igR = (i – ig)S
incident light.
20 × 10–3 × 100 = 10 S
(4) It is 1/e times the maximum kinetic energy of
S = 20 × 10–2 
electrons emitted.
35. The vehicles carrying inflammable fluids usually
Ans. (3)
have metallic chains touching the ground :
Sol. KEmax = h – 0 = eV (1) To conduct excess charge due to air friction to
33. The angular momentum of an electron in a ground and prevent sparking.
hydrogen atom is proportional to : (Where r is the (2) To alert other vehicles.
radius of orbit of electron) (3) To protect tyres from catching dirt from
1 ground.
(1) r (2)
r (4) It is a custom.
1 Ans. (1)
(3) r (4)
r Sol. Static charge is developed due to air friction. This
Ans. (1) can result in combustion. So, metallic chains is
used to discharge excess charge.
36. If n is the number density and d is the diameter of 38. The electrostatic force (F1 ) and magnetic force
the molecule, then the average distance covered by
a molecule between two successive collisions (i.e. (F2 ) acting on a charge q moving with velocity v
mean free path) is represented by : can be written :
1 (1) F1  qV.E , F2  q(B.V)
(1) (2) 2nd 2
2nd 2
(2) F1  qB , F2  q(B  V)
1 1
(3) (4) (3) F1  qE , F2  q(V  B)
2nd 2 2n 2 2d 2
Ans. (3) (4) F1  qE , F2  q(B  V)
Sol. n = number of molecule per unit volume Ans. (3)
d = diameter of the molecule Sol. F1  qE (Theory)
1
 (By Theory) F2  q(V  B)
2d 2 n
37. A particle moves in x-y plane under the influence 39. A man carrying a monkey on his shoulder does
cycling smoothly on a circular track of radius 9m
of a force F such that its linear momentum is
and completes 120 revolutions in 3 minutes. The
P(t)  ˆi cos(kt)  ˆjsin(kt) . If k is constant, the magnitude of centripetal acceleration of monkey is
angle between F and P will be : (in m/s2) :
  (1) zero (2) 16 2 ms–2
(1) (2)
2 6 (3) 42 ms–2 (4) 57600 2 ms–2
  Ans. (2)
(3) (4)
4 3 Sol. Given : R = 9m,
Ans. (1) 120 revolution in 3 min
120 Re v. 120  2 rad 4
Sol. P  cos(kt)iˆ  sin(kt)ˆj ; P  1    rad / s
3min. 3  60 sec 3
P  mv 2
 4 
  9 = 16 m/s
2 2 2
acentripetal =  R = 
 Pˆ  vˆ  3
 v̂  cos(kt)iˆ  sin(kt)ˆj 40. A series LCR circuit is subjected to an AC signal
of 200 V, 50 Hz. If the voltage across the inductor
k sin(kt)iˆ  k cos(kt)ˆj
â  (L = 10 mH) is 31.4 V, then the current in this
k
circuit is ________ :
 â   sin ktiˆ  cos ktjˆ (1) 68 A (2) 63 A
Fˆ  aˆ   sin kt ˆi  cos kt ˆj (3) 10 A (4) 10 mA
Ans. (3)
ˆ ˆ
F.P sin kt cos t  sin kt cos t
cos    0 Sol. Voltage across inductor VL = IXL
Fˆ Pˆ 1 1
31.4 = I[L]
 31.4 = I[L(2f)]

