Ph lc 17

(Ban hnh km theo Thng t s 28/2010/TT-BCT

ngy 28/6/2010 ca B CngThng)

PHIU AN TON HA CHT

Phiu an ton ha cht Logo ca doanh nghip

METHYL ETHYL KETONE (khng bt buc)

S CAS:78-93-3
S UN: 1193
S ng k EC: 302-159-0
S ch th nguy him ca cc t chc xp lai (nu c):
S ng k danh mc Quc gia khc (nu c):
I. NHN DNG HA CHT
- Tn thng gi ca cht: MEK M sn phm nu c
- Tn thng mi: METHYL ETHYL KETONE
- Tn khc (khng l tn khoa hc):
- Tn nh cung cp hoc nhp khu, a ch: FRP a ch lin h trong trng hp khn cp:
SERVICES (ASIA) PTE LTD 112 ROBINSON ROAD, #14- Cng ty TNHH TM DV SAPA
02 SINGAPORE 068902 448 L Thi T P10, Q10
- Tn nh sn xut v a ch: FRP SERVICES (ASIA) T : 08.38348902
PTE LTD 112 ROBINSON ROAD, #14-02 SINGAPORE Fax : 08.38345165
068902
- Mc ch s dng: ha cht dng trong CN sn, giy,
nha
PHN II. THNG TIN V THNH PHN CC CHT
Tn thnh phn nguy him S CAS Cng thc ha hc Hm lng
(% theo trng lng)
MEK 78-93-3 CH3COCH2CH3 100%
Thnh phn 2 (nu c)
Thnh phn 3 (nu c)
Thnh phn 4 (nu c)
Thnh phn 5 (nu c)
III. NHN DNG C TNH NGUY HIM CA HA CHT
1. Mc xp loi nguy him (theo s liu hp l c sn ca cc quc gia, t chc th nghim; V d:
EU, M, OSHA... ) :
2. Cnh bo nguy him :
- Chy, n hoc c khi tip xc : Nhit chp chy: 25oF. Rt d chy v bay hi. Khi s dng, ha
cht ny c th hnh thnh hp cht hi kh d chy n
- C th lm c ch h thn kinh trung ng. Gy hi cho gan, thn. C th nh hng n sinh sn
ng vt.
- Lu khi tip xc, bo qun, s dng
3. Cc ng tip xc v triu chng
- ng mt : gy kch ng va phi cho mt
- ng th : Nu ht vo nhiu c th gy nhc u, chng mt v chong vng,
- ng da : gy kch ng cho da
- ng tiu ha : c th gy tn thng cho h tiu ha nu nut phi.
- ng tit sa.
IV. BIN PHP S CU V Y T
1. Trng hp tai nn tip xc theo ng mt (b vng, dy vo mt) : Ra nc ngay lp tc trong
khong 15 pht trong khi gi m mt
2. Trng hp tai nn tip xc trn da (b dy vo da) : Lp tc di tht nhiu nc t nht 15 pht
v sau ra bng x phng v nc ny c sn
3. Trng hp tai nn tip xc theo ng h hp (ht th phi ha cht nguy him dng hi, kh) :
a nn nhn ra ni thang kh. Nu khng phc hi nhanh, phi a n c s y t gn nht
iu tr thm.
4. Trng hp tai nn theo ng tiu ha (n, ung nut nhm ha cht) Khng p nn ra , a vo
c s y t gn nht iu tr thm. Nu t ng i, c th gi cho u thp khng chy
ngc vo phi
5. Lu i vi bc s iu tr (nu c) :sc ra d dy vi ng h hp c bo v, cho dng than
hat tnh.Lu cho th oxy

