Chapter 5 Chemicals For Consumers: 5.1 Soap and Detergent (A) Soap
Chapter 5 Chemicals For Consumers: 5.1 Soap and Detergent (A) Soap
Chapter 5 Chemicals For Consumers: 5.1 Soap and Detergent (A) Soap
(A) Soap
~ soaps are prepared by hydrolyzing fats or oils under ( acid , alkaline ) condition <=>
__________________________.
(b) Neutralisation of fatty acid and concentrated alkali ~> ______ and water
~ in the process, soap is precipitated out ( using filtration method ) by adding sodium
chloride => _________________________________ of soap in water
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Table 2 : Types of soap and their properties
Solid soap Liquid soap
Harder soap Softer soap
Made from sodium hydroxide and saturated Made from potassium hydroxide and
oil, i.e. coconut oil unsaturated oil, i.e. olive oil
Used for bathing Used as liquid soap and shaving cream
(B) Detergent
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Mechanical agitation during scrubbing helps to pull
the grease free and break it into small droplets, thus
emulsifying the grease
~ formed insoluble long-chain fatty acids => reduces the amount of soap for cleaning
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Table 3 : comparison between soap and detergent
Soap Detergent
Effective cleaners in soft water Effective cleaners in hard water and soft
water
Form scum in hard water Do not form scum in hard water
Form precipitate in acidic water Do not form precipitate in acidic water
Biodegradable Non-biodegradable
Example 1
Which of the following is true about soap ?
I forms scum in acidic water
II does not form scum in soft water
III does not cause environmental pollution
IV it cleansing action is more effective than detergent in hard water
A I, III B II, III C I, II, III D I, II, IV
~ to _______________________________________________________________________
Filler ( Drying agent ) To make the solid detergent dry and enable
(i.e. sodium sulphate, sodium silicate) the liquid detergent to be poured easily
Fragrance To give detergent and fabrics a better smell
Optical brightener To convert some ultraviolet radiation to blue
(i.e. fluorescent dye) light and cause the fabrics look brighter and
whiter rather than yellow
Test 1
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1. The process of making soap is called
A neutralization B sulphonation
C alkaline hydrolysis D double decomposition
Part W Part X
4. Which of the following is correct about the detergent additives and their functions ?
Detergent additives Function
A Sodium perborate To soften the water
B Sodium tripolyphosphate To whiten the fabrics
C Sodium sulphate To remove protein stain
D Diethanolamide To control the foaming
(a) improve the taste, texture or appearance of a food , i.e. beewax coated on apples
is used to improve their appearance
(b) preserve and extend food storage life, i.e. sulphur dioxide is added to some meat
products such as sausage meat to prevent microbial growth
(c) enrich the nutrient of food
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(a) preservatives (b) antioxidants (c) flavouring
(d) stabilizers (e) thickeners (d) dyes or colouring
Preservatives Functions
Salt and sugar To draw the water out of the cells of bacteria or fungi ~>
prevent their growth
(b) Antioxidants
~ added to food to prevent ___________ causes rancid fats and brown fruits
Antioxidants Function
Vitamin E To prevent oils from going rancid
(c) Flavourings : to improve the taste or smell of food and restore taste loss due to food
processing
(d) Stabilisers : substance which helps to mix two liquids that usually do not mix together =>
form an emulsion.
~ Lecithin, acacia gum or gelatin => to prevent oil and water from separating out
(e) Thickeners : substances that thicken food and give food a firm, smooth and uniform
texture
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Thickeners Function
Pectin Indigested , as a dietary fibre
Starch, modified starch, xanthan gum To thicken the food and improve the food
texture
(f) Dyes or colourings : to add or replace colour lost during food preparation, or to make
food look more attractive
~ Azo compounds (red, orange or yellow) ;
Triphenyl compounds (blue, green)
Test 2
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C Preservative Thickener Colouring
D Thickener Preservative Colouring
3. Tumeric and pandan leaf are two types of plants commonly found in Malaysia. They can
be classified as
A antioxidant B colouring
C stabilizer D thickener
4. Diabetic patients are advised not to take too much sugar. Which of the following
additives can replace the function of sugar ?