2 31.4 = I[10 × 10–3(2 × 3.14) × 50
 I = 10 A
41. What is the dimensional formula of ab–1 in the Sol. P = costant  FV = constant
 a 
m
dV
equation  P   (V – b) = RT, where letters V = constant
 V2  dt
V t
have their usual meaning.
(1) [M0L3T–2] (2) [ML2T–2]  VdV  (C) dt
0 0
(3) [M–1L5T3] (4) [M6L7T4]
 V2 
Ans. (2)    Ct
 2 
Sol. [V] = [b]
V  t1/2
 Dimension of b = [L3]
ds
 a   t1/2
& [P]   2  dt
V  S t

 ds  K  t
2 –1 –2 6 1/2
[a] = [PV ] = [ML T ][L ] dt
5 –2 0 0
Dimension of a = [ML T ]
2
1 [ML5T 2 ] S  K  t 3/2
 ab  3
 [ML2T 2 ] 3
[L ]
S  t3/2
42. The output (Y) of logic circuit given below is 0
 displacement is proportional to (t)3/2
only when :
44. Match List-I with List-II :-
A
List-I List-II
B Y EM-Wave Wavelength
Range
1
(A) Infra-red (I) < 10–3 nm
(1) A = 1, B = 0 (2) A = 0, B = 0
(B) Ultraviolet (II) 400 nm to 1 nm
(3) A = 1, B = 1 (4) A = 0, B = 1
(C) X-rays (III) 1 mm to 700 nm
Ans. (2)
(D) Gamma rays (IV) 1 nm to 10–3 nm
Sol.
Choose the correct answer from the options given
OR gate
0A 0 0 below :
0 (1) (A)-(II), (B)-(I), (C)-(IV), (D)-(III)
0B Y0
0 (2) (A)-(III), (B)-(II), (C)-(IV), (D)-(I)
0
1 OR gate (3) (A)-(IV), (B)-(III), (C)-(II), (D)-(I)
AND gate
(4) (A)-(I), (B)-(III), (C)-(II), (D)-(IV)
43. A body is moving unidirectionally under the Ans. (2)
influence of a constant power source. Its Sol. Infrared is the least energetic thus having biggest
displacement in time t is proportional to :
wavelength () & gamma rays are most energetic
(1) t2 (2) t2/3
thus having smallest wavelength ().
(3) t3/2 (4) t
Ans. (3)
45. During an adiabatic process, if the pressure of a Choose the correct answer from the options given
gas is found to be proportional to the cube of its below :
CP (1) (A)-(II), (B)-(IV), (C)-(I), (D)-(III)
absolute temperature, then the ratio of for the (2) (A)-(IV), (B)-(II), (C)-(III), (D)-(I)
CV
(3) (A)-(III), (B)-(IV), (C)-(I), (D)-(II)
gas is : (4) (A)-(III), (B)-(I), (C)-(II), (D)-(IV)
5 9 Ans. (3)
(1) (2)
3 7 Frestoring
Sol. (A) stress 
3 7 A
(3) (4)
2 5 If A = 1
Ans. (3) Stress = Frestoring
(A)-(III)
Sol. P  T3
(B)
PT–3 = constant
PV  Shear stress
 nR = constant from ideal gas equation
T
(P) (PV)–3 = constant (B)-(IV)
P–2 V–3 = cosntant ...(1) (C)
Process equation for adiabatic process is
PVy = constant ...(2)  Volumetric stress
Comparing equation (1) and (2)
CP 3
y (C)-(I)
CV 2
(D)
46. Match List-I with List-II :
List-I List-II  Longitudinal stress
(A) A force that (I) Bulk modulus
(D)-(II)
restores an
47. A vernier callipers has 20 divisions on the vernier
elastic body of scale, which coincides with 19th division on the
unit area to its main scale. The least count of the instrument is
original state 0.1 mm. One main scale division is equal to
(B) Two equal and (II) Young's modulus ____mm.
opposite forces (1) 1 (2) 0.5
parallel to (3) 2 (4) 5
opposite faces Ans. (3)
(C) Forces (III) Stress Sol. 20 VSD = 19 MSD
perpendicular 19
1VSD  MSD
everywhere to 20
the surface per L.C. = 1 MSD – 1 VSD
unit area same 19
0.1 mm = 1MSD  MSD
everywhere 20
(D) Two equal and (IV) Shear modulus 1
0.1  MSD
opposite forces 20
perpendicular to 1 MSD = 2mm
opposite faces
48. A heavy box of mass 50 kg is moving on a 50. The ratio of heat dissipated per second through the
horizontal surface. If co-efficient of kinetic friction resistance 5  and 10  in the circuit given below