V. BIN PHP X L KHI C HA HON

1. Xp loi v tnh chy (d chy, rt d chy hoc cc k d chy, khng chy, kh chy...) : cc k
d chy
2. Sn phm to ra khi b chy: CO v CO2
3. Cc tc nhn gy chy, n (tia la, tnh in, nhit cao, va p, ma st...): tia la, ngun la
4. Cc cht dp chy thch hp v hng dn bin php cha chy, bin php kt hp khc: Bt,
bnh phun nc hoc sng. Bt ha cht kh, CO2, ct hoc t ch dng cho cc m chy nh.
Khng xt hi nc thng vo m chy.
5. Phng tin, trang phc bo h cn thit khi cha chy: mc y qun o bo h v thit b
th bnh hi
6. Cc lu dc bit v chy, n (nu c) :Khng dng nc c xt thnh vi
VI. BIN PHP PHNG NGA, NG PH KHI C S C
1. Khi trn , d r mc nh: Cho cn bc hi hay thm chng bng cht thm thch ng v loi
b cch an tan. Ly t b thm ha cht v loi b an ton
2. Khi trn , d r ln din rng : dn bng phng php c kh nh xe ht n bn cha thu
hi hay x l an tan. Cho cn bc hi hay thm chng bng cht thm thch ng v loi b cch an
tan. Ly t b thm ha cht v loi b an ton
VII. YU CU V CT GI
1. Bin php, iu kin cn p dng khi s dng, thao tc vi ha cht nguy him (thng gi, ch
dng trong h thng kn, s dng thit b in phng n, vn chuyn ni b...): thng gi tt
ni s dng, cch xa ngun chy
2. Bin php, iu kin cn p dng khi bo qun (nhit , cch sp xp, cc hn ch v ngun gy
chy, n, cc cht cn trnh bo qun chung...) : ng knh cc thng khi khng s dng. Bo qun ni
thong mt, cch xa ngun chy, nn tip t cc thit b bo qun v vn chuyn
III. TC NG LN NGI V YU CU V THIT B BO V C NHN
1. Cc bin php hn ch tip xc cn thit (thng gi hoc bin php gim nng hi, kh trong
khu vc lm vic, cc bin php cch ly, hn ch thi gi lm vic...)S dng cc h thng kn
n mc ti a. Thng thang y kim sat nng hi ha cht trong khng kh di
cc gii hn tip xc trc tip vi ha cht.
2. Cc phng tin bo h c nhn khi lm vic
- Bo v mt : s dng knh bchng vng bn ha cht
- Bo v thn th : mc bo h lao ng, nguyn b chng ha cht vi m trm u
- Bo v tay : Bao tay/ gng tay di chng ha cht
- Bo v chn: mang giy bo h
3. Phng tin bo h trong trng hp x l s c
4. Cc bin php v sinh (tm, kh c...) : bn ra mt v vi tm
IX. C TNH L, HA CA HA CHT
Trng thi vt l : lng im si (0C) : 78.5-810C
Mu sc : khng mu im nng chy (0C) : -
im bng chy (0C) (Flash point) theo phng
Mi c trng : mi bc h
php xc nh :-4 0C ( TCC ASTM D56)
p sut ha hi (mm Hg) nhit , p sut tiu Nhit t chy (0C) : >450 0C
chun: 9,500Pa @ 680F
T trng hi (Khng kh = 1) nhit , p sut Gii hn nng chy, n trn (% hn hp vi
tiu chun: 2.4@ 200C khng kh : 11.5
Gii hn nng chy, n di (% hn hp vi
ha tan trong nc : 250 g/l ti 200C
khng kh : 1.8
pH T l ha hi : 3.7 ( Butyl acetate = 1)
Khi lng ring (kg/m3) : 0.804-0.806 kg/m3 Cc tnh cht khc nu c
X. MC N NH V KH NNG HOT NG CA HA CHT
1. Tnh n nh ( bn nhit, nhy vi tc nhn ma st, va p...) : Bn iu kin bnh thng
2. Kh nng phn ng:
- Phn ng phn hy v sn phm ca phn ng phn hy : CO hoc CO2
- Cc phn ng nguy him (n mn, chy, n, phn ng vi mi trng xung quanh) : Phn ng mnh
lit vi cc cht oxy ha mnh
- Cc cht (c phn ng sinh nhit, kh c hi, cc cht khng bo qun chung...): Cht oxy ha mnh
- Phn ng trng hp : S polymer ha nguy him khng xy ra.
XI. THNG TIN V C TNH
Tn thnh phn Loi ngng Kt qu ng tip Sinh
xc vt th
Thnh phn 1 LD 50 >2000mg/kg Gy vin phi ng ming Chut
Methyl ethyl ketone LD 50 >2000mg/kg Nhc u, Da Th
LD 50>20mg/l/4gi chong vng H hp Chut
Thnh phn 2 (nu c)
Thnh phn 3 (nu c)

