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FIITJEE
ALL INDIA TEST SERIES

JEE (Advanced)-2022
FULL TEST – I
PAPER –1
TEST DATE: 23-12-2021
Time Allotted: 3 Hours Maximum Marks: 180
General Instructions:
 The test consists of total 57 questions.
 Each subject (PCM) has 19 questions.
 This question paper contains Three Parts.
 Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
 Each Part is further divided into Three Sections: Section-A, Section-B & Section-C.
Section – A (01 – 04, 20 – 23, 39 – 42): This section contains TWELVE (12) questions. Each question has
FOUR options. ONLY ONE of these four options is the correct answer.
Section – A (05 –10, 24 – 29, 43 – 48): This section contains EIGHTEEN (18) questions. Each question has
FOUR options. ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
Section – B (11 – 13, 30 – 32, 49 – 51): This section contains NINE (09) questions. The answer to each
question is a NON-NEGATIVE INTEGER.
Section – C (14 – 19, 33 – 38, 52 – 57): This section contains NINE (09) question stems. There are TWO
(02) questions corresponding to each question stem. The answer to each question is a NUMERICAL
VALUE. If the numerical value has more than two decimal places, truncate/round-off the value to TWO
decimal places.
MARKING SCHEME
Section – A (Single Correct): Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –1 In all other cases.
Section – A (One or More than One Correct): Answer to each question will be evaluated according to the following
marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial marks : +2 if three or more options are correct but ONLY two options are chosen and both
of which are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a
correct option;
Section – B: Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If ONLY the correct integer is entered;
Zero Marks : 0 In all other cases.
Section – C: Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +2 If ONLY the correct numerical value is entered at the designated place;
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AITS-FT-I (Paper-1)-PCM-JEE(Advanced)/22 2
Physics PART – I
Section – A (Maximum Marks: 12)

This section contains FOUR (04) questions. Each question has FOUR options. ONLY ONE of these four
options is the correct answer.
1. In an X-ray set up accelerating potential difference is set at V volt and first a target metal having
atomic no. Z1 is used then target metal having Z2 is used (  1 is wavelength of K  X–ray from
Z 1 target and   2 is wavelength of K  , x-ray with Z2 target)
(A) If Z 1  Z 2 then   1   min     2   min 
(B) If Z 1  Z 2 then   1   min     2   min 
(C)   
The difference  1   min and  12   min  will be same for both the target metals.
(D) If Z 1  Z 2 then  1   min     2   min 
Ans. B
1 2 1 1
Sol.  RZ  b   2  2 
  n1 n 2 
1 2 1
For K transition  RZ  1 1  
  4
1
    min depends on
3R(Z  1) 2
2. In a YDSE experiment, the two slits are covered with a Screen

transparent membrane of negligible thickness which allows water
light to pass through it but does not allow water. A glass slab w = 4/3 S1
of thickness t = 0.41 mm and refractive index g = 1.5 is d t =30°
placed in front of one of the slits as shown in the figure. The
separation between the slits is d = 0.30 mm. The entire g
s
space to the left of the slits is filled with water of refractive S2
D
index w = 4/3.
A coherent light of intensity I and absolute wavelength  = 5000A° is being incident on the slits
making an angle 30° with horizontal. If screen is placed at a distance D = 1m from the slits, then
the position of central maxima will be
(A) 0.58 cm above the central line of slits
(B) 0.58 cm below the central line of slits
(C) 1.66 cm above the central line of slits
(D) 1.66 cm below the central line of slits
3 AITS-FT-I (Paper-1)-PCM-JEE(Advanced)/22
Ans. D
Sol. If central maxima is formed at point P on the screen, then P Screen

Path difference = S2P + (g–1)t – S1P – wd sin 30° = 0 water x
w = 4/3 S1
xd
 S2P  S1P    w d sin 30  ( g  1)  t d t =30°
D
x  1.66 cm g
s
 S2
D
3. A cylinder is filled with a liquid of refractive index . The radius of the cylinder observer
is decreasing at a constant rate K. The volume of the liquid inside the
container remains constant at V. The observer and the object O are in a state
of rest and at a distance L from each other. The apparent velocity of the
object as seen by the observer, (when radius of cylinder is r) L
object
(1  ) 2 KV
(A)
( r 3 )
(1  ) 2 KV
(B)
( Lr 2 )
(1  )2 K
(C)

(1  ) K
(D)
2
Ans. A
H observer
Sol. X app  L  H 

dX app dH  1    (L–H)
  
dt dt   
r 2 H  V H
dH 2 H dr 2 KH
  
dt r dt r object
dX app 2 KV  1    
   
dt r 3   
4. A car starts from rest from origin an straight line with an acceleration (a) given by the relation
25
a , where a is in m/s2 and x is in metre. The maximum velocity of the car will be (x is
( x  2) 3
the position of the car)
(A) 2.5 m/s
(B) 5 m/s
(C) 10 m/s
(D) Infinite
Ans. A
x
dv 25 v2  1  2 1 1 
Sol. a= v  ,  25    2
, v  25   2
dx ( x  2) 3 2  2( x  2)  o  4 ( x  2) 
1 1  5
v  25   2
, v max   2.5 m/s (at x = )
 4 ( x  2)  2

This section contains SIX (06) question. Each question has FOUR options (A), (B), (C) and (D). ONE OR
MOER THAN ONE of these four option(s) is (are) correct answer(s).
5. An electron in H-atom jumps from second excited state to first excited state and then from first
excited to ground state. Let the ratio of wavelength, momentum and energy of photons emitted in
these two cases be a, b and c respectively. Then
1
(A) c
a
9
(B) a
4
5
(C) b
27
5
(D) c
27
Ans. A, C, D
1  1 1  h
Sol. As  R 2  2  and P 
  n1 n 2  
hc
Also, E

6. In a cylindrical region of radius R, there exists a time varying magnetic field B such that
dB
 k (  0) . A charged particle having charge q is placed at the point P at a distance d (> R)
dt
from its centre O. Now, the particle is moved in the direction perpendicular to OP (see figure) by
an external agent upto infinity so that there is no gain in kinetic energy of the charged particle.
Choose the correct statement/s.
×
× R ×
× × ×
O ×
× × ×
d
qR 2
(A) Work done by external agent is k if d = 2R
4
qR 2
(B) Work done by external agent is k if d = 4R
8
qR 2
(C) Work done by external agent is k if d = 4R
4
qR 2
(D) Work done by external agent is k if d = 6R
4
Ans. A, C, D
  dB ×
Sol.:   dl  A dt
E × R ×
× × ×
O
E 2 x 2  d 2  R 2 k × × ×
×
R 2 k d
E
2 x2  d 2 
  P
qR 2 E
Wext   qE  dx  k
0 4
7. In the given figure a block A rests on a smooth triangular

block B and the block B is given an acceleration of a = 2 A
m/s2 along the plane SB
a

(A) normal force on block A due to block B is m g  a 
(B) acceleration of block A relative to block B is a cos .
(C) If friction is present between block and A and B, the coefficient of friction should be
a
greater than cos  , for no relative motion between A and B
g
(D) If friction is present between block and A and B, the coefficient of friction should be
a cos 
greater than , for no relative motion between A and B.
g  a sin 
Ans. B, D
Sol. From FBD of A with respect to B N

av = 0 ma
mg  N  ma sin 
A
 N  mg  ma sin 
ma cos   ma H  a H  a cos  mg
aH
If block B is having friction then, for aH = 0
ma cos   N  mg  ma sin 
a cos 

g  a sin 
8. Three particles each of mass m, can slide on fixed frictionless circular A v0

tracks in the same horizontal plane as shown. Particle A moves with B
velocity v0 and hits particle B elastically. Assuming that B and C are
initially at rest and lie along a radial line and the spring is initially relaxed k
before impact, then 2R C
R
(A) the velocity of B immediately after impact is v0
2v 0
(B) the velocity of C when the stretch in the spring is maximum is
5
4v 0
(C) the velocity of B when the stretch in the spring is maximum is
5
m
(D) the maximum stretch in the spring in the spring is v0
5k
Ans.
Sol. At the time of maximum elongation angular speed of B and C are equal, let speed of B is 2v and
C is v, By conserving angular momentum of the system about the centre
mv0 2 R  m2v (2 R )  mv ( R )
2v 0 4 v0 2v0
v , vB  , vC 
5 5 5
2 2
1 2 1 2 1  4v  1  2v 
Conserving energy of the system mv0  kx max  m 0   m 0 
2 2 2  5  2  5 
m
 xmax  v0
5k
 (a), (b), (c) and (d)
9. Two concentric spherical shells masses m1 and m2 and radii r1 and

m2 m1
r2 . Then m3
P
r
r1 O
r2
(A) outer shell will have no contribution in gravitational field at point P
(B) force on P is directed towards O
Gm1m2
(C) force on P is
r2
Gm1m3
(D) force on P is
r2
Ans. A, B, D
Sol. Gravitational field intensity inside the spherical shell is zero.

Gravitational force is always directed towards the source mass.
Force on P act only due to m1 because point P is outside the spherical shell of mass m1.
So choice (a), (b) and (d) are correct.
10. A small solid ball of density  is held inside at point A a cubical P Q

container of side L, filled with an ideal liquid of density 4 as shown
in the figure. Now, if the container starts moving with constant
L/2
acceleration a horizontally and the ball is released from point A A a
simultaneously, then L/2
R L S
(A) For ball to hit the top of container at end Q, a = 3g

(B) For ball to hit the top of container at end Q, a = 2g
L
(C) Ball hits the top of container at end Q after a time t =
3g
2L
(D) Ball hits the top of container at end Q after a time t =
3g
Ans. B, C
Sol. F.B.D. of ball in frame of container 4Vg

4Vg  Vg Y
ay   3g
V Va 4Va
L 1 L X
 3 gt 2  t
2 2 3g Vg
4Va  Va
ax =  3a
V
1 2L
L  3at 2  t
2 3a
2L L
Ball to collide at point Q, t    a = 2g
3a 3g
Section – B (Maximum Marks: 12)

This section contains THREE (03) questions. The answer to each question is a NON-NEGATIVE
INTEGER.
11. Inner surface of a cylindrical shell of length l and of material of thermal T1 T2

conductivity k is kept at constant temperature T1 and outer surface of
the cylinder is kept at constant temperature T2 such that T1  T2  as
shown in figure. Heat flows from inner surface to outer surface radially
outward. Inner and outer radii of the shell are R and 2R respectively.
Due to lack of space this cylinder has to be replaced by a smaller
R l
l R 2R
cylinder of length , inner and outer radii and R respectively and
2 4
thermal conductivity of material nk. If rate of radial outward heat flow
remains same for same temperatures of inner and outer surface i.e. T1
and T2, then find the value of n.
Ans. 4
Sol. Since rate of heat flow remains same in both the cases, so
2R R
dx dx
R k 2 x l  R l
 nk  4k  n = 4
nk 2 x 
4 2
12. A block is attached to the ceiling by a spring that has a force constant k = 200
N/m. A conducting rod is rigidly attached to the block. The combined mass of k
the block and the rod is m = 0.3 kg. The rod can slide without friction along two
vertical parallel rails, which are a distance l = 1 m apart. A capacitor of known m
capacitance C = 500 F is attached to the rails by the wires. The entire system B
is placed in a uniform magnetic field B = 20 T directed as shown. Find the 
angular frequency (in rad/sec) of the vertical oscillations of the block. Neglect
the self-inductance and electrical resistance of the rod and all wires.
C
l
Ans. 20
1 2 1 2 1 q2 q
Sol. Total energy E = mv  kx  , e  Bvl 
2 2 2 C C
1 2 2 2 1 2 dE dv  k 
E = ( m  B l C )v  kx as E = constant 0,   2 2
x ,
2 2 dt dt mB l C
k
= = 20 rad/sec.
m  B 2l 2C
13. Find the effective value or rms value of an alternating current that changes according to the law
(All quantities are in S.I. unit and symbols have their usual meaning)
T T
I  10 , when 0  t  T / 8 ; I  0 , when t
8 2
T 5 5 9
I  10 , when t T ; I  0 , when T  t  T ; I  10 , when T  t  T
2 8 8 8
Ans. 5
Sol. We solve this problem using the fact that the effective value of as alternating current is the value
of a direct current that produces the same quantity of heat in a conductor the alternating current
during the same time
The heat produced by the AC current during on time period from 0 to T is
T T
H  10 2 R  0  10 2 R  0
8 8
T
H  10 2 R …(1)
4
In the same time interval 0 to T heat produced by constant direct current I, would have been
H ' I 2 RT …(2)
T
H  H '  I 2 RT  10 2 R
4
10
 I
2
effective value or rms value of required current is 5
Section – C (Maximum Marks: 12)

This section contains THREE (03) question stems. There are TWO (02) questions corresponding to each
question stem. The answer to each question is a NUMERICAL VALUE. If the numerical value has more
than two decimal places, truncate/round-off the value to TWO decimal places.
Question Stem for Question Nos. 14 and 15
Question Stem
A U-shape wire is formed by connecting a resistance R with two parallel B

conducting rod at its both ends and kept on a horizontal table. A sliding P
wire PQ of length l and mass m can slide over the U-Shape wire without R
friction. This rod PQ is connected to a block of mass m through an
insulating string going over a smooth pulley as shown. A vertical
magnetic field B is switched on and rod PQ is allowed to move from rest. Q
After some time it attains a constant velocity v0 (also called terminal m
velocity). Now mass of the block is tripled, it attain another terminal
velocity vT.
(Given B  10T , l = 1 m, v0 = 10 m/s, R = 10, g = 10 m/s2)
14. The value of mass m is
Ans. 1.00
15. The value of terminal velocity vT is
Ans. 30.00
Sol. (Q.14 & 15)

B 2 l 2 v0   Blv0 
Since velocity is constant, Fnet = 0  mg  ilB   i  
R  R R 
On solving we get, m = 1 kg
B 2l 2 v
Now, when mass is tripled 3mg  T  3ma and T   ma
R
B 2l 2v
On solving, 3mg   4ma … (i)
R
3mgR
Now, v  vT when a = 0  vT   30 m/s
B 2l 2
Question Stem
A solid cylinder of mass m and radius R is kept at rest on a plank of m

A R
mass 2m lying on a smooth horizontal surface. Massless and
inextensible string connecting cylinder to the plank is passing over a F
massless pulley. The friction between the cylinder and the plank is 2m
sufficient to prevent slipping. Pulley A is pulled with a constant
horizontal force F.[F =100N, m = 1kg]
16. Acceleration of cylinder with respect to earth is
Ans. 42.86
17. Acceleration of plank with respect to earth is
Ans. 28.57
Question Stem
A light of wavelength  is incident on a metal sheet of work function  = 2eV. The wavelength  varies
with time as  = 3000 + 40t, where  is in Å and t is in second. The power incident on metal sheet is
constant at 100 W. This signal is switched on and off for time intervals of 2 minutes and 1 minute
respectively. Each time the signal is switched on, the  start from initial value of 3000Å. The metal plate is
grounded and electron clouding is negligible. The efficiency of photoemission is 1% (hc = 12400 eVÅ).
18. The time after which photomission will stop is
Ans. 80.00
hc
Sol. Photo emission will stop if    0 

12400
3000  40t 0  , t 0  80 s
2
19. If the total number of photoelectrons ejected in one hour is N x 1020, value of ‘N’ is
Ans. 37.10
Sol. Rate of photo emission at time t

dN 1 100
  [3000  40t ]
dt 100 19840  10 19
1
N 19
[3000t  20t 2 ]80
0
19840  10
N  18.55  1019  1.855  10 20
This is the number of photoelectron ejected in 1 blinking.
In 1 hr, total number of photoelectron ejected is
= 1.855 × 1020 × 20 = 3.71 × 1021
Chemistry PART – II

20. Which of the following is NOT correct about hydrides ?

I. Saline hydrides are stoichiometric and metallic hydrides are non-stoichiometric.
II. BeH2 is monomeric whereas MgH2 is polymeric.
III. Hydrides of the elements of Group 13 are electron deficient.
IV. NaH reacts with water and liberates H2 whereas B2H6 does not react with water.
(A) IV only
(B) I and III
(C) III only
(D) II and IV
Ans. D
Sol. BeH2 is polymetric while MgH2 is monomeric

2NaH  H2O  2NaOH  H2
B2H6  H2O  B(OH)3  H2
21. What is the major organic product of the following reaction?

O OH
CrO /H SO /H O

3 2 4
Acetone
2

(A) O (B) O
CHO COOH
O O
(C) (D)
O CHO O COOH
Ans. D
Sol. OH
O
3CrO /H SO /H O
2 4 2

Acetone
 O COOH
O
22. The solubility product of salt AB  M.W  100  is 4  10 10 M2 at 25ºC. Loss in weight of precipitate
of AB by washing it with 5 litre of water is
(A) 0.1 g
(B) 1g
(C) 104 g
(D) 0.01 g
Ans. D
Sol. 

AB  
A B

s  K sp  2  10 5 moles lit
 in 5 litres of water 5   2  10 5  moles of AB will dissolve.
 104 moles
 10 4  100 g
 0.01g
23. pH of mixture having 0.1 M NH4OH and 0.1 NH4Cl is equal to pK w  pK b . If 0.1 M NH4 OH and
0.1 M  NH4 2 SO 4 are taken, the pH will be
(A) pK w  pK b
(B) pK w  pK b
(C) pK w  pK b  log2
(D) pK w  pK b  log2
Ans. D
NH4 
Sol. Case-I: pOH  pK b  log   pK b NH4   NH4 OH  0.1
 4 
NH OH
pH  pK w  pK b
NH4 
Case-II pOH  PK b  log   NH   0.1 2

4
NH4 OH
pOH  pK b  log2
pH  pK w  log2

24. Which of the following statements is/are not correct for following compounds
(I) SCl2  OCH3 2 and (II) SF2  OCH3 2
(A) OCH3 groups in both cases occupy the same position
(B) Cl-atoms occupy equatorial position in case of (I) and F-atoms occupy equatorial position
in case of (II)
(C) Cl-atoms occupy axial position in case of (I) and F-atoms occupy equatorial position in
case of (II)
(D) Cl and F atoms all occupy axial position in case of both (I) and (II).
Ans. A, B, C, D
Sol. OCH3 F
Cl OCH3
Cl OCH3
OCH3 F
25. Identify the incorrect statement/s
(A) Combustion of methane in an adiabatic rigid container will cause no change in

temperature of the system.
(B) Dimerization of acetic acid causes an increase in entropy of the system
(C) It is possible to have both adiabatic reversible and adiabatic irreversible processes
between two states.
(D) P – V work is always non-zero when there is a change in volume.
Ans. A, B, C, D
Sol. (A) Combustion of CH4 is exothermic so temperature will increase

(B) Entropy decreases during dimerization.
26. According to kinetic theory of gases (more than one correct answers):
(A) Collisions are always elastic
(B) heavier molecules transfer more momentum to the wall of container
(C) Only a small number of molecules have high velocity
(D) Between collision, the molecule move in straight line with constant (average) velocities
Ans. A, B, C, D
Sol. Factual
27. Ethyl acetoacetate gives the test of:
(A) O
C O and C OC2H5 groups
(B) CH  CH and OH groups

(C) O
C O C2 H5 and OH group
(D) –CHO group
Ans. A, B, C
Sol. H
O O
O O
Tautomerism
H3C C CH2 C 
OC2H5  
 H C C C O C2H5
3
CH
28. Which of the following statement(s) is/are correct?
(A) Pot. Tetracyanocuperate (I) tetrahedral complex

(B) Sod. Tetracyanonickelate (II) is a square planar complex
(C) Pot. Tetrachloridopatinate (II) is a tetrahedral complex
(D) Tetraamminecopper (II) sulphate is a square planar complex
Ans. A, B, D
3
Sol. Cu  CN4   tetrahedral sp3  
2
NI  CN 4   squareplanar dsp2  
2
PtCl4   square planar dsp   2
2
Cu NH3  4   square planar  dsp 
2
Hence, (A), (B) and (D) are the correct answer.
29. Select CORRECT order of bond energy.
(A) F2  Cl2  Br2  I2 (halogen-halogen)
(B) N2  N2H2  N2H4 (N  N)
(C) O2  O3  H2 O2 (O  O)
(D) C2H2  C2H4  C2H6 (C  C)
Ans. B, C, D
Sol. N N N N H N N H
H H H H
+ H
O O O
O O O
O
H

INTEGER.
30. What is the number of hyperconjugative structures of the given carbocation
Ans. 7
Sol. Number of hyperconjugative structure = number of alpha Hydrogen.
31. The van der Wal’s constant ‘b’ of a gas is 3.42  10–2 L mol–1. How near can be centres of the two
molecules approach each other with respect to their nuclei (in A)?
Ans. 3
Sol. b  3.42  105 m3mol1

4
b  4  r 3  NA  3.42  10 5
3
 r  3.38  1010 m  1.5A
3
 2r  3A
32. In a first order reaction, the conc. of reactant decreases from 0.8 M to 0.4 M in 15 minutes. The
time take for the conc. to change from 0.1M to 0.025M is:
Ans. 30
Sol. Change of conc. from 0.8M to 0.4M revels t1/2 to be 15 min.

Change from 0.1M to 0.025M requires two half lives. So, the time required
 2  15  30 min.

Question Stem
1
An enclosed glass bulb of volume V contains a pinch of solid NH4 Cl and moles of Ne gas. At 300 K,
100
the internal pressure inside the glass bulb is 114 mm Hg which increases to 908 mm Hg when the bulb is
heated to 600 K. Assume ideal gas behaviour.
33. What will be the partial pressure of NH3  g  (in mm of Hg) in the bulb at 600K
Ans. 340.00
34. What mass of NH4 Cl (in grams) is approximately present in ‘Pinch’
Ans. 0.80
Sol. (Q.33-34)
Volume of bulb (V) can be calculated as per data given at 300 K
PV = nRT
114 1
V   0.0821 300
760 100
V = 1.642 lit,.
Now at 600 K when NH4 Cl would have decomposed
PV = nRT
908
 1.64 = n  0.082  600
760
n= 0.039 moles
NH3  HCl  0.039  0.01  0.029 moles
0.029
NH3   0.0145moles
2
0.029
HCl   0.0145moles
2
0.0145
PNH2   908  340mm
0.039
Question Stem
3.6 gm of Mg is burnt in limited supply of oxygen. The residue was treated with 100 ml of H2 SO4 (35% by
mass, 1.26 g/ml density), 2.463 litre of H2 at 760 mm at 27ºC was evolved. Assume MgSO4 is completely
soluble.
35. Find the % of mass of final H2 SO4
Ans. 22.58
1
Sol. Mg  0.15 moles  
O2  MgO
2
 mgSO 4  H2   0.1 moles 
Mg  H2 SO 4 
MgO  H2 SO4  MgSO4  H2O
Moles of Mg left in first reaction = 0.1 moles
Moles of MgO formed in first reaction = 0.05 moles
Moles of H2 SO4 initially taken = 0.45
Moles of H2 SO4 net consumed = 0.15
H2 SO4 left = 0.30 moles
Water left = water present initially + formed = 81.9 + 0.9 = 82.8g
MgSO4 formed = 18g
Total mass of final solution = 0.3(98) + 82.8 + 18 = 130.2
0.3  98
% by mass of final H2 SO 4   100 = 22.58 %
105
36. Volume of O 2 (in litre) taken initially at STP will be:
Ans. 0.56
Sol. For volume of O 2 consumed at STP

1
Moles taken = (moles of MgO formed) 
2
1
 0.05 moles   0.025
2
Volume of O 2  22.4  0.025  0.56 litre
Question Stem
Three bulbs (I), (II), and (III) of volume V litres, 2V litres and 3V litres are connected by tubes of negligible
volume fitted by stopping valve (as shown in fig). The bulb I is at 1 atm containing 0.3 moles of H2 gas at
temp 127ºC. Bulb (III) contains O2 gas at 77ºC and pressure of 2 atm. Bulb (II) is vacuum and maintained
at temp. 27ºC.
VL 2VL 3VL
1 atm 2 atm
0.3 moles
O2 gas
of H2 valve(a) valve(b)
o o
127o C (i) (ii)
27 C 77 C
(iii)
The valve (b) is opened first and then closed after some time. Then the valve (a) is opened and closed
after same time as for valve (b). The number of moles of O2 diffused into bulb (II) is 0.1 mole
37. The partial pressure (in atm) of H2 observed in bulb (I) after diffusion is
Ans. 0.38
Sol. Number of moles of H2  g  remaining in bulb (I) = 0.3 – 0.185 = 0.115

 P  n (at constant T & V)
Pafter diffusion no. of moles of H2 after diffusion

 
Pinitial no.of moles initially present
0.115 0.115
 Pressure in bulb (I) after diffusion = Piniital   1  0.38atm
0.3 0.3
38. The pressure (in atm) observed in bulb (III) after diffusion is
Ans. 1.90
Sol. 37 - 38.
From bulb (I)
PV  nRT
nRT 0.3  0.082  400
V 
P 1
V  0.3  0.082  400L
Calculation of number of moles of H2 diffused in bulb (II)
rH2 nH2 diffused PH2 MO2 .TO2  PA 
   r 
rO2 nO2 diffused MH2 .TH2 PO2  2MRT 
nH2 diffused nH2 1 32  350 14 3.7
      1.85
nO2 diffused 0.1 2  100 2 2 2
 number of moles of H2 diffused in bulb (II) = 0.185
For bulb (III)
Volume = 3V = 3  0.3  0.082  400 L
PV 2  3  0.3  0.082  400
Number of moles of O2 initially in bulb (III) =   2.05
RT 0.082  350
Number of moles of O2 remaining after diffusion = 2.05 – 0.1 = 1.95
 P  n (at const. T & V)
Pinitial 2.05
 
Pafter diffusion 1.95
1.95 1.95
Pafter diffusion  Pinitial   2  1.9 atm
2.05 2.05
Mathematics PART – III

39. y

(esin x  1)4  (cos x  1)3 esinx  ex  e x   x3  2x2  4
ex
Then the value of y "(0) is
(A) -4
(B) 4
(C) -8
(D) 8
Ans. D
Sol. At x  0,y  4
ex y  x 3  2x 2  4
 y "(0)  8
y "(0)
4 3 3
 
Because y "(0) , esin x  1   cos x  1 e sin x  e x  e x   is always gives zero at x = 0
40. If p, q, r are prime numbers and , ,  are positive integers such that L.C.M. of , ,  is p3q2r
and greatest common divisor of , ,  is pqr then the number of possible triplets (, , ) will be
(A) 6
(B) 12
(C) 72
(D) 96
Ans. C
Sol. LCM of , ,   p3 q2r and H.C.F. = qpr

Let   p m1 qn1 r,   pm2 qn2 r and r  p m3 qn3 r.
Minimum of (m1,m2 ,m3 ) = 1 and maximum of (m1,m2 ,m3 )  3.
 Number of possibilities for m1,m2 ,m3  3  6  3  12
Similarly, number of possibilities for n1,n2 ,n3  3  3  6
And number of possibilities for r1,r2 ,r3  1
Total triplets 12  6  1  72
41. Each of the nine balls can be placed with equal probability in any of the three initially empty
boxes. Let P1 be the probability that there will be four balls in the first box, three in the second box
and two in the third box, and P2 be the probability that three will be in each box then the ratio
(P2 / P1 ) equal to.
4
(A)
3
2
(B)
9
(C) 8
(D) 2
Ans. A
9! 1
Sol. P1  . (4 must go in B1, 3 in B2 and 2 in B3)
4!3!2! 39
9! 3! 1
And P2  . all boxes are different
(3!)3 3! 39
P2 4
 
P1 3
42. If a, b, c are distinct positive real number such that b(a + c) = 2ac, then the roots of ax 2+2bx+c=0
are
(A) real and equal
(B) real and distinct
(C) imaginary
(D) none of these
Ans. C
2ac
Sol. b that means b is the H.M. of a and c.
ac
 ax2+2bx+c=0
 D = 4(b2ac)
Since G.M. of a and c is ac
 ac > b2
 D < 0.

43. If a set ‘A’ is {1, 0, -1, 2} then which of the following is(are) correct?
(A) A square matrix of order 3 is constructed whose elements are from set ‘A’ then the
27
probability that matrix is skew matrix is 9 .
4
(B) A square matrix of order 3 is constructed whose elements are from set ‘A’ then probability
1
that matrix is symmetric is .
64
3
(C) A function f : A A is defined then probability that function is onto is .
32
3
(D) A function f : A A is defined and f is onto then the probability that f(i)  i  i A is .
8
Ans. A, B, C, D
Sol. (A) In skew symmetric matrix aij  a ji and all element of diagonal are zero
3  3  3 27
So required probability   9
49 4
(B) For symmetric matrix aij  a ji
(4)(4)(4)(4)(4)(4)(1.1.1) 1
So, required probability  9

4 64
4! 3
(C) Probability 4

4 32
1 1 1
4!    
2! 3! 4!  9 3
(D) Probability =    .
4! 24 8
44. Three circles C1, C2, C3 with radii r1,r2 ,r3 (r1  r2  r3 ) touches each other externally as shown and
L1,L 2 are two common tangents to these circles from P.
Which of the following is(are) correct?
L1
C3
C2
C1
P D E F L2
r12  r32
(A) r2 
r1  r3
(B) r22  r1 r3
(C) DE  2 r1 r2
(D) DE  r22  r12
Ans. B, C
Sol. DE  AK  (r1  r2 )2  (r2  r1 )2  2 r1r2

L1
C3
C2 C
C1 B
A
K

P D E F L2
Let PD  x and APD  
AD BE CF
 tan    
x x  DE x  DE  EF
r1 r2 r3
 
x x  2 r1r2 x  2 r1 r2  2 r2 r3
r2  r1 r3  r2
   r22  r1r3
2 r1r2 2 r2r3
1 11
45. Let g(x)  ax 2  bx  c, a, b, c  N and  g(x)dx  . Let f(x) be a continuous and derivable
0 6
1
function in (x1, x 2 ). If f(x).f '(x)  x 1  (f(x))4 and lim (f(x))2  1 and lim (f(x))2  , then
x  x1 x  x2 2
minimum value of [x12  x 22 ] is equal to,
Where [.] denotes greatest integer function.
(A) 2  abc
(B) abc
(C) bc
(D) ab
Ans. A, B
1 11 a b 11
Sol.  g(x) dx 
  c   2a  3b  6c  11
0 6 3 2 6
 a  b  c  1 a,b,c  N
f(x) f '(x)
  x  0  h(x)  sin 1(f(x)2  x 2 is non-decreasing function
4
1  f(x))
  
 lim h(x)  lim   x12   x 22  x12  x 22    x12  x 22   1
x  x1 x  x 2 2 6 3
i.e.,  x12  x 22   1.
     1 
46. Given that a and b are two unit vectors such that angle between a and b, is cos1   . If c be a
4
 
         
vector in the plane of a and b , such that c  4, c  b  2a  b and c  a  b then,
(A) 2
(B) sum of values of  = -1
(C) product of all possible values of  = -12
(D) number of distinct values of  is three.
Ans. A, B, C
         
Sol. Given c  b  2a  b  (c  2a) ||b  c  2a  b ..(1)
 = 2
   1
Also (1)  a.c  2   a.b  2   ...(2)
4
  1
Again, (1)  b.c  2a.b      
2
    1 
Again, (1)  c.c  2(a.c)   b.c) 16  2.(2  )      
4 2 
 
 12    2 2     
2 2
47. PQ and RS are normal chord to parabola y 2  8x at P and R on the curve respectively and the
points P, Q, R, S are concyclic. If A is vertex of parabola, then
(A) centroid of APR lies on x-axis
(B) centroid of APR lies on y-axis
(C) PR is parallel to tangent at the vertex
(D) PR is parallel to axis of parabola
Ans. A, C
Sol. Equation of normal chord at P(2t12 ,4t1 ) & R(2t 22 ,4t 2 ) are y  t1x  4t1  2t13  0 and
y  xt 2  4t 2  2t32  0 .Equation of any two degree curve passing through P, Q, R, S is
(y  xt1  4t1  2t13 )(y  xt 2  4t 2  2t32 )   y 2  8x)  0
 P, Q, R, S are concyclic
 1    t1t 2 & t1  t 2  0
4(t1  t 2 ) 2
 Centroid of APR lies on x-axis & slope of PR  2 2

2(t1  t 2 ) t1  t 2
 PR is parallel to y-axis
x 2  9bx  17
48. If f : R  [ 1, 2], f(x)  is onto function and f '(d)  f '(e)  0. Then
ax 3  x 2  bx  33
x2 y2 1
(A) eccentricity of curve 2
  1 can be
(d  e) b 1 2
x2 y2 5
(B) eccentricity of curve 2
  1 can be
(d  e) b 1 2
x2 y2 3
(C) eccentricity of curve   1 can be
(d  e)2 (a  1) 2
x2 y2 7
(D) eccentricity of curve 2
  1 can be
(d e) a 1 2
Ans. A, B, C
Sol.  Domain of function is real number so a = 0

x 2  9bx  17
Now y  2  (y  1)x 2  (by  9b)x  (33y  17)  0
x  bx  33
 x  R so D  0  (by  9b)2  4(y  1)(33y  17)  0
 b  2 and -2
 For b = 2  d = -5 , e = 7
For b = -2  d = -7, e = 5

INTEGER.
49. A 3  3 determinant has entries either 1 or -1. Let S be the set of all determinants such that the
1 1 1
product of elements of any row or column is -1. For example 1 1 1 is an element of S and
1 1 1
number of elements in S is m.
3 2 3 
  m
Let P  2 2 3  and trace of the matrix adj (adj P) is n then the value of is
n
0 1 1
Ans. 8
Sol.  Elements of determinant can be 1 or -1

 First two places of first row can be filled in 2  2 =4 ways and last place can be filled in only
one way to product be 1
 First row can be made in 4 ways
Similarly second row can be made in 4 ways and third row can be made in 1 ways only
 m = 16
3 2 3
 P  2 2 3  1
0 1 1
n2
 adj(adjP)  P P  P  tr(adj(adjP))  tr(P)  2  n.
m 16
  8
n 2
a
50. A normal coin is tossed six times. If p  where a, b are relatively prime positive integers,
b
denotes the chance that there will be exactly one sequence of 3 consecutive heads in six tosses,
 a  b  1
then the value of   is
 4 
Ans. 5
Sol. HHHTXX
THHHTX
XTHHHT
XXTHHH
1 1 1 1 6 3
 P(E)      
16 32 32 16 32 16
3  16  1
5
4
51. If a, b, c, d, e are positive real numbers such that a  b  c  d  e  15 and

ab2c 3 d4 e5  (120)3 .50, then the value of a 2  b 2  c 2  d2  e 2 is
Ans. 55
b b c c c   d d d d e e e e e
a              
Sol. A.M. = 2 2 3 3 3  4 4 4 4 5 5 5 5 5 1
15
1
 b b c c c d d d d e e e e e 15
And G.M. =  a. . . . . . . . . . . . . .   1
 2 2 3 3 3 4 4 4 4 5 5 5 5 5
b c d e
a    
2 3 4 5
 a  1,b  2,c  3,d  4,e  5
 a 2  b 2  c 2  d2  e 2  55

Question Stem
A ten-sided regular polygon is inscribed in a circle |z| = 1. A1A2…….A10 to its vertices, G1 is centroid of 
A1A4A8, G2 be centroid of  A2A6A9 and G3 be centroid of A3A5A7. P is centroid of G1G2G3. If O is the
centre of circle.
52. Angle POA1 is equal to
Ans. 2.51
Sol. Consider x10 = 1

Hence x = eix2r/10 (r = 1, 2,....., 10)
A1  eix2  /10  1
A 2  eix 4  /10   2
A 3  eix6  /10  3
A10  1  10
Here centroid of A1A4A8 is
  4  8
G1  1
3
 2   6  9
G2 
3
3  5   7
G3 
3
1   2  3  ....  9 1
Hence centroid of G1G2 G3 is P  
9 9
4
Hence POA1 
5
53. 100  OP is equal to
Ans. 11.11
Sol. Consider x10 = 1

Hence x = eix2r/10 (r = 1, 2,.....10)
A1  eix2  /10  1
A 2  eix 4  /10   2
A 3  eix6  /10  3
A10  1  10
Here centroid of A1A4A8 is
1   4   8
G1 
3
 2   6  9
G2 
3
3  5   7
G3 
3
1   2  3  ....  9 1
Hence centroid of G1G2 G3 is P  
9 9
1
OP =
9
Question Stem
Define a function  : N  N as follows, (1) = 1,  (rn) = rn-1(r – 1), if r is prime and n  N,  (   n)

=       n  , if H.C.F (  , n )  1 .
54. (1672)  125 is equal to
Ans. 5.76
Sol. 1672  209  8, whose HCF is 1

  1672     209    8     209    23    11 19    23 

55. If  (615) = , then is equal to
1000
Ans. 223.26
Sol.   61n   61n 1  60  612  60
Question Stem
 x   x 
F, g : R  R are functions such that f(x) = 3x – sin   , g  x   x 3  2x  sin  
 2   2 
d 1 1 2
56. The value of f  g  x  x 12 is equal to then k is equal to
dx 3k
Ans. 31.14
Sol.  f 1g1  x     gf  x  1

d 1 1 1
 f g  x  x 12 
d
dx
 gof  x   x 1
dx
57. The area bounded by y = f -1(x), y = g-1(x) is
Ans. 0.50
Sol. Area will be same as bounded by y = f(x), y = g(x)

1
1
  x 3  x dx 
1
2
FIITJEE
JEE (Advanced)-2022
FULL TEST – I
PAPER –2
TEST DATE: 23-12-2021
Section – A (07 –10, 26 – 29, 45 – 48): This section contains SIX (06) paragraphs. Based on each
paragraph, there are TWO (02) questions. Each question has FOUR options (A), (B), (C) and (D). ONLY ONE
of these four options is the correct answer.
decimal places.
MARKING SCHEME
marking scheme:
Partial marks : +2 if three or more options are correct but ONLY two options are chosen and both of which
are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option;
Physics PART – I

1. n number of identical equilateral

prisms are kept in contact as shown 2 4
in figure. If deviation through a single 1 3 5 n
prism is . Then (n, m are integers)
(A) if n = 2m, deviation through n prism is zero.
(B) if n = 2m + 1, deviation through system of n prisms is .
(C) if n = 2m, deviation through system of n prism is 
(D) if n = 2m + 1 deviation through system of n prisms is zero
Ans. A, B
Sol. The consecutive prism produce equal and opposite deviation. Hence if number of prism is even
deviation is zero and if odd, deviation is .
2. A block of mass ‘m’ is attached by means of a spring to the bottom of a

tank of water as shown in figure. At equilibrium, the spring is under
compression. If the tank is now allowed to fall freely, then choose the
correct alternative(s)
(A) the spring comes to its relaxed position
(B) the spring compresses more than its equilibrium compression
(C) the boyant force becomes zero
(D) there will be some elongation is the spring
Ans. B, C
Sol. As the tank allowed to fall vertically, so bouyant force becomes zero, so the spring compresses
more than its equilibrium compression.
3. A 10 m long horizontal stainless steel wire AB of mass 1 kg whose end A is fixed, is connected to
a massless string BC passing over a smooth pulley. String BC is connected to a container of
mass 2 kg at end C. Water (density = 1 × 103 kg/m3) is poured in the container at a constant rate
of 2.25 litre/sec at t = 0. Also at t = 0, a pulse is generated at end A.
(A) Time taken by the pulse to reach point B is 0.612 sec
(B) Time taken by the pulse to reach point B is 0.212 sec
(C) Tension in the string at this moment is 33.77 N
(D) Tension in the string at this moment is 24.77 N
Ans. A, C
Sol. Mass per unit length of the wire = 0.1 kg/m.

At any instant, tension in the string is (2 + 2.25 t) g N
(2  2.25 t ) g
v
0.1
10 t
 dx  10
0 0
2  2.25 t dt
t = 0.612 s
T  2  2.25  0.612  10  33.77 N
4. Three capacitors each having capacitance C = 2F are connected S

with a battery of emf 30V as shown in the figure. When the switch
S is closed. C
C
C
30V
(A) the amount of charge flown through the battery is 20 C
(B) the heat generated in the circuit is 0.6 mJ
(C) the energy supplied by the battery is 0.6 mJ
(D) the amount of charge flown through the switch S is 60 C
Ans. A, C, D
Sol. Charge flow through battery = 20 C

U = energy supplied by battery = 0.6 m
Ui = energy store in capacitor’s before closing = 0.6 m J
Uf = energy store in capacitor after closing = 0.9 mJ
Heat generated = U – (Uf -Ui ) = 0.3 mJ , charge flow through switch is 60C.
5. Two plates of a parallel plate capacitors carry changes q and –q and

are separated by a distance x from each other. The capacitor is
V0
connected to a constant voltage source V0 . The distance between the
plates is changed to x  dx. Then in steady state.
+q –q
 Udx
(A) change in electrostatic energy stored in the capacitor is , where U is initial
x
potential energy.
Ux
(B) change in electrostatic energy stored in the capacitor is 
dx
1
(C) attraction force between the plates is qE
2
(D) attraction force between the plates is qE. (where E is electric field between the plates)
Ans. A, C
1 0 AV02
Sol. Initial stored energy U i 
2 x
1  0 AV02
Final stored energy U f 
2 ( x  dx)
1  1 1
So, U  U f  U i   0 AV02   
2  x  dx x 
1  x  x  dx  1  0 AV02 1  0 AV02 dx Udx
  0 AV02    2
dx   . 
2  x( x  dx )  2 x 2 x x x
dU U
So, choice (a) is correct and choice (b) is wrong. F 
dx x
1  0 A V02 1 A  V 1
F  .    0 .V0 . 0   qE
2 x x 2 x  x 2
1
So magnitude of attractive force is qE.
2
So, choice (c) is correct and choice (d) is wrong.

6. A charged particle of unit mass and unit charge moves with velocity of v  8iˆ  6 ˆj m/s in a

 
magnetic field of B  2kˆT . Choose the correct alternative(s)
2 2
(A) The path of the particle may be x  y  4 x  21  0
2 2
(B) The path of the particle may be x  y  25
2 2
(C) The path of the particle may be y  z  25
(D) The time period of the particle will be 3.14s
Ans. A, B, D
2m 1
Sol. Motion is in x-y plane and T  =  s
qB 12 

This section contains TWO (02) paragraphs. Based on each paragraph, there are TWO (02) questions.
Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct
answer.
Paragraph for Question Nos. 07 and 08
A plane loop is shaped in the form, as shown in the figure with        

radii a = 20 cm and b = 10 cm and is placed in a uniform time
       
varying magnetic field B  20  10t  T , where t is the time in
  a     
second. Answer the following questions based on the above
statement 10F B 10F
  A  b
   
       
7. The induced emf in the loop is
(A) 0.942 V
(B) 1.57 V
(C) 0.157 V
(D) 0.0942 V
Ans. A
Sol.  = instantaneous flux through loop = BA1  BA2

Sense of induced emf is opposite in each loop
dB dB
Hence, the net emf induced  A1
dt
 A2
dt

 10 a 2  b 2 = 0.942 V 
8. The maximum charge on each capacitor is
(A) 4.71  10–6 C

–6
(B) 0.471  10 C
(C) 52  10–6 C
(D) 5.2  10–6 C
Ans. A
Sol. Q  CV  5  10 6  0.942  4.71  10 –6 C
A uniform chain of length L is suspended in equilibrium by an elastic string of natural length h as shown.
The chain is then suddenly cut at point A which is x distance below the upper end of chain.
2h
h
9. If x  L / 3 , the velocity of suspended part of chain when it rises by from its equilibrium
2
position is
gh
(A)
3
4
(B) gh
3
5
(C) gh
4
2
(D) gh
3
Ans. C
Sol. For equilibrium kh = mg

x = L/3 suspended mass = m/3
2
1 m 2 mg h 1  h  1
v   k    kh 2
2 3 3 2 2  2 2
5
v gh
4
10. To allow the elastic string to become slack, the minimum value of x is
L
(A)
2
L
(B)
3
L
(C)
4
2L
(D)
3
Ans. A
Sol. To just slack height raised = h

mx 1
gh  kh 2
L 2
L
x=
2
INTEGER.
11. A block A of mass 2 kg is hanging in a vertical plane with a

spring of stiffness constant k = 100 N/m. A block B of mass 1
kg is kept on block A and the system is in equilibrium.
Suddenly block B is removed. The amplitude of resulting SHM
of A is B
A
Ans. 10
3 g 2 g g 10
Sol. Shift of equilibrium position      0.1 m = 10 cm
k k k 100
Hence amplitude = 10 cm
12. A plano-convex lens has a thickness of 4 cm. When placed on a horizontal table with curved
surface in contact with it, the apparent depth of the bottom most point of the lens is found to be 3
cm. If the lens is inverted such that the plane face is in contact with the table, the apparent depth
of the centre of plane face is found to be 25/8 cm. The focal length of the lens is
Ans. 75
4 4
Sol. 3  =
 3
R  25 cm
1  1 1 
 (  1)  
f  R1 R2 
f  75 cm
13. A galvanometer of coil resistance 1 is converted into V

voltmeter by using a resistance of 5 in series and same
galvanometer is converted into ammeter by using a shunt of
1. Now ammeter and voltmeter connected in circuit as 15 15 6
shown, find the reading of voltmeter. 4.5
12
30 V
A
Ans. 3
Sol. RVoltmeter = 6, Rammeter = 0.5

Req = 10
30
I  3A
10
Reading of voltmeter = 1  3 = 3 volt.

Question Stem
A horizontal frictionless string is threaded through a bead of mass m. The M

m
string is kept in tension between two vertical opposite sides of a cart of
mass M (see figure). Length of thread is L and radius of bead is r (r << L). L
Initially, the bead is at right edge of the cart. At t = 0, the cart is imparted a
velocity v0. All collisions are elastic.[ v0 = 10m/s , M = 2kg, m = 1kg, L =1m]
14. The velocity of C.O.M of the cart and the bead after 3 successive collisions is
Ans. 6.67
Mv0  m(0)
Sol. VCM 
M m
15. Distance traveled by cart before second collision is
Ans. 1.33
 M m L
Sol. Distance = L   v 0
 m  M  v0
 2M 
 L
 M m
Question Stem
A wire is bend at an angle . A rod of mass m can slide along the bend wire
without friction as shown in figure. If a soap film is maintained in the frame and 
l
frame is kept in a vertical position, the rod is in equilibrium.[  = 900 ,m =
100gm, l =1m) soap film rod of mass m
16. Surface tension of the soap solution is [in S.I system]
Ans. 0.25
  mg
Sol. 2T  2l tan   mg ,T =
 2 
4l tan
2
17. If rod is displaced slightly in vertical direction, find the time period of small oscillation
[take g1/2 = π]
Ans. 2.00
Sol. If x be the displacement in vertical direction of the rod from equilibrium position

 4T tan
 2 x,
Fres  2 x tan T  2 , a
2 m
m m l
T  2  2  2
 mg g
4T tan 4
2 4l

Question Stem
The magnetic force on a moving charge is given by x

   Wall
F  qv  B . Further when a charge particle moves in x x
uniform magnetic field such that its velocity is perpendicular to
x1 D=75cm
the magnetic field then its path is circular.
x
A particle with charge 2.4C and mass 3.2 × 10–12 kg is × × × × × × × d=30cm x
initially traveling in the +y direction with a speed v0 = 1.35 × × × × × × × ×
5
10 m/s. It then enters a region containing a v0
uniform magnetic field that is directed into, and perpendicular to, the edge. The magnitude of field is
0.360 T. The region extends a distance of 30 cm along the initial direction of travel; 75 cm from the point
of entry in to the magnetic field region there is a wall. The length of the field free region is thus 45 cm.
When the charged particle enters the magnetic field, it follows a curved path whose radius of curvature is
r. It then leaves the magnetic field after time t1, having been deflected a distance x1. The particle then
travels in the field-free region and strikes the wall after undergoing a total deflection x.
18. The radius r of the curved part of the path is(in cm)
Ans. 50.00
mv 3.2  10 12  1.35  10 5 Wall BA

Sol. R  = 0.5 m x
qB 2.4  10 6  0.36

D=75cm
× × × r× × × ×
Q x
× × × × × × ×
O RP
19. The total horizontal deflection is(in cm)
Ans. 44.00
3
Sol. x = AB + BC = x1 + BQ tan  = x1 + (D – d) tan  = 0.1  (0.75  0.30)  0.44 m
4

20. The time required for an electron to make one complete revolution around nucleus of H-atom in a
higher orbit n2 is 8 times to that of a lower orbit n1 . Therefore n1 and n2 are
(A) 1 and 2
(B) 2 and 3
(C) 2 and 4
(D) 3 and 6
Ans. A, C, D
Sol. Time period  n 3

3
T1  n1 
 
T2  n2 
T2  8 T1  n2  2n1
21. Which of the following compounds acts both an oxidising as well as a reducing agent?
(A) HNO2
(B) H2 O2
(C) H2 S
(D) SO2
Ans. A, B, D
Sol. In H2S oxidation number of sulphur is minimum-2, it can act as only reducing agent.
22. Which compounds would not give 5-keto-2-methylhexanal upon ozonolysis?
(A) CH3 (B) CH3
H3C CH3
(C) CH3 (D) CH3
CH3 H3C
Ans. A, B, D
Sol. Only C will give 5-keto-2-methylhexanal upon ozonolysis.

CH3
O O
O
3
Zn/H2 O
 H C C CH2 CH2 CH C H
3
CH3 CH3
23. Among the follow compounds which do not give positive iodoform test
(A) CH3
|
CH3  CH  CH2 OH
(B) C6H5 CHOHCH3
(C) CH3  CH2  CH(OH)  CH2  CH3
(D) C6H5 CH2CH2OH
Ans. A, C, D
Sol. Alcohols lacking CH3 group do not give iodoform test.
24. Metals which form protective layer of oxide when react with dil. HNO3
(A) Al
(B) Cr
(C) Cu
(D) Zn
Ans. A, B
Sol. Al, Cr form protective layer of oxide and renders passive.
25. For [Ni(CN)4 ]2  and [Ni(CN)4 ]4  , which of the following statement(s) is/are CORRECT?
(A) Differ in hybridisation but magnetic properties are same
(B) Differ in magnetic property and hybridisation but no one can show optical isomerism
(C) Differ in shape and EAN value but no one can show geometrical isomerism
(D) Different number of atoms are in same plane and same dipole moment.
Ans. A, C, D
Sol. (i) [Ni(CN)4 ]2 
Ni2  [Ar]
3d 4s
In presence of ligand:
 [Ar]    
3d CN CN CN CN
=0
Hybridisation = dsp2, geometry – square planar
Magnetic nature – diamagnetic
EAN = [28-2+2×4] =34
(ii)[Ni(CN)4 ]4 
Ni  [Ar]3d8 4s2
[Ar]    
3d CN CN CN CN
 =0
Hybridisation = sp3, geometry – tetrahedral
Magnetic nature – diamagnetic
EAN = [28-0+2×4] = 36

answer.
A charged particle like electron produces induced magnetic field when it is in motion. Therefore the
revolving electrons of an atom can create magnetic field The paramagnetic substances are attracted
towards an external magnetic field because they possess certain magnetic moment. The magnetic
moment of an atom depends on the number of unpaired electrons. It is determined by using the formula
 n  n  2 B.M
26. The magnetic moment of an oxide of vanadium is 1.732 B.M. What is the molecular formula of
the oxide?
(A) VO
(B) VO2
(C) V 2O
(D) V 2O 3
Ans. B
Sol. n n  2   1.732  3
or, n (n + 2) = 3
or, n = 1
The electronic configuration of vanadium is:
V = [Ar]18 3d34s2
In V4+ state, vanadium will contain one unpaired electron.
 The molecular formula of its oxide is V2O4 or VO2
27. The magnetic moment of which of the following ions is same as that of nitrogen atom?
(A) Co2+
(B) Fe3+
(C) Ni2+
(D) Zn2+
Ans. A
Sol. Nitrogen contains three unpaired electrons.

Co2+ (3d7) also contains three unpaired electrons
Co2+ (3d7) =
In the following reaction sequence, the compound J is an intermediate

(i) H2 / Pd / C
(CH3 CO)2 O (ii)SOCl2
I J 
(iii)anhyd.AlCl3
K
CH3 COONa
J(C9H8O2) gives effervescence on treatment with NaHCO3 and a positive Baeyer’s test
28. The compound I is
(A) O H (B) HO
(C) O CH3 (D) H

H
H
Ans. A
Sol. Perkin reaction
29. The compound K is
(A) (B)
O O
(C) (D)
O
Ans. C
Sol. FC acylation

INTEGER.
30. The trade name of one stereoisomer of compound B is Aspartame. How many total
stereoisomers of Compound B exist?
Ans. 4
Sol. There are two chiral centre so total stereoisomers will be 4.
31. 1.3245 g of a monobasic acid when dissolved in 100 g of water lowers the freezing point by
N
0.2046C. 0.2 g of the same acid when dissolved and titrated required 15.1 ml of alkall.
10
(Assuming molarity = molality), the pH of acid solution is: ( K f of water 1.86 K kg mol–1)
Ans. 2
Sol. Meq. of alkali = Meq. of acid

1 0.2
 15.1   1000
10 M
On, solving M = 132.45 g mol–1
1.3245  1000
Now, molality of acid solution (m) =  0.1
132.45  100
 Tf  i  K f  m
0.2048  i  1.86  0.1
I = 1.1 = 1 + 
   0.1
HA 
 
 H  A
Now,C 0 0
C  C C  C C
H   C  0.1 0.1  10 2
 pH  2
32. I.E.1 and I.E.2 of Mg are 178 and 348 kcal mol1 . The enthalpy required for the reaction in
kcal/mole
Mg(g)  Mg2 (g)  2e  is:
Ans. 526
Sol. I.E.  I.E.1  I.E.2

Question Stem
On addition of 0.25 mole of a non volatile solute HA (mono basic acid) in 5 moles of benzene solute gets
partially dimerised and the pressure of solution measured is 581.11 mm Hg.
On further titration of this solution 200 ml of 1.25 M NaOH required to reach end point.
 NaOH  1.21gm ml 

PBenzene  600 mm Hg 
  
PH2 O  23.76 mm Hg
2HA   HA 2
33. Degree of association of solute () in solution is?
Ans. 0.70
34. How many mL of 1.25M NaOH will be required for complete neutralization of the acid?
Ans. 200.00
Sol. (Q.33 – 34)

PS  P. Xsolvent
P  PS n
 solute
PS Nsolvent
600  581.11 n
 , n  0.1625
581.11 5
0.25
When n  0.25 
2
  0.7
Question Stem
The emf of the given cell is –0.46 V

Pt  H2  H2PO4  0.4M , HPO 4  6.4  10 3 M M2   0.81M M  s 
1atm  
1L solution
2
If EºM M  0.76 V  log3  0.477, log 2  0.3010   and temperature is 25ºC.
35. The pH of left compartment initially is
Ans. 4.57
2
0.0591 H 
Sol. 0.46  0.76  log   using Nernst equation
2 0.81
Cell reaction 2H  2H  2e  anode 
2
Mi2  2e 
 M  cathode 
 2
log
H   0.6   0.6 
   
1
.81  
 0.059   0.06  10
 
0.81 
log  2
 10  log1010
 H  
  
 2
H   81 1012
H  9  106
pH  6  3log3
pH  4.5687
36. 

pK a for reaction H2PO4  2 
 HPO 4  H is
Ans. 6.84
Sol. H2PO2 



 HPO 4  H
0.4M 6.4  10 3 9  104
6.4  103  9  106
Ka 
0.4
pK a  9   4log2  2log3  6.8419

Question Stem
Internal energy is a state function quantity. It is a measurement of total energy of system. For ideal gas
potential energy is zero therefore internal energy is function of temperature only. For ideal gas molecules
kinetic energy is divided in three part?
(i) Translational (ii) Rotational (iii) Vibrational
vibrational energy become effective only at very high temperature
Take R = 2 cal/mol/K
37. For diatomic ideal gas molecules C p (molar heat capacity) value (in cal) is equal to
Ans. 7.00
38. C p value (in cal) for water molecules in vapour state is equal to (assuming ideal condition)
Ans. 8.00
Sol. (Q.37-38)
R
Cv  (degrees of freedom) 
2

39. The number of solutions in [0, ] of the equation

sin4 x  cos6 x  a is
1
(A) none if a 
4
(B) three if a = 1
1
(C) two if a 
4
5
(D) three if a 
4
Ans. A, B, C
3 8a  5
Sol. a  1 1  cos 4x   cos 4x 
8 3
For real solution
8a  5
1  1
3
3  8a  5  3
1
2  8a  8   a  1
4
(A) The number of quadratic equations having real roots which remain unchanged even after
squaring their roots is 3.
(B) The number of solutions of the equation tan2  tan3   in the interval [0, ] is equal
to 6.
2x1 128x32 x 23
(C) For x1,x 2 , x 3  0 the minimum value of   equals 24.
x2 x 22 4x1x32
(D) The locus of the mid points of chords of the circle x 2  y 2  2x  6y  1  0, which are
passing through origin is x 2  y 2  x  3y  0.
Ans. A, B, D
Sol. (A) We have     2  2 and    22

 Number of quadratic equations with real roots are 3.
(B) tan3  tan    3  n     n  z


    n  1 ,n  I,
5 (1,3)
Putting n  1,0,1,2,3,4
 2 3 4 5
We get   0, , , , , (0,0)
5 5 5 5 5
M(x1, y1)
(C) AM  GM  minimum value = 4

(D) Let M(x1, y1 ) be the mid-point of chord
 y  3  y1 
Then m1m2  1   1    1
 x1  1  x1 
Locus of M(x1, y1 ) is x 2  y 2  x  3y  0
41. If 4 sin  cos   2 cos   3  2 3 sin  where   [0,2 and L     then
11
(A) maximum value of L is
6
5
(B) minimum value of L is 
6
5
(C) maximum value of L is
3
11
(D) minimum value of L is
6
Ans. A, D
Sol. (2 cos   3 )(2 sin     

3 1
 cos   or sin   
2 2
 11 7  11
 , or   ,
6 6 6 6
 11
maximum where   6 and   
L     
 minimum when    11

 6
 11
L max i  11 ;L min i 
6 6
42. A differentiable function f : R  R satisfies the functional equation

f(x).f(y)  f(x  y)  e x f(y)  ey f(x)  xy  x,y  R. If f '(0)  0 and f(0)  0, then which of the
following statements is/are correct ?
f(x) 1
(A) lim 
x 0 x2 2
x2
(B)   f '(t)  f(t) dt  0  x
x
1
(C) F(x 2 )  F(x1 )x 2  x1, where F(x)  f '(x)  f(x)
(D) There exists at least two horizontal tangents to the curve y  f(x) in (-1, 1).
Ans. A, B, C
Sol. f(x).f(y)  f(x  y)  e x f(y)  e y (x)  xy.

 f(x).f '(y)  f '(x  y)  e x f '(y)  e y f(x)  x
Put y = 0
f(x).f '(0)  f '(x)  e x f '(0)  f(x)  x
 f '(x)  f(x)  x  f(x)  ex  x  1
f(x) ex  x  1 1
 (A) lim  lim  .
x 0 x 2 x 0 x2 2
x2 x2
 t2  x 4  x2
(B)  t dt      0 x  1
x  2 x 2
(C) F(x)  f '(x)  f(x)  (e x  1)  (e x  x  1)  x which is increasing function so
F(x 2 )  F(x1 ) if x 2  x1
(D) Now f '(x)  ex  1 and f "(x)  ex  0x  R
 f '(x) is increasing function or R
 f '( 1)  ve and f '(1)   ve
 f '(c)  0 has exactly are root in (-1, 1).
i.e., one horizontal tangent. In (-1, 1)
43. Let f(x) be the remainder when p(x)  x 73  2x 6  3x3 is divided by x 4 (x 2  1). Identify which of the
following statement is(are) correct?
(A) Range of f  f(x)  is R
(B) Range of f  f(x)  is [0, )
(C) f(x) has exactly 3 points of inflection.
(D) f(x) has exactly one point of inflection.
Ans. A, D
Sol. P(x)  x 73  2x 6  3x3  Q(x).x 4 (x 2  1)  (ax 2  bx  c)x 3

After cancelling x 3
Put x  0  c  3.
x  1a  b  c  2
x  1  a  b  c  6
 a  1,b  2
 f(x)  x5  2x 4  3x 3
Degree of f(f(x)) is 25 so range of f(f(x)) is R

f "(x)  20x 3  24x 2  18x
Only one real root
44. Let S1 : x 2  y 2  10x  16  0 and S2 be image of S1 w.r.t line y = x and S3 be image of S2 w.r.t
y = 0. If S’ be the circle which cuts all three circles orthogonally, then
(A) S' : x 2  y 2  16
(B) S2 : x 2  y 2  10y  16  0
(C) S3 : x 2  y2  10y  16  0
(D) radius of director circle of S’ is 8 2
Ans. A, B, C
Sol.  Centre of S 1  (5,0) and radius r1  3

 Centre of S2 = (0, 5) and radius r2  3 and centre of S3 = (0, -5) and radius r3  3.
 Radical centre of S1,S2 ,S3 will be (0, 0)
Length of tangent from (0, 0) upon S1 or S2 or S3 = 4
 S' : x 2  y 2  16

answer.
Let  denotes
1
the equation of the plane to which the vector (1, 1, 0) is normal and which contains the

line L whose equation is r  î  ˆj  kˆ   î  ˆj  k).
ˆ
 2 denotes the equation of the plane containing the line
L and a point with position vector (0, 1, 0).
45. Vector of magnitude 6 along the line of intersection of planes  1

and  2 perpendicular to
normal vector of plane  1
, is
(A)  2( 1,1,1)
(B)  2(1,  1,1)
(C)  2(1,1,  1)
(D)  2(1,1,1)
Ans. A
46. The acute angle between  1

and  2 is
(A) tan 1(1)  tan1( 2  1)
(B) tan 1 (1)  tan 1(2  3 )
(C) tan 1(1)  tan 1( 2  1)
(D) tan 1 (1)  tan 1(2  3 )
Ans. B
Sol . (Q.45

& 
Q46) 
r.n1  a.n n1  i  j
  
xiˆ  yjˆ  zkˆ . î  ˆj  2
A
xy  2 .... (Plane  ) 1 

1
(1,1,1) r  1, 1, 1   1,  1,  1
Now, AB  î  k;A
ˆ 1,1,1 and B(0, 1, 0)
î ˆj kˆ
     
Now, AB  V  n2 . 1 0 1 n2  AB  V
1 1 1
 
n2  i (0  1)  ˆj(1 1)  k( ˆ 1)
B,  ˆj  LL
 
 n 2  î  2 ˆj  kˆ   î  ˆj  kˆ
Hence, equation of plane
 2
 2 is (r  ˆj).( î  2ˆj  k)
ˆ 0
Or x  2y  z  2
(i) Vector along the line of intersection of
planes
 
 1 and  2 is n1  n2 which is also perpendicular to the normal vector of plane . 1
   ˆ ˆ ˆ
ˆ so required vector   6   i  j  k 
 n1  n 2   î  ˆj  k,  3 

(ii) If  is the acute angle between  1 and  2 then

n1.n2 (iˆ  ˆj).(iˆ  2jˆ  k)
ˆ (1  2) 3 
cos          .
n1 n2 2 6 2 3 2 6
Let A be a square matrix of order n  n . A constant  is said to be characteristic root of A if there exists a
n  1 matrix X such that AX   X
47. If 0 is a characteristic root of A, then
(A) A is non – singular
(B) A is singular
(C) A=O
(D) A  In
Ans. B
Sol. If   0, we get A  0
 A is singular.
48. If  is a characteristic root of A and n  N , then  n is a characteristic root of
(A) An
(B) A n1
(C) A n
(D) A  A n  A n
Ans. A
Sol. We have, A 2 X  A  AX   A  X 
   AX    2 X
 
A 3 X  A A 2 x  A 2 X  
  2  AX    2  X 
 3 X
Continuing in this way, we obtain
A n X  n X  n  N

INTEGER.
49. If the plane 2x  3y  6z  11  0 makes an angle sin 1(  with x-axis then the value of 7 is
Ans. 2
Sol.   sin1()  sin   

  1.2  3.0  6.0
 cos     
 2  4  9  36. 1
2 2
sin      
7 7
 7  2
(2n  1)(2n2  2n  1) n
50. If Tn 
(n  1)2 n2 (n  1)2 (n 2)2
,n  N,n  2 . If K  lim
n

r 2
Tr then 27 k is equal to
Ans. 3
(2r  1)(2r 2  2r  1) (2r  1)(2r 2  2r  1)

Sol. Tr   2
(r 2  1)2 (r 2  2r)2 (r  1)2 ((r  1)2  1)2
 1 1 
 Tr   2 2
 2 2
 (r  1) ((r  1)  1) 
 1 1   1 1   1 1 
 K  lim    2 2
 2 2 
 2 2
 2 2 
 ....   2 2
 2 2 
  (2  1) (3  1)   (3  1) (4  1)   (n  1) ((n  1)  1)  
n
1
k 
9
51. Let f : R  R be a function defined by f(x)  x 3  3x 2  9x  27. If x  (a,b)  (c,d) then

f 3 (x)  3f 2 (x)  9f(x)  27  f(x3  4x 2  3x  19). Then (b  a)  (c  d) is
Ans. 10
Sol. f '(x)  3(x2  2x  3)  3(x  1)(x  3)

Case-I f '(x)  0 i.e. f(x) is increasing the x  3 or x  1
f(f(x)  f(x3  4x 2  3x  19)  f(x)  x3  4x 2  3x  19
 x 2  6x  8  0  x  (2,4)
 x  (3,4)
Case-II f '(x)  0 i.e. f(x) is decreasing then 1  x  3
f(x)  x 3  4x 2  3x  19
 x 2  6x  8  0  (x  2)(x  4)  0  x  2 or x  4
 x  ( 1,2)
 x  ( 1,2)  (3,4)
 b  a  c  d  2  1  3  4  10

Question Stem
Let f be a real valued function from N to N satisfying the relation f(m + n) = f(m) + f(n) for all m, n  N.
52. If range of f contains all the even numbers, then the possible value of f(1) are A & B then
3A  2B
is equal to
5
Ans. 1.40
Sol. f m  n   f m   f n 
m  1, n  N  1
f N   f 1  f N  1
f N  1  f 1  f N  2
:
f N   Nf 1 .
If f(1) = 1  f(N) = N which contains even numbers.
If f(1) = 2  f(N) = 2 which contains even numbers.
53. If domain of f is first ‘3m’ natural numbers and if the number of elements common in domain and
25f 1
range is ‘m’, then the value of is
4
Ans. 18.75
Sol. f(n) = nf(1)

Number of elements common in domain and range is m
n D 
n R  D  
3
Question Stem
Let a sequence T1, T2, T3, …..Tn ……. And Sn = T1 + T2 + ……Tn, S’n = S1 + S2 + S3……Sn,
S"n  S1'  S'2  S3' .....Sn' , Sn"  n4
T3  T2
54. is equal to
4
Ans. 5.75
Sol. S’ = 1, 15, 65, 175

S  1, 14, 50, 110
T  1, 13, 36, 60
Tn = 24n – 36 for n  3
 3A - B 
55. Tn is given by An + B then is equal to
5
Ans. 21.60
Sol. S’ = 1, 15, 65, 175

S  1, 14, 50, 110
T  1, 13, 36, 60
Tn = 24n – 36 for n  3

Question Stem
For a recursive relation in ‘n’ we may generate nth term free from any other term i.e. purely in ‘n’. Based
on this answer the following questions
2
56. If  an 1  an  2  an 1   an  0 and a0  1, then lim 2n  4  an  is
n
Ans. 12.56
2an 1
Sol. Given equation converts to an  2
1   an 1 
  
 a n  tan  n  2 
2 
n 
 lim an 2 
n  4
57. If an  2an21  1 and a0  0, then lim ean  2 (use e = 2.72)

n
Ans. 5.44
1  an
Sol. Given equation converts to an 1 
2
  
 an  cos  n 1 
2 
  
cos  n1 
2 
Hence, lim e e
n 
FIITJEE
FULL TEST – I
JEE (Main)-2022
TEST DATE: 23-12-2021
 Part-A is Physics, Part-B is Chemistry and Part-C is Mathematics.
 Each part has only two sections: Section-A and Section-B.
 Section – A : Attempt all questions.
 Section – B : Do any five questions out of 10 Questions.
Section-A (01 – 20, 31 – 50, 61 – 80) contains 60 multiple choice questions which have only one
correct answer. Each question carries +4 marks for correct answer and –1 mark for wrong
answer.
Section-B (21 – 30, 51 – 60, 81 – 90) contains 30 Numerical answer type questions with answer
XXXXX.XX and each question carries +4 marks for correct answer. There is no negative marking.
AITS-FT-I-PCM-JEE(Main)/2022 2
Physics PART – A
SECTION – A
(One Options Correct Type)
This section contains 20 multiple choice questions. Each question has four choices (A), (B), (C) and
(D), out of which ONLY ONE option is correct.
1. A ball of mass m = 1kg is hung vertically by a thread of length  =

1.50 m. Upper end of the thread is attached to the ceiling of a trolley
of mass M = 4kg. Initially, trolley is stationary and it is free to move 1.50m
along horizontal rails without friction. A shell of mass m = 1kg, moving m M
horizontally with velocity v0 = 6 ms–1, collides with the ball and gets stuck m
v0
with it. As a result, thread starts to deflect towards right. Calculate its
maximum deflection with the vertical. (g = 10 ms–2)
(A) 37
(B) 53
(C) 30
(D) 60
Ans. A
Sol. When shell strikes the ball and gets stuck with it, combined body of mass 2m starts to move to
the right. Let velocity of combined body (just after collision) be v 1.
According to law of conservation of momentum,
v
(m + m) v1 = mv0 or v1 = 0 = 3 ms–1.
2
As soon as the combined body starts to move rightwards, thread becomes inclined to the vertical.
Horizontal component of its tension retards the combined body while trolley accelerates
rightwards due to the same component of tension.
Inclination of thread with the vertical continues to increase till velocities of both (combined body
and trolley) become identical or combined body comes to rest relative to trolley. Let velocity at
that instant of maximum inclination of thread be v. According to law of conservation of momentum
(2m + M) v = 2m.v 1 or v = 1 ms–1
During collision of ball and shell, a part of energy is lost. But after that, there is no loss of energy.
Hence, after collision, kinetic energy lost is used up in increasing gravitational potential energy of
the combined body.
If maximum inclination of thread with the vertical be  then according to law of conservation of
energy,
1 1
(2m) v12 – (2m + M) v2
2 2
= 2mg ( –  cos )
 cos  = 0.8 or  = 37°
3 AITS-FT-I-PCM-JEE(Main)/2022
  
2. The torque (   r  F ) of a force F = –3 î + ˆj +5 k̂ acting at the point r = 7 î + 3 ˆj + k̂ is -
(A) 14 î – 38 ˆj + 16 k̂
(B) 4 î + 4 ˆj + 6 k̂
(C) –21 î + 4 ˆj + 4 k̂
(D) –14 î + 34 ˆj – 16 k̂
Ans. A
Sol. The torque is defined as

=r×F
î ˆj k̂
r×F= 7 3 1
3 1 5
3 1 1 7 7 3
= î + ˆj + k̂
1 5 5 3 3 1
= î (15 – 1) + ĵ (–3 – 35) + (7– (–9))
= 14 î – 38 ĵ + 16 k̂
3. In a two slit experiment with monochromatic light, fringes are obtained on a screen placed at
some distance from the plane of slits. If the screen is moved by 5 × 10–2 m towards the slits, the
change in fringe width is 3 × 10–5 cm. If the distance between the slits is 10–3 m, calculate the
wavelength of the light used.
(A) 4500 Å
(B) 3000 Å
(C) 9000 Å
(D) 6000 Å
Ans. D
Sol. The fringe–width  is given by

D  D'
= and  =
2d 2d
Where  is the wavelength of light used, D is the distance of the screen from the two slits and 2 d
is the separation between two slits.
 (D  D' )
Now – =
2d
(  ' ) 2d
  =
D  D'
(3  10 5 )(10 3 )
 =
5  10 2
= 0.6 × 10–6 m = 6000 Å
 2
4. A certain physical quantity is calculated from the formula (a – b2) h, where h, a and b are all
3
length. The quantity being calculated is-
(A) Velocity
(B) Length
(C) Area
(D) Volume
Ans. D
Sol. Given quantity is = (a2 – b2) h

dimension of h = [L]
dimensions of a2 – b2 = [L2 – L2] = L2
Therefore the dimensions of the given quantity are [L3]. Thus the quantity being measured is
volume
5. A point object O is placed at a distance of 0.3 m from a convex

lens (focal length 0.2 m) cut into two halves each to which is
displacement by 0.005 m as shown in fig. Find the position of the
image. Find the distance between the images.
(A) 0.003 m
(B) 0.002 m
(C) 0.004 m
(D) 0.001 m
Ans. A
Sol. The image formation is shown in fig.
The rays through optical centres O1 and O2 pass undeflected. The image of O are formed at 1
and 2 due to upper and lower lenses respectively.
The number of images formed = two
1 1 1
For a convex lens, – =
v u f
Here u = – 0.3 m and f = 0.2 m
1 1 1 1 1 1
 = + =– + =
v u f 0 .3 0.2 0.6
u = 0.6 m
Let d be the distance between the two images 1 and 2. From OO1O2 and  12, we have
d uv
=
O1O 2 u
d 0.3  0.6
or =
0.0005  0.0005 0 .3
Solving we get d = 0.003 m
6. A truck starts from rest with an acceleration of 1.5 metre/sec2 while a car 150 metre behind starts
from rest with an acceleration of 2 metre/sec2. How long will it take before both the truck and car
to be side by side, and how much distance is travelled by each?
(A) 2.45 sec
(B) 5 sec
(C) 24.5 sec
(D) 5.3 sec
Ans. C
Sol. Let x be the distance travelled by the truck when both truck and car are side by side. The
distance travelled by the car will be
(x + 150) as the car is 150 metre behind the truck. Applying the formula
s = ut + (1/2) a t2, we have
x = 1/2 × (1.5) t2 ..........(1)
and (x + 150) = (1/2) × (2) t2 ..........(2)
Here t is the common time.
From eqs. (1) and (2) we have
x  150 2
= =
x 1 .5
Solving we get x = 450 metre (truck) and
x + 150 = 600 metre (car).
Substituting the value of x in eq. (1),
we get 450 = 1/2 (1.5) t2
450  2
 t= = 600 = 24.5 sec.
1.5
Hence correct answer is (C)
7. The back side of the truck which is moving with 40 km/h

has shining surface. The surface can be treated as a
plane mirror. A motorist trying to overtake the truck from
behind is moving with speed of 100 km/h. Find the 100 Km / h
v = 40 Km / h
velocity of the image of motorist observed to himself and
to a person standing on the roadside.
(A) 10 kmph
(B) 30 kmph
(C) 20 kmph
(D) 5 kmph
Ans. C
Sol. Velocity of object = 100 km/h.

Velocity of mirror = 40 km/h
Due to velocity of mirror the image will move towards right with double the velocity i.e., 80 km/h.
and due to the motion of the object the image will move with velocity 100 km/h towards left.
Hence net velocity of the image is 100 – 80 = 20 kmph towards left.
Velocity of image observed to the motorist = 20 + 100 = 120 kmph towards left.
Velocity of image observed to the standing person = 20 kmph.
8. In the position 1 (figure) the spring of constant K is undeformed. F

 2
Find the work done by the force F (which is always directed along a
0
the tangent to the smooth hemi spherical surface) on the small a 1
block of mass m to shift it from the position 1 to position 2 slowly.
2
KR 2  0
(A) mg R sin θ 0 +
2
(B) mg R sin θ 0
KR 2 0 2
(C) mg R sin θ 0 +
4
(D) Zero
Ans. A
Sol. Let us locate the block at an arbitrary angular position  < 

 
dW = F . dr = Fds = F (Rd) ...(1)
Now from the condition of equilibrium of the block, we have
F = mg cos  + KR  ...(2)
from eq. (1) & (2)
dW = mg R cos  d + KR2  d
Hence the sought work
0 0
W=  dW =  cos  d  KR 2   d
0 0
KR 2  0 2
W = mg R sin  +
2
9. The ionization potential of Li++ ion is 122.4 V. Find the value of its first excitation potential.
(A) 91.8v
(B) 45.9 V
(C) 122.4V
(D) 28.4 V
Ans. A
Sol. According to given data, ionization energy of Li++ ion is 122.4 eV
  Excitation energy of this ion

1 1 
= 122.4  2 – 2 
 1 2 
 1
= 122.4 1 – 
 4
3
= 122.4 × eV
4
 Eex = 91.8 eV
Hence, the value of the first excitation potential
= 91.8 V
10. A rigid body is made of three identical thin rods, each of length L
fastened together in the form of the letter H. The body is free to rotate
about a horizontal axis that runs along the length of one of the legs of
the H. The body is allowed to fall from rest from a position in which the
plane of the H is horizontal. What is the angular speed of the body
3 g
when the plane of H is vertical
2 L
5 g
(A)
2 L
3 g
(B)
2 L
3 g
(C)
4 L
g
(D)
L
Ans. B
Sol. Moment of inertia of the system about the given axis

I = IA + IB + IC
Now as rod is thin
IA = m x 02 = 0
Rod B is rotating about one end
IB = ML2 / 3
And for rod C all points are always at distance L from the axis of rotation, so
IC = mL2 =ML2
 I = 0 + (ML2 / 3) + ML2 = 4ML2 / 3
So if  is the desired angular speed, gain in kinetic energy due to rotation of H from horizontal to
vertical position.
1 1 4 
KR = I2 =  ML2   2
2 2  3 
And loss in potential energy of the system in doing so
L 3
= 0 + Mg + MgL = MgL
2 2
So by conservation of mechanical energy
(2 / 3) ML22 = (3/2) MgL
3 g
or =
2 L
18
11. A radioactive sample has 6.0  10 active nuclei at a certain instant. How many of these nuclei
will still be in the same active state after two half-lives?
(A) 3 1018
(B) 1.5 1018
(C) 0.75  1018
(D) 6 1018
Ans. B
Sol. In one half-life the number of active nuclei reduces to half the original number. Thus, in two half-
1 1
lives the number is reduced to     of the original number. The number of remaining active
 2  2
1 1
nuclei is, therefore, 6.0 × 1018 ×   ×   = 1.5 × 1018
 2  2
12. One solid sphere, having mass 1kg & diameter 0.3m is suspended from a wire. If the twisting
couple per unit twist for the wire is 6 × 10–3 N-m/radian, then the time period of small oscillations
will be:
(A) 0.7 sec
(B) 7.7 sec
(C) 77 sec
(D) 777 sec
Ans. B
I
Sol. T = 2 ......(1)
C
2
= MR2 ......(2)
5
By equation (1) & (2)
2 MR 2
T = 2
5C
given, M = 1kg
R = 0.15 m
C = 6 × 10–3 N-m/rad.
T=?
0.4  1 (0.15) 2
 T = 6.28
6  10 3
9  10 3
T = 6.28 = 6.28 × 1.5
6  10 3
T = 7.7 sec.
13. Find the constant b in Moseley’s equation  = a (Z – b) from the following data.
Element Z Wavelength of KaX-ray
Mo 42 71 pm
Co 27 178.5 pm
(A) 1.43
(B) 1.11
(C) 1
(D) 1.37
Ans. D
Sol. Moseley’s equation is

 = a (Z – b).
c
Thus = a(Z1 – b) …(i)
1
c
and = a (Z2 – b) …(ii)
2
Using equations (i) and (ii), we get
 1 1 
c   = a (Z1 – Z2)
   2 
 1
c  1 1 
 a=  
 
( Z1  Z 2 )  2 
 1
Putting given values
a = 5.06 × 107 Hz
Dividing equation (i) by (ii), we get
2 Z b
= 1
1 Z2  b
178.5 42  b
  =
71 27  b
  b = 1.37
14. A 70 cm long sonometer wire is in unison with a tuning fork. If the length of the wire is decreased
by 1.0 cm, it produces 4 beats per sec. with the same tuning fork. Find the frequency of the tuning
fork -
1
(A) 276 sec
1
(B) 272 sec
1
(C) 269 sec
1
(D) 280 sec
Ans. A
Sol. Let the frequency of the fork be n. In the first case, the length of the wire is 70 cm (0.70 m).
Therefore,
1 T
n= ...(1)
2  0.70 m
On decreasing the length of the wire, its frequency will increase. Hence in the second case when
the length is 69 cm = 0.69 m, then
1 T
n+4= ...(2)
2  0.69 m
dividing equation (1) by (2), we get
n 0.69
 
n 4 0.70
n × 0.70 = (n + 4) × 0.69
4  0.69
n = = 276 sec–1
0.01
15. Mr. Sanjay wants to calculate the current and power dissipated in an LCR series circuit. He connected
100W resistance to an AC source of 200 V and angular frequency 300 radian/sec. When he removed
only the capacitance, the current was found to be lagging behind the voltage by 60°. While on
removing the inductance he found, the current leading the voltage by 60°. Find the value of current
and the power dissipated obtained by him
(A) 200 Watt
(B) 100 Watt
(C) 400 Watt
(D) 300 Watt
Ans. A
L 1 / C
Sol. tan 60º = , tan 60º = .
R R
1
L = .
C
 impedance of the circuit,
1
 2
 1  2
Z =  R 2   L    = R.
  C  
Current in the circuit,
V V 200
i0 = 0 = 0 = = 2 ampere.
Z R 100
1
Average power, P = V0 i0 cos .
2
 L  1 / C
But tan = = 0, cos = 1.
R
1
 P = × 200 × 2 × 1 = 200
2
16. The length of a wire between the two ends of a sonometer is 105 cm. Where the two bridges
should be placed so that the fundamental frequencies of the three segments are in the ratio of
1:3:15.
(A) 75 cm, 25 cm,
(B) 25 cm, 75 cm,
(C) 75 cm, 100 cm,
(D) None of these
Ans. C
Sol. From the law of length of stretched string, we have n11 = n22 = n33
Here n1 : n2 : n3 = 1 : 3 : 15
 n 3 1 n 3
 1  1 = and  = 15/1
2 n2 1  3 n1
 
 2  1 and  3  1
3 15
The total length of the wire is 105 cm.
Therefore 1 + 2 + 3 = 105
1 1 21 1
or 1 + + = 105 or = 105
3 15 15
105  15
1 = = 75 cm.
21
 75
 2 = 1 = = 25 cm
3 3
 75
3 = 1 = = 5 cm
15 15
Hence the bridge should be placed at 75 cm and (75 + 25) = 100 cm from one end.
17. In an LR circuit as shown in fig. when the switch is closed how much L R

time will it take the current to grow a value (where  < 1)
R
S e
1
(A) (L/R) In

1
(B) (L/R) In
1 
1
(C) (2L/R) In

(D) None of these
Ans. B
Sol. We know that


i= (1– e t/)
R

i =  (given)
R
 
n = (1 – e–t /)
R R
or e–t/= 1– 
1
or t =  In
1 
18. An infinite number of charges each equal to q are placed along the x-axis at x = 1, x = 2, x = 4,
x = 8 ...... and so on. Find the electric field at the point x = 0 due to this set of charges.
1 2 
(A) q
40  3 
1 8 
(B) q
40  3 
1 4 
(C) q
40  3 
1 5 
(D) q
40  3 
Ans. C
Sol. As potential V and intensity E due to a point charge at position x are respectively given by-
q q q q q
x=01 2 4 8 16
1 q q q 
E=    ...
40 12 2 2 4 2 
q  1 1 1 
= 1   ....
40  4 16 64 
i.e.,
q 1 1 4 
E= = q
40 [1  (1 / 4)] 40  3 
6 2
19. A large plane charge sheet having surface charge density   2.0  10 C/m lies in the X-Y
plane. Find the flux of the electric field through a circular area of radius 1 cm lying completely in
the region where x, y, z are all positive and with its normal making an angle of 60° with the Z-axis.
2
(A) 15 N- m /C
2
(B) 12.5 N- m /C
2
(C) 17.5 N- m /C
(D) None of these
Ans. C
Sol. The electric field near the plane charge sheet is E = /20 in the direction away from the sheet. At
the given area, the field is along the Z-axis.
The area = r2 = 3.14 × 1 cm 2
= 3.14 × 10–4 m2.
The angle between the normal to the area and the field is 60º.
 
Hence, the flux = E . S = ES cos

= pr2 cos 60º
2 0
2.0  10 6 C / m 2
= ×
2  8.85  10 12 C 2 / N  m 2
1
(3.14 × 10–4m2)
2
= 17.5 N-m2/C
20. Seven capacitors each of capacitance 2 mF are to be connected in a configuration to obtain an

effective capacitance of 10/11 mF . Which of the combination(s) shown in figure will achieve the
desired result?
(A) (B)
(C) (D)
Ans. A
SECTION – B
(Numerical Answer Type)
This section contains 10 questions. The answer to each question is a NUMERICAL VALUE. For each
question, enter the correct numerical value (in decimal notation, truncated/rounded-off to the second
decimal place; e.g. XXXXX.XX).
21. A point charge is placed outside a spherical shell as shown in the figure.
Find the electric potential (in kilo volt) on the surface of shell R
 
(Take: q=1μc and R=50cm ) q
2R
Ans. 00009.00
Sol. Field inside the shell is zero, so potential is uniform

kq
V= =9 kilo volts
2R
22. A spring block system is placed on a horizontal rough surface 4

as shown in the figure. The block is given velocity when the V= 10m/s
5
spring is in natural length. The total distance travelled by the k=50 N/m
2 5kg
block before it finally comes to rest is meters. Find the
k
value of k  =3/5
Ans. 00005.00
2
3 1 1 4
Sol.  50  x    50 x 2   0   5  10 
5 2  2 5 
2
25x 2  30 x  16  0  x= meters
5
2 3
So at maximum compression spring force =50   =20N and friction force =  50   30 N .
5 5
Hence the block will not move so distance  2 / 5m .
23. A small spherical ball of density same as that of liquid is released

from rest in a vessel filled completely with a liquid and accelerating
with acceleration 5iˆ  5 ˆj m / s as shown in the figure. Find the y
initial acceleration of ball just after the release with respect to
x
vessel.