between the box and horizontal surface is 0.3 then is :

force of kinetic friction is : 20 5

(1) 14.7 N
10
(2) 147 N
(3) 1.47 N 10V
(4) 1470 N (1) 1 : 2 (2) 2 : 1

Ans. (2) (3) 4 : 1 (4) 1 : 1

Ans. (2)
Sol.
Sol.
50kg v i1
µk = 0.3
20 5
Fk = µkN = 0.3 × 50 × 9.8 = 147 N
i2 10
49. A satellite revolving around a planet in stationary
orbit has time period 6 hours. The mass of planet is
10V
one-fourth the mass of earth. The radius orbit of
i1 10 2
 
planet is : (Given = Radius of geo-stationary orbit i2 5 1
for earth is 4.2 × 104 km) 2
P1 i12 R1  2  5 2
    
(1) 1.4 × 104 km P2 i 22 R 2  1  10 1
(2) 8.4 × 104 km
SECTION-B
5
(3) 1.68 × 10 km 51. A solenoid of length 0.5 m has a radius of 1 cm
4
(4) 1.05 × 10 km and is made up of 'm' number of turns. It carries a
Ans. (4) current of 5A. If the magnitude of the magnetic
field inside the solenoid is 6.28 × 10–3 T, then the
2r 3/2
Sol. T value of m is :
GM
Ans. (500)
3/2 1/2
T1  r1   M2  Sol. µ0ni = B n = number of turns per unit length
   
T2  r2   M1  m
µ0   i  B
1/2  
6 (r1 )3/2  M 
 4 3/2  
24 (4.2 10 )  M / 4  B. 6.28 103  0.5
m 
µ0i 12.56  107  5
r1 = 1.05 × 104 km
m = 500
52. The shortest wavelength of the spectral lines in the 54. A sonometer wire of resonating length 90 cm has a
Lyman series of hydrogen spectrum is 915 Å. The
fundamental frequency of 400 Hz when kept under
longest wavelength of spectral lines in the Balmer
series will be _______ Å. some tension. The resonating length of the wire
Ans. (6588) with fundamental frequency of 600 Hz under same
Sol. Lyman Series
tension _______ cm.
Ans. (60)
Sol.
n=L

 1 /2
hc 1 
Shortest,  13.6  2  2 
  n1 n 2 
L
hc
 E ;  13.6 1
0
T
Balmer Series : f0 = 400 Hz ; v  = constant
n=3
µ

n=2  L ; v = f0
2
hc  1 1
 13.6  2  2  v
1 2 3   L  v = 2Lf0
2f 0
hc 1 1
 13.6   
1 4 9 L' 
v

2Lf 0
hc  5  2f ' 2f '
 13.6   
1  36  Lf 0 90  400
   60
13.6 0 5 f' 600
  13.6 
1 36 55. A hollow sphere is rolling on a plane surface about
  36 915  36 its axis of symmetry. The ratio of rotational kinetic
1  0 =  6588
5 5 x
53. In a single slit experiment, a parallel beam of green energy to its total kinetic energy is . The value
light of wavelength 550 nm passes through a slit of 5
width 0.20 mm. The transmitted light is collected of x is ________.
on a screen 100 cm away. The distance of first
order minima from the central maximum will be Ans. (2)
x × 10–5 m. The value of x is :  1  2
1 2 2 2
Ans. (275) I   mR  
Sol. Sol. 2   
2 3 
I  mv 2   
1 2 1 1 2 1
 mR 2  2  m(R) 2
y 2 2  2  3  2
 = 550 nm
d = 0.2 mm 2
2
 3 
2
100cm 1 5
3
D 550 109 100 102 x=2
y  = 275
d 0.2 103
56. A hydraulic press containing water has two arms 58. The maximum height reached by a projectile is
with diameters as mentioned in the figure. A force 64 m. If the initial velocity is halved, the new
of 10 N is applied on the surface of water in the maximum height of the projectile is ______ m.
thinner arm. The force required to be applied on Ans. (16)
the surface of water in the thicker arm to maintain u 2 sin 2 
equilibrium of water is _______ N. Sol. H max 
2g
10N
14cm H1max u12

