Materials and Construction - Ii: Lecture No. 04 Dated: 23/04/2017
Materials and Construction - Ii: Lecture No. 04 Dated: 23/04/2017
Materials and Construction - Ii: Lecture No. 04 Dated: 23/04/2017
LECTURE NO. 04
Dated: 23/04/2017
TOPICS TO BE COVERED
– Introduction to Cement
– Composition of Cement
– Different Types of Cement
– Storage of Cement
CEMENT:
HISTORICAL OVERVIEW:
Assyrians and Babylonians were perhaps the first to use clay as cementing
material. In ancient monuments, e.g. forts, places of worship and defence
structures, stones have been invariably used as a construction material with
lime as the binder.
Egyptians have used lime and gypsum as cementing materials in the famous
pyramids.
Vitruvius, a Roman scientist, is believed to be the first to have the know how
about the chemistry of the cementitious lime. One of the most notable
examples of Roman work is the Pantheon. It consists of a concrete dome
43.43m in span. The calcareous cements used by the Romans were either
composed of suitable limestones burned in kilns or were mixtures of lime and
puzzolanic materials (volcanic ash, tuff) combining into a hard concrete.
Vitruvius’s work was followed by the researches made by M. Vicat of France.
Joseph Aspedin of Yorkshire (U.K.) was the first to introduce Portland cement
in 1824 formed by heating a mixture of limestone and finely divided clay in a
furnace to a temperature high enough to drive off the carbonic acid gas.
In 1845, Issac C. Johnson invented the cement by increasing the temperature
at which the mixture of limestone and clay were burned to form clinker. This
cement was the prototype of the modern Portland cement.
ROMAN PANTHEON
DIFFERENT STRUCTURES WITH USE OF CEMENT
COMPOSITION OF CEMENT:
Cements in a general sense are adhesive and cohesive materials which are
capable of bonding together particles of solid matter into a compact durable
mass. These are restricted to calcareous cements containing compounds of lime
as their chief constituent, its primary function being to bind the fine (sand) and
coarse (grits) aggregate particles together.
Cements used in construction industry may be classified as hydraulic and non
hydraulic. The latter does not set and harden in water such as non-hydraulic lime
or which are unstable in water, e g. Plaster of Paris. The hydraulic cement set and
harden in water and give a product which is stable. Portland cement is one such.
Cement can be manufactured either from natural cement stones or artificially by
using calcareous and argillaceous materials. The examples of natural cements
are Roman cement, Puzzolana cement and Medina cement and those of artificial
cement are Portland cement and special cements.
COMPOSITION OF CEMENT:
The various constituents combine in burning and form cement clinker. The
compounds formed in the burning process have the properties of setting and
hardening in the presence of water. They are known as Bogue compounds after
the name of Bogue who identified them. Le-Chatelier and Tornebohm have
referred these compounds as Alite (C3S), Belite (C2S), Celite (CA) and Felite (CAF).
TYPES OF CEMENTS:
– Ordinary Portland Cement (OPC)
– Rapid Hardening Portland Cement
– Quick Setting Cement
– Pozzuolana Portland Cement
– Low Heat Cement
– White Cement
– Sulphate Resisting Cement
– Coloured Cement
ORDINARY PORTLAND CEMENT (OPC):
This cement contains between 45% and 64% Portland cement clinker, 36-55%
Pozzuolanic material and 0-5% minor additional constituents. The properties
of Pozzuolanic cement are very different from those of conventional Portland
cement and these differences and their effects on concrete production and
site practice must be recognized.
At the same cement content, concrete containing Pozzuolanic cement will
have a reduced water demand and hence the slump at a given water/cement
ratio will generally be higher than for a Portland cement concrete.
APPLICATIONS:
• General Construction
• Slabs and Floors
• Mass Concrete / Large Concrete Elements
• Concrete Foundations
• Concrete Exposed to Sea Water
LOW HEAT CEMENT:
STORAGE:
Portland cement products are highly alkaline materials and are significantly
affected by exposure to water.
WHITE CEMENT:
These are stored for short period of time in air tight room avoiding moisture
and dampness, at some distance from walls and at some height from floors.
The stack should be covered with suitable coverings to avoid circulation of
air through the stack and not more than ten bags should be stacked one
over another.
THE END