1. Cc nh hng mn tnh vi ngi (Ung th,c sinh sn, bin i gen...) : Theo ACGIH
khng c t bit gien, khng gy ung th, khng nh hng kh nng sinh sn
2. Cc nh hng c khc : Tip xc cc cht tng t nng cao s gy ra ri lon nhp tim
v tnh trang tim ngng p tam thi
XII. THNG TIN V SINH
1. c tnh vi sinh vt
Tn thnh phn Loi sinh vt Chu k nh hng Kt qu
LC/EC/IC50>1000mg/l C c tnh thp
LC/EC/IC50 > 100 mg/l ng vt khng xng c tnh thp
sng sng trong nc
LC/EC/IC50> 100 mg/l To c tnh thp
Thnh phn 2 (nu c)
Thnh phn 3 (nu c)
Thnh phn 4 (nu c)
2. Tc ng trong mi trng
- Mc phn hy sinh hc : D dng phn hy sinh hc trong thi gian 10 ngy
- Ch s BOD v COD
- Sn phm ca qu trnh phn hy sinh hc : khng c
- Mc c tnh ca sn phm phn hy sinh hc: Sn phm ny khng t ra l cht nguy him ng k cho
i sng di nc
XIII. YU CU TRONG VIC THI B
1. Thng tin quy nh tiu hy (thng tin v lut php) : X l cht thi phi ph hp vi nhng quy
nh v php lut tng ng ca a phng, quc gia v vng
2. Xp loi nguy him ca cht thi : 3
3. Bin php tiu hy : thu hi hoc ti ch nu c th
4. Sn phm ca qu trnh tiu hy, bin php x l
XIV. YU CU TRONG VN CHUYN
Tn quy nh S UN Tn vn Loi, nhm Quy cch Nhn vn Thng
 chuyn hng ng gi chuyn tin
ng bin nguy him b sung
Quy nh v vn
chuyn hng nguy 1193 Methyl 3 II Liquid
him ca Vit Nam: eth fla
- Ngh nh s yl mm
104/2009/N-CP ket abl
ngy 09/11/2009 ca one e
Chnh ph quy nh
Danh mc hng nguy
him v vn
chuynhng nguy
him bng phng
tin giao thng c
gii ng b;
- Ngh nh s
29/2005/N-CP ngy
10/3/2005 ca CP
quy nh Danh mc
hng ha nguy him
v vic vn ti hng
ha nguy him trn
ng thy ni a.
Quy nh v vn
chuyn hng nguy
him quc t ca EU,
USA
XV. QUY CHUN K THUT V QUY NH PHP LUT PHI TUN TH
1. Tnh trng khai bo, ng k cc quc gia khu vc trn th gii (lit k cc danh mc quc gia
tin hnh khai bo, tnh trng khai bo)
2. Phn loi nguy him theo quc gia khai bo, ng k
3. Quy chun k thut tun th.
XVI. THNG TIN CN THIT KHC
Ngy thng bin son Phiu: 25-06-2011
Ngy thng sa i, b sung gn nht:
Tn t chc, c nhn son tho: Cng ty TNHH TMDV SAPA

Lu ngi c:
Nhng thng tin trong Phiu an ton ha cht ny c bin san da trn cc kin thc hp l v mi
nht v ha cht nguy him v phi c s dng thc hin cc bin php ngn nga ri ro, tai nn.
Ha cht nguy him trong Phiu ny c th c nhng tnh cht nguy him khc ty theo hon cnh s
dng v tip xc.

Hng dn b sung:
1. Nhng thng tin c km theo t nu c c bin son ty theo iu kin c th,
khng hm bt buc.
2. Phi ghi y thng tin cn thit vo cc mc trong phiu.
3. Trng hp khng c thng tin, ghi cm t cha c thng tin.
4. Trng hp thng tin khng ph hp, v d: mt cht rn khng bay hi nn khng c
thng s p sut ha hi, ghi cm t khng ph hp.
5. Trng hp cc thng tin c sn ch ra mc khng nguy him tng ng vi mc t
cn ghi, ghi c th, r rng thng tin ch ra tnh cht khng nguy him theo phn loi ca
t chc nht nh; v d: thng tin v nh hng mn tnh, ghi khng c phn loi l
cht gy ung th theo OSHA, ACGIH
6. n v o lng s dng trong phiu p dng theo quy nh ca php lut.
7. Cch ghi hm lng thnh phn
Khng bt buc ghi chnh xc hm lng thnh phn, ch cn ghi khong nng
ca thnh phn theo quy tc sau:
a) T 0.1 n 1 phn trm;
b) T 0.5 n 1,5 phn trm;
c) T 1 n 5 phn trm;
d) T 3 n 7 phn trm;
) T 5 n 10 phn trm;
e) T 7 n 13 phn trm;
g) T 10 n 30 phn trm;
h) T 15 n 40 phn trm;
i) T 30 n 60 phn trm;
k) T 40 n 70 phn trm;
l) T 60 n 100 phn trm.