H 2max u 22

1.4cm 64 u2

H 2 max (u / 2) 2
H2max = 16 m
Ans. (1000 N) 59. A wire of resistance 20  is divided into 10 equal
parts. A combination of two parts are connected in
F1 F
Sol.  2 parallel and so on. Now resulting pairs of parallel
A1 A 2
combination are connected in series. The
F1 10 equivalent resistance of final combination is

(7) 2
 (0.7) 2 _______ .
F1 = 1000 N Ans. (5)
57. The electric field at point p due to an electric Sol.
20
dipole is E. The electric field at point R on  10 equal part
E Each part has resistance = 2
equitorial line will be . The value of x :
x 2 parts are connected in parallel so, R = 1
R Now, there will be 5 parts each of resistance 1,
they are connected in series.
Req = 5R, Req = 5
2r Q
60. The current in an inductor is given by I = (3t + 8)
r where t is in second. The magnitude of induced
emf produced in the inductor is 12 mV. The self-
–q O +q p inductance of the inductor _______ mH.
r
Ans. (4)
Ans. (16) Sol. I = 3t + 8
 = 12 mV
2KP
Sol. EP  E dI
r3  L
dt
KP E
ER  3
 12 = L × 3
(2r) 16 L = 4 mH
x = 16
 CHEMISTRY TEST PAPER WITH SOLUTION
SECTION-A Sol. Fe+2 ions undergoes hydrolysis, therefore while
61. Match List - I with List - II. preparing aqueous solution of ferrous sulphate and
List - I List - II ammonium sulphate in water dilute sulphuric acid
(A) ICI (I) T -Shape
is added to prevent hydrolysis of ferrous sulphate.
(B) ICI3 (II) Square pyramidal
(C) CIF5 (III) Pentagonal 63. Identify the major product in the following
bipyramidal reaction.
(D) IF7 (IV) Linear Br
Choose the correct answer from the options given
below: OH
CH3 Major Product
(1) (A)–(I), (B)–(IV), C–(III), D–(II) C2H5OH
(2) (A)–(I), (B)–(III), C–(II), D–(IV)
(3) (A)–(IV), (B)–(I), C–(II), D–(III) CH2
(1)
(4) (A)–(IV), (B)–(III), C–(II), D–(I)
Ans. (3) Br
Sol. A. I – Cl (iv) linear (2)
Cl
CH3
B. I – Cl (I) T-shape (3)
Cl
CH3
F (4)
F F
C. Cl (II) Square pyramidal Ans. (3)
F F
Sol. CH3 CH3
F Br
F F
D. I F (III) Pentagonal bipyramidal H
F F
F
64. The correct nomenclature for the following
62. While preparing crystals of Mohr's salt, dil. H2SO4 compound is:
is added to a mixture of ferrous sulphate and O
ammonium sulphate, before dissolving this mixture
OH
in water, dil. H2SO4 is added here to: OH O H
(1) prevent the hydrolysis of ferrous sulphate
(1) 2–carboxy–4–hydroxyhept–6–enal
(2) prevent the hydrolysis of ammonium sulphate (2) 2–carboxy–4–hydroxyhept–7–enal
(3) make the medium strongly acidic (3) 2–formyl–4–hydroxyhept–6–enoic acid
(4) increase the rate of formation of crystals (4) 2–formyl–4–hydroxyhept–7–enoic acid
Ans. (1) Ans. (3)
 O 66. Given below are two statements:
7 5 3
CH2 Statement I : On passing HCl(g) through a
Sol. 2 1 saturated solution of BaCl2, at room temperature
OH
6 4 white turbidity appears.
OH C Statement II : When HCl gas is passed through a
O H
saturated solution of NaCl, sodium chloride is
precipitated due to common ion effect.
2-formly-4-hydroxyhept-6-enoic acid In the light of the above statements, choose the
65. Given below are two statements : one is labelled as most appropriate answer from the options given
Assertion (A) and the other is labelled as Reason (R). below:
(1) Statement I is correct but Statement II is
Assertion (A) : NH3 and NF3 molecule have incorrect
