General Chemistry Module 19
General Chemistry Module 19
General Chemistry Module 19
Department of Education
Region I
SCHOOLS DIVISION OF ILOCOS NORTE
General
Chemistry 1
Quarter 1 – Module 19:
Gas Stoichiometry
Prepared by:
MARISSA G. AREOLA
Teacher I
Bangui National High School
General Chemistry 1
Quarter 1 – Module 19: Gas Stoichiometry
First Edition, 2020
Republic Act 8293, section 176 states that: No copyright shall subsist in
any work of the Government of the Philippines. However, prior approval of the
government agency or office wherein the work is created shall be necessary for
exploitation of such work for profit. Such agency or office may, among other things,
impose as a condition the payment of royalties.
Borrowed materials (i.e., songs, stories, poems, pictures, photos, brand
names, trademarks, etc.) included in this book are owned by their respective
copyright holders. Every effort has been exerted to locate and seek permission to use
these materials from their respective copyright owners. The publisher and authors
do not represent nor claim ownership over them.
In addition to the material in the main text, you will also see this box in the
body of the module:
As a facilitator, you are expected to orient the learners on how to use this
module. You also need to keep track of the learners' progress while allowing them to
manage their own learning. Furthermore, you are expected to encourage and assist
the learners as they do the tasks included in the module.
For the learner:
What I Need This will give you an idea of the skills or competencies
to Know you are expected to learn in the module.
1
In this portion, the new lesson will be introduced to
What’s New
you in various ways such as a story, a song, a poem,
a problem opener, an activity or a situation.
What I Can This section provides an activity which will help you
Do transfer your new knowledge or skill into real life
situations or concerns.
2
The following are some reminders in using this module:
1. Use the module with care. Do not put unnecessary mark/s on any part of the
module. Use a separate sheet of paper in answering the exercises.
2. Don’t forget to answer What I Know before moving on to the other activities
included in the module.
3. Read the instruction carefully before doing each task.
4. Observe honesty and integrity in doing the tasks and checking your answers.
5. Finish the task at hand before proceeding to the next.
6. Return this module to your teacher/facilitator once you are through with it.
If you encounter any difficulty in answering the tasks in this module, do not
hesitate to consult your teacher or facilitator. Always bear in mind that you are not
alone.
We hope that through this material, you will experience meaningful learning
and gain deep understanding of the relevant competencies. You can do it!
This module was designed and written with you in mind. It is here to help
you master gas stoichiometry. The scope of this module permits it to be used in many
different learning situations. The language used recognizes the diverse vocabulary
level of students. The lessons are arranged to follow the standard sequence of the
course. But the order in which you read them can be changed to correspond with
the textbook you are now using.
2. Use volume ratios and other stoichiometric principles to solve problems involving
mass, molar amounts and volumes of gases.
What I Know
3
This part of the module is a pre-assessment activity that allows your teacher to
determine your strengths, weaknesses, knowledge and skills about stoichiometry on
gases. Choose the letter of the best answer. Write the chosen letter on a separate sheet
of paper and submit a copy of it to your subject teacher.
2. How many liters of oxygen gas are needed to react with 0.432 grams of SO2 gas at
STP? 2SO2(g) + O2(g) → 2SO3(g)
a. 0.0541 L c. 0. 0755 L
b. 0.0678 L d. 0.128 L
d. The volume of a mole of a gas will always be 22.4 liters, regardless of the
a. 45.87 L c. 51. 58 L
b. 49.26 L d. 57.14 L
5. Refer to the reaction above, how many liters of NH3 will be produced if 8 liters of
N2 are consumed?
a. 15 L b. 16 L c. 17 L d. 18 L
Lesson
19 Gas Stoichiometry
4
Chemical reactions frequently involve both solid substances whose mass can
be measured easily. For the mass of gaseous reactant or product, it can be measured
by collecting it in suitable flask that has been previously weighed while evacuated.
The difference between the flask weight with the gas when evacuated gives the grams
of gas in the flask. As you might imagine, this is not a convenient experimental
approach to working with gases. Fortunately, there are other ways to determine the
quantity of a reagent in the gas phase. You will learn of the ideal gas law, which
provides a relationship between the moles of gas and three variables –pressure,
volume and temperature- that are easily measured. Using the ideal gas law, you will
then solve stoichiometry problems in which the amount of a gas is given in terms of
pressure, volume and temperature.
