mcq3 - D27 Sep 2024
mcq3 - D27 Sep 2024
mcq3 - D27 Sep 2024
1. ) What is the atomic number of an element of M2+ ion. Whose electronic structure is [Ar]3d8 ?
(A) 27 (B) 25 (C) 26 (D) 28
2. ) Which of the following is alloy of Sn ?
(A) Bronze (B) Brass (C) German-silver (D) Stainless steel
3. ) Which of the following option is the correct order for the basic strength of metallic hydroxides ?
(A) Al(OH)3 < Lu(OH)3 < Ce(OH)3 < Ca(OH)2 (B) Ca(OH)2 < Al(OH)3 < Lu(OH)3 < Ce(OH)3
(C) Lu(OH)3 < Ce(OH)3 < Al(OH)3 < Ca(OH)2 (D) Lu(OH)3 < Ce(OH)3 < Ca(OH)2 < Al(OH)3
4. ) Which of the following is a transition element as per the ground state electronic configuration ?
(A) Au (B) Hg (C) Cd (D) Zn
5. ) Which of the following compound is used in gas lighter ?
(A) CeO2 (B) Pyrophoric misch metal
(C) Nichrome (D) Nitinol
6. ) Which of the following ion has the maximum theoretical magnetic moment ?
(A) Fe3+ (B) Cr3+ (C) Ti3+ (D) Co3+
7. ) Which of the following statement is incorrect for KMnO4 ?
(A) It is an oxidising agent. (B) It is used as antiseptic.
(C) It is used as bleaching agent in textile industries. (D) It is dark purple coloured amorphous substance.
8. ) Which of the following oxide has the maximum basicity ?
(A) La2O3 (B) Pr2O3 (C) Sm2O3 (D) Gd2O3
9. ) Which statement is not suitable for interstitial compounds ?
(A) They are hard due to localisation of free electrons.
(B) Chemical bond is formed between metal & non-metal atom.
(C) The proportion of components is not definite is such compounds.
(D) They are resistant to wear and corrosion.
10. ) Which alloy does not contain Ni meatal ?
(A) German silver (B) Bronze (C) Stainless steel (D) Nichrome
11. ) Which statement is incorrect with reference to inner transition elements ?
(A) Pm is radioactive element among actinoids
(B) Only in the electronic configuration of lanthanoids like Ce, Gd and Lu the electrons are filled
in 5d orbitals
(C) The values of ionisation enthalpy of actinoids are less than the values of ionisation enthalpy of
lanthanoids.
(D) The oxides of lanthanoids are basic.
12. ) Which of the following is the correct order for theoretical magnetic moment ?
(A) Cr3+ = Mn2+ < Fe3+ (B) Cr3+ < Mn2+ < Fe3+ (C) Cr3+ < Mn2+ = Fe3+ (D) Cr3+ > Mn2+ = Fe3+
13. ) Which of the following pair possess same magnetic moment ?
(A) Cr3+, Mn3+ (B) Fe3+, Mn2+ (C) Fe2+, Mn2+ (D) Ni2+, Co2+
CGM
14. ) Element A and B do not form an alloy because...
(A) Both elements have similar crystal structures.
(B) Radius of A is 115 pm while radius of B is 187 pm.
(C) Both are the members of same group.
(D) Both have similar electronic configuration in valence shell.
15. ) The divalent ion of which of the following element in aqueous solution has magnetic moment 5.92
BM ?
(A) Co (B) Cr (C) Fe (D) Mn
16. ) Although Zirconium belongs to 4d-transition series and Hafnium belongs to 5d-transition series, even
then show similar physical and chemical properties because.....
(A) Both belongs to d-block.
(B) Both have same number of electrons.
(C) Both have similar atomic radius.
(D) Both belongs to the same group of the periodic table.
17. ) Which product is obtained during reaction of MnO4– with I– in faintly alkaline condition ?
(A) I2 (B) IO– (C) IO3– (D) IO4–
18. ) Identify the incorrect statement :
(A) Atomic sizes of elements of ‘4d’ series are greater than corresponding ‘3d’ series.
(B) ‘Cd’ is not a transition element.
(C) CrO is basic, but Cr2O3 is amphoteric.
(D) Atomic sizes of elements of ‘5d’ series are greater than corresponding ‘4d’ series.
19. ) The transition element that does not exhibit variable oxidation state is......