pyramidal shape with a lone pair of electrons on (2) Both Statement I and Statement II are
nitrogen atom. The resultant dipole moment of incorrect
(3) Statement I is incorrect but Statement II is
NH3 is greater than that of NF3.
correct
Reason (R) : In NH3, the orbital dipole due to lone (4) Both Statement I and Statement II are correct
pair is in the same direction as the resultant dipole Ans. (1)
Sol. BaCl2, NaCl are soluble but on adding HCl(g) to
moment of the N–H bonds. F is the most
BaCl2, NaCl solutions, Sodium or Barium
electronegative element. chlorides may precipitate out, as a consequence of
In the light of the above statements, choose the the law of mass action.
correct answer from the options given below: 67. The metal atom present in the complex MABXL
(where A, B, X and L are unidentate ligands and M
(1) Both (A) and (R) are true and (R) is the correct 3
is metal) involves sp hybridization. The number of
explanation of (A) geometrical isomers exhibited by the complex is:
(2) (A) is false but (R) is true (1) 4 (2) 0
(3) 2 (4) 3
(3) (A) is true but (R) is false Ans. (2)
(4) Both (A) and (R) are true but (R) is NOT the Sol. Tetrahedral complex does not show geometrical
correct explanation of (A) isomerism.
68. Match List - I with List - II.
Ans. (1)
List - I List - II
(Pair of Compounds) (Isomerism)
(A) n-propanol and (I) Metamerism
Sol. N
F Isopropanol
F
F (B) Methoxypropane and (II) Chain Isomerism
ethoxyethane
Resultant dipole moment = 0.80 × 10–30 Cm (C) Propanone and (III) Position
propanal Isomerism
(D) Neopentane and (IV) Functional
N
H Isopentane Isomerism
H
H (1) (A)–(II), (B)–(I), (C)–(IV), (D)–(III)
(2) (A)–(III), (B)–(I), (C)–(II), (D)–(IV)
–30
Resultant dipole moment = 4.90 × 10 cm (3) (A)–(I), (B)–(III), (C)–(IV), (D)–(II)
(4) (A)–(III), (B)–(I), (C)–(IV), (D)–(II)
Ans. (4)
 OH 71. Given below are two statements :
Sol. OH ⇒ Position isomers
& Statement I : The metallic radius of Na is 1.86 A°
and the ionic radius of Na+ is lesser than 1.86 A°.
OCH3
& ⇒ Metamers Statement II : Ions are always smaller in size than
O the corresponding elements.
O In the light of the above statements, choose the
& ⇒ Functional isomers correct answer from the options given below :
C—H
(1) Statement I is correct but Statement II is
O
false
& ⇒ Chain isomers
(2) Both Statement I and Statement II are true
(3) Both Statement I and Statement II are false
neopentane isopentane
(4) Statement I is incorrect but Statement II is
69. The quantity of silver deposited when one coulomb true
charge is passed through AgNO3 solution: Ans. (1)
(1) 0.1 g atom of silver Sol. rNa > rNa+
(2) 1 chemical equivalent of silver So, Statement (I) is correct but size of anions are
(3) 1 g of silver greater than size of neutral atoms.
(4) 1 electrochemical equivalent of silver So statement (II) is incorrect.
Ans. (4) 72. CH3CH2–OH (i) Jone's Reagent
Sol. W = ZIt P
(ii) KMnO4
W = ZQ (iii)NaOH, CaO,∆
W
Q= Consider the above reaction sequence and identify
Z
W = ZQ = (electrochemical equivalent) the major product P.
70. Which one of the following reactions is NOT (1) Methane (2) Methanal
possible? (3) Methoxymethane (4) Methanoic acid
OCH3
Ans. (1)
OH
O
Joner reagent (CrO3 + H⊕)
HBr CH3 — C — OH
(1) Sol. CH3 — CH2 — OH
KMnO4
Soda NaOH
lime CaI
OH Cl process ∆
HCl
(2) CH4 + Na2CO3

