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    Responsi 9

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    teknikpembakaran2013
    1. The document discusses five chemical reactions and calculates various properties: 2. For reactions 1 and 3, it determines the rate equation is zero order in A, second order in B, and half order in C. The overall reaction order is 2.5. 3. It also calculates the rate constant K for reaction 1 to be 80 based on the rate expression and rate data provided.

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    Responsi 9

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    teknikpembakaran2013
    7 views4 pages
    1. The document discusses five chemical reactions and calculates various properties: 2. For reactions 1 and 3, it determines the rate equation is zero order in A, second order in B, and half order in C. The overall reaction order is 2.5. 3. It also calculates the rate constant K for reaction 1 to be 80 based on the rate expression and rate data provided.

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    1. The document discusses five chemical reactions and calculates various properties: 2. For reactions 1 and 3, it determines the rate equation is zero order in A, second order in B, and half order in C. The overall reaction order is 2.5. 3. It also calculates the rate constant K for reaction 1 to be 80 based on the rate expression and rate data provided.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as DOC, PDF, TXT or read online from Scribd
    Download as doc, pdf, or txt
    7 views4 pages

    Responsi 9

    Uploaded by

    teknikpembakaran2013
    1. The document discusses five chemical reactions and calculates various properties: 2. For reactions 1 and 3, it determines the rate equation is zero order in A, second order in B, and half order in C. The overall reaction order is 2.5. 3. It also calculates the rate constant K for reaction 1 to be 80 based on the rate expression and rate data provided.

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    Jawaban Responsi 9 :

    1. Dik : VHCl : 50 ml
    MHCl

    : 0.2 ml

    VNaOH

    : 50 ml

    MNaOH

    : 0.2 ml

    : 3420 J/K

    : 0.645 0C

    Dit : Hreaksi ?

    Jawab :
    HCl + NaOH
    Mol HCl

    Mol NaOH

    Hreaksi

    NaCl + H2O
    =

    VHCl . MHCl

    (50) (0.2)

    10 mmol

    10 . 10 -3 mol

    VNaOH . MNaOH

    (50) (0.2)

    10 mmol

    10 . 10 -3 mol

    (3420) (0.654)
    =
    10 . 10 -3

    223668 J/K

    2. Dik : G = -RT ln K
    T

    = 25 0C

    a. Zn | Zn2+ || Cu2+ | Cu
    Cu2+ + 2e
    Zn
    Eo

    Cu

    , Eo = +0.337 V

    Zn2+ + 2e

    , Eo = - 0.763 V

    Eoreduksi - Eooksidasi

    0.337 (-0.763)

    1.1 V

    n=2
    G

    = - n F Eo

    = - (2) (96500) (1.1) ;


    = -212300

    b. b.

    Eo

    = -RT ln K

    -2121300 = - 8.314 (298.15) ln K


    212300
    ln K
    =
    2478.819
    1
    K = 1.568 . 10 37

    Pb | Pb2+ || Ag+ | Ag

    Ag+ + e
    Pb

    Ag

    , Eo = +0.799 V

    Pb2+ + 2e

    , Eo = - 0.126 V

    Eoreduksi - Eooksidasi

    0.799 (-0.126)

    0.925 V

    n=2
    G

    = - n F Eo

    = - (2) (96500) (0.925);


    = -178525

    = -RT ln K

    -178525 = - 8.314 (298.15) ln K


    212300
    ln K
    =
    178525
    K

    1.897 . 10 31

    3. Dik :

    = 0.5 A

    = 1 jam = 3600 s
    O2 + 4H+ + 4e

    2 H2O

    Dit : O2 yang terbentuk ?


    Jawab :
    e.i.t
    96500

    mO2 =

    4. Dik : T

    (32/4) (0.5) (3600)


    = 0.149 gr
    96500

    = 500 K

    MCO2 = 0.5
    K

    = 0.001

    Jawab :
    2CO2

    2CO + O2

    0.5

    2x

    2x

    0.5 - 2x

    2x

    = [ CO ] [ O2 ]
    [ CO2 ]
    [ 2x ] [ x ]
    [ 0.5 - 2x ]

    0.001=

    x1 = 0.396 ; x2 = 0.1985 ; x3 = 0.1985


    x = 0.1985
    =

    0.5
    2x

    0.5
    2 (0.1985)

    = 1.2594

    5. Dik :
    No Reaksi W (mol/L) X (mol/L) Y (mol/L) Z (mol/L s)
    1
    0.01
    0.05
    0.04
    0.04
    2
    0.015
    0.07
    0.06
    0.08
    3
    0.01
    0.15
    0.04
    0.36
    4
    0.03
    0.07
    0.06
    0.08
    5
    0.01
    0.05
    0.16
    0.08

    Reaksi 1 dan 3

    Reaksi 2 dan 4
    a

    V1 = K (0.01) (0.05) (0.04)


    V2 = K (0.01) (0.15) (0.04)
    0.04 = (0.05)

    0.36 = (0.15)

    a=0

    V1 = K (0.01) (0.05) (0.04)

    V5= K (0.01) (0.05) (0.16)


    0.04 =c (0.04)
    = 1/2

    0.08 = (0.16)

    0.08 = (0.03)

    Reaksi 1 dan 3

    ; c = 1/2

    Orde reaksi total = a+b+c = 0+2+1/2 = 2.5


    Nilai K :
    V = K [ W ]a [X ]b [Y ]c
    Reaksi no1:
    = K [ W ]a [X ]b [Y ]c

    0.04 = K [ 0.01 ]0 [0.05 ]2 [0.04 ]1/2

    K = 80

    V4 = K (0.03)

    (0.07) (0.06)

    0.08 = (0.015)

    b=2

    V2 = K (0.015) (0.07) (0.06)

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