(A) Sc (B) Cu (C) Zn (D) Cr
20.
145) When alkaline KMnO4 is treated with KI, Iodide ion is oxidised to ........
(A) IO3– (B) IO– (C) I2 (D) IO4–
21. ) In the electronic configuration of which of the following element-electron is arranged in 5d-orbital ?
(A) 65Tb (B) 64Gd (C) 63Eu (D) 66Dy
22. ) What is responsible from the following for innertransition elements having +3 stable oxidation
state ?
(A) Ionisation energy (B) Hydration enthalpy
(C) (A) and (B) both (D) Electronic structure
23. ) Which is not innertransition compound ?
(A) TiC (B) VC (C) WC (D) SiC
24. ) Aqueous solution of which element is coloured ?
(A) TiCl2 (B) ZnCl2 (C) CdCl2 (D) Hg2Cl2
25.0) Which of the following is electronic configuration of Palladium (Pd), an element of second transition
series ?
(A) [Kr] 4d9 5s1 (B) [Kr] 4d10 5s0 (C) [Kr] 4d8 5s2 (D) [Xe] 3d10 5s0
26. ) What is the experimental value of magnetic moment of metal ion in [Fe(CN)6]4– ?
(A) 4.90 BM (B) 5.00 BM (C) 0.00 BM (D) 5.92 BM
27. ) Which of the following substance is used in measurement of Chemical Oxygen Demand (COD) in
polluted water ?
(A) H2SO4 (B) KMnO4 (C) MnO2 (D) K2Cr2O7
28. ) Which of the following alloy does not contain Copper ?
(A) Nichrome (B) Bronze (C) Brass (D) German Silver
CGM
) Which of the following alloy does not contain Copper ?
(A) Nichrome (B) Bronze (C) Brass (D) German Silver
29. ) An alloy of which of the following metals is used in filling the cavity in the tooth ?
(A) Hg, Ag, Sn, Cu, Ni (B) Hg, Au, Sn, Cu, Ni (C) Hg, Al, Sn, Cu, Zn (D) Hg, Ag, Sn, Cu, Zn
30. ) Which of the following ion has maximum Second ionisation enthalpy ?
(A) V+ (B) Sc+ (C) Cr+ (D) Mn+
31. ) Which of the following mixture of metals can not form alloy ?
(A) Ni + Mg + Cr (B) Au + Cu + Cr (C) Fe + Cr + Cu (D) Ni + Cu + Cr
32. ) What is the colour of K2MnO4 ?
(A) Red (B) Violet (C) Green (D) Blue
33. ) Which of the following alloy is not used to make resistance wire ?
(A) Nitinol (B) German silver (C) Nichrome (D) Cupronickel
34. ) Choose correct option for the statements given below.
(Correct statement - T, incorrect statement - F)
(i) Electronic configuration of transition metal ion is suitable for formation of complexes.
(ii) A chemical bond is formed between non-metal and metal atoms in interstitial compounds.
(iii) Crystal structures of Cu and Au are different.
(A) T F F (B) F T T (C) T F T (D) T T F
35. ) Which colour will be observed when Manganese dioxide is fused with KOH in presence of O 2 ?
(A) Purple (B) Green (C) Orange (D) Red
36. ) The theoretical magnetic moment of 27Co is 3.87 B.M. Which one is the correct compound from
the following ?
(A) Co(NO3)2 (B) CoCl3 (C) [CoF6]2– (D) [Co(NH3)6]3+
37. ) Which of the following alloys does not contain zinc ?
(A) The mixture used in filling cavity in the tooth (B) Bronze
(C) Brass (D) German silver
38. ) The magnetic moment of a compound of cobalt is 3.87 BM, the compound is ..........
(A) [Co(H2O)6]+3 (B) [Co(CN)6]3– (C) Co(NO3)3 (D) [Co(H2O)6]+2
39. ) Which of the following ion is colourless ?
(A) Sc3+ (B) Ti3+ (C) Mn2+ (D) Cu2+
40. ) Which of the following is the least basic ?
(A) Yb(OH)3 (B) Ce(OH)3 (C) Nd(OH)3 (D) Gd(OH)3
41. ) Which of the following is general electronic configuration of Actinide series ?