73. Consider the given chemical reaction :

Cl OH

NaOH KMnO4–H2SO4
(3) High Temp, H+
Product ''A''
Heat

OCH3 OCH3
Product ''A'' is :
Cl2/AlCl3
(4) (1) picric acid (2) oxalic acid
(3) acetic acid (4) adipic acid
Cl
Ans. (4)
Ans. (2) O
OH Cl
KMnO4, H2SO4 C — OH
Sol. sp2 Sol.
C — OH
Not Possible
O
74. For the electro chemical cell 77. The number of ions from the following that have
M|M2+||X|X2– the ability to liberate hydrogen from a dilute acid is
=
If E 0 2 + = V and E 0 2 −
M /M ( ) 0.46
( X/X) 0.34V. _______. Ti2+, Cr2+ and V2+
(1) 0 (2) 2
Which of the following is correct ?
(3) 3 (4) 1
(1) Ecell = –0.80 V
(2) M + X → M + X is a spontaneous reaction
2 2– Ans. (3)
(3) M + X → M + X is a spontaneous reaction
2+ 2– +2 +2 +2
Sol. The ions Ti , V Cr are strong reducing agents
(4) Ecell = 0.80 V and will liberate hydrogen from a dilute acid, eg.
Ans. (3) +2 + +3
+2 2–
2Cr(aq.) + 2H(aq.) 
→ 2Cr(aq.) + H2 (g)
Sol. M | M || X / X
=
E ocell E oM/M +2 + E oX/X −2 78. Identify A and B in the given chemical reaction

= –0.46 + 0.34 = – 0.12V sequence : -

O
As E ocell is negative so anode becomes cathode and
O
cathode become anode. Spontaneous reaction will be
O Zn–Hg H+
M + X → M + X A B
+2 2–
AlC3 HCl

75. The number of moles of methane required to produce O

11g CO2(g) after complete combustion is:
(Given molar mass of methane in g mol–1 : 16) A- ,B-
(1)
(1) 0.75 (2) 0.25 COOH CH2OH
(3) 0.35 (4) 0.5
Ans. (2) O

3n + 1
Sol. CnH2n+2 + O2 
→ nCO2 + (n + 1)H2O (2) A - ,B-
2 COOH COOH
CH4 + 2O2  → CO2 + 2H2O
O
4gm 11gm
0.25 mole 0.25 mole (3) A - ,B-
0.25 mole CH4 gives 0.25 mole (or 11gm) CO2
76. The number of complexes from the following with O
no electrons in the t2 orbital is _______. O OH
TiCl4, [MnO4]–, [FeO4]2–, [FeCl4]–, [CoCl4]2–
(1) 3 (2) 1 (4) A - ,B-
(3) 4 (4) 2
O OH
Ans. (1)
Sol. TiCl4 ⇒ Ti+4 Ans. (2)
Sol.
⇒ Mn+7 O