Ans. 00000.00
24. A ball is projected from the point O with velocity 20 m/s at an

20m/s A
angle of 60° with horizontal as shown in figure. At highest point
of its trajectory it strikes a smooth plane of inclination 30° at
point A. The collision is perfectly inelastic. The maximum height 60º 30º
75 O
from the ground attained by the ball is meter . Find the value
k
of k ? (g = 10 m/s2)
Ans. 00004.00
25. In the figure shown, pulley and spring are ideal and strings are light and
inextensible. Initially all the bodies are at rest when string connecting A and B is
cut. Find initial acceleration of C.
m A
C 2m
m B
Ans. 00000.00
26. A small ball of mass M=1kg is attached to two identical springs of constant
10 0N/m , which are attached to floor and roof. The springs are initially 1m
unstretched. By what distance ball comes down to attain equilibrium? (in cm) M
Ans. 00005.00
27. In YDSE, when a glass plate of refractive index 1.5 of thickness t is placed in the path of one of
the interfering beams of wavelength , intensity at the position where central maximum occurred
previously remain unchanged. If the minimum thickness of the glass plate is k  . Find the value
of k ….
Ans. 00002.00
Sol. t   1    t 1.5  1    t = 2
28. If the ionization potential of hydrogen atom is 13.6 eV , the energy required to remove from the
third orbit of hydrogen atom is k/2eV . Find the value of k …..
Ans. 00003.00
Sol. Energy required removing the electron from the third orbit
13.6
 2
eV  1.5 eV = 1.5  1.6  10–19J = 3 eV
3
29. When an object is at a distance 3meters and 1meters from the optical centre of a convex lens,
a real and virtual images are formed respectively, with the same magnification. Find the focal
length of the lens (in meters)
Ans. 00002.00
f f u1  u2
Sol.    u 2  f  u1  f  f  2
 u1  f  u 2  f  2
30. A man observes a coin placed at the bottom of a beaker which 1.2 3.6cm
contains two immiscible liquids of refractive indices 1.2 and 1.4 as 1.4
shown in the figure. Find the depth of the coin below the surface, as 7cm
observed from above. coin
Ans. 00008.00
3.6 7
Sol. d  8
1.2 1.4
Chemistry PART – B
SECTION – A
31. In which of the following reactions tertiary butyl benzene is formed?
(A) (B)
+Me3C-OH+BF3 +Me 2 C=CH 2 +H 2SO 4
(C) (D) All of these

+Me 2 CH-CH 2 Cl+AlCl 3
Ans. D
32. In equilibrium:

  Fe  SCN  2    aq 
SCN  aq   Fe 3  aq  
 
colourless yellow
If thiocyanate ions are added in equilibrium mixture
(A) The solution becomes colourless
(B) The yellow colour of solution deepens.
(C) The red colour of the solution deepens.
2
(D) Concentration of  Fe  SCN   ion will decrease.
Ans. C
33.  i  BH 3  THF
 ii  H 2O2 /OH 
CH3
(A) (B)
CH3 H OH
OH CH3 H
(C) (D) OH
CH3 H
CH3
H
OH OH
Ans. B
Sol. Anti-markownikoff addition of H2O and syn-mechanism
34. Which of the following is incorrect?
(A) The heats of hydration of the dipositive alkaline earth metal ions decrease with an
increase in their ionic size
(B) NaNO3 forms Na2O2 on heating
(C) Hydration of alkali metal ion is less than that of IIA group
(D) Alkaline earth metal ions, because of their much larger charge to size ratio, exert a much
stronger electrostatic attraction on the oxygen of water molecule surrounding them.
Ans. B
35. Referring to figure, identify the three spots obtained by electrophoresis at p H  7 of a mixture of
the proteins pepsin p I
 1.1 haemoglobin  p I  6.8  and Lysozyme  p I  11.0  :
Start
 +  electrode     - electrode
A B C
Which of the following options are correct about position of various proteins?
(A) Lysozyme will be present at spot A
(B) pepsin will be present at spot B
(C) pepsin will be present at spot A
(D) haemoglobin will be present at spot C
Ans. C
36. Which of the following is incorrect statement/reaction?
(A) N N
+ aq.HCl
+
N N Cl
H H H
(B)
is less basic than
N N
H
(C) N
N
purine has 3 N's as basic sites
N N
H
(D) E
+ E
E +
N N
H N
H H  very minor product 
 major product 
Ans. A
37. Which of the following statement about diffusion of gas is true?
(A) Rate of diffusion of a gas will increase if an inert gas is added to gaseous mixture and
allowed to diffuse through a pin hole
(B) Rate of effusion of O2 is 2 times that of SO 2 , for every composition of O2 and SO 2

mixture
(C) Rate of effusion decrease on increasing the temperature
(D) All are true
Ans. C
1
Sol. Rate of effusion 
T
38. Which of the following carboxylic acid could be resolved by reaction with an enantiomerically pure
chiral amine?
(A) COOH (B) NO 2 COOH

NO 2
HOOC NO 2
O 2N
COOH
(C) NO2 HOOC (D) COOH
COOH O 2N NO 2
Ans C
Sol. NO2 HOOC
is optically active
COOH O 2N
39. 2, 7-Octanedione on treatment with aq. KOH and 100°C produces?
(A) O (B) O
(C) O (D) O
Ans. B
40. The compound which gives Carbylamine reaction.
(A) H3C (B) H3C

NH
H2N CH3 CH3
(C) NO2 (D) H3C

NH2
O
Ans. A
Sol. Primary amines give Carbylamine test.
41. Which of the following combinations are correct for a binary solution, in which the solute and
solvent are liquid?
(A) C6 H 6 and C6 H 5CH 3 ; ΔH sol >ΔVsol =0
(B) O
H3C C CH3 and CHCl ;ΔH <0;ΔV <0

3 sol sol
(C) H 2 O and HCl; ΔH sol >0;ΔVsol <0
(D) H 2 O and C2 H 5OH; ΔH sol <0; ΔVsol >0
Ans. B
3 3
42. Crystal field splitting energy   0  of complexes CrCl6  3 , Cr  CN 6  and Cr  NH 3 6 
are x, y and z cm1 respectively. Then correct order 0 values is:
(A) x yz
(B) xz y
(C) x yz
(D) xz y
Ans. B
43. Optical isomerism is not shown by the complex:
3
(A) Cr  ox 3 

(B) Cis Co  en  2 Cl2 

(C) Trans Co  en  2 Cl2 
3
(D) Cr  en 3 
Ans. C
44. Consider the following sequence of reaction:

ΔH 5
H 4 H1 H 2 H 3
X    X    X    X 2   X 3
ΔH 6
If electronic configuration of element X is  Ne 3s1 , then which of the following order is incorrect
regarding given enthalpies?
(A) ΔH 4 = ΔH5
(B) ΔH 2 > ΔH1
(C) ΔH 2 > ΔH3
(D) ΔH1 = ΔH 6
Ans. C
Sol. When a reaction is reversed, magnitude of enthalpy change remains same.
45. Which of the following does not represent the correct sequence of property indicated?
(A) Sc3+ > Cr3+ > Fe3+ > Mn3+ - Stability of +3 ions
(B) Sc < Ti < Cr < Mn – number of oxidation states
(C) Mn2+ < Ni2+ < CO2+ < Fe2+ - Magnetic moment
(D) FeO > CoO > NiO > CuO – Basic nature
Ans. C
Sol. Magnetic moment sequence is Mn2+ (3d5) > Fe2+ (3d6) > Co2+ (3d7) > Ni2+ (3d8)]
46. Which plot is the adsorption isobar for chemisorption?
(A) (B)
x x
m m
T T
(C) (D)
x x
m m
T T
Ans. C
Sol. Chemisorption increases with increase in temperature initially and then decreases.
47. Which of the following reaction is non-redox?
(A) 2NaNO 3 
 2NaNO 2 +O 2
(B) KCl+NaNO 3 
 KNO 3 +NaCl
(C) Fe+H 2SO 4 

 FeSO 4 +H 2
-
(D) 4Ag+8CN - +O 2 +H 2 O 
 4  Ag  CN  2  +4OH -
Ans. B
Sol. Oxidation state of all species remain unchanged so it is not redox
48. Find the correct order of reactivity of carbonyl groups with LiAlH 4 :
O O
RO C
 D
A
C
CHO
 BCOCl
(A) A>B>C>D
(B) B>C>D>A
(C) D>C>B>A
(D) B>D>C>A
Ans. B
Sol. Reactivity of carbonyl compounds follow the order acid chlorides > aldehydes > ketones > ester
49. Product of reaction is:

+
OH N NCl 
+ OH
 
-
OCH3
(A) OH (B)
N N
H3OC
OCH3
(C) OH (D)
N N N N
HO
OCH3
Ans. C
Sol. OH  Converts phenol to phenoxide ion which is strongly activating so attack occurs at ortho
position w.r.t. hydroxyl group
50. A sulphide of a metal M with formula MS is white coloured ppt which is soluble in acidic
solution  pH<6  . Metal cation M is:
(A) Pb 2
(B) Zn 2
(C) Hg 2+
(D) Cu 2
Ans. B
Sol. ZnS is white coloured ppt which is soluble in acidic solution below pH=6
SECTION – B
X+Y+Z
51. Calculate value of , here X is O  N  O bond angle in NO3 Y is O  N  O bond
10

angle in NO2 and Z is F  Xe  F adjacent bond angle in XeF4 .
Ans. 00039.00
Sol. X=120 (sp2-hybridization)

Y=180 (sp-hybridization)
3 2
Z=90 (sp d -hybridization)
120  180  90 390
  39
10 10
n
52. The overall charge present on the cyclic silicate anion Si 6 O18   is___
Ans. 00012.00
2
Sol. Given silicate anion is  SiO3  
 6
 n  12
3
53. How many of the following molecules or ions have sp d hybridisation of their central atom ?
I3 ,SbF6 ,F3 ,ClO3 , XeO 2F2 , XeO 64  ,SF4
Ans. 00003.00
Sol. I3 , XeO2F2 ,SF4
54. For the reactions

k
 i  A  P
I
K
 ii  B   Q,following observation is made
II
2M 2M
Concentration Concentration
1M 1M
0.5M  A  B
30 60 30
Time  min  Time  min 
kI
Calculate , where k I and k II and rate constant for the respective reaction:
K II
Ans. 00000.69
55. One mole of a real gas is subjected to a process from (2 bar, 30 L, 300 K) to (2 bar, 40 L, 500 K).
The molar heat capacity of gas at constant pressure is 40J/K mol. What is the change in internal
energy (in kJ) of the gas in this process?
Ans. 00006.00
56. A saturated solution of silver benzoate, AgOCOC6 H 5 , has pH of 8.6 Ka for benzoic acid is
5.0×105 . The value of K sp for silver benzoate is x 103 . Then the value of x is?
 log 2  0.3
Ans. 00006.40
57. P4 +HNO 3   H 3 PO 4 +NO 2   H 2 O

Product mixture is titrated with 0.1M NaOH , indicator shows colour change at second end
point and 100ml of NaOH is used for that. How much volume (in mL) of 1M HNO3 is used
is above reaction?
Ans. 00025.00
Sol. P4  20 HNO3 
 4 H 3 PO4  20 NO2  4 H 2O
100  0.1
m. moles of NaOH  2  m. moles of H 3 PO4  m. moles H 3 PO4  5
2
20
m. moles of HNO3   5  25
4
Volume of HNO3  25 ml
58. Potassium crystallizes in BCC lattice with a unit cell length a  5.0 Å . What is the distance
(in Å ) between next nearest neighbours?
Ans. 00005.00
59. The dissociation constant of a weak acid is 1.6×105 and molar conductivity at infinite dilution is
380  104 Sm 2 mol1 . If the cell constant is 0.01m1 the conductance (in S ) of 0.01M acid
solution is____
Ans. 00001.52
Ka 1.6  105
Sol.  
C 0.01
K×1000
λ m =αλ °m = when λ m is in Scm 2 mol-1
molarity
K
G=
cell constant
60. For 3s orbital of hydrogen atom, the normalised wave function is

3/ 2 r
1  1   18r 2r 2  3 a0
 3s     27   2 e
81 3  a0   a0 a0 
d
If distance between the radial nodes is d, calculate the value of
1.73a0
Ans. 00003.00
SECTION – A
3x2  4 x  1
61.  2
dx is equal to:
x 2
 1 x 1
x 1
(A) 2
c
x 1
2 x 1
(B)  c
x2  1
2
(C)
 x  1 x  1
2
x
(D) c
 x 2  1 x  1
Ans. B
3x2  4 x  1
Sol.  2
dx
x 2
 1 x 1
4 x2  4 x  x 2  1
 2
dx
 x 2  1 x 1
x  x  1 dx dx
 4 
x 2
 1
2
x 1  x  1 x  1
2
x  x  1 dx 
 2 x  1 1 2 x.2 x  1 
4 2
. 2  x 2  1 2 .dx 
 x2  1 x  1  x  1   
x  x  1 dx 2 x 1
 4 2
 2
 x 2  1 x  1 x  1
2 x  1
 c
x2 1
62. The general solution of the differential y xy  x  y  2 2 2

  dx   y  x  x  y   dy
3 2 2 2
is:
y 1
(A)  2 c
x x  y2
x 1 x y
(B)  ln c
y 2 x y
2x 1
(C)  2 c
y x  y2
2x 1
(D)  2 c
y x  y2
Ans. C
Sol.  2
 
y xy   x 2  y 2  .dx  y 3  x  x 2  y 2  dy
2

2 2
 xy 2 dx  y  x 2  y 2  dx  y 3dy  x  x 2  y 2  dy
2
 y 2  xdx  ydy    x 2  y 2   ydx  xdy 
2  ydx  xdy 
 xdx  ydy   x 2  y 2 
y2
2  xdx  ydy  2  ydx  xdy 

2 2 y2
x  y 
2
d x  y  2 2
x
 x  y  2 d  y 
2 2
 2

1 2x
22
 C
x y y
2x 1
  2 C
y x  y2
63. In how many ways can the letters of the word ARRANGE be arranged so that the two A’s are
always together and two R’s are never together.
(A) 240
(B) 260
(C) 300
(D) 340
Ans. A
64. The equation of a circle whose diameter is the common chord of the circle
x 2  y 2  4 x  8 y  5  0 and x 2  y 2  12 x  2 y  29  0 is:
(A) 41x 2  41 y 2  396 x  38 y  781  0
(B) 2 x 2  2 y 2  16 x  6 y  25  0
(C) 41x 2  41 y 2  396 x  38 y  781  0
(D) 17 x 2  17 y 2  300 x  154 y  901  0
Ans. A
Sol. C :  x 2 y 2  4 x  8 y  5     x 2  y 2  12 x  2 y  29   0
 2  6 4   
Centre :  , 
 1  1  
Common chord 4 x  5 y  17  0
Centre lies on common chord
29
 
12
 1  6  29 / 12  4  29 / 12 
 centre  , 
 1  29 / 12 1  29 / 12 
 198 19 
 centre  , 
 41 41 
11
3
65.  0
1  cos 2 x dx is equal to:
11 3
(A)
2
3
(B) 8 2
2
3
(C) 8 2
2
22
(D)
3
Ans. B
11
3
Sol.  0
1  cos 2 x .dx
11
3
 2 cos x .dx
0
3 3  2 /3
 2 cos x .dx   2 cos x dx
0 3
 2  /3
3 2  cos x .dx  2  cos x .dx
0 0
 /2  /2 2 /3
 6 2
0
 cos x  dx  2
0
cos x.dx  2 
 /2
cos x.dx
 3
6 2 2  2
2
3
 2
2
 
66. Consider the vectors a  2iˆ  ˆj  2kˆ and b  3iˆ  ˆj  kˆ . A parallelogram is constructed such
   
that its diagonal are along 2a  b and a  2b . The area of the parallelogram is:
(A) 9 5 sq. units
9 10
(B) sq. units
2
(C) 9 10 sq. units
(D) 18 5 sq. units
Ans. B
 
Sol. 2a  b  iˆ  3 ˆj  5kˆ
 
a  2b  4iˆ  4 ˆj  4kˆ
1    
Area of 
2

2a  b  a  2b   
   
   
2a  b  a  2b  3iˆ  24 ˆj  15kˆ
9 10
Area 
2
π  π  π 
tan  +α  tan  +β  tan  +γ 
67. Let 4  4   4  .Then 12 sin 2  α-β   15sin 2  β-γ   7 sin 2  γ-α  is
5 3 2
equal to?
1
(A) 
2
1
(B)
2
(C) 1
(D) 0
Ans. D
Sol. Taking first two

tan  / 4    5

tan  / 4    3
cos     8
  4
sin     2
 cos      4 sin            1
Similarly
cos       sin             2 
3cos       7 sin            3 
After marking sin 2 terms
1   2    3
Then,
12 sin 2      15sin 2       7 sin       0
cos x 1 2
68. The angle of intersection of the curves y  1  x   sin x and y=
2
 x +x+2 at  h,k 
where h and k are integers, is  , then tan  equals:
3
(A)
4
4
(B)
3
(C) 1
(D) 0
Ans. A
Sol. At x  0, y  1 for both curves intersect

cos x
Now y  1  x   sin x
dy
  2 at x  0
dx
1 2
And y   x  x  2 
2
dy 1
 at x  0
dx 2
1
Now m1  2, m2 
2
2  1/ 2 3/ 2 3
 tan    
1   2 1 / 2  2 4
69. A plane 2 x  3 y  6 z  12 intersects the x-axis, y-axis and z-axis at A, B, C respectively. The
orthocentre of the triangle ABC is:
 24 36 72 
(A)  , , 
 49 49 49 
 36 72 27 
(B)  , , 
 49 49 49 
 24 16 1 
(C)  , , 
 49 49 49 
 36 72 24 
(D)  , , 
 49 49 49 
Ans. A
Sol. Now AH  BC
r
Now D of AH    6,  ,  
A  6,0,0 
H  ,  ,  

B  0,4,0  C  0,0,2 
r
D of BC   0, 4, 2 
Now for 1 lines,
a1a2  b1b2  c1c2  0
 0   6     4   2  0
 4  2  0
2       1
Similarly
6  2  0       2 
6  4   0       3 
2
 2   ; 
3
Now may lie on
2 x  3 y  6 z  12
 2  3  6  12
 2 
2   3  6  2   12
 3 
4  9  36  36
49  36
36

49
24 72
Now,   and  
49 49
24 36 72
 ,  ,     , , 
 49 49 49 
    x 1
70. The domain of the function given by f  x  = log 3  log 1  log 2  log 1  x      is:
  
 2   3    1  3x  4 x 2
 1
(A)  1, 
 3
1 1
(B)  , 
 4 3
1 1
(C)  , 
9 4
1 1
(D)  , 
9 3
Ans. C
Sol. 
f  x   log 3 log1/2  log 2  log1/3   
x 1
1  3x  4 x 2
Now, 1  3x  4 x2  0
4 x 2  3x  1  0
  4 x  1 x  1  0
 x    1,1 / 4 
 
log1/ 2 log 2  log1/3  x    0
log 2  log1/3  x    1
log1/3  x   2
x  1/ 9
1
NowF  f  x    x   x   1,1/ 4 
9
1 1
x , 
9 4
71. Let  and  be the roots of the equation x 2  13 x  5  0 . If S n   n    n ; n   , then the

S  13S12
value of 13 is equal to___
S11
(A) 13
(B) 13
(C) 5
(D) 5
Ans. C
S13  13S12
Sol.
S11
 13    13       13    12 

 11    11
 
5
 n
1  2 3 
72. The value of cot  cot
n 1
 n2

k
k 1


1
(A)
2
1
(B)
4
1
(C)
3
1
(D)
6
Ans. C
2

1
cot  cot 2  n 2 1  n  1
Sol.
n 1 n 2

2
 cot  tan 1 2
n 1  n  1

 cot   tan 1  n  2   tan 1 n 
h 1
 tan 1 3  tan 1 1 
 1 
sn   tan 4  tan 1 2 
 tan 1  n  2   tan 1 n 
 
 3n 2  7n 
sn  tan 1  2 
 n  9n  10 
s  tan 13
1 1
cot tan 13  cot cot 1 
3 3
73. The graph of the function y  f  x  has a unique tangent at  , 0  . If

a
ln 1  9 f  x    sin f  x  
n
A  lima
x  2 f  x
, then A
n 1
is equal to:
1
(A)
3
1
(B)
2
(C) 4
1
(D)
4
Ans. A
 1 
  9 f '  x   cos  f  x   f '  x 
1  9 f  x  
Sol. lim a
x  2 f ' x
9 1
 4
2

1 1
 4 n   2  ......
h 1 4 4
1

3
74. Let ar ' r  1, 2,3, 4 represent four positive real numbers other than unity such that
 1 
 log e ar ,  is a point on a circle whose abscissa of end of diameter are  and  ,
 log e , ar 
then the minimum value of a1  a2  a3  a4 is:
(A) 2
(B) 3
(C) 4
(D) 5
Ans. C
Sol. Centre  0,  f 
Equation of circle
x 2  y 2  2 fy  c  0
2 1  1 
 log a 
e r  2
2f  c  0
 log a 
e r  log e ar 
4 2
 log ar   c  log ar   2 f  log ar   0
log a1 , log a2 , log a3 , log a4 are roots of equation
 log  a1.a2 .a3 .a4   0

a1a2 a3 a4  1
a1  a2  a3  a4 1/4
 1
4
 a1  a2  a3  a4  4
75. The chord of contact of tangents drawn from any point on the circle x 2  y 2  p 2 to the circle
x 2  y 2  q 2 touches the circle x 2  y 2  r 2 , then 2a  log e p, 4a  log e q, 6a  log e r are in (a
is real value):
(A) AP
(B) GP
(C) HP
(D) AGP
Ans. A
Sol.  distance from (centre) to chord of contact

p cos   0  p sin   0  q 2
r
p
 0, 0 
r

p cos  , p sin 
chord of contact
p cos  x  p sin  y  q 2
q 2  rp
p, q, r areinGP
2a  log ep , 4a  log qe , 6 a  log er are in AP
76. If t1 ,t2 and t3 are distinct, the points  t1 , 2at1  at13  ,  t2 , 2at2  at23  and  t3 , 2at3  at33  are
4t1.6t2 .8t3
collinear, then is equal to:
2t1.3t2 .4t3
(A) 0
(B) 4
(C) 2
(D) 1
Ans. D
Sol. G.E. of line

Ax  By  C  0
At1  B  2at1  at13   c  0
Bat13   2aB  A  t1  c  0
Sum of roots
t1  t2  t3  0
2t1.2t2 .2t3  2  1
77. The area of the triangle formed by the linex  y  2 and angle bisectors of the pair of straight
2 2
lines x  y  2 y  1 is a and coordinate of orthocentre of triangle is  b , c  , then 4a  b  c is
equal to:
(A) 0
(B) 4
(C) 2
(D) 3
Ans. D
Sol. x2  y 2  2 y 1  0
2
x 2   y  1  0
 0, 2
1,1
 
 0,1
 2, 0 
 x  y  1 x  y  1  0
Angle bisector
x  y 1 x  y 1

2 2
x  y 1  x  y  1
x  y 1   x  y 1
 y 1  x  0
1 1
Area a   1 1 
2 2
Orthocentre  0,1  b  0, c  1
 4a  b  c  2  0  1  3
th z4 z z2 z4
78. If z is the complex 5 root of unity, then    is:
z4 1 1 z z2 1 z  z 4
(A) 2
(B) 0
(C) 4
(D) 1
Ans. A
Sol. z5  1
z5 z z2 z5
  
z5  z z  1 z 2  1 z 2  z5
1 z z2 1
   2  2
1 z 1 z z 1 z 1
 11  2
x 2 y2
79. If a tangent of slope 3 of the ellipse +  1 is normal to the circle x 2  y 2  4 x  1  0 then
a 2 b2
the maximum value of ab is:
(A) 2
(B) 3
(C) 4
(D) 6
Ans. D
2 2
Sol. Equation of tangent y  3 x  9a  b
This is normal to circle
x2  y2  4x  1  0
Panes – 1 brought  2, 0 
 0  6  9a 2  b 2
36  9a 2  b2
AM  GM
9a 2  b 2
 9 a 2b 2
2
18  3ab
6  ab
x
80. If F  x    f  t  .dt    x 1+x  , then value of f  4   n .
and F x
2 2
Then unit place of
0
n2
 985697  is:
(A) 3
(B) 7
(C) 1
(D) 9
Ans. C
x
Sol. F  x  =  f  t dt
0
x2
F  x 2  =  f  t dt
0
2
 x 1  x 
Diff. both side
F '  x 2  .2 x  2 x  3x 2
3
f  x 2  =1+ x
2
x=2, f  4  =1+3x/2
3
x=2, f  4  =1+ ×2=4
2
16
Unit place  985697   1
SECTION – B
81. A nine digit number is formed from 1, 2,3, 4,5 such that product of all digits is always 1920 . The
total number of ways is 393  P  , where the value of r is________
9
r
Ans. 00002.00
9!
Sol. 1920  5  3  27  5  3  2  2  2  2  2  2  2   98
7!
9!
1920  5  3  4  2  2  2  2  2 1   98 7  6
5!
1920  3,5, 4, 4, 2, 2, 2,1,1

9!
2!2!3!
3,5, 4, 4, 4, 2,1,1,1
9!
3!3!
9! 9! 9! 9!
Total =   
7! 5! 2!2!3! 3!3!
9!
 1  42  210  140 
7!
=393 9 P2
5m
82. The sum   
i 0
20
i
30
5 m i , p
Cq   qp   0 if p  q , is maximum, then m equals________
Ans. 00005.00
Sol. 20c0  30c5 m  20c1  30c5 m 1

......  20c5 m  30c0
5m 20 30
Coeff of x  1  x  1  x 
50
50c5m ,5m   25
2
m5
83. Let f  x  be a function such that f  x   f  x  2   3 f  x  1 for all x  R, then f is

periodic with period T. Then value of T is_______
Ans. 00012.00
Sol. f  x   f  x  2   3 f  x  1
x  x  2       1
f  x  2   f  x  14   3 f  x  3        2 
1   2 
f  x   2   x  2   f  x  14 
 3  f  x  1  f  x  3
 3 f  x  2
f  x   f  x  4   f  x  2
x  x  2       3
f  x  2   f  x  16   f  x  4      4 
 3   4 
f  x  f  x  6  0
f  x  6   f  x 
f  x  12    f  x  6 
 f  x
Period T  12
84. If the sum of first n terms of the A. P. 85,90,95,.... is equal to the sum of first 3n terms of the A.
P. 9,11,13,..., then n  10 equals_____
Ans. 00019.00
4
85. Let f be a continuous and differentiable function in  a , b  , if f  x  . f '  x   x 1  f  x    and
2 1 2
lim  f  x    1 and lim  f  x    2 2
. Then the minimum value of  a  b   80 is
x a x b 2
.  represent greatest integer function  :
Ans. 00081.00
f  x f ' x
Sol. Given x
4
1   f  x 
2 f  x f ' x
 2  0
4
1   f  x 
2
Let g  x   sin 1  f  x    x 2 is non decreasing function
lim g  x   lim g  x 
x a  x b
 
 a 2   b2
2 6

a 2  b 2  ;  a 2  b 2   1
3
40
2 20
86. 
Let 1  x  x    ak x k . If  a11   a10   a9 , where  ,  ,    then the value of
k 0
 
is___

Ans. 00002.00
20 40
Sol. 20 1  x  x 2  1  2 x     kak x k 1 1  x  x 2 
k 1
Equating coeff. Of x 10 on both side

20  a10  2a9   11a11  10a10  9a9
 11a11  10a10  31a9
   31  11
  2
 10
87. If f  x  
3x 3 for all x  Q, then the value of  1   2   3   108  is.
1 x x
f  f   f    ....  f  
3 3  109   109   109   109 
Ans. 00002.00
1
Sol. f  x   f 1  x  
27
54
2
27
88. Let number of non-negative integral solutions of the inequality x  y  z  6 be m and number of
2n
natural solutions of the inequality x  y  z  t  10 be n, then find the value of is__
m
Ans. 00003.00
Sol. m= 9C3 n 9 C4
2n 2 9 C4 2  9! 6! 3! 2  6
 9   3
m C3 4! 5! 9! 4
89. Of the three independent events E1 ,E 2 and E3 , the probability that onlyE1 occurs is  , only E2
occurs is  and only E3 occurs is  . Let the probability p that none of events E1 ,E2 or E3 occurs
satisfy the equations ( -  )p=  and ( -3 )p=2 . All the given probabilities are assumed
to lie in the interval  0,1 .
Probability of occurrence of E1
Then 
Probability of occurrence of E 3
Ans. 00006.00
90. A line is drawn at an angle θ with positive direction of x-axis. It intersects the parabola
2
y  8 x at A and B. If AB is a normal chord which subtend a right angle at the vertex of the
2
parabola, then tan θ equals____
Ans. 00002.00
Sol. y 2  8x
Now, t1t2  4
2
And t2  t1 
t1
A

 at , 2at 
1
2
1
 0,0  

 at , 2at 
2
2 2
B
4 2
 t1 
t1 t1
 t12  2
 t12  2
y 2  4ax
dy 4ax

dx 2 y
dy 1

dx t
2
Slope of normal  t and tan   t12  2
FIITJEE
JEE (Advanced)-2022
FULL TEST – II
PAPER –1
TEST DATE: 04-01-2022
decimal places.
MARKING SCHEME
marking scheme:
correct option;
AITS-FT-II (Paper-1)-PCM-JEE(Advanced)/22 2
Physics PART – I

1. There is a very small hole in a totally enclosed heated furnace. Outside the furnace, the air
temperature is 0°C and the air pressure is 100kPa. The air inside the furnace is kept at a constant
temperature of 57°C by the controlled heating system, and after a sufficiently long time its
pressure also becomes stationary. Calculate (to the nearest integer) the magnitude of this
stationary pressure.
(A) 105kPa
(B) 120kPa
(C) 110kPa
(D) 124kPa
Ans. C
Sol. The number of molecules passing through a hole of cross-sectional area A during a time interval t
is AvNt, where v is the component, perpendicular to the wall, of the average molecular velocity,
and N is the number density (the number of particles in unit volume). At equilibrium no of
molecules going out should be equal to the number of molecules going in.
The square of the speed of the molecules (a measure of the internal energy of the gas) is
proportional to the gas temperature T, and, from the ideal gas equation, the number density is
proportional to the quotient of the pressure p and the tempera-ture.
2. A particle of charge q and mass m is projected with a velocity Magnetic field
v 0 towards a circular region having uniform magnetic field B × × ×

O
× × ×
perpendicular and into the plane of paper from point P as shown v0 × × ×
in the figure. R is the radius and O is the centre of the circular q,m P
region. If the line OP makes an angle  with the direction of v 0
then the value of v 0 so that particle passes through O is
qBR
(A)
m sin 
qBR
(B)
2m sin 
2qBR
(C)
m sin 
3qBR
(D)
2m sin 
3 AITS-FT-II (Paper-1)-PCM-JEE(Advanced)/22
Ans. B
A
3. A ray of light from a liquid    3  is incident on a system of Liquid
i  2
D
air
two right angled prism of refractive indices 3 and 2 as  3
shown. The ray suffers zero deviation when emerges into air from B
CD. The angle of incidence i is C
(A) 450
(B) 350
0
(C) 20
(D) 100
Ans. A
4. In Young's experiment, the interference pattern is found to have an intensity ratio between the
bright and dark fringes as 9. What is the ratio of intensities and amplitudes of the two interfering
waves, respectively?
(A) 4, 2
(B) 9,3
(C) 2.25,1.5
(D) None of these
Ans. A
Sol. In case of interference,

I = I1 + I2 + 2 I 1 I 2 cos 
  (a) for I to be maximum and minimum cos  is 1 and – 1 respectively, i.e.,
Imax = I1 + I2 + 2 I 1 I 2
= ( I1 + I 2 )2
and Imax = I1 + I2 – 2 I1I 2
= I1  I 2 2
According to given problem,

I max ( I1  I 2 ) 2 9
= 2
= ,
I min ( I1  I 2 ) 1
I1  I 2 3
i.e., =
I 2  I1 1
By componendo and dividendo,
I1 3 1
=
I2 3 1
I1 4
i.e., = =4
I2 1
(b) Now as for a wave I  A2,
2 2
I1 A  A 
=  1 ,  1 = 4
I2 A2  A2 
A1
i.e., =2
A2

1 F=kt
5. Two blocks A and B each of mass kg is connected by a B A
2
massless inextensible string and kept on horizontal k= 0.2 k= 0.2
surface. Coefficient of friction between block and surface is s= 0.2 s= 0.4
shown in figure. A force F  kt (where k = 1 N/s and t is
time in second) applied on A. Then (g = 10 m/s2)
(A) work done by friction force on block B is zero in time interval t = 0 to t = 3s.
(B) work done by friction force on block A is zero in time interval t = 0 to t = 3s.
(C) work done by tension on B is also zero in time interval t = 0 to t = 3s.
(D) speed of blocks at t = 10s is 27.5 m/s.
Ans. ABC
6. A particle starts SHM at time t  0. Its amplitude is A and angular frequency is . At time
E
t  0 its kinetic energy is , where E is total energy. Assuming potential energy to be zero at
4
mean position, the displacement-time equation of the particle can be written as
 
(A) x  A cos  t  
 6
 
(B) x  A sin t  
 3 
 2 
(C) x  A sin  t  
 3 
 
(D) x  A cos  t  
 6
Ans. ABCD
7. A 4 μF capacitor is given 20 μC charge and is connected with an 4F 2F

+–
uncharged capacitor of capacitance 2 μF as shown in figure. When switch 20C + –
+–
+–
S is closed. +–
+– C
S
10V
40
(A) charged flown through the battery is μC
3
20
(B) charge flown through the battery is μC
3
200
(C) work done by the battery is μJ
3
100
(D) work done by the battery is μJ
3
Ans. BC
8. A disc of radius R rolls on a horizontal surface with linear velocity V and P

angular velocity . There is a point P on circumference of disc at angle   
with upward vertical diameter measured anticlockwise (see figure), which V
O
has a vertical velocity. Here  is equal to
V
(A)   sin 1
R
 V
(B)  sin 1
2 R
V
(C)   cos 1
R
V
(D)   cos 1
R
Ans. CD
9. A source of sound moves along a circle of radius 2 m with constant angular S

velocity 40 rad/s. Frequency of the source is 300 Hz. A detector is kept at
some distance from the circle in the same plane of the circle (as shown in D
figure). Which of the following is not the possible value of frequency
registered by the detector? (Speed of sound = 320 m/s)
(A) 250 Hz
(B) 360 Hz
(C) 410 Hz
(D) 220 Hz
Ans. CD
10. An electron in H-atom jumps from second excited state to first excited state and then from first
excited to ground state. Let the ratio of wavelength, momentum and energy of photons emitted in
these two cases be a, b and c respectively. Then
1
(A) c
a
9
(B) a
4
5
(C) b
27
5
(D) c
27
Ans. ACD

INTEGER.
11. In a slow reaction, heat is being evolved at a rate about 10mW in a liquid. If the heat were being
32
generated by the decay of P , a radioactive isotope of phosphorus that has half-life of 14 days
32
and emits only beta-particles with a mean energy of 700KeV. The number of P atoms in the
liquid is A×77  1015 find a: [Take: ln 2 = 0.7]
Ans. 2
dn
Sol. P  700 103 1.6  10 19   10  10 3
dt
dN 101 1 1012
 14    λN 0
dt 10 7 16 11.2
ln 2 14  86400 1012
λ  N0   154  1015
14  86400 11.2ln 2
12. An old record player of 10 cm radius turns at 10 rad/s while mounted on
a 30° incline as shown in the figure. A particle of mass m can be placed
anywhere on the rotating record. If the least possible coefficient of 
friction  that must exist for no slipping to occur is  , find 2 3 .
30°
Ans. 6
Sol. f  mg sinθ  mrw 2
μ mg cosθ  mg sinθ  mrw 2

w 2r
or μ  tan θ 
g cosθ
  
13. Consider the circuit shown in figure. With switch S1 closed
  S  S 
and the other two switches open, the circuit has a time S1 2 3
constant 0.05 sec. With switch S2 closed and the other two L C R
switches open, the circuit has a time constant 2 sec. With
switch S3 closed and the other two switches open, the circuit
oscillates with a period T. Find T (in sec). (Take π 2  10 )
Ans. 2
Sol. τ1  RC
L
τ2 
R
 LC  t1t 2  0.1sec
 T  2π LC  2π 1/10  2sec
Question Stem
A two way switch S is used in the circuit shown in fig. First, the capacitor is charged by putting the
switch in position 1.
60V
+ – 10
1 0.1F
2 S 6
4
3
14. What is the heat generated across 4 resistor (in Joules)?
Ans. 120.00
15. What is the heat generated across 10 resistor (in Joules)?
Ans. 0.00
Sol. Initially the switch was in position 1. Therefore, initially potential difference across capacitors was
equal to emf of the battery i.e. 60 volt
 Initially energy stored in the capacitor was
1 1
U = CV2 = × 0.1× 602 J = 180 J
2 2
When switch is shifted to position 2, capacitor begins to discharge and energy stored in it is
dissipated in the form of heat across resistances. Let at some instant discharging current through
the capacitor be i as shown in fig.
+ –
i q
6
i1
i
4 i2
3
According to Kirchoff’s laws,
i1 + i2 = i …(1)
6i1–3i2 = 0 or i2 = 2i2 …(2)
From above two equations,
i 2
i1 = and i2 = i
3 3
But thermal power generated in a resistance R is P = i2 R where is current flowing through it.
Therefore, heat generated P1, P2 and P3 across 4, 6 and 3 resistances is in ratio
4i 2 : 6i12 : 3 i 22
2 4
or P1 : P2 : P3 = 4 : : = 6 : 1: 2
3 3
But total heat generated is
P1 + P2 + P 3 = U
 Heat generated across 4 is
P1 = 120 J Ans.
Heat generated across 6 is
P2 = 20 J Ans.
Heat generated across 3 is
P3 = 40 J Ans.
Since, during discharging, no current flows through 10, therefore heat generated across it is
equal to zero.
Question Stem
A choke coil is needed to operate an arc lamp at 160 V (rms) and 50 Hz. The arc lamp has an
effective of 5  when running at 10 A (rms). Compare the power losses in both cases.
16. Calculate the inductance of the choke coil (in H).
Ans. 0.05
17. If the same arc lamp is to be operated on 160V (dc), what additional resistance is required
(in )?
Ans. 11.00
Sol. Given that Vrms = 160 volt, f = 50 Hz.

R = Resistance of arc lamp = 5.
irms = 10 amp = current through arc lamp.
If L be inductance of required choke coil then impedance of the circuit is
Z= [ R 2  (2fL ) 2 ] = [ 25  (100L) 2 ]
Vrms
 current through arc lamp, irms =
Z
160
or 10 = or, 25 + (100 L)2 = (16)2 = 256 or, (100 L)2
2
25  (100L)
= 256 – 25 = 231
231
 L= Henry = 0.05 H
100
When the same arc lamp is to be operated on 160 volt DC source, then
160
= i = 10. (where R is the additional resistance required to run the lamp)
5 R
Solving, we get : R = 11 
Question Stem
A uniform rod of mass 8m lies on a smooth horizontal table. Two point masses m and 2m moving in the
same horizontal plane with speeds 2v and v (v = 10 m/s) respectively strike the bar as shown in Fig. and
stick to the bar after collision. C denotes the center of mass of the rod and the length of the rod is 6a,
where a = 1m.
2m
v 3a
C
2v
a 2a
m
18. What is the velocity of centre of mass just after collision (in m/s).
Ans. 0.00
19. What is the angular velocity of the system just after collision (in rad/s).
Ans. 2.00
Sol. Both the masses, 2m and m, after striking the bar give equal momentum each 2mv to the bar in
opposite directions. Hence, after collision the bar has no translational motion, i.e. the linear
velocity of the centre of mass of the bar is zero (v c = 0)-
When both the masses stick to the bar, the whole system rotates about the centre of mass C. As
there is no external torque acting on the system, the angular momentum is conserved.
Before collision (bar is stationary), there will be only the angular momentum of 2m and m about
C. Hence the initial angular momentum (see Fig.) is
Ji = 2mva + m (2v) 2a = 6 m v a.
(in an anticlockwise direction)
After collision, the bar and both the masses (2m and m) rotate with angular velocity about the
centre of mass C. The moment of inertia of the bar (mass 8m and length 6a) about C is
M 2 8 m (6 a ) 2
= = 24m a2, and the moments of inertia of 2m and m about C are 2ma2 and 4ma2
12 12
respectively. Hence, after collision the angular momentum of the system is
Jf = (24ma2 + 2ma2 + 4ma2)  = 30ma2
But Ji = Jf (conservation of angular momentum)
6 ma v v
= 2
=
30 ma 5a

20. The necessary condition for a compound to be optically active is:
(A) Presence of chiral carbon atom
(B) Presence of atleast one asymmetric atom
(C) Non-superimposable mirror image.
(D) Absence of plane of symmetry.
Ans. C
21. White phosphorus is a tetra atomic solid  P4  s   at room temperature and on strong heating in
absence of oxygen, it polymerizes into red phosphorus as:
P P P
P P P P P P H=-104KJ/mol of P4
P P P
White  g  red  g 
The enthalpy of sublimation  P4  s  
 P4  g   white is 59 KJ/mol and enthalpy of atomization
is 316.25 KJ/mol of P  g  . The average P  P bond enthalpy in P4 molecule is:
(A) 102 KJ
(B) 201KJ
(C) 104 KJ
(D) 120 KJ
Ans. B
22. Which of the following is weaker base?
(A) N  SiH 3 3
(B) N  CH 3  3
(C) NH  CH 3 3
(D) All are equally basic
Ans. A
Sol. Due to back bonding (A) is a weaker base.
23. Consider the reaction

B
k1
A
k2 C
2
The rate constant for two parallel reactions were found to be 10 dm3 mol 1 s 1 and
4  10 2 dm 3 mol 1s 1 . If the corresponding energies of activation of the parallel reaction are 100
and 120 kJ/mol respectively, what is the net energy of activation  Ea  of A?
(A) 100 kJ / mol
(B) 120 kJ / mol
(C) 116 kJ / mol
(D) 220 kJ / mol
Ans. C

24. Which of the following have transition metal?
(A) Haemoglobin
(B) Vitamin B12
(C) Cis – platin
(D) Chlorophyll
Ans. ABC
25. Which one of the following reactions is/are correct?
(A) CH 3COOK  CF3COOH 

 CH 3COOH  CF3COOK
(B) OH ONa
NO 2 NO 2 NO 2 NO 2
+ NaHCO3 + CO     H O
2 2
NO 2 NO2
(C)

+ NH4
+ + NH3
N N
N H N
(D)  CH 3CH 3ONa  H 2O  CO2   

CH 3CH 2OH  NaHCO3 
Ans. ABC
26. Which of the following carbanions are not resonance stabilized?
(A) O O (B)
O O
(C) (D)
 O
O O O
O 
Ans. BD
27. Which of the following statements are correct?
(A) The highest probability of finding an electron in 1 s orbital is exactly at the middle
between nucleus and circumference.
(B) In the Lyman series as the energy liberated during transition increases then distance
between the special lines goes on decreasing.
(C) The highest probability of finding an electron in 1 s orbital is in the vicinity of the
circumference.
(D) None of these
Ans. BC
28. Which of the following statements is / are correct?

(A) When lead nitrate is heated to at 400 C only brown gas is released.
(B) Complete Hydrolysis of PCl5 gives H3 PO 4 and HCl
(C) N 2O5 (g)+2NaOH(aq.)  2NaNO3  H 2O
(D) CCl 4 cannot be hydrolysed but hydrolysis of SiCl4 conform H 4SiO 4 +HCl
Ans. BCD
29. Which of the following statements is (are) correct?
(A) Antimony on reaction with conc. HNO3 gives antimonic acid.
(B) Manganese on reaction with cold and dilute HNO3 gives NO 2 gas.
(C) HNO 2 disproportionate to give HNO3 and NO
(D) HNO3 on reaction with P4 O10 gives N 2 O5
Ans. ACD

INTEGER.
30. O
C O t
NaOC2 H 5
CH 2   Cyclic Product,
Br  n Br C2 H 5OH
C O t
O
At what value of ' n ' the formation of six membered ring take place.
Ans. 3
Sol. O
Product:
31. Examine the structural formulas of compounds given below and identify number of compounds
which show positive iodoform test.
O
O O O O
, , , ,
H
O
O
O O O
C CH3 , , ,
Ph Ph
O
Ans. 6
Sol. These compounds will give iodoform test
O O O O O
, , , , C CH3
,
H
O
O O
,
Ph Ph
O
32. For oxyacid HClOx , if x  y  z ( x, y and z are natural numbers), then calculate the value
of x  y  z . Where x  Number of ‘O’ atoms.
y= Total number of lone pairs at central atom
z= Total number of pi  π  electrons in the oxyacid
Ans. 6
Sol. The compound is HClO2

Question Stem
The boiling point of water in a 0.1 molal silver nitrate solution (solution A) is x °C . To this solution A, an
equal volume of 0.1 molal aqueous barium chloride solution is added to make a new solution B. The
2
difference in the boiling points of water in the two solutions A and B is y×10 °C .
(Assume: Densities of the solutions A and B are the same as that of water and the soluble salts
dissociate completely.
Use: Molal elevation constant (Ebullioscopic Constant), K b = 0.5 K kg mol1 ; Boiling point of pure water
as 100C .)
33. The value of x is___
Ans. 100.10
34. The value of y is____.
Ans. 2.50
Question Stem
Hindsberg's
'A' white ppt  soluble in basic medium 
reagent
NaNO 2 +HCl
 0  5C 
 HF, O2 ,  H 2 O/H 
'B' 'C' 'D' 'E' 'F' + 'G'
 unstable  
  NaOH, I 2
 compound 
H+yellow ppt
H 2 O/H +
'I'  MW=60 
35. What is the degree of unsaturation in compound 'D' ?
Ans. 4.00
36. What is the molecular weight of compound 'A' ?
Ans. 59.00
Question Stem
Pb  OAc 2
Conc. HCl
'A' 'B'  gas  + Compound 'C'  soluble in hot water 
 black mineral  dil.H 2SO 4
 , air
white ppt
K 2 Cr2 O 7 solution
'D' + 'E'  pungent gas  Green solution.
NaOH
K 2 Cr2 O 7 /AcOH
'F' 'G'  yellow ppt 
excess NaOH
37. The number of p -d bonds in the structure of gas 'E' is____.
Ans. 1.00
38. The sum of oxidation numbers of two metals present in yellow ppt 'G' is_____.
Ans. 8.00

x2 y2
39. If the normals at four points  x1 , y1  ,  x2 , y2  ,  x3 , y3  and  x4 , y 4  on the ellipse 2  2  1
a b
are concurrent then  cos  . sec  is (where  ,  ,,  ,  are the eccentric angles of the
points):
(A) 1
(B) 2
(C) 3
(D) 4
Ans. D
 1
Sol. a 2
 b 2  x 4  2ha 2  a 2  b 2  x3  x 2  2a 4 h  a 2  b 2   a 6 h 2  0    x1      4
 x1 
2
40. Solution of differential equation f '  x  f '''  x   3  f ''  x   ,  y  f  x   is:
(A) x  k1 y 2  k2 y  k3
(B) y  k1 x 2  k2  k3
(C) x  sin y
(D) None of these
Ans. A
3 f ''  x  f '''  x 
Sol. 
f ' x f ''  x 
 3ln f '  x   ln f ''  x   k
d 2x
 c
dy 2
  lnx
1
41. f  x   e   x ln x
Where ever it is defined is:
0 otherwise

(A) not a periodic function
(B) even function
(C) range of f  x  contains more than 1 element
(D) None of these
Ans. B
1
  ln t
Sol. e t  ln t
, t   0,1
42. Suppose f and g are functions having second derivatives f" and g" everywhere, if f(x) g(x) = 1 for
f " ( x ) g" ( x )
all x and f ' (x) and g' are never zero, then  equals
f ' (x) g' (x)
f ' (x )
(A)
f (x)
f ' (x )
(B) 2
f (x )
2g' ( x )
(C) 
g(x )
2f ' ( x )
(D) 
f (x)
Ans. B
d
f " (x ) g" (x ) dx
f ' ( x ) / g' ( x ) g ' d  f '  2f ' x 
Sol.  = = .    f ( x ) . g( x )  1 .
f ' x  g' x  f ' x . g ' (x ) f ' dx  g '  f x 
g ' x 2

  px n  r 2  e  x  r  1 
lim       , x  0
  n  n
r 1 r   
r  1

43. Let f  x    q, x0

lim r  r  e  1 , x  0
n 2 x
 n r 1 r  r  1

Is differentiable is R:
. is G.I.F.and . is F.P.of x  Then:
(A) p=1
(B) q=1
(C) p+q+ =3
(D) if g is inverse of F then g ' 1/ 2   2
Ans. ABCD
 px   , x  0

Sol. f  x    q, x  0
e x , x  0

4 3 2
44. Consider f  x   4 x  24 x  31x  6 x  8 be a polynomial function and  ,  ,  , are the
roots.         . So:
1
(A) p 
  r  r  36

1
(B) p   r  r   18

2
x 1  5 x r 1  2  x  1
(C)  dx  2 ln 2
2
x 2  4 x  1
2
x 1  5 x r 1  2  x  1
(D)  dx  ln 2
2
x 2  4 x  1
Ans. AC
Sol. f  x    2 x  1 2 x  1 x  2  x  4 
45. Each of 2010 boxes in a line contains one red marble and for 1  k  2010, the box is the k th
position also contain k white marbles. A child begins at the fist box and successively drawn a
single marble at random from each box in order. He stops when be first draws a red marble. Let
p  n  be the probability that he stops after drawing exactly n marbles. The possible value(s) of
1
n for which p  n   is:
2010
(A) 44
(B) 45
(C) 46
(D) 47
Ans. BCD
Sol. p  n   Probability that child stops after drawing exactly n marbles

1 2 3  n  1  1  1
p  n   . . .......    
2 3 4  n  n  1  n  n  1
2
46. Consider the equation z   3  i  z   m  2i   0  m  R  . If the equation has exactly one real
and one-non-real complex root, then which of the following hold(s) good:
(A) Modulus of the non-real complex root is 2

(B) The value of m is 3
(C) Additive inverse of non-real root is  1  i 
(D) Product of real root and imaginary part of non-real complex root is 2
Ans. CD
Sol. If  is real root then   2, m  2, non-real root = 1  i
2
2x 1 1  x 2x
47. Consider a function f  x   sin 1 2
 cos 2
 tan 1 2
 a tan 1 x  a  R  , the
1 x 1 x 1 x
value of a if f  x   0 for all x:
(A) 6
(B) 6
(C) 2
(D) 2
Ans. ACD
Sol. If 0  x  1, a  6; if x  1, a  2, if x  1, a  2
 
m2n p
48. 
m 1

n 1  n.3  m.3 
m n
 (Where p & q are coprime) then:
q
(A) p  q  41
(B) pq
(C) p is perfect square
(D) q is perfect square
Ans. ABC
 
 m.n  n m 
Sol. 2S    n n  m
 n
m 1 n 1  m.3  n.3   3 3 

INTEGER.
2010 n 2009 n 1/ n
49. lim  2009 
n 
    2010  ] is equal to a
b
where a, b  N then a  b is….
Ans. 1
2 10
50. A and B are two square matrices such that A B  BA and if  AB   Ak B10 then the value of
k  1020 is….
Ans. 3
51. AI1 I 2 I3 is an excentral triangle of equilateral triangle ABC such that I1 I 2  4 unit, if DEF
Ar  I1 I 2 I 3 
is pedal triangle of ABC then 
Ar  DEF 
Ans. 4


Question Stem
y z x z
A plane P contains the lines L1 :   1, x  0 and L 2 :   1, y  0
b c a c
1 1 1 1
52. If the shortest distance between the lines L1 and L2 is , then 2  2  2 is______
4 a b c
Ans. 64.00
53. 
If B is the image of the point A 1, 0, 0  in the plane P where a=b=c=1 and M 1, 2,3 is a 
point in the space then length BM is____
Ans. 2.24

Question Stem
x2 y2
For the curves 2   1 and y 2  4 x
a 63
54. The maximum integral value of a for which there is only one common normal to the two curves
is_____.
Ans. 8.00
55. If the two curves have only two distinct common normal then the value of a is_____.
Ans. 9.00

Question Stem
ABC is an isosceles triangle with AB = AC = 5 and BC = 6. Let P be a point inside the triangle ABC such
that the distance from P to the base BC equals the geometric mean of the distances to the sides AB and
AC.
56. The minimum distance of the point A from the locus of the point P is____.
Ans. 2.50
57. If R is a point of locus of point P which is nearest to the point A, then ratio of area of ΔABC to
the area of ΔRBC is_____.
[Answer should be rounded off to two decimal planes]
Ans. 2.67
FIITJEE
JEE (Advanced)-2022
FULL TEST – II
PAPER –2
TEST DATE: 04-01-2022
decimal places.
MARKING SCHEME
marking scheme:
are correct;
option;
Physics PART – I

1. A rod of mass ' M  m' carries an insect of mass ‘m’ at its bottom end and its top
end is connected with a string which passes over a smooth pulley and the other
end of the string is connected to a counter mass M. Initially the insect is at rest.
Choose the correct option(s). M
M m
(A) As insect starts moving up relative to rod, the acceleration of centre of mass of the
system (insect + rod + counter mass) becomes non-zero
(B) As insect starts moving up relative to rod, tension in the string remains constant and is
equal to Mg.
(C) As insect starts moving up relative to rod, the tension in the string becomes more than
Mg.
(D) Acceleration of centre of mass of the system (insect + rod +counter mass) is zero when
insect moves with constant velocity.
Ans. ACD
2. In the given circuit the value of m is varying. The correct statements x

about the circuit are +
mr mr
V
(r/m)
y
–
(A) The condition for maximum current flowing from x is m =2.
V
(B) The maximum current is .
2r
(C) The condition for maximum current flowing from x is m = 2.
3V
(D) The maximum current is .
2r
Ans. BC
2mV
Sol. i
r  m2  2 
di
0m 2
dm
V
and i 
2v
3. A triangle is made from thin insulating rods of different lengths; the linear charge density on each
rod is uniform and the same for all three. At which point in the plane of the triangle at which the
electric field strength is zero.
(A) Incentre of the triangle
(B) Centroid of the triangle
(C) Circumcenter of the triangle
(D) None of these
Ans. A
Sol. The electric field due to uniform line charge at a point is equal to the electric field due to a circular
arc centered at that point which touches the line charge and limited by the ends of the line
charge.
4. A uniformly charged insulating square sheet of side length d has charge Q. A point charge q is
placed at a distance a/2 normally from the intersection of diagonals of the sheet. How much
Qq
(A) The force of electrostatic repulsion acts on the point charge due to the sheet is .
2 0 d 2
Qq
(B) The force of electrostatic repulsion acts on the point charge due to the sheet is .
6 0 d 2
Q
(C) The flux of electric field of the point charge that passes through the sheet is .
6 0
Q
(D) The flux of electric field of the point charge that passes through the sheet is .
12 0
Ans. BC
Sol. Force on the sheet due to the point charge = charge density * electric flux passing through the
sheet.
5. A ball of mass m = 1kg is hung vertically by a thread of length  = 1.50 m.

1.50m
Upper end of the thread is attached to the ceiling of a trolley of mass M = m M
4kg. Initially, trolley is stationary and it is free to move along horizontal m
v0
rails without friction. A shell of mass m = 1kg, moving horizontally with
1
velocity v 0  6 ms , collides with the ball and gets stuck with it. As a result,
2
thread starts to deflect towards right (g = 10 ms )
(A) The maximum deflection of the thread with the vertical is 37°
(B) The maximum deflection of the thread with the vertical is 45°
1
(C) The velocity of the trolley at that instant of maximum inclination of thread is 1 ms
1
(D) The velocity of the trolley at that instant of maximum inclination of thread is 2 ms
Ans. AC
Sol. When shell strikes the ball and gets stuck with it, combined body of mass 2m starts to move to
the right. Let velocity of combined body (just after collision) be v 1.
According to law of conservation of momentum,
v
(m + m) v1 = mv0 or v1 = 0 = 3 ms–1.
2
As soon as the combined body starts to move rightwards, thread becomes inclined to the vertical.
Horizontal component of its tension retards the combined body while trolley accelerates
rightwards due to the same component of tension.
Inclination of thread with the vertical continues to increase till velocities of both (combined body
and trolley) become identical or combined body comes to rest relative to trolley. Let velocity at
that instant of maximum inclination of thread be v. According to law of conservation of
momentum.
(2m + M) v = 2m.v 1 or v = 1 ms–1
During collision of ball and shell, a part of energy is lost. But after that, there is no loss of energy.
Hence, after collision, kinetic energy lost is used up in increasing gravitational potential energy of
the combined body.
If maximum inclination of thread with the vertical be  then according to law of conservation of
energy,
1 1
(2m) v12 – (2m + M) v2
2 2
= 2mg (  –  cos )
 cos  = 0.8 or  = 37°
6. If 1 kg of water freezes, then 334 kJ of energy are released. The energy released if 1 kg of super
cooled water at 10°C freezes is Q. Assume that during the freezing process the temperature
remains constant, and the specific heat of water is 4.2kJ kg 1K 1 and constant and specific heat
of ice is 2.1kJ kg 1K 1 which is also constant?
(A) The value of Q is 313 kJ
(B) The value of Q is 334 kJ
(C) The internal energy of ice obtained by this process is not equal to the internal energy of
ice obtained by freezing water at 00 C and then cooled upto 10°C .
(D) The internal energy of ice obtained by this process is equal to the internal energy of ice
obtained by freezing water at 00 C and then cooled upto 10°C .
Ans. AD
Sol. We could first carefully warm up the super cooled water from −10°C to 0°C, and then freeze the
water at its normal freezing point. In the first part of this process, the heat that has to be supplied
is 42 kJ, during the freezing stage the heat released is 334 kJ.
−Q+21 kJ = 42 kJ−334 kJ.
From this, Q = 313 kJ.

answer.
Two capacitors of capacity 6 F and 3F are charged to 100V and 50V separately and connected as
shown in figure. Now all the three switches S1, S2 and S3 are closed.
6F 3F
1 +– 2 3 +– 4
+– + ––
+– S2 +
100V 50V
S1
S3
200V
7. Charges on the 6F capacitor in steady state will be
(A) 400 C
(B) 700 C
(C) 800 C
(D) 250 C
Ans. B
8. Suppose q1, q2 and q3 be the magnitudes of charges flown from switches S1, S2 and S3 after they
are closed. Then
(A) q1  q 3 and q2 = 0
q2
(B) q1  q 3 
2
(C) q1  q 3  2q 2
(D) q1  q 2  q 3
Ans. D
Sol. (Q.7 – 8)
600  q 150  q
  200
6 3
q q
100   50   200
6 3
q
 50  q  100 c
2
Charge on 6  F capacitor  700  c
From conservation of charge q1  q2  q3
In physics laboratory, Peter is trying to calculate the focal lengths of a convex lens. He measures the
distance between a screen and a light source lined up on the optical bench to be 120 cm. When Peter
shifts the convex lens along the axis of optical bench, sharp images of the source is obtained at two lens
positions. He also measures the ratio of these two magnifications to be 1 : 9.
9. The focal length of the convex lens measured by Peter is
(A) 22.5 cm
(B) 30 cm
(C) 45 cm
(D) none of these
Ans. A
10. Which image, as seen by Peter is brighter?
(A) smaller
(B) bigger
(C) both are equally bright
(D) cannot be judged
Ans. B
Sol. (Q.9 – 10)

v  u  120............. 1
m1 I1 v 2 1 v 1
  2    .......  2 
m2 I 2 u 9 u 3
So v  30 cm and u  90 cm so f  22.5 cm
As more light passes through lens, so bigger image is brighter

INTEGER.
11. Ann is sitting on the edge of a Disc that has a radius of 6 m and is rotating steadily. Bob is
standing still on the ground at a point that is 12m from the centre of the carousel. At a particular
instant, Bob observes Ann moving directly towards him with a speed of 1ms 1 . With what speed
(in m/s) does Ann observe Bob to be moving at that same moment?
Ans. 2
Sol. Consider the motions of the bodies both in the original frame of reference and in another frame
that moves with velocity v0 relative to the first one. Apply the Relative motion formulae. If Ann
were sitting at the centre of the disc, she would see the whole world around her rotating with the
same angular speed ω, but in the opposite direction. That means she would observe Bob
standing 12 m away from the centre of the disc, but moving with a speed of 1/6 ×12 = 2 m s−1 in a
direction perpendicular to the line joining him to the centre of the disc. Although Ann is not sitting
at the centre of the disc, but at its edge, the same conclusion applies.
12. A pulley system is attached to a massless board as shown below. θ

F

The board pivots only at the pivot point. A 10 kg mass M sits
exactly in the middle of the board. If the angle  is 60°. The
force F (in N) necessary to hold the board in the position shown is 
M
5  x , find x?
Pivot point
Ans. 5
Sol. 2F
Mg

For equilibrium

Mg  2F 1
2
mg 100
F   25 N
4 4
13. The peak emission from a black body at a certain temperature occurs at a wavelength of 6000 Å.
On increasing its temperature, the total radiation emitted is increased 16 times. These radiations
are allowed to fall on a metal surface. Photoelectrons emitted by the peak radiation at higher
temperature can be bought to rest by applying a potential equivalent to the excitation potential
corresponding to the transition for the level n = 4 to n = 2 in the Bohr's hydrogen atom. The work

function of the metal is given by eV where  is the numerical constant. The value of  is
100
found 53  x , find x? [Take: he = 12420 eV- Å ]
Ans. 3

Question Stem
A quantity, n mol say, of helium gas undergoes a thermodynamic process (neither isothermal nor
isobaric) in which the molar heat capacity C of the gas can be described as a function of the absolute
temperature by C = 3RT/(4 T0 ), where R is the gas constant and T0 is the initial temperature of the
helium gas.
14 The temperature of the gas, when is reaches its minimal volume is nT0 , find the value of n.
Ans. 2.00
15. The work done on the system up until the point at which the helium gas reaches its minimal
 3
volume is   nRT0 , find the value of n.
n
Ans. 8.00
Sol. (Q.14 – 15)

When the helium gas is close to its minimal volume, to first order there is no change in the volume
for a finite change in the temperature. This means that, in this region, the process is
approximately isochoric, and so the molar heat capacity of the monatomic helium gas must be CV

Question Stem
A constant current  flows through a cable consisting of two thin co-axial metallic cylinders of radii R and
2R, as shown in figure
0
16. If the inductance per unit length is loge n. Then find the value of n.
2
Ans. 2.00
0 2
17. If the energy stored in it per unit length and loge n. Then find the value of n.
4
Ans. 2.00
Sol. (Q.16 – 17)

Due to flow of current through the cable, shown in fig. magnetic field is established in the space
between cylinders. Energy is stored in this space due to magnetic field.
Since, energy stored per unit volume in magnetic field of induction B is equal to B2 / 2µ0, therefore,
magnetic induction in the space must be known. But magnetic field in the space is not uniform.
Hence, consider a thin cylindrical coaxial shell in the space. Let radius of the shell be x and radial
thickness dx as shown in fig.
According to Ampere's circuital law, magnetic induction B is given by B 2x = µ0 
dx
x
R 2R
0  
or B =
2 x
 Energy stored per unit length of the shell considered is
B2  2
dU = (2x dx) = 0 dx
2 0 4x
Energy stored per unit length of the cable,
x 2 R   2
0
U = dU = 
x r 4x
dx
2
0
= loge 2
4
1 2
Since, energy stored in magnetic field is U = L where L is self inductance, therefore,
2
2U 
inductance per unit length of the cable is L = 2 = 0 loge 2
 2
Question Stem
A cylindrical tank is filled with two liquids of density 1 = 900 kg m –3 & 2 = 600 kgm–3, to a height h = 60
cm each as shown in figure. A small hole having area a = 4.9 cm2 is made in right vertical wall at a height
y = 20 cm from the bottom. (g = 10 m/s2)
h (2)
h (1)
F y
18. The velocity of efflux is (in m/s)
Ans. 4.00
19. The horizontal force F to keep the cylinder in static equilibrium, if it is placed on a smooth
horizontal plane is (in N)
Ans. 7.00
Sol. (Q.18 – 19)

Since area a of hole is very small in comparison to base area A of the cylinder, therefore, velocity
of liquid inside the cylinder is negligible. Let velocity of efflux be v and atmospheric pressure P0.
Consider two points A (inside the cylinder) and B (just outside the hole) in the same horizontal
line as shown in figure.
2
1
B
A
Pressure at A, PA = P0 + h 2g + (h – y)1g

Pressure at B, PB = P0
According to Bernoulli's theorem,
pressure energy at A
= pressure energy at B + kinetic energy at B
1
 PA = PB + 1v 2
2
 v = 4ms–1 Ans. (i)
When cylinder is on smooth horizontal plane, force F required to keep cylinder stationary equals
horizontal thrust exerted by water jet. But that is equal to mass flowing per second × change in
velocity of this mass.
 F = (av ) (v – 0) = av 2
or F = 7.2 N Ans.(ii)
mg
Fmax 7.2 N
N
N
Total mass of the liquid in the cylinder is
m = Ah1 + Ah2 = 450 kg
Limiting friction = mg = 45 N
 F < Limiting friction, therefore, minimum
force required is zero. Ans. (iii)

20. The vapour pressure of pure liquids A and B are 450 & 700 mm Hg respectively at 350K. If the
total vapour pressure of solution (A+B) is 600 mm Hg, then which of the following is/are correct?
(A) Mole fraction of A in liquid mixture is 0.4

(B) Mole fraction of A in liquid mixture is 0.6
(C) Mole fraction of A in vapour phase is 0.3
(D) Mole fraction of A in vapour phase is 0.35
Ans. AC
21. An optically active alcohol A  C8 H 16O  on oxidation gives B . A on acidic heating gives
C  C8 H 14  as major product. C on ozonolysis produces D  C5 H 8O  and
H3C C CH3 . D on reduction with LiAlH 4 gave OH .

O
Identify correct answer:
(A) CH3 (B) CH3

A is CH2OH B is COOH
H H
(C) (D)
C is D is O
Ans. ABCD
Sol. CH3 CH3

O 
CH2OH  COOH

H H
 A  C8 H16O  B
H / 
H3C
ozonolysis
  O + C O
H3C
C  D
LiAlH 4
OH
22. Which of the following order for basic strength is/are correct?
(A) N (B) O
  NH2 NH2
N N N 
H H
(C) (D)
N NH
 

NH N N
N H H
H
Ans. ABC
Sol. A lone pair of N-atom participating in resonance will be less basic
23. Which of the following is/are correct :
(A) Carbon-carbon bond length in CaC 2 will be more than in CH2CCH2
(B) O–O bond length in KO2 will be more than in Na 2 O 2 .
(C) O–O bond length in O2 [PtF6] will be less than that in KO2
(D) N–O bond length in NO gaseous molecule will be smaller than in NOCl gaseous
molecule.
Ans. CD
24. Anode rays
(A) contain positively charged particles
(B) have constant e/m ratio irrespective of the type of gas used
(C) may contain He+ ions
(D) are always beams of protons
Ans. AC
25. Which is correct for a gas described by van der Waal’s equation:
(A) behaves similar to an ideal gas in the limit of large molar volumes
(B) behaves similar to an ideal gas in the limit of large pressures
(C) is characterized by van der Waal’s coefficients that are dependent on the identity of the
gas but are independent of the temperature.
(D) has the pressure that is lower than the pressure exerted by the same gas behaving
ideally
Ans. ACD

answer.
CrO

3
S
O KOH NH
 3
Zn / H2O
 P   Q 
2 4
EtONa
R
HBr NH
  U  3
excess
V
KOH H2 /Pd


T excess
26. Which of the following statement is correct about S?
(A) It will not give yellow/orange or red colour with 2, 4-DNP
(B) It will give red colour with Cerric Ammonia Nitrate
(C) It will not give Fehling test
(D) None of these
Ans. C
27. Which of the following statement is correct about V?
(A) It will not give mustard oil reaction
(B) It will not give carbylamines test or isocyanide test
(C) It is less basic than aniline
(D) It will give base soluble product with Hinsburg reagent
Ans. D
An acyclic hydrocarbon P, having molecular formula C6 H10 , give acetone as the only organic product
through the following sequence of reactions, in which Q is an intermediate organic compound.
 i  conc.H 2SO 4
O
 Catalytic amount 
 i  dil.H 2SO 4 /HgSO 4  H 2 O  C
P Q 2 H3C CH3
 C6 H10   ii  NaBH 4 /ethanol  ii  O3
 iii  dil.acid  iii  Zn/H 2 O
28. The structure of compounds P is:
(A) CH 3CH 2CH 2CH 2  C  C  H (B) H 3CH 2C  C  CH 2CH 3
(C) H3C (D) H3C

H C C C CH3 H3C C C C CH3
H3C H3C
Ans. D
29. The structure of the compound Q is:
(A) H3C OH (B) H3C OH

H C C CH2CH3 H C CH2CHCH3
H3C H H3C
(C) H3C OH (D) OH
H3C C C CH3 CH 3CH 2 CH 2CHCH 2CH 3

H3C H
Ans. B

INTEGER.
2
30. The number of electrons for Zn cation that have the value of azimuthal quantum number  0 is:
Ans. 6
Sol. Azimuthal quantum number is zero for s-subshell
31. Co forms dinuclear complex with a sigma bond within two Co atoms. Consider that metal
carbonyls follows EAN rule. The complex can be written as CO 2  CO  x . Find the value of x ?
Ans. 8
Sol.  CO  x / 2 Co  Co  CO  x / 2
x
EAN   36   27  1  2 
2
 28  x  36
x8
32. If four atoms of same radius are placed at the alternate corner of a cube touching each other,
than the length of body diagonal of the cube is equal to x  R , where R is the radius of atom.
Find the value of x?
Ans. 6
Sol. A

E 

B D
Face diagonal of cube  AB  =2R
2R
Edge length of cube  BE  =
2
2R
Body diagonal of cube  AD  = 3×
2
= 6R

Question Stem
An aluminium block of 270gm having total heat capacity 490 J/K. at 127°C is placed in a lake at 27°C.
Suniverse is given by x J/K . When the same block at 27°C is dropped in the lake (27°C) from a height of
2
200m. ΔSuniverse is given by y J/K . [ ln  4 / 3   0.29, g  10.0m/sec ]
33. The value of x is_____.

Ans. 21.23
490   400  300 

Sol. ΔSlake   163.33 Sblack  490  ln  300 / 400   142.1
300
x  Suniv  163.33  142.1  21.23 J / K
34. The value of y is_____.
Ans. 1.80
mgh 0.270  10  200

Sol. Sblack  0; Slake    1.8 J/K
300 300
Question Stem
A mixture of NaCl & NaBr weighing 4.0 gm was dissolved and treated with excess of AgNO3 to
precipitate all of the chlorides & bromides as AgCl and AgBr . The washed ppt was treated with KCN to
dissolve the precipitates. The resulting solution was electrolysed, the weight of Ag deposited is 6.0 gm.
electrolysis
K  Ag  CN  2  +KOH   Ag+KCN+O 2 +H 2O
 M.W.of NaCl, NaBr and Ag are 58.5,103,108g/mol 
35. Wight percent of NaCl in the original mixture is____.
Ans. 56.60
36. The volume  at STP,in ltr  of O2 produced during electrolysis is_____.
Ans. 0.31
Sol. (Q.35 – 36)

x mass of NaCl
x 4 x 6
   x  2.264
58.5 103 108
1
Moles of O2 produced = ×moles of Ag
4
Question Stem
2 2 1
At 298 K, the limiting molar conductivity of a weak monobasic acid is 4×10 S cm mol . At 298 K, for an
aqueous solution of the acid the degree of dissociation is  and the molar conductivity
is y×10S cm 2 mol 1 . At 298 K, upon 20 times dilution with water, the molar conductivity of the solution
2
2 2 1
becomes 3y×10 S cm mol .
37. The value of  is____.
Ans. 0.22
mc y  102 y
Sol. 1    
m0 4  102 4
mc 3 y  102 3 y
2     3
m0 4  102 4
C112 C2 2 2
Ka  
1  1 1   2
2
C 2  C / 20  3 

1 1  3
  0.2156
  0.22
38. The value of y is______.
Ans. 0.88
y
Sol.  ; y  4  4  0.22  0.88
4

39. The volume of a right triangular prism ABCA1B1C1 is equal to 3. If the position vectors of the
vertices of the base ABC are A(1, 0, 1) ; B(2,0, 0) and C(0, 1, 0) the position vectors of the vertex
A1 can be:
(A) (2, 2, 2)
(B) (0, 2, 0)
(C) (0, - 2, 2)
(D) (0, - 2, 0)
Ans. AD
Sol. knowing the volume of the prism we find its altitude H = (A A1) = and designating the vertex A1

(x1, y1, z1) relate the co-ordinates of the vector A A1 = (x - 1, y, z - 1) and its length. We get the
 
other equation from the condition A A1 perpendicular to AC ]
40. If the equation | z | (z  1)8  z8 | z  1| where z  C and z(z  1)  0 has distinct roots
z1, z2, z3, ..., zn (where n  N) then which of the following is/are true?
(A) z1, z2, z3, ...., zn are concyclic points

(B) z1, z2, z3, ...., zn are collinear points
n
(C) 7
 Re(z ) 
r 1
r
2
n
(D)  m(z )  0
r
r 1
Ans. BCD
41. If in a ABC, a, b, c are in A.P. and P1, P2, P3 are the altitudes from the vertices A, B and C
respectively, then
(A) P1, P2, P3 are in A.P.
(B) P1, P2, P3 are in H.P.
3R
(C) P1  P2  P3 

(D) 1 1 1 3R
  
P1 P2 P3 
Ans. BD
a1  b1 a1  b2 a1  b3
42. Suppose a1, a2, a3 are in A.P. and b1, b2, b3 are in H.P. and let  = a  b a  b a2  b3 ,
2 1 2 2
a3  b1 a3  b2 a3  b3
then
(A)  is independent of a1, a2, a3, b1, b2, b3
(B) a1 – , a2 – 2, a3 – 3 are in A.P.
(C) b1 + , b2 + 2, b3 +  are in H.P
(D) none of these
Ans. ABC
43. Let A, B, C be nn real matrices and are pair wise commutative and ABC = On and if
 = det(A3 + B3 + C3). det (A + B + C) then
(A) >0
(B) <0
(C) =0
(D)   (-, ) – {0}
Ans. AC
Sol. A 3  B3  C3  A 3  B3  C3  3ABC

=  A  B  C  A 2  B2  C2  AB  BC  CA
=  A  B  C   A  WB  W C  A  W B  WC  [W = cube root of unity]
2 2
=  A  B  C   A  WB  W C  A  WB  W C 
2 2
thus det(A3 + B3 + C3).det(A + B + C)


det(A + B + C)2.det(A + WB + W 2C)det A  WB  W 2 C 
2 2
=  det  A  B  C   . det  A  WB  W C  2
 0.
44. Let f: A  A, where A is a set of non-negative integers and satisfying the condition.
(i) x  f(x) = 19 [x/19]  90[f(x)/90],  x  A
(ii) 1900 < f(1900) < 2000
then f(1900) equals, where [ ] indenter greatest integer function
(A) 1994
(B) 1900
(C) 1904
(D) 1890
Ans. AC
 f 1990  
Sol. Put x = 1990 in(i) we get   = f(1990)  14 ……….(0)(iii)
 90 
1990 f 1990  2000
Using relation(ii)  
90 90 90
 f 1990  
   = 21 or 22
 90 
 f 1990  
of   = 21  f(1990) = 1904 Using (iii)
 90 
 f 1990  
of   = 22  f(1990) = 1994 using (iii)
 90 

answer.
1
Let t be a real number satisfying 2t 3  9t 2  30    0 where t  x  and   R then
x
45. If the cubic equation has three real and distinct solution for x then 
(A) Is greater than 9
(B) Is greater than 11
(C) Is less than 8
(D) Is not equal to 10
Ans. A
Sol. For   10  t1  2, t 2  2 and if x  1/ x  2  x  1 and x  1/ x  t 2 so there will be two

distinct values of x
46. If the cubic equation has exactly two real and distinct roots of x then exhaustive set of values of
 is
(A)    ,3    30,  
(B)    , 22   10,    {3}
(C)   {3,30}
(D) None of these
Ans. B
Sol. Since domain of f  t   2t 3  9t 2  30, t  x  1/ x, t  2 f  2    22, f  2   10, critical

points at t  0 & 3; f  3   3
Let P, Q are two points on the curve y = log1/ 2  x  0.5   log2 4x 2  4x  1 and P is also on the circle
x2 + y2 = 10, Q lies inside the given circle such that its abscissa is an integer.
47. The co–ordinates of P are given by
(A) (1, 2)
(B) (2, 4)
(C) (3, 1)
(D) (3, 5)
Ans. C
 1 2 1
Sol. y = log1/ 2  x    log2  2x  1 But x >
 2 2
 1
= log1/ 2  x    log2  2x  1
 2
y=1
P  (3, 1).
 
48. OP  OQ , ‘O’ being the origin is
(A) 4 or 7
(B) 4 or 2
(C) 2 or 3
(D) 7 or 8
Ans. A

Sol. OP  3iˆ  ˆj
Q  (1, 1) or (2, 1)

OQ  î  ˆj and 2iˆ  ˆj
 
OP  OQ  3  1  4 and 6 + 1 = 7

INTEGER.
49. Consider on equation with x as variable 7 sin3x  2sin9x  sec 2   4cosec 2  then the value of
15 [minimum positive root – maximum negative root] is:
2
Ans. 5
50.  
If the area enclosed by g x ,x  3,x  5 and x-axis where g x is the inverse of  
f  x   x  3x  1 is A, then  A  is ( . is G. I. F)
3
Ans. 4
3
1   f  x 
51. Let f  x   cos2x.cos 4x.cos 6x.cos8x.cos10x then lim equals
x 0 55 sin2 x
Ans. 6
Sol.
ln cos 2x 22 ln cos 4x 42
lim 2
  ,lim 2

x 0 x 2 x0 x 2

Question Stem
Let f  x   x
2010
 x1010  x 510  x 210  x 2 . If f  x  is divided by x 2  x 2  1 , then we get remainder
2 2
as g  x   ax  bx  cx  d .
52. a  b  c  d is equal to____.
Ans. 3.00
2
53. If roots of g  x   0 lies between the roots of the equation x  2  a  1 x  a  a  1  0 then
the number of integral values of a will be_____.
Ans. 0.00

Question Stem
2 3 2.4 5 2.4.6 7
Let f  x   x  x  x  x  .... x   0,1
1.3 1.35 1.3.5.7
1 
54. If the value of f   is (where a, b  ) then a  b is______.
2 a b
Ans. 6.00
 
 (where c   )
2
55. Let g  x   1  x . f  x  for all x   0,1 . If the range of g  x  is  0,
 c
then c is_____.
Ans. 2.00
Question Stem
Let z1 and z2 are two complex numbers such that z1  a and z2  b satisfying the equation
 z 2
3 z12  2 z1 z 2  2 z12  0 and also Re  1   0 . Also P,Q and O are points in complex plane
 z1  2 
corresponding to z1 , z2 and origin respectively.
x2 y 2
56. Eccentricity of the ellipse 2  2  1, is_____.
a b
Ans. 0.58
57. Area of triangle OPQ is______.

Ans. 2.24
FIITJEE
FULL TEST – II
JEE (Main)-2022
TEST DATE: 25-12-2021
answer.
AITS-FT-II-PCM-JEE(Main)/22 2
Physics PART – A
SECTION – A
1. A cannon fires successively two shells with speed 10 m/s, the first at an angle 60 and the
second at an angle 45 to the horizontal in same plane. Find horizontal distance where firing
leads to collision of shells (take g = 10 m/s2 and 3  1.7 )
(A) 3m
(B) 5m
(C) 7m
(D) 9m
Ans. C
Sol. At the point of collision

1 gx 2 1 gx 2
x tan60   x tan 45  
2 u2 cos2 60 2 u2 cos2 45
gx
 (4  2)  3  1
2u2
u2
 x ( 3  1)  7 m
g
2. A ball is held at rest in position A and another identical ball is

released from rest in position B. The ratio of tension T1 and T2
is: (string connecting wall and ball A is horizontal)
30 30
T1 T2
A B
(A) 1
1
(B)
2
4
(C)
3
3
(D)
4
3 AITS-FT-II-PCM-JEE(Main)/22
Ans. C
Sol. T1 cos 30 = mg

and T2 = mg cos 30
T1 4
 sec 2 30 
T2 3
3. If there is air drag in the ascent of a ground to ground projectile:
(A) The magnitude of tangential acceleration increases while magnitude of normal

acceleration decreases.
(B) The magnitude of tangential acceleration decreases while magnitude of normal

acceleration increases
(C) Both increase
(D) Both decrease
Ans. B
Sol. Tangential acceleration = g sin   kv

Normal acceleration = gcos  
kv 90
g sin g cos
g
4. A particle moves along x-axis. Its velocity time graph is shwon in v

figure. The distance travelled by particle in 0 to 3s.
0 1 2 3 t
3 parabola
(A) zero
(B) 4m
(C) 8m
(D) 12m
Ans. C
Sol. Equation of parabola

v  3t 2  6t
2 3
Distance = 
0
vdt   vdt  8m
2
5. In the given figure mass of block A is m and that B is 2m. They are A B
attached at the ends of spring and kept on horizontal surface. Now
m 2m
the spring is compressed by x0 and released. Find displacement of
x
block B by the time compression of the spring is reduced to 0 .  = 0.2  = 0.1
2
Assuem both are slipping in opposite directions together.
x0
(A)
3
x0
(B)
2
x0
(C)
6
x0
(D)
4
Ans. C
Sol. Since net force on the system of two blocks is zero.

x
x A  xB  0
2
mx A  2mxB
x0
 xB 
6
6. A pendulum bob of mass m with string length  can swing in a vertical plane. The bob is given an
initial velocity from lowermost point in horizontal direction such that tension in rope and speed of
pendulum becomes zero simultaneously. Find maximum height rise by pendulum.

(A)
2

(B)
3
(C) 
4
(D)
3
Ans. C
Sol. Given case is only possible for

u  2g
So, maximum height = 
7. A sheet ABCD has mass M. Sides AB and CD are parallel to each other
and perpendicular to BC. The perpendicular distance of mid point of AD
from side BC is half of length of BC then moment of inertia of sheet about A
axis AD is B
O

D
C
M 2
(A)
3
M 2
(B)
2
M 2
(C)
12
4M2
(D)
3
Ans. C
Sol. Plate is half of square plate

M 2
So, I  A
12 B
D
C
8. A uniform rod of m mass is hinged at and kept one end at initially

vertical at rest. It is disturbed slightly. The hinge force when rod is
about to hit ground.
3
(A) mg
2
1
(B) mg
4
37
(C) mg
4
41
(D) mg
4
Ans. C
Sol. Final angular velocity (MEC) Hy

1 m 2 2 
   Mg aC
2 3 2
 3g Hx
 2  mg
2 2
aC
Angular acceleration
 m 2  3g
Mg    
2 3 2 4
3mg mg 37
Hx  , Hy  H mg
2 4 4
9. Two spherical balls of radius 2r and r both having density  are tied up
with light string and released in a viscous fluid of density  >  with the
rope just taut. The tension in rope when spheres attain terminal velocity: 2r
3 3
(A) r (  )g
5
8 3
(B) r (  )g
3
10 3
(C) r (  )g
5
5 3
(D) r (  )g
3
Ans. B
Sol. At internal velocity Balancing forces

 
Mg   1  T  6(2r)v
 
 
mg   1  6rv  T
 
     
Mg   1  T  2 mg   1  T 
     
 M  2m    8
T   1 g  r 3 (  )g
 3    3
10. A planet of mass m revolves around sun of (mass M) along an elliptical orbit such that its
minimum and maximum distance from centre of the sun are r and 3r respectively. Its time period
of revolution will be
2r 3
(A) 4
GM
r3
(B) 2
GM
2r 3
(C) 
GM
 r3
(D)
2 GM
Ans. A
Sol. a + ae = 3r
a  ae = r
 a = 2r
2 3/2
T a
GM
11. Potential energy of a particle of mass 2kg is given as

x3
 2x
6
Initially particle is at equilibrium position, then time period for small oscillation about stabe
equilibrium position is
(A) 2 sec

(B) sec
2
4
(C) sec
3

(D) sec
3
Ans. A
Sol. At stable equilibrium

dF = 2dx
k=2
2
T  2  2 sec
2
12. Two moles of an ideal monoatomic gas undergoes into a process such that internal energy
depends on entropy S  ogeU . Molar specific heat of gas is
(A) 3
(B) 1
(C) 0.5
(D) 5
Ans. C
dU
Sol.  dS
U
dT dQ

T T
ncdT  dT
1
c
n
13. A point source is placed at 1 m perpendicular height of a square plate of side 2m from its center.
A source is producing sound with power 18 J. The amount of energy collected by plate per
second.
(A) 2J
(B) 3 J
(C) 0.18 J
(D) 0.1J
Ans. B
Sol. Similar to Gauss’s Law
14. A point charge 1 nC is placed at 50 cm from the centre of a

conducting shell of radius 20 cm having 3 nC charge. There
is a cavity in the solid sphere having a positive charge 2 nC. A P B
Due to system of shell potential at point P (AP = 10 cm) as
2nC
shown in the figure, is
(A) 27 V
(B) 45 V
(C) 49.5 V
(D) 22.5 V
Ans. C
 1 1 1 
Sol. Potential of shell due to spherical system at P =  9  109  10 9      49.5 V
 0.2 0.1 0.4 
Which is also potential of P.
15. In measurement of resistance by meter bridge. The resistivity of wire increases linearly. Then, the
percentage error is minimum when null point is at
(A) close to 50 cm
(B) close to 57 cm
(C) close to 45 cm
(D) close to 83 cm
Ans. B
 x2 
Sol. Q  P
 1002  x 2 
 
dQ 2dx 2xdx
 
Q x 1002  x 2
dQ
For minimum  x  57 cm
Q
16. Two conductors of same length and area of cross section i  3 i

are connected in series as shown in the figure. An electric
current i flows through them. The total charge accumulated
at junction would be ( and 2 are their resistivity)
(A) i0
(B) 2 i0
(C) 3 i0
(D) zero
Ans. B
Sol. E1 = J Q
E2 = 3J E1 E2
Q
 
0
 Q = 2 i0
17. Two co-axial current carrying loops having currents in I

 3I
opposite directions. Then value of  B.dx ,

where B is
 
magnetic field on x-axis will be
(A) 0I
(B) 20I
(C) 20I
(D) 0I
Ans. B

Sol. For one ring  Bdx   I

00
Due to opposite direction field will cancel out.
18. In the arrangement shown the maximum current in circuit when 4V0 V0
switch is closed.  + +  S
2C C
6C
(A) V0
L
C
(B) V0
L
V0 C
(C)
2 6L
V0 6C
(D)
2 L
Ans. A
Qmax 2CV0 3V0

Sol. maximum current =   +
LC 2C
L 2C/3
3
6C
= V0
L
L
20
19. A toroid has mean radius R  cm and a total of 400 turns of wire carrying a current of 2A. A

metallic ring at 300 K inside the toroid provides core. If the magnetization intensity I = 4.8  102
A/m the susceptibility of metal is:
(A) 2.4  105
(B) 4.2  105
(C) 2.4  104
(D) 4.2  104
Ans. A
I I 4.8  102
Sol. cm     2.4  105
H ni 103  2
20. An EM wave enters from vacuum into a non magnetic medium of refractive index 1.5. Then the
ratio of electric fields in vacuum and medium will be
3
(A)
2
2
(B)
3
1
(C)
2
(D) 2
Ans. A
Sol. E0 = cB0
E = vB
E0 c
 n {B = B0 due to nonmagnetic medium)
E v
= 1.5
SECTION – B
21. An ideal choke takes a current of 8A when connected to an AC source of 100 V and 50 Hz. A
pure resistance under the same conditions takes a current of 10A. If two are connected in series
to an AC supply of 100 V and 40 Hz then current in the circuit is k 2 . Find the value of k.
Ans. 00005.00
100 12.5
Sol. XL   12.5  L 
8 100
100
R  10
10
at 40 Hz
XL  10  Z  102  102  10 2
V
i 5 2 A
Z
22. A combination of two lenses is used to converge

30 cm
parallel beam. If final image is at 1 cm height from
axis, then value of tan  is
f1 = 10 cm f2 = 10 cm
Ans. 00000.10
Sol. h = f tan 
h = 10 tan 
final image has 1 cm height
So, h = 1 cm F  f
Hence tan  = 0.1 
h
23. A hemispherical concave mirror is filled with a liquid of

refractive index 2 . A light centres into liquid at grazing
incidence. The optical path of ray only due to medium at 90
the emerging point is NR. Find the value of N. (R is radius
of concave mirror) P
Ans. 00004.00
Sol. Optical path = n(2 2R)  4R
45 45
24. A radioactive sample contains two radioactive elements A and B having decay constant  and 2.
Initially 25% of total decay comes from A. After how many seconds 75% of total decay comes
from A? (Take  = n3)
Ans. 00002.00
Sol. Ratio of initial activity

RA0 1

RB0 3
Ratio of final activity
R A 0 e t
3
RB 0 e 2 t
 et  9
25. The k  line wavelength is  for an element with atomic number z = 19. Another atom having

k  wavelength   will have atomic number equal to
 4
Ans. 00037.00
2
 A  zB  1 
Sol.  
B  z A  1 
zB = 37
26. Two Silicon and Germanium diodes are connected Si Ge

in a circuit. The knee voltage of Si and Ge are 0.7
V and 0.3 V respectively. The current in resistance
1 is
R = 1 2V
1V
Ans. 00001.70
Sol. As per knee voltage Ge is conducting but Si is blocking 0.3 V

the current
So current
2  0.3 i
i  1.7 A R = 1
1 2V
1V
27. Equation of an amplitude modulated wave is given as

C(t)  20cos(200t)  10cos(200t)cos(2t)
Then ratio of bandwidth and modulation index is :
Ans. 00001.00
Sol. C  200  fc  100 Hz A C  20
m  2  fm  1 Hz Am  20
Band width 2fm
 1
 A C / Am
28. A vernier calipers have 10 divisions on vernier scale coincide with 9 main scale division. When
there is not any object between jaws and jaws touch each other the first main scale division
coincides with first vernier scale division. If one main scale division is 1 mm then find distance
moved by vernier calipers till third vernier scale division coincides with third main scale division (in
mm).
Ans. 00000.20
Sol. 10 VSD = 9 MSD

 L.C. = 0.1 mm
Distance = 0.1 mm  2 = 0.2 mm
29. When water freezes into ice its volume increases by 2%. A rigid spherical shell is filled completely
with water at 0C. Now water is freezed completely then Bulk stress on sunface of ice is N  109
Pa. Find the value of N. (Bulk’s modulus of water = 2  1011 N/m2)
Ans. 00004.00
V
Sol. B  P
V
0.02  2  1011  P
 P = 4  109
 
30. Two vectors a and b are such that
   
(a  2b)  (2a  3b)  2
   
and (a  b)  (2a  b)  1
then the value of 4a2  7b2 is
Ans. 00003.00
 
Sol. 2a2  6b2  a  b  2
 
2a2  b2  a  b  1
4a2  7b2  3
SECTION – A
31. While calculating the strength of KMnO 4 using titration:
(A) KMnO 4 is in burette and conc. H2 SO4 is in conical flask.
(B) KMnO 4 is in conical flask and conc. H2 SO4 is in burette.
(C) KMnO 4 is in burette and oxalic acid is in conical flask.
(D) KMnO 4 is in conical flask and oxalic acid is in burette.
Ans. D
Sol. KMnO 4 is in conical flask and oxalic acid is added from burette. Cannot use H2 SO4 as it is a
secondary standard.
32. Br
KOH conc. H2 SO4
  X   Y; Y is :
(A)
(B)
(C) OH
(D)
Ans. A
Sol. Br OH
KOH
 
OH
CH2
 H2 SO4  HSO4

 H2O   
 
H2 SO 4

33. The hybridization of nitrogen atom in solid state structure of N2 O5 is
(A) sp3 , sp3
(B) sp2 , sp2
(C) sp, sp2
(D) sp2 , sp3
Ans. C
Sol. N2 O5  NO2  NO3 

 
 
sp sp2
34. CFCl carbene and CCl2 carbene are respectively:
(A) Singlet, Singlet
(B) Triplet, Triplet
(C) Singlet, Triplet
(D) Triplet, Singlet
Ans. A
Sol. Both CFCl and CCl2 are capable of back-bonding, therefore, singlet state is more stable.
35. COCH3
Cl2

EtOH
 The major product out of the following is :
(A) COCH3
Cl
Cl
(B) COCH3
Cl
Cl
(C) COCH3
OEt
Cl
(D) COCH3
Cl
OEt
Ans. C
Sol. COCH3 COCH3

COCH3
Cl2 + OEt
  Cl

EtOH
Cl
2
36. The hybridization of central atom in H6 SnO 6  is:
(A) sp3
(B) sp3 d2
(C) sp3 d
(D) sp3 d3
Ans. B
Sol. 2
OH
OH
HO
sp3 d2
Sn
OH
HO
OH
37. O
NH2  2
i Br /h 
 ii KOH  The major product is :

CH2CH3
CH2
(A)
NH
(B)
NH
(C) O
NH
(D) O
NH
Ans. C
Sol. O O O
NH2 Br2 /h

NH2 NH
 KOH
 
CH2CH3 CH2CH3
CH2 CH
Br Br
NH
38. Which of the following form the most stable dihydrate?
(A) O
(B) O
(C) O
(D) O
Ans. A
Sol. H2 O/H  OH
O  
, releases the strain and so form a stable dihydrate.
OH
39. The correct sequence of amino acid present in this tetrapeptide given is:’
OH
Me Me
O O
NH C NH
H2N NH OH
O O Me
OH
(A) Iso-Tyr-Ala-Ser
(B) Ala-Tyr-Iso-Ser
(C) Tyr-Ser-Iso-Ala
(D) Iso-Ser-Tyr-Ala
Ans. D
Sol. Isoleucine  H2N CH COOH ,Serine  H2N CH COOH
OH
Tyrosine  H2N CH COOH , Alanine  H2N CH COOH
CH3
OH
40. What types of forces are present in diethyl ether?
(A) Hydrogen bonding only
(B) London dispersion forces and ion-dipole forces
(C) London dispersion forces and dipole-dipole forces
(D) Dipole-dipole forces and hydrogen bonding
Ans. C
Sol. Diethyl ether has slight polarity so, weak dipole-dipole forces exist along with London-dispersion
forms.
41. Which of the following is an incorrect path of reduction under normal condition?
(A) CH3 CH3
Na

Liq. NH3

(B) NO 2 NH2
Zn Hg

HCl
(C) O
H2 /Ni
H3C C OEt   CH3  CH2OH
(D) H3C CH2 C H2 /Pd/BaSO4

Cl  H3C CH2 C H
Xylene
O O
Ans. C
Sol. H2 / Ni does not react with ester under normal conditions.
42. The total number of stereoisomers of the given compound is/are:

O
Cl CH2NH2
Cl CH C CH CH3
(A) 8
(B) 16
(C) 64
(D) 32
Ans. D
Sol. 5 stereocenters are present.

