Model Answer Lesson 2 Chapter 3

Download as pdf or txt
Download as pdf or txt
You are on page 1of 8

Model answer lesson 2 chapter 3

Question Answer Question Answer


1 A 31 D
2 D 32 B
3 A 33 D
4 C 34 A
5 A 35 A
6 B 36 C
7 B 37 A
8 A 38 B
9 A 39 B
10 B 40 D
11 B 41 B (Steps)
12 B 42 B(Steps)
13 B 43 C(Steps)
14 A 44 D(Steps)
15 A 45 B(Steps)
16 C 46 D(Steps)
17 C 47 B(Steps)
18 B 48 a)A , b)B
19 B 49 B(Steps)
20 C 50 D(Steps)
21 D 51 D(Steps)
22 A 52 A(Steps)
23 C 53 C(Steps)
24 B 54 2500(Steps)
25 D 55 D(Steps)
26 B
27 A
28 A
29 B
30 D
Steps:

41)
[product] [NO2]2
Kc1= [reactants]= [N2O4]

[product] [N2O4]
Kc2= [reactants]= 2
[NO2]

Kc1 x Kc2 = 1

42)

2NO + O2⇄2NO2
2
[product] [𝑁𝑂2 ]2 [0.18]
Kc= [reactants]= [𝑁𝑂]2 [𝑂 ] = 2 = 0.499 ≈0.5
2 [0.52] [0.24]

43)
PCl5⇄PCl3+Cl2
number of moles
Concentration = volume(L)
0.008 -4
Conc PCl5= 8x10 M
10 =
0.0114
Conc PCl3= = 1.14x10−3 M
10

0.0114
Conc Cl2 = = 1.14x10−3 M
10
[Cl2][PCl3] [0.00114][0.00114] -3 -3
Kc = = = 1.6245x10 ≈ 1.62x10
[PCl5] [0.0008]

44)
CH4 +H2O(l)⇄ CO + 3H2

[product] [𝐻2 ]3 [CO] [0.04]3 [0.08] -6


Kc= [reactants] = = =4.266667 X 10
[CH4] [1.2]
-6
≈4.267 X 10

45)

AgCl(s) +2NH ⇄[Ag(NH ) ] + +Cl-


3 3 2

[product] [𝐴𝑔(𝑁𝐻3 )2 ][𝐶𝑙] [5𝑋10−3 ][5𝑋10−3 ]


Kc= [reactants]= = =0.25
[𝑁𝐻3 ]2 [10𝑋10−3 ]2

46)

HA(aq) + BOH(aq) ⇌ BA(aq) + H2O


number of moles
Concentration = volume(L)
0.7
Conc. BOH = 2 =0.35M
1
Conc. BA= = 0.5M
2
0.6
Conc. HA = 2 = 0.3M

[BA] [0.5]
Kc = [BOH][HA]=[0.35][0.3]=4.76
47)

I2(g) + H2(g)⇄ 2HI(g)

KC=1.55

HI=1.035

Since, No. of moles of I2 = No. of moles of H2 at same


volume

Then, conc. of I2 = conc. of H2


[𝐻𝐼]2
Kc=[𝐻
2 ][𝐼2 ]

[1.035]2
1.55= [𝑋][𝑋]

√𝑋 2 =√0.69 , X=0.83 M

48)

N2O4+heat ⇄2NO2

From graph we can detect that conc of NO2 at t1 =


0.65M and conc N2O4 at t1 = 0.6M
2 2

[product] [𝑁𝑂2 ]2 [𝑂.65]2


Kc= [reactants] = = = 0.704 ≈ 0.7
[N2O4] [0.6]
49)

A + 3B ⇌ 2C

From the graph ;

Conc.A=0.1M

Conc.B=0.3M

Conc.C=0.2M
[𝐶]2 [0.2]2
Kc = [𝐵]3 [A]=[𝑂.3]3 [0.1]=14.8

50)

2SO2 + O2 ⇄ 2SO3
[product]
Kc= [reactants]
[SO3]2
Kc= [SO2]2 [O2]
SO2=2O2
[SO3]2 [SO3]2
Kc= [2O2]2 [O2] = 4[O2]2 [O2]
[SO3]2
Kc= 4[O2]3
[6]2
280 = 4[O2]3
3 9
4[O2] = 70
X= 0.3179≈ 0.318 mol/liter
51)

PCl3 + Cl2 ⇄ PCl5


[product]
Kc = [reactants]
[PCl5]
Kc= [
Cl2][PCl3]

[PCl ]
15.57= [0.3][0.84]
5

PCl5 = 3.923 M

52)

2SO2 + O2 ⇄ 2SO3
[𝐩𝐫𝐨𝐝𝐮𝐜𝐭] [𝐒𝐎𝟑]𝟐
Kc= [𝐫𝐞𝐚𝐜𝐭𝐚𝐧𝐭𝐬] = [𝐒𝐎𝟐]𝟐 [𝐎𝟐]
As conc SO3 = conc SO2
1
35.5 = [O2]
[O2]=0.0281 ≈0.028 M

no of moles
Conc [O2] = volume(L)

No of moles = conc[O2] x Volume[O2]

No of moles =0.028 x 2=0.056 moles


53)

2SO2 +O2 ⇄ 2SO3

reversible ➔ 2SO3 ⇄ 2SO2 +O2


2
Kc reversed = 1/Kc = 1/10 = 0.01

54)
K1 500
Kc = K2 = = 2500
0.2

55)

2A ⇄3B +C
[product] [𝐵]3 [𝐶] [0.4]3 [1.8]
Kc = [reactants]= = = 0.32
[𝐴]2 [0.6]2

Kc < 1

Kc<1 ➔ backward is predominant ➔

reactant conc. > product conc

You might also like