⇒ Fe+6 O O
C
O Zn, Hg H⊕

⇒ Fe +2 AlCl3
ESR C
HCl
Clemmension C
ESR
HO Reduction HO O
O O
⇒ Co +2
(A) (B)
79. The correct statements from the following are : SECTION-B
(A) The decreasing order of atomic radii of group 13 81. Combustion of 1 mole of benzene is expressed at
15
elements is Tl > In > Ga > Al > B. C6H6(1) + O2 ( g ) → CO2 ( g ) + 3H 2 O (1) .
2
(B) Down the group 13 electronegativity The standard enthalpy of combustion of 2 mol of
decreases from top to bottom. benzene is – 'x' kJ.
(C) Al dissolves in dil. HCl and liberate H2 but conc. x = ______.
HNO3 renders Al passive by forming a (1) standard Enthalpy of formation of 1 mol of
C6H6(1), for the reaction
protective oxide layer on the surface.
6C(graphite) + 3H2(g) → C6H6(1) is 48.5 kJ mol–1.
(D) All elements of group 13 exhibits highly (2) Standard Enthalpy of formation of 1 mol of
stable +1 oxidation state. CO2(g), for the reaction
(E) Hybridisation of Al in [Al(H2O)6]3+ ion is C(graphite) + O2(g) → CO2(g) is –393.5 kJ mol–1.
3
sp d .
2
(3) Standard and Enthalpy of formation of
1 mol of H2O(1), for the reaction
Choose the correct answer from the options given
1
below : H2(g) + O2 ( g ) → H2O(1) is –286 kJ mol–1.
2
(1) (C) and (E) only Ans. (6535)
(2) (A), (C) and (E) only Sol. 6C(graphite)+3H2(g) → C6H6(); ∆H = 48.5 kJ/mol
(3) (A), (B), (C) and (E) only C(graphite)+O2(g)→ CO2(g); ∆H = –393.5 kJ/mol
(4) (A) and (C) only
H(2 ) + ( g ) → H2O() ; ∆H = – 286 kJ/mol
g 1
Ans. (1) 2
Sol. A. size order T > In > Al > Ga > B equation –(1) × 1 + (2) × 6 + (3) × 3
– 48.5 –6 × 393.5 – 3 × 286
B. Electronegativity order B > Al < Ga < In < T = – 3267.5 kJ for 1 mol
= – 6535 kJ for 2 mol
D. B, Al are more stable in +3 oxidation state Ans. 6535 kJ
So, only C, E statements are correct. 82. The fusion of chromite ore with sodium carbonate
80. Coagulation of egg, on heating is because of : in the presence of air leads to the formation of
products A and B along with the evolution of CO2.
(1) Denaturation of protein occurs
The sum of spin-only magnetic moment values of
(2) The secondary structure of protein remains
A and B is ___ B.M. (Nearest integer)
unchanged (Given atomic number : C : 6, Na : 11, O : 8,
(3) Breaking of the peptide linkage in the primary Fe : 26, Cr : 24]
structure of protein occurs Ans. (6)
(4) Biological property of protein remains Sol. 4FeCr2O4 + 8Na2CO3 + 7O2 →
8Na2CrO4 + 2Fe2O3 + 8CO2
unchanged
A B
Ans. (1) Spin only magnetic moment
Sol. Coagulation of egg give primary structure of For Na2CrO4 µB = 0
protein, which is known as denaturation of protein For Fe2O3 µB = 5.9
sum = 5.9
83. X of enthanamine was subjected to reaction with 86. In the Claisen-Schmidt reaction to prepare 351 g of
NaNO2/HCl followed by hydrolysis to liberate N2 dibenzalacetone using 87 g of acetone, the amount
and HCl. The HCl generated was completely
neutralised by 0.2 moles of NaOH. X is ____ g. of benzaldehyde required is _________g. (Nearest
Ans. (9) integer)
⊕ Θ
Sol. CH3—CH2—NH2 NaNO2 + HCl CH3—CH2—N2Cl Ans. (318)
0.2 mole HOH
MW of ethanamine = 45 Sol. Claisen Schmidt reaction
45 × 0.2 = 9 gm CH3—CH2—OH + N2 + HCl O H
(g) C O
O
0.2 mole ⊕Θ
+ CH3 NaOH
CH3 — CH = CH — C — CH = CH —
84. In an atom, total number of electrons having 2 mole 1 mole
Dibanzal acetone
1 mole
1 3 mole 1.5 mole 351 gm = 1.5 mole
quantum numbers n = 4, |ml| = 1 and ms = – is
2
mw of benzaldehyde = 106
Ans. (6)
Sol. n = 4 106 × 3 = 318 gm. Benzaldehyde is required to
 m give 1.5 mole (or 351 gm) product
0 0 87. Consider the following single step reaction in gas
1 –1, 0, +1 phase at constant temperature.
2 –2, –1, 0, +1, +2, +3
So number of orbital associated with 2A(g) + B(g) → C(g)