(A) [Rn] 5f 0–146d0–27s2 (B) [Xe] 4f 0–145d0–106s2
(C) [Rn] 5f 0–145d0–26s2 (D) [Xe] 4f 0–145d0–16s2
42. ) What is the colour of [Ti(H2O)6]3+ complex ion ?
(A) Blue (B) Violet (C) Pink (D) Green
43. ) Which compound of lanthanoid is used to produce very low temperature by magnetic effect ?
(A) Cerium dioxide (B) Oxides of Lanthanoids
(C) Gadolinium sulphate (D) Cerium sulphate
44. ) Which ion has magnetic moment 5.90 BM ?
(A) Mn4+ (B) Fe3+ (C) Co2+ (D) Fe2+
45. ) Which of the following ion will not form coloured aqueous solution ?
(A) Cu2+ (B) Fe3+ (C) Ti4+ (D) Ni2+
CGM
46. ) Which of the following ion has the maximum theoretical magnetic moment ?
(A) Ti3+ (B) V3+ (C) Cr3+ (D) Co3+
47. ) The correct order of catalytic activity of Cr, V, Fe and Mn metals in increasing order is ........
(A) Fe < Mn < V < Cr (B) V < Fe < Cr < Mn (C) Cr < V < Fe < Mn (D) V < Cr < Mn < Fe
48. ) Which among the following elements is radioactive ?
(A) Pm (B) La (C) Tm (D) Pr
49. ) Which of the following metals are present in German Silver ?
(A) Nickel, Silver and Copper (B) Zinc, Silver and Copper
(C) Germanium, Silver and Copper (D) Zinc, Nickel and Copper
50. ) Which of the following statements is incorrect ?
(A) The ionic size decreases as we move from Ce3+ to Lu3+
(B) The atomic radius decreases as we move from Ce to Lu
(C) Ce(OH)3 is the least basic among the hydroxides of Lanthanoids
(D) The stable oxidation state of all Lanthanoids is (+3)
51. ) What is the magnetic momentum of cuprous chloride on the basis of the axial rotation ?
(A) 1.73 BM (B) 4.90 BM (C) 0.0 BM (D) 2.83 BM
52. ) Assertion [A] : Atomic radii from Cr to Cu is almost similar.
Reason [R] : Sheilding effect of entering electron in 3d-orbital decrease repulsion forces of 4s-orbital
electrons towards nucleus.
(A) [A] and [R] both are true, [R] is correct explanation of [A].
(B) [A] is true, [R] is wrong.
(C) [A] and [R] both are true.
(D) [A] is wrong, [R] is true.
53. ) Which are the correct uses of potassium dichromate from the following ?
(i) As an indicator in redox titration
(ii) As a reagent in COD measurement
(iii) As reducing agent in synthesis of organic compounds
(iv) In leather industry
(A) (i) (B) (ii) and (iv) (C) (i) and (iii) (D) (i), (ii) and (iii)
54. ) The magnetic moment of a divalent ion in aqueous solution if its atomic number is 25 :
(A) 2.84 BM (B) 5.92 BM (C) 4.90 BM (D) 3.87 BM
55. ) Which of the following is amphoteric oxide ? Mn2O7, CrO3, Cr2O3, CrO, V2O5, V2O4
(A) V2O5, Cr2O3 (B) CrO3, V2O4 (C) Mn2O7, CrO (D) Cr2O3, Mn2O7
56. ) Which of the following element having one electron in 5d-orbital in its electronic configuration ?
(A) Pm (B) Tb (C) Nd (D) Gd
57. ) What is the equivalent weight of K2Cr2O7 in acidic medium, if its molecular weight is taken as “M” ?
M M M
(A) M (B) (C) (D)
3 5 6
58. ) Highest oxidation state of manganese in fluoride (MnF4) is Mn+4 but highest oxidation state in
oxides (Mn2O7) is Mn+7 because.....
(A) Fluorine is more electronegative than oxygen.
(B) Fluorine does not possess d-orbitals.
(C) In covalent compounds fluorine can form single bond only while oxygen forms double bond.
(D) Fluorine stabilizes lower oxidation state.
59. ) What is the electronic configuration of Cr ?
(A) [Ar] 3d5 4s1 (B) [Ar] 3d5 4s0 (C) [Ar] 3d4 4s2 (D) [Ar] 3d4 4s0
CGM
) What is the electronic configuration of Cr ?
