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    Equilibrium Worksheet 1

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    bharti250714

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    Equilibrium Worksheet 1

    Uploaded by

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    Equilibrium Worksheet 1

    Uploaded by

    bharti250714

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    © All Rights Reserved
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    WORKSHEET – 1

    EQUILIBRIUM

    Q.1 Conjugate acid of a weak base is always stronger. The


    decreasing order of basic strength of the following conjugate
    bases will be?

    OH–, RO–, CH3COO–, Cl–

    Q.2 Arrange the following in increasing order of pH.

    KNO3 (aq), CH3COONa (aq), NH4Cl (aq), C6H5COONH4 (aq)

    Q.3 The value of Kc for the reaction 2HI (g) ⇋ H2 (g) + I2 (g) is 1 x 10-
    4
    . At a given time, the composition of reaction mixture is [HI] = 2 x
    10-5 mol, [H2] =1 × 10-5 [I2 ] = 1x10-5mol. Determine the direction in
    which the reaction will proceed?

    Q.4 The pH of 0.08 mol dm-3 HOCI solution is 2.85. Calculate its
    ionisation constant.

    Q.5. The solubility product of Al(OH)3 is 2.7 x 10-11. Calculate its


    solubility in g / L and also find out the pH of this solution. (Atomic
    mass of Al = 27 u).

    Q.6 Calculate the volume of water required to dissolve 0.1 g lead


    (II) chloride to get a saturated solution. (Ksp of PbCl2 = 3.2x10-8,
    atomic mass of Pb= 207 u).

    Q.7 How can you predict the following stages of a reaction by


    comparing the value of Kc and Qc ? (i) Net reaction proceeds in
    the forward direction. (li) Net reaction proceeds in the backward
    direction. (iii) No net reaction occurs.
    Q.8. On the basis of the Le Chatelier principle explain how
    temperature and pressure can be adjusted to increase the yield of
    ammonia in the following reaction. N2 (g) + 3H2 (g) ⇋ 2NH3 (g) ΔH =
    – 92.38 kJ mol-1 What will be the effect of addition of argon to the
    above reaction mixture at constant volume?

    Q.9 Write a relation between ΔG and Q and define the meaning of


    each term and answer the following: (a) Why a reaction proceeds
    forward when Q < K and no net reaction occurs when Q = K. (b)
    Explain the effect of an increase in pressure in terms of reaction
    quotient O. for the reaction:
    CO (g) + 3H2 (g) ⇋ CH4 (g) + H2O (g)

    Q.10 The pH of the given 0.1M solution of cyanic acid (HCNO) is 2.34.
    Calculate the ionisation constant of the given acid and the degree
    of ionisation in the solution.

    Q.11 The first ionization constant for H2S is 9.1 × 10–8. Calculate the
    concentration of HS– ion in the 0.1M solution. How would this
    concentration be affected when the solution is 0.1M in HCl also? If
    the second dissociation constant for H2S is 1.2 × 10–13, calculate the
    required concentration of S2– under both conditions.

    Q.12 The pH of the given solution of the strong acid is 5.0. What
    would be the pH of the given solution obtained after diluting the
    given solution 100 times?

    Q.13 Name and explain the factors which influence the state of
    chemical equilibrium .

    Q.14. Explain Le chaterliers’ Principle with an example.


    Q.15. Calculate the pH of the solution in which 0.2M NH4Cl and 0.1M
    NH3 are present. The pKb of ammonia solution is 4.75.

    Q.16. The ionization constant of acetic acid is 1.74 × 10–5. Calculate


    the degree of dissociation of acetic acid in its 0.05 M solution.
    Calculate the concentration of acetate ion in the solution and its
    pH.

    Q.17 . Ionic product of water at 310 K is 2.7 × 10–14. What is the pH of


    neutral water at this temperature?

    Q 18. a) Explain the factors affects acidic strength.

    b) Explain common ion effect and Buffer solutions.

    Q.19. Explain Hydrolysis of salts (a) for strong acid and weak base
    (b) for strong base and weak acid .

    Q.20 What is ostwald’s Dilution law . Derive it’s relation.

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