Total isomer  2n  25  32 .
43. For a reaction A   P, the energy of activation is 15.8 Kcal at 298 K. Calculate the number of
activated molecules if we start with 1 mole of A, considering Arhenius equation to be valid
(Given: e  26.51  3.067  10 12 )
(A) 1.031 10 21
(B) 1.847  1012
(C) 5.86  1023
(D) 3.067  1012
Ans. B
Ea
Total molecules activated 
Sol.  e RT
Total number of molecules present
 15.8103 
 
Molecules activated 2 298 
e 
NA 1 mole 
Molecule activated  3.067  10 12  6.023  1023
 1.847  1012
44. The flocculation values of these effective ions vary in the order for Gold sol as:
(A) Sn4  Al3  Ba 2  Na
(B) PO33   SO24   Cl
(C) Na  Al3  Ba 2  Sn4
(D) SO 24   Na  PO34   Ba 2
Ans. A
1
Sol. Flocculating value 
Flocculating power
According to Hardy-Schulze rule: Flocculating power : Sn4  Al3  Ba2  Na 
45. Equimolar solutions of KCl and compound X in water show depression in freezing point in the
ratio of 4 : 1. Assuming KCl to be completely ionized, the compound X in the solutions must:
(A) Dissociate to the extent of 50%
(B) Hydrolyze to the extent of 80%
(C) Dimerise to the extent of 50%
(D) Trimerise to the extent of 75%
Ans. D
Sol. mKCl  mX
Tf KCl Tf  X
 
iKCl i X
1
i X  
2
For trimerisation to 75% extent
1  3
i  1    1 
6  4
1
i
2
46. The process which is suitable for refining of Ti, Zr and Hf is
(A) Zone refining
(B) Mond’s refining
(C) Electrolytic refining
(D) Van-Arkel method
Ans. D
Sol. All 3 belong to same group and Van-Arkel method is used for this refining.
47. If the colour of Cr  H2 O 6  Cl3 is violet, than the colour for Cr  H2 O 5 Cl Cl2H2 O would be:
(A) Yellow
(B) Green
(C) Violet
(D) Red
Ans. B
Sol. Cr  H2 O 5 Cl Cl2H2 O is green in colour which is expected as Cl is WFL with respect to H2O
hence abs should increase.
48. NaAlSiO 4 is preferred for
(A) Production of silicones
(B) Removing permanent hardness of water
(C) Calculating strength of KMnO 4
(D) Manufacturing high quality soaps
Ans. B
Sol. NaAlSiO 4 is a Zeolite used for removing permanent hardness of water.
49. Acid rain can have a pH value of:
(A) 4.6
(B) 5.7
(C) 6.6
(D) 7.0
Ans. A
Sol. Acid rain has pH < 5.6.
50. Select the incorrect statement:
(A) Novalac is linear polymer
(B) Glyptal is a polymer of ethylene glycol and pthalic acid
(C) Bakelite is a cross-linked phenol formaldehyde polymer
(D) In manufacturing of tyre rubber, 10% of sulphur is used as a cross-linking agent
Ans. D
Sol. 5% of sulphur is used for manufacturing of tyre rubber
SECTION – B
51. The EMF of the cell M | Mn  0.02 M  || H 1M | H2  g1atm  at 25oC is 0.81 V. The valency of
metal if the standard oxidation potential of M | Mn is 0.76 V, is:
Ans. 00002.00
n
Sol. M  s   nH  Mn   aq  H2  g
2
n/2
Ecell  E  o0.059
log
 
Mn   PH 2
cell n
n H 
0.059
0.81  0.76  log  0.02 
n
n2
52. Calculate the entropy change involved to convert 2 Kg H2 O  g at 385 K to

 
H2 O    at 280 K in kJ kg1 k 1 , (magnitude only).
Given: specific heat of water liquid and water vapour are 4.2 and 2 kJ K-1 kg-1 respectively. Latent
heat of vaporization is 2491 kJ K-1 kg-1. [Take log385 = 2.58, log373 = 2.57, log280 = 2.45)
Ans. 00009.20
Sol. H2 O  g  H2 O  g  H2O     H2 O   

385 K 373 K 373 K 280 K
T2
S  mCn
T1
 373 
S1  2  2  2.303log    0.1267
 385 
Hcondensation 2491
S2    6.67
T 373
 280 
S3  2  4.2  2.303log    2.409
 385 
STotal  9.205 kJ kg1 K 1
53. The number of – OH groups acquiring equatorial position in most stable form of
  D      Glucopyranose are:
Ans. 00003.00
Sol. HO CH2OH
O
HO
Only 3 are equitorial position.
OH
OH
54. The ideal limiting radius ratio of Ni  CO  4  is:
Ans. 00000.22
Sol. Ni  CO  4  is sp3 hybridised, hence tetrahedral.

Limiting ratio for tetrahedral is 0.225.
Zr
1/ 2
 Z   Zr  eao
55. Given  2s     2   , the distance from the nucleus of the radial node of 2s electron
 2ao   ao 
2
of Li ion is equal to xao (ao = Bohr radius). The value of x is:
Ans. 00000.67
Sol. For node,  22s  0   2s  0

 Zr 
2    0
 ao 
2a 2a
r  o  o  0.67ao
Z 3
56. 100 mL sample of tap water contain 18 mg MgSO 4 . If the hardness of sample (in terms of
x
CaCO3) is x ppm. Calculate ?
8
Ans. 00018.75
Sol. 100 mL H2 O 
 18 mg MgSO 4
 1 L 
 180 mg MgSO 4
180 mg
nMgSO4  nCaCO3 
120 g / mol
w CaCO3  150 mg in 1 L
 x  150 ppm
x 150
   18.75
8 8
57. Calculate P, if the amount of charge required (in terms of Faraday’s constant) is PF to reduce
12.3 g of nitrobenzene completely in acidic medium.
Ans. 00000.60
Sol. C6H5NO 2  C6H5NH2

Q  n  nf  F
12.3
  6F
123
58. The number of metal-metal bond in Fe2  CO 9  is/are:
Ans. 00001.00
Sol. O
OC
CO
OC Fe Fe CO
OC C CO
59. Calculate the isoelectric point for Aspartic acid

O
O 3 pK a1  COOH  1.88
1 OH
pK a2 NH2   9.60
OH NH2
2 pK a3  COOH  3.65
Ans. 00002.76
pK a1  pK a3 1.88  3.65
Sol. pI  
2 2
= 2.765
60. The sum of reaction numbers that can be used for preparation of diborane amongst given is
ether
1. NaBH4  BF3  
2. NaBH4  I2 
3. BF3  NaH 
Ans. 00006.00
Sol. All three reactions can be used.

 Sum is (1 +2 +3) = 6.
Mathematics PART – C
SECTION – A
61. If r  40, then the greatest possible value of

40
C0  60 Cr  40C1  60Cr 1  40 C2  60Cr 2 ..... 40 C40  60
Cr  40 is
200
(A) C50
60
(B) C50
100
(C) C50
200
(D) C100
Ans. C
40
Sol. C0  60 Cr  40 C1  60Cr 1  40C2  60Cr 2 ..... 40C40  60
Cr  40  100
Cr
This will be maximum when r = 50
62. The value of k for which the equation |x2 – 5x + 6| = k has three real and distinct roots is
(A) 4
(B) 2
1
(C)
4
1
(D)
2
Ans. C
Sol. |x2 – 5x + 6| = k has three real roots when the line y = k touches the parabola y = –(x2 – 5x + 6) at
vertex
D 1 1
 k    
4a 4 4
63. The number of ways in which letters of word IITJEE can be placed in the
squares of the figure as shown, so that no row remains empty, are
(A) 1620
(B) 810
(C) 5040
(D) 2520
Ans. A
6!
Sol. Arrangement of IITJEE is  180 ways 6 place can be selected by 3 C2  3 C2 ways
2!2!
Total ways = 9  180 = 1620
    
64. Let O be the origin and OA  3iˆ  2ˆj  kˆ , OB  î  ˆj  2kˆ and OC  OB  OA for some ,  > 0.
  
If OB  OC  83 and OC  14 , then
1
(A)  = 1,  
3
1
(B)  ,  2
3
1
(C)  , 1
3
1 2
(D)  , 
3 3
Ans. C
     
Sol. OB  OC    OB  OB     OB  OA   83
   3iˆ  7ˆj  5kˆ   83   = 1

Now, OC    î  ˆj  2kˆ    3iˆ  2jˆ  kˆ 

OC     3  î     2  ˆj   2  1 kˆ  14
1

3
1 1
65. Let E, F and G be three events, probability of event P  E  F   , P E  G  ,
2 3
1
P E  F  G  . For any event A, if AC denotes its complement, then P(E  F  GC) + P(E  G
6
 FC) is
1
(A)
3
1
(B)
6
1
(C)
2
2
(D)
3
Ans. C
Sol. P(E  F  GC) = P(E  F) – P(E  F  G)

P(E  G  FC) = P(E  G) – P(E  F  G)
66. The number of 3  3 matrices M with entries from elements of set {0, 1, 2, 3, 4} are there for
which the tr(M) = 5 are (where tr(M) denotes trace of matrix M)
(A) 12(56)
(B) 6(56)
(C) 21(56)
(D) 18(56)
Ans. D
Sol. Let diagonal elements are x1, x2, x3, then x1 + x2 + x3 = 5  x1  

 Coefficient of x5 in (x0 + x1 + x2 + x3 + x4)3  x2  
 18 
   x3 
Now, total matrices are 18(56)
67. A debate club consists 6 girls and 4 boys. A team of 4 member is to be selected from this club
including the selection of a captain and a vice captain (from among these 4 members) for the
team. If the team has to include atmost two boy, then the number of way of selecting the team is
(A) 2200
(B) 2220
(C) 380
(D) 2320
Ans. B
Sol. Number of way of selection of 4 girls = 6C4

Number of way of selection of 3 girls, one boy = 6C3·4C1
Number of way of selection of 2 girls and 2 boys = 6C2·4C2
Now, number of way of selection of one captain and one vice captain = 4C2·2!
Total way =  6 C4  6 C3  4 C1  6C2  4C2  4C2  2!
x2 y2
68. The value of b for which the common tangent to ellipse   1 and the parabola y2 = 4x and
4 b2
their chord of contact to parabola form an equilateral triangle
2
(A)
3
5
(B)
3
7
(C)
3
11
(D)
3
Ans. B
Sol. Let common tangent AB and AC, intersect on x-axis

(by symmetry) B
 ABC is equilateral if BAC = 60
1 1 A
 Slope of AB = ; Slope of AC  
3 3
1 2 2 2 5
  4m  b  b 
m 3 C
f  2  5h2  3h   f  2 
69. If f(x) be a differentiable function such that f(2) = 1, f(3) = 2, then lim equal
h 0 f  3  h2  2h   f  3 
to
1
(A)
4
1
(B)
2
3
(C) 
2
3
(D)
4
Ans. D
f  2  5h2  3h   f  2 
Sol. lim by L. Hospital Rule
h 0 f  3  h2  2h   f  3 
f   2  5h2  3h  10h  3  3
= lim 
h 0 f   3  h2  2h   2h  2  4
70. Equation of common tangent of parabola y2 = 12x and y2 = 16(x – 3) is
(A) 3x  y  3  0
(B) 3y  x  9  0
(C) xy 3 0
(D) 3x  3y  3  0
Ans. B
Sol. Equation of common tangent to both parabola

3
y2 = 12x equation of tangent y  mx 
m
4 1
y2 = 16(x –3) ; y  m  x  3  
by comparing both slope = 
m 3
1 3
So, equation of common tangent y   x
3  1 
 
 3
71. The point on the curve x + y2 = 0 which is closest to the point (0, –3)
(A)  2, 2 
1
2
(B) (–1, –1)
(C) (–1, 1)
(D)  2,  2 1
2
Ans. B
1 1
Sol. For parabola y2 = –x equation of normal  y  mx  m  m3 this passes through (0, –3)
2 4
1 1
3  m  0   m  m3  m = –2
2 4
 1 2  1 
So, point will be (–a(–m)2, –2a(–m)) =    2  ,  2    2  = (–1, –1)
 4 4 
72. Let a, b, c be the sides, ma, mb, mc the lengths of the altitudes and da, db, dc the distances from
the vertices to the orthocentre in an acute triangle, then mada + mbdb + mcdc is equal to
(A) a2 + b2 + c2
(B) 2(a2 + b2 + c2)
a2  b2  c 2
(C)
2
(D) ab + bc + ca
Ans. C
Sol. Let D, E, F are altitudes from A, B, C respectively H be the A

orthocentre of ABC, then the ACD and HAE are similar
triangle
So, AD·AH = ma·da = AC·AE = AE·b similarly in ADB ad AHF F E
H
ma·da = AF·c
AF  c  AE  b BF  c  BD  a
So, ma·da = . Similarly mb  db  ,
2 2
B D C
CD  a  CE  b
mc dc 
2
Therefore mada + mbdb + mcdc

1
=  AE  b  AF  c  BF  c  BD  a  CD  a  CE  b
2
1 1
= BD  CD   a   AE  CE   b  BF  AF   c =  a2  b2  c 2 
2 2
1
73. Let consider a function defined in R, f  x   , then which of the following option is
1  e x 2
correct?
1
(A) lim f  x  
x 0 2
(B) f(x) is discontinuous at exactly one point in R
(C) f(x) is non differentiable at x = 0
(D) x = –ln 2 is point of inflection
Ans. D
1
Sol. f  x  is always continuous and differentiable in R
1  e x 2
2e x
f x  
1  ex 3
2e x  2e x  1
f   x   clearly x = –ln 2 is point of inflection
1  e x 4
74. The contrapositive of p  (~q  ~r) is
(A) (~q  r)  ~p
(B) (q  r)  ~p
(C) (q  ~r)  ~p
(D) (~q  ~r)  ~p
Ans. A
Sol. Contrapositive will be ~(~q  ~r)  ~p

 ~(q  ~r)  ~p
 (~q  r)  ~p
75. The mean square deviation of a set of n observations x1, x2, ….. xn about a point c is defined as
1 n 2
  xi  c  . The mean square deviation about –2 and 2 are 18 and 10 respectively, then the
n i 1
standard deviation of this set of observation is
(A) 3
(B) 2
(C) 1
(D) 4
Ans. A
1 n 2 1 n 2
Sol.   xi  2   10 and   xi  2   18
n i 1 n i 1
n n n n
2 2 2 2
   xi  2     xi  2   28n and   xi  2     xi  2   8n
i 1 i 1 i 1 i 1
n n n n
 2 x i2  8n  28n and 8 x i  8n   xi2  10n and  xi  n
i 1 i 1 i 1 i 1
n
 xi2   xi 
2
10n  n 
2
i 1
   =    3
n  n  n n
3
76. The value of the integral I    x  2   3  x dx is equal to
2

(A)
4

(B)
2

(C)
8
(D) 2
Ans. C
3
Sol. I    x  2   3  x dx put x = 2 cos2  + 3 sin2 
2

I
8
x
77. Let f : [0, )  R be a continuous and strictly increasing function such that f 4  x    t  f 3  t  dt 
0
x > 0. The area enclosed by y = f(x), x-axis and the ordinate at x  2 2 is
(A) 2 2
2 2
(B)
5
2 2
(C)
3
8
(D)
3
Ans. C
x
x x2
Sol. f 4  x    t  f 3  t  dt  f   x    f  x   c , f(0) = 0
0
4 8
x2
 c = 0 ; f x 
8
2 2 2 2
x2  x3  2 2
Area =  dx    
0
8  24  0 3
x2 y 2
78. Tangents are drawn from any point of the hyperbola   1 to the circle x2 + y2 = 1, then the
9 4
locus of midpoint of chord of contact is
x2 y2 2
(A)    x2  y2 
2 3
x2 y2 2
(B)   3  x2  y2 
9 2
x2 y 2 2
(C)   3  x2  y2 
9 4
x2 y2 2
(D)    x2  y2 
9 4
Ans. D
Sol. Let any point on hyperbola is (3 sec , 2 tan )

Equation of chord of contact (3 sec )x + (2 tan )y = 1 ….. (1)
Also, let midpoint (h, k) of chord of contact so equation of chord
xh + yk = h2 + k2 ….. (2)
3 sec  2 tan  1
Equation (1) and (2) are equal   2
h k h  k2
2 2
h k
 sec2  – tan2  = 1  2
 2
1
9  h2  k 2  4 h2  k 2 
79. Three circles are tangent to each other and to the straight
line. The radii of the circles with centres A, B and C are 4, 9, r
respectively, then r is equal to B
A
(A) 1.42
(B) 1.43
(C) 1.44
(D) 1.45
Ans. C
Sol. If two circle touches each other externally, then

Lext = 2 r1r2 when r1 and r2 are radii of circles
 2 4.9  2 r  4  2 r  9
36
 r
25
2 2
80. Orthogonal trajectories of family of the curve x 3  y 3  a where a is an arbitrary constant, is
2 2
(A) x3  y3  c
2 2
(B) x 3  y 3  cx
4 4
(C) x3  y3  c
4 4
(D) x 3  y 3  cx
Ans. C
2 2
Sol. x 3  y3  a
1 1

3

3
dy
Differential equation : x y 0
dx
1 1

3

3
dx
Orthogonal differential equation : x y 0
dy
4 4
Curve x 3  y 3  c
SECTION – B
 
81. If z lies on locus arg(z – 1 – 2i) = and arg(z – 1 + 2i) = , then the number of complex number
4 6
which satisfy both the locus
Ans. 00000.00
Sol. As both of ray

 
arg(z – 1 – 2i) = the originate ray (1) from z1  (1 + 2i) and having argument and ray (2)
4 4
 
arg  z  1  2i   is originating from (1, –2) having argument
6 6
So, arg(ray 1) > arg(ray 2) they will never intersect
82. If z lies on locus ||z – 2| – |z + 2|| = 2, then the min|z – 4| is
Ans. 00003.00
x2 y 2
Sol. z lies on hyperbola  1
1 3
x3  1 2x 2
83. If bx5 + cx4 + dx3 + ex2 + fx + g = is an identity in x, where b, c, d, e, f, g are
4x 3 5x
constants, then |f| is equal to
Ans. 00005.00
Sol. Differentiate once both side and put x = 0

3x 2 4x x 3  1 2x 2
  5bx 4  4cx 4  3dx 3  2ex  f
3 2
4x 5x 12x 5
 f = –5
84. Let S = {(i, j, k) ; 1  i < j  k  20 ; i, j, k, {1, 2, ….., 20}}, then total number of elements in set S
are
Ans. 01330.00
20
Sol. Case-1: 1  i < j < k  20 = C3
20
Case-2: 1 < i < j = k  20 = C2
20 20 21
So, total elements = C3  C2  C3  1330
100 100 100 100 2k1  1

85. The value of C0  C3  C6  C9 ..... 100C99 is , then k1 – k2 is equal to
k2
Ans. 00097.00
Sol. 1  x 100  100

C0  100
C1x1  100
C2 x 2 ..... 100C100 x100
1  1100  100
C0  100
C1  100
C2  100
C3 ..... 100 C100
1   100  100 C0  100
C1  100
C2 2 ..... 100 C100 
1  2 100  100C0  100C12  100C2  ..... 100 C100 2
2100  200  100  3  100
C0  100
C3  100
C6  100
C9 ..... 100 C99 
100
2 1 100 100 100 100
 C0  C3  C6  C9 ..... 100C99
3
86. Suppose that f : R  R is continuous and satisfies the equation f(x)·f(f(x)) = 1 for all real x.
Assuming that f(1000) = 999, then the value of f(10) is
Ans. 00000.10
1
Sol. We have f(1000) = 999 ; f(1000)·f(f(1000)) = 1 ; f  f 1000   
999
1
So, the range of f contains and 999 so by intermediate mean value theorem. Let f(a) = 10
999
1
So, f(a)·f(f(a)) = 1 ; 10f(10) = 1 ; f 10    0.1
10
n
1
87. If a > 0, p  2 evaluate the value of lim
n 
p p
r 1 n  ra
Ans. 00001.00
Sol. By Squeeze Play Theorem

n
1 1 1 1 1 n
p p
 p p
 p p
, then n  p p
 p p p
n  na n  ra n a n  na r 1 n  ra np  a
n n
n n 1
lim p  lim  p  1  lim  p
n 
np  na n r 1 np  a n  p
r 1 n  ra
n 1
 1 
88. If lim  tan1  2    , then [] is equal to (where [.] denotes greatest integer function)
n 
k 1  2k 
Ans. 00000.00
n 1
 1  1  k  1  k  1   1   n  
Sol. tan1  2   tan    tan    nlim  tan1  2k 2   nlim tan1  
 2k   k  1  k  
k 1    n  1 4
89. A rectangle with sides parallel to the coordinate axes is to be inscribed in the region enclosed by
the graphs of y = x2 and y = 4, then maximum length of its perimeter is _____ (in unit)
Ans. 00010.00
Sol. Perimeter = 2(2) + 2(4 – 2) (–, 4) (, 4)

dP
P = 4 + 8 – 22 extrema when  0  4  4   = 1
d 2 2
(–,  ) (,  )
d2P
 4  0 local maxima at  = 1
d 2
So, perimeter P = 4 + 8 – 22  4 + 8 – 2 = 10
90. Suppose that a, b, c d are positive real numbers satisfying (a + c)(b + d) = ac + bd, then the
a b c d
smallest possible value of    is
b c d a
Ans. 00008.00
Sol. Apply A.M.  G.M.

a c  b d  ac bd 
        2  
b d c a  bd ac 
 ac  bd 
 2 
 abcd 
  a  c  b  d 
 2 
 abcd 
 2 ac  2 bd 
 2 
 abcd 
8
FIITJEE
JEE (Advanced)-2022
FULL TEST – III
PAPER –1
TEST DATE: 18-01-2022
decimal places.
MARKING SCHEME
marking scheme:
correct option;
AITS-FT-III (Paper-1)-PCM-JEE(Advanced)/22 2
Physics PART – I

1. A small block of mass m lies above a thin disk of total

mass M, constant surface density  , and radius R. A
hole of radius R/2 is cut into the center of the disk, m M
allowing the mass to pass though. The mass starts at a h R/2
position along the central axis of the disk but is displaced
R 
a height h from the plane of the disk, where h << R.
There are no other external forces at work on this
system; i.e., the disk and block are out in deep space.
Assume m << M. For the first order in h the block
undergoes simple harmonic motion with respect to the
centre of the plane of the disk, compute the period of
oscillation of block.
2R
(A) T
G
R
(B) T
G
R
(C) T
2G
(D) None of these
Ans. A
Sol. m

x
g  2G 1  cos 
 x   x
g  2G 1    2G 1  
 R  x2
2
  R
m
3 AITS-FT-III (Paper-1)-PCM-JEE(Advanced)/22
 x  x 
g  2G  1     1  
  R   R / 2 
2G
g x
R
2R
T
G
2. Consider a metal can placed coaxially inside a long solenoid. The metal can be modelled as a
thin cylindrical shell of radius r. The magnetic field due to the solenoid varies with time t as kt
where k is a positive constant. The resistivity of the can is  and its breaking stress is  . Ignore
the self-inductance of the can and any currents induced in the flat surfaces of the can. Assume
that the magnetic field produced by the induced currents is negligible. Compute the time at which
the can breaks.

(A) t
r 2K 2
2
(B) t
r 2K 2

(C) t
2r 2K 2

(D) t
3r 2K 2
Ans. B
Sol.
Can
Solenoid
Emf is included in the can
dB 2
Emf  r  Kr 2
dt
  2r
R
A
r
i AK
2
A
A
i2rB
From the diagram
i  2rB  2A
2
t 2 2
r K
3. A motor is installed at the top of a pole rigidly fixed on a

platform. A light rod of length r = 1 m is rigidly attached
to the motor shaft at its one end and at the other end a
small ball of mass m is attached. The rod can rotated in 
a vertical plane with the help of the motor. Total mass of m
the platform, the pole and the motor is   4 times the
mass of the ball. The motor rotates the rod at a constant
angular velocity. The platform is placed on a horizontal
surface, where coefficient of friction is   1/ 3. At
which minimum angular velocity 0 of the rod, will the
platform start sliding?
(A) 0  2rad / s
(B) 0  3rad / s
(C) 0  5rad / s
(D) None of these
Ans. C
Sol.

r
  
F on ball+m g  mw 2 r
  
F on platform=m g mw 2 r
5mg
m 2r  0  5rad / s
1  2
4. A ring of mean radius r and cross-sectional area A is made of a

perfectly conducting wire. Inductance L of the ring is so small that
inertia of free electrons cannot be neglected in the current building
process. The free electron density in the conductor is n, mass of an
electron is m and modulus of charge on an electron is e. Initially the
ring is placed ina uniform magnetic field with its plane parallel to B
induction vector B of the field as shown in the figure. Find the current
ring after it is turned through an angle 90°.
Br 2
(A) i
m  r
L
ne2 A
B r
(B) i
m  r
L
ne2 A
Br 2
(C) i
m  2r
L
ne2 A
B  2 r
(D) i
m  r 2
L
ne2 A
Ans. C
Sol. For perfect conductor R = 0 Enet = 0 in loop net  constant

net  self  k  ext
   
=Li  Lki  B A  Lneti  B A
ml
LK  (Where m = mass of one electron, l = loop length)
ne 2 A
As  is constant i   f
 
Initially i  0 & B  A
net  0
Finally   BA ' Lneti
Br 2 Br 2
i 
Lnet m  2r
L
ne2 A

This section contains SIX (06) questions. Each question has FOUR options (A), (B), (C) and (D). ONE OR
5.
L1
L2
For the given figure consider their mutual inductance is M then
L1L 2  M2
(A) Leq  When mutual inductance is not opposing
L1  L 2  2M
L1L 2  M2
(B) Leq  When mutual inductance is not opposing.
L1  L 2  2M
L1L 2  M2
(C) Leq  When mutual inductance is opposing.
L1  L 2  2M
L1L 2  M2
(D) Leq  When mutual inductance is opposing.
2L1  3L 2  2M
Ans. AC
L1L 2  M2 L1L 2  M2
Sol. Leq  & Leq  (Opposing)
L1  L 2  2M L1  L 2  2M
6. In a photoelectric effect experiment, a point source of light of power 40W emits mono-energetic
photons of wavelength 1 that can just exit photoelectrons from an isolated metallic sphere of
radius 1 cm, placed at a distance of 1 km from the light source. Now, three other sources of
wavelength  2 , 3 and  4 which are emitting the same number of photons as that of 1 brought
o o
-6
near the source of 1. Assume photo efficiency of 10 (Take 1  4960 A,  2  4133.33 A,
o o o
3  5000 A,  4  7200 A and hc=12.400 eV  A )
(A) Number of photoelectrons emitted from the sphere per second is 2.5  109
(B) The potential of the sphere when emission of photoelectron stops is 0.8 V.
(C) The potential of the sphere when emission of photoelectrons stops is 0.5 V.
(D) The time after which the emission of photoelectrons will stop is 1.39  103 sec .
Ans. ACD
P
Sol. I
4R2
P R=1M
Energy incident  Ir 2
P  r 2 
No. of Photons incident/sec  
4R2 hc
For 1 no. of photon incident/sec 2.5  1015
Photo electric effect for 1 &  2 only.
h    K max  K max  0 For 1 
12400 12400
E2   3ev =  2.5ev
4133.33 4960
Vs  0.5volt
KQ
 Vs  Q2  ne
r

7. A dog running with a constant speed v is chasing a cat that is running with a constant velocity u .
During the chase, the dog always heads towards the cat. At an instant, direction of motion of the
dog makes angle  with that of the cat and the distance between them is r.
uv sin 
(A) The magnitude of acceleration of dog at this instant is .
r
vr
(B) Radius of curvature of path followed by dog at this instant is .
usin 
uv cos 
(C) The magnitude of acceleration of dog at this instant is .
r
ur
(D) Radius of curvature of path followed by dog at this instant .
v cos 
Ans. AB
Sol. Acceleration of dog = Normal acceleration.

C
an
D
   
A  A f  A i  A i   A .
dv vd v sin 
a   v 
dt dt r
2
v vr
R  .
an usin 
8. A small bead of mass m can slide on a frictionless fixed ring of radius r.

With the help of two identical strings of force constant k, the bead is
A
connected to two nails A and B each on a diameter at a distance 0.5 r
from centre O of the ring. Relaxed length of each string is negligible as
O C
compared to the radius of the ring. The bead is given a small velocity at
point C. What can you predict about subsequent motion of the bead
B
before any of the string strikes a nail? [ignore gravity]
(A) It will keep moving with its initial speed.
(B) It will oscillate simple harmonically about the point C.
(C) Its angular momentum about centre O of the ring is conserved.
(D) Total elastic potential energy stored in both the strings is 1.25kr2.
Ans. AC
 
Sol. F  2 k r toward 0.

0  0
1  2 r2 
P.t  k  r    1.25kr 2
2  4
9. A solid paraboloid of base radius R0 and height h0 is having uniform volume mass density of s is
Inverted and placed just above the surface as shown, of a liquid having volume mass density of
L . When paraboloid is released from rest it has been observed that when it becomes completely
submerged in the liquid the paraboloid comes to the rest again. There exist uniform gravity of g.
Assume that the liquid body is very large so that liquid level is not changing as the paraboloid
enters into the liquid.
R0
s h 0
L
(A) The phenomenon is true for all paraboloids irrespective of their dimensions as long as
density ratio is maintained.
(B) The phenomenon is not true for all paraboloids irrespective of their dimensions as long as
density ratio is maintained.
L
(C) The ratio of is 2.
s
L
(D) The ratio of is 3.
s
Ans. AD
Sol. Let Y  ax 2 ( A parabola)

H 2
Y x ( from given data)
R2
Fup
x
y y
a R
H
mg
x
dy
v
dt
1 dv
mg  L  x 2 y  g  m 
2 dt
dv x2 ygL L x 2 yg
 g g  g  
dt R2H s R 2 H
2s
2
dv L 2
v  g  gy
dy s
0 H
L 2
 vdv   (g 
0 0 s
gy ) dy
gL
o  gH  H
3s
L
3
s
10. A ideal gas having f degrees of freedom is kept inside a thermally insulated vessel, the vessel
has two large pistons each with charge of +Q and -Q. Assume charges are uniformly distributed.
Pistons can move without friction inside the vessel. At an instant the charge of pistons is
increased k times with the help of an external agent. Then which of the following statements are
correct
+Q -Q
Vacuum Vacuum
Gas
K2  f
(A) The Ratio of final to initial temperature of gas in equilibrium is .
2f
2K 2  f
(B) The Ratio of final to initial temperature of gas in equilibrium is .
2f
(C) Work done by the agent in the process is (K 2  1)nRT1 where T1 is initial temperature.
Q2L1
(D) Work done by the agent in the process is  K 2  1 where L1 is initial separation
A 0
between pistons.
Ans. BCD
Sol. Stage 1
+Q -Q
Vacuum Vacuum T1
Gas
L1
Q2 nRT1
P1AL1  nRT1  P1A  (Force Balancing)
2A 0 L1
Stage 2
Charge is suddenly changed
KQ -KQ
Gas T1
L1
System is not in equilibrium
Stage 3
KQ -KQ
T2 L 2 CL1
Gas
L2
Finally system in equilibrium
K 2 Q2 nRT2
P2 AL 2  nRT2  P2 A 
2A0 L2
Energy of the system is conserved between stage 2 and 3.
1 f 1 f
 0E22 AL1  nRT1  0E22 AL2  nRT2
2 2 2 2
On solving all the above equation
T2 2K 2  f Q2L1
 w ext  K 2  1  K 2  1 nRT1
T1 2f 2A0

INTEGER.
11. A conducting sphere with inner radius R and outer radius 3R

has some alloys mixed in it due to which its resistivity
changes with radial distance r according to the function
r  Kr, where K is a +ve constant. Inner surface of the
R
sphere is grounded while outer surface of sphere in
maintained at potential V0 with the help of a battery of emf V0. 3R
Battery is ideal. The potential of the sphere at radial distance + V0
n a -
of 2R is V0 . Find (a + b).
n b
Ans. 5
Sol. V0  I Req
dr
3R
Rr
Req   dR
r dr
Req  
4r 2
3R
Kdr K
Req    Req  n(3)
R 4 r 4 
K r 
R(r)  ln  
4  R 
V
V(r)  IR(r)  0  R(r)
Req
n2
V  2R   V0
 n3
12. In the circuit shown in the figure the electromotive force of the
battery is 9 V and its internal resistance is 15  .The two V1 V2
identical voltmeters can be considered ideal. Let
st 10 20
V1 and V1' reading of 1 voltmeter when switch is open and
nd
closed respectively. Similarly, V2 and V2' be the reading of 2
15
voltmeter when switch is open and closed respectively. Then 9 V
V '  V2
find the value of 2 .
V1  V1'
Ans. 1
Sol. When switch is open
Current in circuit
9
I A  0.2A
45
V1  V2  6V and because in series same current passes and voltmeters are identical so
V1  V2  3V
When switch closed
V1'  2V;V2'  4V
V2'  V2 4  3
 1
V1  V1' 3  2
13. The given thin lenses have R1 R2

R1  R2  10cm and 1  1, 2  2 and 3  4. If final
R  100cm
image formed at object and value of ‘d’ is x  10 cm .
Find ’x’. 1  2 3
O
30cm  d cm 
Ans. 7
Sol.
1 2 3
3 1 3  1 3   2
  
v u R1 R2
4 1 2 1 4  2
  
v 30 10 10
v  30
2
3
1
30cm  d cm 
d  30  100

This section contains THREE (03) questions stems. There are TWO (02) questions corresponding to
each question stem. The answer to each question is a NUMERICAL VALUE. If the numerical value has
more than two decimal places, truncate/round-off the value to TWO decimal places.
Question Stem
There is a hollow prism with hexagonal base of side L0 and height H0 as

shown. There are identical non conducting uniformly charged solid spheres
are placed at each corner and two identical spheres at the centre of flat
hexagonal faces. The charges spheres have uniform density of d0 and
radius of R0 . What will be the flux passing through the shaded region and
average charge density    hexagonal prism. It is given that the flux passing
through the hexagonal flat surface is k times the total flux passing through
the prism.
R 3d
Take 0 0  1 SI units
0
doR0 3
&  1 SI units
L20H0
14. The value of s is _________
Ans. 00000.35
15. The value of d is _________
Ans. 00004.83
Sol.
1
1 s 
2
2  KT
61  22  total
61  2K total   total
1  2K  total qin
1    total 
6 0
Top view
q0 / 6
q0 q
qin  12. 2 0
6 2
4
 3q0  qin  3d0 R03
3
1  2k  4R03 d0
1  
6 0
1  2k  R0 3d0
s   0.35
3 0
qin
Average charge density 
Vprism
8 d0R03
d 2
 4.83
3 3 L 0 W0
Question Stem
One side of a thin metal plate is illuminated by the sun. When the air temperature is T0, the temperature
of the illuminated side is T1 and that of the opposite side is T2. The temperature of each sides be T1' & T2' ,
if another plate of double thickness is used.  Take T0  300 K, T1 =330 K, T2  320 K 
16. The value of T1'  K  is ___________
Ans. 00333.33
17. The value of T2' K  is ___________
Ans. 00316.67
Sol. Left face

Power from sun = P
T1 T2
To l
d d
  T1  T0     T1  T0 
dt dt
  4eAT03
kA  T1  T2 
P    T1  T0   ....(i) ( For left surface)

KA  T1  T2 
   T2  T0  (For right surface)

When thickness is doubled
P    T1 ' T0  

kA T1'  T2'  .....(iii)
2

KA T1'  T2' 
2

  T1'  T0  ......(iv)
on solving
2T 2  T1T2  T0  3T1  T2   T22
T1'  1  333.33k.
2  T1  T0 
T1T2  T0  T1  3T2   T22
T2'   316.67k.
2  T1  T0 
Question Stem
A boat is travelling in a river with a speed of 10 m/s along the stream flowing with a speed of 2 m/s. From
this boat, a sound transmitter is lowered into the river through a rigid support. The wavelength of the
sound emitted from the transmitter inside the water is 14.45 mm. Assume that attenuation of sound in
water and air is negligible. The frequency detected by a receiver kept inside the river downstream is f 0
and the transmitter and the receiver are now pulled up into air. The air is blowing with a speed 5 m/sec in
the direction opposite the river stream the frequency of the sound detected by the receiver is f 1.
(Temperature of the air and water = 20°C; Density of river water = 103 kg/m3; Bulk modulus of the water =
2.088  109 Pa; Gas constant R = 8.31J / mol  K; Mean molecular mass of air = 28.8  103 kg / mol;
Cp/Cv for air = 1.4)
Note: Boat velocity is with respect to ground & receiver is stationary w.r.t ground
18. The value of f0 (KHZ) is__________
Ans. 00100.69
19. The value of f1 (KHZ) is__________
Ans. 00103.04
Sol. Use doppler effect.

20. The compound (B) would be

O
(1) OH
(B)
(2) H
O
(A) OH (B)
O
HO
O
C
O
C
O
(C) (D)
OH
COOH
OH
OH
Ans. C
Sol.
O
O
OH OH O
COOH H COOH
C
O OH
O O OH
21. How many methoxy group present in the molecule of a compound (A) would be present by the
result of a Zeisel method. Treatment of compound (A) C20H11O 4N with hot conc. HI gives CH3I
indicating presence of methoxy group. When 4.24 mg of a compound (A) is treated with hot conc.
HI and CH3I thus produced is digested with alc. AgNO 3 , 11.62 mg of AgI is obtained.
(A) 1
(B) 2
(C) 3
(D) 4
And. D
AgNO3
Sol. C20H11O4N  HI 
 CH3I   AgI
1.24 11.62
 .013  0.05
329 235
No. of mole of AgI  4  mole of C20H11ON
22. The blue colour produced on adding H2 O2 to acidified K 2 Cr2 O7 solution and shaking with ether is
due to the formation of
(A) Cr2O3
(B) CrO42
(C) CrO3
(D) CrO5
Ans. D
ether
Sol. K 2Cr2 O7  H2 O2  H2SO 4   CrO5
(Blue)
23. A 0.001 molal solution of a complex [MA8] in water has the freezing point 0.0054o C . Assuming
100% ionization of the complex salt and Kf for H2O = 1.86 K-Kgmol–1, write the correct
representation of the complex.
(A) MA 8 
(B) MA 7  A
(C) MA 6  A 2
(D) MA 5  A 3
Ans. C
w  1000
Sol. Tf  i K f  i Kfm
M.W  W
.0054  i 1.86  .001
.0054
i  2.90
1.86  .001

24. A cation which form am amine complex ion with excess of NH3 is
(A) Ag
(B) Cu2
(C) Co2
(D) Al3
Ans. ABC

Sol. Ag  2NH3   Ag  NH3 2 
2
Cu2  4NH3  Cu NH3  4 
2
Co 2  6NH3  CO NH3 6 
25. Which of the following statements regarding P4O10 is correct?
(A) It is an anhydride of metaphosphoric acid
(B) It is a strong dehydrating agent
(C) In P2O5, each phosphorous is attached to three oxygen atoms through normal covalent
bond and also with another oxygen atom through a coordinate bond.
(D) The dehydrated product of HNO3 obtained by treating it with P4O10 is NO2.
Ans. ABC
Sol. HNO3 on dehydration gives N2O5
26. Choose the correct option(s) for the following set of reactions
(i) MeMgBr Conc. HCl
C6H10O Q S
(ii) H2O
(Major)
20%, H3PO4, 360 K
(i) H3/Ni HBr, benzoyl peroxide

T R U
(ii) B3/hv s (Major)
(Major) (Major)
(A) CH3 (B) CH3

H3C Br H3C Br
Cl Cl
(S) (T) (U) (S)
(C) CH3 (D) CH3

H3C Cl H3C Br
Br Br
(S) (U) (U) (T)
Ans. C
Sol. O
H 3C OH H3C Cl
(i) MeMgBr Conc. HCl
H2O
(Q) (S)
20%, H3 PO4 , 360K
CH3 CH3 CH3

Br
Br
H3/Ni HBr
Benzoyl peroxide
Br3/hv
(T) (R) (U)
27. The reaction(s) leading to the formation of 1, 3, 5 trimethyl benzene is/are
(A) O (B) heated iron tube

Conc. H2SO4 Me CH
373 K
(C) H3 C CH3 (D) CHO
(i) Br2/NaOH Zn/Hg(HCl)
(ii) H3 O
OHC CHO
(iii) sodalime
O O
Ans. ABD
Sol. CH3
O
conc. H2SO4
H 3C CH 3 Δ
H 3C CH3
CH 3
heated iron tube

Me C CH
873 K
H 3C CH 3
CHO CH 3
Zn/Hg(HCl)
CHO CHO H 3C CH 3
(A) If temperature coefficient is greater than zero, cell reaction is endothermic.
(B) If temperature coefficient is less than zero, cell reaction is endothermic.
(C) If temperature coefficient is less than zero, cell reaction is exothermic.
(D) If Ecell is negative then G is negative and cell reaction is spontaneous.
Ans. AC
 dE  E 2  E1
Sol.   , According to Nernst equation, on  in temp. E.M.F  es.
 dT  T2  T1
29. In which of the following pair of solution will the values of Vant Hoff factor be same?
(Assuming same dissociation)
(A) 0.05 M K 4 Fe  CN 6  and 0.10M FeSO 4
(B) 0.10 M K 4 Fe  CN 6  and 0.05 M FeSO 4 . NH4  2 SO 4 .6H2O
(C) 0.20 M NaCl and 0.10 BaCl2

(D) 0.05 M FeSO 4 . NH4 2 SO4 .6H2 O and 0.02M KCl.MgCl2 .6H2 O
Ans. BD
4
Sol. K 4 Fe  CN6   4K   Fe  CN 6 
i  5 No. of ions
FeSO 4 . NH4  2 SO 4 .6H2O  Fe 2  2NH4  2SO42
i = 5 = No. of ions

INTEGER.
+
30. Find the quantum numbers of the excited state of electrons (Let n1 and n2) in He ion which on
transition to ground state emit two photons of wavelength 30.4 nm and 108.5 nm respectively.
Find the sum of  n1  n2   ?
Ans. 7
1 2  1 1
Sol.  RH  z   2  2 
  n1 n2 
for n1  1 n2  ?
1 1 1
9
 1.09678  107  4  2  2 
30.4  10 1 n2 
n2  2
for n1  2 (first excited state), n 2  ?
1 1 1
9
 1.09678  107  4  2  2 
108.5  10 2 n2 
n2  5
sum of n1 & n2  2  5  7
31. A compound AB forms NaCl type crystals and another compound XY forms CsCl type crystals.
The formula. Mass of XY is three times that of AB but the cubic edge length of unit cell of AB
crystals is twice that of XY. Calculate the ratio of density of XY to that of AB.
Ans. 6
4  M1
Sol. Density of AB = ...(i)
Nar  13
Let molar mass of AB be M1 gm/mol and edge length of unit cell be  1(m) .
1 3M1 8  3  M1
Density of XY   …(ii)
 1 
3
Nar  13
Nar   
2
(ii) /(i) = 6
32. Size of ring in product formed C is?

R RCO3H
H
(B) (C)
R O
Ans. 5
Sol. R R R
H
R R +
O O R
OH
H
RCO3H R
R
Baeyer villager R
O O R OH
R
R O

Question Stem
For the following reaction scheme

i) O3 CH 3OH i) NaOCH3CH 3, etoh H3 O 100o
A B C D E
ii) HOOH H3 O ii) CH 3CH2CH2CH 2I
33. The molecular wight of B is ……………
Ans. 00132.00
34. The molecular weight of E is………….
Ans. 00116.00
Sol. (for Q. 33-34)

COOH COOCH3 COOCH3
H2C H2C HC
COOH COOCH3 COOCH3

H2C CH2 CH2 CH3
(B)
(A)
C5H8O4 (C)
(M.W=132)
H3O
COOH
Δ
H3C CH2 CH2 CH2 CH2 COOH H3C CH2 CH2 CH2 HC
( CO2 ) COOH
(E) (D)
C6H12 O2 (M.W = 116)
Question Stem
A 10–3 molal aqueous solution of a chromium complex having same number of ammonia molecule and Cl
ions freezes at 0.00558o C . If all the ammonia molecules are acting as ligands and the percent of
hydrogen in the complex is 4.6 (Given K f (H2 O)  1.86K Kgmol1 ) and assume 100% ionization self.
35. Find the number of Cl atom is complex is___.
Ans. 00004.00
36. The value of Vant Hoff factor is______.
Ans. 00003.00
Sol. (for Q. 35-36)

Let the molecular formula of the complex is Cr NH3  x Clx
 % H is in the complex
3x
 100  4.6
52  17x  35.5x
x  4.08  4
Now, Tf  i k f m
.00558
i 3
1.86  10 3
Question Stem
The isoelectric point (PI) is the PH at which the amino acid exists only as a dipolar ion with net charge

  
 
zero. Structure of lysine and aspartic acid are COOCH  NH3   CH2  4 NH2 and CO OCH  NH3  CH2COOH
   
respectively. The PKa1 ,PKa2 and PKa3 of the dictation lysine are 2.18, 8.95 and 10.53 respectively. The
PKa1 , PKa2 and PKa3 of the cation of aspartic acid are 1.88, 3.65 and 9.60 respectively.
37. Isoelectric point lysine is__________.
Ans. 00009.74
Sol. The dissociation of cationic form of lysine can be represented.
COOH COO COO COO

P 
Ka1
P  Ka2
PKa3
HC NH 3 OH HC NH 3 OH
HC NH 3 OH HC NH2
(CH 2)3 H (CH 2)3 H (CH 2)3 H (CH 2)3
CH 2NH 3 H2C NH 3 CH 2NH 2 CH 2NH 2
Net change (+2) (+1) (0) (–1)
PKa2  PKa3 8.95  10.53
PI    9.74
2 2
38. Isoelectric point of Aspartic acid is __________.
Ans. 00002.77
Sol. The dissociation of cationic form of Aspartic acid can be shown as

COOH COO COO COO
PKa1   P  Ka2  PKa3
HC NH 3 OH HC NH 3 OH
HC NH 3 OH HC NH2
CH 2 H CH2 H CH2 H CH2
COOH COOH COO COO
Net change (+1) (0) (–1) (–2)
PKa2  PKa2 1.88  3.65
PI    2.77
2 2

 1  1
39. Polynomial function f (x) satisfying the condition f(x)f    f(x)  f   . If f (10) = 1001, then
x x
f(20) is
(A) 7001
(B) 8001
(C) 8000
(D) None of these
Ans. B
 1  1
Sol. f(x)f    f(x)  f  
x
  x
let f(x)  an x  an 1x n 1  an  2 x n  2  .....  aa x  a0
n
 1 a a 1 n
f    nn  nn11  an 2  n2  ..........   a0
x x x x x
 1
f(x)  f    a0 an xn   an1a 0  an a1  xn1  xn2  a0 an2  a1an1  a2 an 
x
 1
f(x)  f    an x n  an1xn1  xn2 an2  ........  a1x  a0
x
a a a a
 nn  nn 11  nn  22  .......  1  a0
x x x x
an  1 a0  1 ; a1  a 2  a3  ......  an1  0
f(x)  x n  1
f(10)  10n  1  103  1
n=3
f(x)  x3  1
3
f(20)   20   1  8001
e x

sgn x  e x sgn x 
40. Let f  x   e and g  x   e  
  and   denotes the fractional and
, x  R where
integral part functions, respectively. Also h  x   log  f  x    log  g  x   then for real x, h  x  is
(A) An odd function
(B) An even function
(C) Neither odd nor an even function
(D) Both odd as well as even function
Ans. A
h  x   log  f  x  . g  x    log e     y   y   e sgn x

y  y x
Sol.
 ex , x  0
x 
 h  x   e sgn x   0, x  0
 e x , x  0

x
e , x  0

 h   x    0, x  0  h  x   h   x   0 for all x.
 e x x  0

x  11 y  2 z  8
41. The length and foot of the perpendicular from the point (2, -1, 5) to the line  
10 4 11
are
(A) 14, 1,2, 3 
(B) 14, 1, 2,3 
(C) 14, 1,2,3 
(D) None of these
Ans. C
Sol. Let co-ordinates of foot of perpendicular are (a, b, c)

a  11 b  2 c  8
Since   k
10 4 11
Then a  10k  11,b  4k  2,c  11k  8
Here all alternative give a = 1, then k = -1. So foot is (1,2,3) and perpendicular distance between
(1,2,3) and (2,-1,5) is 14 .
2 2
42. If x = 9 is the chord of contact of the hyperbola x  y  9 , then the equation of the
corresponding pair of tangent is
(A) 9x 2  8y 2  18x  9  0
(B) 9x 2  8y 2  18x  9  0
(C) 9x 2  8y 2  18x  9  0
(D) 9x 2  8y 2  18x  9  0
Ans. B
Sol. Equation of chord of contact

xh  yk – 9 = 0 ….(1)
x–9=0 …..(2)
h = 1 and k = 0
pair of tangent
SS '  T 2
2
x 2

 y 2  9  8    x  9  9x 2  8y 2  18x  9  0

43. Which of the following options are correct?
2
n 1 n  3 2
(A) n n n n n
( C0  C3  C6  .....)  2 ( C1  C2  C4  C5  .....)   4
 
 n
C1 n C2 n C 4 n C5  .....  1
(B) If a and b are two positive numbers such that a5 b2  4 then the maximum value of
log21/5  a 2   log21/2  b2  is equal to 4
(C) Constant team in ((((((x  2)2  2)2  2)2  2)2  2)2 .......2)2 is equal to 2
25
 25 C  25
C2   C3   25
C4 
(D) The coefficient of x 24 in  25 1  x   x  22 25  x  3
2
25 x  4
2
25  .....
 C0  C1   C2   C3 
25
 2 C25 
 x  25 25  is equal to 2925
 C24 
Ans. ABD
n
Sol. (A) 1  x  n C0  n C1x  n C2 x 2  n C3 x 3  ......  n Cn x n
1 i 3
Put x   where    
2 2
n
 n

C0  n C3  n C6  .....  ........   n

C1  n C 4  n C 7  ......    n
C 2  n C 5  n C8  ...... 2  1  
 1 i 3  1 i 3
 n
C0 n C3 n C6  .....    n
C1 n C4 n C7  .....   
 2  
2 
 n
C 2  n C 5  n C 8  .....   
 2 
2 
 
1 n i 3 n
 n
C0 n C3 n C6  .... 
2
 
C1 n C2  n C4  n C5  ...... 
2
  n
C1 n C 2  n C 4 n C 5  .....  2   
(B) a5 b2  4  5log2  a   2log2  b   2
y  10log2 a  4log2 b  40log2 a  log2 b
5log2  a   2log2 b 
A.M.  G.M.   10log2 a  log2 b
2
1
log2 a  log2 b   y  4,y  4 when 5log2 a  2log2 b  a5  b2  2
10
(C) For constant term put x = 0 and get constant term = 4

(D) Coefficient of x 24  1.25  2.24  3.23  ......  25.1  2925
44. a1,a2 ,a3 ,...... are distinct terms of an A.P. We call (p,q,r) an increasing triad if ap ,aq ,ar are in G.P.
where p,q,r  N such that p  q  r. If (5, 9, 16) is an increasing triad, then which of the following
options is/are correct
(A) If a1 is a multiple of 4 then every term of the A.P. is an integer
(B)  85,149,261 is an increasing triad
1 1
(C) If the common difference of the A.P. is , then its first term is
4 3
th
(D) ratio of (4k + 1)th term and 4k term can be 4
Ans. ABC
Sol. Let R be the common ratio of the G.P. and D be the common difference of A.P.
a5  a5 ,a9  Ra5 ,a16  a5R2
a9  a5  4D   R  1 a5  4D
a16  a9  7D  R  R  1 a5  7D
1 4 7
From equation (1)/(2), we get  R 
R 7 4
2 9a5
From equation (2) – (1), we get  R  1 a5  3D   3D
16
3 3 3 4D
 a1  4D   D  a1   1   D  a1 
16 16  4 3
e x 1 ex
45. If  x 2x dx  AF  x  1  BF  x  4   C and F  x    dx, then
2
 5x  4  x
(A) A  2 / 3
(B) B   4 / 3  e3
(C) A 2/3
(D) B   8 / 3  e3
Ans. AD
2x C D
Sol.  
 x  1 x  4  x  1 x  4
2x  C  x  4   D  x  1
 C  2 / 3, D  8 / 3
e x 1 x 1  2 / 3 8/3 
   x  1 x  4  2x dx   e  x  1  x  4  dx
2 8
  F  x  1  e3F  x  4   C
3 3
 A  2 / 3, B  8 / 3 e3
46. The vertices of a triangle ABC are A  (2,0,2), B  1,1,1 and C  1, 2,4  . The points D and E
divide the sides AB and CA in the ratio 1:2 respectively. Another point F is taken in space such
that the perpendicular drawn from F to the plane containing ABC , meets the plan at the point of
intersection of the line segment CD and BE. If the distance of F from the plane of triangle ABC is
2 units, then
7
(A) the volume of the tetrahedron ABCF is cubic units
3
7
(B) the volume of the tetrahedron ABCF is cubic units
6

(C) one of the equation of the line AF is r 2iˆ  2kˆ   2kˆ  î    R     

(D) one of the equation of the line AF is r  2iˆ  2kˆ   î  7kˆ    
Ans. AC
Sol. F A  2iˆ  2kˆ 
 3iˆ  ˆj  5kˆ 
D  
 3 
 4iˆ  4 ˆj  10kˆ 
 3 
 
E
P

C î  2 ˆj  4kˆ  
B  î  ˆj  kˆ 
 

CD : r  î  2ˆj  4kˆ  7 ˆj  7kˆ
3
  
 
  
BE : r  î  ˆj  kˆ  7iˆ  7ˆj  7kˆ
3

P  (iˆ  ˆj  3k)
ˆ
Area of tetrahedron ABCF
1 7
  Area of base triangle   height  cubic unit
3 3
  
AB AC  7ˆj  7k,
ˆ PF  PF  2 units
  7 ˆj  7kˆ 
PF  2   ˆj  kˆ  P.V. of F-P.V. of P
 49  49 
 
ˆ ˆ
P.V. of F=i+4k

  
Vectors equation of AF is r 2 î  ˆj    î  2kˆ 
47. Let the equation of a straight line L in complex form be az  az  b  0, where a is a complex
number and b is a real number, then
z  c iz  c 
(A) the straight line   0 makes an angle of 45° with L and passes through a
a a
point c (where c is a complex number)
z  c iz  c 
(B) the straight line  makes an angle of 45° with L and passes through a point
a a
c (where c is a complex number)
a
(C) the complex slope of the line L is 
a
a
(D) the complex slope of the line L is
a
Ans. ABC
Sol. Let P(z) be any point on the required line.


CP z c
Then, 
i.e. is a unit vector parallel to it
zc
CP
*P(z)
A(z1)
*
C(c) P(z)
45°
45°
B(z2)
Let A(z1) and B(z2) be two points on

z  z1
az  az  b  0 then 2 is a unit vector parallel to the line
z 2  z1
az  az  b  0
 
zc z  z1  i 4 
 2 e
zc z 2  z1
2 2
z  c  z 2  z1  i

 e 2
 z  c  z  c   z2  z1  z2  z1 
zc  z  z1 
 i  2 
zc  z2  z1 
 A(z1 ) and B  z 2  are on the line az  az  b  0 therefore az1  az1  b  0
az2  az  b  0
a z 2  z1
 
a z2  z1
z  c iz  c 
From equation (1) and (2) we get  0
a a
1/3
48. The function f  x   x  x  1
(A) has two inflection points
(B) has one point of extremum
(C) is non – differentiable
(D) Range of f  x  is  3  28/3 ,  

Ans. ABCD
Sol. f  x   x1/3  x  1
df  x 
4 1/ 3 1 1 1
 x  . 2/3  2/ 3  4x  1

dx 3 3 x 3x
 f  x  changes sign from –ve to +ve, x  1 / 4 , which is point of minima.
Also f  x  does not exist at x  0 as f  x  has vertical tangent at x  0 .
4 1 1 2 1 2  1 2  2x  1
f " x  . 2/3  . . 5/3  2/3 2    2/3 
9 x 3 3 x 9x  x  9x  x 
1
 f "  x   0 at x   which is the point of inflection at x  0, f "  x  does not exists but f "  x 
2
changes sign, hence x  0 is also the point of inflection.
From the above information the graph of y  f  x  is as shown.

INTEGER.
49. A, B, C and D cut a pack of 52 cards successively in the order given. If the person who cuts a
 
spade first receives Rs. 350 and if the expectation of A is  then   is equal to (where [.]
 64 
denotes greatest integer function)_________
Ans. 2
Sol. E = even of any one cutting a space in one cut
n  E  13 C1
n  S  52 C1
 
P(E)  1/ 4  p,P E  q
Probability of a winning  p  qqqp  qqqqqqp  .............
P 64
 3
  128
1 q 175
 
 64   2
 
x 2n1  ax 2  bx
50. Let f  x   lim . If f  x  is continuous for all x  R , then the value of a  8b is
n x 2n  1
Ans. 8
ax 2  bx for  1  x  1

a  b 1 x  1
 2
Sol. f  x  a  b  1
 x 1
 2
 1
 for x  1 or x  1
 x
a b 1
for continuity at x  1 we have a  b 
2
hence, a  b  1 (1)
for continuity at x  1
a  b  1 a  b  1 (2)
hence a  0 and b  1
51. A and B are two independent events. The probability that both A and B occur is 1/6 and the
probability that at least one of them occurs is 2/3. Find 8P  A   9P B  if P  A   P B  .
Ans. 7
Sol. P  A  B   P  A  P B   1/ 6  P  A  P B 
P  A  B   P  A   P B   P  A  B 
1 1
 2 / 3  PA   
6P  A  6
2
 6  P  A    5P  A   1  0  P  A   1/ 2,P B   1/ 3
So, 8P  A   9P  B   4  3  7

Question Stem
Consider the locus of the complex number z in the Argand plane given by Re  z   2  z  7  2i .
Let P z1 .Q  z2  . Be two complex numbers satisfying the given locus and also satisfying
 z   2  i  
arg  1
 z   2  i   2 
   R .
 2 
52. The minimum value of PR.QR where R represents the point (7, -2) is
(A) 25
(B) 12
(C) 10
(D) 50
Ans. 00025.00
2 2
Sol.  x  2   x  7   y  2
It is parabola
P
R
(7,-2)
2a
x=2 Q
2
PR RQ   4a
2
5
=4   
 2
=25
 z   7  2i  
53. arg  1 equals
 z   7  2i  
 1 
Ans. 00001.57
Sol. Re z  2  z  7  2i
Let P  z1  ,Q  z 2 
 z   2  i   
arg  1
 z   2  i   2 
  R 
 2 
z
z1 z2
Question Stem
T is the region of the plane x + y + z = 1 with x, y, z >0. S is the set of points (a, b, c) in T such that just
1 1 1
two of the following three inequalities hold: a  ,b  ,c  .
2 3 6
54. Area of the region T is
Ans. 00000.86
Sol. T is an equilateral triangle with the vertices at (1, 0, 0), (0, 1, 0) and (0, 0, 1)
3
 area of the region T is .
2
55. Area of the region S is
Ans. 00000.34
 1 1 1
Sol. Take a point P  , ,  on the plane x + y + z = 1
2 3 6
A(0, 0,1)
(5/6, 0, 1/6)
(0, 1/3, 2/3)
(1/2, 0, 1/2)
(0, 1/2, 1/2)
(1, 0, 0)B C(0, 1, 0)

(1/3, 2/3, 0) (5/6, 1/6, 0)
The region S is shown as shaded region.

3 3 2
Area of S 
2

4
 a  b2  c 2 , where a, b, c are sides of the small equilateral triangles
7 3
 .
36
Question Stem
x 1 y z 1
Consider the line   and the point C  1, 1, 2  . Let D be the image of C in the line.
2 1 2
56. The distance C from the line is
Ans. 00003.73
57. The distance of the origin of the plane through the line and the point C is
Ans. 00000.45
x2 y z 1
Sol.  
z 1 2
C(-1, 1, 2)
P 
(1, 0, -1) Q
CQ  CP sin 
 
CP L
= 
L
i ˆj kˆ
2 1 3
2 1 2 125
= 
4  1 4 3
FIITJEE
JEE (Advanced)-2022
FULL TEST – III
PAPER –2
TEST DATE: 18-01-2022
decimal places.
MARKING SCHEME
marking scheme:
are correct;
option;
Physics PART – I

1. A wire having a uniform linear charge density  , is bent in the form of a a1

ring of radius R. Point A as shown in the figure, is in the plane of the
ring but not at, the centre. Two elements of the ring of lengths a1 and r1
a2 subtend very small and equal angles at the Point A. They are at A
distances r1 and r2 from the point A respectively.
r2
a2
r1
(A) The ratio of charge on elements a1 and a2 is .
r2
(B) The element a1 produces greater magnitude of electric field at A than element a2.
(C) The element a1 and a2 produce same potential at A.
(D) The elements a1 produces greater potential at A than element a2.
Ans. ABC
Sol. dq1 = a1

dq2  a 2
dq1 a1  r1 r1
  
dq2 a2  r2 r2
kdq1 kdr1 
E1   2 
r12 r1 r1
1
E1 
r1
2. Four particles A, B, C and D of masses m A, mB, mC and mD respectively, follow the paths shown
in the figure, in a uniform magnetic field. Each particle moving with same speed. QA, QB,QC and
QD are the specific charge of particles A,B,C and D respectively :
X X X X X X X X X X
X X X X X X X X X X
X X X X X X X X Constant
X X
magnetic
X X X X X X X X fieldX X
X X X RX X X X X X X
X X X X X X X X X X
X X X AX X X X X X X
2R C
X X X X X X X X X X
B
X X X X X X X X X X
R
X X X X X X X X X X
X X X X X X X X D X X
(A) QA < QB <QC <QD
(B) QD < QB < QC < QA
(C) Charge on the particle B and particle D is of different nature
(D) Work done by magnetic force on the particle C is minimum as compared to other particle
Ans. B
Sol. Since B & revolve in opposite since, thus they are oppositely charged. From direction of motion of
the charges QA = + ve QB & QD  -ve QC  neutral
3. consider a metal rod of length L that is given a uniform acceleration as shown in figure (a) and an
identical rod rotating with constant angular velocity in figure (b).
B
a l
R
A B
A
l
Stationary conducting
(a) Circular Frame
(b)
(A) If VA and VB are potentials of end A and B respectively, then VA < VB in figure (a)
(B) If VA and VB are potentials of end A and B respectively, then VA > VB in figure (b)
ma
(C) Electric field inside rod has magnitude in figure (a)
e
m 2r
(D) Electric field inside rod has magnitude in figure (b)
e
Ans. ABCD
Sol. Due to psuedo force, electrons move from B to A.

a
A E B VA > VA
-ive +ive
In figure (b) electron moves from A to B
Region I Region II
4. There is a spherical glass ball of refractive index 1 and

another glass ball of refractive index  2 inside it as shown in 1
figure. The radius of the outer ball is R1 and that of inner ball is i2 B
r2 C
R2. A ray is incident on the outer surface of the ball at an A r1 O D
angle i1. Mark the correct options. i1
1
R1 R2 2
-1  sini1 
(A) The Value or r1 is sin  
 1 
 R 
(B) The value of r2 is sin1  1 sini1 
  2R2 
 sini2 
The value of r1 is sin   
-1
(C)
 2 
 R 
(D) The value of r2 is sin1  2 sini1 
 R
 2 1 
Ans. AB
Sol. 1 sinr1  sini1

 sini1 
 r1  sin1  
 1 
1
sini2  sinr2
2
1 R1 sini1
 sinr2
 2 R 2 1
 R 
r2  sin1  1 sini1 
 R
 2 2 
5. A bead is fixed on a rigid ring of radius r and of mass that

negligible as compared to that of the bead. Assembly thus formed
is held motionless on a horizontal floor with the plane of the ring
vertical and the bead on the top. Coefficient of friction between the
ring and the floor is  . Now the assembly is given a slight push so
that the ring starts rolling Acceleration of free fall is g. Choose the
correct statements.
(A) The angle rotated by the ring before it begins to slide tan-1   
(B) The speed of centre of the ring before it begins to slide  gR
-1
(C) The angle rotated by the ring before it begins to slide 2tan  
(D) The speed of the centre of the ring before it begins to slide.  2gR
Ans. BC
Sol. 

V
N
P N
VC is Horizontal only.
  

VP  VPC  VC
VP  0
Mechanical energy conservation,
1 2
mgR 1  cos    mVbead VBead  2v cos  / 2
2
gR  2sin2  / 2  2v 2 cos2  / 2
V = gR tan  / 2

em  Icm  0 As Icm  0
NR sin   N  R  R cos  
tan  / 2  
  2 tan1   
6. An adiabatic container of volume 4 V0 is divided into two equal parts by rigid fixed wall whose
lower half is conducting and upper half in non-conducting. Initially the right portion is divided into
two equal parts by a freely moving massless & non conducting piston. Section A has 2 moles, B
and C each has one mole of an ideal gas with adiabatic exponent    1.5. If the heater in left part
is switched on till the final pressure C becomes (125/27) Po. Mark the correct statements
Non Conducting
Po
B
A Vo
Po
2Vo Po
C
Vo
Conducting
205Po Vo
(A) Final temperature in section A
27R
5Po Vo
(B) Final temperature in section B
3R
205Po Vo
(C) Final temperature in section C
27R
368
(D) Heat supplied by the Heater Po Vo
9
Ans. ABCD
Sol. For piston to be in equilibrium

PB = PC
Process in B is adiabatic,
Process in A is Isochoric
At every instant Temperature of A = Temperature of C
For B
1.5 125 9Vo
P oV o = Po v1.5 V =
27 25
16Vo
Volume of C will increase by
25
41Vo
VC 
25
125 9Vo 5Po Vo
TB  Po 
27 25 3R
205 Po Vo
TC =   TA
27 R
Net work done by gas is zero as there is no pushing of surroundings.
Q Heater =  Usyst
368
Q Heater = Po Vo
9

answer.
A small bead starts sliding down a frictionless rigid helical wire frame. The axis of the R
helix is vertical, radius is R and pitch is h.
A h
Axis
7. In How much time, will the Bead descend a Height H?
2H h2  42R2
(A)
g h
H h2  42R2
(B)
g h
H h2  42R2
(C)
g 2h
(D) None of these
Ans. A
Sol. Motion along Helix = Motion in horizontal plane + Motion along Axis.
a t cos 
at
h a t sin 

2 R
Top view
an
v cos  a t ,cos 
a t  gsin 
A along Axis = a t sin   gsin2 .
1 2H 1 2H h2  42R2
H gsin2 . t=  
2 g sin  g h
8. How much force will the wire frame exert on the bead when the bead has descended a height H?
[Acceleration of free ball g]
h2  42R2  162H2
(A) 2mgR
h 2  4 2 R 2
mgR h2  42R2  162H2

(B)
h2  42R 2
mgR h2  2R 2  42H2

(C)
h2  4 2R 2
(D) None of these
Ans. A
Sol. N2
N1
mg
v cos 
2
2 2
m  v cos  
N= N N
1 2 N1  N2  mgcos 
R
v  2gH
2mgR h2  42R 2  162H2
N=
h2  42R2
A prism shaped Styrofoam of density styrofoam < water is held completely submerged in water. It lies with
its base horizontal. The base of foam is at a depth h0 below water surface and atmospheric pressure is
Po. Surface is open to atmosphere. Styrofoam prism is held in equilibrium by the string attached
symmetrically.
 Take : styrofoam  f ; water    .
l
ho
90o
PL
l 90°
9. Net force exerted by liquid on the Styrofoam is:
(A) 2 gl2L
(B) 2 gl2L
l2L
(C) g
2
(D)  gl2L
Ans. C
10. Magnitude of force on any one of the slant face of Styrofoam is:
(A)
 o  o 
P   g h  2l  Ll
 
  l 
(B) Po   g  ho    Ll
  2 
  l 
(C) Po   g  ho    Ll
  2 
  l 
(D) Po  p g  ho    Ll
  2 2 
Ans. D
l2L
Sol. Net force exerted by liquid on Styrofoam is buoyant force =  g
2
Average pressure on slant surface
 l 
Po  gho    Po  gho  
 2
Pavg 
2
 1 
  Po   gho  
 2 2
Force on any one of the slant surface
  l 
Po  p g  ho    Ll
  2 2 

INTEGER.
11. An arrangement consisting of slabs is show in the figure. When system is placed in situation (a)
with temperature difference is maintained between (1) and (2), equivalent thermal conductivity of
system is K and when system in changed to situation (b) and temperature difference is
maintained between (3) and (4) then equivalent thermal conductivity increases by 20%. Find
number of slabs in the arrangement.
d
l d
2l
k
d
(3) 2k
d nl (4)
(1) (2)
k 2k nk
nk
2l nl (b)
l (a)
Ans. 4
Sol. In first case

l  2l  .....  nl l 2l 3l nl
    ...... 
k eq A kA 3kA 3kA nkA
k eq1 
 n  1 k
2
In second case
k eq2 
 k1Ai
 Ai
kA '  2k  2A '   ......   nk  nA ' 

A ' 2A ' .....  nA '

 2n  1 k
2
 2n  1 k
6  n  1 k

3 5 2
9n + 9 = 10n + 5
n=4
12. A small boat is travelling downstream with velocity 5 m/s relative to river
flowing with speed 7/3 m/s. it encounters a log floating in the river at some
distance from itself. It turns by an angle of 37o and just crosses the edge of
the log after 8 sec. Find time taken by boat to just cross the edge of log if
log is kept fixed.
Ans. 6
Sol. Q
Vbr = 5
PQ = 5  8  4 0 m
37o w.r.t Ground
P Boat
  

Vb  Vbr  Vr
Velocity must be along PQ
vbr sin   vr sin37
sin   7 / 25
Vbr Vb Q
Q
P Vr
40
t  6 sec.
v br cos   v r cos 37o
13. A pendulum with massless string of length l and bob of mass m is

attached inside a railway carriage which is moving with speed v 0 as V0 V0
shown. Carriage is brought to rest uniformly by applying brakes.
When carriage comes to rest pendulum string is horizontal. Minimum
magnitude of retardation of carriage such that bob completes vertical
circular motion is (3k-2) ms-2. Find k. (g = 10 ms-2)
Ans. 9
Sol. Acceleration of train = a 

Motion of bob w.r.t. train:

Initially V bob /train  O
From A   B, pseudo force F = ma  acts on bob. Let bob turns through 180o and has
speed v’ at highest position
V’
1800
v
F 
F = ma A
(pseudo) at rest
W/E theorem A  B :
1
FR = mv 2  mgh
2
mv 2
 2  ma  mg …….(i)
R
B   C : Now train has stopped, a = 0,
No pseudo force acts on bob.
Conservation of Energy
1 1
mgR + mv '2  mv 2
2 2
mv '2 mv 2
  2mg
R R
T + mg = 2 (ma – mg) – 2mg [From eq. (i)]
On solving a  25m / s 2
3K – 2 = 25 K=9

Question Stem
Consider two neutral concentric conducting thin spherical shells of radii r and 3r. A particle of positive
charge Q is fixed at a distance 2r from the common center of the shells. The inner shell can be electrically
connected to the outer shell through a resistance R1 with the help of switch S1 and outer shell can be
grounded through a resistance R2 with the help of another switch S2 as shown.
H1 (total heat) is dissipated in the resistance R1 after the switch S1 is closed keeping the switch S2 open
until a steady state is reached:
S2
R1 3r
S1 +Q
r R2
2r
When steady state is reached after closing the switch S1, the other switch S2 is closed. Total Heat
dissipated after the switch S2 is closed until a new steady state is reached is H2.
Q2
(Take  108 SI units]
0 r
14. Then the value of H1 is ___________
Ans. 00000.56
Q2
Sol. H1 =
1920 r
15. Then the value of H2 is ___________
Ans. 00004.33
Q2
Sol. H2 
24 0r

Question Stem
A glass plate is placed above a glass cube of 2 cm edges in such a way that there
remains a thin air layer between them, see figure. Electromagnetic radiation of
d
wavelength between 400 nm and 1150 nm (for which the plate is penetrable) incident
perpendicular to the plate from above is reflected from both air surfaces and h
interferes. In this range only two wavelengths give maximum reinforcements, one of
them is 400 nm.  is the second wavelength. T is change in temp. necessary to warm
up the cube so as it would touch the plate. The coefficient of linear thermal expansion
is   8  106. the refractive index of the air   1 . The distance of the bottom of the
cube from the plate does not change during warming up.
Then,
16. The value of  (in nm) ______
Ans. 00666.67
17. The value of T (in o C) ______
Ans. 00003.10
Sol. 2d   2n  1  / 2 for constructive interference

4d

2n  1
4d 4d 4d
  4d, , , -------
3 5 7
As n   
4d
400   4d  400  2n  1
2n  1
400 31
 1150  30n  31 n> n = 2, 3, -----
2  n  1  1 30
4d 77
 1150  n  n = 0,1,2 ----
2 n  2  1 30
n = 2 (common)
4  1 d
 400 d = 500 nm.
5
d
L  L  T T  3.1o C .
L
 = 666.67 nm
Question Stem
A heavy steel ball held in contact with an extremely light steel ball at height h
= 5 3 m above a hard horizontal floor. The line joining the centres of the balls
makes angle   30o with a vertical. If all the collisions are elastic and sizes of
the balls are negligible as compared to the height h, the horizontal range of the
lighter ball. Is R & speed Just after collision is u.
Then,
h

18. The value of R (in m) is ______
Ans. 00120.00
19. The value of u (in m/s) is _____
Ans. 00034.82
Sol. Y
LOC
 v co s  v s in 
v cos  v
Heavy
Let velocity of light ball along LOC after collision is V1

V1 – v cos   2v cos 
V1  3v cos 
2
Speed u = v12   v sin  
 9v 2 cos2   v 2 sin2 
v 2  2gh
3 1 56gh
u  9  2gh   2 g h 
4 4 4
u  14gH  34.82 m/s
3v cos 
v s in 
Find Range R = 8hsin2  4cos 2   1
3  3 
R = 85 3    4   1  120m.
2  4 

20. Which of the following statement(s) is correct?
(A) Most four-coordinated complexes of Ni2 ions are square planer rather than tetrahedral.
3 3
(B) The Fe  H2 O  6  ions is more paramagnetic than the Fe  CN 6  ion.
(C) Square planar complexes are more stable than octahedral complexes.
4 3
(D) The Fe  CN 6  ion is paramagnetic but Fe  CN6   ion is diamagnetic.
Ans. ABC
4
Sol. Fe  CN6  has Fe 2 and have no unpaired electron, so it is diamagnetic and
3
Fe  CN6  has Fe 3 and having one unpaired electron, so it is paramagnetic.
21. Regarding the structure of compound, PBr2Cl  CH3 2 , which of the following is incorrect
statement(s)?
(A) Both CH3 occupy axial position

(B) Both Br occupy axial position
(C) One Cl and one Br occupy axial position.
(D) One CH3 and one Br occupy axial position
Ans. ABD
Sol. Cl
H3C
P less electronegative atom occupy equatorial position.

Br CH3
Br
22. Which of the following statement(s) is correct.
(A) In metallic carbonyls the ligand CO molecule acts both as donor and acceptor.
(B) The ligand thiosulphate, S2 O32 can give rise to linkage isomerism.
(C) The complex ferricyanide does not follow effective atomic number (EAN) rule.
(D) The complex Pt Py  NH3  NO2  ClBrI exist in eight geometrical forms.
Ans. ABC
Sol. In complex Pt(Py)(NH3 )(NO2 )ClBrI , 15 geometrical isomers exist.
23. In an oxide ions are placed with FCC unit cell in which B+3 ion occupy x% of octahedral void and
A+2 ion occupy y% of tetrahedral void, then what is incorrect about the unit cell?
(A) Formula is A 3B2 O6 in which x = 50% and y = 12.5%
(B) Formula is A 2B4 O 6 in which x = 50% and y = 50%
(C) Formula is AB2 O 4 in which x = 50% and y = 12.5%
(D) Formula is AB2 O 4 in which x = 12.5% and y = 50%
Ans. ABD
Sol. A1B2 O 4 of x = 50% and y = 12.5%

A 4B2O 4 of x = 50% and y = 50%
AB2 O 4 of x = 50% and y = 12.5%
A 4B1/2 O 4 of x = 12.5% and y = 50%
24. If E0Zn2 /Zn  0.76V,ENi

0
2
/Ni
0
 0.24,EFe 3
/Fe
0
 0.04V,ECd2
/Cd
 0.40V
Which is/are correct statements
(A) Zn2  Cd  Cd2  Zn , spontaneous
(B) Ni2  Cd  Ni  Cd2 , spontaneous
(C) Fe 3  Ni  Ni2  Fe, spontaneous
(D) Cd2  Zn  Zn2  Cd, spontaneous
Ans. BCD
Sol. E0cell is (+) ve, then cell reaction is spontaneous

E0cell  E(R.P) o(R.P)
cathode  E Anode
 0.76  0.40
 0.36 (Nonspontaneous)
25. Each of the following options contains a set of four molecules. Identify the option(s) where all four
molecule possess permanent dipole moment at room temperature.
(A) BeCl2 , CO2 , BCl3 , CHCl3
(B) NO2 , NH3 , POCl3 , CH3 Cl
(C) BF3 , O3 ,SF6 , XeF6
(D) SO 2 , C6H5 Cl, H2 Se, BrF5
Ans. BD
Sol. O Cl
N N H P Cl C H
O O H H Cl Cl H H
angular Pynomidal Tetrahedral but Tetrahedral but
attached atom are attaned atom are
different different
F F
Cl
Br
S Se
O O H H F F
F
angular Angular
square pyramidal

answer.
Imagine a universe in which the four quantum numbers can have the same possible values as in our
universe except the angular momentum quantum number "  " can have integral values of 0, 1, 2, 3
…….n (instead of 0, 1, 2……….(n -1) and magnetic quantum numbers “m” can have integral values of
    1 to 0 to    1 instead of  to 0 to   .
26. Electronic configuration of the element with atomic number 25, based on the above assumption
is.
(A) 1s2 ,1p6 ,2s2 ,1d10 ,2p5
(B) 1s2 ,1p10 ,2s2 ,1d11
(C) 1s3 ,1p9 ,2s3 ,2p9 ,3s1
(D) 1s6 ,1p10 ,2s6 ,2p3
Ans. D
27. Based on above assumption magnetic moment of the element with atomic number 18 is
(A) 24 B.M.
(B) 8 B.M.
(C) Zero B.M.
(D) 15 B. M.
Ans. B
Sol. (26 – 27)

1s6 ,1p10 ,2s6 ,2p3 ,2d
 spin only  n  n  2   2  2  2   8 B.M.
A compound (x) of molecular formula C8H8O is treated with two equivalent of Br2 in ether at 0oC in
presence of a base to give a substituted product (Y) of molecular formula C8H6OBr2. Compound (Y) on
treatment with alkali followed by HCl forms -hydroxy acid (z) of molecular formula C8H8O3. (x) forms an
oxime as well as showing positive iodoform test.
28. Compound (X) is
(A) O (B) OH
HC CH C H
HC CH3
(C) O (D) O CH CH2
C CH3
Ans. C
29. Compound (z) is
(A) OH O (B) OH O
C 6H 5 CH C OH H C C OC 6 H 5
(C) O O (D) OH OH
C 6H 5 C C H C 6H 5 C C H
H H
Ans. A
Sol. (for Q. 28-29)

(X) is likely to be a methyl ketone since it form an oxime as well as shown positive iodoform test.
Further degree of unsaturation of (x) is 5. Therefore (X) would be
C 6H5 C CH3
O O H2 O
2Br2 OH
C 6 H5 C CH3 C 6H 5 C CH (OH )2 C 6H 5 C C H
C 6H 5 C C H Br2
O O O
(X) (Y)
The formed compound undergoes intramolecular Cannizaro reaction.