(A) [Ar] 3d5 4s1 (B) [Ar] 3d5 4s0 (C) [Ar] 3d4 4s2 (D) [Ar] 3d4 4s0
184) Cu2+ aqueous solution has ......... colour.
60.
(A) Violet (B) Green (C) Blue (D) Yellow
61. ) Which of the following compound has the highest magnetic moment ?
(A) MnSO4 (B) Ni(NO3)2 (C) CrCl3 (D) FeSO4
62. ) Which is transition element ?
(A) Zn (B) Cd (C) Hg (D) Cu
63. ) Colour of K2MnO4 is ......
(A) violet (B) green (C) blue (D) red
64. ) From the following which ion has lowest magnetic moment ?
(A) Ti 3+ (B) Co3+ (C) Cr3+ (D) Fe3+
65. ) Which compound's aqueous solution is colourless ?
(A) CuSO4 (B) MnSO4 (C) NiSO4 (D) ZnSO4
66. ) Which ion has highest ionisation enthalpy ?
(A) Ti+ (B) V+ (C) Cr+ (D) Mn+
67. ) Which compound has magnetic moment equal to 4.90 BM ?
(A) FeSO4 (B) NiSO4 (C) MnSO4 (D) Cr2(SO4)3
68. ) Which oxidation state is common for lanthanoid elements ?
(A) +4 (B) +3 (C) +2 (D) +5
69. ) If “M” is the molecular weight of KMnO4, than what would be the equivalent weight of KMnO4 in
neutral solution ?
M M M
(A) (B) (C) (D) M
5 3 2
70. ) Which of the following metal ion has magenetic moment m = 4.90 BM.
(A) Co2+ (B) V2+ (C) Cu2+ (D) Cr2+
71. ) Which of the following compound is colourless ?
(A) TiO2 (B) TiO (C) Ti2O3 (D) V2O3
72. Electronic configuration of a transition element X in (+3) oxidation state is [Ar]3d5. What is its
atomic number ?
(A) 25 (B) 26 (C) 27 (D) 24
73. The electronic configuration of Cu(II) is 3d9 whereas that of Cu(I) is 3d10. Which of the following
is correct ?
(A) Cu(II) is more stable
(B) Cu(II) is less stable
(C) Cu(I) and Cu(II) are equally stable
(D) Stability of Cu(I) and Cu(II) depends on nature of copper salts
74. Metallic radii of some transition elements are given below. Which of these elements will have
highest density ?
Element Fe Co Ni Cu
Metallic radii/pm 126 125 125 128
76. On addition of small amount of KMnO4 to concentrated H2SO4, a green oily compound is obtained
which is highly explosive in nature. Identify the compound from the following.
(A) Mn2O7 (B) MnO2 (C) MnSO4 (D) Mn2O3
77. The magnetic nature of elements depends on the presence of unpaired electrons. Identify the
configuration of transition element, which shows highest magnetic moment.
(A) 3d 7 (B) 3d 5 (C) 3d 8 (D) 3d 2
78. Which of the following oxidation state is common for all lanthanoids ?
(A) +2 (B) +3 (C) +4 (D) +5
79. Which of the following reactions are disproportionation reactions ?
(a) Cu+ ® Cu2+ + Cu
4 + 4H ® 2MnO 4 + MnO2 + 2H2O
(b) MnO2– + –
81. There are 14 elements in actinoid series. Which of the following elements does not belong to this
series ?
(A) U (B) Np (C) Tm (D) Fm
82. KMnO4 acts as an oxidising agent in acidic medium. The number of moles of KMnO4 that will be
needed to react with one mole of sulphide ions in acidic solution is .......... .
2 3 4 1
(A) (B) (C) (D)
5 5 5 5
83. Which of the following is amphoteric oxide ?
Mn2O7, CrO3, Cr2O3, CrO, V2O5, V2O4
(A) V2O5, Cr2O3 (B) Mn2O7, CrO3 (C) CrO, V2O5 (D) V2O5, V2O4
84. Gadolinium belongs to 4f series. It’s atomic number is 64. Which of the following is the correct
electronic configuration of gadolinium ?
(A) [Xe]4f 7 5d1 6s2 (B) [Xe]4f 6 5d2 6s2 (C) [Xe]4f 8 6d2 (D) [Xe] 4f 9 5s1
85. Interstitial compounds are formed when small atoms are trapped inside the crystal lattice
of metals. Which of the following is not the characteristic property of interstitial compounds ?
