CHE882Unit3 L15

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Chemistry and

consumer products
Electroplating 
(often just called "plating") is the
deposition of a metal coating onto
an object by putting a negative
charge on it and putting it into a
solution which contains a metal salt.

The metal salt contains positively


charged metal ions which are
attracted to the negatively charged
object and are "reduced" to metallic
form upon it.
The overall process of electroplating uses an electrolytic cell, which
consists of putting a negative charge on the metal and dipping it
into a solution that contains metal salt (electrolytes) which contain
positively charged metal ions. 

Cu, Ag, Cr and Au are extensively used


Purposes of Electroplating:
 Protection
 Appearance, decoration
Special surface properties
 Engineering or mechanical properties

The plating is most commonly a single metallic element, not


an alloy. However, some alloys can be electrodeposited,
notably brass and solder.
Many everyday items made from iron are plated with
zinc (in a process called galvanization) to make them
resistant to corrosion
METALS AND METAL ALLOYS
A metal is a material (an element) that is typically hard,
opaque, shiny, and has good electrical and thermal
conductivity.

Physical properties of
metals
 They are characteristically
shiny
 most are malleable, ductile,
dense
 very good electrical
conductors and have high
melting points.
Chemical Properties
Metals Nonmetals
Usually have 4-8 electrons in their
Usually have 1-3 electrons in their
outer shell.
outer shell.
Gain or share valence electrons
Lose their valence electrons easily.
easily.
Form oxides that are basic.
Form oxides that are acidic.
Are good reducing agents.
Are good oxidizing agents.
Have lower electronegativities.
Have higherelectronegativities.
Physical Properties
Metals Nonmetals
Good electrical conductors and Poor conductors of heat and
heat conductors. electricity.
Malleable - can be beaten into thin Brittle - if a solid.
sheets.
Ductile - can be stretched into wire. Non ductile.-Do not possess
Possess metallic luster(Shine). metallic luster(Shine).
Opaque as thin sheet. Transparent as a thin sheet.
Solid at room temperature (except Solids, liquids or gases at room
Hg). temperature.
What are alloys?
Mixtures of metals, called alloys, are more commonly used than
the pure metal. By alloying, some of the important properties of
metals can be improved.

Solder, which is used in the electronics industry, is a mixture


of tin and lead. One type of solder (63% tin and 37% lead) has a
lower melting point but is harder than either of the metals. These
properties allow it to be used successfully.

An amalgam is an alloy based on mercury. Dental amalgam is an


alloy of mercury, silver, tin, copper and zinc. It is hard-wearing,
corrosion-resistant and has high-impact strength.

A titanium alloy known as Ti6Al4V is used in the aerospace


industry. It is lightweight, very strong and has high corrosion-
resistance properties.
Alloy Constituents Uses
Nickel Steel 3-5% Ni Metal shield plate, wire,
propeller blades of aeroplane

Chromium Steel 12% Cr Stainless cutlery


Stainless steel Ni, Cr Table ware, Knives, utensils

Manganese steel 12-14% Mn Grinding Machinery, rock


chrushers, burglar proof safes

Tungsten Steel 18% W High speed tools


Coinage metal Cu, Ni Coins
Brass Cu, Zn Utensils, musical instruments

Bronze Cu, Sn Statues, monuments, medals

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