What’s In
Before you proceed with the next lesson, recall your previous knowledge on gas
laws. Write the letter of the best answer on a separate sheet of paper and submit a
copy of it to your subject teacher
1. An aerosol can of air freshener is sprayed into a room. What happens to the
pressure of the gas if its temperature stays constant?
a. increases c. increases then decreases
b. decreases b. remains the same
2. The variable that stays constant when using the combined gas law is
a. Amount of gas c. temperature
b. Pressure d. volume
4. Under which of the following volumes will 1.00 mol of an ideal gas exhibit
the greatest pressure at 300 K?
a. 0.01 L b. 0.10 L c. 1.00 L d. 10.0 L
5. Which among the following systems will have the greatest volume at STP?
a. 1.00 g N2 gas (M = 28 g/mol) c. 1.00 g CO2 gas (M = 44 g/mol)
b. 1.00 g NH3 gas (M = 17 g/mol) d. 1.00 g He gas (M = 4 g/mol)
5
Note the Teachers
The teacher must consider the prerequisite skills needed in
the development of this competency including the schema or
background knowledge which may reinforce learning. This module
will help the learners bridge the gap of learning to attain mastery
of the lesson in its spiral progression.
What’s New
This part of the module will let you understand the concepts on stoichiometry
on gases. Indicate whether each statement is true or false. Write your answer on a
separate sheet of paper and submit a copy of it to your subject teacher.
1. The molar volume of a gas is the volume that 1 mol occupies at 00C and 1.0 atm
pressure.
2. The number of moles of a gas (n) is equal to the mass (m) divided by the molar
mass (M).
3. The molecular weight/ molar mass of a gaseous compound is a non-variable
quantity.
4. Gases have low densities.
5. When gases react, coefficients in the balanced equation represent molar amou
nts and relative volumes.
What is It
Gas Stoichiometry
Gas Stoichiometry deals with reactions involving gases, where the gases are
at known temperature, pressure, and volume and can be assumed to ideal gas. With
the ideal gas law, we can use the relationship between the amount of gases in moles
and their volumes in liters to calculate the stoichiometry of reactions involving gases,
6
if the pressure and temperature are known. For gases, the volume ratio is ideally the
same as the ideal gas law, but the mass ratio of a single reaction has to be calculated
from the molecule masses of the reactants and products. In practice due to the
existence of isotopes, molar masses are used instead when calculating the mass ratio.
As before, we also need to consider mole ratios, when examining reactions
quantitatively. At times, you will be able to use 22.4 L/mol at STP (standard
temperature and pressure)
By an extension of Avogadro’s principle, when gases react, coefficients in the
balanced equation represent molar amounts and relative volumes.
Example: Given the Haber process N2(g) + 3H2(g) → 2NH3(g). How many liters of
NH3 can be produced at a temperature of 270 C and a pressure of 760 torr, if 20 moles
of N2 are consumed?
Note: You have to make sure that the chemical equation given is balanced.
1 mole of N2 (given) = 2 mole of NH3(unknown), this can be used as a conversion
factor.
Solution: You have to calculate the n (amount of substance, moles) of NH3 from the
given mole of N2 (always start with the given)
2 𝑚𝑜𝑙𝑒 𝑜𝑓 𝑁𝐻3
20 mols of N2 x = 40 mols of NH3
1 𝑚𝑜𝑙𝑒 𝑜𝑓 𝑁2
To solve for the volume in liters, we will use the ideal gas law equation, PV=nRT,
7
R= 0.08201 L-atm/mol K
Note that all units will cancel except liters, solving for V you need to divide both
sides by 1 atm.
V = 984.12 L of NH3
Example: CH4 burns in O2, producing CO2 and H2O. A 1.22 L CH4 cylinder, at 150C
registers a pressure of 328 kPa.
a. What volume of CO2 (at STP) is produced if only 2.15 g of the CH4 was
burned?
b. What volume of O2 at STP will be required to react completely with all of the
CH4?
CH4(g) + 2O2(g) → CO2(g) + 2H2O(g)
Since we have the number of moles of CH4, we can solve the volume at the given
condition STP using ideal gas law, PV=nRT
8
Dividing both sides by (0.08205)(288), we can now solve for n
n = 0.167 mol of CH4
From the mol of CH4 we can now solve the number of mol of
2 𝑚𝑜𝑙 𝑜𝑓 𝑂2
0.167 mol of CH4 x = 0.335 mol of O2
1 𝑚𝑜𝑙 𝑜𝑓 𝐶𝐻4
Solution: You have to find the number of moles of the unknown using the given
mass of the given to be able to apply the ideal gas law equation.
