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    DPP 14 Ionic Equilibrium

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    DPP 14 Ionic Equilibrium

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    DPP 14 Ionic Equilibrium

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    uddeshranaprsnl766s

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    © All Rights Reserved
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    Date of Discussion: 13-July 2021

    Marks: 64 Time: 30 min Challenger DPP No:14

    Batch: Spark & Legend Ionic Equilibrium Topic: Mixed Topics

    1. The solubility of PbCl2 in water is 0.01 𝑀 at 25℃. Its maximum concentration in 0.1 𝑀 NaCl will be:
    a) 2 × 10−3 𝑀 b) 1 × 10−4 𝑀 c) 1.6 × 10−2 𝑀 d) 4 × 10−4 𝑀
    2. The solution of AgCl is unsaturated if:
    a) [Ag + ][Cl− ] < 𝐾𝑠𝑝 b) [Ag + ][Cl− ] > 𝐾𝑠𝑝 c) [Ag + ][Cl− ] = 𝐾𝑠𝑝 d) None of these
    3. A decimolar solution of ammonium hydroxide is ionised to the extent of 1.3%. If log 1.3. If log 1.3 = 0.11,
    what is the pH of the solution?
    a) 11.11 b) 9.11 c) 8.11 d) Unpredictable
    4. 𝐾𝑐 for the reaction : [Ag(CN)2 ]− ⇌ Ag + + 2CN − , the equilibrium constant at 25C is 4.0 × 10-19, then the
    silver ion concentration in a solution which was originally 0.1 molar in KCN and 0.03 molar in AgNO3 is :
    a) 7.5 × 1018 b) 7.5 × 10−18 c) 7.5 × 1019 d) 7.5 × 10−19
    5. For which salt the pH of its solution does not change with dilution?
    a) NH4 Cl b) CH3 COONH4 c) CH3 COONa d) None of these

    6. Mohr’s salt is a:
    a) Normal salt b) Acid salt c) Basic salt d) Double salt
    7. The dissociation equilibrium of a gas AB2 can be represented as :
    2𝐴𝐵2 (g) ⇌ 2𝐴𝐵 (g) + 𝐵2 (g)
    The degree of dissociation is ′𝑥′ and is small compared to 1. The expression relating the degree of
    dissociation (𝑥) with equilibrium constant 𝐾𝑝 and total pressure 𝑝 is :
    a) (2𝐾𝑝 / 𝑃 )1/3 b) (2𝐾𝑝 / 𝑃 )1/2 c) (𝐾𝑝 /𝑃) d) (2𝐾𝑝 /𝑃)
    8. 𝐾sp for Cr(OH)3 is 2.7 × 10−31 . What is its solubility in mol/L?
    a) 1 × 10−8 b) 8 × 10−8 c) 1.1 × 10−8 d) 0.18 × 10−8
    9. The solubility of CaF2 is 2 × 10−4 mol/L. Its solubility product (𝐾sp ) is
    a) 2.0 × 10−4 b) 4.0 × 10−3 c) 8.0 × 10−12 d) 3.2 × 10−11
    10. SnCl2 and HgCl2 cannot co-exist in a solution because of:
    a) Common ion effect
    b) Le − Chatelier′s principle
    c) Conc. of Cl− increases to precipitate both
    d) Redox change
    11. 1 dm3 solution containing 10−5 moles each of Cl ions and CrO−2
    4 ions is treated with
    10− 4 moles of silver nitrate. Which one of the following observation is made?
    [𝐾sp Ag 2 CrO4 4 ∗ 10− 12 ]
    [𝐾sp AgCl 1 ∗ 10−10 ]
    a) Precipitation does not occur
    b) Silver chromate gets precipitated first
    c) Silver chloride gets precipitated first
    d) Both silver chromate and silver chloride start precipitating simultaneously

    Chemistry for IIT JEE Main & Advance MAHaqueSir @ Telegram


    12. In the system, CaF2 (𝑠) ⇌ Ca2+ (𝑎𝑞) + 2F − (𝑎𝑞), increasing the concentration of Ca2+ ions 4 times will
    cause the equilibrium concentration of F − ions to change to :
    a) ¼ of the initial value
    b) ½ of the initial value
    c) 2 times of the initial value
    d) None of the above
    13. 10−6 𝑀 HCl is diluted to 100 times. Its pH is:
    a) 6.0 b) 8.0 c) 6.95 d) 9.5
    14. The indicator used in titration of oxalic acid with caustic soda solution is
    a) Methyl orange b) Methyl red c) Fluorescein d) Phenolphthalein
    15. The pH of 0.1 𝑀NaHS is, 𝐾𝑎1 and 𝐾𝑎2 for H2 S are 1.3 × 10−7 and 7.1 × 10−15 respectively:
    a) 10.52 b) 9.52 c) 12.52 d) 13.52
    16. 𝐾𝑠𝑝 for sodium chloride is 36 mol2 /litre2 . The solubility of sodium chloride is:
    1 1
    a) 𝑀 b) 𝑀 c) 6 𝑀 d) 3600 𝑀
    36 6

    Chemistry for IIT JEE Main & Advance MAHaqueSir @ Telegram . 2

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