INTEGER.
3
30. In how many number of molecule/ions central element is sp hybridized state.
ClO 2 , I3 , IF6 , BrF6 , ICl2 , CsBrCl2 , Br  XeO6 ,  CN  2
3 2
Co  NH3 6  , Ni  CN4  , Ni  CO  4 
Ans. 3
Sol. Only in ClO 2 , ICl2 , Ni  CO  4  is sp3 hybridized.
31. A saturated solution of a sparingly soluble salt MCl2 has a vapour pressure of 31.78 mm of Hg at
30oC. While pure water exert a pressure of 31.82 mm of Hg at the same temperature. Calculate
the solubility product of the compound at this temp. is approximately x  10 5 mol3L3 . Find the
value of x.
Ans. 5
Sol. Let the solubility of MCl2 be small/lit


MCl2(s)  2 
 M(aq)  2Cl(aq)
s 2s
Using Roult’s law
P0  Ps n

P0 N
31.82  31.78 3s

31.82 1000
18
On solving s = 0.0232 mol/lit
 Ksp  4s 3
 4.9  10 5  5  10 5
32. What are the number of total plane of symmetry in a cube?
Ans. 9
Sol. Plane of symmetry
Diagonal Plane of symmetric (6) Rectangular plane of symmetric (3)
(12 edge)

Question Stem
OCH 3
Mg HBr / 
 HBr  A 
(1 eq)
 B  C(C18H22 O 2 )
(1eq) (C10H13 OBr ) (C20H26 O2 )
HC CH CH3
33. Degree unsaturation of compound A is ________.
Ans. 00004.00
34. Degree unsaturation of compound B is________.
Ans. 00008.00
Sol. (for Q. 33-34)

In the case H+ from HBr gas to the double bond making it a carbocation that can be stabilized by
delocalization
OCH 3 OCH 3 OCH 3 OH OH
(A) (B) (C)
CH CH2 CH3 CH CH CH CH
Br H 5 C2 C2 H 5 H5 C 2 C 2 H5
Question Stem
Heavy metal compound (A) with a (+2) oxidation state on the central metal on heating produces a gas
(B). The element of gas(B) forms a paramagnetic oxide (C). (A) on treatment with a chromate salt
produces yellow crystalline p.p.t (D). (B) on reaction with water procures two acids (E), (F); (F) on heating
gives (B) {Atomic weight of Pb = 207, Ba = 137}
35. Molecular weight of compound (A) is_________.
Ans. 00331.00
36. Molecular formula of (E) is HNOx, the value of x is _______.
Ans. 00002.00
Sol. (for Q. 35-36)

1 K 2 CrO4
Pb(NO3 )2  PbO  2NO2  O2 , Pb(NO3 )2   PbCrO 4
(A) (B) 2 (D)
Disproportioration
NO2  H2 O  HNO3  HNO 2reaction
(F) (E)
1
2HNO3  2NO2  H2 O  O2
(F) 2
(C) is NO
Question Stem
An organic compound undergo number of parallel reaction can give product P1, P2, P3 ……….Pn. The rate
constant of these parallel reaction are K, 2K, 3K …….. nK and activation energy for each parallel reaction
is E, 2E, 3E ……….nE respectively.
E  2n  1
37. The overall activation energy of reaction is given by . The value of x is_______.
x
Ans. 00003.00
38. A reaction follow two parallel path have activation energies 100 and 200 kJ/mol respectively. Rate
constant of these parallel path are respectively 2  102 & 3  102 min1 . The overall activation
energy reaction in (kJ) is_____.
Ans. 00160.00
Sol. (for Q. 37-38)

P1
E
K,
2K, 2E
A 3K, 3 P2
E
nK, n
P3
E
Pn
Let rate cont. K 0  K  2K  3K  ........nE

E
 0
RT
K 0  Ae
E
dK 0  0  E 
 Ae RT  0 2 
dT  RT 
dK 0 E0
 K0
dT RT 2
1 dK 0 E
 02
K 0 dT RT
1  d E
 K  2K  3K  ........nK   02
K 0  dT  RT
1  K.E 2K.2K 3K.3E nk.nE  E0
K0  RT 2  RT 2  RT 2  ......... RT 2   RT 2
 
K.E 2 E
1  22  32  ...........n2   0 2
RT 2  RT
K.E     1
n n  1 2n
 E0
K 1  2  3  .....n  6
n  n  1  2n  1
 E0
n  n  1 6
2
 2n  1
E0  E
3
Overall activation anergy of two parallel path is given by
K E  K 2 E2
E 1 1
K1  K 2
E
100  2  10 2
 200  3  102 
2 2
2  10  3  10
800  102

5  102
 160

39. If D1, D2, D3,……...D1000 are 1000 doors and P1,P2P3 ............P1000 are 1000 persons. Initially all
doors are closed. Changing the status of doors means closing the door if it is open or opening it if
it is closed. P1 changes the status of all doors. Then P2 change s the status of D2, D4, D6,........
D1000 (Doors having number which are multiples of 2). Then P3 changes the status of D3, D6, D9 .
.......D999 (doors having number which are multiples of 3) and this process is continued till
P1000 changes the status to D1000, then the doors which are finally open is/are
(A) D961
(B) D269
(C) D413
(D) D729
Ans. AD
Sol. Dm will be open finally if m is the perfect square
40. f(x) = cos( |x| +[x] ), then
(A) f is continuous at x = 1/2
(B) f is continuous at x = 0
(C) f is differentiable in ( -1, 0)
(D) f is differentiable in (0, 1) .
Ans. ACD
Sol. f(x) = cos( |x| +[x])

f(0) =1, f(0 – 0) = cos( -1) = –1
 1 1   1
f(1/2) = cos   = 0 , f   0   cos    = 0,
 2 2  2
1  
f   0   cos  0
 2  2
for x  (0, 1) f(x) = cosx
for x  (-1, 0) f(x) = cos ( -x- 1) = - cos x .
41. If z1,z2 ,z3 ,z4 are complex numbers in an Argand plane satisfying z1  z3  z2  z4 . A complex
 z  z2   z3  z2 
number ‘z’ lies on the line joining z1and z4 such that Arg    Arg   . It is given that
 z1  z2   z  z2 
z  z4  5, z  z 2  z  z 3  6 then
(A) area of the triangle formed by z,z1z2 is 3 7 sq. units
15 7
(B) area of triangle formed by z,z3 ,z 4 is sq. units
4
27 7
(C) area of the quadrilateral formed by the points z1,z2 ,z3 ,z4 taken is order is sq. units
2
47 7
(D) area of the quadrilateral formed by the points z1,z2 ,z3 ,z4 taken is order is sq. units
3
Ans. ABC
42. Which of the following is/are correct?
(A) If A is a n  n matrix such that aij   i2  j2  5ij    j  i  I and j then trace  A   0
(B) If A is a n  n matrix such that aij   i2  j2  5ij    j  i  I and j then trace  A   0
(C) If P is a 3  3 orthogonal matrix, , ,  are the angle made by a straight line with OX, OY,
 sin2  sin   sin  sin   sin  
 
OZ and A   sin   sin  sin2  sin   sin   and Q  PT AP, then PQ6P T  32A
 sin   sin  sin   sin  sin2  

(D) Id matrix A  aij  33 and matrix B  bij  33 where aij  a ji  0 and bij  b ji  0  i and j
then A 6B7 is a singular matrix
Ans. ACD
Sol. (A) aij  a ji  aij  a ji  0  A is skew symmetric matrix

(B) A 2  2A  A 3  22 A  A 6  25 A
(D) A 6B7 is a skew symmetric matrix of odd order
43. If three normals can be drawn from the point (h, 0) to the parabola y 2  4x , then h can be
(A) any real number in the interval  , 3 
(B) any real number in the interval  4, 3 
(C) any real number in the interval ( , 4)
(D) any real number
Ans. ABC
Sol. (h, 0) satisfy the equation of the normal y  mx  2am  am3
dy x 2  y 2  1
44. The solution of  satisfying y(1) = 1 is given by :
dx 2xy
(A) a system of hyperbola

(B) a system of circles
(C) y2 = x(1 + x) – 1
2 2
(D) (x – 2) + (y – 3) = 5
Ans. AC
Sol. Put y2 = u
du u 1
We get  =  x , which is in linear form.
dx x x

answer.
Let y = f(x) is a curve and P(x, y) be any point on it. The tangent and the normal drawn at P meets x-axis
at T and N respectively PT and PN are called length of tangent and length of normal at P. If M is the foot
of perpendicular drawn from P on x-axis, then MT and MN are called length of sub-tangent and length of
sub-normal at P. Answer the following questions.
45. The equation of the curves passing through (0, 1), if the length of sub-normal at any point of the
curve remains unity is
(A) y2 =  x + 1
x
(B) y2 =  1
2
(C) y2 =  2 x + 1
(D) y2 =  3x + 1
Ans. C
dy
Sol. y  1  y2 = 2x + 1
dx
46. The equation of the curve passing through (1, 2), if the intercepts of normal on x-axis is equal to
thrice of the abscissa of point P is
(A) 3x2 – y2 + 1 = 0
(B) x2 – 2y2 + 7 = 0
2 2
(C) 2x – y + 2 = 0
(D) x 2 – y2 + 3 = 0
Ans. C
dy 2 2
Sol. x+y = 3x; solving we get 2x – y + 2 = 0.
dx

1
m 1
If m  0, n  0, the definite integral I =
x (1  x)n1 dx depends upon the values of m and n and is
0
denoted by  (m, n), called the beta function.
1 1
e.g.  x 4 (1  x)5 dx  x
5 1
(1  x)6 1 dx   (5, 6) and
0 0
1 1
5/2  7 1
x (1  x)1/ 2 dx  x
7 / 2 1
(1  x)1/ 2 1 dx    ,  . Obviously,  (n, m) =  (m, n).
0 0
2 2
/2
2m
47. The integral
 cos  sin2n  d is equal to
0
1  1 1
(A)  m , n 
2  2 2
(B) 2 (2m, 2n)
(C)  (2m + 1, 2n + 1)
(D) None of these
Ans. A
Sol. Writing sin2  = x, we get 2 sin  cos  d = dx, and hence the given integral is equal to
/2
1 2m 1
 cos sin2n 1  (2 sin  cos ) d
2
0
1 2m 1 2n 1 1
1 1 m 1/ 2 n 1/ 2 1  1 1
  cos    sin  
2 2
=
2
0
2 2 dx 
2  1  x 
0
x dx   m  , n   .
2  2 2
 
x m 1 x n1
48. If  (1  x)
0
mn
dx  k  (1  x)
0
m n
dx , then k is equal to
m
(A)
n
(B) 1
n
(C)
m
(D) None of these
Ans. B
x z 1 dz
Sol. Writing  z, we get x = ,1+x= and dx = .
1 x 1 z 1 z (1  z)2
1 1
zm 1 dz
L.H.S. =  (1  z) m 1
1  z m n 2
 z
m 1
(1  z)n1 dz =  (m, n)
0
(1  z) 0
 n 1
x
=  (1  x)
0
m n
dx .

INTEGER.
49. If the least value of the area bounded by the line y = mx +1 and the parabola y  x 2  2x  3 is 
6
where m is a parameter then the value of is ________
32
Ans. 2
Sol. A    y1  y 2  dx where ,  are the


roots of x 2  2x  3  mx  1, on solving we will get
 ,0 
,0 
1 2 3/2 32
6

m  4m  20  : Hence  
3
6
 2
32
2 2 2 1
50. The shortest distance between 1  x    x  y    y  z   z 2  and 4x+2y+4z+7=0 in 3 -
4
dimensional coordinates system is equal to _________
Ans. 2
Sol. Let a  1  x
b xy
c  yz
dz
1
then a+b+c+d=1 and a2  b2  c 2  d2 
4
2 2 2 2 2 2
  a  b    a  c    a  d  b  c   b  d   c  d  0
abcd
3 1 1
x  , y  ,z 
4 2 4
 3 1 1
So the distance from the point  , , 
4 2 4
3  1 1 7
From the plane 4x  2y  4z  7  0 is 2
6
51. The equation of the plane passing through the intersection of the planes 2x  5y  z  3 and
x  y  4z  5 and parallel to the plane x  3y  6z  1 is x+3y+6z=k, where k is
Ans. 7
Sol. Equation of plane passing through the intersection of the planes 2x  5y  z  3 and x+y+4z=5 is
 2x  5y  z  3     x  y  4z  5   0
  2    x   5    y  1  4   3  5  0 .... i 
Which is parallel to the plane x  3y  6z  1.
2   5   1  4
Then  
1 3 6
2   5   1  4
Then,  
1 3 6
11
 
2
from eq. (i)
7 21 49
   y  21z  0
2 2 2
 x  3y  6z  7
Hence, k = 7


Question Stem
Experiment -1: Let ‘S’ be the sample space obtained when two different coloured unbiased coins are
tossed. Two subsets P and Q (of two elements each) are randomly chosen from S one after another with
replacement.
Element obtained in P and Q are recorded.
Experiment -2: The same two coins used in the previous experiment are tossed. The outcomes are
recorded.
If the outcomes obtained in experiment 2 matches with nay of the outcomes of experiment 1, then both
the experiments are declared ‘successful’.
(Note that experiment ‘2’ is conducted after experiment 1)
52. Probability that ‘success’ is from ‘P’ but not from ‘Q’
Ans. 00000.25
Sol. Case  1: n P  Q   0
Let SP denote ‘success’ from P, then
4
1  E1  1 C2

P SP  SQ   P   

  .
 n  P  Q   0  2  C2 
2
2 4
Case  2 : n P  Q   1  n P  Q   3
1  E1  1 4 C3 3 C1  2

P SP  SQ   4
P  
 n P  Q   1  4 2
.
 
4
C2  
Case  3 : n P  Q   2

P SP  SQ  0 
P S P  SQ   122  121  41 .
53. Probability that there is no ‘success’ if experiment 1 is conducted after experiment 2
Ans. 00000.25
Sol. Case  2 : n P  Q   0
 n P  Q   4

 P SP  SQ  0 
Case  2 : n P  Q   1  n P  Q   3
3
C1  2 1

P SP  SQ   2

6
.
 4
C2 
Case  3 : n P  Q   2  n P  Q   2
3
C2 1

P SP  S Q   2

12
.
 4
C2 
2 1 1

P SP  SQ     .
12 12 4

Question Stem
 
Let r is a position vector of a variable point in Cartesian OXY plane such that r  10ˆj  8iˆ  rˆ  40 and  
2 2
      8
p1  max  r  2iˆ  3ˆj  ,p2  min  r  2iˆ  3ˆj  . A tangent line is drawn to the curve y  2 at the point A
    x
with abscissa 2. The drawn line cuts x-axis at a point B.
54. p2 is equal to
Ans. 00003.40
 2
Sol. p2  min r  2i  3j


where r  10ˆj  8iˆ  rˆ  40 

take r  xiˆ  yjˆ
 xiˆ  yjˆ   10  y  ˆj  8  x  î 
 x  8  x   y 10  y   40
x 2  y 2  8x  10y  40  0
2 2
 x  4   y  5  1 (i)
2
xiˆ  yjˆ  2iˆ  3ˆj
2
  x  2  î   y  3  ˆj
2 2 2
  x  2    y  3   minimum distance of  x, y  from  2,3  
C
(-4,5)
Q
(-2,3)
P
2
= PQ 
2
= PC  1
2

= 2 2 1 
=8+1-4 2  9  4 2
 
55. AB OB is
Ans. 00003.00
Question Stem
Let   0 and  C denotes the determinant of cofactors, then  C   n 1, where n (>0) is the order of  .
56. If a, b, c are the roots of the equation x 3  px 2  r  0, then the value of

bc  a 2 ca  b2 ab  c 2
ca  b2 ab  c 2 bc  a2 is (if p = 0.9)
ab  c 2 bc  a2 ca  b2
Ans. 00000.53
2
Sol.  a  b  c  p,ab  bc  ca  0,  a2  b2  c 2   a  b  c   2  ab  bc  ca   p2
a b c bc  a2 ca  b2 ab  c 2
If = b c a then  C  ca  b2 ab  c 2 bc  a2   3 1   2
c a b ab  c 2 bc  a2 ca  b2
2
a b c a b c a b c
 C  b c a  b c a b c a
c a b c a b c a b
a2  b2  c 2 ab  bc  ca ab  bc  ca p2 0 0
2 2 2
 ab  bc  ca a  b  c ab  bc  ca  0 p2 0
ab  bc  ca ab  bc  ca a2  b2  c 2 0 0 p2
57. If a, b, c are the roots of the equation x 3  3x 2  3x  7  0, then the value of

2bc  a2 c2 b2
c2 2ac  b2 a2 is
2 2 2
b a 2ab  c
Ans. 00000.00
3
Sol.  x  1  8  x  1  2, 2, 22
 x  1,1  2,1  22
 a  1,b  1  2,c  1  22
a b c2 a b c a c b 2bc  a2 c2 b2
 b c c  b c a b a c  c2 2ac  b2 a2
c a b c a b c b a b2 a2 2ab  c 2
FIITJEE
FULL TEST – III
JEE (Main)-2022
TEST DATE: 04-01-2022
answer.
AITS-FT-III-PCM-JEE(Main)/2022 2
Physics PART – A
SECTION – A
1. What are the dimensions of electrical permittivity?

–2 –2 –2
(A) ML T Q
–1 2 –3 –1
(B) M LT Q
(C) M–1 L–3T2Q2

–1 3 –2 –2
(D) M LT Q
Ans. C
Sol. Permittivity  
ch arg e2 
Q2
 M 1L3 T 2 Q 2
2
force  dis tan ce 
2 2
MLT  L
2. Two particles A and B are projected simultaneously in the directions vB= 10 3 m/s
shown in figure with velocities v A  25m/s and v B  10 3 m/s. If they vA=25m/s
collide in air after 2s, the angle  is
 60°
x
(A) 30°
(B) 45°
(C) 53°
(D) 37°
Ans. D
Sol. For collision, vB= 10 3 m/s

vA sin  = vB sin 60°
vA=25m/s
3
25 sin  = 10 3   60°
2
x
3
sin  =
5
or = 37°
3 AITS-FT-III-PCM-JEE(Main)/2022
3. A uniform chain of length L has one of its end attached to the wall at
A
3L
point A, while of the length of the chain is lying on table as shown 37°
4
in figure. The minimum co-efficient of friction between table and chain
so that chain remains in equilibrium is
(A) 1/3
(B) 1/4
(C) 3/4
(D) 1/5
Ans. B
L F
Sol. F cos 37  g N
4 T f
T
(where  is the mass/length of the chain). L
g 3L
F sin 37  T  f  N 4 g
4
1 1
    min 
4 4
4. A block of mass m is released from rest when the extension in the k
spring is x0. The maximum downward displacement of the block is
Mg
(A)  x0
2k
Mg
(B)  x0
2k
2Mg
(C)  x0
k
2Mg
(D)  x0
k
Ans. A
Sol. If block M moves a distance of x the extension in spring increases by 2x.

By work energy theorem,
1
k[ x02  ( x 0  2 x ) 2 ]  Mgx  O
2
1
 k ( 4 x 2  4 xx0 )  Mgx  O
2
1
k ( 4 x  4 x 0 )  Mg
2
Mg
x  x0 
2k
Mg
x  x0
2k
5. A particle is projected with such a velocity that its range is R. The particle
undergoes elastic collision with a wall placed at a distance of x (> R/2). x
The horizontal distance of point of projection and point where particle
hits the ground is R
(A) R+x
(B) x–R
(C) 2x – R
(D) R + 2x
Ans. C
Sol. Since collision is elastic, the horizontal velocity reverses its direction.
6. A ball of mass m is attached to the end of a thread fastened to the top of a O

vertical rod which is fitted to a horizontally revolving round table as shown. If w
l
the thread forms an angle  with the vertical, the angular velocity  of table
is r
g
(A)
l cos 
r
(B)
g tan 
g tan 
(C)
r  l sin 
g tan 
(D)
r
Ans. C
Sol. T sin   m 2 R Tcos

T cos   mg T 
2 R Tsin
tan  
g
mg
g tan  g tan 
  R= r+lsin
R r  l sin 
7. An artificial satellite of mass m is moving in a circular orbit at a height equal to the radius R of the
earth. Suddenly due to internal explosion the satellite breaks into two parts of equal masses. One
part of the satellite stops just after the explosion. The increase in the mechanical energy of the
system (satellite + earth) due to explosion will be
(Given: acceleration due to gravity on the surface of earth is g)
(A) mgR
mgR
(B)
2
mgR
(C)
4
3mgR
(D)
4
Ans. C
m m
Sol. Conserving momentum during the explosion mv   0  v' or v' = 2v
2 2
1m 1 1
Increase in the mechanical energy = K + U = K + 0 = ( 2v) 2  mv 2  mv 2
2 2 2 2
GMm mgR  GM 
=  v  
4R 4  2R 
8. A container has two immiscible liquids of densities 1 and 2 (>

1). A capillary tube of radius r is inserted in the liquid so that
its bottom reaches upto the denser liquid. The denser liquid
rises in the capillary and attains a height h from the interface of h 1
the liquids, which is equal to the column length of the lighter
liquid. Assuming angle of contact to be zero, the surface
tension of heavier liquid is 2
(A) 2r 2 gh
 2 rgh
(B)
2
r
(C)  2  1 gh
2
(D) 2r  2  1 gh
Ans. C
2T r
Sol. P0  h1 g   2 gh   P0 , T   2  1 gh
r 2
9. A cylindrical vessel contains a liquid of density  upto a height h. The liquid

is closed by a piston of mass m and area of cross-section A. There is a m, A
small hole at the bottom of the vessel. The speed v with which the liquid
comes out of the hole is: (neglect presence of atmosphere)
h
v
(A) 2 gh
 mg 
(B) 2 gh  
 A 
 mg 
(C) 2 gh  
 A 
mg
(D) 2 gh 
A
Ans. B
Sol. Applying Bernoulli’s theorem at 1 and 2

mg 1 2 m, A
gh   v
A 2 h
1 2
v
 mg 
or v  2 gh  
 A 
10. Find the natural frequency of the system as shown in figure. The pulleys are
massless and frictionless. k
2 k
(A)
 m
1 k
(B)
2 m
4 k
(C)
 m
8 k
(D)
 m
Ans. A
Sol. Let m is displaced downward by x from its mean position then spring will stretched by x0  4 x .
x0 2 2 k
 x , m x  4 kx0  16 kx  f 
4  m
11. A stationary wave is set up on a string fixed at both ends. The distance between two consecutive
nodes is 18 cm at a particular mode of vibration and for the next higher mode of vibration in the
same string the distance between two consecutive nodes is 16 cm. The length of string is
(A) 144 cm
(B) 140 cm
(C) 36 cm
(D) 32 cm
Ans. A
1 
Sol. n  n  1 2 … (i)
2 2
(Given  1 = 36, 2 = 32)
n=8
n 1
 l  l = 144 cm
2
12. The give curve represents the variation of temperature as a function of T

volume for one mole of an ideal gas. Which of the following curves
represents the variation of pressure as a function of volume?
To 45°
(A) P (B) P
V V
(C) P (D) P
V V
Ans. A
Sol. T  V tan 45  T0

T  V  T0
PV
For one mole of an ideal gas T 
R
PV
  V  T0  ( P  R ) V  RT0
R
Hence graph is rectangular hyperbola given in option (a).
13. A solid conducting sphere having a charge Q is surrounded by an uncharged concentric

conducting hollow spherical shell. The potential difference between the surface of solid sphere
and the outer surface of the hollow shell is V. If the shell is now given a charge of –3Q, the new
potential difference between the same two surfaces is
(A) V
(B) 2V
(C) 4V
(D) –2 V
Ans. A
Sol. In the given situation potential difference is independent of charge on outer shell.
14. A potentiometer wire AB is 100cm long and has total 10V

resistance of 10. Find the value of unknown resistance R so
that null point is obtained at a distance 40 cm from A.
40cm
C B
A
E = 5V G
r = 1
(A) 1
(B) 2
(C) 3
(D) 4
Ans. D
10 5
Sol.  40  5   1  R = 4
100 R 1
15. A conducting wire bent in the form of a parabola y  2 x carries a

2 y i A
current i = 2A as shown in figure. This wire is placed in a uniform
 2.0
magnetic field B  4kˆ tesla. The magnetic force on the wire is O x(m)
(A) –16 iˆ
(B) 32 iˆ
(C) –32 iˆ
(D) 16 iˆ
Ans. B
 
Sol.     
Fm  2 4  ˆj  4  kˆ = Fm  32iˆ
16. A very long uniformly charged rod falls with a constant velocity V through the +
center of a circular loop. Then the magnitude of induced emf in loop is (charge +
+
per unit length of rod = ) +
+
+
+
+
0
(A) V 2
2
0
(B) V 2
2
0
(C) V
2
(D) zero
Ans. D
Sol. Magnetic flux linked with the loop is always zero.

So induced emf is also zero
17. A capacitor of capacity 2 F is charged to a potential difference of 12V. It is then connected

across an inductor of inductance 0.6 mH. The current in the circuit at a time when the P.D. across
the capacitor is 6.0 V is
(A) 0.6 A
(B) 1.2 A
(C) 2.4 A
(D) 3.6 A
Ans. A
1 10 5
Sol.  
LC 12
q  q 0 cos t
2  10 6  6  2  10 6  12 cos t
1 
cos t   t 
2 3
dq
i   q0  sin t
dt
i=6A
18. A thin converging lens of refractive index 1.5 has power of +5D. When this lens is immersed in a
liquid, it acts as a diverging lens of focal length 100 cm. The refractive index of the liquid is
(A) 2
15
(B)
11
4
(C)
3
5
(D)
3
Ans. D
1 2 =1.5
Sol. P  (  1)
f R 
2
P  (1.5  1)  5
R
R = 20 cm
Focal length of this lens in medium (  ' )
1    2  1.5  2
   1    1
f '  '  R  '  20
 1  1. 5  1 1.5 1 9
   1   1 
10  ' 1 ' 10 10
15 5
'  
9 3
19. Unpolarized light of intensity 32Wm–2 passes through three polarizers such that transmission
axes of the first and second polarizer makes and angle 30° with each other and the transmission
axis of the last polarizer is crossed with that of the first. The intensity of final emerging light will be
–2
(A) 32 Wm
(B) 3 Wm–2
(C) 8 Wm–2
(D) 4 Wm–2
Ans. B
Sol. I 0  32 Wm -2
I0
After passing through first polarizer, I 1  = 16 W/m2
2
2
After passing through second polarizer, I 2  I1 cos 30  12 W/m2
2
After passing through third polarizer, I 3  I 2 cos 60  3 W/m2
20. When photons of energy 4.25 eV strike the surface of a metal A, the ejected photoelectrons have
maximum kinetic energy TA eV and de Broglie wavelength A. The maximum kinetic energy of
photoelectrons liberated from another metal B by photons of energy 4.70 eV is
TB  (T A  1.50) eV. If the de Broglie wavelength of these photoelectrons is B = 2A, then
choose the incorrect statement.
(A) the work function of A is 1.25 eV
(B) the work function of B is 4.20 eV
(C) TA = 2.00 eV
(D) TB = 0.5 eV
Ans. A
Sol.  B  2 A  4TB  TA
TB  TA  1.5
TB  0.5 eV
T A  2 eV
 A = 2.25 eV and B = 4.2 eV
SECTION – B
21. A binary star consists of two starts A (mass 2.2 MS) and B (mass 11 MS), where MS is the mass of
the sun. They are separated by distance d and are rotating about their centre of mass, which is
stationary. The ratio of the total angular momentum of the binary star to the angular momentum of
star B about the centre of mass is
Ans. 00006.00
L total (IA  IB )w m A rA2 11

Sol.   2
 1  1 6
LB IB .w mBrB 2.2
22. Degree of freedom for a gas is 6. This gas does 25 J of piston work at constant pressure. Net
heat absorbed by the gas during this process is ……… .
Ans. 00075.00
Sol. Work done at constant pressure is

 1
W   1    Q total
 r
 1
 25   1   Qtotal
 r
2 2
But, r  1  1
f 6
4
or r
3
 3
So, 25   1    Q total
 4
or Q total  100 J
So, net heat absorbed by the gas = 100 – 25 = 75 J
23. A thin plano-convex lens of focal length f is split into two halves. One of
the halves is shifted along the optical axis. The separation between
object and image planes is 1.8 m. The magnification of the image formed
by one of the half lens is 2. Find the separation between the halves.
Ans. 00000.60
v
Sol.  2 or u  2 u
u
When u = –x, then v = + 2x and x  v  1.8m
 3x  1.8m or x  0.60 m
24. A uniformly charged thin spherical shell of radius R carries uniform

surface charge density 6 per unit area. It is made of two hemispherical
shells, held together by pressing them with force F. The value of F will
2 2
be (Take,  R = 40)
Ans. 00002.00
Sol. For the given area total force will be u dA

When dA is the area, then electrical force per unit area
2
1 1    2
  0E 2  0   
2 2  20  2ge0
Projection area  r 2
 2  2
 Net electrical force    ( R )
 2 0 
In equilibrium, this force should be equal to the applied force,
2R 2 40
F  2
2 0 20
25. Find charge supplied by the cell after the switch is closed (in C)
Ans. 00016.80
Sol. The potential difference across 1 F and 2 F (uppermost) capacitor

must sum up to
q q/2 24
 6q C
1 2 5
24
 Answer is 12   16.8C
5
26. Light of wavelength 1800 Å ejects photoelectrons from a plane of a metal whose work function is
2 eV. If a uniform magnetic field of 5  10–5 tesla is applied parallel to plate, what would be the
radius of the path (in metre) followed by electrons ejected normally from the plate with maximum
energy.
Ans. 00000.15
Sol. Energy of incident photons in eV is given as

12431
E eV
1800
As work function of metal is 2eV, the maximum kinetic energy of ejected electrons is
KEmax  E  
 KEmax  6.9  2eV
 KEmax  4.9eV
If max be the speed of fastest electrons then we have
1 2
m max  4.9  1.6  1019 joule
2
2  4.9  1.6  10 19
  max 
9.1 10 31
  max  1.31 10 6 m/s
When an electron with this speed enters a uniform magnetic field normally it follows a circular
path whose radius can be given by
mv mv 2
r [As qvB  ]
qB r
9.1 10 31  1.31 106
 r
1.6  10 19  5  105
 r  0.149 m
27. A U tube contains water and methylated spirit separated by mercury. The mercury columns in the
two arms are at the same level with 10.0 cm of water in one arm and 12.5 cm of spirit in the other.
What is the relative density of spirit?
Ans. 00000.80
Sol. For water column in one arm of U tube, h1 = 10.0 cm; 1 (density = 1 gcm–3)
For spirit column in other arm of U tube, h2 = 12.5 cm; 2 = ?
As the mercury columns in the two arms of U tube are in level, therefore pressure exerted by
each is equal.
h11 10  1
Hence h11 g  h2  2 g or  2    0.8 g cm–3
h2 12.5
Therefore, relative density of spirit = 2 /1 = 0.8 / 1 = 0.8
28. In an -decay the kinetic energy of -particle is 48 MeV and Q-value of the reaction is 50 MeV.
The mass number of the mother nucleus is X. Find the value of X/4. (Assume that daughter
nucleus is in ground state)
Ans. 00025.00
my
Sol. We have K   .Q
my  m
A4 A4
 K  .Q  48  .50  A  100
A A
29. Electrons in hydrogen like atom (Z = 3) make transitions from the fifth to the fourth orbit and from
the fourth to the third orbit. The resulting radiations are incident normally on a metal plate and
eject photoelectrons. The stopping potential for the photoelectrons ejected by the shorter
wavelength is 3.95 volts. Calculate the work function of the metal (in eV).
7 –1
(Rydberg constant = 1.094  10 m )
Ans. 00002.00
Sol. For hydrogen like atom energy of the nth orbit is

13.6 2
En   Z eV/atom
n2
For transition from n = 5 to n = 4,
1 1  13.6  9  9
hv  13.6  9     16  25  2.754 eV
 16 25 
For transition from n = 4 to n = 3,
 1 1  13.6  9  7
hv  13.6  9      5.95 eV
 9 16  9  16
For transition n = 4 to n = 3, the frequency is high and hence wavelength is short.
For photoelectric effect, hv - W = eV0, where W = work function
5.95  1.6  10–19 – W = 1.6  10–19  3.95
 W = 2  1.6  10–19 = 2 eV
30. The convex surface of a thin concavo-convex lens of glass of

refractive index 1.5 has a radius of curvature 20 cm. The concave
surface has a radius of curvature 60 cm. The convex side is silvered
and placed on a horizontal surface. At what distance should a pin be
placed on optical axis so that image is formed at same place.
Ans. 00015.00
Sol. This silvered concavo-convex lens behaves like a mirror whose focal length can be calculated by
the formula
1 2 1
 
f f1 f2
f 1 = focal length of concave surface.
f 2 = focal length of concave mirror.
1 2 1 4
   
f 30 10 30
 f = –7.5 cm
Using mirror formula
1 1 1 1 1 1
      x  15 cm
f v u 7.5  x  x
SECTION – A
31. When the letters shown have their usual meanings, the velocity of photoelectrons is:
1/2
 2hc  0   
(A)   
 m  0 
2
 2hc  0    
(B)   
 m  0  
2hc
(C)
m
2
 m 
(D)  
 2hc 
Ans. A
Sol. KE  h(v  v 0 )
1 1 1 
mv 2  hc   
2   0 
2hc  0   
v2   
m   0 
32. Which of the following properties is not shown by NO?
(A) It is a neutral oxide
(B) It combines with oxygen to form nitrogen dioxide
(C) Its bond order is 2.5
(D) It is diamagnetic in gaseous state
Ans. D
Sol. NO has total 15 electrons and one electron is unpaired.
33. AlCl3 and FeCl3 can be separated from their mixture by using:
(A) NH4OH
(B) NaOH
(C) H2O
(D) magnetic method
Ans. B
Sol. AlCl3 dissolves in aqueous NaOH while FeCl3 gives brown ppt. of Fe(OH)3 which on separation
can again be converted to respective chlorides.
NaOH
AlCl3  3NaOH 
3NaCl
 Al(OH)3 
 Na[Al(OH)4 ]
solution
FeCl3  3NaOH 
3NaCl
 Fe(OH)3
(brown ppt.)
34. OH
+
 ; Major product is ........

(A) OH (B) OH
(C) OH (D) OH
Ans. A
Sol. OH
OH
+
(for 1,4-addition)
35. What is R in the following set of reactions?

COOH
CH2
SOCl AlCl
Zn/Hg/HCl

2
 P 

3
Q  R
(A) (B)
CH2
OH
(C) (D)
Ans. C
Sol. CH2 CH2
SOCl AlCl

2
 2

HO C C
Cl
O O
(P)
ZnHgHCl
 
O
(Q)
(R)
36. Which of the following species has the shortest bond length?
(A) NO2-
(B) NO+
(C) NO
(D) NO-
Ans. B
Sol. MOT of NO,

* *
1s2  1s 2  
2s2
 2s 2  
2px 2
 2py 2  2pz 2  px1  2py
10  5
B.O   2.5
2
For NO 
10  4
B.O.  3
2
For NO2 
10  7
B.O.   1.5
2
10  6
For NO  ,B.O.  2
2
1
Bond length 
Bond order
37. Consider the standard reduction potentials (in volts) as shown below. Find Eo.
0.936 0.576 1
SO24   SO32   S2O32
2
Eo  ?
(A) 0.326 V
(B) 0.425 V
(C) 0.756 V
(D) 0.512
Ans. C
Sol. Go  G1o  Go2

nFEo  nFE1o  nFEo2
4FEo  2F  (0.936)  2F(0.576)
4Eo  2  0.936  2  0.576
1.872  1.152
Eo   0.756
4
38. 100 mL of 0.2 M CH3COOH, 50 mL of 0.1 M HCl and 50 mL of 0.5 M NaOH are mixed together at
25°C If Ka (CH3COOH) = 10-5, then pH of the resulting solution will be;
(A) pH = 8
(B) pH = 9
(C) pH = 8.5
(D) pH = 9.5
Ans. B
Sol. (1) HCl + NaOH  NaCl+H2

5 25 0
0 20 5
(2) CH3 COOH + NaOH  CH3 COONa+H2 O

20 20 0
0 0 20
20
C  0.1M
200
1
pH  7  {5  log(0.1)}  9
2
39. Which of the following does not exist?
(A) PF5
(B) SF4
(C) BiI5
(D) BiI3
Ans. C
Sol. BiI5 doesn’t exist due to the inert pair effect of Bi and reducing property of I--.
40. For equilibrium process S8(g)  4S2 (g) reaction starts with S8(g), at equilibrium V.D. of mixture
is found to be 64. Calculate degree of dissociation of S8.
(A) 2/3
(B) 1/3
(C) 4/3
(D) 5/3
Ans. B
Sol. S8  4S2
1 
32  8
1  3  2
32  4
1
 
3
41. What is the free energy change for the process:
H2 O(l, 10o C,0.28Pa,1 mole)  H2O
(s, -10o C,0.26 Pa, 1 mole)
Given that vapour pressure of water and ice at
-10°C is 0.28 and 0.26 Pa respectively.
14
(A) R  263  ln
13
13
(B) R  263  ln
14
13
(C) R  10  ln
14
(D) Zero
Ans. B
Sol. dG  VdP  SdT

dG  VdP (T=constant)
P   0.26 
G  nRT ln  2   263R ln  
 P1   0.28 
 13 
 263Rln  
 14 
42. Beryllium shows diagonal relationship with aluminium, which of the following is incorrect?
(A) Be2C like Al4C3 yields methane on hydrolysis
(B) Be, like Al is not rendered passive by HNO3
(C) Be(OH)2 like Al(OH)3 is basic
(D) Be forms beryllates and Al forms aluminates
Ans. C
Sol. Factual
43. Select the incorrect statement.
(A) In alkaline solution XeO3 forms xenate ions
(B) Perxenate ions can be formed by disproportionation of xenates in alkaline conditions
(C) In perxenates Xe is in +6 oxidation state
(D) Perxenates can act as oxidizing agents
Ans. C
Sol. Xenates (+6), Persenates (+8)

XeO3  NaOH  Na  [HXeO 4 ]
2[HXeO 4 ]  2OH  [XeO6 ]4   Xe  O2  2H2 O
44. Which one of the following pairs of isomers and types of isomerism are correctly matched-
(P) [Co(NH3 )5 (NO2 )]Cl2 and [Co(NH3 )5 (ONO)]Cl2 ... linkage
(Q) [Cu(NH3 )4 ](PtCl4 ) and [Pt(NH3 )4 ][CuCl4 ].... co-ordination
(R) [Pt(NH3 )4 Cl2 )] Br2 and [Pt (NH3 )4 Br2 ]Cl2 .....ionization
Select the correct answer using the codes given below:
(A) Q and R
(B) P, Q and R
(C) P and R
(D) P and Q
Ans. B
Sol. Factual
45. IUPAC name of the complex compound Na3 [Cr(O)2 (O2 )(O2 )2 (NH3 )] where half of the
coordination number are occupied by neutral ligands with magnetic moment   15 must be:
(A) Sodium amminedioxodioxygensuperoxochromate (III)
(B) Sodium amminedioxygendioxodisuperoxochromate (III)
(C) Sodium amminebisdioxygendioxoperoxochromate (III)
(D) Sodium amminebisdioxygendioxoperoxochromium (III)
Ans. C
Sol. Factual
46. An aqueous solution of colourless metal sulphate M, gives a white ppt., with NH4OH. This was
soluble in excess of NH4OH. On passing H2S through this solution a white ppt. Is formed. The
metal M in the salt is:
(A) Ca
(B) Ba
(C) Al
(D) Zn
Ans. D
Sol. Zn2   2NH3  2H2O  Zn(OH)2  2NH4

2
Zn(OH)2  4NH3  [Zn(NH3 )4 ](soluble)  2OH
Zn2  H2S  ZnS   2H

(white ppt)
47. A pale green crystalline metal salt of M dissolves freely in water. On standing it gives a brown ppt.
On addition of aqueous NaOH. The metal salt solution also gives a black ppt. On bubbling H2S in
basic medium. An aqueous solution of the metal salt decolourizes the pink colour of the
permanganate solution. The metal in the metal salt solution is:
(A) copper
(B) aluminium
(C) lead
(D) iron
Ans. D
Sol. The salt could be iron (II) sulphate, in the presence of NaOH and air is oxidised to ferric
hydroxide. On passing H2S forms FeS which is black in colour, potassium permanganate oxidises
Fe+2 to Fe3+ and itself get reduced to Mn+2 due to which the pink colour disappears.
48. In which of the following cases the compound written on right shows the mentioned phenomenon
more than the compound written on left?
(p)
(acidity)
(q) O O
Br
(acidity)
H H
(r) O
H3C
OEtH3C . (Nucleophilic attack)
O
. .
(A) p, q
(B) q, r
(C) p, r
(D) in all
Ans. B
Sol. Factual.
49. A mixture of organic compound responded positively for following reagents (X, Y, Z):
(i) PhSO 2Cl (i) Zn/NH4Cl
(X) (ii) KOH
;(Y) = 
(ii) Tollen's reagent
;
(Z) = Na metal.
The mixture has:
(A) OH NH2 NO 2
+ +
(B) NH2 COOH

+
(C) H3C CH2 CH CH 2 N CH3
NO 2 C2H5
C CH
+
(D) H C C CH2 CH2 N CH3
CH3
N O
OH
Ans. A
Sol. A primary amine gives positive test with Hinsberg reagent (PhSO2Cl), a –NO2 group gives
positive test with mulliken’s reagent (Zn/NH4Cl, Tollen’s reagent and an acidic functional group
gives positive test with sodium metal.
50. In Fishcher-Killiani synthesis, the anomeric carbon of the reactant:
(A) remains as carbonyl
(B) is lost as CO2
(C) becomes the new epimeric centre
(D) becomes a nitrile carbon.
Ans. C
Sol. Fischer-Killiani synthesis produces C-2 epimers.
SECTION – B
51. On the basis of the information available from the reaction;

4 2
Al  O2  Al2O3 ; G  827 kJ mol 1 of O2
3 3
The minimum EMF required to carry out electrolysis of Al2O3 is:
(1 F = 96500) C mol-1 of electrons)
Ans. 00002.14
Sol. 1 mol Al, n = 3 (electron exchanged)

4 4
mol Al,n   3  4
3 3
Go  nFE0  E0  2.14V
52. Calculate  (ratio of Cp and Cv) for triatomic linear gas at high temperature. Assume that the
contribution of vibrational degree of freedom is 75%:
Ans. 00001.18
3 3 11
Sol. Cv  R  R  4R   R;
2 4 2
11 13
Cp  R  R  R
2 2
Cp 13
  1.18
Cv 11
53. In the presence of excess of anhydrous SrCl2, the amount of water taken up is governed by Kp =
1012 atm-4 for the following reaction at 273 K
SrCl2 .2H2O(s)  4H2O(g)  SrCl2 .6H2O(s)
What is equilibrium vapour pressure (in torr) of water in a closed vessel that contains
SrCl2.2H2O(g)?
Ans. 00000.76
1
Sol. Kp 
PH42O( g)
1/ 4
 1 
 PH2 O(g)  
 K 
 p
 (10 )  10 3 atm
12 1/ 4
 K p  10 3  760  0.76 torr
54. Consider the following first order competing reactions:

k1 k2
X  A  B and Y  CD
If 50% of the reaction of X was completed when 96% of the reaction of Y was completed, the ratio
of their rate constants (k2/k1) is:
Ans. 00004.65
1 100
Sol. K 2  ln ...(i)
t 4
1 100
K 1  ln ....(ii)
t 50
K 2 ln 25
  4.65
K2 ln 2
55. If 0.50 L of a 0.60 M SnSO4 solution is electrolysed for a period of 30.0 min using a current of
2+
4.60 A. If inert electrodes are used, what is the final concentration of Sn remaining in the
solution?
[At. Mass of Sn = 119]
Ans. 00000.51
W 4.6  30  60
Sol. 2 
M 96500
2+
Moles of Sn reduced = 0.043
Initial moles of Sn2+  0.5  0.6  0.30;
2+
Remaining moles of Sn = 0.30 – 0.043
0.257
 [Sn2+ ]=  0.514M
0.5
56. 9.2 grams of N2O4(g) is taken in a closed one litre vessel and heated till the following equilibrium
is reached N2O 4 (g)  2NO2 (g)
At equilibrium, 50% N2O4(g) is dissociated. What is the equilibrium constant (in mol litre-1)
(molecular mass of N2O4 = 92)
Ans. 00000.20
Sol. N2O 4 (g)  2NO2 (g)

t = 0 0.0(1-) 2(0.1)
   0.5
[NO2 ]2
Kc 
[N2 O 4 ]
57. 9 moles of “D” and 14 moles of E are allowed to react in qa closed vessel according to given
reactions. Calculate number of moles of B formed in the end of reaction, if 4 moles of G are
present in reaction vessel. (Percentage yield of reaction is mentioned in the reaction)
80%
Step-1 3D  4E   5C  A
50%
Step-2 3C  5G   6B  F
Ans. 00002.40
Sol. L.R.
80%
3D  4E   5C  A
5
9 mole 14 mole  9  0.8  12 mole
3
50%
3C  5G   6B  F
12 mole 4 mole
L.R. is G
6
Moles of B formed   4  0.5  2.4
5
58. A sample of 28 mL of H2O2 (aq) solution required 10 mL of 0.1m KMnO4 (aq) solution for
complete reaction in acidic medium. What is the volume strength of H2O2?
Ans. 00001.00
Sol. Eq. of H2O2 = Eq. of KMnO4

(25  M  2)  (10  0.1 5)
M  0.089
Volume strength = M  0.1 =1
59. Calculate the value of A.

E
A  1,2 where En,Z  Energy of electron in nth orbit, Z = atomic number of hydrogen like
2E2,1
species.
Ans. 00008.00
E1,2 13.6  22  22 16
Sol. A   8
2E2,1 2  12  ( 13.6)  12 2
60. 2 mole of zinc is dissolved in HCl at 25°C. the magnitude of work done in open vessel is (in kJ)
Ans. 00004.95
Sol. w  P.V  nH2

2  8.314  298
RT    4.955 kJ
1000
SECTION – A
 
61. The vectors a and b are non-zero and non-collinear. The value of x for which vector
     
c = (x –2) a + b and d = (2x +1) a – b are collinear.
(A) 1
(B) 1/2
(C) 1/3
(D) 2
Ans. C
 
Sol. Since c and d are collinear.
 
We have pc  qd = 0 where p + q = 0 for some scalars p and q.
 
  
p { (x –2) a + b } + q{ (2 a +1) a – b } = 0
   
 p(x –2) = -q(2x +1) and p b =q b (since a, b are non-colinear)
 p(x –2) = - p(2x +1)
 x = 1/3.
62. If in ABC,  A = sin–1(x),  B = sin–1(y) and  C = sin–1(z), then

x 1  y 2 1  z 2  y 1  x 2 1  z2  z 1  x 2 1  y 2 is equal to
(A) xyz
(B) x+y+z
1 1 1
(C)  
x y z
(D) None of these
Ans. A
Sol. In a ABC
sin(A+ B+ C)= 0
= sinA cosB cosC + sinB cosC cosA + sinC cosA cosB – sinA sinB sinC
 xyz = x 1  y  2
1  z   y 1  x 1  z   z 1  x 1  x 
2 2 2 2 2
63. The value of a for which the equation 4cosec2( (a + x)) + a2 – 4a = 0 has a real solution, is
(A) a=1
(B) a=2
(C) a = 10
(D) None of these
Ans. B
Sol. 4 [1 + cot2 (a + x)] + a2 – 4a = 0

2 2
4cot  (a + x) + (a – 2) = 0
2
 a – 2 = 0 and cot  (a + x) = 0
 a = 2.
64. If a sinx + bcos(C + x) + bcos (C –x) = , then the minimum value of |cosC| is
 2  a2
(A)
b2
 2  a2
(B)
4b 2
 2  a2
(C)
16b 2
(D) None of these
Ans. B
Sol. We have asinx +2bcosCcosx = 

The maximum value of asinx + 2bcosCcosx is a 2  4b 2 cos 2 C
which increases as | cosC| increases. So the minimum value of |cosC| will correspond to the
situation when a 2  4b 2 cos 2 C is just equal to , so as to give a real solution of the
equation.
 a 2  4b 2 cos 2 C = 
2  a2  2  a2
cos2C = ; | cosC| = .
4b 2 4b 2
65. If 5a + 4b + 20c = t, then the value of t for which the line ax + by + c  1 = 0 always passes
through a fixed point is
(A) 0
(B) 20
(C) 30
(D) None of these
Ans. B
ax by
Sol. Equation of line   1  0 has two independent parameters. It can pass through a
c 1 c 1
fixed point if it contains only one independent parameter. Now there must be one relation
a b a
between and independent of a, b and c so that can be expressed in terms of
c 1 c 1 c 1
b
and straight line contains only one independent parameter. Now that given relation can be
c 1
5a 4b t  20c
expressed as   .
c 1 c 1 c 1
Now RHS be independent of c if t = 20.
66. Consider the equation x2 +x – n = 0, where n is an integer lying between 1 to 100. Total number
of different values of ‘n’ so that the equation has integral roots is
(A) 6
(B) 4
(C) 9
(D) None of these
Ans. C
Sol. x2 +x –n = 0, discriminent = 1+ 4n = odd number = D(say)

Now given equation would have a integral solution if D is a perfect square .
Let D = (2 +1)2  n =  +2 = ( +1) = even number
 n can be 2, 6, 12, 20, 30, 42, 56, 72, 90.
n
r2  r  1
67. r 1 r  1!
is equal to
n
(A)
(n  1)!
1
(B)
(n  1)(n  1)!
n
(C) 1
(n  1)!
(D) None of these
Ans. B
n n
r2  r  1 r 1 r  n
Sol. r 1 r  1!
  
r 1 r!
 
(r  1)!  (n  1)!
.
68. Two events A and B have probabilities 0.25 and 0.50 respectively. The probability that both A and
B occur simultaneously is 0.14. Then the probability that neither A nor B occurs is
(A) 0.39
(B) 0.25
(C) 0.11
(D) None of these
Ans. A
Sol. P(A) = .25, P (B) = .50, PA  B   .14

PA  B   P( A )  P(B )  P ( A  B)
= .25 + .50 – .14 = .61
   
P A  B  P A  B  1  PA  B  = 1 – .61 = .39
69. The number of positive integral solutions of the equation x1 x2 x3 = 60 is
(A) 54
(B) 27
(C) 81
(D) None of these.
Ans. A
Sol. Here x1x2 x3 = 22  3  5

Let number of two’s given to each of x 1 , x2 , x3 be a, b, c .
Then a + b + c = 2, a, b, c  0
The number of integral solutions of this equations is equal to coefficient of x 2 in (1 – x)-3 i.e. 4C2
i.e. the available 2 two’s can be distributed among x 1, x2 and x3 in 4C2= 6 ways.
Similarly, the available 1 three can be distributed among x 1, x2, x3 in 3C2 = 3 ways.
(= coefficient of x in (1 – x)-3)
4 3 3
 Total number of ways = C2  C2  C2 = 6  3  3 = 54 ways.
70. In a bag there are 15 red and 5 white balls. Two balls are chosen at random and one is found to
be red. The probability that the second one is also red is
12
(A)
19
13
(B)
19
14
(C)
19
15
(D)
19
Ans. C
14
C1 14
Sol. Probability that out of remaining balls the one that is red is =
19

C1 19
71. Let S be the set of 6-digit numbers a1a2a3a4a5a6 (all digits distinct)
where a1 > a2 > a3 > a4 < a5 < a6. Then n(S) is equal to
(A) 210
(B) 2100
(C) 4200
(D) 420
Ans. B
Sol. First, 6 distinct digits can be selected in 10C6 ways. Now the position of smallest digit in them is
fixed i.e. position 4. Of the remaining 5 digits, two digits can be selected in 5C2 ways. These two
digits can be placed to the right of 4th position in one way only. The remaining three digits to the
left of 4th position are in the required order automatically.
So n(S) = 10C6  5C2 = 210  10 = 2100.
72. If the normals at the end points of a variable chord PQ of the parabola y2 – 4y – 2x = 0 are
perpendicular, then the tangents at P and Q will intersect at
(A) x+y=3
(B) 3x – 7 = 0
(C) y+3 = 0
(D) 2x + 5 = 0
Ans. D
Sol. Since normals at P and Q are perpendicular, the tangents at P and Q will also be perpendicular
but any two perpendicular tangents of a parabola always intersect on its directrix.
The parabola is (y – 2)2 = 2( x +2). So its directrix is 2x + 5 = 0
4
73. If A is a skew–symmetric matrix of order 3, then matrix A is
(A) skew–symmetric
(B) symmetric
(C) diagonal
(D) None of these
Ans. B
Sol. We have A    A     A  A  A  A   A A A A 
and A 4
4
=   A   A   A   A    1 A 4  A 4
Hence (B) is the correct answer.
sin2 x, x rational
74. Let f(x) =  . Then set of points, where f (x) is continuous is
 sin2 x, x irrational
  
(A) 2n  1 , n  I
 2 
(B) null set
(C) {n, n  I}
(D) set of all rational numbers
Ans. C
Sol. If a is any number for which sin a  0, then we don’t get any fix tendency of f (x) to approaches
where x  a
so lim f (x) does not exist
x a
but if sin a = 0, lim f (x) = 0
x a
x7 / 2
75.  dx equals to
x9  1
(A) sin–1 x 2  9  c
1  x 9  1 
(B) In c
2  x 9  1 
2  9/2
(C) In  x  x 9  1   c
9  
(D) None of these
Ans. C
9/2 9 7/2
Sol. Put x x dx  dt , So given integral reduces to
= t then
2
2 dt 2 2
  In  t  t 2  1  c  In  x 9 / 2  x 9  1   c
9 t 1 9 
2  9  
76. Four points are such that the line joining any two points is perpendicular to the line joining other
two points. If three points out of these lie on a rectangular hyperbola then the fourth point will lie
on
(A) the same hyperbola
(B) conjugate hyperbola
(C) one of the directrix
(D) one of the asymptotes
Ans. A
Sol. The points are such that one of the points is the orthocentre of the triangle formed by other three
points. When the vertices of a triangle lie on a rectangular hyperbola the orthocentre also lies on
the same hyperbola.
x2  
77. The value of ‘’ so that the range of the function y = is R, is
x 1
(A) ( ,  2]
(B) ( ,  1]
(C) ( , 0)
(D) None of these
Ans. B
x2  
Sol. Given that y =
x 1
 x2  yx +   y = 0
 y2  4(  y)  0  y2 + 4y + 4  4 + 4
4 + 4  0     1.
(3 x  4 y  7 ) 2
78. The length of the major axis of the ellipse (5 x  10) 2  (5 y  15) 2  is
4
(A) 10
20
(B)
3
20
(C)
7
(D) 4
Ans. B
2
 1 3x  4y  7 
Sol. ( x  2) 2  ( y  3) 2    is an ellipse, whose focus is (2, -3), directrix 3x – 4y + 7
2 5 
1
= 0 and eccentricity is .
2
3  2  4  ( 3)  7
Length of  from focus to directrix is 5
5
a a 10
 ae  5  2a   5  a 
e 2 3
20
So length of major axis is
3
/2
n 1
79. If I(n) =   . sin
n
d , n  N, n > 3, then the value of I(n) - In  2 is
0
n
1
(A)
n2
1
(B)
n 1
1
(C) 2
n 1
1
(D)
n 1
Ans. A
/2
n
Sol. I(n) =   . sin
0
 d
/2
 I(n) =   . sin
n 2
 
 1  cos2  d
0
/2
  . cos  . cos . sin

n 2
= I(n-2) –  d
0
/ 2
sinn 1   / 2 sin n 1

= I(n-2) - .cos .
n 1 0
  . sin   cos .
0
n 1
d
/ 2 /2
1 1
= I(n-2) -  . sinn  d  n 1
 cos . sin  d
n  1 0
n 1 0
1 1 /2
= I(n-2) - .In   . sinn 
n  1 n  1n 0
n 1 n 1 1
 In   In  2  ,  I(n) – I(n –2) .  2 .
n 1 n  1n n n
x1 y1 z1
80. Let x1y1z1, x2y2z2 and x3y3z3 be three 3–digit even numbers and  = x 2 y2 z 2 . Then  is
x3 y3 z3
(A) divisible by 2 but not necessarily by 4
(B) divisible by 4 but not necessarily by 8
(C) divisible by 8
(D) none of these
Ans. A
100 x1  10 y1  z1 y1 z1 2A y1 z1
Sol.  = 100 x 2  10 y 2  z2 y2 z2 = 2B y2 z 2 , where A, B, C  I
100 x 3  10 y 3  z3 y3 z3 2C y 3 z3
A y1 z1
= 2 B y2 z2 , which is divisible by 2 but not necessarily by 4 or 8.
C y3 z3
SECTION – B
81. If the line y = 3x cuts the curve x4 + ax2y + bxy + cx + dy + 6 = 0 at A, B, C and D, then
OA.OB.OC.OD (where O is the origin) is
Ans. 00096.00
r r 3
Sol. The line y = 3x can be written as x = , y= . If this line cuts the given curve, then
2 2
r 4 ar 3 3 br 2 3 cr dr 3
     6  0.
16 8 4 2 2
Therefore OA. OB.OC.OD = |r1| |r2| |r3| |r4| = |r1 r2 r3 r4| = 96
82. The value of ‘a’ for which the equation  a 2  4a  3  x 2   a 2  a  2  x   a  1 a  0 has more than
two roots is –k, then the value of k+2020? is
Ans. 02021.00
Sol. a 2
  
 4a  3 x 2  a 2  a  2 x   a  1 a  0   a  1 a  3  x 2   a  1a  2  x  a  1 a  0
 a  1  a  3  x 2   a  2  x  a   0
if a = 1, then quadratic have more than two roots.
83. Equation of the normal to the curve x2 = 4y which passes through the point (1, 2) is x + y = k-12,
then k =
Ans. 00015.00
Sol. Equation of the normal to the curve x 2 = 4y is x = my – 2m – m3, passes through the point
(1, 2)  m = –1.
84. If the value of the sum 29  30   28  30   27  30   ......  1 30   0  30    30  where  n   n Cr ,

 0 1  2  28   29   30  r 
32
is equal to k2 , then the value of k is equal to
Ans. 00003.50
 30   30   30   30   30   30 
Sol. S  29    28    27    ......  1   0     
 0 1   2  28   29   30 
 2S  28  C 0  C1  C 2  ....  C30   28  230 
30 30 30 30
7 32 7
Hence, S  14  230  2 .  k 
2 2
85. Let A  a ij  be a 3  3 invertible matrix. If determinant value of matrix A is 3, then the value of
det((adjAT)T) + det.((adjA–1)–1) (where det(B) denotes determinant value of matrix B)
Ans. 00018.00
Sol. det((adjA T )T )  (det A)2  9

det((adjA 1 )1 )  (det A)2  9
86. If z1, z2, z3 are complex number such that |z1| = 2, |z2| = 3, |z3| = 4 then maximum value of
| z1  z 2 |2  | z 2  z 3 |2  | z3  z1 |2 is
Ans. 00087.00
Sol. | z1  z 2 |2  | z 2  z 3 |2  | z3  z1 |2
= 2(|z1|2 + |z2|2 + |z3|2) – (z1z2  z1z2  z2 z3  z2 z3  z3 z1  z3 z1 )
= 58 – (z1z2  z1z2  z2 z3  z2 z3  z3 z1  z3 z1 ) ……(1)
2
Now |z1 + z2 + z3|  0
2 2 2
 |z1| + |z2| + |z3| + z1z2  z1z2  z2 z3  z2 z3  z3 z1  z3 z1  0
 – (z1z2  z1z2  z2 z3  z2 z3  z3 z1  z3 z1 )  29 ……(2)
from (1) and (2)
maximum value = 58 + 29 = 87.
87. A point P (x, y) is said to be integral point iff both x, y are integers. Then number of integer points
2 2
inside or on the circle x + y = 9 is
Ans. 00029.00
Sol. Let (n, m) be a integer point, then

n2 + m2  9
if n2 = 9, m2 = 0  2  1 = 2 points
if n2 = 4, m2 = 0, 1, 4  2  5 = 10 points
2 2
if n = 1, m = 0, 1, 4  2  5 = 10 points
if n = 0, m2 = 0, 1, 4, 9  1  7 = 7 points
2
so in total, we have 29 points, which are integral points.
8 80 240
88. Let (1 + x)n = 3 
  4  .... , x, n  R. Then the sum of the series
3 33 3
8 80 240
3   3  4  .... is
3 3 3
Ans. 00027.00
8 80 240 n(n  1)x 2

Sol. (1+ x)n = 3   3  4  .... = 1 + nx + +....
3 3 3 2
2
On comparison, n = -3 and x = .
3
ai
89. If ai, i = 1, 2, 3, 4 be four real numbers of the same sign, then the minimum value of a j
,
i, j  {1, 2, 3, 4}, i  j, is
Ans. 00012.00
ai
Sol. a j
, i, j  {1, 2, 3, 4}, i  j has a total of 4  4 – 4 = 12 terms i.e. 6 pairs, each pair of the
 ai a j 
type   .
 a j ai 
 
a aj  ai
Now  i   2 (as  0)
 a j ai  aj
 
ai ai
  aj
 26 a j
 12 .
N
90. Let N be any four digit number say x1 x2 x3 x4. Then maximum value of is
x1  x 2  x 3  x 4
equal to
Ans. 01000.00
N 1000 x1  100x 2  10 x 3  x 4
Sol. 
x1  x 2  x 3  x 4 x1  x 2  x 3  x 4
= 1000 −
900x 2  990x 3  999x 4   maximum value of N
= 1000
x1  x 2  x 3  x 4  x1  x 2  x 3  x 4
FIITJEE
JEE (Advanced)-2022
FULL TEST – IV
PAPER –1
TEST DATE: 18-01-2022
Section – A (01 – 04, 20 – 23, 39 – 42): This section contains TWELVE (12) questions. Each
question has FOUR options. ONLY ONE of these four options is the correct answer.
Section – B (11 – 13, 30 – 32, 49 – 51): This section contains NINE (09) questions. The answer to
each question is a NON-NEGATIVE INTEGER.
decimal places.
MARKING SCHEME
marking scheme:
correct option;
AITS-FT-IV (Paper-1)-PCM-JEE(Advanced)/22 2
Physics PART – I
1. Two identical simple pendulums each of length  are suspended from the
ceiling. Their bobs each of mass m are connected by a very light relaxed
elastic cord of force constant k as shown in the figure. If the bobs are
symmetrically pulled apart slightly and released, what is period of the
ensuing oscillations?
1

 2k g  2
(A)   
 m 
1 1
   
 2k  2  g  2 
(B)       
 m   

1 1
   
 k g  2  g  2 
(C)        
 m    

1 1
   
 2k g  2  g  2 
(D)       
 m    

Ans. D
Sol.
kx
mg
mean position
mg
Add time period of left and right motion from mean position.
 y
2. In the given figure, dipole moment m of a small magnetic dipole placed at P
the origin is shown by a small directed line segment. Magnetic induction A
 r
vectors at distant points A (0, y) on the y-axis and B (x, 0) on the x-axis 
respectively are 


O B x
 0m m
(A) ĵ and 0 3 î
4y 3 2x
3 AITS-FT-IV (Paper-1)-PCM-JEE(Advanced)/22
 0m m
(B) 3
ĵ and 0 3 î
2y 4x
 0m m
(C) 3
ĵ and  0 3 ĵ
4y 2x
 0m m
(D) 3
ĵ and  0 3 ĵ
2y 4x
Ans. D

 0m
Sol. Use result M.F. due to dipole on axis 
2r 3

0 m
Use result M.F. due to dipole on equatorial line  
4r 3
3. Three small balls of the same mass, white (w), green (g), and blue (b), are fixed by weightless
rods at the vertices of the equilateral triangle with side l. The system of balls is placed on a
smooth horizontal surface and set in rotation about the centre of mass with period T. At a certain
instant, the blue ball tears away from the frame.
Determine the distance L between the blue and the green ball after the time T.
2
2  1
(A)   3  
3  2
2
4  1
(B)   3  
3  2
4 2
(C)    3  1
3
2
3  1
(D)   3  
4  2
Ans. D
Sol. Displacement of G = Displacement w.r.t. C + Displacement of C

Further, by mathematical calculations, it can be solved.
B
v
v
3v

C 60 
a
60  
4. The refractive index of the medium within a certain region, x > 0, y > 0, changes with y. A thin
light ray travelling in the x-direction strikes the medium at right angles and moves through the
medium along a circular arc.
How does the refractive index depend on y?
[R : Radius of path & 0 : Initial refractive index]
2R
(A) 0
Ry
R 0
(B)
Ry 2
Ry
(C) 0
R
R
(D) 0
Ry
Ans. D
Sol. Equation of circle is y

(x  0)2  (y  R)2  R 2 …(1)
dy
 tan  …(2)
dx 
By Snell’s law sin(90  )    1 0 …(3) x

5. A closed organ pipe of length  is sounded together with another closed organ pipe of length
  x(x  ). Both vibrate in their fundamental modes. If the speed of sound is v, then the beat
frequency heard is
vx
(A)
2 2
vx
(B)
42
vx 2
(C)
4
(D) None of these
Ans. B
 
v v v  1  v  x  vx
Sol. f    1   1 1   2
4 4(  x) 4   x   4    4
  1    
 
6. Five equal resistances, a capacitor and two batteries are V

A R
connected in a circuit as shown in the figure. The capacitor D
is initially uncharged and each battery has negligible internal
resistance. It is given that R = 1, C = 1F and V = 8 volt. R R
On the basis of above information answer the following E C
questions, if switch ‘S’ is closed at t = 0. (Assume e–1 = 0.37, B R
if required) S R
2V
(A) Current in the branch of capacitor at t = 5/8 s is (approximately) 6 A
(B) Current in the branch AB at t = 5/8 s is (approximately) 1.7 A
(C) Potential difference between points A and C at t = 5/8 s is (approximately) 2.5 V
(D) Potential difference between points A and C at t = 5/8 s is (approximately) 6 V
Ans. A, B, C
5RC
Sol. time constant of capacitor () 
8
Maximum charge on capacitor at steady state (q0 )  5CV / 4
Charge on capacitor at any time
5CV  
8t
 V
q  1  e 5RC  .... (i) A R
4  D

R R
Current in the branch of capacitor at any time C
8t i2 C
2V  5RC E
i1  e i1 i1 - i2 R
R
i1  1.7 amp R
Now, v A  i2R(i1  i2 )R  VC D 2V
VA  v C  2.52 volt
7. A charged particle of charge –q and mass m is projected with V0

qQ
initial velocity v 0  from a distance a from the fixed
40am 
a m
charge +Q at an angle of  = 60° with the line joining the charges
+Q –q
as shown in the figure. It is found that the particle moves on an
elliptical orbit with the charge +Q at one of its foci.
(A) The length of the semi-major axis of the ellipse equals to a
3 2
(B) The area of the ellipse orbit equals to a
2
163  0ma3
(C) The time period of one revolution will be
qQ
8 3 0ma3
(D) The time period of one revolution will be
qQ
Ans. A, B, C
1 qQ qQ V0
Sol. Total energy E  mv 2  
2 4 0a 80a a 
qQ 
E D
40 (2a)
 The particle is moving on an ellipse of semi-major axis a a
a3 163ma3
and the time period will T  2 
 qQ  qQ
 4 m 
 0 
From geometry b  a sin 
3 2
 Area A = ab = a2 sin   a
2
8. Consider the situation shown in the figure. Two slits S1 and S2 Screen
are placed symmetrically about the line OP which is S air
perpendicular to screen and bisector to line joining the slits. 3
The space between screen and slits is filled with a liquid of d S1
refractive index 3. A plate of thickness t and refractive index d
2 P
2 is placed in front of one of the slit. A source S is placed O
air 3
above OP at a distance d in front of slit. S2 t
(Given that D = 1m, d = 2 mm, t = 6 10–6m., 2 = 1.2, D 2D
 3  1.8 , Choose the correct alternatives
(A) Position of central maxima from point P is 2 mm.
(B) Position of central maxima from point P is 1 mm.
(C) If slab is removed, the central maxima shifts by a distance of 2 mm.
(D) If slab is removed, the central maxima shifts by a distance of 1 mm.
Ans. A, C
Sol. Path difference = 0

d2 yd  2 
   1 t
D 2D  3 
y = 2 mm
d2 y1d
When slab is removed then path difference =  = 0, y1 = 2d = 4mm
D 2D
9. A particle of mass m is moving in a field where the potential energy is given by

U ( x )  U 0 (1  cos ax) , where U0 and a are constants and x is the displacement from mean
position . Then (for small oscillations)
m
(A) the time period is T  2
aU 0
(B) the speed of particle is maximum at x = 0

(C) the amplitude of oscillations is
a
m
(D) the time period is T  2 2
a U0
Ans. B, C, D
 dU
Sol. U  U 0 (1  cos ax) , F   aU 0 sin ax
dx
d 2x
m 2   a 2U 0 x (For small oscillations)
dt
m
 T  2 2
a U0

Potential energy is maximum at x =
a

amplitude is
a
Speed of particle is maximum at x = 0 ( PE is minimum)
10. Which of the following statement is correct regarding induced electric field (symbols have their
usual meanings)?
(A) Work done in moving a test charge in an induced electric field can be zero.
(B) Induced electric field is non conservative is nature.
(C) Induced electric lines of force form closed loops.
  d
(D) Induced e.m.f. in the loop in    E.d   .
dt
Ans. A, B, C, D
Sol. Induced electric field is a non-conservative field, therefore potential is not defined for such fields.
d
e.m.f.  
 E.d   dt .

INTEGER.
A
11. A body executing SHM with time period T and amplitude A. When it is at from equilibrium
2
position moving toward right. It receives an impulse which doubles its velocity without changing
1  K 
direction. Time taken by the block to reach the right extreme position is t  T cos  .
 13 
Find K .
Ans. 1
Sol. Velocity =  A2  x 2
2 3 A
= (doubles)
T
2 3 A 2
 A2  x 2
T T
13
A1  A
2
A/2 1  1  1  
cos       cos  
A1 13   3 
 1 
cos 1    t
 13 
 1 
t  T cos 1  
 13 
12. A uniform elastic plank moves due to a force distributed uniformly over the end face. The cross-
sectional area is A and Young’s modulus Y. The strain produced in the direction of the force is
1 F0
. . Find X .
X AY
Ans. 2
Sol. The tension is not constant along the length of the plank. Let force at a distance x from one end
be F.
F0 x
Then F 
l
F F x change in length of element dx
Stress at any cross section =  Y  strain  0 

A lA dx
1
F F
Increase in length of element, dx  xd  l  0  xdx
lAY lAY 0
l 1 F0
Hence strain  .
l 2 AY
13. A radioactive sample contains two different types of radioactive nuclei; A-with half-life 5.0 days
and B-with half-life 30.0 days. Initially the decay rate of the A type nuclei is 64 times that of B type
of nuclei. Their decay rates will be equal when time is 9n days. Find the value of n.
Ans. 4
0.69 0.69
Sol. A  day 1 and  B  day 1
5 30
 dN   dN 
Given  OA   64  OB 
 dt   dl 
  A NOA  64BNOB
dNA dNB
At time t, 
dt dt
  A NA  BNB
NOA N 
Dividing equation (1) and (2)  64  OB 
NA  NB 
1 1
But NA  NOA 2  and NB  NOB 2B
 Equation (3) becomes  1  64e2 e t
 a (  A  B )t  64
 ( A  B )t  ln(64)  2.303log10 64
2.303log10 64
 t  36 days
 0.693 0.693 
 5  30 
 

Question Stem

A cutting tool under microprocessor control has several forces acting on it. One force is F   xy ˆj , a
2
force in the negative y-direction whose magnitude depend on the position of the tool. The constant  is
2.50 N. Consider the displacement of the tool from the origin to the point x = 3.00 m, y = 3.00 m.

14. Calculate the magnitude of work done on the tool by F . If this displacement is along the straight-
line y = x that connects these two points (in J)
Ans. 50. 60

Sol. dr  dxi  dyj , dw  F .dr   x y 2 dy
3
On the path x = y, so  y dy ,
y 2 3
w   y 3 dy  –50.6
y1  0

15. Calculate the work done on the tool by F of the tool is first moved out along the x-axis to the
point x = 3.00m, y = 0 and then moved parallel to the y-axis to x = 3.00 m, y = 3.00 m (in J)
Ans. 67.50
Sol. d  xy 2 dy from x = 0 to x = 3 dw = 0

w  2.50  3 = 67.5 J
Question Stem
 V 
A steel tank has internal volume V0 (= 100 litre). It contains half water  volume  0  and half kerosene
 2 
oil at temperature 1 = 10°C
16. Calculate the mass of kerosene that flows out of the tank at temperature of 2 = 40°C.
Coefficients of cubical expansion for different substances are: k = 10–3°C–1; w = 2  10–4°C–1;
steel = 1.2  10–5°C–1. Density of kerosene at 10°C is 1 = 0.8 kg/litre
Ans. 1.37
Sol. Volume of kerosene that spills out

V = Vk + Vw - Vs
V V V 
 0 k   0  w   V0  s   0 ( k   w  2 s )
2 2 2
100  30
 [103  0.2  103  2  0.012  103 ]
2
Density of kerosene at 2 is
1 0.8 0.8
2   3
  0.78 kg / litre
1   k (2  1 ) 1  10  30 1.03
 Mass of K.oil that flows out is
V  (    w  2 s )
m  V 2  0 1 k (2  1 )
2 1   k ( 2  1 )
 0.78  1.76  1.37kg
17. The height of water in the container at 1 = 10°C is H1 = 1.0 m.

Find the height of water at 2 = 40°C.
Ans. 1.01
V0
Sol. Volume of water at 2 is V  [1   w ] [where  = 2 – 1]
2
V
The area of cross section of the tank at 1 is A 1  0
2H1
 2  V  2 
At 2 cross section will be A 2  A1 [1  ]  A 1 1   s    0 1   s  
 3  2H1  3 
Height of water column is
V0
[1   w ]
V
H2   2
A2 V0  2 
1   s  
2H1  3 

Question Stem
A double pan window used for insulating a room thermally from outside consists of two glass sheets each
of area 1 m 2 and thickness 0.01 m separated by 0.05 m thick stagnant air space. In the steady state, the
room-glass interface and the glass-outdoor interface are at constant temperatures of 27°C and 0°C
respectively. The thermal conductivity of glass is 0.8 Wm–1K–1 and of air 0.08 Wm–1K–1.
18. Calculate the temperature of the inner glass-air interface.
Ans. 26.50
19. Calculate the rate of flow of heat through the window pane.
Ans. 40.50
Sol. (for Q. 18 & 19)

Let T2 and T3 be the temperatures of the glass 1-air interface and air-glass 2 interface
respectively
dQ1 dQ 2 dQ3
The equations of heat flow are  
dt dt dt
dQ K g A(T1  T2 ) K a A(T2  T3 ) K g A(T3  T4 )
    ...(A)
dt dg da dg
dQ K g A(300  T2 ) K a A(T2  T3 ) K g A(T3  273)
   
dt dg da dg
 50 (300 – T2) = T2 – T3 ...(i)
And 300 – T2 = T3 – 273 ...(ii)
dQ
Solve (i) and (ii) to get T2 and T3. Put this in (A) to get
dt
20. If the elevation in boiling point of a solution of non-volatile, non-electrolytic and non-associating
-1
solute in solvent (Kb = xK.Kg.mol ) is y K, then the depression in freezing point of solution of

same concentration would be K f  zK.kg.mol1 
2xz
(A)
y
yz
(B)
x
xz
(C)
y
yz
(D)
2x
Ans. B
Sol. Tb  Kb  m
y
 m= ....(1)
x
 f  K f m .....(2)
y
Tf    z
x
21. The function of zymase is to:
(A) change starch into sugar
(B) ferment glucose to alcohol and CO2
(C) change malt sugar into glucose
(D) change starch into malt sugar and dextrin.
Ans. B
Zymase
Sol. C6H12O6 
 CO2  C2H5OH
22. The density of a pure substance ‘A’ whose atoms are in cubic close pack arrangement is 1g/cc. If
all the tetrahedral voids are occupied by ‘B’ atom, what is the density of resulting solid in g/cc.
[Atomic mass (A) = 30 g/mol and atomic mass (B) = 50g/mol]
(A) 3.33
(B) 4.33
(C) 2.33
(D) 5.33
Ans. B
Sol. Let volume of fcc unit cell = V

4  MA
 
NA .V
8  MB
B 
NA .V
A M 30
 A   0.3
B 2MB 2  50

  A  3.33g / cc
0.3
Total density      4.33g / cc
23. A reaction system in equilibrium according to reaction 2SO2(g) + O2(g)  2SO3(g) in one litre
vessel at a given temperature was found to be 0.12 mole each of SO2 and SO3 and 5 mole of O2.
In another vessel of one litre contains 32 g of SO2 at the same temperature. What mass of O2
must be added to this vessel in order that at equilibrium 20% of SO2 is oxidized to SO3?
(A) 0.4125g
(B) 11.6 g
(C) 1.6g
(D) 5.55 g
Ans. B
Sol. 2SO2 (g)  O2 (g)  2SO3 (g)

(0.12)2
Kc   0.2
(0.12)2  5
Another vessel
2SO2 (g)  O2 (g)  2SO3 (g)
Moles at eqm. 0.5-2x y-x 2x
20
As per given 2x   0.5  0.1
100
(0.1)2
Kc   0.20
(0.4)2 (y  0.05)
y  0.3625 mole
 mass of O2 added = 11.6 g

24. From the above compound (A), (B), (C) & (D) achiral compound is:
H3C H
H Me
.
NH2
O NH2
O .
(C) (D)
(A) (B)
(A) A
(B) B
(C) C
(D) D
Ans. B, C, D
Sol. H3C H
is perpendicular to the ring.
. no POS
no COS
O Thus, chiral
O .
Plane of symmetry and centre of symmetry is not present in compound(A)
 It is chiral.
25. Select equations having endothermic step.
(A) S - (g)  S2  (g)
(B) Na  (g)  Cl (g)  NaCl(s)
(C) N(g)  N (g)
(D) Al2  (g)  Al3  (g)
Ans. A, C, D
Sol. Factual
26. The standard electrode potentials of some of the alkali metals are
Li / Li  3.05V; Na+ / Na  2.71V; K + / K  2.93V
Alkali metals react with water according to the following reaction. (M = alkali metal)
2M  H2O  2MOH  H2
It is found that Li reacts gently with water whereas potassium reacts violently with water.
Which of the following statement(s) is/are correct regarding the above two experimental facts?
(A) G values have nothing to do with the kinetics of a reaction
(B) The metal having large standard oxidation potential will have lesser reactivity
(C) K has a low melting point, and the heat of reaction is sufficient to make it melt or even
vapourize. This leads to exponential increase in its surface area
(D) The ionization potential of K is greater than that of Li.
Ans. A, C
Sol. Factual.
27. Amongst CuF2, CuCl2 and CuBr2:
(A) only CuF2 is ionic
(B) both CuCl2 and CuBr2 are covalent
(C) CuF2 and CuCl2 are ionic but CuBr2 is covalent
(D) CuF2, CuCl2 as well as CuBr2 are ionic.
Ans. A, B
Sol. Factual
28. At 27°C, 1 mole of N2O4(g) placed in container of volume 8.21 lit, no dissociation will take place at
this temperature. When gas is heated to 127°C, N2O4 is partially dissociated into NO2 and final
pressure is found to be 4.5 atm.
Select the correct statement.
(A) No. of moles of NO2 at 127°C is 0.5 moles
(B) No. of moles of NO2 at 127°C is 0.25 moles
7
(C) Mole fraction N2O4 in gaseous mixture at 127°C is
9
8
(D) Ratio of the pressure of the system at 127°C will be .
9
Ans. B, C, D
Sol. N2O 4  2NO2

1-x 2x
4.5  8.21
Total moles = 1 + x   1.5
0.0821 300
x  0.5
29. For the pairs of canonical forms written below what is/are true?
I II
(p) F3C  CH  CH  CH  CH3 (p) F3C  CH  CH  CH  CH3
(q) Br (q) .
Br
.
(A) In both (p) and (q), I is more stable than II
(B) In both (p) and (q), II is more stable than I
(C) In (q), II is more stable than I
(D) In (p), II is more stable than I
Ans. A
Sol. Factual

INTEGER.
30. For the all reaction

2AgCl  H2  2Ag  2H  2Cl
Temperature coefficient of emf of the cell is 0.02 VK-1. S° for the above reaction in kJ/K is
(nearest integer).
Ans. 4
 dE 
Sol. So  nF  cell 
 dT P
 2  96500  0.02  3.86kJ / K
31. 200 L of 600 ppm CaCO3 dilute aq. Solution is mixed with 50L of 0.02 M H2SO4 solution using
following reaction,
CCO3  H2SO 4  CaSO 4  H2CO3
Calculate pH (excluding decimal part) if H2CO3 dissociates completely. [Given: log4 = 0.6]
Ans. 2
Sol. nH2SO4 500.021
n 600 1
CaCO3   200103  1.2
106 100
 L.R. is H2SO4
1
[H2CO3 ]   4  103 M
250
pH   log2  4  10 3  3  3log 2  3  0.903  2.1
32. 0.1 M HA is titrated against 0.1 M NaOH. Find pH at the end point. Dissociation constant for t acid
-6
HA is 5  10 and the degree of hydrolysis h < 1.
Ans. 9
Sol. HA  NaOH  NaA  H2O at the end point, their equivalent amounts reacts together.
weak
 In the final solution.
0.1
[NaA]   0.05 M
2
As NaA is a salt of weak acid and strong base, it hydrolyses as,
A   H2O  Ha  OH
1
pH  7  [pK a  logc]
2
1
 7  [  log(5  106 )  log0.05]  9
2

Question Stem
Electrolysis of cold sodium chloride solution produces NaOH and Cl2. Cl2 produced, dispropontionates
into NaOH solution to give NaClO and NaCl. 103L of 7.45% (w/w) solute of NaClO is produced if cell
current is 9.65 ampere. Assume density of solution is 1g/m.
33. Find moles of Cl2 required
Ans. 1000.00
34. How long will a cell operate to produce the above mentioned NaClO (x  107)
Ans. 2.00
Sol. (Q33 & 34) Cl  Cl2  2e 

Cl2  2NaOH  NaClO  NaCl  H2O
106  1 7.45 /100
Moles of NaClO required =
7.45
 103 mol
Moles of Cl2 required = 103

Eq. Of Cl2 required = 2  107  t
Question Stem
Standard Gibb’s energy of reaction (rG°) at a certain temperature can be compouted as rG° = rH° and
the change in the value of r Ho and r So for a reaction with temperature can be computed as follows:
Ho  r Ho  r Cop (T2  T1)
T2 T1
T 
r So  r So  r Cpo ln  2 
T2 T1
 T1 
r Go  r Ho  T.r So
And by r Go  RT lnK eq.
Consider the following reaction: CO(g)  2H2 (g)  CH3OH(g)
Given:  f Ho (CH3 OH,g)  201 kJ/mol;  f Ho (CO,g)  114kJ / mol
So (CH3 OH,g)  240J / K  mol; So (H2 ,g)  29JK 1mol1
So (CO,g)  198J / mol  K; Co
p,m (H2 )  28.8 J/mol-K
o o
Cp,m (CO)  29.4J/ mol  K; Cp,m (CH3OH)  44 J/mol-K
 320 
And ln    0.06, all data at 300 K.
 300 
35. rS° at 320 K is:
Ans. -18.78
320
dT
Sol. r S  16 

300
r Cp
T
320
r S  16  (44  29.4  2  28.8)ln
300
320
r S  16  ( 43)ln  18.78
300
36. rH° at 320 K is:
Ans. -87.86
320
Sol. r H  87 

300
r Cp dT

Question Stem
Cu2Cl2 HCl R2O2

H  C  C  C  H   A  B  C
NH4Cl 1eq 
Answer the following questions on the basis of above sequence of reactions:
x
37. Degree of unsaturation in A is x. Find .
2
Ans. 1.50
38. Ratio of number of carbon atom to number of H-atom in molecule B is
Ans. 0.80
Sol. (for Q.37–38)

H H
HCl R O
2 2 (C)
H2C C C C H  H2C C C CH2 
1eq. 
(A)
Cl
(B)
C is artificial rubber (polymerization, free radical).

39. The equation of the line of latus rectum of the rectangular hyperbola xy = c2 is
(A) x  y  2c
(B) x  y  2 2c
(C) x  y  2c
(D) x+y=0
Ans. B
Sol. OA = c A = (c, c) L
AS = eOA ( e  2 )
AS = 2c S xy=c2
 Co–ordinates of S =  2c, 2c  A
Equation of line through LL’ O
Slope of line = –1 and passing through  2c, 

2c is
y  
2c  1 x  2c  
y  2 c  x  2 c
x  y  2 2c .
1/ 3
 3x  x 
21
40. The value of  7x 9  21x 3 20
 x 8  x 2 dx is
1
(A)
84

3x 28  7x12  21x 4  c 
1
(B)
21

3x 20  7x8  21x 2  c 
1
(C)
80

3x21  7x9  21x3  c 
(D) None of these
Ans. A
1/ 3
 3x  x 
21
Sol.  7x 9  21x 3 20
 x 8  x 2 dx
put 3x21 + 7x9 + 21x3 = t

20 8 2
63[x + x + x ]dx = dt
1
1 3 1 t4 / 3 1 4/3
I2  
63
 t dt 
63

4

84

3x 21  7x 9  21x3  c
3
1
=
84

3x 28  7x12  21x 4  c . 
 n2  n  1 
The sum to ‘n’ terms of the series whose n term is given by Tn  ( 1)n 
th
41.  is
 n! 
n1
(A)  1n 1
n!
n n
(B)  1 1
 n  1 !
n (n  1)
(C)  1 1
 n  1 !
(D) None of these
Ans. A
r2  r  1
r r  r r  1
Sol. Tr   1   1   
r!   r  1 ! r ! 
r r 1 r 1 r
Tr   1   1
r! r  1 !
Tr = Vr – Vr–1
n
n n 1
T
r 1
r  Vn  V0   1
n!
1
42. The co-ordinate of the foot of perpendicular drawn from the point (0, –2, 3) to the plane
2x – 3y + z = 5 is
 4 8 19 
(A)  7, 7, 7 
 
 4 8 19 
(B)  7, 7, 7 
 
 4 8 19 
(C)  7, 7 , 7 
 
(D) None of these
Ans. C
Sol. Equation of line through (0, –2, 3) and perpendicular to plane is

x0 y2 z3
   k (say)
2 3 1
Co–ordinates of a point on this line is (2k, –2 – 3k, 3 + k). This point when lying on the plane
satisfies the equation of the plane. Hence 2(2k) – 3(–2 – 3k) + (3 + k) = 5.
 4k + 6 + 9k + 3 + k = 5
2
 14k = – 4 or k = .
7
 4 8 19 
 The point on the plane is  , , .
 7 7 7 

5
 1 32 1  1 32 n  1  , then which of the
43. Let Sn  lim  6  6  .......   and Tn  lim  6  6  ......... 
n n
 n n n  n n n6 
 
following is/ are true?