𝑚𝑜𝑙 12 𝑚𝑜𝑙 𝑜𝑓 𝐶𝑂2
100 g of C3H5(NO3)3 x = 1.32 mol of CO2
227 𝑔 4 𝑚𝑜𝑙 𝑜𝑓 𝐶3 𝐻5 (𝑁𝑂3)3
The easiest since according to the law of combining gas volumes, gases combine
at the same temperature and pressure in simple whole number of volumes. What this
means is that we can use the coefficient in the balanced equation to form volume
relationship.
Example: How many liters of H2 gas will react with 5.0 L of O2 to form water?
Given: V of O2 = 5.0 L V of H2 = ?
9
Note: 2 L of H2 = 1 L of O2 (from the balanced chemical equation)
2 𝐿 𝑜𝑓 𝐻2
Solution: 5.0 L of O2 x = 10 L of H2
1 𝐿 𝑜𝑓 𝑂2
What’s More
This part of the module will strengthen your understanding and skills of the
topic. Each problem needs more information to determine the answer. List as many
letters as are needed to answer and solve the problem. Write the chosen letter/s on a
separate sheet of paper and submit a copy of it to your subject teacher.
10
What I have Learned
Directions: Fill in the table and complete the following phrases to generalize the
things you have learned about the topic. Write your answer on a separate sheet of
paper and submit a copy of it to your subject teacher.
What I Can Do
Directions: Create a road map to Gas Stoichiometry. You will decide, choose your
own adventure how do you prefer to do it. You can use numbered text, bullet type or
you can construct a diagram. Figure out where you’re starting from and where you’re
ending that correspond the journey you need to take. Submit your output to your
subject teacher. (see attached rubric for the scoring)
1. Mole to Volume (Volume to Mass)
2. Mass to Volume (Volume to Mass)
3. Volume to Volume
11
Assessment
This is a task which aims to evaluate your level of mastery. Answer each
question briefly. Write your answer on a separate sheet of paper and submit a copy
of it to your subject teacher.
1. Consider the reaction 2H2(g) + O2(g) → 2H2O (g), then answer the
following questions
a. List at least two types of information provided by the coefficients in the
equation.
_____________________________________________________________
______________________________________________________________
d. List the steps you would use to find the mass of oxygen that would
react with a known number of moles of hydrogen.
e. Find the mass of water produced from 4.0 L H2 at STP if all of it reacts.
12
Additional Activities
Directions: Solve the following completely. Write your solution on a separate sheet
of paper and submit a copy of it to your subject teacher.
1. Ammonia NH3 gas can be synthesized from nitrogen gas N2 and hydrogen gas
H2. What volume of ammonia at 450 kPa and 800C can be obtained from the
complete reaction of 7.5 g hydrogen gas?
2. Hydrogen gas and NaOH is produced when sodium metal is added to water.
a. Write the balanced chemical equation.
b. What mass of Na is needed to produce 20.0 L of H2 at STP?
13
interpretations
and conjectures.
Steps, Diagrams Diagrams and Diagrams and/or Diagrams Diagrams
and Sketches /or sketches are sketches are and/or sketches and/or sketches
(Process) clear and clear and easy to are somewhat are difficult to
greatly add to understand difficult to understand or
the reader’s understand are not used
understanding
of the
procedure(s)
14
References
https://courses.lumenlearning.com/boundless-chemistry/chapters/gas-stoichiometry/
hhtps://www.ck12.org/chemistry/gas-stoichiometry/lesson/Gas-Stoichiometry-CHEM/
https://www.everettcc.edu/files/programs/academic-resources/transitional-
studies/support/tutoring-center/chemistry/w320-gas-stoichiometry-worksheet.pdf
https://www.chemteam.info/Stoichiometry/Mass-Volume-Prob1-10.html
http://www.chalkbored.com/lessons/chemistry-11/gas-stoichiometry-answers.pdf
Flores. Rodante G. et. al.(2016). General Chemistry 1. Quezon City: Lorimar Publishing, Inc.
Office Address: Brgy. 7B, Giron Street, Laoag City, Ilocos Norte
Telefax: (077) 771-0960
Telephone No.: (077) 770-5963, (077) 600-2605
E-mail Address: ilocosnorte@deped.gov.ph
15