Section 916 Bituminous Materials 916-1 General

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(REV 5-19-15) (FA 7-13-15) (1-16) Includes 9160000

SECTION 916
BITUMINOUS MATERIALS

916-1 General.
All products supplied under this Specification shall be one of the products included on
the Approved Product List (APL). Producers seeking evaluation of a product for inclusion on the
APL shall submit an application in accordance with Section 6.
For liquid anti-strip agents, in addition to the above, producers shall include a report of
test results from an independent laboratory confirming the material meets the requirements of
this section. In lieu of submitting test results from an independent laboratory, the Department
will evaluate the material. For each liquid anti-strip agent, the producer will submit one pint of a
representative sample of liquid anti-strip agent to the State Materials Office when submitting the
APL application to the Department’s Product Evaluation Section.
Any marked variation from the original test values for a material below the established
limits or evidence of inadequate quality control or field performance of a material will be
considered sufficient evidence that the properties of the material have changed, and the material
will be removed from the APL.

916-2 Superpave PG Asphalt Binder:


916-2.1 Requirements: Superpave Performance Graded (PG) asphalt binders, identified
as PG 52-28, PG 58-22, PG 67-22, polymer modified asphalt (PMA) binders, PG 76-22 (PMA)
and PG 82-22 (PMA), and asphalt rubber binders (ARB), PG 76-22 (ARB), shall meet the
requirements of 916-2 and AASHTO M332-14. All PG asphalt binders shall meet the following
additional requirements:
1. The intermediate test temperature at 10 rad/sec. for the Dynamic Shear
Rheometer (DSR) test (AASHTO T315-12) shall be 26.5ºC for PG grades PG 67 and higher.
2. An additional high temperature grade of PG 67 is added for which the high test
temperature at 10 rad/sec for the DSR test (AASHTO T315-12) shall be 67ºC.
3. All PG asphalt binders having a high temperature designation of PG 67 or
lower shall be prepared without modification.
4. All PMA binders having a high temperature designation higher than PG 67
shall only be produced with a styrene-butadiene-styrene (SBS) or styrene-butadiene (SB)
elastomeric polymer modifier and the resultant binder shall meet all requirements of this Section.
5. Polyphosphoric acid may be used as a modifier not exceeding 0.75% by weight
of asphalt binder for PG 76-22 (PMA), PG 76-22 (ARB), and PG 82-22 (PMA) binders.
6. PG 76-22 (ARB) shall meet the additional requirements of 916-2.1.1.
7. All PG asphalt binders having a high temperature designation of PG 67 or
lower shall not have a high temperature true grade more than 5.9°C higher than the specified PG
grade, (for example, if a PG 58-22 is specified, do not supply a PG 64-22 or higher).
For all PG binder used in all hot mix asphalt, silicone may be added to the PG
binder at the rate of 25 cubic centimeters of silicone mixed to each 5,000 gallons of PG binder. If
a disbursing fluid is used in conjunction with the silicone, the resultant mixture containing the
full 25 cubic centimeters of silicone shall be added in accordance with the manufacturer’s
recommendation. The blending of the silicone with the PG binder shall be done by the supplier
prior to the shipment. When the asphalt binder will be used with a foaming warm mix
technology, refer to the technology supplier’s guidance on the addition of silicone.
(REV 5-19-15) (FA 7-13-15) (1-16) Includes 9160000

Where an anti-strip additive is required, per the requirements of Sections 334 and
337, the amount shall be from 0.25% to 0.75% by weight of asphalt binder. The anti-strip
additive shall meet the requirements of 916-4. The anti-strip additive shall be introduced into the
PG binder by the supplier during loading.
916-2.1.1 Additional Requirements for PG 76-22 (ARB): The following
additional requirements apply only to PG 76-22 (ARB):
1. The asphalt binder shall contain a minimum of 7.0% ground tire rubber
(GTR) by weight of asphalt binder.
2. The GTR shall meet the requirements of Section 919.
3. Polymer modification is optional for PG 76-22 (ARB).
4. Use of excess PG 76-22 (ARB): The Contractor may use excess PG 76-
22 (ARB) in other asphalt concrete mixes requiring the use of a PG 67-22 binder by blending
with straight PG 67-22 binder so that the total amount of ground tire rubber in the binder is less
than 2.0%. The Contractor may use excess PG 76-22 (ARB) in asphalt concrete mixtures
requiring the use of a PG 52-28 or PG 58-22 by blending with the designated binder in such
proportions that the total amount of ground tire rubber in the binder is less than 1.0%.
916-2.2 Compliance with Materials Manual: Producers of Superpave PG binders shall
meet the requirements of Section 3.5, Volume II of the Department’s Material Manual, which
may be viewed at the following URL:
http://www.dot.state.fl.us/programmanagement/Implemented/URLinSpecs/Section35V2.shtm
916-2.3 Reporting: Specification compliance testing results shall be reported for the tests
in the table below, unless noted otherwise. Quality control (QC) testing results shall be reported
for original binder DSR (G/sin δ and phase angle, as applicable).