1
(A) Sn 
6
1
(B)  Sn  Tn  
3
1
(C)  Sn  Tn  
3

1
(D) Tn 
6
Ans. A, C, D
 1 32 243 1
Sol. S n  lim  6  6  6  ........ 
n n
 n n n
 1 32 243
Tn  lim  6  6  6  .......
n  15 

n n n n n6 
  O 1
n 5 1 6 1
r x 1
S n  lim  6
  x 5 dx  
n 
r 1 n 0
6 0
6
 
1 1
 Sn    ; Tn   
6 6 included in Sn excluded in Tn
But since x5 is concave upward the area included in Sn for
any two consecutive values of r is more than area
excluded in Tn for same values of r.
1 1 1
 Sn    Tn  S n  Tn 
6 6 3
44. z1, z2 ......zn be non-zero complex numbers of equal modulus and satisfying the equation
zn  | z |z n1  1  0 , then
 n n zj 
(A) Re    = 0
 j 1 k 1 zk 
 n n zj 
(B) Re    = 1
 j 1 k 1 zk 
 n n zj 
(C) Im    = 0
 j 1 k 1 zk 
 n n zj 
(D) Im   
 j 1 k 1 zk 
Ans. B, C
n n zj 1 1 1
Sol. Let S     z1  z2  .....zn     ........ 
j1 k 1 zk z
 1 z 2 z n 
If z1  z2 ........ zn  r
1 zk
 
zk r 2
1
S   z1  z2  .....zn  z1  z2  .......zn 
r2
2
z1  z 2  .....zn

r2
But z1  z2  .....zn  z  r
r2
S  1
r2
     
45. If log2  log 1 (log2 (x)   log3  log 1 (log3 (y))  = log5  log 1  log5 (z)   0 for positive x, y and z, then
 2   3   5 
which of the following is/ are NOT true?
(A) zxy
(B) xyz
(C) yzx
(D) zyx
Ans. B, C, D
Sol. Solving we get x  21 2 , y  31 3 , z  51 5

Using graph of x 1 x
2 e 3 5
 31 3  51 5
Also 2 1 2  31 3 2 1 2  51 5
3 2
as 2  3 25  52
y  x  z
Hence (B), (C) & (D) are NOT true
46. A drawer contains red and black balls. When two balls are drawn at random, the probability that
1
they both are red is . The number of balls in the drawer can be
2
(A) 21
(B) 11
(C) 4
(D) 3
Ans. A, C
Sol. Let the drawer contains p balls of which ‘m’ are red.
m
C2 1
Probability of drawing two red balls at random is p

C2 2
 2m m  1  p p  1
2
 2m  2m  p 2  p  0

2  4  8 p  p2 
1  1  2p  2p2
m  
4 2
 1  2p  2p2 should be an odd perfect square.
i.e., p = 21, 4 but p  3
when 3 balls out of 4 are red.
15 balls out of 21 are red.
47. If a function satisfies  x  y  f  x  y    x  y  f  x  y   2  x 2 y  y 3   x, y  R and f(1) = 2, then
(A) f(x) must be polynomial function
(B) f(3) = 12
(C) f(0) = 0
(D) f(x) may not be differentiable
Ans. A, B, C
Sol.  x  y  f  x  y    x  y  f  x  y   2y  x  y  x  y  
Let x  y  u; x  y  v
uf  v   vf  u   2uv  v  u 
f v f u 
  v u
v u
 f v   f u  
  v    u  =constant
  
 v   u 
f  x
Let x
x
 f  x    x  x2 
f 1  2
 1  2    1
f x  x 2  x
48. In a ABC medians AD and BE are perpendicular to each other, then
1 a
(A)  2
2 b
1 c
(B)  2
2 a
1 a
(C)  2
2 c
1 b
(D)  2
2 a
Ans. A, D
1 1 A
Sol. AG  2b 2  2c 2  a 2 and BG  2a 2  2c 2  b 2
3 3
c E
AG 2  BG 2  c 2
G
 2b 2
 
 2c 2  a 2  2a 2  2c 2  b 2  9c 2 
 a 2  b 2  5c 2 ...(i) B D C
and for ABC exist
ab  c or ba  c
2
 b2
 a  b 2  c 2  a 2  b 2  2ab  a
 2 a 2  2b 2  5 ab  0
5
2
a a a 5  25  16 5  3 1
 2   5   2  0     2,
b b b 4 4 2
1 a
  2
2 b
1 b
Similarly,  2
2 a
INTEGER.
a3 2 a2
49. The locus of the vertices of the family of parabolas y  x  x  2a is 64xy  21k, where k is
3 2
equal to
Ans. 5
Sol. Given equation is

a3 x2 a2 x
y   2a
3 2
a3  2 3 
 y  2a  x  x
3  2a 
 2
a3 3  9 
 y  2a   x    
3  4a  16a2 
2
3 9  3 
 3
(y  2a)  2
 x  
a 16a  4a 
2
3  3   3 
 3 
y  2a  a    x  
a  16   4a 
2
3  35   3 
 3 
y a  x  
a  16   4a 
Which is of the form X2  4AY .
Vertex is given by
X  0, Y  0
3
 x 0
4a
35
and y a0
16
3 35 105
 x and y   a  xy 
4a 16 64
105 21
  k  k  5.
64 64
50. Tangents are drawn from the point (4, 3) to the circle x 2  y2  9 . Then the area of the triangle
64 
formed by these tangents and the chord of contact is square units where  is equal to
25
Ans. 3
Sol. The equation of the chord of contact of the two tangents that can be drawn from P(4,3) to the
circle x 2  y2  9 is (S1  0)
4x  3y  9  0 ….(1) A
For area of PAB, we need

| AB | and | MP | M
P O
2 2 (4,3) 90° (0,0)
Here, | OP | (4  0)  (3  0)  5
Also, | OM | distance of O(0,0) from line (1)
|009| 9 B
 
42  32 5
 | AB | 2 (radius)2  OM2
2
9 144 24
 2 32     2 
5
  25 5
and | MP || OP |  | OM |
9 16
5  .
5 5
1
Hence area PAB  | AB || MP |
2
1  24  16  192
     square units
2  5  5  25
64 192
   3.
25 25
51. A straight line L with negative slope passes through the point (8, 2) and cuts the positive co-
ordinate axes at point P and Q. As L varies, the absolute minimum value of OP+ OQ is (O is
origin)
Ans. 18
Sol. The equation of line L be y  2  m  x  8  , m  0 co-coordinates of P and Q are

 2 
P  8  , 0  and Q  0, 2  8m  .
 m 
2
So, OP  OQ  8   2  8m
m
2 2
 10   8   m   10  2  8   m  18
 m   m 
So, absolute minimum value of
OP  OQ  18

Question Stem
Consider the circle x2 + y2 = 9 and the parabola y2 = 8x. They intersect at P and Q in the first and the
fourth quadrants, respectively. Tangents to the circle at P and Q intersect the x-axis at R and tangents to
the parabola at P and Q intersect the x-axis at S. Now answer the following questions
52. The ratio of the areas of the triangles PQS and PQR is
Ans. 0.25
Sol. 
P  1, 2 2  
Q  1,  2 2 
Equation of PR : x  2 2y  9
R   9, 0 
Equation of PS : 2 2 y  4  x  1
S   1, 0 
1
 2 4 2
PQS 2 1
Area  
PQR 1  8  4 2 4
2
53. The radius of the circumcirlce of the triangle PQR is
Ans. 4.50
Sol. Diameter of circum circle of  PQR will be OR = 9

Where O is origin
Question Stem
If the locus of the circumcentre of a variable triangle having sides y-axis, y  2 and x  my  1, where
(,m) lies on the parabola y 2  4ax is curve C, then
54. Coordinates of the vertex of this curve C is (–2a, ) then the value of 2    101 is
Ans. 104.75
55. The curve C is symmetric about the line y = k then value of |2021k|
Ans. 3031.50
 1
Sol.  C   0, 
 m
 1  2m 
B ,2  ,A(0,2)
  
Let (h, k) be the circumcenre of ABC y
1  2m 1  2m
 h : k C
2 2m B
y=2
1  2m 1 A
 2h  : k  1 x
 2m o
1 k 2 x  my  1
 m : 
1k  2 2h(k  1)
 (,m) lies on y 2  4ax

 m2  4a
2
 1   k 2 
    4a  
 2k  2   2h(k  1) 
h  8a(k 2  3k  2)
 locus of (h,k) is
x  8a(y2  3y  2)
2
 3 1
 y    (x  2a)
 2 8a
 3
 vertex is  2a, 
 2
1
 Length of smallest focal chord  length of latus rectum 
8a
3
From the equation of curve C it is clear that it is symmetric about line y  .
2

Question Stem
Consider a general equation of degree 2, as x2 – 10xy + 12y2 + 5x – 16y – 3 = 0
56. The value of '' for which the line represents a pair of straight lines is
Ans. 2.00
57. For the value of  obtained in above question, if L1 = 0 and L2 = 0 are the lines denoted by the
given line pair then the absolute value of the sum of abscissa and ordinate of their point of
intersection is
Ans. 13.50
Sol. (for Q. 56 &57)

a = ; h = – 5; b = 12; g =(5/2) ; f = – 8, c = – 3
(12)(–3) + 2(–8)(5/2)(– 5) –  (64) – (25/4)· 12 + 3 · 25 = 0
– 36 + 200 – 64 – 75 + 75 = 0  100 = 200   = 2 Ans.
(ii) 2x2 – 10xy + 12y2 + 5x – 16y – 3 = 0
consider the homogeneous part
2x2 – 10xy + 12y2
2x2 – 6xy – 4xy + 12y2
or 2x(x – 3y) – 4y(x – 3y)
or (x – 3y)(x – 2y)
 2x2 – 10xy + 12y2 + 5x – 16y – 3  (2x – 6y + A)(x – 2y + B)
solving A = – 1; B = 3
hence lines are 2x – 6y – 1 = 0 and x – 2y + 3 = 0
solving intersection point (-10, -7/2)
 product = 35
FIITJEE
JEE (Advanced)-2022
FULL TEST – IV
PAPER –2
TEST DATE: 18-01-2022
decimal places.
MARKING SCHEME
marking scheme:
are correct;
option;
Physics PART – I

1. The strength of the electric field produced by charges uniformly

distributed over the surface of a hemisphere at its centre O is E0. A part
of the surface is isolated from this hemisphere by two planes passing
through the same diameter and forming an angle  with each other. 
Determine the electric field strength E produced at the same point O by O
the charges located on the isolated surface (on the “mericarp”).
E0 
(A) sin
2 2
2E0 
(B) sin
3 2

(C) E0 sin
2

(D) 2E0 sin
2
Ans. C
 
Sol. E1 cos  E2 sin (i) 2
2 2
  
E1 sin  E2 cos  E0 (ii)
2 2  
Solving we get E1 
2 2
/2
E2 E1
2. Two point masses, each of mass M are kept at rest at points A and B respectively. A third point m
is released from infinity with a negligible speed, so that it can move along y-axis under the
influence of mutual gravitational attraction on it due to point masses kept at A and B respectively
as shown in the figure -1. Figure 2 represents the potential energy of system (includes m, M at A
and M at B) with position of m at y-axis. (Neglect any other forces other than gravity) (given
2
Gm /d = 12 Joule(m = 6 kg). Choose the correct option(s)
y U
C m
A B
M = 2m M = 2m x y
d U1
d
U0
(A) Point mass m will perform periodic motion
(B) U1 = 24 Joule
(C) Maximum speed of particle is 24 m/s
(D) Maximum speed of particle is 4 m/s
Ans. A, B, D
2GMm GM2
Sol. U 
d2  y 2 2d
2GMm 2Gm2
 
d2  y2 d
 2 1
= 2Gm2   
 d2  y 2 d 
 
1 2
= U  mv
2
3. A coil of radius R carries a current I. Another concentric coil of radius r (r < < R) carries current
I
. Initially planes of the two coils are mutually perpendicular and both the coils are free to rotate
2
about common diameter. They are released from rest from this position. The masses of the coils
are M and m respectively (m < M). During the subsequent motion let K1 and K2 be the maximum
kinetic energies of the two coils respectively and let U be the maximum magnitude of potential
energy of magnetic interaction of the system of the coils. Choose the correct options.
2
K1 M  R 
(A)   
K2 m  r 
Umr 2 UMR 2
(B) K1  2 2
K2 
mr  MR mr 2  MR 2
0 I2r 2
(C) U
4R
(D) K 2  K1
Ans. B, C, D
Sol. 1  2
 dt  
I
1

I
1 1
K.E.  12 
2 I
mr 2
K1
 2
K 2 MR2
2
2
K1 m  r 
  
K2 M  R 
K1  K 2  U
2
m r 
K2    K2  U
MR
UMR 2
K2 
mr 2  MR2
Umr 2
K1 
mr 2  MR2
I  I  I2 r 2
U  r 2 0  0
2 2R 4R
4. A uniform rod of mass m and length L performs small oscillations about horizontal axis passing
through its upper end. Find the mean kinetic energy and angular amplitude  of rod, if at t = 0 it is
deflected from vertical by an angle 0 and imparted an angular velocity 0.
2L02
(A)   02
3g
3 4L02
(B)  k f  MgL  02
4 3g
1 2L02
(C)  k f  MgL  02
8 3g
3 L20
(D)   20
2 g
Ans. A, C
Mg
Sol. 
I
MI2 1
Where I  and  
3 2
Mg(L / 2) 3g
Thus  
ML2 / 3 2L
3g 2
0    02
2L
2L02
  02
3g
1 2 2
 k f  I 
4
1  ML2   3g  2L20
or      20
4 3   2L  3g
1 2L02
or  MgL  02
8 3g
2
5. The resistive force suffered by a motor boat is  V when the engine was shut down. When the
velocity is V0 find the average velocity at any time t.
V0  V
(A) Vav =
2
VV0
(B)
2V0  V 
V0
VV0 log e
(C) V
V0  V 
V0
2VV0 log e
(D) V
V0  V 
Ans. C
V t
dV dV 1 1 
Sol.  kV 2 , V 2 
 kdt     kt
dt  V V0 
V0 0
1 1 1 
or t=   
K  V V0
V x
dV dx dV
.  kV 2or   kdx  
dx dt V
V0 0
log e V0 / V
loge V0 – logeV = kx x
k
x log e V0 / V   k
or VaV = 
t 1 1 
k  
 V V 0
V0
VV0 log e
or VaV = V
V0  V 
6. A disc of mass ‘m’ is released from top of an inclined plane of

inclination  as shown in figure. If the coefficient of friction
between inclined surface and disc is . Then choose the
correct statement (s)
1 2mg sin 
(A) If   tan  , the net force acting on disc is
3 3
1 4gh
(B) If   tan  , the velocity of disc at the bottom of inclined plane is
3 3
mg sin 
(C) If disc rolls on inclined plane without slipping, then frictional force is
3
1
(D) If   tan  , the acceleration of disc along the inclined plane is g sin 
3
Ans. A, B, C
mr 2
Sol. For pure rolling mg sin   f s ma and f s r   , a  r
2
2 g sin  mg sin 
On solving a  and f s 
3 3
mg sin 
For no slipping,  mg cos 
3
tan  f
And If   , slipping will be there so, a  g sin   k  g sin 
3 m
1 2 1 2 4gh
And velocity of disc mgh  mv  I gives v 
2 2 3

answer.
A wire loop carrying current I is placed in the X-Y plane as shown in the figure. If a particle with charge
+Q and mass m is placed at the centre P and given a velocity along NP (figure).
7. Find the instantaneous acceleration
QV 0I  3 3 
(A)   2
m 6a   

QV 0I  3 3 
(B)   1
m 4a   

QV 0I  3 3 
(C)   1
m 6a   

(D) None of these
Ans. C

Sol. ˆ
B at centre  (Bst. wire  B arc )( k)
 1  1  2   ˆ
 0 (2sin 60)  0    ( k)
 4 R cos 60 4 R  3 
0I  3 3 
ˆ
   1 ( k)
6a   

For charge particle – qvB = ma
qv0I  3 3 
 a   1
6ma   


8. If an external uniform magnetic field B  B î is applied, find the torque acting on the loop due to
the field.
  3  2ˆ
(A)   BI   a j
 3 4 
 
  3  2ˆ
(B)   BI   a j
 3 2 
 
  3  2ˆ
(C)   BI   a j
 6 4 
 
(D) None of these
Ans. A
  
Sol. ˆ  B î
T  M  B  NIA(k)
  3 2 ˆ
 T  I  a2  a  Bj
3 4 
 
A circular loop of wire of radius ‘a’ is bent about its diameter such that
the angle between the two halves becomes 60°. The resistance per unit
length of the wire is r0. A uniform magnetic field directed along (+) Z-axis,
is varying as B  B0 t. (Neglect self inductance of the loops)
9. Magnitude of induced emf in the loop is
B 0 a2
(A)
8
B0 a2
(B)
4
B0 a2
(C)
2
(D) 2B0 a2
Ans. B
Sol. For loop PQR,

   a2 
1  B  A  B0 t.A cos0  B0 t  
 2 
d1 B 0 a2
e1  
dt 2
 a 2 
For loop PSR, 2  B0 t   cos 60
 2 
d2 B a 2
So e2   0
dt 4
B0 a2
e  e1  e2 
4
10. If the system is maintained in the position shown at all the time the external torque need to keep
the loop in the position shown at any time is
3B 20 a3 t
(A)
32r0
3B 20 2 a4 t
(B)
16r0
B 20 2 a4 t
(C)
16r0
B 20 a3 t
(D)
32r0
Ans. A
e Ba
Sol. i  0
2ar0 8r0
For loop PQR,  = 0
 3   B0 a  a2   3
For loop PSR,   MB sin60  (iA)(B0 t)    (B0 t) 
 2   8r  2 
   0    2 
3B 20 a3 t

32r0

INTEGER.
11. The prism spectrum is spread out more at violet end than at the red end. Angular dispersion is
d
defined as   , if deviation of small prism  is defined as   (  1)A 0 and wavelength is
d
B
defined as   A  2 , where A and B are constants and A 0 is prism angle, then dispersion

1
  N . Find the value of N.

Ans. 3
d
Sol. As, 
d
This can be written as
d d
  ,   (  1)A 0
d d
d
 A0
d
B d 2B
A 2
  3
 d 
2BA 0 1
So,  3  3
 
So, N=3
12. A cylinder of radius R is kept embedded along the wall of a dam as

R
shown. Take density of water as r and length of cylinder as L. The
gLR2 R
vertical force exerted by water on the cylinder is . Find the
X
value of X.
Ans. 2
R dF
Sol. fv   g(2R  Rcos )(LRd)cos 
0
d 
R
2 2
= LgR (2cos   cos )d

0

= gLR2
2
13. Two square metal plates of side 1 m are kept 0.01 m apart like a parallel plate capacitor in air in
such a way that one of their edges is perpendicular to an oil surface in a tank filled with an
insulating oil. The plates are connected to a battery of emf 564 V. The plates are then lowered
vertically into the oil at a speed of 0.001 ms–1. Calculate the current (in nano ampere) drawn from
the battery during the process. (Dielectric constant of oil = 11, 0 = 8.85  10–12C2N–1m–1)
Ans. 5
Sol. The adjacent figure is a case of parallel plate capacitor. The combined capacitance will be
C  C1  C2
k 0 (x  1) 0 [(1  x)  1)
 
d d

C  0 [dx  1  x] ...(i)
d
After time dt, the dielectric rises by dx. The new equivalent capacitance will be
C  dC  C1   C2 
0  [(1  x  dx)  1]
 [(x  dx)  1]  0
d d
0
 [kx  kdx  1  x  dx] ...(ii)
d
We know that q  CV
dq dC
V ...(iii)
dt dt

 I  V 0 (k  1)
d
From (i) and (ii)
564  8.85  1012
I (11  1)  0.001  5  10 9 A
0.01

Question Stem
A bar of mass m is held as shown between 4 uniform discs, each of mass m and radius r = 75 mm. The
bar has been released from rest, knowing that the normal forces exerted on the discs by vertical wall are
sufficient to prevent any slipping. Answer the following questions. (Acceleration due to gravity is 10 m/s2)
14. If m = 5 kg and m = 2 kg, what is acceleration of the bar
Ans. 7.65
Sol. F.B.D. of disc

 In horizontal direction N = Nx ...(i)
In vertical direction mg – f – Ny = ma ...(ii)
Torque due to friction;
mR 2
fR  
2
As a = R
mR2 a
 fR 
2 R
mR2 a
 fR 
2 R
ma
 f put in (ii)
2
3ma
 ma  Ny 
2
3ma
Ny  mg  ...(iii)
2
Now, F.B.D. of bar;
4Ny  mg  ma
Put Ny from (iii)
4ma – 6ma + mg = ma ...(iv)
As m = 2 kg and m = 5 kg
 8g – 12a + 5g = 5a
13g 130
a =
17 17
15. If the mass m of the bar is negligible, then acceleration of the bar is
Ans. 6.67
2g 20
Sol. From equation (iv) (neglecting m) a  =
3 3
Question Stem
A cat initially hanging on a rod in static equilibrium as

shown in figure. If the cat climbs up on the rod from its
lower end towards its upper end with a monotonically
increasing acceleration starting at t = 0 and crossing the
midpoint of rod at t = t0 and the average speed of cat in
this time interval (t = 0 to t = t0) is 2m/sec relative to the
rod then in the time interval t = 0 to t = t0 :
(Use SI units)
16. If the angle made by displacement of center of mass of (block + cat) is  with horizontal, then
tan  is
Ans. 2.40
17. The distance (in meter) travelled by the block is
Ans. 0.08
Sol. (for Q. 16 & 17)

As system was at equilibrium initially
So mcat = 1 kg
Now f – 1g = |a|
(where f is the force on cat applied by rod)
4g + f – 2T = 4a2
T – 25 = 5(2a2)
Solving these question:

a1 = 24 a2
So, average velocity will have same relation
v1  24v 2
Relative velocity of cat w.r.t. rod
2 m/s = v1 + v2
So, v2 = (2 / 25) m/sec
v1 = (48/25) m/sec
1 1
For displacement of cat t 0   s
v1  v 2 2
 48 
Mcat Ycat    1 12
25 
tan      ...(i)
Mblock Xblock  4  5
 5
 25 
4 1 2
Displacement of block   
25 2 25

Question Stem
A small block of mass m is projected horizontally from the top of the smooth and fixed hemisphere of
radius r = 8 m with speed u as shown. For values of u  u0 , (u0  gr ) it does not slide on the
hemisphere.
[i.e., leaves the surface at the top itself]
18. For u = 2 u0, it lands at point P on ground. Find OP:
Ans. 22.63
mu02
Sol. mg   u0  gr
r
1 2 2r
Now, along vertical; r  gt  t 
2 g
Along horizontal; OP  2u0 t  2 2r
19. For u = u0/3, find the height from the ground at which it leaves the hemisphere:
Ans. 5.63
Sol. As at B it leaves the hemisphere,

 N=0
h mv 2
mg 
r r
mv 2  mgh ...(i)
By energy conservation between A and B
2
1 u  1
mgr  m  0   mgh  mv 2
2  3  2
19r
Put u0 and mv2  h 
27

20. By reacting with which of the following reagents CH3NH2 will form a solid derivative?
(A) PhSO2Cl
(B) (COOEt)2
(C) H2SO4
(D) CHCl3 + KOH
Ans. A, B, C
Sol. With (A) solid sulphonamide, with (B) solid substituted oxamide with (C) solid salt.
21. Which of the following is /are soluble in alkaline water?
(A) Me3CCOOH
(B) (COOH)2
(C) PhCOOH
(D) HCOOH
Ans. A, B, C, D
Sol. Because of salt formation all are soluble.
22. Which of the following will form phthalic anhydride by following this scheme?
(P) KMnO4, OH- (Q) H3O+
(R) 
(A) o-xylene (B) m-xylene
(C) p-xylene (D) CHO
CH2Cl
Ans. A, D
Sol. Only (A) and (D) on oxidation form phthalic acid.
23. Nylons is/are characterized by:
(A) high melting solid polymer
(B) high degree of crystallinity
(C) hydrophobic
(D) high mechanical
Ans. A, B, D
Sol. Can form H-bond with H2O and hence are hydrophilic.
24. Which of the following statement(s) is/are true?
(A) In metal carbonyl complexes dC-O increases compared to that in CO molecule.
(B) The pair of compounds [Cr(H2O)6Cl3] and [CrCl3 (H2O)3 ].3H2O show hydrate isomerism.
(C) d orbital of central metal atom/ion is used in dsp2 hybridization.

z2
(D) Facial and Meridional isomers associated with [Ma3b 3 ]n  type complex compound, both
are optically inactive.
Ans. A, D
Sol. Factual
25. Correct statement is/are:
(A) an acidified solution of K2Cr2O7 liberates iodine from KI
(B) K2Cr2O7 is used as a standard solution for estimation of Fe2+ ions
(C) in acidic medium N = M  6 for K2Cr2O7.
(D) (NH4 )2 Cr2O7 on heating decomposes to yield Cr2O3 through an endothermic reaction
Ans. A, B, C, D
Sol. Cr2O27   I  Cr 3  I2

answer.
Green compound as mineral (A) decomposes on heating to give black residue (B) and gaseous
compound (C) and (D). When (D) come in contact of CuSO4, it gives blue colour. (C) gives milkiness with
lime water and it is colourless and odourless gas. (B) reacts with sulphuric acid to give soluble compound
which can react with potassium ferrocyanide to give red brown ppt. (E).
26. Compound (E) is:
(A) Cu2 [Fe(CN)6 ]
(B) Zn2 [Fe(CN)6 ]
(C) Cl2 [Fe(CN)6 ]
(D) Fe 4 [Fe(CN)6 ]3
Ans. A
4 NH OH
27. Compound (B) + H2SO 4  (X) 
(Y), compound (Y) is:
excess
(A) [Zn(NH3 )4 ]SO4
(B) Cu(OH)2
(C) [Cu(NH3 )4 ]SO 4
(D) [Cd(NH3 )4 ]SO4
Ans. C
Sol. (for Q. 26-27)

(A) Malachite
(B) CuO
(C) CO2
(D) H2O
(E) Cu2 [Fe(CN)6 ]
Covalent radius is half of the distance between two nuclei of two like atoms bonded together by a single
d
covalent bond. Considering the homonuclear diatomic molecule A2, covalent radius, rA  A  A , where
2
dA  A is bond length but if covalent bond is formed between two elements of different electronegativity,
then we use the following relation, given by Stevenson in 1941. dA B  rA  rB  0.09(XA  XB ) XA and
XB are electronegativities of A and B. (E. N. of Cl = 3.0)
28. If bond length of Cl2 is 1.98Å, then covalent radius of Cl atoms is:
(A) 0.99Å
(B) <0.99 Å
(C) >0.99Å
(D) None of these
Ans. A
29. If bond length A2 molecule is 0.8Å and EN of A-Cl is 1.0 then calculate bond length of A-Cl:
(A) 1.39 Å
(B) 1.30 Å
(C) 2.78Å
(D) 2.60 Å
Ans. B
Sol. (for Q. 28-29)

rA = 0.4 Å
RCl = 0.99 Å
dA B  rA  rB  0.09(XA  XB )

INTEGER.
30. For a certain reaction the variation of the rate constant with temperature is given by the equation
 ln3  o
lnK t  lnK 0    T(T  0 C)
 10 
The value of the temperature coefficient of the reaction rate is therefore.
Ans. 3
K  t
Sol. ln  t   (ln3) : when t = 10;
K
 0 10
Kt
 temperature coefficient.
K0
10
 ln (temperature coefficient) = (ln 3)   ln3
10
31. Determine percentage degree of dissociation of 0.05 M NH3 at 25°C in a solution of pH = 11.
Ans. 2
Sol. NH4OH  NH4  OH

0.05 0 0
(0.05 0.05  ) 0.05 0.05 
pH  11,[H ]  1011
[OH ]  103  C
32. The number of substrates which neither show SN1 nor SN2.
Cl
CH2Cl
H
HC C Cl
Br
MeCl, H2C CH CH2 Me3Cl, D3C Cl
Br
Ans. 3
Sol. 2, 3, and 4

Question Stem
In an ionic compound A  X  , radii of A+ and X- ions are 1.0 pm and 2.0 pm, respectively The volume of
the unit cell of the crystal AX is x pm 3
x
33. Find the value of
5
Ans. 43.20
34. Coordination number of cations is
Ans. 6.00
Sol. (for Q.33 & 34)

r 1
  0.5 [FCC]  cations in octahedral void.
 2
r
a
r  r 
2
a6
3
Volume = a
Question Stem
  
If the slope of ‘Z’ (compressibility factor) vs. ‘P’ curve is constant  slope= atm1  at a particular
  
temperature (300 K) and very high pressure,
35. Calculate radius of the molecules. (in Å)
Ans. 2.50
36. Find the value of vander waal constant “b”
Ans. 0.16
Pb
Sol. Z  1 at high pressure
RT
b 
Slope  
RT 

 b=  0.0821 300 and

4
b  r 3  4NA
3

Question Stem
0.10 g of a sample containing CuCO3 and some inert impurity was dissolved in dilute sulphuric acid and
volume made up to 50 mL. This solution was added into 50 mL of 0.04M KI solution where copper
precipitates as CuI and I is oxidized into I3 . A 10 mL portion of this solution is taken for analysis, filtered
-
and made up free I3 and then treated with excess of acidic permanganate solution. Liberated iodine
required 20 mL of 2.5 mM sodium thiosulphate solution to reach the end point.
37. Determine mass percentage of CuCO3 in the original sample.
Ans. 74.10
38. Find milimoles of I which are reacted with CuCO3
Ans. 1.50
Sol. M-moles of KI = 50  0.04 = 2

m-equivalent of Na2S2O3 reacted with 10 mL solution = 20  2.5  10-3 = 50  10-3 = 50  10-3
100
m-equivalent of I left unreacted in 100 mL solution  50  103   0.5
10
m=moles of I which reacts with CuCO3  2  0.5  1.5
 2Cu2+  5I  2CuI  I3
2+ 2
m-moles of Cu   1.5  0.6
5
weight of CuCO3 0.6  10 3  123.5  0.0741
0.0741
weight % of CuCO3   100
0.1
= 74.1

39. Let z1, z2 , z3 be the coordinate of vertices A, B, C of the triangle if W1  z1  z2 , W2  z3  z2 and

A  90 , then
W 
(A) Re  2  1
 W1 
(B) Re(W1W2 )  | W1 |2
(C) Re(W1W2 )  | W2 |2
W 
(D) Re  1   1
 W2 
Ans. A, B
Sol.
W2 W
 1 e i
C z3
W2 W1
W2 W
  2 e i  1  i tan 
W1 W1
W1 90°
W1 W2 
W2
W2
2
 W1 
W2 ei   W1  i W1
2
W2 sin   
A z1 B z2
2 n 2 2n
40. Let (1  x  x )  a 0  a1 x  a 2 x .........  a 2 n x , where n is odd integer, if
S1  a0  a4  a8  ..............
S 2  a1  a5  a9  ..............
S 3  a2  a6  a10  ..............
S 4  a3  a7  a11  .............. then
(A) S1  S 3
(B) S2  S4
(C) S 2  S4  0
(D) either S1  S 2  S 3 or S1  S 3  S 4
Ans. A, D
Sol. (1  x  x 2 ) n  a 0  a1 x  a 2 x 2    a 2 n x 2 n …(1)
n
3 1
 a0  a 2  a 4  
2
3n  1
a1  a 3  a 5  
2
Put x  i in equation (1) where i   1
If n  4m  1
 a1  a3  a5   1
a0  a 2  a4   0
3n  1
So, a1  a 5  a 9    S2
4
3n  3
a 3  a 7  a11    S4
4
Similarly if n  4m  3
3n  3 3n  1
Then, S2  and S 4 
4 4
41. Let  
f 1 ( x)  sin 1 cos(sin2 x) , f 2 ( x)  cos1 (sin(cos2 x))
f 3 ( x)  sin 1
cos(cos 2

x) , f 4 ( x)  cos 1 (sin(sin 2 x)), then choose the correct option(s)
4
(A)  f ( x )  2  2
i 1
i
4
i
(B)  (1)
i 1
f i ( x)  0
4 i 
 
(C)  (1)  3  f i ( x)  0 (where [.] is greater integer function)
i 1
(D) f 1 ( x )  f 2 ( x)  cos2x  0
Ans. A, B, C, D
 
Sol. f1 ( x )   sin 2 x , f 2 ( x )   cos 2 x
2 2
 
f 3 ( x )   cos 2 x , f 4 ( x )   sin 2 x
2 2
42. If the area of a triangle is given  and angle C is given and if the value of the side C opposite to
angle C is minimum then
2
(A) a=
sinC
2
(B) b=
sinC
4
(C) a=
sinC
4
(D) b=
sinC
Ans. A, B
Sol. c2 = a2 + b2 – 2ab cosC

= (a – b)2 + 2ab(1 – cosC)
1
 = absinC
2
4
or 2ab =
sinC
 1  cos C 
here c2 = (a – b)2 + 4  
 sinC 
C
= (a – b)2 + 4tan
2
C 4
4tan is constant so for c2 to be minimum a = b thus 2ab = 2a2 =
2 sinC
2
a=b= .
sinC
43. f : [1, 4 ]  [7 , 14 ] is a surjective, twice differentiable function such that f ' ' ( x )  0 ,
49
 x  (1, 4) , then the equation ( f ' ( x )) 2  has
9
(A) at least one root in (1, 4)
(B) exactly one root in (1, 4)
(C) at least two roots in (1, 4)
(D) at most two roots in (1, 4)
Ans. A, D
Sol. Since f x   0 graph of f x  is concave upward.

7 7
Now f  x    having a solution would mean line having slope  touching the curve.
3 3
The graph will strictly lie in the rectangle formed by x  1, x  4, y  7 , y  14 .

If f is monotonic the line parallel to either of diagonal of rectangle will touch the graph exactly
once and if f is non-monotonic, then lines parallel to diagonals will touch the graph exactly once.
2 2 2 1 2m
44. If     then
1!13! 3!11! 5!9! 7!7! n!
(A) m + n =27
(B) m2 = 1 + 2n
2 2
(C) n – m = 27
(D) n=1+m
Ans. A, C, D
2 2 2 1 1 14 1 141 213
Sol.     (2 C1  214 C3  214 C5 14 C7 )  2   m = 13, n = 14
1!13! 3!11! 5!9! 7!7! 14! 14! 14!

answer.
Let A 1,G1,H1 denote the arithmetic, geometric and harmonic means, respectively of two distinct positive
numbers. For n  2 , let A n 1 and Hn 1 has arithmetic, geometric and harmonic means as A n ,Gn Hn
respectively.
45. Which of the following statements is a correct statement?
(A) G1  G2  G3  .....
(B) G1  G2  G3  .....
(C) G1  G2  G3  ......
(D) G1  G3  G5  ........ and G2  G4  G6  ...
Ans. C
46. Which of the following statements is correct?
(A) A 1  A 2  .....
(B) A1  A 2  A 3  ......
(C) A1  A 3  A 5  ........ and A 2  A 4  A 6  ...
(D) A1  A 3  A 5  ...... and A 2  A 4  A 6 ....
Ans. A
Sol. (for Q. 45 and 46)

Let two distinct positive numbers be a and b.
1 2ab
A1   a  b  ,G1  ab, H1 
2 ab
1
A n   A n1  Hn1  ,Gn  A n1  Hn1
2
2A n1Hn1
Hn 
A n1  Hn1
For n  2 .
A nHn  A n 1Hn 1
Thus A1H1  A 2H2  A 3H3  .....
 G12  G22  G32  ......
G1  G2  G3  .....
As a and b are distinct, A 1  H1
 A 1  A 2  H2  H1
 A1  A 2  A 3  H3  H2  H1
And so on.
Thus, A1  A 2  A 3  ....
and H1  H2  H3  .....
Let Vr denotes the sum of first r terms of an arithmetic progression (A.P.) whose first term is r and the
common difference is (2r – 1). Let Tr  Vr 1  Vr  2 ;
1 1
Qr  Tr 1  Tr , Wr   and Xr  3Qr for r  1,2,...
Tr 4 r  1
47. The sum V1  V2  .....  Vn is:
1
(A)
12

n  n  1 3n2  n  1 
1
(B)
12

n  n  1 3n2  n  2 
1
(C)
2

n 2n2  n  1 
1
(D)
3

2n3  2n  3 
Ans. B
r
Sol. Vr  2  r   r  1 2r  1 
2
1 3 2

2

2r  r  r 
n n
1 n 2 1 n
3

k 1
 V  k
k
k 1
k  2 
2 k 1

k 1
k
1 2 1 1
 n2  n  1  n  n  1 2n  1  n n  1
4 12 4
1
 n  n  1 3n  n  1   2n  1  3 
12
1

12

n  n  1 3n2  n  2 
48. Tr is always:
(A) an odd number
(B) an even number
(C) a prime number
(D) a composite number
Ans. D
Sol. Tr  Vr 1  Vr  2
3 1 2 1
 r  1  r 3    r  1  r 2    r  1  r   2
  2  2
1 1
 
 3r 2  3r  1   2r  1   2
2 2
 3r 2  2r  1   3r  1 r  1
Tr is always a composite number.

INTEGER.
49. If  ,   1 is an interior point of ABC where A   0, 3  , B   2, 0  and C   6, 1 , then

the number of integral values of  is/are
Ans. 2
Sol. Since the point lies inside the triangle,   8    1  2  0 ,   3    1  9  0 and

6 3
3  2    1  6  0 . Solving these, we get   .
7 2

50. Angle between the tangents drawn from (1, 4) to the parabola y 2  4x is , where m is equal
m
to
Ans. 3
2
Sol.
2
 
Equation of the pair of tangents is y  4x 16  4   4y  2  x  1 
2
 
 12 y 2  4x  4  2y  x  1
 
 3 y 2  4x  4y 2  x 2  1  4xy  2x  4y
 x 2  y 2  4xy  14x  4y  1  0
If  is the angle between these lines
2
2  2   11
Then tan    3
1  1
 
  m3
3 m
1
51. If the lengths of the semi major axis of an ellipse is 68 and the eccentricity is then the area of
2
the rectangle formed by joining the vertices of the latus rectum of the ellipse is equal to A, where
A – 6930 is
Ans. 6
x2 y2 2 2 1
Sol. Let the equation of the ellipse be 2
 2  1where a 2   68  and b2   68   1   vertices
a b  4
2
 b 
of the lateral recta are  ae,  
 a
2b 2 3 1
Area of the rectangle formed by joining these points  2ae   4b2 e  4  68  
a 4 2
=6

Question Stem
There are five different boxes and seven different balls. All the seven balls are to be distributed in the five
boxes placed in a row so that any box can receive any number of balls.
52. If  be the number of ways these balls can be distributed so that no box is empty and order of

putting the balls in the boxes is considered then the value of is
11
Ans. 6872.73
Sol. Select 4 gaps out of 6 gaps between the balls to create 5 distinct partitions. Then permute the 7
balls
 total = 6C4 × 7! = 15 7
53. Suppose, all the balls are identical, then number of ways these balls can be distributed into these
3k
boxes if empty boxes are also allowed is k then the value of is
4
Ans. 247.50
Sol. No. of non-negative integral solution of the equation x1 + x2 + x3 + x4 + x5 = 7

11
 total is C7.
Question Stem
By taking B(–3, 0) and C(3, 0) triangles PBC of perimeter 16 are constructed. If S is the locus of incentre
of triangle ABC, then
x2 y 2 2
54. Equation of S is   1 then b is
a2 b2
Ans. 2.25
Sol. As ID  BC
Now x = BD – BO = 5 – b b = 5 – x
 C  10  b  5  x
Now   8  8  6 8  5  x  8  5  x 
2
 8y   16  3  x  3  x 
 x  4y 2  9
2
 3 3  3
55. A ray emanating from   , 0  is incident on the curve S at P whose ordinate is . The
 2  2
x y
equation of the reflected ray is   1 then b is
a b
Ans. 1.50
Sol. Equation of s is x2 + 4y2 = 9

 3
P   0, 
 2
 3 3 
Foci are   , 0
 2 
Equation of the reflected ray is 2x + 2 3y  3 3

Question Stem
For a recursive relation in ‘n’ we may generate nth term free from any other term i.e. purely in ‘n’. Based
on this answer the following questions
2
56. If  an 1  an  2  an 1   an  0 and a0  1, then lim 2n  4  a n  is
n 
Ans. 12.56
2an 1
Sol. Given equation converts to an  2
1   an 1 
  
 a n  tan  n  2 
2 

 lim an 2n 
n  4
57. If an  2an21  1 and a0  0, then lim 2ean (use e = 2.72)

n
Ans. 5.44
1  an
Sol. Given equation converts to an 1 
2
  
 an  cos  n 1 
2 
  
cos  n1 
2 
Hence, lim e e
n
FIITJEE
FULL TEST – V
JEE (Main)-2022
TEST DATE: 06-02-2022
answer.
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, SarvapriyaVihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
AITS-FT-V-PCM-JEE(Main)/22 2
Physics PART – A
SECTION – A
 
1. If E (x, t) = E0 sin (t kx) ĵ and B (x,t) = B0 sin (tkx) k̂ are the electric field and magnetic field
vectors respectively in an electromagnetic wave. What would be the direction of propagation of
the EM Wave?
(A) î
(B) î  ˆj
(C) k̂
(D) ˆj  kˆ
2. The percentage modulation in AM Wave is 60% and the peak value of information voltage is 18
Volt. Then the sum of maximum voltage Vmax and minimum voltage Vmin is
(A) 36 V
(B) 60 V
(C) 30 V
(D) 72 V
3. If the radiation of highest wavelength in the ultraviolet region of hydrogen spectrum is just able to
eject photoelectrons from a metal. The value of threshold frequency for the given metal is:
(A) 3.83  1015 Hz
(B) 4.33  1014 Hz
(C) 2.46  1015 Hz
(D) 7.83  1014 Hz
4. A particle is projected with speed u at an angle  with horizontal. Which of the following is the
correct representation of kinetic energy of the particle with respect to time? (Take g = 10 m/s2)
(A) KE (B) KE
t t
(C) KE (D) KE
t t
3 AITS-FT-V-PCM-JEE(Main)/22
5. In the given DC circuit diagram each resistor R is of 65 .

Find the current through ammeter?
5
(A) A
3
3
(B) A
5
7 A
(C) A
3
3
(D) A
7 100 V
6. In a composite slab as shown, the temperature at the interface between two materials is equal to
the average of the temperature at the two ends. Assuming steady heat flow through conduction,
choose the correct option.
Interface T0
Thermal Qout
 Qin Temperature T2
Temperature T1 conductivity k1
2b b
Thermal
conductivity k2
(A) 2k1 = k2
(B) k1 = k2
(C) 2k1 = 3k2
(D) k1 = 2k2
7. A beam of unpolarized light of intensity I0 falls on a system of

four identical linear polarizers placed in a line as shown in the
figure. The transmission axis of any two successive polarizers
make an angle of 30 with each other. If the transmitted light
I
has intensity I, the ratio is
I0
81
(A)
256
9
(B)
16
27
(C)
64
27
(D)
128
8. If in the circuit shown, the current through the ideal battery R1

remains constant after the switch S is closed. Then the values of
R1 and R2 respectively are (an ideal inductor and capacitor are 90mH
used) R2
(A) 300  each
(B) 200  and 300  30V 1F
(C) 300  and 200 
(D) 200  each
S
9. Two smooth spheres of radii R and 2R, specific gravity 0.1 and 0.2 respectively are released from
the bottom of a sufficiently deep-water tank (coefficient of viscosity 10 poise). The spheres travel
all the way to the surface of tank, emerges out and goes up to height H1 and H2 respectively in
air. Then,
(A) H1 = H2
(B) H1> H2
(C) H1< H2
(D) can’t be determined
10. Arrange the following telescopes, in order of decreasing resolving power: (where D is the
telescope diameter and  is the wavelength)
(I) D = 100 m,  = 21 cm
(II) D = 2 m,  = 500nm
(III) D = 1 m,  = 100 nm
(IV) D = 2 m,  = 10 mm
(A) (III), (II), (IV), (I)
(B) (II), (III), (I), (IV)
(C) (IV), (III), (II), (I)
(D) (III), (II), (I), (IV)
11. For a gas under isothermal conditions its pressure P varies with volume V as P  V2/3. Then the
bulk modulus B will be proportional to
(A) V 2/3
(B) V 5/3
(C) V 2
2

(D) V 5
12. When a liquid is placed in vacuum (e.g. a leak from a space vehicle) it evaporates very fast and
can lead to rapid cooling. A water droplet at 10 °C escapes into space and begins to evaporate.
Find its temperature when it has lost 1% of its mass. (To heat 1 kg of water by 1 °C requires 4.2
kJ of energy; to evaporate 1 kg of water requires 2.26 MJ of energy)
(A) 5.6 °C
(B) 4.6 °C
(C) 4.2 °C
(D) 5.4 °C
13. Three infinitely long wires, each carrying equal current are placed in the xy-plane along x = 0, +d
and d. On the xy-plane, the magnetic field vanishes at
d
(A) x
2
 1 
(B) x  d  1  
 3
 1 
(C) x  d  1  
 3
d
(D) x
3
 x 
14. The velocity v(x) of a particle moving in one dimension is given by v(x)  v 0 sin   , where V0
 x0 
x
and X0 are positive constants of appropriate dimensions. If the particle is initially at   , where
x0
|| <<1, then in the long time, it
(A) Executes an oscillatory motion around x = 0
(B) Tends towards x = 0
(C) tends towards x = x0
(D) executes an oscillatory motion around x = x 0
15. Two electric dipoles P1 and P2 are placed at (0, 0, 0) and (1, 0, 0) respectively with both of them
pointing in the +z direction. Without changing the orientations of the dipoles P1 is moved to (0, 2,
0). The ratio of the electrostatic potential energy of the dipoles after moving to that before moving
is
1
(A)
16
1
(B)
2
1
(C)
4
1
(D)
8
16. A light rigid rod with two equal masses m at the ends, is held with
one end on a horizontal surface. The other end rests on a circular
curve of radius 3.4 m, at a distance from the horizontal
corresponding to 1/8th of the circumference of a circle, as shown
in Figure. If the surface is frictionless, what is the speed of the rod
and masses when released and both masses slide on the flat
surface? The masses remain in the same vertical plane.
(A) 2.1 m/s
(B) 3.1 m/s
(C) 4.1 m/s
(D) 5.1 m/s
17. A block of mass 0.38 kg is kept at rest on a frictionless surface

and attached to a wall with a spring of negligible mass. A bullet
weighing 0.02 kg moving with a speed of 200 m/s hits the
block at time t = 0 and gets stuck to it. The equation of
displacement of the block (in meter) with respect to the
equilibrium position is given by (spring constant = 640 N/m)
(A) 2 sin(5t)
(B) cos(10t)
(C) 0.4 cos(25t)
(D) 0.25 sin(40t)
18. A spherical capacitor consists of two concentric conducting spheres of radii a and b (a>b). The
outer sphere is grounded and a charge Q is placed on the inner sphere. The outer conductor then
contracts from radius a to radius a. Find the work done by the electric force.
Q2 (a  a)
(A)
80 aa
Q2 (a  a)
(B)
60 aa
Q2 (a  a)
(C)
40aa
Q2 (a  a)
(D)
20 aa
19. A mass m is attached to one end of a weightless stiff rod of

length L which is rigidly connected to the center of a uniform M
R
cylinder of radius R as shown in the figure. Assuming that the
cylinder rolls without slipping, the natural angular frequency of C
oscillation of the system will be (for small oscillation)? L
2mgL 
(A) 2
rad/s
3MR
 m(L  R)2
2
m
2mgL
(B) rad/s
MR2
 m(L  R)2
2
mgL
(C) rad/s
3MR2
 m(L  R)2
2
mgL
(D) rad/s
MR  m(L  R)2
2
20. The phase difference () between input Vi and output voltage V0 for the following circuit (i) and
(ii) will be
C R
C V0 C V0
Vi Vi
(i) (ii)
(A) 0 and 0

(B) /2 and 0 <  < respectively
2
 
(C) and
2 2

(D) 0 and 0 <  < respectively
2
SECTION – B
21. A ray incident on a glass sphere of refractive index 2 as shown in

figure. Angle of refraction of the ray inside sphere is 30. If total
deviation suffered by the ray is 30x, then find x. 30
22. Find the current (in A) through battery in following circuit.

1 6 6 6 6
36 V 3 3 3 3
1 6 6 6
23. The voltage on a capacitor in a certain circuit is given by V(t) = V0et/RC. If R = 50 k 5% and
C = 0.01 F  10% and the fractional error in the voltage at t = 50 s is N. Find the value of 100N.
24. An alternating current is expressed as i  2cos t  2 sin t . The RMS value of current is N. Find
the value of N?
25. An ideal gas undergoes an isothermal expansion along a path AB, P

adiabatic expansion along BC, isobaric compression along CD,
isothermal compression along DE, an adiabatic compression along A
EA, as shown in the figure. The work done by the gas along the B
process BC is 10J. The change in the internal energy along process
EA is 16J. The absolute value of the change in the internal energy (in
Joule) along the process CD is N. Find the value of N? E
C
D
V
26. Two transverse waves y1 = 5 cos(kxt) cm, and y2 = 5 cos (kx + t) cm, travel on a string along
x-axis. If the speed of a point at x = 0 is zero at t = 0 s, 0.25 s and 0.5 s, then the minimum
frequency (in Hz) of the waves is
27. Consider N1 number of ideal gas particles enclosed in a volume V1. If the volume is changed to
V2 and the number of particles is reduced by half then the mean free path becomes four times of
V
its initial value. The value of 1 is X. Find the value of X?
V2
28. A ball is thrown from a height h = 0.5m above the ground. The
ball leaves the point located at distance d = 10m from the wall at y
45 to the horizontal with velocity u = 20m/s. How far from the
wall (in horizontal direction) does the ball hit the ground,
assuming collision from the wall to be elastic? (Take g= 10m/s2) O
h
29. A semicircular disc of radius R= and mass M has density  y-axis

2
which varies as  = Cr , where r is the distance from the center of the
base and C is a constant. The distance of center of mass of the
semicircular disk from O is
O x
30. A body slides down a rough plane inclined to the horizontal at 30. If 70% of the initial potential
energy is dissipated during the descent, then the coefficient of sliding friction is N . Find the value
of 10N ? (Take root 3 as 1.73)
SECTION – A
31. Permagnate ion oxidizes H2O2 in acidic solution according to the following equation
2MnO 4  aq   5H2 O 2  aq   6H  aq   2Mn2  aq   5O 2  g   8H2 O   
If 35.0 ml of an acidic 0.150 M KMnO 4 solution is required to consume all the H2O2 in 50.0 ml of
a disinfectant solution, what is the concentration of H2O2 in the disinfectant?
(A) 0.042 M
(B) 0.105 M
(C) 0.263 M
(D) 0.368 M
32. Decomposition of 1 gm of which of the following compounds into its constituent elements gives
the greatest amount of N2 gas?
(A) NO
(B) NO 2
(C) N2O4
(D) NH3
33. The natural logarithm of the vapour pressure (in bar) of HCN (s) as a function of the reciprocal of
the absolute temperature is plotted below:
- 2.0
y  4544x  15.864
- 3.0
- 4.0
nP
- 5.0
- 6.0
- 7.0
0 0.0038 0.0040 0.0042 0.0044 0.0046 0.0048 0.0050
1 1
k
T
What is heat of sublimation of HCN?

(A) 4.54 kJ/mole
(B) 15.9 kJ/mole
(C) 37.8 kJ/mole
(D) 132 kJ/mole
34. Which changes to this galvanic cell increase the measured potential?
Cu  s  / Cu2   aq , 0.10M || Ag  aq , 1.0 M / Ag  s 
I. Increasing Cu2   in the Cu / Cu2 half-cell to 0.5 M.
II. Adding Cl to the Ag / Ag half-cell until Cl   0.01 M .

(A) Only I
(B) Only II
(C) Both I and II
(D) Neither I nor II
35. Rank the element Si, P, Ge, and As in increasing order of their first ionization energy
(A) Si < P < Ge < As
(B) As < Ge < P < Si
(C) Ge < Si < As < P
(D) Ge < As < Si < P
36. The isoelectric point of a protein is the pH at which it is electrically neutral. Which mutation of an
amino acid NH2  CH COOH in the protein would have the greatest effect
|
R
on its isoelectric point, assuming that the mutation does not significantly affect the protein’s
overall structure?
(A) Serine  R  CH2  OH  Ly sine R  CH2  CH2  CH2  CH2  NH2 
(B) Glutamine R  CH2  CH2  CONH2   Methionine R  CH2  CH2  S  CH3 
CH3
(C)
Isoleucine R  CH  CH3  CH2  CH3   Valine R = HC
CH3
(D) Alanine  R  CH3   Glycine  R  H
37. The melting point of silicon dioxide is (1713oC) is higher than the melting point of silicon (1414oC).
What is the best explanation for this difference?
(A) Silicon – oxygen bond are stronger than Silicon – Silicon bonds.
(B) Silicon – dioxide is an ionic solid while Silicon is metallic solid.
(C) Silicon – dioxide is polar while Silicon is non-polar.
(D) Silicon – dioxide forms tetragonal crystal while Silicon forms cubic crystals.
38. Metallic gold will not dissolve in nitric acid alone, but will dissolve in aqua regia. Which is the best
explanation for this observation?
(A) Chloride ion complexes gold (III), stabilizing it as AuCl4 .
(B) Nitric acid is a stronger oxidant in more acidic solution.
(C) Nitric acid and hydrochloric acid react to form NO2 Cl, which react readily with metallic
gold.
(D) Nitric and hydrochloric acid react to form Cl2 , which react readily with metallic gold.
39. Guanine is one of the bases in DNA, is susceptible to attack by alkylating agents. Which nitrogen
in guanine is most prone to alkylation?
O
B
H N C
N
H2N N N D
A DNA
(A) A
(B) B
(C) C
(D) D
40. Sodium halide crystallize in the rock salt structure, which has a cubic unit cell with 4 formula units
per unit cell. If sodium halide has density of 2.83 g / cm 3 and a unit cell edge length of 462 pm.
Which compound is it?
(A) NaF
(B) NaCl
(C) NaBr
(D) NaI
41. The degree of hydrolysis of a salt of weak acid and weak base in its 0.1 M solution is found to be
50%. If the molarity of the solution is 0.2 M, the percentage hydrolysis of the salt should be:
(A) 100%
(B) 50%
(C) 25%
(D) None of these
42. Solution of chemical compound x react with AgNO3 solution to form white ppt. ‘Y’, which
dissolves in NH4OH to give a compound ‘Z’. When ‘Z’ is treated with dil, HNO3 , ‘Y’ reappears.
The chemical compound ‘X’ can be
(A) NaCl
(B) CH3 Cl
(C) NaBr
(D) NaI
43.  
The  n2  n1  and n22  n12 for He ion in atomic spectrum are 4 and 8 respectively. The wave
length of emitted photon when electron jump from n2 to n1 is
32
(A) RH
9
9
(B) RH
32
9
(C)
32RH
32
(D)
9RH
44. The vapour pressure of a saturated solution of sparingly soluble salt  XCl3  was 17.20 mm of Hg
at 27o C . If the vapour pressure of pure H2 O is 17.25 mm of Hg at 300 K, what is the solubility of
sparingly soluble salt XCl3 in mole/lit?
(A) 4.04  102
(B) 4.08  102
(C) 2.02  102
(D) 4.04  103
45. O O O
C C C
H OH H OH H OH
I II III
Among these canonical structure, the correct order of stability is
(A) I > II > III
(B) III > II > I
(C) I > III > II
(D) II > I > III
46. Sulphuric acid cannot be used as:

(A) Hygroscopic agent
(B) Oxidizing agent
(C) Sulphonating agent
(D) Efflorescent
47. n. moles of ‘He’ gas are placed in a vessel of volume V lit. At TK, if V1 is free volume of ‘He’ then
diameter of ‘He’ atom is
1/3
 3 V1 
(A)  
 2 NA n 
1/3
 3  V  V1  
(B)  
 2NA n 
1/3
 6  V  V1  
(C)  
 2NA n 
1/3
 3V1 
(D)  
 N A n 
48. Blister copper is refined by stirring molten impure metal with green logs of wood because such a
wood liberates hydrocarbon gases. This process X is called____________and the metal contains
impurities of Y is___________
(A) X  Cupellation; Y  CuO2
(B) X  Polling; Y  Cu2O
(C) X  Polling; Y  CuO
(D) X  Cupellation; Y  CuO
49. 0.001 mole of Co NH3 5 NO3  SO4  was passed through a cation exchanger and the acid
coming out of it required 20 ml of 0.1 M NaOH for neutralization. Hence, the complex is:
(A) Co  SO 4  NH3   NO3
 5
(B) Co  NO3  NH3   SO4

 5
(C) Co  NH3   SO4NO3

 5
(D) None of these
50. First generation automobile air bags were inflated by decomposition of Barium azide. What mass
of barium azide would be required to inflate a 20 L air bag to a pressure of 1.23 atm at 27o C ?
(Given at. Mass of Ba = 137.327 and N = 14).
(A) 78.6 gm
(B) 74 gm
(C) 157 gm
(D) 52.4 gm
SECTION – B
51. The specific heat capacity of iron is 0.461 J g1 k 1 and that of titanium is 0.544 J g1 k 1 . A
sample consisting of 10.0 g Fe and 10 g of titanium at 100.0o C losses 200 J of heat to the
environment. What is the final temperature of the sample?
52. The Ksp of Ca  OH2 at 298 K is x  10 6 at 298 K

Half reaction Eo V
Ca2  aq   2e  Ca  s  2.87 V
Ca  OH2  s   2e   Ca  s   2OH  aq 3.02 V

Find x? [Given antilog 0.9263 = 8.44
53. Sulphur trioxide is formed from the reaction of sulphur dioxide and oxygen
1
SO2  g  O2  g  SO2  g
2
At 1000 K, an equilibrium mixture has partial pressure of 0.562 bar
SO 2 , 0.101 bar O2 and 0.332 bar SO3 . What is the equilibrium constant KP for this reaction at
this temperature.
54. In an amino acid, the carboxylic group ionizes at pK a1  2.34 and ammonium ion at pK a2  9.60 .
The isoelectric point of the amino acid is at pH?
yz
55. If the following molecule undergo dimerization then find the value of .
x
ClO3 ,OF, GaH3 , AlCl3 , ICl3 , BeH2 , NO2
Where x = Number of molecules which are hypervalent in dimeric form.
y = Number of molecule which complete octet in dimer form.
z = number of molecule which are hypovalent in dimeric form.
56. Find the number of basic radicals among the following cations, which can form soluble complex
on adding excess of NH3 .
Cd2  aq  ,Pb2 aq ,Ni2  aq ,Mn2  aq ,Zn2   aq  ,Ag  aq ,Hg2   aq  ,Fe 3  aq  ,Mg2  aq 
57. Find the total number of electron of Co2  ion which are present in non axial-d-orbitals in the
complex compound Co  dmg2 
o o
58. Calculate the I – I distance in A for given compound H2CCI2 if C – I bond length is 2.35 A
 sin60 o
 0.866 
59. At constant temperature and pressure, 5.0 L of SO 2 is combined with 3.0 L of O 2 according to
the equation
2SO2  g  O2  g   2SO3  g 
After SO 3 formation is complete, what is the volume of the mixture?
60. An element ‘E’ has electronic configuration of ‘K’ shell is  n  5  s2 and it has total number of
electron in its outer most shell is 2, in penultimate shell is 8 and in anti penultimate shell is 25.
Find the total number of unpaired electron in element ‘E’ in their ground state.
SECTION – A
61. Many states use a sequence of three letters followed by a sequence of three digits as their
standard license-plate pattern. Given that each three-letter three-digit arrangement is equally
likely, the probability that such a license plate will contain at least one palindrome (a three-letter
arrangement or a three-digit arrangement that reads the same left-to-right as it does right-to-left)
m
is , where m and n are relatively prime positive integers, then the value of m + n
n
(A) 58
(B) 59
(C) 60
(D) 63
62. There are 20 students participating in an after-school program offering classes in yoga, bridge,
and painting. Each student must take at least one of these three classes, but may take two or all
three. There are 10 students taking yoga, 13 taking bridge, and 9 taking paining. There are 9
students taking at least two classes, then number of students who are taking all three classes?
(A) 1
(B) 2
(C) 3
(D) 4
63. Right triangle ABC has right angle at C and BAC = ; the point D is chosen on AB so that
|AC| = |AD| = 1; the point E is chosen on BC so that CDE = . The perpendicular to BC at E
meets AB at F, then lim EF is equal to
0
1
(A)
2
1
(B)
3
1
(C)
4
1
(D)
5
64. All values of the real parameter ‘a’ such that the nonnegative solutions of the equation
(2a – 1) sin x + (2 – a) sin 2x = sin 3x form an infinite arithmetic progression are
(A) a < –2 or a > 2  {0}
(B) a < –3 or a > 3  {0}
(C) a < –5 or a > 5  {0}
13 13
(D) a<  or a >  {0}
2 2
1
65. If z  ei /13 , then is equal to (where i  1 )
1 z
(A) 1  z 2  z 4  z 6  z 8  z10  z12
(B) 1  z 2  z 4  z 6  z8  z10  z14
(C) z  z 3  z 5  z7  z9  z11
(D) z  z 3  z5  z7  z9  z11
66. If |z1| = 1, |z2 – 2| = 3 and |z3 – 5| = 6, then maximum value of |2z1 – 3z2 – 4z3| is
(where z1, z2 and z3 are complex numbers)
(A) 43
(B) 44
(C) 45
(D) 61
 Px 
67. Let P(x) be a polynomial of degree 4 having a local maximum at x = 2 and lim  3    27 . If
x 0  x 
P(1) = –9 and P(x) has a local minimum at x = 2. If global maximum value of y = P(x) on the set
A  x : x 2  12  7x is 4M, then the value of M is
(A) 6
(B) 7
(C) 9
(D) 13
68. The parabola y2 = x – y divides the triangle formed by the tangent to it at the origin and the
A p
straight line x + y = 0 and y = –1 into two parts whose areas are A1 and A2. If 1  where p, q
A2 q
p
 N and is in simplest form, then the value of (p + q)
q
(A) 3
(B) 4
(C) 5
(D) 6
69. Circles C1 and C2 of radii r and R respectively, touch each other as C2

shown in the figure. The line  , which is parallel to the line joining
A P B
the centres of C1 and C2 is tangent to C1 at P and intersects C2 at A, 
2 2 O
B. If R = 2r , then AOB equals
1 C1
(A) 22
2
(B) 45
(C) 60
1
(D) 67
2

t
70. Let x > 0 be a fixed real number. Then the integral e
0
x  t dt is equal to
–x
(A) x + 2e – 1
(B) x – 2e–x + 1
(C) x + 2e–x + 1
(D) –x – 2e–x + 1
71. The largest perfect square that divides 20143 – 20133 + 20123 – 20113 + ..... + 23 – 13 is
2
(A) 1
2
(B) 2
(C) 10072
(D) 20142
72. The sum of non-real roots of the polynomial equation x3 + 3x2 + 3x + 3 = 0

(A) equals 0
(B) lies between 0 and 1
(C) lies between –1 and 0
(D) has absolute values bigger than 1
73. If a, b are positive real numbers such that the lines ax + 9y = 5 and 4x + by = 3 are parallel, then
the lest possible value of a + b is
(A) 13
(B) 12
(C) 8
(D) 6
x
 t
74. For real x with –10  x  10 define f  x   2 dt (where [.] denotes greatest integer function).
10
The number of points of discontinuity of f(x) in the interval (–10, 10) is
(A) 0
(B) 10
(C) 18
(D) 19
n n
3n  2r
75. If 1  x 3    a x 1  x 
r
r
, then ar is (where n  N natural number)
r 0
n r
(A) Cr 3
r
n  1
(B) Cr  
3
n
(C) C2r 3r
(D) None of these
  3 
76. Number of solution of the equation sin1  sinx   x   ; x    , is
 2 2 
(A) 0
(B) 1
(C) 2
(D) 3
77. Let S = {1, 2, 3, 4, 5, 6, 7} P is a subset of S. After replacing back in S the elements of P, again
subset Q is selected. The number of ways such that n(P  Q) = 2, n(P  Q) = 4 is
(A) 810
(B) 820
(C) 830
(D) 840
dy 4x  5y  3
78. The general solution of  is
dx 5x  6y  2
(A) 2x2 – 5xy – 3y2 + 3x + 2y + c = 0
2 2
(B) 2x + 5xy + 3y + 3x + 2y = c
2 2
(C) 3x – 5xy + 2y + 2x + 3y = c
(D) 4x2 – 5xy + 6y2 + 3x – 2y = c
79. “If you are born in India then you are citizen of India” contrapositive of this statement is
(A) if you are born in India then you are not citizen of India
(B) if you are not citizen of India then you are not born in India
(C) if you are citizen of India then you are not born in India
(D) if you are citizen of India then you are born in India
80. The angle between the lines whose direction cosines are given by l + m + n = 0 and 2l2 + 2m2 –
n2 = 0
1
(A)   cos1  
3
 1
(B)   cos 1  
4
1
(C) cos 1  
4

(D)
3
SECTION – B
9x 2 sin2 x  4
81. The minimum value of for 0 < x < 
x sin x
82. A triangle has vertices P = (–8, 5), Q = (–15, –19) and R = (1, –7). The equation of the bisector of
P can be written in the form ax + 2y + c = 0, then the value of a + c
83. Let a, b, c be the three sides of a triangle, and let , ,  be the angles opposite them.
2 2 2 cot 
If a + b = 1989c , then the value of is equal to
cot   cot 
84. Let f(x) = |x – p| + |x – 15| + |x – p – 15|, where 0 < p < 15. Then the minimum value taken by f(x)
for x in the interval p  x  15 is equal to
85. For any integer n  5, let there are two n  n invertible matrices with real entries A. B satisfy the
equation A–1 + B–1 = (A + B)–1. If |A| = 3, then the value of |B|
86. The number of 2  2 matrices A with elements from the set {–1, 0, 1} such that A2 = I is
x 3 y 8 z 3 x3 y7 z6

87. Shortest distance between the lines   and   is
3 1 1 3 2 4
88. Number of common tangents with finite slope to the curve (x – 1)(y + 2) = 9 and (y + 2)2 = 8(x – 1)
is
    
89. Let r be a variable vector and a  î  ˆj  kˆ such that the scalars  r  î  ,  r  ˆj  ,  r  kˆ  are positive
  
integers. If r  a is not greater than 10, then total number of possible vectors r is given by
90. A student obtained the mean and standard deviation of 100 observations as 40 and 5.1
respectively. It was later found that he had wrongly copied down an observation as 50 instead of
40. The correct standard deviation is
FIITJEE
FULL TEST – V
JEE (Main)-2022
TEST DATE: 06-02-2022
ANSWERS, HINTS & SOLUTIONS

Physics PART – A
SECTION – A
1. A  
Sol. Direction of propagation is E  B
2. B
Sol. Peak value of information voltage = 18 V
modulation percentage  peak carring voltage
18 =
100
VC = 30 V
V  Vmin
Peak carrier voltage VC  max
2
 Vmax + Vmin = 60 V
3. C
Sol. Lyman series  UV region
Highest  n = 2  n = 1
E2 E1 = 10.2 eV
kmax  10.2 eV  
0 = 10.2 eV  (just able to eject)
 10.2 eV
v th    2.46  1015 Hz
h h
4. C
Sol. v x  ucos  , v y  usin   gt
AITS-FT-V-PCM(Sol.)-JEE(Main)/22 2
1 1
K.E.  mv 2  m u2 cos2   (usin   gt)2 
2 2  
As v(t)  ucos  î  (u sin   gt)jˆ
K.E.  t 2 parabola
and K.E. 0 in projectile
5. A
Sol. KCL at x 50 V x
(100x)V
x 50  x (100  x)  x
  0
R R R i1
75
x= V i2
2
and KCL at y
100 V 0V
y 50  y 50  y (100y) y
 
R R R i1
100
y  V (100x)V 50 V
3 x
2(x) y 325 5
Current = 2i1 + i2 =    amp
R R 3R 3
6. D
d d
Sol. in  out
dt dt
k1A 1(T1  T0 ) k 2 A 2 (T0  T2 )

2b b
T1  T2
T0  and A1 = A2
2
We get k1 = 2k2
7. D
I0 I I
Sol. I1  , I2  0 cos2 30, I3  I2 cos 2 30  0 cos 4 30
2 2 2
6
I I  3 27
I4  I3 cos 30  2 cos6 30  0 
2
  I0
2 
2 2  128
8. A
V  t/R2 C V
Sol.
R2
e 
R1
 
1  eR1t/L  constant
V  t/R2C V R1t/L
 e  e  R1  R2
R2 R1
R1 1

L R2C
L
 R1R 2 
C
3 AITS-FT-V-PCM(Sol.)-JEE(Main)/22
9. C
Sol. As the tank is sufficiently deep, the ball will attain terminal velocity Fb
v
2(  b )R2g
vT 
9
Fv
 = density liquid
b = density body
T (  b )R2
mg
 T(2)  T(1)
 H2> H1
10. D

Sol. d  1.22
d
dI  2.56  103
dII  3.05  107
dIII  1.22  107
dIV  6.1 103
1
Resolving power =
d
RPIII  RPII  RPI  RPIV
11. A
Sol. For isothermal Bulk modulus  Pressure
12. B
Sol. Using Principle of calorimetry
mc T = 0.01 mL
hence T = 0.01 L/c = 0.01 × 2.26 × 106/4200 = 5.4°C F.
New temperature (assuming no other losses) is 4.6°C.
13. D
Sol. B1 + B2 = B3 y
0I  I 0I
 0 
2(d  x) 2x 2(d  x) 1 2 3
1 1 1 x  d x 1
   
d x x d x x(d  x) (d  x) x
x
 (d + 2x) (d  x) = dx +x 2 d d
 d2xd + 2xd  2x2 = dx + x2
 d2 + xd 2x2 = dx + x2
d
 3x2 = d2 x = 
3
14. C
 x 
Sol. v(x)  v 0 sin  
 x0 
 x   dx  x    x 
 a(x)  v 0 cos    v 0 cos   v0 sin  
 x0  x0 dt  x0  x 0  x0 
v 20  2x  v 20  2x  2 v02

a(x)  sin    a(x)    2 x
2x0  x0  2x0  x0  x0
So, motion is not oscillatory
d2 x v
2
 k 2 x  0  x  Aet  Bet , where k  0
dt x0
t
As t , x = Ae if we assume k small and t is large, we can assume x is some fixed quantity.
15. D
1 U2 r13 1
Sol. Electrostatic potential energy U  3
  
r U1 r23 8
16. B
Sol. h = r – rcos
r 45°
= r(1 – cos )
h
= 3.4 (1 – cos 45°) r

 1.7 2  2 m 
1
and from energy conservation, mgh =  2m  v 2
2

Hence, v  gh  9.81 1.7 2  2  3.1 ms1 
17. D
k 640
Sol.    1600
m  m 0.38  0.02
 = 40 rad/s
Let v be the velocity acquired by the block m where bullet m strikes it and comes to rest in it.
By conservation of momentum
m 0.02 0.02
(m  m)v   mv  v   v  200   200  10 m/s
m  m 0.38  0.02 0.4
The block is set in oscillation about it mean position with maximum amplitude A
dx
 x   A sin t    A cos t
dt
In the mean position, the velocity is maximum
10 10
 A = 10  A    0.25
 40
 x = 0.25 sin(40t)
18. A
Sol. The electric fields at r < b and r > a are both zero. At b < r <a the electric field is
Q
E er
40r 2
Hence the field energy is
a 2
1  Q  2 Q2  1 1 
W 
b
0   4r dr 
2  40r 2



80  b a 
When the outer spherical surface contracts from r – a to r = a, the work done by the electric force
is equal to the decrease of the electric field energy
Q2 2
 1 1  Q (a  a)
Wa  Wa     
80  a a  80 aa
19. C
Sol. C is the point of contact around which the masses M and m rotate. As it is the instantaneous
center of zero velocity, the equation of motion is of the form C = IC, where IC is the moment of
inertia of masses M and m with respect to point C. Now
1 
IC   MR2  MR2   md2 …(i)
2 
Where d2  L2  R2  2RL cos  …(ii)
For small oscillation, sin   , cos   1 and
3MR 2
IC   m(L  R)2
2
Therefore, the equation of motion become
 3MR 2 
  m(L  R)2    mgL sin   mgL
 2 
mgL
Or   2
0
3MR 2
 m(L  R)
2
mgL
  2
rad/s
3MR 2
 m(L  R)
2
20. D
XC v 1
Sol. (i) v0  v i  0  , phase difference () is 0
XC  XC vi 2
XC v 1 1 1
(ii) v 0  vi  0    eiCR phase difference () is 0
R  XC vi R 1  iCR 1  ( CR)2
1
XC

Phase difference () is 0 <  <
2
SECTION – B
21. 00005.00
sini
Sol.  2  i  45
sinr
Total deviation 30
= (45 30) + 1802(30) + (45 30) 30
= 30 + 120
= 150 = 30x 30
x=5
22. 00009.00
Sol. Equivalent circuit can be drawn as following 1 6
Req = 4
So, I = 9A
36 V 3
1
23. 00001.50
t
Sol. In V = nV0 
RC
V t d  1 t d 1
0 R  C
V C dR  R  R dC  C 
t  R C  50  106  5 10 
     8 4 
   0.015 =N
CR  R C  10  5  10  100 100 
24. 00001.73
  i
Sol. i  2sin   t   2 sin t 2
 2 
i  (2)2  ( 2 )2  6
i 6
iRMS    3
2 2 2
25. 00006.00
Sol. UAB = 0, UDE = 0 P
 (U)cycle = 0
A
UBC + UCD + UEA = 0 Isothermal
Adiabatic B Adiabatic
10 + UCD + 16 = 0
U = 16J  = 10
UCD = 6
E
C
D Isobaric
Isothermal V
26. 00002.00
Sol. Time difference (Separation) between two zero velocities
T
 0.25 s, T  0.5 s
2
1 1
So, frequency f    2 Hz
T 0.5
27. 00000.50
1 V
Sol.  
2nd2 2Nd2
V
    V  N
N
V1 1N1 1N1
   0.5
V2  2N2 N 
(41 )  1 
 2 
28. 00014.14
gx 2
Sol. y  x tan  
2u2 cos2 
y=5m y

velocity just before collision v  10iˆ  0ˆj
 O
Apply elastic collision, velocity v x  10( î) m/s
 5m
vy  0
1 2 10 m
s  ut  at in y-axis
2
1
 (y  5)  0  (10)t 2
2
10
 10   t 2
2
t  2 sec
Range after collision in x-axis (v x)t = 10 2  14.14 m
29. 00001.60
Sol. dm  rdr  cr 2 rdr  cr 3dr y-axis
2r
 dm 
y cm 
dr
 dm
R
2r 2 r 4 dr 2 R5 r
 c 3
r dr  O x
y cm    0
R
  45
3 2r R
 cr dr  2 r dr 4
3
8R 
y cm  
5 5
30. 00004.04
Sol. Let the body travel a distance s on the incline and come down through a height h.
Potential energy lost = mgh = mgs sin 
Work done against friction W = fs = mg cos.s
70
By problem mg cos s = mgs sin 
100
 = 0.70 tan  = 0.7 tan30 = 0.404
SECTION – A
31. C
Sol. From the chemical equation, we can have
1 1
 0.15  35  10 3 L   H2O2   50  103 L
2 5
 H2 O 2   0.263 M
32. D
Sol. The mass% of nitrogen is higher in their compound hence gives greatest amount of N2 gas.
33. B
Sol. As we know that
G  H  TS  RT nk
Here the reaction is vapourisation, therefore, the equilibrium constant equal to vapour pressure of
the liquid
H S
Thus,  nP   
RT R
H
Slope of the graph in the question is equal to 
R
 H  4544  8.314
= 37.8 kJ/mol.
34. D
Sol. Cu  s   2Ag  aq  Cu2  aq   2Ag  s 
By Nernst equation
RT
E  Eo  nQ
nF
Cu2  
Q   
 2
 Ag 
 
 Increasing Q will decrease E.
Hence, I is incorrect and by adding Cl to the Ag .
 Cell precipitate
  Ag   es hence Q is  es
And  II is also incorrect.
35. C
Sol. Ge < Si < As < P
Si = 786 kJ/mole; P = 1012 kJ/mole; Ge = 761 kJ/mole; As = 947 kJ/mole.
36. A
Sol. Isoelectric point is significantly determined by its amine and carboxylic acid functinalities.
37. A
Sol. Si – O bond require more energy becomes it is stronger than Si – Si bond, as ‘O’ atom is smaller
than Si.
Si is not a metal and SIO2 is not a ionic compound and also not polar but Si and SiO2 forms 3D
network covalent solid.
38. A
Sol. Conc. HNO3 or HCl cannot oxidize Au to Au3  because standard reduction potential
3 
Au  3e  Au is too high.
But Cl in aqua regia complex with Au3 , lowering down the reduction potential throuh stabilizing
it as AuCl4 .
39. C
Sol. Most basic, hence easily alkylation.
40. A
1
 4  23  4x  
Sol. 6.023  1023  2.83 g / cm3
3
 1 cm 
 462 pm  
 1010 Pm 
92  4x 3
6.023  10 23 
 2.83  462  10 10 
92  4x  168
168  92 76
x   19
4 4
 NaF
41. B
Sol. % hydrolysis does not depend on the concentration, in case of weak acid + weak base; salt.
42. A
Sol. NaCl  AgNO3  AgCl  NaNO3
Withe ppt.
AgCl  NH4 OH   Ag NH3 2  Cl
 Ag  NH3 2  Cl  2HNO3  AgCl  NH4NO3
43. C
Sol. n22  n12  8
 n2  n1  n2  n1   8
8
n2  n1  2
4
n2  n1  4
 n2  3
n1  1
1  1
 RH  4 1  
  9
9

32RH
44. A
Po  Ps
Sol.  m  mol. wt. of solution
Ps
Po  Ps 1000
 m
Ps 18
17.25  17.20 1000
m   0.1615
17.20 18
If m = M = 0.1615.
xCl3  x  3Cl
Mtotal s  3s  4s  0.1615
0.1615
s  0.04  102
4
 4.037  102
45. C
Sol. Neutral species is more stable than charged and complete octet resonance is more stable than
incomplete octet resonance.
46. D
Sol. Sulphuric acid does not show efflorescent.
47. B
Sol. b  4Vm
4 3
 4  NA  r
3
V1  V  nb
nb  V  V1
V  V1 4
b  4.NA  r 3
n 3
1/3
 3  V  V1  
r 
 16NA n 
1/3
 3  V  V1  
D  2 3 
 2  2 NA n 
1/3
 3  V  V1  
D 
 2NA n 
48. B
Sol. The refining process of blister copper is known as polling and Cu2O impurities are present in the
Cu metal.
49. B
Sol. Meq. of complex = Meq. Of acid = Meq. of NaOH
W
 1000  N  V
E
 0.1 20
W 0.1 20
 nf 
M 1000
0.1 20
n  nf 
1000
0.1 20
nf  2
0.001 1000
50. B
Sol. PV = nRT
RV 1.23  20
n  1
RT 0.0821 300
Ba  N3 2 

 B  3N2
1 3
1
Number of moles Ba N3 2 required for 1 mole of N2  mole
3
1
  137.327  84 
3
221.327
  74
3
SECTION – B
51. 00080.10
Sol. By law of conservation of environment
t  1  2
200  10  0.461 T  100   10  0.544  T  100 
  T  100  0.461  0.544   10
T  80.1o C
52. 00008.44
Sol. The dissociation reaction of Ca  OH2 is
Ca  OH2  s   Ca2  aq   2OH  aq
Ca  s   Ca2  aq  2e 

Ca  OH 2  s   2e   Ca  s   2OH
Ca  OH2  s   Ca2   aq  2OH
Eo  E ocal  E oanode
 3.02 V   2.87 V   0.15
From Nernst equation
RT
E  Eo  nQ
nF
At equilibrium E = 0
RT
Eo  nK sp
nF
Eo .nF
nK sp 
RT
E o .nF 0.15  2  96500
logK sp  
2.303RT 2.303  8.314  298
28950
logK sp   5.0737
5705.848
logK sp  5.0737
K sp  Anti log  5.0737 
 Antilog 6.9263
K sp  8.44  10 6
53. 00001.86
1
PSO  0.332
Sol. KP   2   1.86
1/2 1/2
PSO  PO2   0.562  0.101
 2
54. 00005.97
pK a1  pK a2 2.34  9.60 11.94
Sol. PI     5.97
2 2 2
55. 00003.00
Sol. 2ClO3  Cl2 O6 hyper valent 
2OF  O2F2  complete octet 
2GaH3  Ga 2H6 hypovalent 
AlCl3  Al2Cl6 complete octet 
2ICl3  I2Cl6 hyper valent 
2BeH2  be2H4 hypovalent 
2NO2  N2O 4  complete octet 
x  2| y  3| z  2
yz 3x2
  3
x 2
56. 00004.00
Sol.  Soluble in excess of NH3 sol.
Cd2  aq ,Ni2  aq ,Zn2  aq ,Ag  aq 
57. 00005.00
Sol. Number of electron in non-axial d-orbital
 
dxy ,dyz ,dxz  2  2  1  5
58. 00004.07
Sol. H I
o
60
C C O
H I
IO  C  I sin 60 o  4.07
 I  I  2  IO
 2  2.035  4.07
59. 00005.50
Sol. 2 SO 2  g   O 2  g   2SO 3  g 
 
5 3
Limiting reagent is SO2, hence total volume of gas after complete formation of SO3 = 5 L SO3 +
0.5 L O2 = 5.5 L.
60. 00007.00
Sol. K  n  5  s2

6
Outer most shell = 2
Penultimate shell = 8
Anti penultimate shell = 2
1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6 6s2 4f 7
25 8 2
SECTION – A
61. B
Sol. Consider the three-digit arrangement, aba. There are 10 choices for a and 10 choices for b (since
10  10 1
it is possible for a = b), and so the probability of picking the palindrome is 3

10 10
1
Similarly, there is a probability of picking the three-letter palindrome
26
1 1 1 35 7
By the Principle of inclusion-exclusion, the total probability is    
26 10 260 260 52
 7 + 52
62. C
Sol. By property of inclusion/exclusion, we have A1  A 2  A 3   A  A
i i  Aj  A
Number of people in at least two sets is  A A i j  2 A1  A 2  A 3  9
So, 20 = (10 + 13 + 9) – (9 – 2x) + x, which gives x
63. B

Sol. Let G be the point obtained by reflecting C about the line AB. Since ADC = ,
2

we find that BDE      ADC   ADC    BDC    BDC
2

sin  
BE BE  2  where we have used the law of sines in BDG. But by L’Hospital’s
EF   
BC BG  3 
sin  
 2 
Rule
 
sin   cos  
lim  2   lim 2  1
 0 3
    0  3  3
sin   cos  
 2   2 
64. A
Sol. Since sin 2x = 2 sin x cos x and sin 3x = sin x (4 cos2 x – 1), we may write the equation in the
2 a
form sin x (2 cos x – (2 – a) cos x – a) = 0. Thus sin x = 0, cos x = 1 or cos x =  . The
2
nonnegative solutions of the equations sin x = 0 and cos x = 1 are x = k and x = 2 k, k = 0, 1, 2,
a
.... respectively. Let |a| > 2. In this case the equation cos x =  has no solution and therefore
2
the nonnegative solutions of the initial equation are 0, , 2, ....., which form an arithmetic
a
progression. Let now |a|  2 and let x0 be the only solution of the equation cos x =  in the
2
interval [0, ]. In this case the nonnegative solutions of the last equation are x = x0 + 2k and x =
2 – x0 + 2k. It is clear now that the nonnegative solutions form an arithmetic progression only

when x0 = 0, x0 = and x0 = , so giving a = –2, a = 0 and a = 2. The values of a are a = 0 and
2
|a| > 2.
65. D
1  z13
Sol. z  ei /13  z13  1 ; z13  1  0  0
1 z
2 3 12
 1 – z + z – z + ..... + z = 0 ..... (1)
1  z13 2
 
1 z 1 z
2
 1 + z + z2 + z3 + ..... + z12 = ..... (2)
1 z
From equation (1) and (2), we get
1 1
1 + z2 + z4 + z6 + z8 + z12 = and z + z3 + z5 + ..... + z11 =
1 z 1 z
66. D
Sol. |2z1 – 3z2 – 4z3| = |2z1 = 3(z2 – 2) – 4(z3 – 5) – 26|  2|z1| + 3|z2 – 2| + 4|z3 – 5| + 26 = 61
67. A
 Px  4 3 2
Sol. lim  3    27  P(x) has no constant term let P(x) = ax + bx + cx + dx
x 0  x 
 3 – d = 27  d = –24
P(x) = ax4 + bx3 + cx2 – 24x ; P(2) = 0, p(1) = –9, p(2) = 0
P(x) = 4ax3 + 3bx2 + 2cx – 24 ; P(x) = 12ax2 + 6bx + 2c
P(x) = 24ax + 6b ; a + b + c – 24 = –9
 a + b + c = 15 ..... (1)
P(2) = 0
 4a(8) + 3b(4) + 2c(2) – 24 = 0
 8a + 3b + c = 6 ..... (2)
P(2) = 0
 24a(2) + 6(b) = 0  8a + b = 0 ..... (3)
Solving (1), (2) and (3)
a = 1, b = –8, c = 22
 P(x) = x4 – 8x3 + 22x2 – 24x ; P(x) = 4x3 – 24x2 + 44x – 24 = 4[x3 – 6x2 + 11x – 6]
P(x) = 4[(x – 1)(x – 2)(x – 3)]
P(x) = 4[3x 2 – 12x + 11] > 0  x  [3, 4] = 4[(3) (2) (1)] = 24 = 4M  M = 6
68. A
Sol. Tangent to parabola at origin is x – y = 0 y = –x y=x
2
2  1 1 O
y + y = x ; y    x 
 2 4
Let A be the shaded area
0 0
 y3 y 2 
A    y  y  dx    
2

3 2  1 (0, –1) B(1, –1)
1 y = –1
  1 1  1 A(1, –1)
=        
  3 2  6
1 1 1 1
 
1 A1 A 1 2 p 1 2
Area of OAB =  1 2  1 ;  2 6 or 2 6  1  or   or p+q=3
2 A2 1 1 1 1 A2 2 1 q 2 1
 
2 6 2 6
69. B
Sol. 
Equation of AB y = r : A R  R2  r 2 , r using R2 = 2r2 
 
B R  R2  r 2 , r point A(R – r, r) B(R + r, r) slope OA 
r
Rr
 m1
r m  m2 
Slope OB   m2 ; tan   1  1 ;    45
Rr 1  m2m2 4
70. A
 x 
Sol.  e1 x  t dt  e1 t  x dt  e1  x  t dt apply integration by parts
     
II I II I
0 0 x
x 
=  x  t   e1    1 e  t 0   x  t  e t  e t  x = x + 2e – 1
–x
71. C
3 3 3 3 3 3 3
Sol. –(1 + 2 + 3 + ...... + 2014) + 2(2 + 4 + ..... + 2014 )
2 2
 2014  2015  3  1007  1008  2 2 2 2
=    22   = –(1007) (2015) + 4(1007) (1008)
 2   2 
= –(1007)2 [(2016)2 – (2015)2] = (1007)2 4031
72. C
Sol. f(x) = x3 + 3x2 + 3x + 3 = 0 ; f(x) = 3x2 + 6x + 3 = 3(x + 1)2  0 ; f(x) is increasing function
Now f(–3) = –6 < 0 ; f(–2) = 1 > 0
 real root  lies between –3 and –2
 +  +  = –3 ; –3 <  < –2 ;  +  – 3 <  +  +  <  +  – 2
 +  – 3 < –3 <  +  – 2 –1 <  +  < 0
73. B
a 9
Sol.   ab = 36 using AM  GM
4 b
ab
 ab  a + b  12
2
74. A
Sol. Let r be an integer in (–10, 10)
x  9 8 r h 
   