(A) They have high melting points in comparison to pure metals.
(B) They are very hard.
(C) They retain metallic conductivity.
(D) They are chemically very reactive.
86. The magnetic moment is associated with its spin angular momentum and orbital angular
momentum. Spin only magnetic moment value of Cr3+ ion is ............ .
(A) 2.87 BM (B) 3.87 BM (C) 3.47 BM (D) 3.57 BM
87. KMnO4 acts as an oxidising agent in alkaline medium. When alkaline KMnO4 is treated with KI,
iodide ion is oxidised to ........... .
(A) I2 (B) IO– (C) IO–3 (D) IO–4
CGM
88. Which of the following statements is not correct ?
(A) Copper liberates hydrogen from acids.
(B) In its higher oxidation states, manganese forms stable compounds with oxygen and fluorine.
(C) Mn3+ and Co3+ are oxidising agents in aqueous solution.
(D) Ti2+ and Cr2+ are reducing agents in aqueous solution.
89. Highest oxidation state of manganese in fluoride is (+4)(MnF4) but highest oxidation state in oxides
is (+7) (Mn2O7) because ............
(A) Fluorine is more electronegative than oxygen.
(B) Fluorine does not possess d-orbitals.
(C) Fluorine stabilises lower oxidation state.
(D) In covalent compounds fluorine can form single bond only while oxygen forms double bond.
90. When acidified K2Cr2O7 solution is added to Sn2+ salts then Sn2+ changes to .......... .
(A) Sn (B) Sn3+ (C) Sn4+ (D) Sn+
91. Although Zirconium belongs to 4d transition series and Hafnium to 5d transition series even then
they show similar physical and chemical properties because ............ .
(A) Both belong to d-block.
(B) Both have same number of electrons.
(C) Both have similar atomic radius.
(D) Both belong to the same group of the periodic table.
92. Why is HCl not used to make the medium acidic in oxidation reactions of KMnO 4 in acidic
medium ?
(A) Both HCl and KMnO4 act as oxidising agents.
(B) KMnO4 oxidises HCl into Cl2 which is also an oxidising agent.
(C) KMnO4 is a weaker oxidising agent than HCl.
(D) KMnO4 acts as a reducing agent in the presence of HCl.
93. Generally transition elements and their salts are coloured due to the presence of unpaired electrons
in metal ions. Which of the following compounds are coloured ?
(A) KMnO4 (B) Ce(SO4)2 (C) TiCl4 (D) Cu2Cl2
94. Transition elements show magnetic moment due to spin and orbital motion of electrons. Which of
the following metallic ions have almost same spin only magnetic moment ?
(A) Co2+ (B) Cr2+ (C) Mn2+ (D) Cr3+
95. In the form of dichromate, Cr(VI) is a strong oxidising agent in acidic medium but Mo(VI) in MoO3
and W(VI) in WO3 are not because....
(A) Cr(VI) is more stable than Mo(VI) and W(VI).
(B) Mo(VI) and W(VI) are more stable than Cr(VI).
(C) Higher oxidation states of heavier members of group-6 of transition series are more stable.
(D) Lower oxidation states of heavier members of group-6 of transition series are more stable.
96. Which of the following actinoids show oxidation states upto (+7) ?
(A) Am (B) Pu (C) U (D) Np
97. General electronic configuration of actionoids is (n–2)f 1–14 (n-1)d0–2ns2. Which of the following
actinoids have one electron in 6d orbital ?
(A) U (Atomic no.92) (B) Np (Atomic no.93)
(C) Pu (Atomic no.94) (D) Am (Atomic no.95)
98. Which of the following lanthanoids show (+2) oxidation state besides the characteristic oxidation
state (+3) of lanthanoids ?
(A) Ce (B) Eu CGM (C) Yb (D) Ho
Which of the following lanthanoids show (+2) oxidation state besides the characteristic oxidation
state (+3) of lanthanoids ?
(A) Ce (B) Eu (C) Yb (D) Ho
99. Which of the following ions show higher spin only magnetic moment value ?
(A) Ti3+ (B) Mn2+ (C) Fe2+ (D) Co3+
100. Transition elements form binary compounds with halogens. Which of the following elements will
form MF3 type compounds ?
(A) Cr (B) Co (C) Cu (D) Ni
CGM
d & f mcq 3
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