SUPERPAVE PG ASPHALT BINDER


Specification
Test and Method Conditions Minimum/Maximum
Value
Superpave PG Asphalt
Report
Binder Grade
APL Number Report
Polymer, Ground Tire Rubber with
Modifier (name and type) Approved Product List (APL) number Report
and any Rejuvenating Agents
Original Binder
Minimum 99.0%
Solubility,
in Trichloroethylene (Not applicable for PG
AASHTO T 44-13
76-22 (ARB))
Flash Point,
Cleveland Open Cup Minimum 450ºF
AASHTO T48-06 (2010)
Rotational Viscosity,
275ºF Maximum 3 Pa·s(a)
AASHTO T 316-13
Dynamic Shear G*/sin δ Minimum 1.00 kPa
(REV 5-19-15) (FA 7-13-15) (1-16) Includes 9160000

Rheometer (b), Phase Angle, δ(c)


AASHTO T315-12 PG 76-22 (PMA) and PG 76-22 (ARB)(d) Maximum 75 degrees
PG 82-22 (PMA) Maximum 65 degrees
Separation Test,
ASTM D 7173-11 and 163±5°C
Softening Point, Maximum 15°F
AASHTO T53-11 48 hours (PG 76-22 (ARB) only)
Rolling Thin Film Oven Test Residue (AASHTO T 240-09)
Rolling Thin Film Oven,
Mass Change % Maximum 1.00
AASHTO T240-13
Multiple Stress Creep
Grade Temperature
Recovery, Jnr, 3.2 ”S” = 4.50kPa-1 max
(Unmodified binders only)
AASHTO M332-14
Multiple Stress Creep “V” = 1.0 kPa-1 max
67°C
Recovery, Jnr, 3.2(d, e, f) “E” = 0.5 kPa-1 max
(Modified binders only)
AASHTO M332-14 Maximum Jnr,diff = 75%
Multiple Stress Creep %R3.2 ≥ 29.37
(d, e) 67°C
Recovery, %Recovery (Jnr, 3.2)-0.2633
(Modified binders only)
AASHTO M332-14
Pressure Aging Vessel Residue (AASHTO R 28-12)
Dynamic Shear Rheometer, G*sin δ,
Maximum 5000 kPa(f, g
AASHTO T315-12 10 rad/sec.
Creep Stiffness, S (Stiffness), @ 60 sec. Maximum 300 MPa
AASHTO T313-12 m-value, @ 60 sec. Minimum 0.300
(a) Binders with values higher than 3 Pa·s should be used with caution and only after consulting with the supplier as to any
special handling procedures, including pumping capabilities.
(b) Dynamic Shear Rheometer (AASHTO T 315) shall be performed on original binders for the purposes of QC testing only.
(c) The original binder phase angle (AASHTO T 315-12) shall be performed at grade temperature.
(d) AASHTO T 315-12 and AASHTO T 350-14 will be performed at a 2 mm gap for PG 76-22 (ARB)
(e) All binders with a high temperature designation >67 will be tested at 67°C. PG 76-22 (PMA) and PG 76-22 (ARB) shall pass
a “V” graded and PG 82-22 (PMA) shall pass an “E” grade per AASHTO M 332-14.
(f) A maximum Jnr diff = 75% does not apply for any Jnr value < 0.5 kPa-1.
(g) For all PG grades of a PG 67 or higher, perform the PAV residue testing at 26.5°C with a maximum of 5000 kPa.

916-3 Asphalt Emulsions.


916-3.1 Compliance with Materials Manual: Producers of asphalt emulsions shall meet
the requirements of Section 3.4, Volume II of the Department’s Material Manual, which may be
viewed at the following URL:
http://www.dot.state.fl.us/programmanagement/Implemented/URLinSpecs/Section34V2.shtm
916-3.2 Requirements: Use a prime coat meeting the requirements of AASHTO M140-
08 for anionic emulsions, AASHTO M208-01 (2009) or AASHTO M316-13 for cationic
emulsions, or as specified in the Producer’s QC Plan. For anionic emulsions, the cement mixing
test will be waived. For tack products the minimum testing requirements shall include percent
residue, naphtha content (as needed), one-day storage stability, sieve test, Saybolt Furol
viscosity, original DSR, phase angle, and solubility. Residue testing shall be performed on
residue obtained from distillation (AASHTO T59-13) or low- temperature evaporation
(AASHTO PP72-11(2013) Method B).
(REV 5-19-15) (FA 7-13-15) (1-16) Includes 9160000

916-4 Liquid Anti-strip Agents.


916-4.1 Requirements: Liquid anti-strip agents shall be tested in accordance with FM 5-
508. Tensile strength ratios will be calculated for the following two conditions and expressed as
percentages:
1. conditioned mixture without anti-strip to unconditioned mixture without anti-
strip, and
2. conditioned mixture with anti-strip to unconditioned mixture without anti-strip.
A 20% gain in tensile strength ratio for condition 2 as compared to condition 1 shall be
required.
916-4.2 Mix Design Verification: Inclusion of a liquid anti-strip agent on the APL does
not guarantee that the anti-strip will be approved for use in an asphalt mixture. Specifications
may require subsequent moisture susceptibility testing per FM 1-T283 for the particular mix
design. Results from this testing may indicate the need for a larger dosage rate of anti-strip agent
(up to 0.75% maximum) or a different anti-strip agent to meet the specification requirements.

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