Now, LHL = lim  2 t dx = lim  2 t dt  2 t dt  .....  2 t dt 
  
x r h0  
10  10 9 r 1 
= lim  210  2 9  .....  2r 1 
1  h  
h 0
10
= 2  29  .....  2r 1 ..... (1)
x  9 8 r h 
   
lim  2 t dt = lim  2 t dt  2 t dt  .....  2 t dt 
  
x r h0  
10  102 9 r 
= 2 10  29  .....  2r 1 ..... (2)
r
t
f r   2 dt = 2 10  29  .....  2r 1 ..... (3)
10
From equation (1), (2) and (3), we get f(x) is continuous at all integers
75. A
n n n r
 1  x 2  3x  
 a x  1  x  
r 2
Sol. r
r 0
n r n n r
  n 
Cr 1  x 
2
  3x 2   
a r x r 1  x 
2

r 0
2n  2r r
Compare the coefficients of x 1  x 
76. B
  
 x ;  x
2 2
Sol. sin1  sin x   
  x ;  3 
x
 2 2
77. D
Sol. R.N.W = 7 C2   5 C2  22   840
78. A
Sol. –4xdx + 6ydy + 5(xdy + ydx) – 3dx – 2dy = 0
Integrating –2x2 + 3y2 + 5xy – 3x – 2y = c
79. B
Sol. pq
Contrapositive ~p  ~q
80. A
Sol. l2 + m2 + n2 = 1 ; l + m + n = 0 ; 2l2 + 2m2 – n2 = 0
 1 1 2  1 1 2
Solving above equations, we get the direction cosines as  , ,  and  , , 
 6 6 3  6 6 3 
 1 1 2  1 1 2
or   , ,  and   , , 
 6 6 3  6 6 3 
 1
The angle between these lines in both the cases is cos1   
 3
SECTION – B
81. 00012.00
9y 2  4 4
Sol. Let y = x sin x. We can rewrite the expression as  9y 
y y
Since, x > 0 and sin x > 0 because 0 < x < , we have y > 0. So we can apply AM – GM
4 4 4 4 2
9y   2 9y   12 . The equality holds when 9y   y 2   y 
y y y 9 3
Therefore, the minimum value is 012.
82. 00089.00
Sol. Use the angle bisector theorem to the angle bisector of P divides QR into segments of length
25 15 25 15 QP 5
  x , . It follows that  and so
x 20  x 2 2 RP 3
 5x  3x Q 5yR  3y Q   23 
P   R ,    5,  
 8 8   2 
11
The desired answer is the equation of the line PP·PP has slope  , from which the equation
2
to be 11x + 2y + 78 = 0. Therefore, a + c = 089
83. 00994.00
2 2 2 2 2
Sol. a + b – 2ab cos  = c = 1989c – 2ab cos   ab cos  = 994c
cot  cos  sin  sin  cos  sin  sin  ab ab 99c 2
Now,    cos    = 994
cot   cot  sin  sin2  c2 c 2 ab
84. 00015.00
Sol. It is best to get rid of the absolute values first. Under the given circumstance, we notice that
|x – p| = x – p, |x – 15| = 15 – x, and |x – p – 15| = 15 + p – x
Adding these together, we find that the sum is equal to 2\30 – x, which attains its minimum value
(on the given interval p  x  15) when x = 15, giving a minimum of 015
85. 00003.00
Sol. A–1 + B–1 = (A + B)–1  (A–1 + B–1)(A + B) = (A + B)–1(A + B)
 2I + A–1B + B–1A = I  A–1B + B–1A = –I
Let A–1B = P
P + P–1 = –I  P2 + I + –P  P2 + I = –P  P2 + P + I = 0
 (P – I)(P2 + P + I) = 0  P3 = I
|B| = 1  |A–1| |B| = 1  |A| = |B|
86. 00016.00
a b  a2  bc  a  d b   1 0 
Sol. A2     
c d c  a  d  bc  d2  0 1
If a + d = 0, a2 + bc = 1, b = 0, c = 0, d = 1, –1, a = 1, –1
or c = 0, b = 1, –1, a = 1, –1
If b = 0, c = 0, a = 1, –1, d = 1, –1
Number of quadruples (a, b, c, d) = 16
87. 00016.43
2
Sol.  3  3   5  8  7   1  3  6   3 30
30 30 30
88. 00001.00
4 1
Sol. m3   
49 9
89. 00120.00
Sol. x + y + z  10  R.N.W = 9 C2  8 C2  .....  2 C2 = 36 + 28 + 21 + 15 + 10 + 6 + 3 + 1 = 120
90. 00005.00
Sol. Let the variable be x. Here n = 100, incorrect A = 40, incorrect  = 5.1
From formula A 
 x
 x  nA
n
 Incorrect x = 100  40 = 4000
 Correct x = incorrect x – 50 + 40 = 4000 – 50 + 40 = 3990
2 2  x2 2 2 2
Again, from   A  , we get x = n( + A )
n
2 2 2
 Incorrect x = 100{(5.1) + (40) } = 100 (26.01 + 1600) = 162601
 Correct x = incorrect x – 50 + 402 = 162601 – 2500 + 1600 = 161701
2 2 2
 Correct mean A 
 x 3900
  39.9
n 100
 x 2 161701
Correct   2  A 2     1617.01
n 100
 Correct 2 = 1617.01 – (correct A2) = 1617.01 – (39.9)2 = 1617.01 – 1592.01 = 25
FIITJEE
FULL TEST – VI
JEE (Main)-2022
TEST DATE: 13-02-2022
answer.
AITS-FT-VI-PCM-JEE(Main)/22 2
Physics PART – A
SECTION – A
1. The upper end of a simple pendulum is fixed to a vertical z-axis and set in motion such that the
bob moves along a horizontal circular path of radius 1 m paralle!t the x-y plane, 5 m above the
origin. The bob has a speed of 4 m/s. The string breaks when the bob is vertically above the x-
2
axis. Taking g = 10 m/s ; the point where hits, the bob lies in the
(A) x-y plane at (1 m, 4 m)
(B) y-z plane at (1 m, 4 m)
(C) x-y plane at (4 m, 1 m)
(D) y-z plane at (5 m, 1 m)
 1 2 0
2. Resistance of a conductor of length L and area of cross-section A is given by R   L  2 L  ,
  A
where  is a constant and 0 is resistivity at 0°C. Then the resistivity  of the conductor varies
along the length x of the conductor as
(A)   0 (1  x)
(B)   0 (1  x2 )
(C)   0 (1  2 x)
(D)   0 (1  x)
3. A rod of length 2 is moving such that its ends A and B move in

contact with the horizontal floor and vertical wall respectively as B
shown in figure. O is the intersection point of the vertical wall and
horizontal floor. The velocity vector of the centre of rod C is C
always directed along tangent drawn at C to the

(A) circle of radius whose centre lies at O
2
(B) circle of radius  whose centre lies at O O A
(C) circle of radius 2 whose centre lies at O
(D) None of these
4. The secondary coil of an ideal step down transformer is delivering 500 watt power at 12.5 A
current. If the ratio of turns in the primary to the secondary is 5: 1, then the current flowing in the
primary coil will be
(A) 62.5 A
(B) 2.5 A
(C) 6A
(D) 0.4 A
3 AITS-FT-VI-PCM-JEE(Main)/22
5. Two block of masses m1 and m2 are connected with a m1 m2

massless unstretched spring and placed over a plank
moving with an acceleration 'a' as shown in figure. The a
coefficient of friction between the blocks and platform
is .
(A) spring will be stretched if a  g
(B) spring will be compressed if as a  g
(C) spring will neither be compressed nor be stretched a  g
(D) spring will be in its natural length under all conditions
6. Liquid of density  is filled in the container of negligible mass

having area A. Area of hole ‘a’ very small (a << A) is made
near the bottom in the wall of container. Co-efficient of friction
a
between container and surface is equal to   . As liquid is
A
coming out of vessel, instantaneous acceleration of the
container is:
A
(A)  a g
 
3g
(B)
2
a
(C)  A g
 
(D) zero
7. A uniform triangular plate ABC of mass m and moment of a B

inertia I (about an axis passing through A and perpendicular to A
plane of the plate) can rotate freely in the vertical plane about
point 'A' as shown in figure. The plate is released from the
position shown in the figure. Line AB is horizontal. The a a
acceleraion of centre of mass just after the release of plate is:
mga2
(A)
3I C
2
mga
(B)
4I
mga2
(C)
2 3I
mga2
(D)
3I
8. A capacitor is made of two concentric spherical shells A and B of radii a and b respectively,
where a < b. The external shell B is grounded (VB = 0). Inner shell i.e., (r  a) is filled with a
uniform positive charge of density . Variation of electric field versus distance from the centre.
(A) E (B) E
a b r a b r
(C) E (D) E
a b r a b r
9. All three spheres are identical having radius 10 cm. There is no slipping at any point of contact.
Plank P and Q are moving in opposite direction with speed 10 and 30 cm/sec. height of
instantaneous axis of rotation of sphere A from the ground is:
Q
v1 = 30 cm/s
v2 = 10 cm/s A
P
B C
(A) 20 cm
(B) 30 cm
(C) 15 cm
(D) 25 cm
10. Two strings A and B of equal length but unequal linear mass density are tied together with a knot
and stretched between two supports. A particular frequency happenes to produce a standing
wave on each part, with node at the knot as shown. If linear mass density of the two strings A and
B are 1 and 2 respectively, then:
String A String B
(A) 1  2
(B) 1  2
(C) 1  2
(D) can’t be decided
11. Figure shows variation of magnetic field inside and outside two cylindrical wires P and Q carrying
currents that are uniformly distributed across the cross section of wires. If current density for two
wires are jP and jQ, then:
B
Wire Q
Wire P
r
(A) jP  jQ
(B) jP  jQ
(C) jP  jQ
(D) can’t be decided
12. Radius of curvature of a concave spherical surface air

separating air-glass medium is R. A point object is glass
placed on the principal axis in the glass (g = 1.5).
For the image to be real, seen by observer in air,
distance of the object from P should be:
(A) 2R < u < 3R P
object
(B) u < 2R
(C) u=R
(D) u > 3R
13. A parent radioactive nucleus A (decay constant A) converts into a radio-active nucleus B of
decay constant b, initially number of atoms of B is zero. At any time Na, Nb is number of atoms of
nuclei A and B respectively then maximum value of Nb is:
aNa
(A)
b
bNa
(B)
a
(a  b )Na
(C)
b
bNa
(D)
(a  b )
14. Initially spring is compressed by distance x 0 from K

equilibrium position. At this compression block is
3K
given velocity x 0 , so that compression in the
m x0
spring increases and block start S.H.M. (Spring Equilibrium
constant is K). Equation of motion of the block is: position
 K 
(A) y  3x 0 sin  t 
 m 3
 
 K 
(B) y  2x 0 sin  t 
 m 6 

 K 
(C) y  3x 0 sin  t 
 m 6 

 K 
(D) y  2x 0 sin  t 
 m 3
 
15. An electric circuit consists of three conducting rods M

MO, ON and PQ as shown in the figure. Resistance
of rods per unit length is . The rod PQ slides at a
constant velocity v, keeping its tilt angle relative to
ON and MO fixed at 45°. At each instant, circuit is v B
closed. The system is placed in a uniform magnetic P
field B which is directly perpendicular to the page.
The rate of change of induced emf at any instant of 45
time t is O Q N
(A) Bv t = t
(B) Bv 2
(C) Bv 3 t = 0
(D) B2v
16. 1.5 mW of 400 nm light is directed at a photoelectric cell. If 0.10% of the incident photons
photoelectrons, the current in the cell is
(A) 0.36 A
(B) 0.48 A
(C) 0.42 mA
(D) 0.32 mA
17. Loop ABCD and long straight wire are in the same plane. C
Side CD = 2AB. Distance between long straight wire and
AB is equal to the distance between AB and CD. Net force B 
on the loop is:
(A) Towards the long straight wire I
(B) Away from the long straight wire I O
(C) Parallel to the long straight wire
(D) Net force on the loop will be zero A 
18. A hollow circular tube of radius R and negligible internal y

diameter is fixed on horizontal surface. Ball A of mass m is
given velocity v0 in the shown direction. It collides with ball mB = 2m
B of mass 2m. Collision is perfectly elastic. If centre of loop
is origin of co-ordinate system, then co-ordinate of next
collision.
 3 R (0, 0)
(A)  R,   O x
 2 2 
 3 R
(B)   R, 
 2 2  mA = m
R 3 
(C)  , R

2 2 
R R
(D)  2,2
 
19. Mirror is moving towards the particles with speed 2 v0 = 2 cm/sec

cm/sec. Speed of particles A and B are 10 2 and 5
cm/sec respectively in the direction shown in figure.
Magnitude of velocity of image of the particle B with
respect to image of A. B
(A) 325 cm/sec
45
(B) 15 cm/sec
(C) 13 cm/sec
(D) 269 cm/sec
20. In the figure shown if a parallel beam of white light is

incident on the plane of the slits, then the distance of
central white spot on the screen from point O is: [assume
d << D,  << d] 2d/3
d O
(A) 0
(B) d/2
(C) d/3
(D) d/6
D
SECTION – B
1
21. The least count of a stopwatch is second. The time of 20 oscillations of a pendulum is
5
measured to be 50 sec. What will be the minimum percentage error in the measurement of time.
22. Determine the current in the circuit in ampere.
5
0.2V
23. A vernier calipers has 1 mm marks on the main scale. It has 10 equal divisions on the vernier
scale which match with 8 main scale divisions. What will be the least count of vernier calipers in
cm.
24. The angle of dip at a place where horizontal and vertical componetns of earth’s magnetic field are

equal is . Find the value of N.
N
25. A sinusoidal electromagnetic plane wave travels thorugh empty space in x-direction. At a certain
point P in space, the oscillating electric field Ey has amplitude of magnitude E0 = 63 V/m. Find the
maximum magnitude B0 of the magnetic field at the same point in microtesla. (speed of light c =
3  108 m/s)
26. Three point charges, each of charge +q are rigidly fixed at the three corners of an equilateral
triangle of side a. The surface tension of soap film is T. The system of charges and plane film are
1/N
 q2 
in equilibrium and a  k   , where k is constant. Then find N.
 T
 
27. n moles of an ideal monoatomic gas undergoes a process in which the temperature changes with
volume as T = kV2. If the temperature changes from T0 to 4T0 then the work done by the gas is
N
nRT0 . Find the value of N.
2
28. A semi-infinite conductor AB lies along the axis of

conducting circular loop of radius R, such that one end of
conductor is at the centre of loop. If the current in conductor
AB varies at a rate of 0.2 amp/sec then what will be
induced emf (in volt) in the loop. (Radius of loop R = 2m) A B
29. A complex current wave is given by

i = 3 + 3 sin t. What will be its average value over one time period in ampere?
30. A charge +Q is uniformly distributed in a spherical volume of radius R. A particle of charge +q and
mass m is projected with velocity v 0 from the surface of spherical volume towards its centre. The
R
minimum value of v0 such that it just reaches at a distance from the centre of spherical volume
2
3Qq
is . Find the value of N. (There is no other resistance force on charged particle except
Nm 0R
electric force)
SECTION – A
31. Which of the following graphs represents the relation between inter atomic potential energy V(r)
and inter atomic distance r for ideal gas?
(A)
V(r)
0
r
(B)
V(r)
0
r
(C)
V(r)
0
r
(D)
V(r)
0
r
32. In which of the following molecules, the shortest O – O bond length can be expected?
(A) O3
(B) O2
(C) O2F2
(D) KO2
33. The graph of ionization enthalpies for elements with atomic number 3 to 10 is best shown as
(A)
-1
H/kJ mol
Atomic number (Z)

(B)
-1
H/kJ mol
Atomic number (Z)
(C)
-1
H/kJ mol
Atomic number (Z)

(D)
-1
H/kJ mol
Atomic number (Z)
34. Considering the graph, which of the following gases has the highest critical temperature TC?
Z
1.0 Gas B
Gas A
Gas C

1/ V m
(A) A
(B) B
(C) C
(D) All have identical TC
35. Which of the following alkali metal is not miscible with other alkali metals in their molten phase?
(A) Li
(B) K
(C) Rb
(D) Cs
36. Which of the following is correct reason behind greater volatility of reaction between potassium
with water compare to that of lithium?
(A) K has greater reducing nature than Li
(B) K has lower reducing nature than Li
(C) K has high melting point than Li
(D) K has low melting point than Li
37. One mole of an ideal mono-atomic gas is carried around the cycle as shown in the figure below.
Find the amount of heat added in the process A to B is
 3R 
 Given : C V  
 2 
atic
P diab
A
A C
V
(Given: TA = 300 K, TB = 600 K, TC = 455 K)
(A) 3742 J
(B) 3742 J
(C) 2812 J
(D) 3228 J
38. Which of the following statement is not correct?

(A) With increase in temperature, the fraction of molecules having energy lower than
activation energy decreases.
(B) With increase in temperature, the collision frequency of reactant molecules increases.
(C) With decrease in temperature, the pre-exponential factor in collision theory increases.
(D) Rate constant can be less than pre-exponential factor in Arrhenius equation.
39. Find the incorrect statement.

(A) The concentration of oxygen in air is greater than the concentration of oxygen in Lake’s
water.
(B) In cold winter season, thick ice forms on the surface of water in Lake; this leads to
restriction on light entering into Lake and hence photosynthesis of plants under water
stops. This consequently leads to increase in concentration of oxygen in the water
(C) The irritant red haze in the traffic and congested places is due to oxides of nitrogen
(D) Carbon dioxide gas is confined to troposphere only
40. The addition of NaH2PO4 to 0.1 M H3PO 4 will cause

(A) no change in pH value
(B) increase in its pH value
(C) decrease in its pH value
(D) change in pH but cannot be predicted
41. If experimentally, it has been found that there are two types of C – C bond length in cyclobuta-
1,3-diene. Based on this, the compound will be
(A) aromatic
(B) anti-aromatic
(C) non-aromatic
(D) can not predict
42. The total number of paramagnetic compounds in the following group is

Na3 CoF6 ,Na2O2 ,CsO2 ,K 3 Co  CN6  ,  V H2O 6  FeF6 2 ,K 3 Fe H2O 6  ,Ni  CO  4
3
(A) 4
(B) 5
(C) 3
(D) 6
43. In Ellingham diagram, where we plot Go for the formation of oxides of various metal with
respect to temperature. Which of the following statement (s) is/are correct?
I. A metal with higher slope of curve gets always oxidized.
II. A metal with lower slope of curve never get reduced at any temperature.
III. The slope of the curve for some metal changes after particular temperature because of
phase change of metal.
IV. If two metals have same slopes, the one which has greater y-intercept usually get
oxidized by the other one.
V. If two metals have same slopes, the one which has greater y-intercept usually get
reduced by the other one.
(A) II, III and V
(B) III and V
(C) All are wrong
(D) III, IV and V
44. In the series Sc (Z = 21) to Zn (Z = 30), the enthalpy of atomization is lowest for which metal?
(A) Sc
(B) Mn
(C) Cu
(D) Zn
45. How many P = O bonds are present in Orthophosphoric acid?

(A) 1
(B) 2
(C) 0
(D) 3
46. In the given reaction, the wrongly matched product is

18
O
||
H O

3

CH3  CH2  C  O  CH3 
 A  B
 Acid  Alcohol
(A) 18
O
||
A  CH3  CH2  C  O  H
(B)
O
||
A  CH3  CH2  C  O H
18
(C)
18
B  CH3  O  H
(D) B  CH3  O  H
47. H
D
NH2
H3C NaOH, Br2
 Product;
O
The possible product is:
(A) D
H
H2N CH3
(B) D
H
H3C NH2
(C) D
H3C NH2
H
(D) NH2
D CH3
H
48. Clemmensen’s reduction (unbalanced reaction)

O
||
CH3  C  CH3  Zn  HCl  CH3  CH2  CH3  ZnCl2  H2O
Find the stoichiometric coefficient of zinc in the balanced Clemmensen’s reduction reaction if
stoichiometric coefficient of acetone is 2.
(A) 4
(B) 2
(C) 8
(D) 6
49. Which of the following compound can produce chiral compound upon treatment with CH3MgCl
and then acidification?
(A) Formaldehyde
(B) Pentanone
(C) 2-hexanone
(D) 3-hexanone
50. Which of the following compound is chiral?

(A) CH3  CH  CH  CHCl  CH  CH  CH3
 cis  R  cis 
(B) CH3  CH  CH  CHCl  CH  CH  CH3
 cis  S  trans 
(C) CH3  CH  CH  CHCl  CH  CH  CH3

 trans  S  trans 
(D) CH3
H Cl
Cl H
CH3
SECTION – B
51. The mass of glucose (in gm) which is present in 500 gm of 0.1 m aq. Glucose solution is?
52. Calculate the wavelength (in nm) of light emitted in the transition of electron in between two
energy levels of Li2  ion whose sum is equal to the degeneracy of first excited state of H-atom
and the difference is equal to number of waves possible in second orbit of H-atom
RH  109,688 cm1 
53. A natural gas may be assumed to be a mixture of methane and ethane only. On complete
combustion of 20 L of gas at STP, the heat evolved was 800 kJ.
o
 combHCH4
 g  894 kJ mol1
 combHCo 2H6  g   1500 kJ mol1
Calculate the percentage composition of methane by volume.
54. Treating 12.8 g of calcium carbide with water produces compound ‘A’ with 50% yield. ‘A’ on
passing through red hot iron tube at 873 K gives compound B. Compound B upon sulphonation
and then treating with NaOH produces C. C can be molecule or ion. Find the mass of C formed
(in gm).
55. 1 mole of But-2-yne upon reaction with Lindlar’s catalyst produces compound X. Find the mass
(in gm) of any one of the products for the reaction in which bromination of ‘X’ has happened in
presence of CCl4 . (Atomic mass Br = 80)
56. Twice the amount of a solute is dissolved in solvent A than in the same amount of solvent B. The
elevation in boiling point for solution A is twice the elevation in boiling point for solution B. Find
the ratio of boiling point elevation constants for solvent A to B, respectively
57. The total number of tetrahedral voids that will be unoccupied and which constitute 422.63 gm of
ZnS (Zinc blende) is xNA ( NA is Avogadro number). Find the value of x? (Atomic mass of
Zn = 65)
 Zn2 
58. A graph is plotted between log  2   Y  axis  and Ecell  x  axis  . The curve is linear with
Cu 
 
intercept on y-axis equal to 37.28. Calculate Ecell for the cell
Zn  s  | Zn2   0.1 M || Cu2  0.01 M | Cu
59. A solution containing equimolar mixture of lead acetate and silver nitrate is titrated with H2 S
solution. And, then the solution is boiled with hot water. After filtration, the weight of precipitate
was 6.2 gm. Assuming the yield of the experiment to be 100%, find the mass of lead acetate that
was present in the initial mixture (in gm). [Given: Atomic mass, Pb = 207.3, Ag = 108, S = 32].
60. A 100 mL of 0.1 M metallic-copper colloidal solution is titrated with sufficient amount of dilute
nitric acid. Find the mass (in gm) of the oxide of nitrogen which has been formed.
SECTION – A
–1 –1
61. Let A and B are two non-singular matrices of order 3 such that A  B  2 I and A +B = 3I ,
then AB is equal to (where I is the identity matrix of order 3)
(A) 2I
2I
(B)
3
(C) A
(D) B
a sin x  bx  cx 2  x 3
62. If lim exists and finite, then which of the following is not correct?
x 0 2x 2 ln 1  x   2x 3  x 4
(A) a=6
(B) a=b
(C) c=2
(D) c=0
5 2016  2015
63. If A    , then the value of A  5A 2014 is
 1 403 
(A) 1
(B) –1
(C) 5
(D) –2016
  
   ab
64. If a and b are two non-collinear unit vectors such that a  b  , then the value of
2
   2
a   a  b  is
3
(A)
4
2
(B)
3
1
(C)
2
1
(D)
4

1
 2x 24  3x16  6x8  
65.  x
24
 x16  x 8   2x16  3x 8  6  8 dx =
c

(where ,  are co-prime natural numbers and c be constant of integration), then the value of  +
 +  is
(A) 61
(B) 51
(C) 71
(D) 91
66. PQR is a triangular park with PQ = PR = 200 m. A tower stands at the mid-points of QR. If the
angles of elevation of the top of the tower at P, Q and R are respectively 45, 30 and 30, then
the height of the tower (in m) is
(A) 100
(B) 200
(C) 150
(D) 125
67. Let L1 : x = y = z and L2 : x – 1 = y – 2 = z – 3 be two lines. The foot of perpendicular drawn from
the origin O(0, 0, 0) on L1 to L2 is A. If the equation of a plane containing the line L1 and
perpendicular to OA is 10x + by + cz = d, then the value of b + c + d is
(A) 12
(B) –12
(C) 10
(D) –10
 4x  1  2  3x   2 dy  k
68. If y  tan1  2   tan   where x   0,  . If  2
, then is
 5x  1   3  2x   3 dx 1  kx 10
(where  and k are natural numbers)
(A) 5
(B) 3
(C) 2
(D) 6
69. Let R = {(a, b) : a2 + b2 = 4, a, b  R}, then relation R is

(A) symmetric
(B) transitive
(C) reflexive
(D) anti-symmetric
70. The contrapositive of the conditional “If Ram works hard, then he gets a first class” is
(A) if Ram does not work hard, then he does not get a first class
(B) if Ram does not get a first class, then he works hard
(C) if Ram does not get a first class, then he does not work hard
(D) if Ram get a first class, then he does not work hard
71. Number of complex numbers satisfying the relation z  z  z  z  2 and z  i  z  i  2 , is

(A) 1
(B) 2
(C) 3
(D) 4
72. The coefficient of x 13 in the expansion of (1 – x)5(1 + x + x2 + x3)4 is

(A) 24
(B) 12
(C) 6
(D) 4
1
73. If 4cos36  cot 7   n1  n2  n3  n4  n5  n6 (where n1, n2, n3, n4, n5, n6 are natural
2
6
2
numbers), then the value of  n i 
i 1
(A) 19
(B) 91
(C) 81
(D) 101

1  3n2  3n  1 
74. The value of  tan  6 5 4 3  is
 n  3n  3n  n  1 
n 1

(A)
2

(B)
3

(C)
4

(D)
6
75. If a variable takes the values 0, 1, 2, ….., n with frequencies 1, nC1, n C2 , ....., nCn , then the
Arithmetic Mean is
2n
(A)
n
n
(B)
2
(C) n+1
(D) n
76. If f() = |cos  + 1| + |cos  – 2| + |cos  – 1| + |cos  – 3|, where 0    2, then the product of
maximum and minimum values of x is
(A) 45
(B) 30
(C) 27
(D) 36
77. The real values of  such that (2 – 4 + 3)x2 + (2 – 5 + 6)x + (2 – 9) = 0 has more than two
roots is
(A) 2
(B) 1
(C) 0
(D) 3
1 1 5x  12y  7xy
78. If 2
 2
 1 , then the maximum value of is
x y xy
(A) 7
(B) 13
(C) 15
(D) 20
360
 1  p
79. If  n   (where p ad q relatively prime integers), then |p – q| is
n  1   n  1 n  q
n 1 
(A) 0
(B) 1
(C) 2
(D) 3
80. If f 1  x   x3  3x  4 , then the value of |36f(0)| is

(A) 2
(B) 3
(C) 1
(D) 0
SECTION – B
81. Let f(1) + g(1) = 9e ; f(x) = –x2g(x) ; g(x) = –x2 f(x). If

4
 f  x  g x   k
1
  x 2  dx  k e  e 4 , then 2 is 
1
y   ye2x
82. If y = a cos(ex) + b sin (ex), then is
y
x2 y2 x 2 y2
83. In the coordinate plane, ellipse C1 :   1 (a1 0, b1 > 0 and hyperbola C 2 :  1
a12 b12 a22 b22
(a2, b2 > 0) has the same focus points F1, F2. Point P is one of the intersection points of C1 and C2
and PF1 is perpendicular to PF2. If e1 is the eccentricity of C1 and e2 is the eccentricity of C2. Then
minimum value of 9e12  e22 is
84. If x1, x2, x3, x4 and x5 be 5 positive numbers such that x1 + 2x2 + 3x3 + 4x4 + 5x5 = 15 and
x  x 2  x3  x 4  x5
x1  x 22  x 33  x 44  x55  1 , then 1 is
2
85. If tangent drawn to the parabola y2 = –ax (a > 0) from a point A(1, 0) which also touches the
x2 y 2
hyperbola   1 at B such that ASB = 90, where S is the focus of the hyperbola, then the
4 b2
value of a + b2 is
86. Let E1, E2, E3 be three independent events associated with a random experiment such that
3P E1  E 2  E3   P  E1  E2  E3  = 9P E1  E2  E3   3  3P  E1  E 2  E3  ,
where P(E1), P(E2), P(E3)  1 and P(A) denotes probability of event A. If absolute value of
P  E1  P E 2  P  E3 
a ab
P  E2  P E3  P E1   , where a, b  N, then the least value of   is
b  10 
P  E3  P  E1  P  E2 
87. A number x is selected from the set of first 9 natural numbers (i.e., x = 1, 2, 3, ......, 9). If the
2 m
probability that f(f(x)) = x where f(x) = x – 3x + 3 is , then m is equal to
9
4 3 2
88. If , , ,  be four roots of the equation x – 10x + 37x – 60x + 32 = 0.
1 1 1 1 p
If 2
 2  2  2  , where p and q are co-prime
  5  10   5  10   5   10   5  10 q
numbers, then p + q is
3
89. A straight line L with the slope touches a circle whose radius is 5 units and centre lies on the
4
a
x-axis. If the length of this tangents from a point on the x-axis is where a, b  N, then the least
b
ab
values of is
10
10
90. The coefficient of x 8 in the expansion of  2  9x 3  6x 4  x 5  is 5  2p  3q , where p, q  N,
pq
then is
5
FIITJEE
FULL TEST – VI
JEE (Main)-2022
TEST DATE: 13-02-2022

Physics PART – A
SECTION – A
1. A
Sol. The pendulum would strike the xy plane
When the string is cut z = h = 5m and v = 4 m/s parallel to the y-axis
1
The time taken by the bob to hit the xy plane is 5   10  t 2
2
 t = 1 sec
During this time it covers a distance 4 m along the y-direction. The point where it hits the xy plane
along the x-axis is 1 m because the radius is 1m. Hence the bob hits the xy plane at (1m, 4m)
2. D
0 1 2
Sol. R  x  2 x 
A  
x
Also, R = 
A
Taking differentiation of (1) and (2), we get
 
dR  0 (dx  x dx) and dR   dx
A A
 
 0 (dx  xdx)  dx
A A
  = 0(1+ x)
3. B
AITS-FT-VI-PCM(Sol.)-JEE(Main)/22 2
Sol. At any instant of time the rod makes an angle  with horizontal, the x
and y coordinates of centre of rod are B
x =  cos y =  sin
 x2 + y2 = 2 C
Hence, the centre C moves along a circle of radius with centre at O. x
y
 velocity vector of C is always directed along the tangent drawn 
at C to the circle of radius  whose centre lies at O.
A
4. B
Sol. P = VI
For secondary :
P 500
V2  2   40 volts
I1 12.5
For an ideal transformer (100% efficient)
Pinput = Poutput
 V 1I 1 = V 2I 2
VI 40(12.5)  n1 V 5 V 
 I1  2 2   2.5 A   1   1
V1 40  5  n2 V2 1 40 
5. D
Sol. Let the value of 'a' be increased from zero. As long as a  ug, there shall be no relative motion
between m1 or m2 and platform, that is m1 and m2 shall move with acceleration a. As a > g the
acceleration of m1 and m2 shall become ug each.
Hence at all instants the velocity of m 1 and m2 shall be same
 The spring shall always remain in natural length.
6. C
Sol. At any time
Fthrust  Ffriction  ma
av 2  mg  ma
a
a(2gh)  (Ah)g  (Ah)a
A
a
2agh  agh  Aha ; g  a
A
7. C
Sol. Torque about A a/2
a a B
mg  I
2 A
a/23
mga
 
2I a a
a mga2 a/3 mg
 acceleration 
3 2 3I
C
3 AITS-FT-VI-PCM(Sol.)-JEE(Main)/22
8. B
Sol. Since spherical shell b is earthed therefore potential will be zero.
KQ KQ
i.e.,   0  Q   Q
b b
where Q is total charge inside A and Q is charge on sphericla shell B
Therefore field outside B will be zero.
And electric field inside A will be
KQ
E  3 r (linearly increasing)
a
Between spherical shell A and B
KQ
E 2
r
9. D
Sol. Let x be the distance of axis of rotation from the top of v1 = 30 cm/s
sphere A (downward).
Since angular velocity of the top and bottom point of x
sphere A will be same, therefore, A
30 10
 
x (2R  x)
30 10

x (20  x) v2 = 10 cm/s
 x = 15
 Distance from ground
= 2R + (2R  x) = 20 + 5 = 25 cm
10. C
Sol. f1 = f2
1 < 2
c = f
c1 < c2
T
c

1  2
11. C
Sol. At the surface of current carrying wire,
1
B  0 jr
2
B
j
r
As slope of wire P > slope of wire Q
12. D
2 1 2  1
Sol.  
v u R
1 1.5 1  1.5
 
v ( u) R
For v to be positive
1 3
  0  u  3R
2R 2u
13. A
Sol. Nb reaches maximum when activity of A will be equal to activity of B.
 N
i.e., aNa  bNb  Nb  a a
b
14. B
Sol. From COE
2
1 2 1  3K  1
Kx 0  m  x 0   Kx 2
2 
2  m  2

1 2 3 2 1 2
Kx0  Kx0  Kx ; 4x 20  x 2
2 2 2
x = 2x0 (Amplitude)
 K 
Equation y  2x 0 sin  t 
 m 6
 
Satisfies condition given in the question.
15. B
Sol. e = Bv
de d
  Bv at any instant of time ‘t’
dt dt
d
 Bv (x 2  y 2 where x = OQ and y = OP
dt
 dx dy   dx dy 
 2x dt  2y dt   x dt  y dt 
 Bv    Bv  
2 2 2 2
2 x y x y
 dx x dy y 
= Bv   
 dt x  y
2 2 dt x  y 2
2 
 
 dx dy 
= Bv  cos   sin  
 dt dt 
dx dy
= Bv(v cos  cos  + v sin  sin ) [  v cos  = , v sin  = ]
dt dt
= Bv2 (cos2  + sin2) = Bv2
16. B
Power(watt)  Emission%
Sol. no. of photoelectron emitted per second, n 
Energy of 1 photon (in J)  100
1.5  10 3  0.1 0.48 1240 nm eV
   10 6 (energy of 1 photon =  e joule )
1240(nm)(eV) e 400 nm
 e  100
400(nm)
 Photo current = ne = 0.48 A
17. B
Sol. Magnitude of force on AB (F1) and magnitude of C
force on CD (F2) will be equal in magnitude and
opposite in direction.
   B
Hence, F1  F2  0 . Resultant of F3  F4 will be
away from the long straight wire. I
v1 v2
18. A
Sol. mv0 + 0 = mv1 + (2mv2)
v 0 = v1 + 2v2 …(i)
v  v1
e 2 1
v 0
v 2  v1   v 0 …(ii)
From (i) and (ii)
2v v
v 2   0 ; v1  0
3 3
Total dis tance 2R
T 
Velocity of separation v0
2 4
 Angle rotated by A  radian and angle rotated by B  radian.
3 3
19. A
Sol. Velocity of image of particle B
 ˆ  4( î)  î
v  5(i)
B
Velocity of image of particle A
v A  10( î)  4(î)  10ˆj   14(i)
ˆ  10ˆj 
 
Relative velocity of image
  
vBA  vB  v A  î   14(i) ˆ  10ˆj   15iˆ  10ˆj
 

v BA  325 cm/sec
20. D
Sol. We know that P will be the central maxima (at
which path difference is zero)
d d d
OP    2d/3
2 3 6 d P
d/2 y = (d/2d/3)
d/3 O
SECTION – B
21. 00000.40
1
Sol. Error in measuring 50 sec =  0.2 sec
5
0.2
% error =  100  0.4 %
50
22. 00000.00
Sol. In reverse biased diode offers infinite resistance
23. 00002.00
 8 
Sol. L.C   1    0.2 mm  2 cm
 10 
24. 00004.00
B
Sol. tan   V
BH
25. 00000.21
E
Sol. B0  0
C
26. 00003.00
q2
Sol.  Ta
a2
1/3
 q2 
a  k 
 T
 
27. 00003.00
Sol. N=3

W  PdV  nRkVdV
 …(i)
2
T = kV  dT = 2kVdV …(ii)
From (i) and (ii)
4T0
dT nR 3
W  nRk
2k

2  dT  2 nRT
T0
0
28. 00000.00
Sol. No change in flux.
29. 00003.00
T
 idt
0
Sol. Average value in one time period = T
3
 dt
0
30. 00016.00
kQ
Sol. At surface V 
R
kQ
at r < R, V  3
(3R2  r 2 )
2R
for r = R/2
11 kQ
V
8 R
1  11 kQ kQ 
 mv 20  q  
2  8R R 
SECTION – A
31. B
Sol. Ideal gaseous particles have no inter atomic interactions, so, zero potential energy.
32. C
Sol. O2F2  O22 Bond order  3
KO2  O2 Bond order  1.5
O3 Bond order  1.5
O2 Bond order  2
Higher bond order means lower bond length.
33. C
Sol. Ionization enthalpies is in the order : Li < B < Be < C < O < N < F < Ne.
34. C
8a  a  1
Sol. TC   TC  a , and Z  1   
27Rb  RT  Vm
35. A
Sol. Lithium is not miscible with other alkali metals.
36. D
Sol. Beacause K has lower melting than Li, it melts easily and provide greater surface area during
reaction with water.
37. A
 3R 
Sol. W  0, U  q  nCV T  q  C V  
 2 
38. C
Sol. The pre-exponential factor does not increase with decrease in temperature.
39. B
Sol. Due to restriction on light and stopping of photosynthesis, plants start using oxygen which
consequently decreases the oxygen inside the water.
40. B
+
Sol. Increasing the concentrtion of conjugate base (or salt) decrease the H concentration, thus
increases pH.
41. C
Sol. If two types of C – C bond length; it means there is no conjugation in this
compound.
42. A
Sol. Paramagnetic compound :
Na3 CoF6 ,CsO2 ,  V H2O 6  FeF6 2 ,K 3 Fe H2 O  6 
3
43. B
Sol. The slope change in the Ellingham diagram is due to phase change of metal. And, the higher
values of Go generally show its inability to form oxide.
44. D
Sol. Zn has a less enthalpy of atomization because of low inter-atomic attraction.
45. A
Sol. O
H O P O H
O
H
46. C
Sol. During the given de-esterification reaction, the C – O bond of alcohol (here it is methanol) does
not break. So, oxygen will remain O16 isotope.
47. A
Sol. H O H
H3C C 
 H3C NH2
NH2
D D
The configuration around the chiral carbon remain same.
48. A
Sol. O
||
CH3  C  CH3  2Zn  4HCl  CH3  CH2  CH3  2ZnCl2  H2O
Balanced equation 
49. D
Sol. O O H
||
 i CH3MgCl
CH3  CH2  C  CH2  CH2  CH3 
ii H O, H
 H3C CH2 C CH2 CH2 CH3
2
CH3
50. B
Sol. In the given Newmann projection, after the rotating the group of atoms around C2  C3 bond, it
will have plane of symmetry; so, it is not chiral.
SECTION – B
51. 00008.84
Sol. Let the mass be x gm
x 1000
  0.1
180  500  x 
x  8.84
52. 00011.40
Sol. Let the transition occurs between n1 and n2, (n2 > n1)
Number of waves in 2nd orbit of H-atom = 2
st
Degeneracy of 1 excited state of H-atom = 4
n1  n2  4
n2  n1  2
n1  1, n2  3
Find 
53. 00099.65
Sol. Let CH4  x lit, then C2H6   20  x  L
800 
x
 894 
 20  x   1500
22.4 22.4
x  19.93
54. 00003.10
Sol. 50%
CaC2  2H2 O   Ca  OH2  C2H2
 0.2 mole  0.1 mole 
Re d hot iron
3C2H2 
873 K

 0.1 mole 
 0.1 
 mole 
 3 
SO 3H O
Oleum NaOH
  
 0.1 
 mole 
 3 
 0.1 
Required mass    93  gm  3.1
 3 
55. 00108.00
Sol. H3C CH3
H3C C C CH3 
Lindlar 's catalyst
C C
H H
cis
CH3 CH3
H3C CH3 H Br Br H
Br2
C C 
CCl4
 
Br H H Br
H H
CH3 CH3
50% 50%
56. 00001.00
Sol.  Tb A  K b  A   m
 Tb B  K b  B   m
 m  2m
And,  Tb  A  2  Tb B
Kb  A 
Hence, 1
K b B 
57. 00004.36
Sol. 422.63 gm of ZnS means 4.36 moles of ZnS.
There are 4 moles of ZnS in each mole of unit cell (in Zinc blende structure). Each unit cell also
contain 4 unoccupied tetrahedral voids.
58. 00001.07
0.059 Zn2 
Sol. Ecell  o
E cell
 log  2 
2 Cu 
 
2
 Zn  2Eo 2E
 log  2    
Cu  0.059 0.059
 
  y  C  mx 
2E
 1  37.28 
0.059
 E  1.07
59. 00008.13
Sol. Passing through H2 S solution produces PbS and Ag2 S as precipitates, but PbS gets dissolved
upon heating. Hence, only Ag2S will remain as precipitate.
0.1
6.2 of Ag2S  moles of Ag2S
4
0.1
 mole of PbS
4
60. 00000.20
Sol. 3Cu  8HNO3  3Cu NO3 2  2NO  4H2 O
 dilute 
SECTION – A
61. B
Sol. A B  2I ….. (1)
A–1 + B–1 = 3 I ….. (2)
Multiplying by matrix A in equation (2)
–1 –1 –1
AA + AB = 3A I  I + AB = 3A
Now multiplying by matrix B
I B + AB–1B = 3AB  B + A = 3AB
2I
 2 I = 3AB  AB 
3
62. C
 x3 x5 
 a  b  x  cx2   1  a  x 3  a x5  .....
ax    .....   bx  cx 2  x 3
Sol. lim  3! 5!  = lim  3!  5!
2 3 5 6
x 0  x x  x  0 2x 2x
2x 2  x    .....   2x 3  x 4   .....
 2 3  3 4
a
Limit is finite, if c = 0, a – b = 0, 1   0
3!
63. D
2014 0 2016
Sol. A 2015  5A 2014 = A 2014  A  5I = A 2014 A  5I =  1  2016
1 398
64. A
 
  2 2 1 2 2  
Sol. ab 
ab
 a b sin2   
a  b  2 a  b 
2 4
1 1
 sin2    2  2cos    2sin2   1  cos   cos   
4 2
   2 2  2 2 2 3
a   a  b   a a  b  a b sin2  
4
65. C
1
1 
Sol. I 48x 23  48x15  48x 7  2x 24  3x16  6x 8  8 dx
48 
Let 2x24 + 3x16 + 6x8 = y
1 9
1 1 8
I   y  8 dy    y  8  c
48 48 9
9
1
I  y 8  c
54
66. A
Sol. Let height of tower MN is h P
MN
In QMN, tan30 
QM
200 45º 200
1 h
 
3 QM N
 QM  3 h 30º 30º
Q M R
In MNP, MN = PM
2
In PMQ, MP   200    3 h 
2
 h  40000  3h2  h2 + 3h2 = 40000
 4h2 = 40000  h2 = 10000  h = 100 meters
67. D
Sol. OA is perpendicular to line L2 = 0 O(0, 0, 0)
1( + 1) + 1( + 2) + 1( + 3) = 0 x=y=z
  = –2
A
= (–1, 0, 1)
OA  î  kˆ
 x–1=y–2=z–3
 A normal vector to required plane is OA
A( + 1, + 2,  + 3)
Equation of required plane is –1(x – 0) + 1(z – 0) = 0
 –x + z = 0  –10x + 10z = 0  10x – 10z = 0
b = 0, c = –10, d = 0
68. B
 2 
 x 
 5x  x  3 =  tan1  5x   tan1  x     tan1  x   tan1  2  
Sol. y  tan1  1
  tan     

 1  5x x   1  2x    3 
 3 
5
y 
1  25x 2
69. A
Sol. (a, b) and (b, a) lie on circle
70. C
Sol. Ram does not get a first class, then he does not work hard
71. B
Sol. z = i or –i
72. D
Sol. (1 – x)5(1 + x)4(1 + x2)4 = (1 – x)(1 – x4)4
Coefficient of x13 = (–1)(–4) = 4
73. B
 5  1
Sol. 4cos 36  4   5 1
 4 
 3  1
1  

 1  1  cos 15   2 2  =
cot  7     6 3 2 4
 2  sin15 3 1
2 2
6
2 1
 n i   12  22  32  42  52  62 =  6  7  13  91
i 1 6
74. A
 n3   n  13 
Sol. Tn  tan1  3

3
1  n  n  1 
–1 3 –1 3
Tn = tan (n ) – tan ((n – 1) )
75. B
n 1
0.1  1 nC1  2  n C2  .....  n  nCn n   2 n
Sol. Arithmetic Mean = = 
1  nC1  nC2  .....  n Cn 2n 2
76. A
Sol. f() = (cos  + 1) – (cos  – 1) – (cos  – 2) – (cos  – 3) = 7 – 2 cos 
f()max = 9 ; f()min = 5
77. D
Sol. 2 – 4 + 3 = 0   = 1, 3
2 – 5 + 6 = 0   = 2, 3
2 – 9 = 0   = 3 ;  = 3
78. D
Sol. x = sec  ; y = cosec 
5x  12y  7xy 5 12
    7 = 5 sin  + 12 cos  + 7
xy y x
79. B
360 360
p 360  1  n 1  n  1 1 
Sol. 
q n1  n n  1  n  n  1 
=   
n n  1  n  1  n  n1  n
 
n 1
n 1
 1   1 1   1 1  1 18
= 1      ....     = 1  19  19
 2   2 3   360 360 
 |p – q| = 1
80. C
Sol. Let g(x) = f 1  x   x3  3x  4
1
 f(g(x)) = x  f   g  x   
g  x 
g 1 6 1
f   g 1    3
 f   0    3

 g 1   6  36
 36f   0   1
SECTION – B
81. 00004.50
4
 x 2  f   x   g  x   4
Sol. I 2
dx =   f  x   g  x  1    f  4   g  4   9e 
1 x
Now, f(x) + g(x) = –x2(f(x) + g((x))
f   x   g  x  1
  dx    x 2 dx   c
 
f x g x   x
1
 f(x) + g(x) = ae x  a = 9
 1
 
I   9e 4  9e  9 e  e 4
1

82. 00001.00
Sol. 
y   a sin  e x   b cos  e x  e x 
y   a cos  e x   b sin  e  e
x x
 
 ex  a sin  e x   b cos  e x  e x = ye2x  y
y   ye2x
 1
y
83. 00008.00
Sol. a1e1 = a2e2
PF12  PF22  4a12e12
PF1  PF2  2a1
PF1  PF2  2a2
2 2
PF1  PF2    PF1  PF2   4  a12  a22 
 2 PF12  PF22   4  a12  a22   4a12 e12  2  a12  a22 
2 2
a  e  1 1
 2e12  1   2   2e12  1   1   2  2  2
 a1   e2  e1 e2
1 1
Let  2 cos  ;  2 sin 
e1 e2
9 1
E  9e12  e22  sec 2   cosec 2 
2 2
1 1
E 10  9 tan2   cot 2   ; Emin  10  6   8
2 2
84. 00002.50
1
x1  2x 2  3x 3  4x 4  5x 5
Sol.   x1  x 22  x 33  x 44  x 55 15
15
 x1 = x2 = x3 = x4 = x5 = 1
85. 00028.00
a y
Sol. Tangent to parabola is y  mx  (1, 0) B
4m
a 2
O m  a = 4m
4m x
S
(1, 0) lies on the directrix of the hyperbola
A(1, 0)
2
1  e = 2
e
2
4  b2  2  2  b = 12
Tangent to hyperbola y  mx  4m2  b2
2 2 2 2 2 2
 (–m) = 4m – b  3m = b = 12  m = 4
2 2
a + b = 4m + 12 = 28
86. 00004.10
Sol. Let P(E1) = x ; P(E2) = y ; P(E3) = z
 3x(1 – y)(1 – z) = (1 – x)y(1 – z) = 9(1 – x)(1 – y)z = 3(1 – x)(1 – y)(1 – z)
3x y 9z 1 3 1
   3  x ; y ; z
1 x 1 y 1 z 2 4 4
1 3 1
2 4 4 2 3 1
3 1 1 1 9
 3 1 2 
4 4 2 64 32
1 2 3
1 1 3
4 2 4
87. 00002.00
Sol. Clearly all the solutions of f(x) = x are also solutions of f(f(x)) = x. First, we solve f(x) = x, f(x) = 0
 x2 – 3x + 3 = x  x2 – 4x + 3 = 0  (x – 1)(x – 3) = 0  x = 1, 3
Therefore x = 1, 3 are also solutions of f(f(x)) = x. We want to seek if there are any more solutions
of f(f(x)) = x other than 1 and 3.
2 2 2 2
f(f(x)) = x  f(x – 3x + 3) = x  (x – 3x + 3) – 3(x – 3x + 3) + 3 = 0
4 3 2 2 2
 x – 6x + 12x – 9x + 3 = 0  (x – 4x + 3)(x – 2x + 1) = 0
 (x – 1)(x – 3)(x – 1)2 = y  x = 1, 3
In this case we have no additional solutions. Therefore the probability that x satisfies equation
2
f(f(x)) = x is , therefore m = 2
9
88. 00007.00
Sol. (x2 – 5x + 10)(x2 – 5x + 2) + 12 = 0
 (x2 – 5x + 10)(x2 – 5x + 10 – 8) + 12 = 0
 (x2 – 5x + 10)2 – 8(x2 – 5x + 10) + 12 = 0
x2 – 5x + 10 = 2, 6
1 1 1 1 4
Required sum =    
2 2 6 6 3
89. 00002.30
3 y
0C 3
4 A y= xC
Sol. 5 4
2
 3   2
   1
4 B
x
 3  4C  4 C(, 0)
    5
 4  5
3  4C 25
 
3 3
2 2 2
 4C   3  4C   25  20
AB       25 =    25 =    25 
 3   3   3  3
90. 00002.80
10
Sol.  2  x 3  3  x 2 

10 10  r 2r
Cr   2   x 3r  3  x 

2r
Ck  32r k  xk
3r + k = 8  r = k = 2
 Coefficient of x8 = 10C2·28·4C2·32 = 5·29·35
FIITJEE
FULL TEST – VII
JEE (Main)-2022
TEST DATE: 27-02-2022
answer.
AITS-FT-VII-PCM-JEE(Main)/22 2
Physics PART – A
SECTION – A
1. If energy stored in the capacitor C1 and C2 are same, then the C2

2R
C
value of 2 is
C1
25 R
(A) C1
36
36
(B) E
25
4
(C)
9 E
5
(D)
4
2. In the given circuit, find I2  I1 I1 2

(A) zero
1
(B) A
13
2 10V 3 6V
(C) A
13
34 4 I2
(D) A
13
3. A particle-1 of mass m, kinetic energy K and momentum P collides head on with another
particle-2 of mass 2m at rest on horizontal smooth surface. If collision is elastic, find ratio of
kinetic energy of particle -2 and particle-1 after collision.
(A) zero
(B) 1
(C) 1/8
(D) 8
4. Two blocks of mass m and 2m are connected by a spring of spring constant k. The system is
placed on a horizontal frictionless surface. Now at t = 0, the block 2m is projected horizontally
with velocity v0 towards right. What is the minimum time when the elongation in spring is
maximum?
 2m
(A)
4 3k
 2m
(B)
2 3k
3 2m
(C)
4 3k
2m
(D) 
3k
3 AITS-FT-VII-PCM-JEE(Main)/22
5. In the AC circuit drawn below find the phase difference I1 xC

between current I1 and I2.
  X  XC  xL R
(A)  tan1  L  I2
2  R 
  X  XC 
(B)  tan1  L  ~
2  R  AC source
 X 
(C)  tan1  L 
2  R 
 X 
(D)  tan1  L 
2 R 
6. Plates of capacitor have charges 2CV and CV initially. Find the 2CV CV
charge flowing through capacitor of capacitance 2C long time
after switch is closed.
(A) zero
CV
(B)
2 2C
S
(C) CV
3CV
(D)
2
V R
7. In the figure drawn below, if pulleys are massless and frictionless. String is
inextensible then find the time period of oscillation.
k
9m
(A) 2
16k
3m
(B) 2
4k
9m
(C) 
16k
3m
(D) 2k
4k
8. A hydrogen atom is in an excited state of principal quantum number n. When it returns to the
ground state, it emits a photon of wavelength 0. If R is Rydberg constant, then the value of n is
R0  1
(A)
R 0
R0  1
(B)
R0
R 0
(C)
R0  1
R0
(D)
R0  1
9. Two particles are projected horizontally and simultaneously from top of a tower in mutually
perpendicular directions with same speed 30 m/s. After how much time their velocity vectors will
be at angle 60 from each other (g = 10 m/s2)
(A) 1 sec
(B) 3 sec
(C) 4 sec
(D) 5 sec
10. An infinite current carrying wire, carrying current I is bent in V

z
shape, lying in y-z plane as shown in the figure. Find the
magnetic field at P, if OP = 2a.
 0I
(A) (2  3 )iˆ P
2a
 0I I 30 I
(B) (2  3)iˆ 30
2a
0I
(C) (2  3 )iˆ
4a
0I O y
(D) (2  3)iˆ
4a
11. A certain mass of a gas undergoes a process given by dW = 2dU. If the molar heat capacity of
gas for this process is 7.5R, then the gas is (where R is universal gas constant)
(A) Monoatomic gas
(B) Diatomic gas
(C) Polyatomic gas
(D) Insufficient data
12. A string is stretched between pulley and a wave generator consisting of a plate vibrating up and
down with small amplitude and frequency 120 Hz. The standing wave pattern has a 4 nodes as
shown. The load (in gm) is required for standing wave with 5 nodes is (Here m = 256 gm initially)
1.5 m
(A) 216
(B) 512
(C) 288
(D) 144
13. If a spring of stiffness k is cut into two parts A and B of length  A :  B  2 : 3 , then the stiffness of
spring B is given by
(A) k
2k
(B)
5
3k
(C)
5
5k
(D)
3
14. If the pin hole in the container is very small compared to the
area of the base of container and a block floats in the ideal
liquid then the speed of efflux is m
(A) less than 2gh
h
(B) greater than 2gh
(C) equal to 2gh
(D) equal to 2gH H
15. A uniform rod AB of mass 2kg and length 1m is placed on A B

a sharp support O such that AO = 0.4m and OB = 0.6 m.
A spring of force constant k = 600 N/m is attached to end
B. To keep the rod horizontal, its end A is tied to a thread O
k
such that spring is elongated by 1 cm. The reaction of
support on the rod when thread is burnt is
(A) 10 N
(B) 20 N
(C) 30 N
(D) 40 N

16. The electric field of two plane electromagnetic waves in vacuum are given by E  E0 cos( t  kx)jˆ
 
and E2  E0 cos( t  ky)kˆ . At t = 0, a particle of charge q is at origin with a velocity v  0.8cjˆ . The
instantaneous force experienced by the particle is
(A) qE (0.8iˆ  ˆj  0.2k)
0
ˆ
(B) qE0 ( 0.8iˆ  ˆj  0.2k)
ˆ
(C) qE (0.8iˆ  ˆj  0.2k)
0
ˆ
(D) qE0 ( 0.8iˆ  ˆj  0.2k)
ˆ
17. 25 W/m2 energy density of sunlight is normally incident on the surface of a solar panel. Some part
of incident energy 25% is reflected from the surface and the rest 75% is absorbed what is the
force exerted on 2 m 2 surface area of solar panel? (take c = 3  108 m/s)
(A) 10  108 N
(B) 20  108 N
(C) 25  108 N
(D) 35  108 N
18. In the given circuit, S is closed at t = 0. Find the power delivered by 9V C

th
 1
24 V battery, when potential energy stored in capacitor is   of S
4
its maximum value. 12V
(A) 31.5 W
(B) 94.5 W 4
(C) 126 W 24V
(D) 63 W
4
19. A beam of unpolarised light of intensity I0 is passed through a polaroid A and then through
another polaroid B which is oriented so that its principal plane makes an angle of 30 relative to
that of A. The intensity of the emergent light is:
I0
(A)
2
3I0
(B)
8
I0
(C)
8
(D) I0
20. The combination of gates shown below yields

(A) XOR gate
(B) NAND gate
(C) NOT gate
(D) OR gate
SECTION – B
21. In the circuit drawn below initially capacitor C is uncharged and I1 C R

1
switch ‘S’ is closed at t = 0. If C  F , L = 4H and R = 8, the
16 I2 L R
I
value of 2 at t = n2 sec will be
I1
S
E
22. A soap bubble of radius R, surface tension T exists in equilibrium in vacuum. A monoatomic gas
is trapped inside the soap bubble. Charge Q is given to bubble such that bubble expands from
radius a to radius 2a under adiabatic condition. If surface charge on surface is found to be
x0 T
. Find the value of x +y.
ya
23. Two complete turns of the circular scale of a screw gauge covers a distance of 1 mm on its main
scale. The number of divisions on the circular scale is 50. The screw gauge has a negative zero
error of 0.03 mm. If the main scale reading is 3mm and circular scale reading is 35 during the
measurement of diameter of wire, then find the diameter of wire in mm.
24. The output signal from an AM modulator is given as,

S(t) = 5 cos(1800 t) + 20 cos(2000t) + 5 cos(2200 t)
What is the modulation index of the modulation wave?
25. A parallel beam is incident on a thin t

lens (1 = 1.4) and radius of curvature 1 = 1.4
of each surface is 25 cm as shown in
the figure. Find the thickness of slab
in cm (2 = 1.5) between the lens and
screen so that final image is formed
on the screen if distance between
lens and the screen is 35 cm.
2 = 1.5
screen
35 cm
26. A particle is executing SHM on a straight line. A and B are two points at which velocity is zero. It
passes through a certain point P(PA < PB) with a speed of 3 2 m/s. It moves from A to P in time
0.5 sec and P to B in time 1.5 sec. Find the maximum speed in m/s.
27. A radioactive nuclei P decays simultaneously into two stable

nuclei Q and R with half life of 1 hour and 2 hour respectively as Q
k T1/2 = 1hour
shown in the figure. If the effective half life of P is hours,
9
then find the value of k. P
T1/2 = 2hour
R
28. Two identical containers A and B with frictionless pistons contains the same ideal gas at the
same temperature and the same volume V. The mass of the gas in A is m A and that in B is m B.
The gas in each cylinder is now allowed to expand isothermally to the final volume 2V. The
m
changes in the pressure in A and B are found to be P and 1.5P respectively. Find B
mA
29. Equation of standing wave in a string is given as,

   
y  2 sin  2x   sin  200t   cm ,
 4  6
Where x is in cm and t is in second. Find the distance between two consecutive nodes in mm.
30. A galvanometer, whose resistance is 50 , has 25 divisions on it. When a current of 4  104 A
passes through it, its needle deflects by one division. What resistance in  should be connected
to galvanometer to make it a voltmeter of range 2.5 V?
SECTION – A
31. Br
1. Mg, dry ether

2. CH3  CHO

3. H3 O
N
H
The major product of the reaction is
(A) CH CH3
OH
N
H
(B)
N CH CH3
H OH
(C) CH CH2
N
H
(D)
N
HC OH
CH3
32. Myosin is the common example of

(A) Vitamin
(B) Fibrous proteins
(C) Carbohydrates
(D) Globular proteins
33. Which of the following is positively charged sol?

(A) Copper sols
(B) Sols of Gum
(C) Oxides eg. TiO2 sol
(D) Metallic sulphides
34. Which of the following statements is incorrect?

(A) All Cu(II) halides are known except the iodide.
2+
(B) The standard reduction electrode potential for Cu to Cu has negative value.
(C) Permanganate titrations in presence of HCl are unsatisfactory as HCl is oxidized to
chlorine.
(D) The Eo value for Mn3+/Mn2+ couple is much more positive than that for Cr3+/Cr2+ or
Fe3+/Fe2+.
35. NH2
Conc. HNO3 

H2 SO 4
A B  C
The percentage yield is A > C > B. The A, B, C respectively are:

(A) NH2 NH2 NH2
NO 2
, ,
NO 2
NO 2
(B) NH2
NH2 NH2
NO 2
, ,
NO 2
NO 2
(C) NH2
NH2 NH2
NO 2
, ,
NO 2
NO 2
(D) NH2 NH2 NH2
NO 2
, ,
NO 2
NO 2
36. The rate of solvolysis of I – IV follows

Br Br
Br
Br
II III IV
I
(A) I > II > III > IV
(B) III > I > II > IV
(C) III > II > I > IV
(D) IV > I > II > III
37. Which of the following precipitate of sulphide is yellow in colour?

(A) HgS
(B) PbS
(C) CuS
(D) CdS
38. Which of the following complex is a diamagnetic complex?

3
(A) Co  C2O4  
 3
3
(B) MnCl6 
3
(C) Fe  CN 
 6
3
(D) CoF6 
39. Which of the following has correct matching of curve and orbital?
4r R (r)
4r R (r)
4r R (r)
2
2
2
2
r r r
(I) (II) (III)
(I) I(2p) II(1s) III(4p) (II) I(3p) II(3d) III(3s)
(III) I(4d) II(2p) III(5d) (IV) I(2s) II(4f) III(3d)
(A) II, III
(B) I, III
(C) III, IV
(D) All of the above
40. van der Waals equation for one mole of CO 2 gas at low pressure will be:
 a 
(A)  P  2  V  RT
 V 
a
(B) P  V  b   RT 
V2
RT
(C) P
V b
 RT a 
(D) P  2
 V b V 
41. The major product formed in the following reaction is

CO 2H
I2 , NaHCO3
 H2 O

(A) O
O
I
(B) O
O
I
(C) O
O
I
(D) O
O
42. The correct statement for the following structures is

H
N H N
N N N H
H H N
N N N N N H
N
1 2 3
(A) 1, 2, 3 are resonance structures
(B) 1 and 2 are resonance structures, where are 3 is an isomer of 1 and 2

(C) 1 and 3 are resonance structures, where as 2 is an isomer of 1 and 3
(D) 1, 2 and 3 are constitutional isomer
43. Which of the following compounds has a positive enthalpy of solution?

(A) LiF
(B) LiCl
(C) LiBr
(D) LiI
 E 
44. The temperature derivative of electrochemical cell potential E at constant pressure   is given
  T P
by
S
(A) 
nF
S
(B)
nF
S
(C)
nFT
S
(D) 
nFT
45. The d-orbitals involved in the hybridization to form square planar and trigonal bipyramidal
geometries are respectively
(A) dz2 and dz2
(B) dyz and dz2
(C) dx2  y 2 and dz2
(D) dx2  y 2 and dyz
46. The major product formed in the following reaction sequence is:
O
OEt
1. ,NaOEt
OEt
CHO
O ,

2.  CH3  NH

2
3. LiAlH4
4. BF3 ,HCHO
N
(A) OH
OH
OH
N
(B) H3C CH3

N
N O
(C) OH OH
CH3
N
CH3
N
(D) HO

O
HCN, KCN

160o C
(A)
O
CN
(B)
CN
(C) O
CN
(D) O
CN
48. The treatment of formic acid with concentrated sulphuric acid gives
1
(A) HCHO  O2
2
(B) CO2  H2
(C) CO  H2 O
(D) CO  H2
49. Zone refining may be employed for refining of metals like

(A) Ni and Zr
(B) Si and B
(C) Zn and Hg
(D) Cu and Ga
50. Which of the following order is correct?

(A) Li < Na < K < Rb < Cs (melting point)
(B) Li > Na > K > Rb > Cs (density)
(C) Be > Mg > Ca > Sr > Ba (ionization energy)
(D) Be < Mg < Ca < Sr < Ba (melting point)
SECTION – B
51. The maximum limit of nitrate in drinking water is________ppm.
52. Sea water containing 1 M NaCl has to be desalinated at 300 K using a membrane permeable
only to water. The minimum pressure (in atm) required on sea water side of the membrane
is______atm.
53. The dissociation constant of a weak monoprotic acid is 1.6  105 and its molar conductance at
infinite dilution is 360.5  104 mho m2 mol1 for 0.01 M solution of this acid, the specific
conductance is n  10 2 mho m 1 . The value of n is_________
54. A salt mixture (1 g) contains 25 wt% MgSO4 and 75 wt% M2SO4. Aqueous solution of this salt
mixture on treating with excess BaCl2 solution results in the precipitation of 1.49 g of BaSO4. The
atomic mass of M in g mol1 is___________
(Atomic mass of Ba is 137 g mol1 )
55. For the molecule CH3  CH  CH  CH  OH  CH  CH  CH  C CH3 2 the number of all
possible stereoisomers is
o
56. Calcium crystallises in fcc lattice of unit cell length 5.56 A and density 1.4848 g cm3 . The
percentage of Schottky defects in the crystal is________
57. The standard reaction enthalpy of the reaction Zn  s   H2 O  g  ZnO  s   H2  g is

1 1
223 kJ mol and the standard reaction Gibb’s functions is 33 kJ mol at 1520 K. Assuming
that both H and S remains constant. The minimum temperature x  102 K is the
o o
temperature above which equilibrium constant becomes greater than one. What is the value of x?
58. The rate of a first order reaction is 0.04 mol litre1 sec 1 at 10 minutes and 0.03 mol litre1 sec 1
at 22 minutes after initiation. The half-life of the reaction (in minutes) is
59. How many molecules of H2 O are required to hydrolyse 1 molecule of borazine?
60. One mole of an ideal gas ( = 1.4) is expanded isothermally and reversibly at 27oC till its volume
is doubled. It is then adiabatically compressed reversibly to its original volume. The magnitude of
total work done (in J) by the gas is__________
 0.4 4 1 1 
 2  ,R  8.3 JK ,mol 
 3 
SECTION – A
 
 cos 2x  cos3x
1  cos x cos2x cos3x 1   cos x 
61. If L1  lim and L 2  lim , then the value of L1  L 2
x 0 x2 x0 x2
is equal to
(A) 0
5
(B)
2
13
(C)
2
3
(D)
2
62. If  is satisfying the equation sin1  ex   sin1  x 2   0 ,   R and  is number of solution of
 2x
 1  tan   
equation cos1   2    x     , then which of the following is true?
 1  tan2 x 
 
 2 
(A) +>0
(B) +<0
(C) >
(D) >0
63. In ABC if a(2 cos A – 1) + b(2 cos B – 1) + c(2 cos C – 1) = 0, then value of
A B  C
a2 sin   b2 sin   c 2 sin  
2 2  2  is
bc ac ab
(A) 1
(B) 3
1
(C)
2
3
(D)
2
9
 z  2
64. If 1, 2, 3, ….., 9 are the roots of the equation    1 , where z = x + iy, x, y  R,
 z 1
9
i  1 , then value of  i is equal to
i 1
27
(A)
2
9
(B)
2
(C) 0
(D) 1
 1 0 0
 
65. If matrix M  2 2 1 and let M1 and M2 be two matrix such that M1  M4  4M3  5M2 ,
0 0 1
M2  M  5M2  2M , then det(M1M2) is equal to
4
(A) 27
(B) 24
13
(C) 2
11
(D) 2
 x 
ln  
66. Let h(x) be a function such that h(x) = ln 1  x   e  x 1 , then which one is correct for h(x)?
(A) h(x) is decreases for some interval in its domain
(B) h(x) has two point of inflections
(C) h(x) is increasing in its domain
(D) h  x  is increasing for all x in its domain
67. The integral values of k for which the equation x2 + (2022 + k)x + 2022k + 1 = 0 has integral roots,
are k1 and k2, then focii of hyperbola x2 – y2 = k1 – k2 will be
(A)  5 2, 0 
(B)  0,  6 2 
(C)  0,  2 2 
(D)  2, 0 
120
68. If a1, a2, a3, ….., a120 are positive divisors of M, where M  2  32  53  74 and P   ai &
i 1
120
 ai
i 1
Q 120
, then value of the following is true?
1
a
i 1 i
P
(A)  M12
Q
(B) PQ < M12
P
(C)  M12
Q
12
(D) PQ = M
69. Let sides of a PQR are represented y the equations PQ: x + y + 6 = 0, QR: x – y – 2 = 0 and RP:

y = 0 and if the point t,  4  t 2  lying inside the triangle PQR, then number of integral value(s)
of t is?
(A) 5
(B) 3
(C) 1
(D) 0
70. Let normals of an ellipse E at point A(–2, 3) and B(1, 2) intersect at M(0, 1) and S is the focus of
the ellipse E, then length of SA is equal to
2
(A)
10
10
(B)
2
2
(C)
3
3
(D)
2
1 1 1
71. If a, b, c are positive real numbers such that    1 , then the minimum value of
a b c
(a – 1)(b – 1)(c – 1) is
(A) 6
(B) 8
(C) 1
(D) 3
72. How many three digit numbers of the type a1a2a3 (decimal representation) where ai  {0, 1, 2,
….., 9}, a1  0 are formed such that a1 < a2 > a3 (a1, a2, a3 are distinct digits)
(A) 120
(B) 204
(C) 320
(D) none of these
           
73. If a, b, c are three vectors such that a  b  3 , c  6 , a  b  1, a  c  2 and b  c  2 , then
  
the volume of parallelepiped formed by the vectors a, b, c
(A) 4
(B) 16
(C) 2
(D) 12
max f   
74. Let f     16 cos2   25 sin2   25cos2   16 sin2  where   R, then value of is
min f   
41
(A)
5
41
(B)
9
82
(C)
5
82
(D)
9
    
75. If p, q are non parallel unit vectors and r is a vector in a plane perpendicular to p and q such
    2     
that r  5 and p  q  p  q , then p q r   p  q is equal to
23
(A)
5
17
(B)
5
3
(C)
5
19
(D)
5
76. Let the set of complex numbers (p1, q1), (p2, q2), (p3, q3), ..... denoting the points on the complex
plane satisfying the relation  pn1, qn1    3 pn  qn , 3 qn  pn   n = 1, 2, 3, ..... if
 p100 , q100    2, 4  , then the value of p1 + q1 is
1
(A)
256
1
(B)
297
1
(C)
298
1
(D)
299
77. The number of real values of x, x  R satisfies the equation

3x 2  18x  52  2x 2  12x  162  x 2  6x  280 , is
(A) 1
(B) 2
(C) 3
(D) infinite
15x  2022
78. If standard deviation of the variate x is 5, then standard deviation of the variate is
7
2022
(A)
5
2077
(B)
7
35
(C)
15
75
(D)
7
 3x  3x  1  x 
79. If y = g(x) is a function, g : [0, 3]  R, g  x   tan1    tan 
2   , then the maximum
3 3 x   3
value of g(x) is

(A)
4

(B)
3
3
(C)
4

(D)
6
80. If there are n number of integers between 1 and 10000 which have the property that “sum of
digits of the number is equal to 12”, then n is
(A) 415
(B) 455
(C) 514
(D) 554
SECTION – B
   
81. If OAB is a triangle such that OA  a , OB  b , O is origin if D, E, F are points on the OB, AB, OA

 1   2   2a  b
respectively such that OF  a , OD  b , OE  if AD, FB, OE intersect at R, Q, P points
3 3 3
area of ABC m
respectively, if  , m, n are coprime, then (m + n) equal to
area of PQR n
82. How many three digit numbers abc (decimal representation) a  0 can be formed by using
decimal digit with the property that a < b and c < b
83. If number of values of 1 for which tan 31 – tan 21 = 1 + tan 31 tan 21, 1  [0, 2022] are 1
8 8
and number of value of 2 for which sin  2   cos  2   1 , 2  [0, 100] are 2, then 1 + 2 is
equal to
5 4 3 2
84. If z1, z2, z3, z4, z5 are the roots of the equation z + z + z + z + z + 1 = 0 and if
2
 
1i j 5
zi  z j , then the value of  is
85. There is a non-zero complex number z3 such that z12  z2 z3 and z22  z1z3 , if |z1| = |z2| = |z3| = 6
and if area of triangle formed by z1, z2 and z3 as vertices are , then  is equal to
86. In a triangular park ABC a pole of height h standing on the vertex A and there are three
  
equidistant points on the side BC whose angle of depression are observed to be , and
6 4 3
2
respectively, then the value of h is
87. If M be a square matrix of order 3  3 such that det(M) = 4, then det(adj (2M)) is equal to
88. If length of the path traced by the locus of mirror image of foci (both the focus) of ellipse
16x2 + 4y2 = 1 with respect to its variable tangent y = mx + c is L, then [L] is equal to
(where [.] denotes greatest integer function)
2 
89. Let AB is a focal chord and MN is latus rectum of the parabola y = 2x, if AB makes angle with
6
positive x-axis (point A and M in first quadrant), then the value of
2
 1 1 
 area of  MAS  area of  NBS  , (where S is the focus of given parabola) is
 
3 p 20 20
1  m  
90. If the sum of series  tan
p 1 r 1 n 1 m 1
    , then the value of
n 
is
FIITJEE
FULL TEST – VII
JEE (Main)-2022
TEST DATE: 27-02-2022

Physics PART – A
SECTION – A
1. A
E C2
Sol. I 2R R
3R
In loop PSQP, +Q2 Q2
Q I R
E 1 E  0
C1 C1
 Q1 = 2EC1 P Q
Q E S+Q Q1
Also, E IR  2  E  0 1
C2
5EC2 E
Q2 
3
Q12 Q2
Also,  2
2C1 2C2
2
C Q  25
 2  2 
C1  Q1  36
2. C
Sol. Applying KVL, we can get
34 36
I1  A and I2  A
13 13
2
 I2  I1  A
13
AITS-FT-VII-PCM(Sol.)-JEE(Main)/22 2
3. D
Sol. P = P 1 + P2
K = K 1 + K2
P2 P2 P2
 1  2
2m 2m 2m
Solving, we get
P 4P
P1   , P2 
3 3
k 8k
k1  , k 2 
9 9
4. B
2m
Sol. Time period T  2
3k
T
Required time is t 
4
 2m
 t
2 3k
5. C
 X 
Sol. Phase difference is  tan1  L 
2  R 
6. D
CV 3CV
Sol. Hence charge flowing the battery is 2CV  
2 2
3CV/2 CV/2 CV/2 3CV/2 3CV/2 2CV 2CV 3CV/2
7. A
Sol. In this case angular frequency is
16k

9m
2 9m
 T  2
 16k
8. C
1 1 1
Sol.  R 2  2 
0 1 n 
R0
 n
R0  1
9. B
Sol. At time t, velocity of 1st is

v1  30iˆ  gtkˆ
3 AITS-FT-VII-PCM(Sol.)-JEE(Main)/22

From 2nd, v 2  30 ˆj  gtkˆ
 
Also, v1  v 2  v1v 2 cos60
Solving we get t = 3 sec
10. C
 2 I
Sol. B  0 (sin60  sin90)iˆ
4a
 I
B  0 (2  3 )iˆ P
4a
M 2a
I 30 I
30
11. B
Sol. dQ = dU + dW = 3dU
dQ = 3nCVdT = nCdT
 C = 3CV
 7.5 R = 3CV
5R
 CV 
2
Gas is diatomic
12. D
Sol. when m = 256 gm
3 256g
120  …(i)
2  1.5 
When m = m, then
4 mg
120  …(ii)
2  1.5 
Solving (i) and (ii), we get
m = 144 gm
13. D
Sol. If  = length of spring
   A  B …(i)
 A : B  2 : 3 …(ii)
From (i) and (ii)
2 3
 A  , B 
5 5
3
k    kb 
5
5k
 kb =
3
14. C
Sol. It will be equal to 2gh
15. B
Sol. for rotation N
mg(0.1) + kx(0.6) = I A B
2
Solving,  = 30 rad/s 
For translational
mg + kx  N = m(0.1) O
 N = 20 newton mg kx
16. A
Sol. Net force
     

F  q(E1  E2 )  q v  (B1  B2 

 F  qE0 (0.8iˆ  ˆj  0.2k)
ˆ
Here at t = 0, x = y = 0
 
E  E ˆj, E  E kˆ
1 0 2 0
 E ˆ  E
B1  0 k, B 2  0 î
C C
17. B
IA
Sol. F  (1  r)
C
(1  0.25)(25)(2)
  20  108 N
3  108
18. D
th
 1
Sol. When potential energy is   its maximum value, then current through 24 V battery is
4
21
I A
8
21
 Power = VI = 24  W = 63 W
8
19. B
Sol. If a beam of unpolarized light of intensity I0 is passed through the two polaroids, the intensity of
the emergent light is
I
I  0 cos2 
2
I0 3I
I  cos2 30  0
2 8
20. D
Sol. Truth table for given combination is
A B X
0 0 0
0 1 1
1 0 1
1 1 1
This comes out to be truth table of OR gate
SECTION – B
21. 00003.00
E
Sol. I1  e  t /RC
R
 tR
E 
I2   1  e L 
R 
I2 1  e 2t
 3
I1 e 2t
22. 00019.00
4T 4
Sol. P1  , V1  a3
a 3
2 4T 4
P2   , V2  (2a)3
2 0 2a 3
 Process is adiabatic,
P1V15 /3  P2 V25/3
Solving we get
150 T

4a
23. 00003.38
Sol. Reading = 3 + (35  0.01)  (0.03) = 3.38 mm
24. 00000.50
Sol. S(t) = 5cos(1800 t) + 20 cos(2000 t) + 5 cos(2200 t)
 1 
= 20 1  cos(200t) cos(2000t)
 2 
 modulation index is 0.50
25. 00011.25
1  2  4
Sol.  (1.4  1)  
f  25  125
f = 31.25 cm
Normal shift = 35  31.25 = 3.75 cm
 1   1 
 3.75  t  1    t 1  
 2   1.5 
 t = 11.25 cm
26. 00006.00
Sol. Here time period is T = 4 sec P O
2
x  A sin t A B
T
 2  Mean position
v  v max cos  t
 T 
Time from O to P is t = 0.5 sec
T
t
8
v 3 2
 v max    6 m/s
2 T 1
cos 
T 8 2
27. 00006.00
Sol. Effective half life is
TT
Teff  1 2
T1  T2
(1)(2) 2 
Teff    hour
1 2 3 9
k=6
28. 00001.50
Sol. In container A;
n RT nA RT nA RT
P  A   …(i)
V 2V 2V
In container B;
n RT nBRT nBRT
1.5P  B   …(ii)
V 2V 2V
By solving
n m
1.5  B  B
nA m A
29. 00005.00
Sol. Here  = 1cm

  0.5cm  5 mm
2
30. 00200.00
Sol. V  Ig (Rg  RH ) G
Ig RH
2
2.5  (10 )(50  RH )
RH  250  50  200
SECTION – A
31. D
Sol.
Br MgBr O
||
CH  C H
Mg  3
  
N N N
N
MgBr
H H
HC CH3
O
H3 O
N
HC CH3
OH
32. B
Sol. Myosin (in muscles) is fibrous protein.
33. C
Sol. Oxides eg. TiO2 sol is positively charged sol.
34. B
Sol. EoCu2  /Cu has positive value which is equal to 0.34 V.
35. C
Sol. NH2 NH2 NH2 NH2
NO 2
HNO3
 
  
H2 SO4
NO 2
NO 2 2%
51% 47%
36. C
Sol. Solvolysis depends on stability of carbocation.
37. D
Sol. HgS, PbS and CuS are black but CdS is yellow.
38. A
Sol. Co2   3d6 4so
C2O24 is chelating ligand. So, t 2g  3d6 and eg  3do
39. A
Sol. The orbitals with same number of radial nodes has same shape of curve.
40. A
Sol. At low pressure V is high so, b can be neglected in comparison to V.
41. B
Sol.
CO 2H COO
I2 , NaHCO3
 H2 O
 I
anti  attack
O
O
42. D
Sol. Change in position is not allowed in resonance structures. So, 1, 2, 3 are not resonance
structures, they are constitutional isomers.
43. A
Sol. LiF is sparingly soluble due to its high lattice energy.
44. B
 dG 
Sol. G  H  T  
 dT P
G  nFE
G  H  TS
45. C
46. B
Sol. O
OEt O
C OEt
O
OEt C
C H CH
O C OEt
,

NaOEt

O
N N
 CH3 2 NH
H3C CH3
N
H3C CH3 CH CH(COOEt) 2

N LiAlH4
CH CH2OH
HC N
CH2OH
N
BF3 , HCHO
H3C CH3
N
CH O
HC
O
N
47. C
Sol. CN shows 1,4-conjugae addition.
48. C
conc. H2 SO4
Sol. HCOOH  CO  H2O
Conc.H2SO 4 acts as dehydrating agent.
49. B
Sol. Zone refining is useful for producing metals of very high purity, e.g. germaniumm, silicon, boron
etc.
50. C
Sol. As size increases ionisation energy decreases.
SECTION – B
51. 00050.00
Sol. The maximum limit of nitrate in drinking water is 50 ppm.
52. 00049.26
Sol.   iCRT
  2  1 0.0821 300
  49.26 atm
53. 00001.44
Sol. K a  C2
1.6  10 5  0.01  2
4  102  
 m
 m o
,4  102 
m 360.5  104
m  1442  106 mho m2 mol1
 14.42 mho cm2 mol1
1000  K
m 
M
K  1.442  104 mho cm 1
K  1.442  102 mho m 1
54. 00039.20
Sol. MgSO 4  BaCl2  MgCl2  BaSO 4
M2SO 4  BaCl2  2MCl  BaSO4
Total moles of BaSO4 = Total moles of MgSO4 + Total moles of M2SO4
1.49 0.25 0.75
 
233 120 2x  96
x  39.2
55. 00008.00
Sol. Number of all stereoisomers  23  8 .
56. 00003.95
ZM 4  40
Sol.  3
 3
 1.5458
NA  a 3
6.022  10   5.56   10 8
23
 
1.5458  1.4848
%Schottky defect   100  3.95
1.5458
57. 00017.84
Sol. Go  Ho  TSo
190
33  223  1520 S o ,  So
1520
So  0.125 kJ mol1 K 1
For K eq  1 Go  0 Go  Ho  T So  0
Ho 223
o
 T, T
S 0.125
T  1784
T  17.84  102
58. 00028.90
0.04  k A o e  
 k 10
Sol. R1  k A1,
0.03  k A o e  
 k 22
R2  k A 2 ,
4 10k  22k 4 12k
e , e
3 3
4 1 4
n  12k k n
3 12 3
0.693
t1/2 
k
59. 00009.00
Sol. B3N3H6  9H2O  3NH3  3H3BO3  3H2
60. 00349.66
r 1
V 
Sol. For adiabatic process T2  T1  1 
 V2 
T2  400K
W  W1  W2
 V   nR
  nRTn 2     T2  T1  
 V1   r  1 
= 349.66 J
SECTION – A
61. C
1
Sol. L1  7 , L 2 
2
62. B
x 2
Sol. e  (0, 1]  x  (–, 0] ; x  [0, 1]  x  [–1, 1]  x  [–1, 0)
  < 0 and x  (2n + 1)   = 0
63. D
Sol. r = 2R   is equilateral
64. A
9
27
Sol.  i   2
i 1
65. C
Sol. If (M – I)2(M – 2I) = 0  M3 – 4M2 + 5M – 2I = 0
 M1 = 2M, M2 = 4M3  |M1M2| = |8M4| = 114
66. C
1 1
Sol. Domain  (0, ), h  x     0  x, h(x) < 0  x  D
1  x  1  x 2
67. C
Sol. (x + 2022)(x + k) = –1
 So, equation of hyperbola can be x 2 – y2 = 4
68. A
1
Sol. P = M60 and  ai  M  a Q=M
i
69. C
Sol. t  (–2, 0)
70. A
Sol. Equation of the directrix is x – 3y + 13 = 0
71. B
1 1 1
Sol. Let a  ,b  ,c 
x y z
 1  x   1  y  1  z 
    8
 x   y   z 
72. B
9
Sol. C3  2  9C2
73. A
     
aa a b ac
   2      
Sol. a b c   b  a bb b  c  16  V = 4
     
c a c b ca
74. D
Sol.  f   2  16  25  2 162  252  sin2  cos2   16  25  sin4   cos4  
max f     2 16  25  , min f() = 4 + 5
75. A
     3
Sol. p q r   4 and p  q 
5
76. C
Sol. Let zn  pn  iqn  zn1   3  i  zn
77. A
Sol. x = 3 is the only solution
78. D
x   
Sol. For the variate the new standard deviation = a
 
79. A
x
Sol. g  x   tan1  
3
80. A
Sol. Coefficient x12 in (x0 + x1 + ..... + x9)4
 15 C3  4 C1  5 C2  415
SECTION – B
81. 00008.00
m 7
Sol. 
n 1
82. 00240.00
9 9
Sol.  r2   r  285  45  240
r 1 r 1
83. 00100.00
Sol. 1 = 0, 2 = 100
84. 00024.50
Sol. z1, z2, ..... z5 will be 1, , ,  ,  
2 13

1 i j5
zi  z j  1
4
 2  1 1 4  3  3  4  1
  = 24.50
85. 00046.77
Sol. Triangle formed by z1, z2, z3 will be equilateral triangle
86. 00001.71
Sol. In AQC
2 2 2 2
(QA) + (QC) = 2(QB + BC)
h 
2
 h 1 6
 2 2  2  2 A C
 cot  cot  cot 
 3 6 4
12 
 h
7 3 B
87. 01024.00
Sol. |adj 2M| = z6 |M|2 = 210
88. 00012.00
Sol. Locus will be a circle of radius two times of length of major axis
89. 00021.33
1 1 2
Sol.   for y2 = 4ax
1  2 3a2
90. 00600.00
20 20 20 20
m n
1 
Sol. Let k   tan1   ; k   tan  
n1 m 1
n n1 m 1
m
3 p

 2k = 400
2
 k = 100  100  600
p 1 r 1
FIITJEE
FULL TEST – VIII
JEE (Main)-2022
TEST DATE: 06-03-2022
answer.
AITS-FT-VIII-PCM-JEE(Main)/22 2
Physics PART – A
SECTION – A
1. A solid object having uniform density () and varying cross-sectional

R1
area (which is circular) is placed on smooth horizontal surface as
R
shown. Then the value of 1 if the stress throughout its height remains
R2
same and having value equal to c. H
gH

2c
(A) e
gH
(B) R2
2c
gH

(C) e c
gH
(D)
c
2. A uniform disc is held in equilibrium on a rough horizontal surface

(coefficient of friction = ) by applying a force as shown. Then the
maximum value of F for this to be possible is (weight of disc is W).
(A) zero R/2
2w
(B) R
3
w
(C)
1  3
2w
(D)
1  3
3. A system of two charge particle A and B having charges +q and q and B

mass m and 2m respectively and connected with an ideal massless
R
inextensible string which lies along the axis of a uniform charged fixed
non-conducting ring as shown. If gravity is neglected and ignore the
force between A and B, find the tension in the string at this instant. Q,R
(A) zero
kqQ R
(B)
3 2R 2
kqQ A
(C)
2 2R 2
kqQ
(D)
6 2R2
3 AITS-FT-VIII-PCM-JEE(Main)/22
4. A body takes 5 minutes to cool down from 50 to 40C in surrounding of temperature 20C. Then
the time taken by the same body to cool down from 40C to 30C in a surrounding of temperature
10C is (Assuming Newton’s law of cooling is valid)
(A) 10 minutes
(B) 20 minutes
(C) 40 minutes
(D) 80 minutes
5. A positively charged particle having charge q and mass m enters P

in isosceles right angle triangular region having uniform magnetic

field B as shown in gravity free space. The maximum value of v
so that particle must comes out through the region from side PQ   
is   
BqL    
(A)
2m v    
( 2  1)BqL (q, m) Q R
(B) L
m
BqL
(C)
2 2m
( 2  1)BqL
(D)
2m
6. If the final image of the object O coincides with it  =1

then the sum of all possible values of x is
(A) 5R
(B) 4R O Plane
(C) 3R mirror
(D) 2R x
 = 3/2
R
9R
7. A tennis ball is thrown in downward direction with speed v from height h towards fixed horizontal
surface with which it collides inelastically with coefficient of restitution e. The minimum value of v
so that the ball will able to reach at the point of projection is
(A) 2gh(1  e)
(B) 2gh(1  e2 )
1 
(C) 2gh   1
e 
 1 
(D) 2gh  2  1
 e 
8. A galvanometer is connected as shown in figure. What should be the S

resistance connected to it in parallel so that its deflection is reduced to
half
(A) 90  G
(B) 91  100  R = 1 k
(C) 99 
(D) 100 
2V
9. A particle is moved along the curve x 2  y 2  2xy from (0, 0) to (1, 1) by some forces. If one

among them given as F  y 2 î  2xyjˆ . Then the work done by the given force is
(A) zero
(B) 1 Joule
(C) 1 Joule
(D) 2 Joule
10. Which of the following statement is INCORRECT for the given I2 R

circuit.
I1 L C
I
~

1
(A) For   , I1 leads I2
LC
1
(B) For   , phase difference between I1 and I2 is 90
LC
1
(C) for   , phase difference between I1 and I2 is 90
LC
1
(D) for   , is not permissible for the circuit.
LC
11. The correct value of current (i1, i2, i3) in the circuit shown i3 10 k
in the figure is
(A) i1 = 12 mA, i2 = 6 mA, i3 = 18 mA i2 i1
+
(B) i1 = 12 mA, i2 = 4 mA, i3 = 16 mA 240 V 5k
(C) i1 = 16 mA, i2 = 0 mA, i3 = 16 mA 60V
(D) i1 = 16 mA, i2 = 8 mA, i3 = 8 Ma
12. All the pulleys and strings are ideal and massless and  = 0.2 F = 4N
1 kg
the system shown is at rest. Now a force F = 4N is
applied on the pulley shown. Then the frictional force
acting between the blocks is 2 kg
(A) 2N
(B) 1.96 N smooth fix
(C) 3N
(D) 0N
13. The speed of sound in hydrogen gas is v 0 at temperature T0. Then the speed of sound in the
mixture of helium and oxygen gas having same number of moles at temperature T0 is
v0
(A)
3
3
(B) v0
14
5
(C) v0
42
5
(D) v0
21
14. An ideal gas is expanding such that PT2 = constant. The coefficient of volume expansion of the
gas is
1
(A)
T
2
(B)
T
3
(C)
T
4
(D)
T
15. A small smooth metal sphere of radius r and density  falls from rest in a viscous liquid of density
 and coefficient of viscosity . Due to friction, heat is produced. The rate of production of heat
when the sphere has acquired the terminal velocity is proportional to
(A) r2
(B) r3
(C) r4
(D) r5
16. Magnifying power of an astronomical telescope in near point adjustment is 110% of its magnifying
power in normal adjustment. Then the focal length of objective when the length of the telescope
in normal adjustment is 10 cm. (Take least distance of clear vision = 25 cm)
(A) 2 cm
(B) 2.5 cm
(C) 7.5 cm
(D) 8 cm
17. Initially the capacitor is uncharged and now switch is closed. Then L = 2H C = 8F
the maximum current through the circuit is
(A) 1 mA
(B) 4 mA
(C) 2 mA V0 = 2V
(D) 8 mA
18. If key is closed in the circuit shown in the figure and the C
galvanometer does not give any deflection at any time, then the 3F
value of C is
(A) 3 F G
(B) 9 F
(C) 4 F 2 6
(D) 1 F
+ 
V0 k1
19. A parallel beam of light having intensity I = 10 Wm2 is continuously falling on emitter plate in the
photoelectric effect setup at angle of 37 with the normal. If area of plate is 1 m 2 and wavelength
of light is 621 nm and one photon is capable to eject one electron. Then saturation current in the
circuit is (th > 621 nm)
(A) 3A
(B) 4A
(C) 1.8 A
(D) 3.2 A
20. In a YDSE experiment, if a slab whose refractive index can be varied is placed in front of one of
the slits then the variation of resultant intensity at mid-point of screen with ‘’ will be best
represented by ( 1). (Assume slits of equal width and there is no absorption by slab)
(A) I0 (B) I0
=1  =1 
(C) I0 (D) I0
=1  =1 
SECTION – B
21. A particle is thrown towards a stationary planet with

4kGM M, R
speed so that it grazes the planet as shown. 30
105R
C
Find k.
5R
22. Two source resonance are observed at length 53.8 cm and 75.8 cm in a resonance column tube.
Then the radius of the tube (in cm) is R. Find the value of R.
23. A projectile is thrown from ground towards a large vertical wall which is at a distance of 8 m from
the point of projection. If launching speed of projectile from ground is 10 2 m/s. If projectile hits
the wall at a height h from ground. Then maximum possible value of h is ……..(in meter) (Take g
= 10 m/s2)
24. k wavelength emitted by an atom of atomic number z = 11 is . Then the atomic no. of an atom
that emits k radiations of wavelength 4.
25. If power directed by the cell to the circle is same either switch is 7.2 
closed or open. Then the internal resistance of cell is r . Find the
value of r.
S
9
26. If 3rd excitation potential for a hypothetical hydrogen like atom is 15 volt. Then the value of 2nd
ionization energy for this hypothetical atom is N eV. Find the value of N.
27. Heat is given to an ideal gas (closed system) so that pressure and volume are increased by 10%
and 20% respectively. Then percentage increase in temperature is N. Find the value of N.
28. Two Polaroids are placed on x-axis such that their planes are parallel to y-z plane and pass axis
of these polaroids are making an angle of 45 with x-axis and also perpendicular to each other. If
an unpolarised light of intensity I0 propagating along x-axis having intensity after passes through
KI
the system of two polaroids is 0 .Then find K.
16
29. The total number of images formed by the lens n1 = 3/2

shown if the object is placed at O. n1 n2
n2 = 4/3
n2 n1
30. Assume that an electron and a positron pair is formed from a gamma ray photon having energy
3.0 MeV. Find the total kinetic energy (in MeV) of the system of electron and positron that is
formed. (Given rest mass energy of electron is 0.51 MeV)
SECTION – A
31.
 3
i O 
 ii H2 O  H2O2  A 
 B
Identify product B?
(A) O
O
(B) O O
O O
(C) O O
O O
O O
(D) O O
O O
O O
32. HCOOH has following possible resonating structures

O O O O
H C OH H C O H H C OH H C OH
(I) (II) (III) (IV)

Decreasing order of stability is:
(A) I > II > III > IV
(B) III > IV > I > II
(C) III > II > I > IV
(D) II > III > I > IV
33. Identify which of the following reaction has negative r S (change in entropy)
(A)  
 CH  CH  CH
3 2
(B) CH3 COO  

 aq  H3O  aq  CH3 COOH  H2O
(C) S  s   S  g 

(D) H2  CH2  CH2  CH3  CH3
34. Correct sequence of filling of electrons for 6s, 6p, 5d, 4f will be
(A) 6s  6p  5d  4f
(B) 6s  5d  4f  6p
(C) 5d  6s  6p  5d
(D) 6s  4f  5d  6p
35. For following electron gain enthalpies

(i) O  g   e  O  g   egH1  141 kJ / mol
(ii) O   g  e  O2  g   egH2
(iii) O  g   2e  O2  g  egH   egH1   egH2
Identify correct statements:
(A)  egH2 is more negative than  egH1
(B)  egH for reaction (iii) will be negative
(C)  egH2 will be positive
(D)  egH1 and  egH2 have almost same value
36. The shape of ICl4 , ICl4 , and ICl5 are respectively

(A) Trigonal bipyramidal, Tetrahedral and Tetrahedral
(B) See saw, Square planer and Square pyramidal
(C) See saw, Tetrahedral and Octahedral
(D) Trigonal bipyramidal, Trigonal bipyramidal and Octahedral
37. Identify compound A  C8H8 O2  which gives following reaction


H2 O/H P.C.C. Neutral FeCl3
A   B  C test
 positive
aq. KOH Conc. KOH

.