n = 4, |m| = 1 are 6 The initial rate of the reaction is recorded as r1

– 1 when the reaction starts with 1.5 atm pressure of A

Now each orbital contain one e with ms = –
2 and 0.7 atm pressure of B. After some time, the
85. Using the given figure, the ratio of Rf values of
rate r2 is recorded when the pressure of C becomes
sample A and sample C is x × 10–2. Value of x is
–1
__________. 0.5 atm. The ratio r1 : r2 is ________ × 10 .

12.5 cm Solvent front (Nearest integer)

10.0 cm Sample C Ans. (315)

6.5 cm Sample B Sol. 2A(g) + B(g) → C(g)

Sample A
5.0 cm r1 1.5 atm 0.7 atm
0.0 cm Base line
r2 0.5 atm 0.2 atm 0.5 atm

Samples (A,B,C)  r = K [PA]2[PB]

Fig : Paper chromatography of Samples
r1 = K [1.5]2[0.7]
Ans. (50)
r2 = K [0.5]2[0.2]
5 10
Sol. Rf of A = Rf of C =
12.5 12.5 r1 7
=9 × =31.5 =315 × 10 –1
r2 2
R f (A) 1
Ratio = = = 0.5 or 50 × 10–2
R f (C) 2 Ans. 315
88. The product © in the following sequence of Sol. Mass of CH3COOH = V × d
reactions has _________ π bonds. = 5 ml × 1.2 g/ml
= 6 gm
KMnO4–KOH H3O+ Br2
A B C
∆ FeBr3 6
=
n CH3COOH = 0.1mol
60
Ans. (4)
0.1
O m CH3COOH ≈ M CH3COOH = =
0.1M
1
Θ ⊕
C—OK CH3COOH CH3COO– + H+
Sol. A =
C
C – Cα Cα Cα
O
Cα 2
C — OH Ka =
1− α
B=
1 – α ≈ 1 ⇒ Ka = Cα2

O Ka 6.25 × 10 –5
=α = = 25 × 10–3
C — OH C 0.1
C= V.f. (i) = 1 + α(n – 1) = 1 + α(2 – 1) = 1 + α
= 1 + 25 × 10–3 = 1.025
Br ∆Tf = iKfm
π bonds = 4 = (1.025)(1.86)(0.1)
89. Considering acetic acid dissociates in water, its = 0.19
–5
dissociation constant is 6.25 × 10 . If 5 mL of = 19 × 10–2
acetic acid is dissolved in 1 litre water, the solution 90. Number of compounds from the following with
–2
will freeze at –x × 10 °C, provided pure water zero dipole moment is ___________.
freezes at 0 °C. HF, H2, H2S, CO2, NH3, BF3, CH4, CHCl3, SiF4,
x = _________. (Nearest integer) H2O, BeF2
–1
Given : (Kf)water = 1.86 K kg mol . Ans. (6)
–1
density of acetic acid is 1.2 g mol Sol. H2, CO2, BF3, CH4, SiF4 , BeF2
–1
molar mass of water = 18 g mol . are symm. molecule so dipole moment is zero
–1
molar mass of acetic acid = 60 g mol .
density of water = 1 g cm–3
Acetic acid dissociates as
CH3COOH  CH 3COO Θ + H ⊕
Ans. (19)