A aspartame B xanthan gum
C sodium citrate D modified starch
5.3 Medicines
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~ Traditional medicines => to aid the body in healing itself and not just suppressing
symptoms of disease <= work very slowly
~ TM can cause side effects ,i.e. nausea, thirst, diarrhea, worsening the disease or death.
Some herbs are highly toxic.
analgesics
~ commonly known as painkiller => relief pain without causing numbness or affecting
consciousness
~ table below shows some common analgesics
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Antibiotics
~ used to treat infections caused by bacteria but not to cure infections cause by viruses
such as flue and cold
~ obtained from bacteria and fungi
~ table below shows some example of antibiotics
Psychotherapeutic
~ do not cure mental illness but just reduce the symptoms of mental illness
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(C) Side effect of modern medicine
Test 3
2. Gonorrhoea and syphilis are sexual transmitted diseases. Which of the following
medicines is used to treat these diseases ?
A Chlorpromazine B paracetamol C penicillin D stimulant
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5. What is the side effect of amphetamine if it is abused ?
A gastric B arthritis pain
C gain in weight D mental disorder
2 Which of the following is one of the products formed when palm oil is boiled in dilute
sodium hydroxide solution?
I Sodium chloride II Glycerol III Sodium palmitate IV Sodium acetate
A II, III B I, II, III C II, III, IV D I, II, III, IV
3 What is observed when vegetable oil is heated with excess potassium hydroxide
solution?
A Two layers of clear liquids are formed C A fragrance odour is detected
B White solid floats on the liquid surface D The layer of oil disappeared
8 Which of the following processes occur during the cleaning action of soap?
I The wetting ability of water increases
II The grease particles form emulsion
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III The hydrophobic part of the soap molecule dissolves in grease
IV The mechanical agitation during scrubbing helps free the grease from the clothes’
surface
A I, II B III, IV C I, II, III D I, II, III, IV
9 Which of the following pairs regarding additives in detergent and their functions in
incorrectly matched?
Additives in detergent Function
A Sodium silicate Enhance cleaning efficiency
B Sodium tripolyphosphate Prevent removed dirt particles from
redepositing onto fabrics
C Protease To convert stains into colourless substances
D Stibene To add brightness to white fabrics
10 Which of the following is not true about soap?
I It reduces surface tension of soap
II It is less effective than detergent in soft water
III Its anions form micelles when dissolves in water
IV Its cation dissolves in water but the anion dissolves in grease
A I, II B II, IV C I, III, IV D I, II, III, IV
11 One way of preparing soap by boiling palm oil with sodium hydroxide solution. What is
the name of the chemical reaction involved?
A Neutralisation B Esterification C Saponification D Sulphonation
13
C D
The chemical equation shows the reaction involved in the preparation of soap. Which of
the following statements is true?
A A is an unsaturated oil
B B can be replaced by ammonia
C C is insoluble in water
D D is precipitated when excess sodium chloride is added to its solution
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14 Which of the following represent the structure of a detergent unit?
17 Which of the following correctly describes the order of the reactions involved in the
synthesis of detergent?
A Alkylation Sulphonation Neutralisation
B Neutralisation Sulphonation Alkylation
C Sulphonation Alkylation Neutralisation
D Alkylation Neutralisation Sulphonation
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19 The following structure shows a part of the structural formula of a detergent
molecule.
23 Sulphur dioxide is a common food additive. Which of the following are uses of
sulphur dioxide?
I To fumigate the fruit
II To extend the shelf life of vegetables
III To improve the appearance of food
IV To preserve the wine
A I, II B II, III C I, II, IV D II, III, IV
24 Salt is used to preserve food. The preservative action of salt (NaCl) is due to
A the presence of chlorine C its dehydrating properties
B its saltiness D its toxicity
25 Which of the following is not the reason for using food additives?
A To make food stay fresh longer
B To increase food production
C To make seasonal crops available throughout the yeat
D To improve quality of food
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26 Dyes of colourings are added to food to replace colours lost during preparation, or
to make food look more attractive. Which of the following is an artificial colour?