HBr
D GH
(A) OCH3
H3CO
(B)
OH
H3CO
(C)
OH
HO
(D) OH
OH
38. OH
KOH

CHCl3
Products
CH3
Which of the following product is not possible?
(A) O
H3C CHCl 2
(B) KO CHCl 2
CH3
(C) OK
CHO
CH3
(D) Both (A) and (B)
39. Identify wrong statement

(A) Rickets and osteomalacia disease cause by deficiency of Vitamin–D.
(B) Vitamin-A, D,E and K are stored in liver and adipose (fat storing) tissues.
(C) Cellulose is a branched chain polysaccharide composed both   D  Glucose and
β-D-Glucose
(D) During denaturation secondary and tertiary structures are destroyed but primary structure
remains intact.
40. 1.5 moles of gas A and y moles of gas B exert a pressure of 50 Pa and volume of container is

10 m3 at 200 K. y is R  JK 1 mol1 
 1  6R 
(A)  
 4R 
 1 R 
(B)  
 4R 
4 R
(C)
2R
R
(D)
1  4R
41. Identify which of conformer of 3-amino-2-butanol is most stable?

(A) OH
NH2
H CH3
H CH3
(B) OH
H CH3
CH3
H
NH2
(C) OH
CH3
CH3
H
H2N
(D) OH
H3C NH2
CH3
H
H
42. Equilibrium constant for the mutarotation of glucose,   D  glucose  -D-glucose is 1.4
percent of   form remains under equilibrium is…..
(A) 30
(B) 45
(C) 34.5
(D) 41.67
43. Identify correct statement

(A) Powder of kernel of tamarind seeds has been found to an effective material to make
municipal and industrial water waste clean.
(B) Maximum limit of nitrate in drinking water is 100 ppm.
(C) Lead can not damage kidney, liver and reproductive systems.
(D) Clean water would have BOD value more than 17 ppm.
44. Total number of possible isomers for Pt NH3 4 Br2  Cl2 ?
(A) 5
(B) 7
(C) 6
(D) 4
45. Which of the following is not rubber?

(A) Neoprene
(B) Buna-N
(C) Vulcanised rubber
(D) Teflon
46. Value of G in the process of melting ice at 10o C is

(A) equal to zero
(B) less than zero
(C) greater than zero
(D) none of these
47. Which of the following reaction occur at cathode when electrolysis of NiCl2  aq take place at Pt
o
electrode. ENi2/Ni
 0.25 V 
2
(A) Ni  2e  Ni  s 
(B) Pt 2  2e  Pt  s 
(C) 2H2O  2e  H2  2OH
(D) 2H  2e  H2
48. Which of the following reaction is incorrect?


(A) NH4NO3   N2 O  H2O

(B) NH4NO2   N2  H2 O
(C) Sn  HNO3  dil.  Sn NO3 2  NO2  H2O
(D) Fe  HNO3  very dil   Fe NO3 2  NH4NO3  H2O
49. Total number of S – O – S linkages in  form of SO3 are

(A) 2
(B) 3
(C) 4
(D) 5
50. In which of the following ore carbonate is present?

(A) Limonite
(B) Zincite
(C) Diaspore
(D) Siderite
SECTION – B
51. 10 gm carboxylic acid C xHy Oz   with molecular mass 118 gm/mole, neutralizes 169.5 ml of 1 M
KOH. When 1 mole of carboxylic acid is heated 1 mole of H2 O release without loss of CO 2 . Total
number of carbon atoms and hydrogen atoms in the carboxylic acid are x and y respectively. Find
y/x?
52. “a’ and “b” are total number of correct and incorrect reactions respectively. Find a/b?

(i)  CH3 3 CCl  AlCl3   CH3 3 C   AlCl4 

(ii)  CH3 3 C  COCl  AlCl3   CH3 3 C   AlCl4   CO
1
(iii) HC  CH  Na  HC  C  H2  Na
2
2
(iv) CH2I2  Zn  CH2  ZnI2

(v) CH3  CHI2  Zn  CH3  CH  ZnI2


(vi) CH3  N  N  CH3   2CH3  N2

(vii) CH2  CH2  DBr  CH2  CH  D  Br 
53. 1.5 gm of O2 and some NaCl is formed by heating sample of NaClO3 . The residue is reacted with
excess of AgNO3 and form AgCl. Mass of AgCl (in gram) will be (answer in two decimal places)
54. x are total number of correct statements

(i) Dihydrate of calcium sulphate is known as gypsum.
(ii) None alkaline earth metal hydrides are ionic in nature.
(iii) Phenol gives paraquinol with S2O82 / OH as major product.
(iv) Phenol can give electrophilic aromatic substitution in absence of Lewis acid  AlCl3  .
(v) Solvay process can not be used to prepare K 2CO3 due to precipitation of KHCO3 .
x5
(vi) Salicyclic acid can give white/yellow solution with Br2 / CS2 . Find  ?
 4 
55. x are the total number of chiral carbon atoms and y are total number of hydrogen atoms which
are attached to chiral carbon atoms
C N
OH
H2N
56. Chamber A and B are filled with 2 atm He and 4 atm H2 respectively. Both chamber are
separated by small tube (negligible volume) with stopcock at 300 K temperature as given in
diagram
A B
2 litre
3 litre
After opening stopcock find out total pressure (atm) in chamber A.
57. Solution of 0.05 mole of sugar in 500 gm of water shows 0.279o C freezing point. Cane sugar
solution has inversion as follows
Cane sugar  H2O     Glucose + Fructose
Find out mass of cane sugar left without inversion. (m.wt. of cane sugar = 342 gm/mole)
2
58. Surfactant solution of 100 ml 50 mM solution forms a monolayer covering 67.5 cm on a polar
substrate. If polar head is approximate as a cube. What is its edge length in Pm? No  6  1023  
59. A gas equation is P(V – nb) = nRT for a state, where Vm  5b , for any pressure and temperature.
Compressibility factor of gas for this condition is……(b = van der Waal’s constant, R = Universal
gas constant, Vm = molar volume).
x
60. Enthalpy change (in kcal) for the reaction XeF2  Xe   g  F   g  F  g is ‘x’. Find out
?
100
(Average bond enthalpy of Xe – F = 34 kcal/mol, 1st ionization enthalpy of Xe (g) = 279 kcal/mol,
Electron gain enthalpy of F(g) = - 85 kcal/mol).
SECTION – A
61. Number of ways in which first 11 natural numbers can be 1 2 3 4 5

arranged in the given figure such that aij > akj whenever i > k  j 1
is (aij represents element in ith row and jth column)
(A) 69300 2
(B) 11550
3
(C) 34650
(D) None of these 4
62. Let f(x) = 2x 2 + 4x + 9 and g(x) = f(cos2 x – sin x), then number of points of extrema in x  (0, 2)
is
(A) 3
(B) 4
(C) 5
(D) 6
 x  2k ; 2k  x  2k  1
63. Let f  x    , where k  I. Consider the following statements:
 2k  2  x ; 2k  1  x  2k  2
(1) f(x) is even function
(2) f(x) is periodic function
(3) range of f(x) is [0, )
(4) f(x) = f(2 – x)  x  R
The correct statements are
(A) 1, 2, 3
(B) 1, 2, 4
(C) 2, 3, 4
(D) 1, 3, 4
64. The solution of the differential equation

 x 4 y3 x 6 y5 x8 y7   x 3 y 4 x5 y 6 x7 y8 
dy  x 2 y     .....   dx  xy 2     .....   0
 3 5 7   3 5 7 
(A) xy tan1  xy   ln 1  x 2 y 2   c
(B) xy tan1  xy   ln 1  x 2 y 2   c
1
(C) xy tan1  xy  ln 1  x 2 y 2   c
2
1
(D) xy tan  xy   ln 1  x 2 y 2   c
1
2
65. Variance of set of 100 observation given by 3, 5, 7, 9, ..... is

(A) 9999
(B) 6666
(C) 3333
(D) 1111
66. Logical statement (p  q)  (q  r) is equivalent to

(A) (p  r)  (~p  ~q  ~r)
(B) (p  r)  (~p  ~q)  (~q  ~r)
(C) (p  r)  (~p  q  ~r)  (~p  ~q  ~r)
(D) (p  r)  (~p  ~q  r)  (p  ~r  q)
67. Let R = {(a, b) | a – b is irrational ; a, b are real numbers}, then relation R is

(A) reflexive and symmetric relation
(B) transitive and symmetric
(C) symmetric relation
(D) equivalence relation
68. There is a circular park of radius 100 m having two trees of equal height h on its circumference. A
person is standing on the circumference of the park such that the angle of elevation of top of both
the trees is equal to 30. The person starts running at a speed of 10 m/s along the periphery and
reaches one of the tree in 5 seconds, then h equals (in metres)
200  1
(A) sin  
3 4
200  1
(B) cos  
3 4
200  1
(C) sin  
3 2
200  1
(D) cos  
3 2
f 2  x   2xf  x   2x  1
69. If f(x) = xf 2(x) + x2  x, then  1 2xf  x  f  x   f  x 1  x   2x  1 dx equals
1
(A) c
x  f  x
1
(B) c
x  f  x
1
(C) 2
c
x  f  x
1
(D) 2
c
x  f x
70. Let 2x2 + 2y2 – 5xy = 0, y = mx + c form a triangle such that reflection of any point (x, y), lying
inside the triangle, in the line y = mx also lies inside the triangle, then minimum possible value of
m – m equals
(A) –2
(B) 0
(C) 2
(D) None of these
71. Given a point P from which tangents T1 and T2 are drawn to a unit circle Ci such that the chord of
2
contact so formed subtends at the centre of circle. Now, circle Ci + 1 is drawn which touches
3
T1, T2 and Ci externally (i = 1, 2, 3, .....). If ri represents radius of circle Ci and ri + 1 < ri  i  N,
n
then lim
n
r
i1
i equals
20
(A)
7
31
(B)
9
5
(C)
3
3
(D)
2
72. Let a mirror be placed along the parabola y2 = 4x. A ray of light parallel to x-axis is incident on the
mirror at point P and after reflection is incident on the parabola again at point Q. If reflected ray at
Q is same as incident ray at Q, then coordinates of P are
(A)  2, 2 2 
(B)  3, 2 3 
(C) (4, 4)
(D) P does not exist
674 2022 674 2020 674 2018 674 674

73. C0 C674  C1 C674  C2 C674  .....  C674 C674 equals
674
(A) 2
(B) 21348
(C) 22022
(D) None of these
74. Let A be set of all 2  2 symmetric nilpotent real matrices and B be set of all 2  2 skew
symmetric nilpotent real matrices, then n(A  B) equals
(A) 0
(B) 1
(C) 4
(D) None of these
 
75. Number of solutions of the equation 3 tan x  3 3 cot 3 x  4 sin2   x   0 in x  [0, 2022] is
6 
equal to
(A) 2022
(B) 4044
(C) 8088
(D) None of these
76. A given circle has chord AB of length 4 units, chords BC of length 5 units and chord AC of length
6 units, then area of the circle is
16
(A)
7
32
(B)
7
64
(C)
7
192
(D)
7
77. Number of values of x satisfying the system of equation

 2 
 2x  1 1  x
sin1    cos 
1
  2cos x is
 1 x2   1  x2 
(A) 0
(B) 1
(C) 2
(D) infinite
78. Let P1 : x + y + z = 0, P2 : x + y + 2z = 1, P3 : ax + by + 3z = 1. If P1, P2, P3 have infinite points of

y 1 z 1
intersection, then the value of a + b such that distance of P3 from x  1   is maximum
2 3
is
(A) 3
(B) –3
(C) 6
(D) –6
 
79. If all values of x  (a, b) satisfy the inequality tan x tan 3x + 1 < 0, x   0,  , then maximum
 2
possible value of (b – a) equals

(A)
12

(B)
6

(C)
4

(D)
3
 
80. Let a, b be two non-zero vectors representing points A and B respectively in space. If A and B lie
   
on plane P and any other vector r in plane P can be written as r  a  b (,   R), then
(A) origin cannot lie on P
(B) origin must lie on line AB
(C) origin can lie anywhere on P except on line AB
(D) nothing can be said about location of origin based on given information
SECTION – B
p
81. If letters of the word ‘IITJEE’ are rearranged, then probability that J appears before T is
q
(where p and q are coprime), then the value of p + q is
cos x
82. Let f(x) = max{2 , |sin x|, |cos x|} for x  (0, 2), then the number of critical points of f(x) is
83. Let f(x) = [sin x + [cos x + [tan x + [cot x + [cosec x + [ sec x]]]]]]
       3  
A   y | y  f  x ; x   0,   ; B   y | y  f  x ; x   ,   and I be set of all integers, then
  4     2 4 
n((I – A)  (I – B)) is equal to

3
2022  2023 cosec 2 x 2p  3q  1
84. 

sin2022 x
dx equals 
3r
, then p + q + r is equal to
85. If f(x + f(y)) + f(x – f(y)) = f(x)  x, y  R and (0, 2) lies on y = f(x), then
12 24

0
f  x  dx    f  x  36  dx where  equals
24
86. Number of ways to distribute 5000 similar objects to 100 people P1, P2, ....., P100 such that Pi gets
atleast (i – 1) objects equals n Cr , then maximum value of n + r equals

87. Let L1 : tangent to y = sin x at x = 0, L2 : tangent to y = sin x at x  , L3 : tangent to y = sin x at x
2
= , then area bounded by L1, L2, L3 and y = 0 equals
88. Value of r such that the system of equations |z| = r, |z – 6| = r, z  3  3 3 i  r have a unique
solution is
 esgn x  1  esgn x  1
89. Let m  lim   and n  lim   (where [.] denotes greatest integer function and
x 0  sgn x  x 0  sgn x 
sgn (x) represents signum function), then m – n equals
1 1 1 1
90.     ..... equals
1.2 3.4 5.6 7.8
FIITJEE
FULL TEST – VIII
JEE (Main)-2022
TEST DATE: 06-03-2022

Physics PART – A
SECTION – A
1. A
Sol. Stress at any point at distance h from the top is due to the weight of part
above it
mg
 c (constant) m
r 2 h r
cr 2
m
g dh r + dr
dm
c2rdr
dm 
g
2c
r 2 dh  rdr
g
H R
2c 2 dr
 dh 
0 g R1 r
2c  R2 
H n  
g  R1 
gH
R2 
 e 2c
R1
gH
R1 
 e 2c
R2
AITS-FT-VIII-PCM(Sol.)-JEE(Main)/22 2
2. D
Sol. The disc is in complete equilibrium
F
 f (Rotational equilibrium and translation equilibrium)
2
3 60
F  N  W (Translational equilibrium along vertical direction) W
2 N 30
Also f  N f
F  F 2 
   w
2  2 
 
F
1  3   w
2 
2w
F
1  3
3. D
T  qE qE  T q
Sol.  a
2m m T+qE
T + qE = 2qE  2T
qE
T T
3 a
qkQR kQqR +q
T 
3(R 2  R 2 )3 /2 3(2R2 )3/ 2
kQqR kQq qE
T 
3 2 2  R 3
6 2R 2
 
4. C
dT
Sol.   k  T  TS  also k  TS3
dt
Case I : when TS = 20C  k1 = k
Case II: when TS = 10C  k2 = k/8
50  40  50  40 
k  20  …(i)
5 min  2 
40  30 k  40  30 
   10  …(ii)
t 8 2 
t
From (i) and (ii) 8
5 min
 t = 40 minutes
3 AITS-FT-VIII-PCM(Sol.)-JEE(Main)/22
5. B
Sol. For v to be maximum the line x + y = L must be y
tangent to the circle (0, L)
x 2  (y  R)2  R2

Hence R   
2 1 L    X+Y=L
LBq  R 
Vmax  ( 2  1) (0, R)
m    
(L, 0)
   
Path of particle x
6. A
Sol. Only two value of x are possible
O O
x2
x1
9R
3  3 
3 1   1 3 1   1
2  2 
   
2( )  x1 R 2(9R) x 2 R
x1 = 2R x2 = 3R
x1 + x2 = 5R
7. D
Sol. To reach at point P after collision, velocity of ball just after collision must P
be greater than or equal to 2gh
v
2gh
 speed of ball before collision is greater than or equal to
e h
According to of conservation of mechanical energy
2
1 2 1  2gh 
mv min  mgh  m  
2 2  e 
 1 
vmin  2gh  2  1
e 
8. B
1 2   S  2
Sol.   
2  1000  100   100  S   100S 
 1000  
 100  S 
S  91 
9. C
  (1,1) (1,1)
(1,1)
Sol. W   F  dr   (y 2 dx  2xydy)   d(xy 2 )   xy 2   1 Joule
(0,0)
(0,0) (0,0)
The given force is conservative and work done by this force is some along any path.
10. A
1
Sol. For    x L > xC
LC
Hence I2 leads I1
11. A
Sol. 5k(i1) = 60 V, i1 = 12 mA
240V  i3 10 k = 60 V, i3 = 18 mA
 i2 = 6mA
12. D
Sol. There is no tendency of slipping as acceleration of both the blocks are same in the absence of
friction
f=0N
13. C
RT
Sol. v
M
7RT
v0 
5(2)
mixRT
vmix 
Mmix
n  4   n  32
Mmix   18
2n
2n n n
 
mi x  1  7   5 
  1   1
5  3 
3
  mix 
2
5
v mix  v0
42
14. C
Sol. PT2 = constant
T3
  constant
V
TdV = 3VdT
dV 3
 
VdT T
15. D
Sol. When terminal velocity is acquired, then
fB  fv  W
4 4
 r 3 g  6 rrv T   r 3 g
3 3
vT  r 2
fv  6rv T
Rate at which heat is produced = fV (v T )  6rv T2  r 5
16. C
 fe  110  fo 
fo
Sol.  1  D   100   f 
fe
   e
fe 1

D 10
25
fe  cm  f e = 2.5 cm
10
L = fe + fo (in normal adjustment)
10 cm = 2.5 cm + f o
 f o = 7.5 cm
17. B
Ldi q L C
Sol. V0   (KVL) …(i) i
dt C + 
dq q
Also, i  …(ii)
dt
From (i) and (ii) + 
d2i 1 V0
 i  i  im sin(t)
dt 2 LC
di
At t = 0, L  V0
dt
Lim   V0
V0 V0 C
im    V0
L 1 L
L
LC
8
im  2  103 A  4 mA
2
18. D
 1   1
   
Sol.  3F    C   C = 1 F
2 6
19. B
IeA cos 
Sol. i 4A
hC
20. A
  t  
Sol. I0  cos2 (  1)   
   
SECTION – B
21. 00008.00
1 GmM 1 GmM
Sol. mv 02   mv 2  …(i) (conservation of mechanical energy)
2 5R 2 R
mv 0
5R  mvR …(ii) (conservation of angular momentum about C)
2
from (i) and (ii)
32GM
v0  k=8
105R
22. 00002.00

Sol. (2n  1)  53.8 cm  e e = end correction
4

(2n  3)  75.8 cm  e
4
 n = 2,  = 44 cm  e = 1.2 cm
e = 0.6 r, r = 2 cm
23. 00008.40
gx 2
Sol. y  x tan   sec 2  y
2u2
gL2
h  L tan   2 (1  tan2  )
2u
For h to be maximum h
u
dh 2
 0  u = Lg tan 
d 
(10 2)2 5
 tan  =  x
8(10) 2 L
2
 5  10 8  29 
hmax  8       8.4 m
 2  2 200  4 
24. 00006.00
1
Sol. 
(z  1)2
25. 00006.00
 2 (9)  2 (4)
Sol. 2

(9  r) (4  r)2
 r = 6
26. 00004.00
E0
Sol. Energy in nth orbit =   En
n2
E  E1 15 E0
 n  15 V   15 V
e 16 e
E
Also, E  E2  0  4eV
4
27. 00032.00
Sol. P0V0 = nRT0
1.1P0  1.2V0 = nRT
 T = 1.32 T0
T
% change in T =  100  32 %
T
28. 00000.00
I0
Sol. After passes through 1st Polaroid, intensity of light becomes as it becomes polarised. Now the
2
pass axis of 2nd poloroid is perpendicular to the first, hence the intensity after passes through 2nd
polaroid is zero.
29. 00001.00
Sol. Upper half and lower half has the some focal length.
30. 00001.98
Sol. Applying energy conservation
h  2m0 c 2  E1  E2
3 MeV  2 0.51MeV  E1  E 2
E1 + E2 = 1.98 MeV
SECTION – A
31. D
Sol. O O
HOOC COOH

  3
i O   O O
ii  H2O  H2O2 
HOOC COOH
O O
32. C
Sol. II and III are more stable than I and IV due to complete octet. I is more stable than IV because in
I, more electronegative atom has – ve charge.
33. D
Sol. (A) S   ve because in chain form more rotation is possible in C – C single bond.
(B) Ions have more solvated H2 O than H2 O hence when they form CH3 COOH and H2O,
more H2 O will be free. S  0 .
(C) Solid to gas entropy increases. S  0 .
(D) Two gas molecules are forming one molecule hence S  0 .
34. D
Sol. n  n   
6s 6 0 6
6p 6 1 7
4f 4 3 7
5d 5 2 7
Electrons are filled in increasing order of energy level.
6s  4f  5d  6p
35. C
Sol. O   g  e  O2  g   egH2   ve
It is endothermic process.
36. B
Sol. Cl
Cl
See saw
I
Cl Cl
Cl
Cl
Square planer
I
Cl Cl
Cl
Cl
Square pyramidal
I
Cl Cl Cl
37. B
Sol. OH OH
CHO
 P.C.C.
H2O /H Neutral FeCl3
   test
 positive
OCH3 OH OH
aq. KOH Conc. KOH

Br
CH2OH COOK
.
   CH3Br 
HBr
OH
OH OH
 Cannizaro reaction
38. B
Sol. OH O OK
CHO
KOH
 
CHCl3
CH3 CHCl 2
39. C
Sol. A, B, D are correct statements. Cellulose is a straight chain polysaccharide composed only of
  D  Glucose. units.
40. A
Sol. PV  nRT 1P .m
a
3
 1 Joule 
50  10  1.5  y  R  2000
1
1.5  y  R 
4
1 3 1
1.5  y  y
4R 2 4R
1 3 1  6R
y  
4R 2 4R
41. D
OH NH2
Sol. 3-amino-2-butanol H3C C C CH3

H H
It’s Gauche form is most stable due to hydrogen bonding

H
O
H3C NH2
CH3
H
H
42. D
Sol.   D  glucose  -D-glucose
K eq 
  1.4
 
1
  1.4  1
 
  1
    2.4
1
% of   form   100  41.67
2.4
43. A
Sol. B, C and D are wrong options.
Maximum limit of nitrae is 10 ppm in drinking water.
BOD value would have less than 5 ppm in clean water
44. C
Sol. Pt NH3 4 Br2  Cl2 has 2 geometrical isomers
Pt NH3 4 ClBr  ClBr has 2 geometrical isomers
Pt NH3 4 Br2  Cl2 has 2 geometrical isomers
45. D
Sol. Neoprene and Buna-N are synthetic rubber. Valcanised rubber is rubber which is formed by
natural rubber and sulphur at proper temperature.
46. C
Sol. Melting of ice at 10o C is a non-spontaneous process. Hence, G > 0.
47. A
Sol. NiCl2  aq  Ni2 aq  2Cl  aq 
At Pt cathode reduction will take place
Ni2  2e  Ni  s 
48. C
Sol. (C) is incorrect reaction
4Sn  10HNO3  dil.  4Sn  NO3 2  NH4NO3  3H2O
49. B
Sol. S3O9 is  form of SO3
O O
S
O O
O S S O
O
O O
50. D
Sol. Limonite  Fe2O3 .3H2 O
Zincite  ZnO
Diaspore  Al2O3 .H2O
Siderite  FeCO3
SECTION – B
51. 00001.50
Sol.  COOHn  nKOH  n  COOK   nH2 O
Moles of acid × n = moles of KOH
10 169.5  1
n 
118 1000
n2
n  2 means two – COOH groups are present. Since, no loss of CO 2 take place, it means
– COOH will be separated by carbon atoms.
Mass of left C and H in acid = 118 – 90 = 28
It will be by 2C and 4 hydrogen atoms.
Acid will be HOOC  CH2  CH2  COOH
y6
x4
4 6 3
   1.5
x 4 2
52. 00002.50
Sol. (iv) and (vi) are incorrect.

CH2I2  Zn  CH2  ZnI2

CH3  N  N  CH3  2CH3  N2
a5
b2
a 5
  2.50
b 2
53. 00004.48
(Range 4.46 – 4.50)

Sol. 2NaClO3   2NaCl  3O2
NaCl  AgNO3  AgCl  NaNO3
2 2
Moles of O 2  moles of NaCl  moles of AgCl
3 3
2 2  1.5 
Moles of AgCl  moles of O2    
3 3  32 
2 1.5
Mass of AgCl    143.5 gm
3 32
= 4.484 gm
= 4.48 gm
54. 00002.25
Sol. Correct statements are 4(i, iii, iv and v)
x4
x5 45
  2.25
4 4
55. 00001.50
Sol. C N
OH
CH3
H2N
Only four chiral carbon atoms have hydrogen atoms.
x=6
y=4
56. 00003.20
22
Sol. For He gas PHe  Use P1V1  P2 V2 
5
43
For H2 gas PH2  Use P1V1  P2 V2 
5
4 12 16
Ptotal  PHe  PH2     3.20 atm
5 5 5
Total pressure will be same in both chambers A and B.
57. 00008.55
(Range 8.50 – 8.60)
Sol. Cane sugar  H2 O     Glucose + Fructose
t=0 0.05 mole 0 0
t 0.05-0.05 0.05 0.05
Total moles  0.05  0.05  0.05  0.05
 0.05 1   
Tf  iK f m
 0.05 
0.279  1    1.86   
 500 / 1000 
0.279  5
1      1.5
1.86  0.5
  0.5
Moles of cane sugar left  0.05  0.05
= 0.025
Mass of cane sugar left  342  0.025
= 8.55 gm
58. 00001.50
 100 50  23 21
Sol. Total number of surfactant molecules      6  10  3  10
 1000 1000 
Total area of surfactants  3  1021  a2  67.5 cm2
(a = edge length)
67.5
a2  21
 22.5  1021
3  10
a2  2.25  1020 cm2
a  1.5  1010 cm
a  1.50 Pm
59. 00001.25
Sol. P  V  nb   nRT
For 1 mole V  Vm  5b
P  5b  b   RT
RT
P
4b
PV RT V
 
RT 4b RT
V 5b
Z Z
4b 4b
Z = 1.25
60. 00002.62
Sol. XeF2  Xe   g  F  g   F  g  Hr
Hr  2HXe F  I.E Xe  E.G.E.F 
 2  34  279  85
= 262
SECTION – A
61. A
11!
Sol.  2! 3!  69300
4! 4! 2! 3!
62. A
7 3 11
Sol. g(x) changes sign at , ,
6 2 6
63. B
Sol. f(x) is even, has period 2, range is [0, 1] and symmetric about x = 1
64. D
1
Sol.  tan
1
 xy  d  xy   xy tan1  xy   ln 1  x 2 y 2   c
2
65. C
 1002  1 
Sol. Variance = 4     3333
 12 
66. C
Sol. Can be easily seen from truth table
67. C
Sol. (a, a)  R
if (a, b)  R  (b, a)  R
if (a, b)  R, (b, c)  R  (a, c)  R
68. A
1
Sol. Angle subtended by person at the centre in 5 seconds = radians
2
  1 1 200  1
 h  2  100 cos     tan  30  = sin  
2 2 2 3 4
69. B
1  2x f  x   2x  f 2  x  dx
Sol.  1 2x f  x    x2  f 2  x   2x f  x 
2x  f 2  x 
1
1  2x f  x  1 f  x  1
=   x  f  x  2
dx    x  f  x  2
dx =
x  f  x
c
70. A
Sol. Either m = 1, m = –1 or m = –1, m = 1
71. D
 T1
1  sin
ri 1 6  1
Sol. 
ri  3 ri
1  sin ri+1
6 P 30 Ci
n Ci+1
31
lim
n
 ri  
1 2
i1 1
3
T2
72. D
 2
Sol. Let Q(t) and P  t    –t2 – 2 = –1  t2 = –1
 t
So, point P does not exist
73. A
674 674
Sol. Coefficient of x 674 in 1  x  x 674  x  2   2674
74. B
Sol. Null matrix is the only matrix in set A and set B
75. A
 4
  
Sol. tan x + 3 cot3 x =
sin2   x   tan x  3 and sin2   x   1
3  6   6 
   
 x  n  and  x  n  ; x  n 
3 6 2 3
76. C
abc 456 8
Sol. R  
4 15  7   5  3  7
4     
2  2   2  2 
Area = R2
77. B
–1 –1
Sol. 2 tan x = 2 cos x is only satisfied for one value of x
78. D
Sol. dr’s of normal vector of P3 should be proportional to –1, –1, 1
So, a = b = –3
79. A
cos 2x
Sol. 0
cos x cos3x
 
Now solve using Wavy Curve Method to get x    
6 4
80. C
 
Sol. As any vector in plane can be expressed as linear contribution of a and b
 
 a, b lie in plane and are non-collinear
SECTION – B
81. 00269.00
p 90 90
Sol.  
q 180  1 179
82. 00006.00
Sol. Shown in the figure y=2
cos x
2
1 y = |cos x|
y = |sin x|
0   3 2
2 2
83. 00008.00
Sol. A = {3, 4, 5, ....., } ; B = {....., –7, –6}
84. 04045.50


22022  31012  1
3
2022  2023 cosec 2 x cot x 3
Sol. 
sin 2022
x
dx 
sin 2022
x 

31011.5
6
6
85. 00000.25
Sol. f(0) = 2  f(x + 2) + f(x – 2) = f(x)  f(x) = f(x + 12)
12 24
1

0
f  x  dx 
4  f  x  36 dx
24
86. 00248.00
5000  4950 100 1 149
Sol. Number of ways = C1001 = C99
87. 00002.14
Sol. Bounded area =   1
0  
2
88. 00003.46
Sol. r2 3
89. 00001.00
Sol. m = 1, n = 0
90. 00000.69
1
Sol. Tr  (where r = 1, 2, ......)
 2r  1 2r
1 1
=   S = ln 2
2r  1 2r
FIITJEE
FULL TEST – IX
JEE (Main)-2022
TEST DATE: 03-04-2022
answer.
AITS-FT-IX-PCM-JEE(Main)/22 2
Physics PART – A
SECTION – A
1. A shell of mass m is at rest initially. It explodes into three fragements having masses in the ratio
2 : 2 : 1. The fragements having equal masses fly off along mutually perpendicular directions with
speed v. What will be the speed of the ligher fragment?
(A) v
(B) 2v
(C) 2 2v
(D) 3 2 v
2. In a P–N Junction diode when not connected to any circuit

(A) potential is the same every where.
(B) the P - type side is at a higher potential than the N - type side.
(C) there is an electric field at the junction directed from the N - type side to the P-type side.
(D) there is an electric field at the junction directed from the P - type side to the N-type side.
3. Mark the correct statement

(A) The energy contained in a small volume through which an electromagnetic wave is
passing oscillates with the frequency of the wave.
(B) Magnetic energy has zero average value in a plane electromagnetic wave.
1
(C) Intensity in electromagnetic wave is given by 0E02 c where E0 is maximum electric field.
2
1
(D) Energy density of electromagnetic wave is given by 0E02 c .
2

4. An electric dipole is projected with velocity v in B B
a uniform magnetic field directed inside the
plane of paper as shown. Choose the correct  
v P
option. (dipole is completely inside the field)  
v
P
Case-I Case-II
(A) Dipole will experience a net force in case-I due to external magnetic field
(B) Dipole will experience a net force in case-II due to external magnetic field
(C) Dipole will experience a net torque in case-I due to external magnetic field
(D) Dipole will experience a net torque in case-II due to external magnetic field
3 AITS-FT-IX-PCM-JEE(Main)/22
5. The time variations of signals are given as in A, B and C. Point out the true statement from the
following.
(A) e(volt) (B) e(volt)
1.0 1.0
0 time 0 t(time)
(C) e(volt)
1.0
0 t(time)
(A) A, B and C are analogue signals
(B) A and C digital, but B is analogue signal
(C) A and C are analogue but B is digital signal
(D) A, B and C are digital signal
6. If the P-V diagrams of two thermodynamics devices working in a cyclic process are as shown in
the figure, then:
P P
O (A) V O (B) V
(A) A is a heat engine, B is a heat pump/refrigerator
(B) B is a heat engine, A is a heat pump/refrigerator
(C) both A and B are heat engines
(D) both A and B are heat pumps/refrigerator
7. Figure shows a colour coded carbon resistor. What is the Gold

resistance of this resistor?
(A) 47 × 101 Ω ± 5%
(B) 23 × 101 Ω ± 5%
(C) 47 × 102 Ω ± 5%
(D) 23 × 102 Ω ± 10%
Yellow Brown
Violet
8. Select the correct statement :

(A) Total internal reflection takes place when light travel from rarer to denser medium.
(B) Focal length of a convex lens is positive irrespective of medium in which it is placed.
(C) Focal length of spherical mirror depends on its radius of curvature not on the surrounding
medium.
(D) Blue colour of sky appear due to total internal reflection.
9. A glass hemisphere of radius R and material having refractive

index 1.5 is silvered on its flat face as shown in the figure. A small h
object of height h is located at a distance 2R from surface of
hemisphere. The final image will form :- (Assume paraxial
2R
approximation)
(A) at a distance of R from silvered surface, on right side
(B) on the hemispherical surface
(C) at the plane surface
(D) at a distance of 2R from the curved surface on left side
10. A solid sphere of mass M and radius r slips on a rough A

horizontal plane. At some instant it has translational velocity
 = v 0/2r
v0
v0 and rotational velocity about the centre . The
2r
translational velocity after the sphere starts pure rolling : B r v0
(A) 6v 0 / 7 in forward direction
(B) 6v 0 / 7 in backward direction A
(C) 7v 0 / 6 in forward direction
(D) 7v 0 / 6 in backward direction
11. Which of the following figures best represents the stable equilibrium of a uniform semicircular rod
in vertical plane. It is hinged at point A.
(A) A (B) A
(C) (D) A
12. Two radioactive sources A and B of half lives of 2hr and 4hr respectively, initially contain the
same number of radioactive atoms. At the end of 2 hours, their rates of disintegration are in the
ratio
(A) 4:1
(B) 2:1
(C) 2 :1
(D) 1:1
13. One end of a thermally insulated rod is kept at a T1 1 2 T2

temperature T1 and the other at T2. The rod is composed
of two sections of lengths 1 and 2 and thermal
conductivities K1 and K2 respectively. The temperature at
the interface of the two sections is (cross-sectional area of K1 K2
both rods are same)
(K 2  2 T1  K11T2 )
(A)
(K11  K 2  2 )
(K 2 1T1  K1 2 T2 )
(B)
(K 2 1  K1 2 )
(K1 2 T1  K 2 1T2 )
(C)
(K1 2  K 2 1 )
(K11T1  K 2  2 T2 )
(D)
(K11  K 2  2 )
14. A conducting sphere of radius R and a concentric thick spherical

shell of inner radius 2R and outer radius 3R is shown in figure. A
charge +10Q is given to the shell and inner sphere is earthed. Then 3R
charge on inner sphere is : 2R
(A) –4Q
(B) –10Q R
(C) zero
(D) none of these
15. Two vessels A and B of different shapes have the same base
area and are filled with water up to the same height h as
shown in the figure. The force exerted by water on the base is
FA for vessel A and FB for vessel B. The respective weights of
the water filled in vessels are W A and W B. Then h
(A) FA  FB ; WA  WB
(B) FA  FB ; WA  WB A B
(C) FA  FB ; WA  WB
(D) FA  FB ; WA  WB
16. The graph shows current v/s voltage in a series RLC a.c. voltage
circuit. The arrow indicates the direction that this curve is
drawn as time progresses. In this plot, the
(A) current lags the voltage by about 90 degrees
(B) current leads the voltage by about 90 degrees current
(C) current and voltage are in phase
(D) current and voltage are 180 degrees out of phase
17. When monochromatic light falls normally on the surface of the soap film in air, the intensity of the
reflected light depends on the wavelength: it has a maximum at 1 = 630nm and the minimum at
2 = 525 nm. What can be the film thickness? Refractive index of the film n = 4/3.
(A) 590.625 nm
(B) 640 nm
(C) 562.625 nm
(D) 466.66 nm
18. In a resonance tube experiment, an 80 cm air column is in resonance with a tuning fork in first
overtone. Which equation can represent correct pressure variation in the air column (x = 0 is the
top point of the tube, neglect end correction, speed of sound = 320 m/sec)
 15x 
(A) P0 sin   cos  600t 
 8 
 15x 
(B) P0 cos   sin(600t)
 8 
 15x 
(C) P0 cos   sin(300 t)
 8 
 15x 
(D) P0 sin   sin(600t)
 8 
19. In the circuit, when the voltage between a and c is 1 4

20 V, the voltage between b and d is 10V. When the a b
voltage between b and d is 20 V, what is the voltage R
between a and c?
(A) 4V c 1 4 d
(B) 5V
(C) 8V
(D) 10V
20. In the circuit, the electric (in ampere) current through the battery 2
is ……….
(A) 1
(B) 2.5
(C) 4 8 4
(D) 1.5
4V 4
SECTION – B
21. The acceleration due to gravity (g) at a place is determined by using a simple pendulum of length
 = (100 ± 0.1) cm. If the time period is T = (2 ± 0.01) s. Then maximum percentage error in the
measurement of g.
22. 1000 small mercury (Hg) drops each of the radius r and charge q coalesce together to form one
spherical drop. The potential of the bigger drop is 10n times larger than of the smaller ones then
the value of n is
23. In the following combination of logic gates, the outputs of A, B and C are x, y and z respectively
then the value of x + y + z is
(A) 1 (B) 0
1
y
x 1
0
(C) 1
1
z
1
24. A small block slides along a track with elevated ends and A
a flat central part as shown in the figure. The flat portion D
BC has a length  = 3.0 m. The curved portions of the h
track are frictionless. For the flat part, the coefficient of
kinetic friction is k = 0.20, the particle is released at
point A which is at height h = 1.5 m above the flat part of B E C
the track. The block finally comes to rest. Find its
distance BE where it stops.
25. In the atmosphere of a planet there are only two gases Helium and Oxygen in the mass ratio 1 : 4
C 10K
respectively. The value of   P of the mixture is given by   1  . Find the value of K.
CV 11
26. If the ratio of rms speed of molecules ( = 3/2) and speed of sound in the gas at the same
temperature is x, then find the value of x. ( 2  1.41)
27. A direct current of 2A and an AC of peak value 2A flows through resistances 2 and 1
H 
respectively. Find the ratio of heat  ac  produced in the two resistances in same interval.
 Hdc 
28. The current in a coil of self inductance 2.0 H is increasing according to I = 2 sin(t 2) ampere. Find
the amount of energy (in joule) spent during the period when the current changes from zero to
2A.
29. The difference in angular momentum associated with electron in two successive orbit of hydrogen
xh
atom is . Find the value of x.

30. A small fish, 0.4 m below the surface of lake, is viewed through a simple converging lens of focal
length 3m. The lens is kept at 0.2 m above the water surface such that the fish lies on the optical
axis of the lens. Find the image from optical centre of lens of the fish seen by the observer. The
 4
refractive index of water is   .
3
SECTION – A
31. Which statement is wrong?

(A) White lung cancer is caused by textiles.
(B) Depletion of ozone layer causes skin cancer.
(C) PAN is a secondary pollutant.
(D) London smog is nitrogenous smog.
32. Which of the following type of polymers have the weakest force of interactions?
(A) Thermosetting plastic
(B) Thermoplastic
(C) Elastomers
(D) Fibers
33. Which of the following compounds does not go mutarotation?

(A) Glucose
(B) Sucrose
(C) Ribose
(D) Fructose
34. The major product formed in the following reaction is:

H3C CD3
CH

 
N
H3C O
CH3
(A) H3C CD3
C
+
N
H3C CH3
(B) H3C  CH  CD2
(C) CH3  N  CH2
(D) H2C  CH  CD3
35. The products obtained in the reaction

OH Cl
Conc. NaOH
C C Cl  
 Final products
H Cl
(A) C6H5 CHO and CH2Cl2
(B) C6H5 CHO, HCOONa
(C) PhCH2O Na ,HCOONa 
(D) PhCOONa, PhCH2OH and HCOO Na
36. How can we distinguish the products obtained by acidic hydrolysis of

H
CH3
(II) OCOCH3
(I) C
C H3C C
H2C OCOCH3
H
(A) Fehling’s solution
(B) NaHSO3
(C) Brady’s reagent
(D) Lucas test
37. Which of the following is incorrect?

OH
H excess
 



(I) HO
OH
AgNO2
(II) C2H5I 
 C2H5  O  N  O
Major product 
(III) Benzene > Naphthalene > Anthracene (decreasing order of aromaticity)
Br Br
Br
Br2 /FeBr3
(IV) 
Major 
Br Br
NO2 ClO 4
(V)  
Major 
NO 2
(A) II, IV
(B) I, III, V
(C) I, II, IV
(D) IV, V
38. Number of compounds formed (including stereoisomers)

Cl
h
 Cl2 1 eq 
(A) 4
(B) 5
(C) 6
(D) 7
39. Among KO2 ,AlO2 ,BaO2 and NO2 unpaired electron present in
(A) KO2
(B) NO2 and BaO 2
(C) KO2 and AlO2
(D) BaO2
40. Which is correct among the following?

(A) Li < Na < K < Rb < Cs (according to density)
(B) B < Al < Ga < In < T (according to atomic radii)
(C) BF3  BCl3  BBr3  BI3  acidic nature 
(D) LiF > NaF > KF > RbF> CsF (solubility)
41. Which can be used to distinguish H2 O2 and O3 ?
(A) PbS
(B) Starch and iodine
(C) KMnO 4
(D) Bleaching powder
42. Which of the following are correct?
3
(I) In  CoF6  complex; 0 unpaired electron
(II) NiCl4 2 and Ni  CO4  both are tetrahedral

2
(III) Ni NH3   is a outer complex
 6
(IV) 3 moles of ions are produced by 1 mole of K 2 PtCl6 

(A) II, III, IV
(B) I, II, IV
(C) I, III, IV
(D) I, IV
43. Chemical volcano is produced on heating?
(A) NH4NO3
(B) NH4 2 Cr2O7
(C) NH4NO2
(D) K 2Cr2O7
NH Cl 
44. HgCl2  KI  excess   X 
4
NaOH
 Y; X and Y are:
X Y
(A) HgI2 NH4I
(B) K 2HgI4 NH4 2 HgI4
Hg
(C) K 2HgI4 O NH2I
Hg
Hg
(D) HgI2 O NH2I
Hg
45. Two closed vessel A and B of equal volume containing air at pressure P1 and temperature T1 are
connected to each other through a narrow open tube. If the temperature of one is now maintained
at T1 and other at T2 (where T1 > T2) then what will be the final pressure?
T1
(A)
2P1T2
2P1T2
(B)
T1  T2
2P1T2
(C)
T1  T2
2P1
(D)
T1  T2
46. Which of the following has been arranged in order of decreasing freezing point?
(A) 0.05M NaNO3  0.04 M CaCl2  0.140M glucos e  0.075M ZnSO 4
(B) 0.04M CaCl2  0.140M glucose  0.075 M ZnSO 4  0.05M NaNO3
(C) 0.075M ZnSO4  0.140M glucose  0.04M CaCl2  0.05M NaNO3
(D) 0.075M ZnSO4  0.05M NaNO3  0.14M glucos e  0.04M CaCl2
47. Colloidal solutions of gold prepared by different methods are of different colours because of
(A) different diameters of colloidal gold particles
(B) variable valency of gold
(C) different concentration of gold particles
(D) impurities produced by different methods
48. Which is correct from the followings?
(A) Packing efficiency of FCC is 74%
(B) F-centre crystal is coloured due to excess electron is trapped in tetrahedral voids
(C) When Ge is doped with As, then electrical conductivity decreases.
(D) Bragg’s equation is n  dcos 
49. For a closed container n = 200 mole of an ideal gas fitted with movable, frictionless, weightless
piston operating such that pressure of gas remains constant at 16.42 atm. Which graph
represents correct variation of logV vs logT
(A)
logV
30o
logT
(B)
45o
logV
1
logT
(C)
logT
logV
(D)
logV
45o
logT
50. Which salt from the following is treated with NaOH, produced insoluble hydroxides but soluble in
aqueous NaOH?
(A) FeCl3
(B) HgCl2
(C) ZnSO4
(D) MnSO 4
SECTION – B
51. 3 g sample of peanut oil is mixed to 25 ml of 0.40 M NaOH. After complete saponification, 4 ml of
0.28 M H2 SO4 is added to neutralize excess of NaOH. The saponification number of peanut oil is
[Given : Saponification number is milligrams of NaOH or KOH used by 1 g oil]
52. If radiation corresponds to second line of “Balmer series” of Li2 ion knocked out electron from
first excited state of H-atom then kinetic energy of ejected electron would be in eV?
3
53. The nucleidic ratio of 1H to 11H in a sample of water is 6.0  10 18 : 1. Tritium undergoes decay
with half life period of 12.3 years. If x  106 tritium atoms are present from 10 g of such sample
after 40 years after the original sample collected. [Given: log9.506 = 0.978, Avagadro’s number =
6.022 × 1023].
54. What is the pH at which 1.25  10 4 M Co2  ions in solution precipitate as Co  OH 2 ?
K sp 
of Co OH2 is 2.5  10 16 [Given : log1.414 = 0.1504].
55. Calculate the heat produced (in kJ) when 112 g of CaO is completely converted to CaCO3 by the
reaction with CO2 at 27o C in a container of fixed volume.
Given: Hof CaCO3 ,  s    1207 kJ / mol
Hof CaO,  s    635 kJ / mol
Hof CO2  g   394 kJ / mol
R  8.3 JK 1 mol1
56. 50 ml of 0.1 M CuSO4  aq solution was electrolysed using inert electrodes by passing current till
the pH of the resulting solution was 2. The solution after electrolysis was neutralized and then
reacted with excess KI and formed iodine (I2) titrated with 0.04 M Na2S2O3 . Calculate the
required volume (in ml) of Na2S2O3 .
57. 0.535 g ethanol and acetaldehyde mixture when heated with Fehling’s solution gave 1.2 g of a
red precipitate. What is the percentage of ethanol in the mixture? [At. Wt. of Cu = 63.5 g].
58. In an evacuated vessel of capacity 110 litres, 4 moles of Argon and 5 moles of PCl5 were
introduced and equilibriated at a temperature 250oC. At equilibrium, the total pressure of the
mixture was found to be 4.678 atm. Calculate KP for the reaction
PCl5  PCl3  Cl2 at this temperature.
59. What is the percentage vacant space in one layer of square packing of spheres touching each
other having 4 spheres?
60. The optical rotation of the   form of a pyranose is 150.7o and   form is 52.8o . In solution
an equilibrium mixture of these anomers has an optical rotation of 75.7o . The percentage of the
  form in equilibrium mixture is
SECTION – A
2
 esin x   1 
61.  sin x    cos x  dx  loge  f  x    g  x   c ; where c is constant, then f() – g() is
 e  x   x 
 1
(A)
 1
 1
(B)
 1
 1
(C)

(D) none of these
62. In ABC, a semicircle is inscribed touching sides AC and BC internally and having its extremities
on side AB. If radius of semicircle is 4 and length of angle bisector through C is 8, then C is

(A)
6

(B)
4

(C)
3
5
(D)
12
63. If the number of matrices A  aij 

22
where aij  2,  1, 0, 1, 2 such that a ij  0 is k, then
(A) k = 85 if A is non skew symmetric matrix
(B) k = 80 if A is non skew symmetric matrix
(C) k = 75 if A is non skew symmetric matrix
(D) k = 65 if A is non skew symmetric matrix
  
 tan x ; x 1
64. The number of points in [0, 2] where the function f  x     4  is either
 3x  4  x  ; x  1

discontinuous or non differentiable is/are (where [.] denotes greatest integer function)
(A) 3
(B) 4
(C) 5
(D) 2
65. If the numbers 1, 2, 3, 4, 5, 6 are arranged in a circle, then the probability that the sum of any two
consecutive numbers must not be equal to 7 is
2
(A)
15
1
(B)
5
4
(C)
15
1
(D)
3
  
66. If (cos x cot y – sin x tan y)dy + (cos x ln cos y – sin x ln sin y) dx ; 0  y  . If y    , then
2 2 4
the value of y(0) is

(A)
8

(B)
6

(C)
4
3
(D)
8
 e
67. The area bounded by the curve x = loge y, x = ey – 2, x = e – ey, x = –1 is A  B ln  1   , then
 2
|A + B| is
1
(A) 2
e
1
(B) 2e
e
(C) 2
1
(D)
e
n
r 2  2r  1 103
68. If 
r 1
 r  1!
3
101!
, then the value of n is
(A) 99
(B) 100
(C) 101
(D) 103
69. If the planes x – y – z = 0, x – y + sin  · z = 0 and x + sin  · y – z = 0 pass through a straight

line, then number of values of  in [0, 2021] is/are
(A) 1010
(B) 1011
(C) 2020
(D) 2021
70. Let T be the set of isosceles triangles in which a circle of radius r can be inscribed. If the least
2
perimeter of all such triangles possible in T is 18, then the value of r is
3
(A)
2
(B) 2
(C) 3
(D) 6
71. The mean and standard deviation of the marks of 20 students were found to be 40 and 15
respectively. Later, it was discovered that a score of 60 was wrongly read as 40, then the correct
variance will be
(A) 232
(B) 236
(C) 240
(D) 244
72. Which of the following is a tautology?
(A) p  (p  q)
(B) p  (p  q)
(C) (p  (p  q))  q
(D) q  (p  (p  q))
73. If the pair of straight line x 2 – 2cxy – 7cy2 = 0; c is parameter intersect the parabola y2 = 4x also at
points A and B other than origin, then the locus of the point of intersection of tangents drawn at
points A and B on the parabola y2 = 4x is
(A) 7y + x = 0
(B) 7x + 2y = 0
(C) 7x + 2 = 0
(D) 2x + 7 = 0
x2 y2
74. Let y = 2x be one of the diagonal of a parallelogram inscribed in an ellipse   1; a > b
a2 b2
a2  8
having eccentricity . If the maximum area of parallelogram is 16 2 , then the value of a
a
is
(A) 2 2
(B) 4
(C) 4 2
(D) 8
 cos  
75. If there does not exist any chord drawn from the point  2 2 sin ,  to the circle
 3 
3  x 2  y 2   2 6 sin   cos y which are bisected by x-axis, then
 n 
(A)    , n  ; n  Z
 3 
  
(B)    n  , n   ; n  Z
 3 3
  
(C)    n  , n   ; n  Z
 6 6
  
(D)  n  , n   ; n  Z
 6 2
76. Let the tangent drawn at any point P(t) on the curve y2 = 4ax ; a > 0 having focus at S intersects
the axis at point T. If the locus of the orthocentre of PST intersects y2 = 4ax at points A and B
other than origin, then (AB)2 is
(A) 3a2
(B) 12a2
2
(C) 36a
2
(D) 48a
  
77. The vector a  î  2ˆj  kˆ lying in the plane of the vectors b  î  ˆj and c bisects the angle
    
between b and c . If c  2 , then c  a is
(A) 1
(B) 2
(C) 3
3
(D)
2
78. A tower subtends angles , 2, 3 at points A, B and C respectively all lying on a horizontal line
AB
through the foot of tower. If  1  2 , then  is equal to
BC

(A)
8

(B)
10

(C)
12

(D)
15
79. If R be a relation defined as R = {(x, y) : x + y = p for some rational p; x, y are real numbers}, then
R is
(A) reflexive but not symmetric
(B) reflexive but not transitive
(C) only reflexive
(D) equivalence
2x
80. Let f  x   4  e 4  10  2x  x 3  x 5 and g  x   f 1  x  , then the value of g(50) is
1
(A)
92
1
(B)
2
1
(C)
95
1
(D)
94
SECTION – B
4 3 2
81. One root of the equation x + 2x + ax + bx + c = 0 is tan 15. If all the roots are real and a, b, c
are rational parameter, then minimum value of b – a is
4036 4035 4034
82. The polynomial f(z) = az + bz – cz has real coefficients where a, b, c belongs to (–,
4038]. If f    4032  4038


e 3
i
3 i , then the value of |a – b| is

 1 1 
83. If   4r  1  4r  3   L , then [4L] is (where [.] denotes greatest integer function)
r 0
84. Let a = sin–1 sin 26, b = cos–1 cos 36, c = cos–1 cos(a + b), then the largest integer x for which
|x + 10 – c|  cos–1 cos x is
x5 f  x 
85. Let f(x) be a polynomial satisfying lim  10 , f(2) = 3, f(3) = 7, f(4) = 13, f(–5) = 31, f(–1)
x  x10  10
f  x   x  x2  1
= 3, then lim is
x 5  x  5   x  4   x  3
 2022 x 1 4043
 r 
86. Let f  x  
 2022  x 1
1
, then the value of  f  2022  is
r 1
   5 
87. The number of solution(s) of the equation sin  3x    2cos2  x    1  0 in [0, 2022]
 6  18 
n
88. If  log
r 1
2 r
  1898 (where [.] denotes greatest integer function), then number of zeroes at the
end of n! is/are
89. Let N be the total number of six digits number formed which consists the digit {0, 1, 2, 3} at least
once and whose sum of digits is 10, then the sum of even divisors of N is
10 10 10  k
Ck Ck p
90. If 
k 0  2  k

q
where p and q are coprime, then the value of p + q is
FIITJEE
FULL TEST – IX
JEE (Main)-2022
TEST DATE: 03-04-2022

Physics PART – A
SECTION – A
1. C
Sol. Value of masses after explosion
2m 2m m
, ,
5 5 5
Pi  Pf
2m ˆ 2m ˆ m 
0 vi  vj  v 
5 5 5

| v  | v 5
2. C
Sol. Due to formation of depletion layer electric field is setup from N side to P side.
3. C
1
Sol. Intensity in electromagnetic wave is given by 0E02 c where E0 is maximum electric field.
2
4. C
Sol. Since qnet on dipole = 0  no net force F = qvB F = qvB
F = qvB F = qvB
non zero torque non zero torque
no net force no net force
AITS-FT-IX-PCM(Sol.)-JEE(Main)/22 2
5. C
Sol. As shown, we conclude that A and C are continuous function while B is discrete function.
6. A
Sol. From A : ΔQ > 0, ΔU = 0, ΔW > 0
From B : ΔQ < 0, ΔU = 0, ΔW < 0
7. A
Sol. The number for yellow colour is 4. The number for violet colour is 7. Brown colour gives a
1
multiplier of 10 . Gold indicates a tolerance of 5%. So the resistance of the given resistor is 47 ×
10Ω ± 5%
8. C
Sol. f = R/2
9. D
Sol. Here, three optical phenomena take place first refraction, then =1.5
reflection, and finally refraction.
h
For refraction at first
1.5 1 1.5  1 1.5
    0 v =  2R
v 2R R v
i.e., rays after refraction get parallel to axis and strike the mirror normally, get retraced back and
the final image is formed at the same place where the object is and of the same size. Image
would be real.
10. A
Sol. Angular momentum can be conserved about lowest point A
2 v 2 v
mv0r  mr 2 0  mv r  mr 2  = v 0/2r
5 2r 5 r
10mv 0r  2Mv 0r 7mv r B
 r
10 5 v0
6v F
v  0 A
7
11. B
Sol. Centre of mass ring must be vertically below point A.
12. C
Sol. Let initially they have n atoms
A → the half time two hours
B → the half time four hours
1
After two hours A posses 1 half life and B posses half life
2
n
Remaining atoms of A 
21
n
Remaining atoms of B =
(2)1/2
3 AITS-FT-IX-PCM(Sol.)-JEE(Main)/22
13. C
Ak1(T1  T) k 2 (T  T2 )A
Sol. 
1 2
14. A
KQ KQ1 K(10Q  Q1 )
Sol.   0
R 2R 3R
3Q1  20Q  2Q1  0  Q1  4Q 3R 2R
R
Q1
Q1
10Q+Q1
15. B
Sol. W A > W B as mass of water in A is more than in B
PA = PB
Area of A = Area of B
or PA AreaA = PB AreaB
or FA = FB
16. A
Sol.  Current lags voltage by 90 vmax 0
0 0 Imax Imax
vmax 0
17. A

Sol. Path difference x = 2nt 
2
8 
For maximum t   n
3 2
8  1
t   n   630 …(i)
3  2
8   1
For minimum t   m  
3 2  2
8
t  m(525) …(ii)
3
Equation (i) divided by equation (ii)
1
n
2  2.5
m 3
1
i.e. n   2.5
2
So from (i) t = 590.625
18. A
Sol. At the open end pressure node is present so that
at x = 0 p should be zero and v = f,
3
For first over tone  0.80
4
 f = 300
  = 2f =600 t
 15x 
Hence P = P0 sin   cos(600 t)
 8 
19. A
Sol. Ist Case: i
20
i a 1 4 b
R2
Reading of voltmeter i R V
20V i
V = iR = 10 Volt
20R c 1 4 d
  10  2R  R  2
R2
R = 2
IInd Case: 1 4 b
a
20 i
i1   2 amp R i1 1
442 V i1 20V
Reading of voltmeter
V = i1R = 4 Volt c 1 4 d
20. D
3
Sol. Current through battery is  1.5 ampere.
2
SECTION – B
21. 00001.10
L 42L
Sol. Simple pendulum T  2 g 2
g T
L = 100 cm = 1 m, T = 2 …(i)
Taking log both side in equation (i)
2
ng = n 4 + n   nT
dg d dT
0 2
g  T
% error
dg d dT
 100   100  2  100
g  T
0.1 0.01
=  100  2   100  0.1  1  1.10
100 2
22. 00002.00
4 4
Sol. R3  1000  r 2
3 3
R = 10r
k(1000q)
V
10r
23. 00002.00
Sol. (A) 1 1 0 (B) 0 1
x=1
1
NOT 0 y=1
AND 1
0 NOR 0
(C) 1 0 x=1
1
y=1
NOR 1
z=0 z=0
AND x+y+z=2
24. 00001.50
Sol. An initial mechanical energy of the nlock is mgh and final is zero, so loss in mechanicla energy =
mgh. This mechanical energy is lost in doing work against friction in the flat part,
So, loss in mechanical energy = work done against friction
h 1.5
Or mgh = mgd i.e., d    7.5 m
 0.2
After starging from B, the block will reach C and then will riese up till the remaining KE at C is
convert inot potential energy. It will then again descent and at C will have the same value as it
had when ascending, but now it will move from C to B. The same will be repeated and finally the
block will come to rest at E such that
BC + CB + BE = 7.5
or 3 + 3 + BE = 7.5
ie. BE = 1.5
So, the block comes to rest at the centre of the flat part.
25. 00000.60
n1(4) 1
Sol.   n1  2n2
n2 (32) 4
3  5 
n1  R   n2  R 
Now, Cv  
2   2   11R
n1  n2 6
17
CP  C V  R  R
6
CP 17 6
    1
CV 11 11
26. 00001.41
Sol.  = 3/2
3RT RT V 3
Vrms  , Vsound   rms   2
M M Vsound r
27. 00000.25
Sol. In time t heat produced by a DC current I1 is given by
H1 = I2Rt
 H1 = (2)2 (2)t = 8t
RMS value of AC is given as
i 2
irms  0   2A
2 2
Heat produced by the rms current in time t is given as

2
H2  irms Rt
2
 H2   2 (1)t  2t
H1 8t
  4
H2 2t
28. 00004.00
Sol. The energy stored in a coil of self inductance L when the current changes by 2A is given as
1 1
E  LI2   (2)  (2)2  4J
2 2
This is equal to the amount of energy spent by the source which is supplying the current.
29. 00000.50
nh
Sol. L
2
h nh h h
L(n 1)  Ln  (n  1)    (0.5)
2 2 2 
30. 00000.60
Sol. The apparent position of the object O from
the surface of water is
h 0.4
h    0.3
  4/3
P
The distance PI = 0.3 + 0.2 = 0.5 m
For convex lens, we use 0.2 m
u  0.5m, f  3m A
1 1 1 h
  , we have
v u f 0.4 m
1 1 1
    v =  0.6 m O
v 0.5 3
I
SECTION – A
31. D
H O
Sol. SO 2  O2  SO3 2
 H2 SO4
Composition of London smog is fog of H2 SO4 droplets deposited on carbon particles. So, it is
sulphurous smog.
32. C
Sol. Elastomers – Polymer chains are held together by weak van der Waal’s interaction.
Fibres – These have the strongest force of attraction due to formation of H-bonding or dipole-
dipole interaction.
Force of attraction : Fibre > Plastic > Elastomers.
33. B
Sol. Due to the absence of a free hemiacetal or hemiketal group, sucrose does not exhibit
mutarotation.
34. D
Sol. H D
H
H C C D H3C H
H  C  D
 N O  H2C C CD3
H  N
C O H3C
H CH3
H
C – H bond is weaker than C – D.
35. D
Sol. H
O
O
C CCl 3  OH  C  HCCl3
H H
NaOH
Cannizzaro reaction
O
+
H C O Na
COONa  CH2OH and HCOONa
36. A
Sol. CH3
H3O 
Tautomerism
(I)  C Ketone
H2C OH
O
OH Tautomerism O
(II) 3

H O C
C C
Aldehyde
Aldehyde and Ketone can be distinguished by Fehling’s solution.
37. A
Sol. AgNO2
C2H5I   C2H5NO2
AgNO2 is predominantly covalent in nature.
Br Br Br
Br
Br2
 FeBr3 
Major  Minor 
NO 2
38. D
Sol. Cl
Cl Cl Cl Cl
Cl
Cl Cl
Can't form (1) (2) O.A

(1)
O.I.A O.I.A
Cl
Cl
Cl
(1) (2) CH3
O.I.A O.A
Tn = 7
39. A
Sol. O2  Superoxide   1 unpaired electron
O22   Peroxide   No unpaired electron
O2   No unpaired electron
NO2  No unpaired electron
40. C
Sol. 1. Li < Na > K < Rb < Cs (Due to abnormal increase in size of K).
2. B < Ga < Al < In < Tl (Ga comes after 3d series).
3. Due to back bonding.
4. LiF < NaF < KF < RbF < CsF (Due to lattice energy).
41. C
Sol. KMnO4  H2 SO4  H2O2  MnSO4  K 2SO4  H2O  O 2
KMnO 4  O3  No reaction
42. A
3
Sol. (I) CoF6 
Co 3d6 4so 4po 4do
F is a weak ligand.
Co3
4so 4po
4 unpaired electron sp3 d2
2
(II) NiCl4 
Ni2 3d8 4so 4po 4do
Cl is a weak ligand.
Ni2
3d8 4so 4po
sp3  Tetrahedral
After pairing
3d10 4so 4po
sp3  Tetrahedral
Ni  CO  4 
Ni 3d8 4s2 4po
CO is a strong ligand.
2
(III) Ni NH3  
 6
Ni2 3d8 4so 4po 3do
Ni2
sp3 d2
2
(IV) K 2 PtCl6   2K   PtCl6 
  
1 mol 3 moles
43. B

Sol. (A) NH4NO3   N2O  2H2O

(B) NH4 2 Cr2O7   N2  g  Cr2O3  Volcanic ash   4H2O

(C) NH4NO2   N2  2H2 O

(D) 4K 2Cr2O7   4K 2CrO 4  2Cr2O3  3O2
44. C
Hg
KI NaOH
Sol. HgCl2  KI  excess  
KCl
 HgI2   K 2HgI4  
NH Cl
 O NH2I
4
 Orange   Soluble  Hg
Brown ppt.
45. B
Sol. Final P is same in both which is different from initial T1 > T2.
Let initial P = P1
Final P = P2
x is number of moles transfereed from A to B
P2 V   n  x  RT1, P2 V  n  x  RT2
 n  x  RT1   n  x  RT2
nT1  T1x  nT2  xT2
 n  T1  T2   x  T2  T1 
n  T1  T2 
x
T1  T2
nRT1
V
P1
nRT1  n  T1  T2  
P2   n   RT1
P1  T1  T2 

 n  T1  T2   n  T1  T2   P1
P2   
 T1  T2  n
 nT  nT2  nT1  nT2  P1
P2   1 
 T1  T2 n
2nT2 P1
P2  .
T1  T2 n
2P1T2
P2 
T1  T2
46. A
Sol. Tf  i  K f  m
Tf  Number of particles
NaNO3  0.10
CaCl2  0.12
Glucose  0.140
ZnSO4  0.150
Tf  ZnSO 4  Glucose>CaCl2  NaNO3
Tf  ZnSO 4  Glucose<CaCl2  NaNO3
47. A
Sol. Colour of colloidal solution depends upon the size of the colloidal particles.
48. A
4 3
4 r
Sol. (A) Packing efficiency in FCC =  3  100  74%
a3
(B) Electrons are present in anion vacancies.
(C) When Ge is doped with As , then 5th electron of As is free which increases electrical
conductivity rapidly.
(D) Bragg’s equation is n  2dsin  .
49. D
nRT 200  0.0821 T
Sol. V 
P 16.42
logV = logT
50. C
Sol. (A) FeCl3  NaOH  Fe  OH3  NaCl
Re d ppt.
Insoluble 
(B) HgCl2  NaOH  Hg  OH2   NaCl
unstable

HgO  H2O
 Yellow 
(C)  ZnSo  NaOH  Zn  OH  Na SO

4 2 4
 2
 White

  insoluble 

 Zn  OH 2  NaOH  Na2 ZnO2  H2O

  Soluble 
(D) MnSO4  NaOH  Mn  OH2  Na2SO 4
Buff coloured ppt.
 insoluble 
SECTION – B
51. 00103.47
Sol. Saponification number is milligram of KOH or NaOH consumed by 1 g oil.
Equivalent of NaOH used by oil   25  0.40  4  0.28  2  10 3
 7.76  10 3
Moles of NaOH  7.76  10 3
 Mass of NaOH  7.76  103  40  103 mg
= 310.4 mg
310.4
 Saponification 
3
= 103.46666
= 103.47
52. 00019.55
1 1
Sol. EPhoton  13.6   32  2  2 
2 4 
27
 13.6 
16
1 1 
Energy required to remove electron from n = 2 in H-atom  13.6  12    2 
4  
13.6

4
27 13.6
 Kinetic energy of ejected electron  13.6  
16 4
13.6  27  13.6  23 
  1   
4  4  4  4 
= 19.55 eV
53. 00000.422
Sol. 18g H2 O  6.022  1023  2 atoms of H
18g H2 O has 13H atoms  6  1018  6.022  10 23  2
6  10 18  6.022  1023  2  10
 10g H2O has 13H atoms 
18
 2.0073  2  106
 4.0146  106
0.693 2.303 4.015  106
 log
12.3 40 N
4.015  106 0.693  40
log 
N 12.3  2.303
= 0.978
4.015  106
 9.506
N
4.015  106
N  0.422  106
9.506
54. 00008.15
2
Sol. K sp Co  OH2   Co2  OH   2.5  10 16
2
1.25  104  OH   2.5  10 16
2 2.5  10 16
OH  
  4
 2  1012
1.25  10
OH   1.414  106
 
pOH   log1.414  106
 6  0.1504
= 5.8496
 5.85
 pH  14  5.85  8.15
55. 00351.02
Sol. CaO  s   CO2  g  CaCO3  s 
Hro  Hof  CaCO3 ,s   Hof  CaO,s   Hof  CO2  g  
 1207  635  394
 178 kJ / mol
E  H  ngRT
 1  8.3  300
 178 
1000
 178  2.49
 175.51 kJ
112
nCaO  2
56
qV  n.E  2   175.51
 351.02 kJ
56. 00118.75
Sol. Initial milli moles of Cu2  50  0.1  5
Meq or m moles of H+ produced  50  102  0.5
0.5
 m moles of Cu2 converted into Cu   0.25
2
m moles of Cu2 left in solution = 5 – 0.25 = 4.75
2Cu2  4I  Cu2I2  I2

I2  2Na2S2O3  2NaI  Na2S4 O6
m moles of Cu2 left  m moles of Na2S 2O3
4.75  V  0.04
4.75
V  118.75 ml
0.04
= 118.75
57. 00031.02
Sol. WC2H5OH  WCH3 CHO  0.535 g
Let x g of C2H5OH and y g of CH3CHO in the mixture
x  y  0.535 g
CH3 CHO  2CuO  CH3 COOH  Cu2 O
44 g 79.6  2 63.5  2  16
Molecular mass of CuO = 63.5 + 16 = 79.6
143 g of Cu2O is produced by 44 g
44
1.2 g Cu2O is produced by  1.2
143
= 0.369
 WC2H5 OH  0.535  0.369  0.166
0.166
% of C2H5OH   100  31.02
0.535
58. 00001.75
(Range : 1.72 – 1.75)
Sol. PCl5  g  PCl3  g   Cl2  g 
5 0 0
5x x x
Total number of moles = 5 – x + x + x + 4= 5 + x + 4 = 9 + x
PV 4.678  110
ntotal    11.984
RT 0.0821 523
 12
x  11.984  9  2.984  3
2
 3 
  4.678 
 12   1.754
KP 
 2 
  4.678 
 12 
59. 00047.60
(Range : 47.60 – 47.70)
Sol. 4R
Volume = 4R  4R  2R
 32R3
4 3
Volume of 4 spheres  4  R
2R 3
16 R3
% vacant space  100  100 
3  32R3
22
With ,   With,   3.14
7
 22  
 100  1    100  100 
 76  6
 22   
 100  1    100  1  
 42   6
 11   100 1  0.523 
 100  1  
 21  = 47.7%
 21  11  Range : 47.6 to 47.7
 100  
 21 
10
 100 
21
= 47.62%
60. 00023.39
Sol. 150.7  X   52.8 1  X   75.7
 150.7X  52.8  52.8X  75.7
 97.9X  22.9
 X  22.9  97.9  0.23391
= 0.23391
% of X =23.39%
SECTION – A
61. B
Sol. Put 1  xe sin x  t
62. C
1 1 C
Sol. r a  b   ab sinC
2 2
ab 2ab C b x a
r sinC ; x  cos
ab ab 2
r r
C C
2sin cos
r
 2 2  8  sin C  1  C  
A O B
x C 2 2 3
2cos
2
63. B
11
Sol. Total number of matrices = C3  46 C3  85
Number of skew symmetric matrix  aii  0  , aij  i  j  1,  2, 0
64. A
Sol. Use graph
65. C
2 4
Sol. n  EC   3 C1 4! 2!  3C2 3!  2!  3 C3  2!   88
88 4
 P(E) = 1 – P(EC) = 1 – 
120 15
66. C
Sol. cos x d(ln sin y) + ln sin y d(cos x) + sin x d(ln cos y) + ln cos y d(sin x) = 0
 d(cos x ln sin y) + d(sin x ln cos y) = 0  cos x ln (sin y) + sin x ln (cos y) = C
1 1 
C  ln . Also, ln(sin y) = ln  y
2 2 4
67. D
 e 2 e 2
0 2 e 2
1
 e  ln  x  2   dx   ln  e  x   ln  x  2   dx
x
Sol.
1

0
= 1 
e e 2 
ln t dt  
1
ln t dt
1 e2 1 e2
1   e  1  ln    2  e    e  2  ln  
e  2  e  2 
68. B
r  r  1  r  1  r  r  1  1
Sol.  
 r  1!  r  1! r  1!
r  r  1  r 1 r  2 
Tr    2  
r !  r  1 !  r  1!  r  2 ! 
n
 n3 
T
r 1
r  3 
  n  1 ! 
69. A
Sol. x – y + sin  · z + (x – y – z) = 0 ..... (1)
x + sin  · y – z = 0
1     1 sin   
  
1 sin  1
 sin  = –1
70. C
   A
Sol. P  r  4 cot  2 tan   90 – 
 2 
dp
0 D r F
d
 1   I
 tan  ; 
2 3 3 2
B E C
 Pmin  6 3 r
71. D
800  40  60
Sol. Corrected mean =  41
20
2
2
Incorrect SD =
x i

 
 x 
i
20  n 
  xi2  20  225  1600   36500
 Corrected sum = 36500 – 402 + 602 = 38500
38500 2
 Variance =   41 = 1925 – 1681 = 244
20
72. C
Sol. Use truth table
73. A
Sol. Equation of AB is yk = 2(x + h) A
Combined equation of OA and OB is given by
 yk  2x  P(h, k)
y 2  4x   O
 2h 
2 2
i.e., 4x + hy – 2kxy = 0 ..... (1)
x2 – 7cy2 – 2cxy = 0 ..... (2)
B
4 h 2k x
   locus of P is y  
1 7c 2c 7
74. B
b2 8
Sol. 1 2
 1  b2 = 8
a a2
2 2a
Area of parallelogram = 2a cos   2 2 sin  
a2  2
A max  4 2a  16 2  a = 4
75. C
cos2 
Sol. If (h, 0) be the mid-point of chord, then h2  3 2 sin  h  4 sin2   0
6
1
For non real root D < 0  tan2  
3
76. D
Sol. y – 0 = t(x – a) ..... (1) P(t)
x = at2 ..... (2)
2
 y  x
Locus of orthocentre is   
 x  1  a
2 2 T S
 x(x – a) = ay
For intersection x(x – a)2 = a · 4ax
 x = 0, 3a
Point of intersection  3a,  2 3 a 
77. C
ˆ ˆ  ˆ
Sol. î  2ˆj  kˆ    i  j  cˆ   ĉ   1  1  î   2  1  ˆj  k
    
 2   2  2
 ˆ ˆ
   2  c  jk
78. A
AB
Sol.  1  2cos2
BC
79. D
p
Sol. x+x=p x ; x + y = p  y + x = p ; x + y = p, y + z = p, then x + z = p
2
80. C
1
Sol. g  50  
f  2
SECTION – B
81. 00004.00
Sol. Given polynomial is (x2 – 4x + 1)(x2 – x + ) where  = –2 and  = a + 7, b = 2 – 4 = –26 – 4a
2
 Roots are real   
4
 a + 7  1  a  – 6 and b  –2
82. 00006.00
Sol.    a  c    b  c ;    1  i 3
f e

i
3
2
 1 i 3
 a  c       b  c  4038 3 i  4032
 2 2 
ca
 a + c = 8076 ;    b  4032
 2 
 a = c = 4038 and b = 4032
83. 00003.00
  1 1
dt 
Sol.   t 4r 1  t 2  dt   1  t 
2

 r 0 0
 0
1  t4  
84. 00015.00
Sol. a = sin–1 sin(8 + 26 – 8) = 26 – 8 |x– 4|
–1 –1
b = cos cos 36 = cos cos(12 – (12 – 36) = 12 – 36
c = cos cos(a + b) = cos–1 cos(4 – 10) = 4 – 10
–1
 |x – 4|  cos–1 cos x

 x  15 O 2 3 4 5
85. 10080.00
2
Sol. f(x) = 10(x + 1)(x + 5)(x – 2)(x – 3)(x – 4) + x – x + 1
86. 02021.50
Sol. f(x) + f(2 – x) = 1
87. 01011.00
   5 
Sol. sin  3x    cos  2x    2
 6  9 
   5 
 sin  3x    1 and cos  2x    1
 6  9 
11
 x  2n  ;n Z
9
88. 00074.00
7
k 8
Sol. k  2
k 0
 1538  1538 + 8(n – 2 + 1) = 1898
 n = 300  Number of zeroes = exponent of 5 in 300! = 74
89. 01524.00
5  5! 5! 
Sol. C1     5 C2 4!  640
 2! 3! 
90. 00191.00
10 10 10 k
Ck C10
Sol. 
k 0  2 k

10 10 1  x 11 10 1  x 12 1  x 20 
Coefficient of x in  10 C0 1  x   10 C1  C2  .....  10
C10 
 2 22 210 
Coefficient of x10 in
 2 3 10 
1  x 10  10 C0  10C1  1  x   10 C2  1  x   10 C3  1  x   .....  10 C10  1  x  
  2   2   2   2  
10
10 10   1 x  
Coefficient of x in 1  x   1   
  2 
10 1  x 2 10 10
C5 252 63
Coefficient of x in 10
 10
 
2 2 1024 128
FIITJEE
FULL TEST – X
JEE (Main)-2022
TEST DATE: 10-04-2022
answer.
XXXXX.XX and each question carries +4 marks for correct answer and –1 mark for wrong answer.
AITS-FT-X-PCM-JEE(Main)/22 2
Physics PART – A
SECTION – A
1. The true value of angle of dip at place is 60, the apparent dip in a plane inclined at an angle of
30 with magnetic meridian at this place is
 1
(A) tan1  
2
1
(B) tan  2
2
(C) tan1  
3
(D) none of these
2. In the figure shown, A & B are free to move.

All the surfaces are smooth. then : (0 <  < 90º) A
(A) the acceleration of A will be more than g sin
(B) the acceleration of A will be less than g sin 
(C) normal force on A due to B will be more than mg cos  B
(D) normal force on A due to B will be equal to mg cos 

3. Identify the logic operation performed by the

A
circuit given below
(A) NOT A
(B) AND
B y
(C) OR
(D) NAND B
4. If the voltage between the terminals A and B is 17 V I

and zener breakdown voltage is 9V, then the potential
A R
voltage across R is
(A) 6V
(B) 8V
(C) 9V 2R
(D) 17V
5. The plates S and T of an uncharged parallel plate S T k

capacitor are connected across battery. The battery is
then disconnected and the charged plates are now
connected in a system as shown in the figure. The
system shown is in equilibrium. All the strings are
insulating and massless. The magnitude of charge on m
one of the capacitor plates is: [ Area of plates = A ]
(A) 2mgA0
3 AITS-FT-X-PCM-JEE(Main)/22
4mgA0
(B)
k
(C) mgA 0
2mgA0
(D)
k
6. The graph represents the decay of a newly prepared

sample of radioactive nuclide X to a stable nuclide Y. The Number Y
half-life of X is . The growth curve for Y intersects the of atom X
decay curve for X after time T. The time T is

(A)
2

(B) n  
2
0 T time
(C) 
(D) 2
7. Moment of inertia of a uniform solid hemi-sphere about given IB

axis is IA and IB then:
(A) IA > IB
(B) IA = IB
(C) IA < IB IA
(D) Can’t be predicted
8. A hydrogen atom at rest emits a photon during its transition from n = 2 to n = 1. Choose the
incorrect statement.
(A) De-Broglie wavelength of hydrogen atom during recoil will be same as wavelength
of emitted photon.
(B) Energy of emitted photon will be less than 10.2 eV
(C) Kinetic energy of recoil H-atom will be less than 10.2 eV
(D) Kinetic energy of recoil H-atom will be equal to energy of emitted photon.
9. A monoatomic gas is undergoes a process T*P(-1/3) = constant. If heat is given to the gas during
the process, then:
(A) Its temperature remains constant
(B) Its temperature will increase
(C) Its temperature will decrease
(D) Cann't be predicted
10. An object is placed at a point, which is at a

distance x from the focus of a convex lens
and its image is formed at I, which is at a
distance x’ from the focus f’ (as shown in the O
f f
figure), The distance x and x' satisfy the x x I
relation
x x'
(A) f
2
(B) f  xx '
(C) x  x '  2f
(D) x  x '  2f
11. An air bubble of diameter 2 mm rises steadily through a solution of density 1750 kg/m 3 at the
rate of 0.35 cm/s. The coefficient of viscosity of the solution is nearly (Assume mass of the
bubble to be negligible)
(A) 9 poise
(B) 6 poise
(C) 11 poise
(D) 4 poise
12. A metallic cylinder of radius r and height h is totally

submerged in a liquid contained in a beaker as shown in the
figure. If a force F is applied on the string to pull the cylinder
with a constant velocity v, the graph showing the variation of
force F against displacement of cylinder is best represented
by
(A) F (B) F
S S
(C) F (D) F
S S
13. In a YDSE experiment the primary source S (which is far away Screen
from the slits) is moved towards slits symmetrically and slowly.
As a result d
(A) Fringe width increases O
S
(B) Fringe width decreases
(C) Positions of maximas remains the same.
(D) Intensity of fringes decreases. D
14. The given graph illustrates a transverse wave travelling on a string at a particular instant, and the
points P, Q, R and S represent elements of the string. Which of the following statements about
the motion of the elements is correct?
displacement
P S
Q
distance along the
string
R
(A) The speed of the element at P is a maximum

(B) The displacement of the element at Q is always zero
(C) The energy of the element at R is entirely kinetic
(D) The magnitude of acceleration of the element at S is maximum.
15. A tunnel is dug along the diameter of the earth. The time
period of oscillation of a body dropped (from surface) in the
tunnel is T1. If T2 is the time period of similar body dropped
(from surface) in a straight tunnel dug along any chord except T1
through the centre of the earth, then T2
(A) T2 < T1
(B) T2 = T1
(C) T2 > T1
(D) any of A, B or C
16. Suppose we consider a large number of containers each containing initially 10000 atoms of a
radioactive substance with a half life of 1 year. After 1 year
(A) all the containers will have 5000 atoms of the material,
(B) all the containers will contain the same number of atoms of the material but that number
will only be approximately 5000.
(C) the containers will in general have different numbers of the atoms of the material but their
average will be close to 5000.
(D) none of the containers can have more than 5000 atoms.
17. A uniform cylinder of mass M and radius R is to be F

pulled over a step of height a (a < R) by applying a force
F at its centre ‘O’ perpendicular to the plane through the
axes of the cylinder on the edge of the step (see figure).
The minimum value of F required is:
O
R
a
a2
(A) Mg 1 
R2
2
 R 
(B) Mg   1
Ra
a
(C) Mg
R
2
Ra
(D) Mg 1   
 R 
3
18. The heat capacity C of a certain solid is related to its temperature T by the equation C = aT ,
where a is a constant characteristic of the solid. Heat is supplied to the solid at a steady rate.
Which graph best represents the variation of its temperature T with time t?
(A) T (B) T
O t O t
(C) T (D) T
O t O t
19. Two point masses, each of mass M are placed at (L, 0) and (L, 0). A third equal point mass M, is
2 2 2
uniformly rotating on the circle x + y = L . Equation of path traced by COM of system of these 3
point masses is
(A) x 2  y 2  L2
L2
(B) x2  y2 
3
(C) x=y=0
L2
(D) x2  y2 
9
20. If a proton is moving along the +ve x-axis at a speed v (small compared to speed of light), then
find the magnetic field at (aiˆ  bj)
ˆ , when the proton is at origin. Take charge on proton as q.
0 qva
(A) ĵ
4(a2  b2 )
0 qva
(B) k̂
4(a2  b2 )3/2
0 qva
(C)  k̂
4(a2  b2 )3 /2
0 qva
(D) k̂
4(a2  b2 )
SECTION – B
st
21. A string of length 1m fixed at both ends is vibrating in 1 overtone. Tension in string is 200 N and
linear mass density is 5 gm/m. Frequency (in Hz) of these vibrations is :
22. A conducting rod of mass m and of negligible resistance A

and length 0.5 m slides on a pair of parallel metallic rails,
which are connected by a resistance R= 10 ohm and
capacitance C= 1μF as shown in the figure. A magnetic R B
field B= 1 T is applied normal and into the plane of the F C
circuit. At t=0, a force F=0.4 N is applied on the rod AB.
The terminal speed (in m/s) acquired by the rod will be
B
23. When the voltage applied to an X-ray tube is increased from V1= 15.5 kV to V2 = 31 kV, the
wavelength interval between the Kα line and the cutoff wavelength of the continuous X-ray
22
spectrum increases by a factor of . If the atomic number of the element of the target is Z, the
19
value of Z is (Take hc= 1240 eV-nm, Rydberg const= 107 m-1)
2 3
24. A cylindrical block of wood of base area 30 cm , floats in a liquid of density 900 kg/m . The block
is depressed slightly and then released. The time period of the resulting oscillations of the block is
equal to that of spring with block of same mass, then spring constant of this spring is equal to:
(take g = 10 m/s2)
25. The current gain of a common emitter amplifier is 99. If the emitter current is 12 mA, then
collector current in mA is
26. An unpolarized light of intensity 128 W/m2 passes through three polarizers namely P1, P2 and P3
arranged one after the other such that P1 is 1st, P2 is 2nd and P3 is last. The transmission axis of
P3 is parallel to that of P1. The intensity of light detected through the last polarizer is found to be 4
W/m2, then angle between the polarization axis of P2 and P3 in degrees is
27. A vernier caliper (Non standard) is constructed which has one main scale division of length 1 mm
and 20 vernier scale divisions measure 18 mm. In an experiment, zero of vernier scale lies
between 0.4 and 0.5 cm on main scale and 2nd division of vernier scale coincides with a main
scale division (when jaws of vernier are in closed position). When a cylinder whose diameter is to
be measured is kept between the jaws of vernier caliper, the zero of vernier scale lies between
2.4 and 2.5 cm on main scale and 12th division of vernier scale coincide with a main scale
division. The diameter of cylinder in cm is
28. A parallel plate air capacitor has a capacitance C (figure-1).