A Tumeric B Pandan C Saffron D
Tartrazine
28 Browning occurs when cut apples or potatoes are exposed to air. Which of the
following food additives can be used to prevent browning?
A Flavouring B Stabilisers C Antioxidants D Dyes
33 Which of the following pairs regarding traditional medicines and their uses is
correctly matched?
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36 Which of the following are psychotherapeutic medicines?
I Penicillin II Stimulant III Antidepresent IV Antipsychotic
A II B II, III C II, III, IV D I, II, III, IV
44 Today, barbiturates are gradually phasing out as sedatives and are replaced by
mild tranquilisers such as benzodiazepines.
Which of the following could be the reason for phasing out barbiturates?
A To avoid physical and psychological dependency
B To reduce bacterial infection
C to avoid stomach discomfort
D to improve drug tolerance
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46 A patient must finish a full course of antibiotic prescribed by the doctor. Which
of the following statements best explains this?
A To prevent bacteria from becoming more resistant to the antibiotic.
B To improve the body immunity
C To minimize the side effect
D To prevent wastage
47 Codeine is synthesized from morphine and has analgesic property. Which of the
following is not the side effect of using codeine?
A Dry mouth B Drowsiness C Nausea D Diarrhoea
48 A patient claims that other people read his mind and controlling his thought.
Question 1
The equation below shows the reaction for the preparation of soaps.
(ii) For every one molecule of palm oil used, how many soap molecules are
produced?[1m] _____________________________________________
(iii) If a potassium soap is needed, what reagent must be used instead of sodium
hydroxide?[1m]
_______________________________________________________________
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(b) What is the purpose of adding sodium chloride to the mixture solution?[1m]
________________________________________________________________
________________________________________________________________
________________________________________________________________
________________________________________________________________
________________________________________________________________
________________________________________________________________
________________________________________________________________
________________________________________________________________
________________________________________________________________
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Question 2
P : _________________ Q : ____________________
(b) When compound P dissolves in water, it dissociates to form sodium ion and
anion. The anion is made up of two parts according to their behaviour towards
water.
(i) Based on diagram above, write the structural formula of the anion formed
and identify the two parts by drawing a rectangle over each part.[2m]
____________________________________________________________
____________________________________________________________
(iii) Write an equation to show why Q is less effective than P in hard water.
[1m]
____________________________________________________________
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Question 3
A : _____________________________________________________________
C : _____________________________________________________________
______________________________________________________________
D : _____________________________________________________________
________________________________________________________________
________________________________________________________________
(d) Which of the medicine listed in the table above may lead to addition of
misused? [2m]
________________________________________________________________
Question 4
______________________________________
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____________________________________________________________
____________________________________________________________
____________________________________________________________
____________________________________________________________
(c) (i) Name the reaction that occurs when aspirin is refluxed with dilute
hydrochloric acid. [1m]
____________________________________________________________
____________________________________________________________
(iii) Circle the functional groups present in aspirin that are relatide to one
another chemically in diagram above.[2m]
Question 5
(a) Common salt (sodium chloride), sugar and spices are three natural compounds
used to preserve food apart from improving the taste of food.
(i) What is a food preservative?[1m]
____________________________________________________________
____________________________________________________________
____________________________________________________________
____________________________________________________________
____________________________________________________________
(iii) Sodium nitrite is an artificial food preservative. Ascorbic acid (vitamin C),
a naturally occurring compound can also act as a food preservative. Explain
how the two act to preserve food.[2m]
____________________________________________________________
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____________________________________________________________
____________________________________________________________
(iv) State one adverse side effect for the excessive intake of sodium nitrite.
[1m]
____________________________________________________________
(b) Sugar is used as food preservative as well as for sweetening. Patients with
medical conditions such as diabetes mellitus or obesity must be wary of their
intake of sugar.
(i) Name one artificial sweetener that can replace sugar. [1m] ____________
(ii) Name one natural sweetener that can replace sugar. [1m] ______________
(c) Artificial food colourings are used in some processed foods. Suggest two
reasons for using food colouring. [2m]
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