When it is half filled with a dielectric of dielectric constant 2
(figure-2), the percentage increase in the capacitance will be
k=2
C
Figure-1 Figure-2
29. A block and a sphere of equal mass m are placed on an inclined

plane. If the maximum frictional force that can exist between the
block and the plane is equal to the weight of the block, and there
is no frictional force between the sphere and the plane, what is
the maximum angle  at which the plane can be inclined before
the block starts to slip (in degrees) is 
30. The amplitude of a damped harmonic oscillator become half in 3 second and will become 1/x of
the initial amplitude in next 6 second where x is :-
SECTION – A
31. When intermolecular attractive forces are neglected, isobar formed between V and T at constant
p is of the type

  tan1 0.1642


V dm 3

0.20 dm3 mol1
O
T K  
Pressure at which isobar is made,
(A) 2 atm
(B) 0.5 atm
(C) 1 atm
(D) 4 atm
32. Which of the following on the addition will not cause deep red colour to disappear?
2
Fe3  aq  SCN  aq  Fe  SCN    aq
Pale yellow Colourless Deep red
(A) AgNO3
(B) HgCl2
(C) H2 O
(D) H2C2O 4
33. For the calomel half-cell, Hg,Hg2Cl2 | Cl  aq values of electrode potentials are plotted at different
log Cl  . Variation is represented by
(A)
E

O log Cl 
(B)
E

(C)
E

(D)
E

34. K a of HCN and CH3COOH are respectively 4.5  10 10 and 1.5  105 at 298 K. Thus, equilibrium
constant for CN  CH3COOH  CH3 COO  HCN would be
(A) 3.1 105
(B) 3.2  105
(C) 3.3  104
(D) 3.3  104
35. Which of the following set of species have planar structures?


(A) I3 ,CH3 ,ClO3 ,SiF62 I
(B) I3 ,ICl4 , Al2Cl6 ,TeCl4
(C) SCl2 ,N2 O5 ,SF4 , XeOF4
(D) I2Cl6 , XeF2 ,BrF4 , XeF5
36. XCl2  excess   YCl2  XCl4  Y ;

 1
YO 
 400o
O 2  Y; Ore of Y would be:
2
(A) Siderite
(B) Cinnabar
(C) Malachite
(D) Hornsilver
37. Nitrogen dioxide cannot be obtained from:

(A) Cu  NO3 2
(B) Hg  NO3 2
(C) NaNO3
(D) AgNO3
38. Calcium imide on hydrolysis gives gas (B) which on oxidation by bleaching powder gives gas (C).
Gas (C) on reaction with magnesium give compound (D) which on hydrolysis gives again gas (B).
Identify (B), (C) and (D)?
(A) NH3 ,N2 ,Mg3N2
(B) N2 ,NH3 ,MgNH
(C) N2 ,N2 O5 ,Mg NO3  2
(D) NH3 ,NO2 ,Mg NO2 2
39. Select the correct statement about silicates:

(A) Cyclic silicate having three Si atoms contains six Si – O – Si linkages
1
(B) 3 over oxygen atoms of per tetrahedron unit are shared in double chain silicate
2
(C)  Si2 O5 n2n  is formula of double chain silicate
(D) SiO44 units polymerize to form silicate because Si atom has less tendency to form
  bond with oxygen
40. Which is not true regarding nylons?

(A) Usually a high melting solid polymer
(B) Possesses a very high degree of crystallinity
(C) Nylons are usually hydrophobic
(D) Nylons have very high mechanical strength
41. What is the most likely product form the following reaction?

EtONa H /H2 O
CH2  COOC2H5  2  Br  CH2  2 Br 
EtOH



(A) COOC2H5
(B) (COOC2H5)2
(C) COOH
COOH
(D) COOH
42. An ester (A) with molecular formula C9H10 O2 was treated with excess of CH3MgBr and the
complex so formed, was treated with H2 SO4 to give an olefin (B) whose ozonolysis gave a
ketone with molecular formula C8H8 O which shows positive iodoform test. The structure of (A) is
(A) C6H5 COOC2H5
(B) C2H5COOC6H5
(C) C6H5 CH2COOC2H5
(D) p H3OC COCH3
43. O
O
H3C C H 
C C OH  A
H3C H
The product (A) in given reaction would be:
(A) O O
C C
H3C C OH
H CH3
(B) O OH
C
O
C H
H3C
CH3
(C) O
H
H3C C
C H
CH3
(D) O
HO
C H
C C
H3C CH3
44. What is the principal product of the following reaction?

CH2 CH O
NaOH

Ethanol, water, 
 H2 O  ?
CH2 CH O
(A) CH O
CH O
(B) CH O
(C) OH
OH
(D) O
O
 ||
45. This structure of glycine (amino acid) is H3 NCH2 C O (Zwitter ion). Select the correct statement
of the following?
(A) Glycine, as well as other amino acids are amphoteric.

(B) The acidic functional group in amino acids is  NH3 .
(C) The basic functional group in amino acids is CO2 .
(D) All the statements are correct.
46. Select the incorrect statements about SO2 :

(A) It acts as oxidant and reductant both
(B) It acts as bleaching agent but bleaching action is temporary
(C) Its bleaching action is weak and that too by nascent H-atom
(D) It bleaching action is due to oxidation of coloured matter in presence of moisture
47. What is the major product of the following reaction?

O
o
10% NaOH, H2O/ /100 C
  
O O
(A) O
O
(B) O
(C) O
O
(D) O
48. Hydrogen peroxide in its reaction with KIO4 and NH2OH respectively, is acting as a
(A) reducing agent, oxidizing agent
(B) reducing agent, reducing agent
(C) oxidizing agent, oxidizing agent
(D) oxidizing agent, reducing agent
49. The reaction of white phosphorous with aqueous NaOH gives phosphine along with another
phosphorous containing compound. The reaction type; the oxidation states of phosphorous in
phosphine and the other product are respectively
(A) redox reaction; – 3 and – 5
(B) redox reaction; + 3 and + 5
(C) disproportionation reaction; – 3 and + 1
(D) disproportionation reaction; – 3 and + 3
50. Select the incorrect statements

(A) Nitropentaammine chromium III chloride shows ionization isomerism
(B) Among silver halides and calcium halides only AgF and CaF2 are water soluble
(C) In Fe  CO 5 , the Fe – C bond possesses both  and   character
(D) Cu and ethylene diamine gives a chelate compound due to multiple denticity
SECTION – B
51. The freezing point of an aqueous saturated solution of I2 is 0.0024o C . More than this can
dissolve in a KI solution because of the following equilibrium
I2  aq  I  aq  I3  aq
0.1 M KI solution dissolves 12.5 g L1 of I2 . Calculate the equilibrium constant K C for the above
equilibrium. Assume molarity to be equal to molality and also assume that concentration of I in all

saturated solutions is same. K t of water is 1.86 K molal1. 
52. Mosely equation is represented as v  a  Z  b  , where a and b are constant. If OA = 1,

calculate nuclear charge Z and 400 Hz. When frequency is 400 Hz
45o
O A Z
53. How many of the following species show paramagnetism?

Na ,O 2 ,Cu2 ,Fe2  ,Zn2 ,Cr 3  ,Cu ,O2 ,O22
54. An ideal solution is made up of volatile liquids A and B for which

poA  125 Torr and pBo  46.3 Torr As the pressure is reduced, first vapour is observed at 70.0
Torr. Calculate X A .
55. Rate constant of decomposition of H2 O2 to H2O and O2 is 0.0693 min1 . Calculate volume of O 2
(in litres) obtained from the decomposition of 1.00 mole of H2O2 at 760 mm Hg and 293 K after
20.0 minutes.
x
56. Graph between log   and log p is a straight line inclined at an angle of 45o and log k = 0.6990
m
x
for Freundlich’s adsorption isotherm,   is the amount of adsorbate adsorbed per gram of the
m
x
adsorbent. What is the value of   at 0.80 atm?
m
57. Consider the following complex compounds

(I) Pt NH3 2  SCN2  (II) Co  NH3   NO2  
 3 3

(III) Pt  en  Cl2  (IV) Cr  en  Br2 
 2 
3 2
(V) Rh  en 3  (VI) CoCl2Br2 
Then calculate sum of total number of geometrical isomers in all above complex compounds.
58. 10 g of a mixture of hexane and ethanol are reacted with sodium to give 200 ml hydrogen at
27o C and 760 mm pressure. What is the percentage of ethanol into the mixture?
59. The mass adsorbed per g of adsorbed O2 having pressure 10 atm at 400 K, if placed in contact
with solid surface of 2 g in one litre vessel. The pressure of O2 after adsorption becomes 2 atm.
-1 -1
Assume no change in temperature and R = 0.08 litre atm K mol .
60. How many enol tautomers (including stereo isomers) can you draw for the following diketone?
O O
SECTION – A
1
61. If  is only real root of the equation x 3 + cos1x2 + sin1x + 1 = 0, then tan1   tan1 is equal to

(A) 0

(B)
2

(C) 
2
(D) 
62. f(x) is a polynomial of degree 4, f(1) = f(2) = f(3) = f(4) = 0, then root of f(x) = 0 is
5
(A)
11
5
(B) 
11
11
(C)
5
11
(D) 
5
63. If a curve passing through (1, 1) satisfies the differential equation x 2 dy = y2 dx + xy d(xy), then
the equation of the curve is
1 1
(A) log xy  2  2
x y
1 1
(B) log xy  
x y
1 1
(C)  log xy  2

y x2
1 1
(D)  log xy  
x y
n
 1k
64. The value of S  k 3
 nCk is
k 0  9k 2  26k  24
1
(A)
n  3  n  4 
1
(B)
2 n  3  n  4 
1
(C)
2 n  1 n  2 

1
(D)
n  1n  2 
65. Let complex number z = (a + cos ) + (2a – sin )i. If |z|  2 for any   R, then the range of a is
 1 1 
(A)  , 
 5 5
 1 1 
(B)  , 
 5 5
 2 2 
(C)  , 
 5 5
 2 2 
(D)  , 
 5 5
66. The value of positive real parameter a such that the area of region bounded by parabolas y = x –
ax2, ay = x2 attains its maximum value is equal to
1
(A)
2
(B) 2
1
(C)
3
(D) 1
67. Let S be the set of all those 2007-place decimal integers 2a1a2a3 ..... a2006 which contain odd
number of digit 9 in each sequence a1, a2, a3, ....., a2006. The cardinal number of S is
1  2006
(A) 10  82006 
2
1  2006
(B) 10  82006 
2
(C) 102006  82006
(D) 102006  82006
68. Nine balls of the same size and color, numbered 1, 2, ....., 9, were put into a packet. Now A draws
a ball from the packet, noted that it is of number a, and puts back it. Then B also draws a ball
from the packet and noted that it is of number b. Then the probability for the inequality a – 2b +
10 > 0 to hold is
52
(A)
81
59
(B)
81
60
(C)
81
61
(D)
81
1
 x
 log 
  5x   5 4 
 log5  
69. If L  lim   4  , then [L] is (where [.] denotes greatest integer function)
x 4  20 
 log5 
 x 
(A) 3
(B) 7
(C) 9
(D) 12
70. A tower subtends angles , 2 and 3 respectively at points A, B and C, all lying on a horizontal
line through the foot of the tower. Then AB/BC is equal to
sin3
(A)
sin2
(B) 1 + 2 cos 2
(C) 2 cos 2
sin2
(D)
sin 
71. The SD of 15 items is 6 and if each item is decreases by 1, then standard deviation will be
(A) 5
(B) 7
91
(C)
15
(D) 6
72. ~(p  q)  (~p  q) is logical equivalent to

(A) ~p
(B) p
(C) q
(D) ~q
 1 0 0
73. If matrix A   1 0 1 , then which of the following is in correct?
0 1 0 
(A) A – A2 = A – I
3
(B) A 2022  I  0
 1 0 0
50  
(C) A  25 1 0 
25 0 1
 1 1 0
 
(D) A 50  50 1 0 
50 0 1
74. The distance of the point P(–1, –2, 4) from the plane x + y + z = 7 measured parallel to z-axis is
(A) 4
(B) 3
(C) 5
(D) 6

75. The sum of all possible real values of ‘a’ for which vectors r1  ln a î  ajˆ  kˆ and

r2  1  a2  î  ˆj  a  1 kˆ are orthogonal is
(A) –2
(B) 0
(C) 2
(D) 4
a
76. Let f be a continuous function that p  x    f  t  x  t dt
2
where x  (–2, 2), then the value of
2
p  x 
 f  x  dx
0
is equal to
(A) 0
(B) 1
(C) 2
(D) 4
77. A line L1 passing through point A(2, 0) and makes an angle  with positive x-axis in anti-clockwise
1
direction, where tan   . Now, L1 is rotated about the point A in anti-clockwise direction through
2
an angle of ( – 4). If the line in the now position in L2. Then the positive slope of the angle
bisector between the lines L1 and L2 is
(A) 2
3
(B)
2
1
(C)
2
2
(D)
3
sin2 
78. If tan       , then tan  = f(). The value of f   equals
3  cos 2 4
(A) 2
1
(B)
2
(C) 3
1
(D)
3
79. In a parabola y2 = 4ax, two points P and Q are taken such that the tangents drawn to parabola at
these points meet at directrix in R. Focus of locus of circumcentre of PQR will be
a 
(A)  , 0
2 
(B) (a, 0)
 3a 
(C)  , 0
 2 
 5a 
(D)  , 0
 2 
tan3 x
80. If f  x    2  tan 2
dx , then
x
2  sin2 x
(A) f  x   log C
cos x
2  sin2 x
(B) f  x   log C
cos x
2  cos 2 x
(C) f  x   log C
sin x
2  cos2 x
(D) f  x   log C
sin x
SECTION – B
81. The number of integral points (i.e., the points whose x and y-coordinates are both integers) within
the area (not including the boundary) enclosed by the right branch of hyperbola x 2 – y2 = 1 and
the line x = 100 is
82. Let f(x) be an odd function on R, and f(x) = x 2 for x  0. Suppose for any x  [a, a + 2], f(x + a) 
2f(x). Then the range of real number a is   ,  . Then  is
 
83. The largest possible value of the expression
S  sin x1  cos x 2  sin x2  cos x 3  .....  sin x 99  cos x100  sin x100  cos x1 , where x1, x2, x3, ....., x 100
are arbitrary real numbers is
84. Four letters, two ‘a’s and two ‘b’s, are filled into 16 cells of a matrix as
shown in figure. It is required that each cell contains at most one letter,
and each row or column cannot contain the same letters. Then there are
_____ different ways that the matrix can be filled
z z
85. Given that |z| = 1 and satisfies   1 . Then the number of solution of the equation is
z z
1 1 2 3
86. Suppose a and b are positive real numbers satisfying   2 2 and (a – b) = 4(ab) . Then
a b
loga b is equal to
87. Let a, b be real numbers, and f(x) = ax + b satisfies |f(x)|  1 for any x  [0, 1]. Then the maximum
of ab is
88. Let n = aaaaaa be a six digit number (all digit repeated) and N is divisible by 924. Let a and b are
2
the roots of the equation x – 11x +  = 0, then the sum of possible values of  is

89. Let ABC be a triangle with angle B  and c = 8. A circle with centre A and radius AB meets BC
4
at D. If altitude from vertex A to the side BC meets the circle at E. Then area of the BED is

 
   1 . Then the value of

is
90. Given 2022 vectors on a plane. Sum of every 2021 vectors is a scalar multiple of the other vector.
Not all vectors are scalar multiple of each other. The magnitude of sum of all these vectors is
FIITJEE
FULL TEST – X
JEE (Main)-2022
TEST DATE: 10-04-2022

Physics PART – A
SECTION – A
1. B
V
Sol. tan    3
H
V V
tan   
H Hcos 
3
tan   2
cos 30
  tan1(2)
2. A
Sol. Since, all surfaces are frictionless
Acceleration > g sin 
3. B
Sol. Truth table of AND gate
4. B
Sol. Voltage (regulated) across zener diode being 9 V, therefore V across resistor is (17  9) = 8V
5. A
 2 
Sol. mg    A; q = σA
 20 
q2
 mg =    2mgA0
2A0
AITS-FT-X-PCM(Sol.)-JEE(Main)/22 2
6. C
Sol. N0 et  N0 1  et 
1
et 
2
n2
t1/2   

1
T n2

T= 
7. C
3R
Sol. IA < IB since COM is at from IA (close to axis A than to axis B)
8
8. D
Sol. Conceptual
9. C
Sol. TP1/3 = constant
(PV/nR)*P1/3 = constant
P2/3 V = constant
PV3/2 = constant
3 5
x  ,  
2 3
R R 3R R R
C    
  1 1 x 2 3 2
1
2
 C is negative
Q = nCT
 if Q is +ve T is ve
10. D
Sol. From the figure for real image formation
x  x ' 2f  4f
 x  x '  2f
11. C
4 3
Sol. Buoyant force on a bubble (B) = r g 
3
Viscous force (F) = 6rv
For uniform velocity F = B
2r 2  g
Equating both, we get  =
9v
Putting values   11 poise
12. A
Sol. As long as cylinder is completely inside, B is constant in magnitude, then its value decreases
linearly with displacement and finally becomes zero.
3 AITS-FT-X-PCM(Sol.)-JEE(Main)/22
13. C
Sol. There is no change in fringe pattern, with symmetric motion of source. Intensity at maxima
increases because intensity at slits increases.
14. D
Sol. Velocity of particles at extreme position is zero and acceleration of particle at extreme position is
maximum.
15. B
Sol. Time period of SHM is independent of position of the tunnel
16. C
Sol. conceptual
17. D
1/2
Sol. 
FR  Mg R2  (R  a)2 
1/2
  R  a 2 
F  Mg 1    
  R  
18. C
dq T
Sol.  constant = i (lets say)
dt
dT dT i
i  aT 3 , 
dt dt aT 3
i
dT  dt
aT 3
T t
3 i
 T dT  dt
T0 a 0
O t
4
T 4 T0 i
  t
4 4 a
19. D
Sol. COM of M(L, 0) and M(L, 0) is (0, 0)
x y
Therefore COM of three particle system when third mass is at (x,y) is at  , 
3 3
2
L
COM traces path given by x2 + y2 =
9
Where radius is L/3
20. B
  q (v  r )
Sol. B 0
4 r 3

r  a î  bjˆ

v  v î
 q vb kˆ
 B 0
4 (a2  b2 )3/ 2
SECTION – B
21. 00200.00
Sol. 1st overtone
2V V 1 200
f    (200)
2L L 1 (5 / 1000)
f = 200 Hz
22. 00016.00
B V dV A
Sol. i  CB.
R dt V
B  dV  R B
i   V  RC C = 1F
 R  dt  F
I
dV B2 2  dV 
m F  V  RC 
dt R  dt  IR B IC
dV  B2  2 
m  B2 2 C  F  V
dt  R 
dV
0
When rod attains terminal velocity vT, dt
FR 0.4  10
vT  2 2   16
B 1 0.25
23. 00021.00
1 1 1
Sol.  R(z  1)2  2  2  …… (i)
k  1 2 
hc
0  ; ……. (ii)
eV1
 0  22
 k    (k  0 )
 2  19
25
Therefore, k  0 ;
6
Putting values from (i) and (ii) in above equation, we get Z= 21
24. 00027.00
Sol. Let say the displacement of cylinder from its equilirbrium position is ‘x’.
 ma = gAx
 gA 
 a   x
 m 
gA
 cylinder  …(i)
m
k
 springblock  …(ii)
m
 cylinder  springblock …(iii) (given)
 K = gA [from (i), (ii), (iii)]
K = 27 N/m
25. 00011.88
  
Sol.   IE  IC
 1  
99
 12  11.88 mA
100
26. 00060.00
Sol. I0 = 128 W/m2 ; I1 = I0/2; I2 = I0/2 cos2
I3 = I0/2 cos4  = 4
27. 00002.00
Sol. Diameter = 2.4 + 2  LC  (0.4 + 2  LC) = 2 cm
28. 00050.00
A A
0   20  
Sol.
2
C      2   3 0 A  1.5 C
d d 2 d
29. 00030.00
1
Sol. 2mg sin  = mg  sin  >
2
 = 30
30. 00008.00
Sol. A  A 0 e bt
A0
 A 0 e b(3)
2
1
e 3b  …(i)
2
A   A 0 e b(9)
 1
A   A 0   from equation (i)
8
SECTION – A
31. B
 a 
Sol.  p  2   V  b   RT
 V 
a
 0  neglected
V2
 p  V  b   RT
pV  pb  RT
 pV  RT  pb
R 
V   T  b
p 
Isobar is made at constant pressure between V(y-axis) and T(x-axis)
R
Slope   tan   0.1642 dm3 K 1
p
R 0.0821 dm3 mol1 K 1
p  
tan  0.1642 dm3 K 1
 0.5 atm mol1 .
32. C
Sol. (A, B, D) colour dissapers if a reactant added removes Fe3  or SCN .
Ag  SCN  AgSCN 
Hg2  2SCN  Hg  SCN2 
3
C2O24  Fe3   Fe  C2 O4 3 
33. D
Sol. This represents oxidation half-cell
2Hg  2Cl  Hg2Cl2  2e 
1 0.0591
 Q  E  Eo  logQ
 2 2
Cl 
 
0.0591 1
 Eo  log 2
 Eo  0.0591log Cl 
2 Cl 
 
When Cl   1 M, E  Eo and E increases on increasing log Cl 
E

Eo
34. D
Sol. HCN  H  CN , K a  4.5  1010
CH3 COOH  H  CH3 COO  , K a  1.5  10 5
1
CN  H  HCN, K a 
Ka
CH3 COOH  CN  HCN  CH3 COO  , K eq  K a .K a
1
 1.5  105   3.33  10 4
4.5  10 10
35. D
Sol. F
Cl Cl Cl F F F F
I I Xe Br F Xe
Cl Cl Cl F F F F
F
3 2 3 3 2
sp d sp d sp d sp d
3 3
Planar Linear: It is planar as three Square planar Pentagonal planar

points are in same plane
36. B
Sol. SnCl2  HgCl2  SnCl4  Hg
 XCl2   YCl2   XCl4   Y 
 1
HgO 
 400o
Hg  O2
2
HgS : Cinnabar
37. C
below 1
Sol. NaNO3 
500o C
NaNO2  O2
2
Hg  NO3 2 
  Hg  2NO2   O 2 
38. A
Sol. Ca NH  2H2O  Ca  OH2  NH3  g
B 
2NH3  3CaOCl3  N2  g  3CaCl2  3H2O
B  C 
N2  g  3Mg  Mg3N2
C D 
Mg3N2  6H2 O  3Mg  OH2  2NH3
D  B 
39. D
Sol. .
. .
Cyclic silicate having three Si atoms Si3 O96   contains three Si – O – Si linkage.
One tetrahedron shares three oxygen atoms while other share two oxygen atoms and these two
tetrahedrons constitute one unit. Therefore, number of oxygen atoms sheared per tetrahedron or
32 1
Si atom = 2
2 2
6n 
 General formula of double chain silicates :  Si4 O11 n .
 As the tendency of formation of multiple bond increases the extent of polymerization
decreases. Silicon has large size hence, it forms less effective p  p overlapping with oxygen.
40. C
Sol. Due to presence of amide groups, nylon forms intermolecular H-bond with water and therefore,
possesses high hydrophilicity.
41. D
Sol. EtONa
CH2  COOC2H5  2  CH  COOC2H5  2
EtOH
Br  CH2 3 Br  CH  COOC2H5  2  Br  CH2 3 CH  COOC 2H5  2
EtONa
COOH H2C CH2

H / H2 O
 COOC2H5
H2C C
COOC2H5
42. A

H Ozonolysis
Sol. C9H10 O 2  CH3MgBr  B   Ketone  Positive iodoform test
 C8H8 O 
10  5  5 Excess   Olefin 
OH
O
||

C6H5  C  OC2H5  CH3MgBr  excess   H5C6 C CH3 H
 H5C6 C CH2
CH3 CH3
Ozonolysis
O
||
NaOH, I2
CHI3  C6H5  C  O    H5C6 C O
CH3
43. C
Sol. H
O
O O
O H3C
H3C C H 
C C OH C C C O H
H H3C H
H3C
Unstable
H  CO2
H H3C OH
H3C O
C C C C
H3C H H3C H
Enol
44. B
Sol. H CH O
CH CH O CH CH O
 OH
O
H2 O
CH2 CH O CH2 CH O
H2O OH
CH O
OH
,  H2 O
CH O

 ,   unsaturated aldehyde 
45. D
Sol. Glycine and all other amino acids are amphoteric because of the presence of NH2 and CO2H

group both. The amino acid exists and Zwitterion and acid group is  NH3 while basic group is
CO2 .
46. D
Sol. SO 2  2H2O  H2SO4  2H
Oxidation of SO2 and thus bleaching of coloured matter by reduction.
47. D
Sol. O O O O O
 
 
HO
 
 H2O
 
O O O O O
Conjugate addition OH
48. A
Sol. KIO4  H2O2  KIO3  H2O  O2
I7   2e  I5 
O 1
2
 O2  2e
 Reductant 
NH2OH  3H2O2  HNO3  4H2 O
N  N5  6e
 O   2e  2O
1
2
2
 Oxidant 
49. C
Sol. The balanced disporoportionation reaction involving white phosphorous with aq. NaOH is
Oxidation of P0 to P1 state
3 1
P40  3NaOH  3H2 O  PH3  3NaH2 P O2
Re duction of P0 to P3 state
50. B
Sol. AgF is water soluble but CaF2 is insoluble in water.
SECTION – B
51. 00707.20
Sol. We know that Tt  K t m.
0.0024
Therefore, m   0.0013 mol kg1
1.86
or molarity  0.0013 mol L1 (in case of solvent water molarity = molality).
The reaction involved is
I2  aq   I  aq  I3  aq

Initial moles 0.0492 0.1 0
Moles at equilibrium 0.0492  x 0.1  x x
Total number of moles at equilibrium = 0.0492 – x + 0.1 – x + x = 0.1492 – x.
Now, 0.1492 – x = 0.0013 because of conc. of I2 in all saturated solutions is same, so x = 0.0479.
I3  0.0479
Hence, the equilibrium constant is K C      707.2
I2  I  0.0013  0.0521
52. 00021.00
Sol. By Mosely’s equation
v  a Z  b
v  aZ  ab
This represents a straight line between v  y  axis  and Z(x-axis)
45o
O A Z
At v  0, aZ  ab
 Z  b  OA  1
Also, slope  a  tan 45o  1
When v  400, then 400  Z  1
 v  Z 1
 Z  21
53. 00005.00
Sol. Species with at least one or more unpaired electron(s) are attracted by the magnetic field and is
said to be paramagnetic
Na ,Zn2  Cu and O22 
No unpaired electron hence, diamagnetic
O2  Two unpaired electrons, in anti-bonding molecular orbitals
Fe2   Four unpaired electrons in 3d-orbital
Cr 3  Three unpaired electrons in 3d-orbital
Cu  One unpaired electron in 3d-orbital
O2  One unpaired electron in anti-bonding molecular orbitals
54. 00000.30
Sol. First vapour appears at 70 torr. It means total vapour pressure = 70.0 torr.
 p total  poA X A  pBo 1  X A 
70.0  125X A  46.3 1  X A 
 70  46.3   125  46.3  XA
23.7  78.7X A
 X A  0.30
55. 00009.00
Sol. 2H2O  2H2O  O2
k  0.0693 min1
0.693 0.693
 T50    10 min
k 0.0693 min1
20
H2 O2 left in 20 min, y  2
10
y 2
1 1 1
 A t   A o    1 mol    mol
2
  2
  4
1 3
Thus, H2 O2 decomposed  1   mol
4 4
3
O2 formed  mol
8
nRT
V 
p
3
mol  0.821 L mol1 K 1  293K
 8  9.02 L
 760 
  atm
 760 
56. 00004.00
1
x
Sol. By Freundlich’s adsorption isotherm    k  p  n
m
x 1
log    logk  logp
m
  n
x 45o
log  
m
0.6990
O logp 
y  C  mx
1
 m  slope  tan 45o  1
n
n  1
log k = 0.6990 = C
 K  50
1
x
 k  p  n  5.0  p 
m
When, p = 0.80
x
 5.0  8.0  4
m
57. 00006.00
Sol. Complexes Number of geometrical isomers
(I) Pt NH3 2  SCN2  2
(II) Co  NH3 3  NO2 3  2
(III) Pt  en  Cl2  0

(IV) Cr  en 2 Br2  2
3
(V) Rh  en 3  0
2
(VI)  CoCl2Br2  0
Hence, sum of total number of geometrical isomers = 6.
58. 00007.48
Sol. Given, Hexene + Ethanol = 10 g
1
Therefore, C2H5OH  Na  C2H5 ONa  H2
2
PV 760  200
Now, mole of H2 formed  
RT 760  1000  0.0821 300
 8.13  103 mole
 200 ml H 2 is formed at 27o C and 760 mm pressure 
1
Now, mole H2 is formed by  46 g C2H5 OH
2
8.13  10 3 is formed  46  8.13  103  2 g C2H5 OH
= 0.748 g
0.748  100
 % of ethanol in mixture   7.48%
10
59. 00004.00
PVM 10  2   32
Sol. Mass of O2 adsorbed    8g
RT 400  0.08
X 8
  4
m 2
60. 00006.00
Sol. OH O O OH
OH O
(Two geometrical isomers) (Two geometrical isomers)

(d,l)
SECTION – A
61. C
Sol. Let f(x) = x3 + cos1x2 + sin1x + 1 = 0
f(x) = 3x2 + 2cos1x + sin1
f(x) > 0
1 
So, the real root is negative tan1   tan1 
 2
62. A
Sol. Let f(x) = (ax + b)(x – 2)(x – 3)(x – 4)
b 5
f(1) = 5a + 11b = 0   
a 11
63. B
x2 dy  y 2 dx  xy  d  xy  dy dx d  xy  1 1
Sol. 2 2
x y
 2 2
x y
  y  x  
2 2 xy
    log xy  c
y x
64. B
Sol. k3 + 9k2 + 26k + 24 = (k + 2)(k + 3)(k + 4)
n
 1k k  1 1
n
S   n Ck =   k  1  n 4 Ck  4
k 0
 k  1 k  2   k  3   k  4   n  1 n  2   n  3   n  4  k 0
n4
  
  1
k
 k  3   n  4 Ck = n  1 n  2
k4
2
1
So, S 
2 n  3  n  4 
65. B
Sol. |z|  2
 (a + cos )2 + (2a – sin )2  4  2a(cos  – 2 sin )  3 – 5a2
 2 5 a sin       3  5a2  2 5 a  3  5a2
 1 1 
 a   , 
 5 5
66. D
x2 a
Sol. For point of intersection x  ax 2   x = 0,
a 1  a2
a
1 a2
 2 x2  5 a2
Area =
0
 
 x  ax 
a 
 dx 
6 1  a2 2
Area maximum when a = 1
67. B
Sol. Define A as the number of the elements in S, we have
 2006  2005  2006  2003  2006 

A  9  9  .....   9
 1   3   2005 
2006 2006
2006  2006  2006 k 2006  2006  k 2006 k
On the other hand,  9  1   
k 0 
k


9 and  9  1   
k 0 
k
  1 9

 2006  2005  2006  2003  2006  1 2006
So, A   9  9  ......    9 = 10  82006
 1   3   2005  2
68. D
Sol. Since each has equally 9 different possible results for A and B to draw a ball from the packet
2
independently, the total number of possible events is 9 = 81. From a – 2b + 10 > 0 we get 2b < a
+ 10. We find that when b = 1, 2, 3, 4, 5, a can take any value in 1, 2, 3, ....., 9 to make the
inequality hold. Then we have 9  5 = 45 admissible events
When b = 6, a can be 3, 4, ....., 9 and there are 7 admissible events
When b = 7, a can be 5, 6, 7, 8, 9 and there are 5 admissible events
When b = 8, a can be 7, 8, 9, and there are 3 admissible events
When b = 9, a can only be 9, and there is 1 admissible events
45  7  5  3  1 61
So, the required probability is 
81 81
69. B
 x
1
x2
 log  log5
 5x  5 4  lim 16
 log5 4  1
x 4
log5
x
Sol. L  lim 1    e 4  e2
x4
 log 20 
5
 x 
 [L] = 7
70. B
h E
Sol. In ECD, tan3 
CD
 CD = h cot 3 ..... (1)
h
In EBD, tan2 
BD h
 BD = h cot 2 ..... (2)
h
In EAD, tan  
AD  2 3
 AD = h cot  ..... (3) A B C D
From equation (2) and (3), we have AD – BD = h cot  – h cot 2
AB = h (cot  – cot 2) ..... (4)
From equation (1) and (4), we have BD – CD = h cot 2 – h cot 3
 BC = h(cot 2 – cot 3) ..... (5)
cos  cos 2 sin  2   
  
AB h cot   cot 2
From equation (4) and (5), we have   sin  sin 2  sin  sin2
BC h  cot 2  cot 3  cos 2 cos 3 sin  3  2 

sin2 sin3 sin2 sin3
sin3 2
=  3  4 sin   3  2 1  cos2   1  2cos2
sin 
71. D
Sol. If variable is decreased by 1 then there is no effect on standard deviation
72. A
Sol. ~(p  q)  (~p  q)  (~p  ~q)  (~p  q)  ~p  (~q  q)  ~p  t  ~p
73. D
1 0 0 1 0 0 
  2  
Sol. A  1 0 1 ; A  1 1 1
0 1 0  1 0 1
1 0 0 1 0 0
   
A 3  2 0 1 ; A 4  2 1 0 
 1 1 0  2 0 1
1 0 0 0 0 0 
2n   2n  
 A  n 1 0  ; n  N ; A  I   n 0 0 
n 0 1 n 0 0 
74. D
x 1 y  2 z  4
Sol. Equation of line parallel to z-axis passing through A is   
0 0 1
Point on the line is (–1, –2,  + 4) which lies on x + y + z = 7
–1 –2 +  + 4 = 7   = 6
So, required distance is 6 units
75. B
 
Sol. r1  r2  0 y
ln |a|(1 + a2) – a + a – 1 = 0 (0,1)
1
ln a 
1  a2
From the graph it is clear that number of values of x2 x1
‘a’ are two i.e., x1, x2 and x1 + x2 = 0
76. D
x 2 x 2
Sol.  f  t  x  t  dt  f  t  t  x  dt ; p  x  
  f  t  dt  f  t  dt

2 x 2 x
2 2
p  x 
p  x   f  x   f  x   2f  x  ;  f  x  dx  2 dx  4
0 0
77. A
  y
Sol. Slope = tan   2     cot   2
2 
 – 4 L1
x
A(2, 0)
L2
78. A

sin
  2 1 tan   1 1
Sol. tan          tan  = 2
 4  3 1  tan  3
3  cos
2
79. C
Sol.  Tangent at end of focal chord meet at directrix at 90
 PQ is focal chord and its mid-point will be circumcentre
a 2a 
Let P = (at2, 2at)  Q   2 ,  and circumcentre = (h, k)
t t 
 1  1  1 2 
 2h  a  t 2  2  and 2k  2a  t    2h  a  t    2 
 t   t  t 
 k2 
 2h  a  2  2   2ha = k2 + 2a2  Locus is, y2 = 2a(x – a)
a 
 3a 
 Focus =  , 0 
 2 
80. B
 sec 2 x  1 tan x
Sol.   tan2 x  2 dx ; Put sec x  t  sec x tan x dx = dt
 t 1 
 dt  log 1  t   log t  C
2
=   1  t 2

t  t  1 
2
1  cos 2 x 2  sin2 x
 log  C  log C
cos x cos x
SECTION – B
81. 09800.00
99
Sol. Number of integral points within the area above the x-axis is   99  k   99  49  4851
k 1
The total number of integral points within the area is 2  4851 + 98 = 9800
82. 00002.00
 x 2 x0
Sol. f  x  
2
  x x0
So, 2f(x) = f  2 x   f(x + a)  f  2 x 
As f(x) is increasing are R, then x + a  2x
 a   2  1 x since x  [a, a + 2] ;  2  1 x is maximum at x = a + 2
So, a   2  1  a  2  ; a   2,  

83. 00050.00
Sol. 2ab  a2 + b2 using this
sin2 x1  cos2 x2 sin2 x100  cos2 x1
S  .....   50
2 2
84. 03960.00
4
Sol. It is easy to see that there are    P24  72 different ways to put two ‘a’s into the matrix such that
2
4
each row and each column contains at most one ‘a’. similarly, there are also    P24  72
2
2
different ways for two ‘b’s to do the same thing. By the multiplicative principle, we get 72 ways.
Among them we exclude 72 cases in which two ‘b’s occupy the same cells as the two ‘a’s do, and
 16 
exclude    P29  16  72 cases in which one ‘a’ shares the same cell with a ‘b’.
 1
Therefore there are 722 – 72 – 16  72 = 3960 different ways that meet the requirement.
85. 00008.00
Sol. Let z = cos x + i sin x
z z z2  z 2
  2
 2 cos2x  1
z z z
cos 2x = 1 or cos 2x = –1
 5 7 11  2 4 5
x , , , , , , and
6 6 6 6 3 3 3 3
So, 8 solutions
86. 00001.00
1 1
Sol. From   2 2 , we have a + b  2 2 ab
a b
3 2
On the other hand (a + b)2 = 4ab + (a – b)2 = 4ab + 4(ab)3  4  2 ab   ab   8  ab 
And that means a  b  2 2 ab ..... (1)
Therefore, a  b  2 2 ab ..... (2)
The equality in (1) holds only where ab = 1. Associating it with (2), we get
a  2  1 , a  2  1
 and  . So the answer is loga b  1
b  2  1 , b  2  1
87. 00000.25
Sol. It is easy to find that a = f(1) – f(0), b = f(0), then
2
 1  1 2 1 2 1
ab  f  0    f 1  f  0      f  0   f 1    f 1    f 1  
 2  4 4 2
1 1
When 2f(0) = f(1) = 1, i.e., a = b =  , we get ab =
2 4
1
Therefore, the maximum of ab is = 0.25
4
88. 00052.00
Sol. N = a(111 111)
924 = 4  7  11  3 so a must be divisible by 4, a = 4, 8
Sum of roots of equation = 11
If a = 4, then b = 7,  = 28 ; a = 8, then b = 3,  = 24
89. 00016.00
Sol. AF  4 2
FE = 8  4 2 A
BD  8 2
8
1
Area of BED = 8 2  8  4 2  = 32  2  1 /4
C
2 B F D
 = 32 ;  = 2 E
90. 00000.00
Sol. Let a1, a2 , ....., a2022 be the vectors
 a1  a2  .....  a2021   a2022
 a1  a2  .....  a2020  a2022   a2021
  a2022   a2021  a2021  a2022
+1=+1=0
  =  = –1
 a1  a2  a3  .....  a2022  0
FIITJEE
FULL TEST – XI
JEE (Main)-2022
TEST DATE: 17-04-2022
answer.
XXXXX.XX and each question carries +4 marks for correct answer and –1 mark for wrong answer.
AITS-FT-XI-PCM-JEE(Main)/22 2
Physics PART – A
SECTION – A
1. A glass wind screen whose inclination with the vertical can be changed is mounted on a car. The
car moves horizontally with a speed of 4 m/s. At what angle  with the vertical should the wind
screen be placed so that rain drops falling vertically downwards with velocity 12 m/s strike the
wind screen perpendicularly?
 1
(A) tan1  
3
1
(B) tan (3)
(C) cos1(3)
 1
(D) sin1  
3
2. Find the amount of work done to increase the temperature of one mole of an ideal gas by 30C if
it is expanding under the condition V  T 2/3
(A) 166.2 J
(B) 136.2 J
(C) 126.2 J
(D) None of these
3. A particle is hanging from a string of length  = 10 m. It is imparted a velocity of 20 m/s at the

bottom. The velocity of the particle at its highest point is (g = 10 m/s2)
20
(A) m/s
3
20 2
(B) m/s
3 3
20
(C) m/s
3
2
(D) 20 m/s
3
1
4. Suppose the gravitational force varies inversely as the power of distance. Then the time
nth
period of a planet in circular orbit of radius R around the sun will be proportional to
 n 1
 
(A) R 2n 
 n 1
 
2 
(B) R
(C) Rn
 n2 
 
2 
(D) R
3 AITS-FT-XI-PCM-JEE(Main)/22
5. A ball of mass m and density  is immersed in a liquid of density 5 at a depth h and released. To
what height will the ball jump up above the surface of liquid? (neglect the resistance of water and
air).
(A) h
(B) h/2
(C) 4h
(D) 3h
6. As shown in the figure, a mass m and another mass 10m are u

connected with a string. Friction is sufficient to prevent the 10m
slipping of 10m. Mass m is given a velocity u in vertical direction.
L
m
For complete circular motion of mass m keeping heavier particle
stationary, the value of u is
(A) u  3gL
(B) 2gL  u  5gL
(C) 3gL  u  13gL
(D) 11gL  u  15gL
7. If the length of a simple pendulum is equal to 2R, where R is the radius of earth, its time period of
S.H.M. will be
2R
(A) 2
3g
R
(B) 2
2g
2R
(C) 2
g
R
(D) 
2g
8. An organ pipe of length 33 cm closed at one end vibrates in its 5th overtone. If amplitude of a
particle at antinodes is 6 mm, then amplitude of a particle which is at a distance 18 cm from
closed end is
(A) 3 cm
(B) 3 2 mm
(C) 2 mm
(D) zero
v0
9. A uniform ring of radius R is given a back spin of angular velocity and thrown on a horizontal
2R
rough surface with velocity of centre to be v 0. The velocity of the centre of the ring when it starts
pure rolling will be
v0
(A)
2
v0
(B)
4
3v 0
(C)
4
(D) 0
10. The depletion layer is silicon diode is 1 m wide and the knee potential is 0.6 V, then the electric
field in depletion layer will be
(A) zero
(B) 0.6 V/m
(C) 6  104 V/m
(D) 6  105 V/m
11. The wavelength corresponding to maximum spectral radiancy of a black body A is A = 5000Å.
Consider another black body B, whose surface area is twice that of A and total radiant energy by
B is 16 times that emitted by A in same time. The wavelength corresponding to maximum
spectrum radiancy for B will be
(A) 5000(2)3/ 4 Å
(B) 2500 Å
(C) 10000 Å
(D) 5000(2)3/ 4 Å
12. The wavelength of characteristic K line emitted by a hydrogen like element is 0.32 Å. The
wavelength of the K line emitted by the same element will be
(A) 0.25 Å
(B) 0.27Å
(C) 0.30Å
(D) 0.35Å
13. In the circuit shown, the capacitors C1 and C2 have capacitance C R C1

each. The switch S is closed at time t = 0. Taking Q0 = CE and  = RC,
the charge on C2 after time t will be C2
(A) Q0 1  e t /2  
E
(B) 
Q0 1  e t /
 S
Q

(C) 0 1  e t/2 
2

(D) Q0 1  e2t /  
14. The output of an AC generator is given by:

   3 
E  Em sin  t   and current is given by i  im sin  t   . The circuit contains a single
 4  4 
element other than the generator. It is:
(A) a capacitor
(B) a resistor
(C) an inductor
(D) not possible to decide due to lack of information
15. A particle undergoes SHM with a time period of 2 second. In how much time will it travel from its
mean position to a displacement equal to half of its amplitude
1
(A) sec
2
1
(B) sec
3
1
(C) sec
4
1
(D) sec
6
16. Two beams of light having intensities I and 4I interfere to produce a fringe pattern on a screen.
The phase difference between the beams is /2 at point A and  at point B on the screen. Then
the difference between resultant intensities at A and B is:
(A) 2I
(B) 4I
(C) 5I
(D) 7I
17. An inductor of inductance L = 400 mH and three resistor of

resistance R1 = 4, R2 = 2 and R3 = 10 are connected E L
to a battery of emf E = 10V as shown in the figure. The
R1 R2
internal resistance of the battery is negligible. The switch S
is closed at tim t = 0. What is the potential drop across L as S R3
a function of time?
(A) 10e25t volt
(B) 10e5t
(C) 5e5t volt
(D) 30e16t volt
18. 3.2 kg of ice at 10C just melts when with a mass m of steam, at 100C is passed through it.
Then (specific heat of ice = 0.5 cal/gmC, latent heat of ice = 80 cal/gm, latent heat of
vaporization of water = 540 cal/gm, specific heat of water = 1 cal/gmC
(A) m = 400 g
(B) m = 800 g
(C) m = 425 g
(D) m = 900 g
19. To get maximum current through a resistance of 2.5 , one can use ‘m’ rows of cells, each row
having ‘n’ cells. The internal resistance of each cell is 0.5. What are the values of n and m, if the
total number of cells is 45.
(A) 3, 15
(B) 5, 9
(C) 9, 5
(D) 15, 3
20. In the figure shown, A is a fixed charge. B (of mass m) is v

given a velocity V perpendicular to line AB. At this moment
the radius of curvature of the resultant path of B is +q +q
A B
r
(A) 0
(B) (infinity)
4 0r 2mv 2
(C)
q2
(D) r
SECTION – B
21. A uniform cube of side a and mass m rests on a rough horizontal table. A horizontal force F is
applied normal to one of the faces at a point that is directly above the centre of face, at a height of
4
a above the base. The minimum value of F for which the cube will begin to tilt about an edge is
5
kmg
. Find the value of k. (assume that the cube does not slide)
4
22. A ring of mass m is placed on a rough horizontal surface with its plane vertical. A horizontal
impulse J is applied on the ring of mass m along a line passing through its centre. The linear
kJ
velocity of the centre of the ring once it starts pure rolling is . Find the value of k.
m
23. A particle of mass 1kg is performing SHM with maximum kinetic energy 2J. The average speed of
particle during the interval of time in which it moves from one extreme position to the other
n
extreme position is m/s. Fin the value of n.

24. Two bodies of mass 1 kg and 2 kg move towards each other in mutually perpendicular direction
with the velocities 3 m/s and 2 m/s respectively. If the bodies stick together after collision what will
be the value of heat liberated in joule.
25. A positive charge q is projected in magnetic field of width        

mv    B    
with velocity v as shown in the figure. Then time taken by
2qB        
       
km
charged particle to emerge from the magnetic field is . Find        
qB q v     
the value of k.
mv
2qB
26. A ray of light enters into a transparent liquid from air as

shown in the figure. The refractive index of the liquid varies 45
1 air
with depth x from the topmost surface as   2  x
2
where x in meters. The depth of the liquid medium is
sufficiently large. Find the maximum depth (in cm) reached
by the ray inside the liquid.
27. A heavy nucleus having mass number 200 gets disintegrated into two small fragments of mass
number 80 and 120. If binding energy per nucleon for parent atom is 6.5 MeV and for daughter
nuclei is 7 MeV and 8 MeV respectively, then the energy released in the decay will be k  102
MeV. Find k.
28. The equivalent resistance of the circuit across points A B 15  10 

A and B is n. Find the value of n.
10  15 
30  20 
20  30 
29. A paramagnetic substance of susceptibility 3  104 placed in a magnetic field of 4  104 Am1.
Then, the intensity of magnetization in the unit of Am1 is k  108. Find the value of k.
30. The maximum kinetic energy of photo electrons emitted from a metal surface, when photon of
energy 6eV fall on it is 4 eV. Find the stopping potential in volts.
SECTION – A
o
 
31. The de-Broglie’s wavelength of electron in a certain orbit of Li2 is 2ao ao  0.53 A  . What is
 
the quantum number of that orbit?
(A) 2
(B) 3
(C) 4
(D) 1
32. 24 miligram of MgSO 4 is present in 500 ml of a water sample. What is the hardness of water in
ppm?
(A) 60 ppm
(B) 20 ppm
(C) 40 ppm
(D) 50 ppm
33. Which of the following statement is incorrect?

(A) The hybridization of Be in solid BeCl2 is sp3 .
(B) In B2H6 all of the B – H bonds are not of equal length.
(C) The angle between H – O and O – O bond in hydrogen peroxide is same in gas and in
solid.
(D) O3 is a polar molecule.
34. Which of the following statement is incorrect?

2 3
(A) 1 H and 2He are isotones
37 39
(B) 17 Cl and 18 Ar are isodiaphers
7 7
(C) 3 Li and 4Be are isobars
3 4
(D) 1 He and 2 He are mirror nuclei
35. In which of the following cases, the oxidation sate number changes by 8?
(A) MnO 4  MnO2
(B) C2O24  CO2
(C) AsO33   AsO34
(D) NO3  NH4
M M
36. 20 ml of H3PO4 solution is treated with 40 ml of NaOH solution. What is the pH of the
10 10
resulting solution? pK1  3, pK 2  7, pK 3  13 for H3PO4 
(A) 10
(B) 9
(C) 5
(D) 8
37. Calculate Eo for MO2  M4 in 1 M acidic medium in the following diagram
0.97 V ? 1.01 V
MO2   MO2   M4   M3
1.02 V
(A) 1.20 V
(B) 1.08 V
(C) 1.32 V
(D) 1.5 V
38. In the Lassign’s test of an organic compound, if FeCl3 is added in the final extract, a red
colouration is observed. Which elements are present in the compound apart from carbon and
hydrogen?
(A) N and O
(B) N and P
(C) S and O
(D) S and N
39. 3 mole of nitrogen initially at 300 K and 10 atm expands irreversibly and adiabatically against a
constant pressure of 1 atm. Calculate the final temperature of the gas CP  29.133 K 1 .  
(A) 230 K
(B) 270 K
(C) 223 K
(D) 242 K
40. If K 4 Fe  CN6  undergoes 50% dissociation in water, calculate the van’t Hoff factor i?
(A) 4
(B) 5
(C) 3
(D) 2
41. Phosphorescence shown by phosphorus is due to

(A) Oxidation of P in P2 O3
(B) Oxidation of P in P2 O5
(C) Oxidation of Luciferin by Lucifeze enzyme
(D) Reduction of P into phosphide ion
42. Choose the correct order of o for the following complexes

2
I. Co  H2O  
 6
3
II. Co  H2O  
 6
3
III. Fe  H2 O  
 6
3
IV. Fe  CN 
 6
(A) I < II < III < IV
(B) I < III < II < IV
(C) I < II = III < IV
(D) I < II < IV < III
43. Which of the following acetate salts gives the metal on heating?
(A) Na2C2O4
(B) Ag2C2O4
(C) FeC2O 4
(D) SnC2O4
44.
I II III
The correct order of stability of the given carbonium ions is
(A) II > I > III
(B) III > II > I
(C) I > III > II
(D) II > III > I
45. Identify the correct reagents required for the following transformation
HC O CH2OH
?
 
COOEt CHO
(A)  i NaBH4 ii  H3 O
(B)  i LiAlH4 ii  H3 O
(C)  i HOCH2CH2  OH ii LiAlH4 iii  H3O 
(D)  i HS  CH2  CH2  SH, H ii  LiAlH4  iii  H3 O 
46. The correct order of rate of solvolysis of the following molecule is
Br
Br
Br
I II III
(A) III > II > I
(B) II > I > III
(C) III > I > II
(D) II > III > I
47. The metal ion M2 in the following reaction is
M2   S2   Black precipitate 

Hot conc.
HNO3
 White precipitate
(A) Mn2
(B) Fe2
(C) Cd2
(D) Cu2

OH
N

H .
 
(A) CN
OH
(B) O
NH
(C) O
CH3
NH2
(D) H O
N
49. What is the reactivity of the following compounds towards nucleophile

CH3
O N O
H H OCH3
P Q R
(A) P>Q>R
(B) Q>P>R
(C) Q>R>P
(D) R>P>Q
50. The major product in the following reaction

O
OH
K 2CO3

PhCH2Br

OH 1 mole 
(A) O
OCH2Ph
OH
(B) O
OH
OCH2Ph
(C) O
OCH2Ph
OCH2Ph
(D) O
OH
CH2Ph
HO
SECTION – B
51. For the following amino acids pK a of the groups are given
HOOC CH2 CH2 CH COOH pK a  2.19
pK a  4.25 NH3
pK a  9.67
What is the pH corresponding to the isoelectric point of the amino acid?
52. Calculate the volume occupied by 8.8 gm of CO 2 at 31.1o C and 1 bar pressure
53. Solid Ca HCO3  2 decomposes as

Ca HCO3 2  s   CaCO3  s   CO2  g  H2 O  g
If the total pressure is 0.2 bar, at 420 K, what is standard free energy change of the reaction (in
kJ/mole)
54. O
1. CH3MgBr Conc. H2 SO4


2. H
 A  75% yield   
 B  80% yield 
 X
How many grams of B is obtained (in gram) if initially 9.8 gm X was present?
55. Calculate EMF of the cell in volt.

Pt | H2  g || BOH  aq || HA  aq  | H2  g | Pt
0.1 bar 1M 0.1 M 1 bar
56. Using van der Waal’s equation, find the constant ‘a’ (in L2 mol2 ) when two moles of a gas is
confined in 4 L flask exerts a pressure of 11 atm at a temperature of 300 K?
 b  0.05 L mol 1
, R  0.082 L atm / K mol 
57. A first order reaction is 50% completed in 20 minutes at 27o C and in 5 minutes at 47o C . What is
the activation energy of the reaction (in kJ/mole)  n2  0.7
58. A solution contains 8.2% Na3PO4 and 12% MgSO 4 by weight. If percent ionization of Na3PO4
and MgSO 4 are 50 and 60 respectively, then what is the boiling point in o C ?  
Kb H2 O   0.5 kg mol1 
 
59. Molybdenum (At. Wt. = 96 gm/mole) crystallises as bcc. If the density of crystals 10.3 gm / cm3 .
1/3
Given 3.1 1023  3.14  10 8 
What is the radius of Mo atm (in pm)? NA  6  1023 
   
2x
60. If the number of equivalent Cr – O bonds in CrO24 is x, then ?
3
SECTION – A
61. The number of integral ordered pairs (x, y) that satisfy the system of equation |x + y – 4| = 5 and
|x – 3| + |y – 1| = 5 is/are
(A) 2
(B) 4
(C) 6
(D) 12
3n3  4
 n  4n4 1
62. The value of lim  n  is
n  n 
3
(A) e4
3

(B) e 4
(C) e–1
(D) 0
1
4 
  xe  ye x  f  y  dy , if h(x) = f(x) + 3x is strictly increasing in (–, k), then  ek 
y
63. f  x   1
3 
0
equals to
(A) 1
(B) 2
(C) 3
4
(D)
5
64. If a, b  R distinct numbers satisfying |a – 1| + |b – 1| = |a| + |b| = |a + 1| + |b + 1|, then the

minimum value of |a – b| is
(A) 1
(B) 2
(C) 3
(D) 4
p b c
p q r
65. If a  p, b  q, c  r and a q c  0 , then the value of   ?
pa qb r c
a b r
(A) 1
(B) –1
(C) 2
(D) –2
66. A coin is tossed (m + n) times m > n, find the probability of getting atleast m consecutive heads is
(m > n)
n2
(A)
mn
n2
(B)
2m
n2
(C)
2m 1
n2
(D)
2n  1
3 2  
67. If , ,  are the roots of 2x + x – 7 = 0, then find the value of      
(A) 3
(B) –3
(C) 2
(D) –2
68. A matrix of order 3  3 are formed by using the elements of the set A = {–3, –2, –1, 0, 1, 2, 3},
then find the probability that the matrix is either symmetric of skew symmetric is
1 1
(A) 
76 73
1 1 1
(B)  
79 73 76
1 1 1
(C)  
73 76 79
1 1
(D) 
73 79
2
d
69. If  f  x   g  x  ; d  g  x   f  x2  , then d 2 f  x 3  can be expressed in the form
dx dx dx
kx a f  xb   px g  x x  where a, b, c, k, p  N, then the value of (k + p + a + b + c) equal to
(A) 26
(B) 27
(C) 28
(D) 30
70. If A and B are two square matrix such that A2B = BA and if (AB)10 = AkB10, then k is
(A) 1001
(B) 1023
(C) 1042
(D) 1025
x2 y2
71. Two perpendicular chords of the ellipse   1 (a > b) each passing through exactly one of
a2 b2
x2 y2 2
the foci meet at point P and PQ and PR are tangents to   1 , then 4 cosec (QPR) is
a2 b2
equal to
(A) 4
(B) 16
(C) 32
(D) 48
72. A circle touches the parabola y2 = 4x at (1, 2) and also touches it’s directrix, then the y-coordinate
of the point of contact of the circle and the directrix is
(A) 2
(B) 2
(C) 2 2
(D) 4
73. If x1, x2, x3 are non negative real roots of equation x 3 – 6x2 + 3px – 2p = 0 (p  R), then value of
 1 1  1  1  1  1 1
sin1     cos    tan    is equal to
x
 1 x 2  x
 2  x 3  x
 3 x1

(A)
4

(B)
2
3
(C)
4
(D) 
1
 n n n
74. 
lim   2009 
2010
    2010 2009
  is equal to ab (a, b  N), then a – b = ?
n
(A) 2009
(B) 1
(C) –1
(D) 0
x
75. f : R  R defined as f  x   x3  2x 2  4x  sin and g be the inverse of f, then g(8) equals
2
1
(A)
9
(B) 9
1
(C)
11
(D) 11
76. The maximum value of (cos 1)(cos 2)(cos 3) ..... (cos n) under the restrictions

0  1, 2, 3 ..... n  and cot 1  cot 2  cot 3 ..... cot n = 1 is
2
1
(A) n
22
1
(B)
2n
1
(C)
2n
(D) 1
77. The X – Y plane is rotated about it’s line of intersection with Y – Z plane by 45, then the equation
of new plane is
(A) z–x=0
(B) x–y=0
(C) y–z=0
(D) x+y+z=0
        
78. If a r b , then vector v in terms of a and b satisfying the condition v  a and v  b = 1 and
  
 v a b   1 is
  
b ab
(A) 2   2
b ab
  
b ab
(B)    2
b ab
  
b ab
(C) 2   
b ab
 
 a  b
(D) b  
ab
79. Which of the following is not tautology?

(A) (p  q)  p
(B) (p  q)  (p  ~q)
(C) p  (p  q)
(D) (p  q)  (~p  q)
80. The mean of two samples of sizes 200 and 300 were found to be 25 and 10 respectively, their
standard deviations were 3 and 4 respectively the variance of combined sample size of 500 is
(A) 64
(B) 65.2
(C) 67.2
(D) 64.2
SECTION – B
1 a
 x 2010  x804  x 402   2x1608  5x 402  10  402 1  2010
 5x 804  10x 402  402 , then find the
81. If  =
10a
2x
value of a
82. The sum of the squares of the lengths of the chords intercepted by the family of the lines x + y = n
(n  N) from the circle x2 + y2 = 4 is
x2 y2 x2 y2
83. Let t and f(t) be the eccentricities of the ellipse   1 and  1
3b2  2a2 2b2  a2 2b2  a2 b2
1
2
where b2 > a2 (a  0) respectively, then  fofofof  t  dt is equal to
0
1
4
  4x  f  x   f  x  dx 
3
84. If , then find the area of region bounded by y = f(x), x-axis and
7
0
coordinate x = 1 and x = 2
4 3 8  15 12  35
85. If the sum of first 84 terms of the series    ..... = 549k, then k is equal
1 3 3 5 5 7
to
1995 1995 1995

86. The digit at the unit place in the number 17   11  7
3a b c  1
 
87. If a, b, c  R and abc = 1 if A   b 3c a  and A T A  4 3 I & |A| > 0, then the value of
 c a 3b 
a3 + b3 + c3 is
88. Let circle S1 and S2 on argand plane be given by |z + 1| = 3 and |z – 2| = 7 respectively. If a

variable circle (S) |z – z0| = r be inside circle S2 such that it touches S1 externally and S2
internally, then the locus of z0 describes a conic E. If eccentricity of E can be written in simplest
p
from as , then find p + q is (where p, q  N)
q
89. A curve y = f(x) is passing through (2, 0) and slope of it’s tangent at any point (x, y) is
 x  12  y  3 m
, then the area bounded by the curve y = f(x) and x-axis is (where HCF of m
x 1 n
and n is 1), then value of m + n is
90. Consider two numbers N1 = 1083 and N2 = 1070 the probability that a randomly chosen positive
1
divisor of N1 is an integer multiple of N2 is , then  is equal to
9
FIITJEE
FULL TEST – XI
JEE (Main)-2022
TEST DATE: 17-04-2022

Physics PART – A
SECTION – A
1. B
  
Sol. Velocity of rain with respect to car v RC  v R  vC should be 
vC = 4m/s
perpendicular to the wind screen. 90°

From figure,  wind screen
v 12 
tan   r  vRC 
vR =12m/s
vc 4
  tan 1 (3)
2. A
Sol. PV = RT for 1 mole
RT
W   PdV   dV
V
V  CT 2/3
2 dV 2 dT
 dV  CT 1/3 dT or 
3 V 3 T
2 T
 2  dT 2
 W   RT    R(T2  T1 )  166.2 J
T1 3 T 3
3. B
Sol. vb = 20 m/s < 5g
 Particle leaves the circular path.
AITS-FT-XI-PCM(Sol.)-JEE(Main)/22 2
2
20  g(2  3 cos )  cos  
3
20 2
Velocity at top =  
g cos  cos  
3 3
m/s
4. A
1
Sol. mR 2 
R1/ n
5. C
m v=0
Sol. Volume of ball V  g
 H
Acceleration of ball inside the liquid
h
F upthrust  weight a
a  net 
m m
m
 (5 )( g )  mg
or a 
 = 4g (upwards)
m
 Velocity of ball while reaching at surface
v  2ah  8 gh
 The ball will jump to a height
v 2 8 gh
H   4h
2g 2g
6. C
Sol. At the top
mv 2
T  mg 
L
T  10mg
v  11gL
7. A
Sol. F = mg sin 
F = mg sin(+)
ma = mg( + ) 
2R
 x x
a  g   
 2R R  x
 3g  
a   x …(i) mg 
 2R 
a = 2x …(ii)
from equations (i) and (ii)
2R
T = 2
3g
3 AITS-FT-XI-PCM(Sol.)-JEE(Main)/22
8. D
5 
Sol. For fifth overtone  = 33 cm,  = 12 cm
2 4
at a distance 18 cm (= 3/2) from closed end node is formed
9. B
v0
Sol. Here u = v0, 0  
2R
At pure rolling,
F  v V  F   FR
v  v 0   1  t and   0   1  t (in pure rolling v = R) ( =  1 2
m R 2R  mR  I mR
v
 v0  v  v  0
2
v v
 2v  0  v  0
2 4
10. D
V 0.6
Sol. By using E   6  6  105 V/m
d 10
11. D
Sol. P = AT4
4
PA A A  TA  3/ 4
     TB  TA (2)
PB A B  TB 
 T
as mT = constant  A  B
B TA
3

 B = 5000(2) 4 Å
12. B
1 1 1 1 1 1
Sol.  RZ 2  2  2  and  RZ2  2  2 
k  1 2  k 1 3 
Dividing we get,
k  0.27 Å
13. B
Sol. Rearranging the circuit, we observed that C1 is joined directed to R C2
the cell and acquires its full charge when S is closed. It plays no
part in the charging of C2 through R.
So, q2 = Q0 1  e  t /  
C1
14. C
Sol. The current lags the emf by /2, so the circuit should contain only an inductor.
15. D
2 A
Sol. x  A sin t; for x 
T 2
A 2
  A sin t
2 T
T
Solving, t 
12
16. B
Sol. I1 = I and I2 = 4I
 Inet  I1  I2  2 I1I2 cos 
 IA = I + 4I = 5I ( A = /2)
and IB = I + 4I 2 4I  I  I (B = )
 IA  IB = 4I
17. A
Sol. I = Imax (1  e t /  )
18. C
Sol. miceSice(10) + miceLice = MLV + MSwater (100)
 3200(0.5) (10) + 3200(80) = m[540 + 100]
 m = 425 gm
19. D
Sol. For maximum current, net resistance of cell must be equal to 2.5
n(0.5)
i.e.  2.5 …(i)
m
and m  n = 45
solving, we get n = 15, m = 3
20. C
kq2  1 
Sol. F ; k  
r2  40 
kq2 mv 2
 2 
r RC
mv 2r 2 40 v 2r 2m
RC  ; R C 
kq2 q2
SECTION – B
21. 00002.50
Sol. Taking moments about the edge about which the cube is likely to tilt,
4 a
F  a  mg 
5 2
5
 F  mg
8
22. 00000.50
Sol. Let v be the velocity of centre of mass of ring just after the
impulse is applied and v is its velocity in pure rolling. v0 v
J  mv0 
J P P
v0 
m
Conserving angular momentum about point of contact with ground
mv0 r  mvr  I cm 
v0 J
 v 
2 2m
23. 00004.00
1 2 2 A 4 A 4 A 4
Sol. mv max  2 J , v max  2 m/s  A , vavg     m/s
2 T /2 T 2 
24. 00004.33
Sol. m1  1kg , m2  2kg , u1  3 ms 1 , u 2  2 ms 1
Initial momentum  ( m1u1 ) 2  ( m2 u 2 ) 2  9  16 = 5 kg ms–1
5
If combined velocity is v, (m1  m2 )v  5 , v  ms 1
3
1 2 1 2 1 2 13
Heat liberated = loss in kinetic energy  m1u1  m2u 2  ( m1  m2 )v  J
2 2 2 3
25. 00000.25
mv
2qB 1 
Sol. sin   
mv 2
qB
  = 45
T m
t 
8 4qB
26. 00100.00
Sol. At maximum depth the ray graze the surface (i.e. the angle made by the ray with normal will
become 90)
Applying snell’s law
 1 
1 sin 45   2  x  sin90
 2 
1 1
 2 x or x = 1 m
2 2
27. 00002.20
Sol. Energy released = (80  7 + 120  8  200  6.5) = 220 MeV
28. 00037.50
Sol. equivalent circuit is 10  15 
= 37.5 
20  30  15 
A 10  B
20  30 
29. 00012.00
Intensity of magnetistation(I)
Sol. () 
Magnetizing field(H)
Or, I = H
30. 00004.00
K.Emax
Sol. eV0 = K.  V0 
e
SECTION – A
31. B
Sol. If n – quantum number, then, n  2r   de  Broglie' s wavelength
n2 ao
r
Z
n2ao
n  2
Z
2nao
 Z  3 for Li2
Z
  2ao
2nao
2ao 
3
n3
32. C
Sol. 500 ml of water contains 24 mg of MgSO 4
 1000 ml of water contains 24  2  48 mg of MgSO 4
48
48 mg MgSO 4  gm MgSO4
1000
 0.048 gm MgSO4
0.048
Number of moles of MgSO 4 
120
 4  104 mole
i.e. number of moles of CaCO3 (hypothetical) would be 4  104 in 1 litre.
Mass of CaCO3  4  104  100  0.04
= 40 mg.
 Hardness in ppm = 40
33. C
Sol. Cl Cl
Be Be Be
Cl Cl
3
Be is sp hybridised.
H
H H
B B
H H H
The bridge H forms longer bond
O O
H
o H
94.5
o
O 101.9
O
H
Gas H
Solid
The angle between H – O and O – O are not the same in solid and gas.
O O
O O O O
O3 is polar, as there is a charge separation and the molecule is bent.
34. D
2 3
Sol. 1 H and 2He are isotones as they have same number of neutrons but different mass number.
37 39
17 Cl and 18 Ar are isodiaphers as they have same excess of neutron over protons (A – 2Z).
7 7
3 Li and 4Be are isobars as they have same mass number but different atomic numbers. Mirror
nuclei have equal mass numbers but their atomic numbers differ by 1.
2 3
1 H and 2He can not be mirror nuclei as mass numbers are different.
35. D
Sol. 5 3
NO3  NH4
8
36. A
1
Sol. 10 milimoles of H3PO 4  20  2
10
Milimoles of NaOH = 4
H3PO 4  NaOH  NaH2PO 4  H2 O
2 4 2
0 2 2
NaH2PO4  NaOH  Na2HPO4  H2O
2 2 4
i.e. the resulting solution contains 4 milimoles of Na2HPO 4 .
pK 2  pK 3
i.e. pH of the solution 
2
7  13
  10
2
37. B
Sol. MO22  e  MO 2 Eo  0.97 V G1o
MO2  4H  e  M4  2H2O Eo  Eo2 G2o
M4  e  M3 Eo  1.01 V Go3
MO22  4H  3e  M3 Eo  1.02 V Go
G1o  G2o  G3o  Go
F   0.97   F  Eo2  F  1.01  1.08
Eo2  1.08 V
38. D
Na
Sol. C  N  S   NaCNS
3NaCNS  FeCl3  Fe  CNS 3  3NaCl
Red colour 
39. D
Sol. n3 P1  10 atm T1  300K, CP  29.13 JK 1
Wirr  P2  V2  V1   nCV  T2  T1 
 nRT2 nRT1 
P2     nCV  T2  T1 
 P2 P1 
 P 
R  T2  T1 2    CP  R  T2  T1 
 P1 
 1
8.314  T2  300     29.13  8.314  T2  300 
 10 
T2  222.94 K  223 K
40. C
Sol. Let,  be the degree of dissociation of K 4 Fe  CN6 
4
K 4 Fe  CN6   4K   Fe  CN 6 
1    4 
i
1     4    1  4
1
  0.5
i  1  4  0.5
=3
41. A
Sol. Factual
42. B
Sol. CN is a strong field ligand. Greater be the oxidation state, greater be o .
43. B
Sol. Ag2C2O 4 

 2Ag  2CO2
44. D
Sol. Planarity at the bridgehead position is not permitted. However, the flexibility of the molecule is
increased as number of carbon atoms in the bridge increases.
45. C
Sol.
O H O O O O
C CH CH HC O
 i
HO OH 4 ii LiAlH iii H O
    3


H
COOEt COOEt CH2OH CH2OH
46. D
Sol. Greater be the stability of carbocation, greater be the rate of solvolysis.
Aromatic
CH2
Stabilised through +R effect of benzene ring.
Anti-aromatic.
47. C
Sol. Cu2   S 2   CuS Hot conc.
  Cu NO3  2  H2 S
HNO3
Black precipitate  White precipitate
48. D
Sol.
OH OH 2
N H N


H
N O
H
H
O H OH
N N
H
O
N
49. A
Sol. O is more electronegative than N. In R, the +R effect of OCH3 reduces reactivity of carbonyl
group.
50. A
Sol. O O
O H O
OH 
 H2 C Ph
OH OH
more acidic Br
OCH2Ph
OH
SECTION – B
51. 00003.22
2.19  4.25
Sol. PHI 
2
= 3.22
52. 00004.98
8.8
Sol. n  0.2 T  273  31.1  304.1
44
P  1 bar  1 atm
nRT 0.2  0.082  304.1
V 
P 1
 4.98 
53. 00016.083
Sol. Ptotal  0.2 bar
At equilibrium, PCO2  PH2 O  0.1 bar
2
KP  PCO2 .PH2O   0.1  0.01 bar
Go  RTnK eq  8.314  420  2.303log  0.01
= 16.083 kJ.
54. 00005.76
Sol. 9.8 gm X was present
O H3C CH3
OH
1. CH3 MgBr Conc. H2 SO4


2. HCl
  

9.8 gm A B
 0.1 mole 0.075 mole 0.06 mole
Amount of B formed = 0.06  96  5.76 gm
55. 00000.39
Sol. K a  HA   10 7 , K b BOH  10 5
o
Ecell 
0.06
log
H 
 RHS PH2   LHS
2
2 H 
 LHS PH2   RHS
OH   Kb C OH   103

 
   
11
H 
 LHS  10
4
H 
 RHS  K a C  10
2
Ecell 
0.06
log
 
104  0.1
 0.39 V
2
2

10 11 
56. 00006.46
 n2a 
Sol.  P  2   V  nb   nRT
 V 
n2a nRT
  P
V2 V  nb
2
 nRT V
a  P 2
 V  nb n
V  4, P  11 atm, n  2, b  0.05, R  0.082
a  6.46
57. 00055.87
0.7
Sol. k1  T1  300 K
20
0.7
k2  T2  320 K
5
k 2 Ea  1 1
n    
k1 R  T1 T2 
RT1T2 k
Ea  n 2
 T2  T1  k1
8.314  320  300
  n4
20
= 55.87 kJ/mol
58. 00101.785
Sol. For Na3PO4 i  1  3  1  3  0.5  2.5
MgSO 4 i  1.6
100 gm solution contains 8.2 gm Na3PO4 and 12gm MgSO4
Tb  iK bm
 8.2 12 
 164  2.5  120  1.6 
 0.5    1000
 79.8 
 
 1.785o C
Boiling point  100  1.785  101.785o C
59. 00135.96
Z M  2 96
Sol. a3    
d  NA  10.3 6  1023
3a
a  314 pm, r  135.96 pm
4
60. 00002.66
Sol. O
Cr
O
O O
2x
x4  2.66
3
SECTION – A
61. D
Sol. Let x – 3 = X ; y – 1 = Y, then |X + Y| = 5 and |X| + |Y| = 5
Hence, total 12 ordered pairs
62. B
3n3  4
 n  4n4 1
Sol. Let y  lim  n 
n   n 
1
3n3  4  n 3 3
log y = lim
n 4
4n  1
log  n  =
n  4
0

log x dx  
4
3

 ye 4
63. C
1 1
Sol. f(x) = 1 + Ax + Bex where A  e y f  y  dy ; B  yf  y  dy
 
0 0
1 1
A  e y 1  Ay  Be y  dy ; B  y 1  Ay  Bey  dy
 
0 0
3 2
A ; B
2 e1
3 2e x
h(x) > 0  f(x) + 3 > 0    3 0
2 e 1
3 4 4 
e x   e  1 ; e x   e  1   ek   3
4 3 3 
64. B
Sol. f(x) = |x – a| + |x – b| 2x – a – b
a + b – 2x
f(0) = f(1) = f(–1)
Let a > b
f(x) is constant in [b, a]
b  –1 and a  1 minimum |a – b| = 2
b a
65. C
p b c
Sol. ab qb 0  0 (R3  R3 – R2 and R2  R2 – R1)
0 bq r c
p b c
pa qb rc
(p – a)(q – b)(r – c) 1 1 0
0 1 1
 p b c 
(p – a)(q – b)(r – c)    0
pa qb r c 
p b c p  b   c 
   0 ;   1    1  2
pa qb r c pa qb  rc 
p q r
  2
pa qb r c
66. C
Sol. Following cases (x  stands for H or T any one)
m
1
HH ..... H x x x x .....    1
m times 2
m
1  1
T HHH .....  x x x x x .....  1     1
m times 2 2
m
1  1
x T HHH ..... m times  x x x .....  1    1
2 2

m m m 1 m
 1  1  1  1  n n2
x x x ..... T HHH .....   1   =    n  =   1   = m 1
m times 2 2 2  2   2 2
67. B
1 1 1      
Sol.        
    3     
        
        
     
   3

  
 

       
0 3


   ;


      3
 
68. C
76 1
Sol. Probability matrix is symmetric = 9

7 73
73 1
Probability matrix is skew symmetric = 9

7 76
One matrix containing all 0 is common in both
1 1 1
Required probability = 3  9  9
7 7 7
69. C
Sol. f(x) = g(x)
2 3
g(x) = f(x ) = f(x) let y = f(x )
dy
 f   x3  3x 2
dx
d2 y
2
 3 3x 2 x 2 f   x 3   2xf   x 3   = 9x 4 f   x 3   6x f   x 3  = 9x 4 f  x 6   6x g  x 3 
dx
k+p+a+b+c=9+4+6+6+3
70. B
3 2
Sol. (AB)(AB) = A(BA)B = A B
3 2 3 3 2 3 3 2 7 3
AB AB AB = A B AB = A B(BA)B = A B A B B = A (BA) AB B = A A (BA) B B = A B
 AB n  A  2 1
n
Bn . If n = 10  k   210  1  1023
71. A
Sol. Equation of two chords are y = m(x – ae) ..... (1)
1
y    x  ae  ..... (2)
m
Multiply equation (1) and (2), we get x 2 + y2 = a2e2  x2 + y2 = a2 – b2
Which is director circle of the hyperbola
72. C
Sol. Tangent at (1, 2)
2y = 2(x + 1)
y=x+1 (1, 2)
Equation of circle
(x – 1)2 + (y – 2)2 + (x – y + 1) = 0 ..... (1)
Put x = –1
y2 – 4y – y + 8 = 0
D = 0  ( + 4)2 = 32
  4 4 2
y  y  2 2
2 2
73. A
x1  x2  x3 3
Sol. Let x1, x2, x3 are roots of equation A.M.  2 ; H.M 2
3 1 1 1
 
x1 x 2 x 3
A.M = H.M ; x1 = x2 = x3 = 2
 1 1  1  1 1  1  1 1   
Hence, sin1     cos     tan    = 0 
 x1 x 2   x 2 x3   x 2 x1  2 4 4
74. C
1 1
2009 2010
Sol.   2010  2010   2009  2009 ;  2010    2009 
1
1 n n
 
 n n n  2010 2009 
 lim   2009      2010 2009  
2010 2010  

; lim 2009  1  
n n    2009 2010  
   
 2009 2010  ab ; a = 2009 ; b = 2010  a – b = –1
75. C
1 1  1  1
Sol. g  y   ; g  8   =   =
f  x f  1  x   11
 3x2  4x  4   cos  
  2  2  x 1
76. A
Sol. cot 1  cot 2  cot 3 ..... cot n = 1
cos 1  cos 2  cos 3 ..... cos n = sin 1  sin 2 ..... sin n
Let y = cos 1  cos 2 ..... cos n
y = sin 1  sin 2 ..... sin n
sin21  sin 2 2 .....sin2n

y2 
2n
1 1
Maximum of y 2  n
; maximum of y 2  n
2
22
77. A
Sol. Equation of family of plane passing through intersection of X – Y plane and Y – Z plane is z + x
= 0 this plane makes an angle 45 with the xy plane (z = 0)
1
cos 45  ;  2  1  2 ; 2  1  2 ;  =  1
2
1  1
Hence, plane are z + x = 0 ; z – x = 0
78. A
         1
Sol. Let v  xa  yb  z a  b  ; v  a  0  x  0 ; v  b  1  y   2
b
  
     2 1  b ab
v  a  b  z a  b   1 ; z  ; v 2 
 2  2
ab b ab
79. B
Sol. (p  q)  (p  ~q)
p q pq p  ~q
T T T T
T F T T
F T T F
F F F T
80. C
n1x1  n2 x2 80
Sol. Combined mean x    16
n1  n2 5
d1  x1  x  25  16  9
d2  x2  x  10  16  6
Combined mean 2 
  
n1 12  d12  n2 22  d22 = 200  9  81  300 16  36 
= 67.2
n1  n2 500
SECTION – B
81. 00403.00
1
Sol.
 x  x 2009  x 803  x 401   2x1608  5x 402  10  402 dx
1
 x 2009  x803  x 401   2x2010  5x804  10x 402  402 dx


Put 2x 2010  5x804  10x 402  t
 a = 403
82. 00022.00
n
Sol.  2  n < 2 2 ; n = 1 or 2
2
Length of chord = 16  2n2 the sum = 22
83. 00000.25
2b2  a2 b2  a2 2
b2  a2
 t   1  b
2
Sol. t2  1  2  ;  f 
3b  2a2 3b2  2a2 2b2  a2 2b2  a2
t2 t t
 f  t  2  2
and f(t) > 0 ;  f  t    ; fof  t  
1 t 1 t 2
1  2t 2
1
2
t 1
fofofof  t  
1  4t 2
;  fofofof  t  dt  4  0.25
0
84. 00007.50
1 a 1
4 2 4
  4x f  x   f  x   4x  4x  dx    f  x   2x 
3 2 6 6
Sol. ;  4x 6 dx  3
dx 
7 7
0 0 0
1 2
2 15
  f  x   2x 
3 3
0
dx  0  f(x) = 2x ;  f  x  dx 
0
2
85. 00002.00
a2  b2  ab a3  b3
Sol.  2 ; 549k = 1098  k = 2
ab a  b2
86. 00001.00
Sol.  7  10 1995  1  10 1995   7 1995 = (a number of multiple of 10) + 1
Unit place digit is 1
87. 00009.00
3a b c 
  3 3 3
Sol. A   b 3c a  ; det(A) = 29abc – 3(a + b + c )
 c a 3b 
1
2
A T A  4 3 I ; AT A  4 ; A  4 ; |A| = 2
3 3 3
a +b +c =9
88. 00013.00
Sol. cc1 = r + r1
cc2 = r2 – r C1(–1, 0)
r
cc1 + cc2 = r1 + r2
Locus of c is an ellipse with focus c1 and c2 C(h, k)
r1 + r2 = 2a = 10 C2(2, 0)
r
|c1c2| = 2ae = 3
3
e
10
p + q = 13
89. 00007.00
Sol. f(2) = 0
2
dy  x  1  y  3
 ; let x + 1 = X and y – 3 = Y
dx x 1
dY X2  Y Y dY Y d Y
  X ;  X ;   1
dX X X dX X dX  X 
Y 2
 X  c ; (y – 3) = (x + 1) + c(x + 1)
X
Put (2, 0) y = x2 – 2x
4
x = –4 A
3
90. 00004.00
83 83 83
Sol. N1 = 10 = 2 5
70 70 70
N2 = 10 = 2 5
So, divisor are of type 29 56
0  a, b  83 (for N1)
For multiple of 1070  70  a, b  83
14  14 1
Probability =    = 36
84  84 36

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FIITJEE

ALL INDIA TEST SERIES

Section – A (Maximum Marks: 12)

(A) If Z 1  Z 2 then   1   min     2   min 

(B) If Z 1  Z 2 then   1   min     2   min 

2. In a YDSE experiment, the two slits are covered with a Screen

(A) 0.58 cm above the central line of slits

(B) 0.58 cm below the central line of slits

(C) 1.66 cm above the central line of slits

(D) 1.66 cm below the central line of slits

Sol. If central maxima is formed at point P on the screen, then P Screen

(A) 2.5 m/s

Section – A (Maximum Marks: 24)

7. In the given figure a block A rests on a smooth triangular

(A) normal force on block A due to block B is m g  a 

(B) acceleration of block A relative to block B is a cos .

Sol. From FBD of A with respect to B N

8. Three particles each of mass m, can slide on fixed frictionless circular A v0

(A) the velocity of B immediately after impact is v0

9. Two concentric spherical shells masses m1 and m2 and radii r1 and

(A) outer shell will have no contribution in gravitational field at point P

(B) force on P is directed towards O

Sol. Gravitational field intensity inside the spherical shell is zero.

10. A small solid ball of density  is held inside at point A a cubical P Q

(A) For ball to hit the top of container at end Q, a = 3g

Sol. F.B.D. of ball in frame of container 4Vg

Section – B (Maximum Marks: 12)

11. Inner surface of a cylindrical shell of length l and of material of thermal T1 T2

Section – C (Maximum Marks: 12)

Question Stem for Question Nos. 14 and 15

A U-shape wire is formed by connecting a resistance R with two parallel B

14. The value of mass m is

15. The value of terminal velocity vT is

Sol. (Q.14 & 15)

A solid cylinder of mass m and radius R is kept at rest on a plank of m

16. Acceleration of cylinder with respect to earth is

17. Acceleration of plank with respect to earth is

Question Stem for Question Nos. 18 and 19

18. The time after which photomission will stop is

Sol. Rate of photo emission at time t

Section – A (Maximum Marks: 12)

20. Which of the following is NOT correct about hydrides ?

(B) I and III

(C) III only

Sol. BeH2 is polymetric while MgH2 is monomeric

21. What is the major organic product of the following reaction?

Section – A (Maximum Marks: 24)

(A) OCH3 groups in both cases occupy the same position

25. Identify the incorrect statement/s

(A) Combustion of methane in an adiabatic rigid container will cause no change in

(B) Dimerization of acetic acid causes an increase in entropy of the system

(D) P – V work is always non-zero when there is a change in volume.

Sol. (A) Combustion of CH4 is exothermic so temperature will increase

(A) Collisions are always elastic

(B) heavier molecules transfer more momentum to the wall of container

(C) Only a small number of molecules have high velocity

27. Ethyl acetoacetate gives the test of:

C O and C OC2H5 groups

(B) CH  CH and OH groups