Sample Paper Jee With Answers
Sample Paper Jee With Answers
Sample Paper Jee With Answers
Answer Key
PHYSICS
1. a 2. d 3. a 4. c 5. a 6. b 7. b 8. b 9. b 10. b
CHEMISTRY
1. a 2. b 3. d 4. c 5. d 6. c 7. c 8. d 9. b 10. a
MATHEMATICS
1. b 2. b 3. d 4. c 5. b 6. a 7. b 8. b 9. c 10. b
1 A truck is pulling a car out of a ditch by means of a steel cable is 9.1 m long and has a radius of 5 mm. When the car just begins
to move, the tension in the cable is 800 N. How much has the cable stretched? (Young's modulus for steel is 2 × 10 11 N/m 2 .)
Solution
Radius, r = 5 mm = 5 × 10 -3 m
Change in length l = ?
A
×
l
Δl
or Δ l =
F
πr
2
×
l
=
800
−3
2
×
9.1
11
3.14×(5×10 ) 2×10
= 4.64 × 10 -4 m
2 Three wires of same material (Young's modulus Y) but length L, 2L and 3L and radii R, 2R and 3R respectively are joined end to
end and weight ω is suspended as shown below. Then the elastic potential energy of system neglecting the self weight is
Solution
1 (stress)
E = × × volume
2 Y
V1 = (πR )L = πR L
2 2
2 2
V2 = π(2R) (2L) = 8πR L
2 2
V3 = π× (3R) × (3L) = 27πR L
⇒ σ 1 =
Area
W
=
W
πR
σ 2 =
W
2
and σ3 =
W
4πR 9πR
Now, E = E 1 + E 2 + E 3
2 2 2
σ σ σ
1 1 1 2 1 3
⇒ E = ⋅ ⋅ V1 + ⋅ V2 + ⋅ ⋅ V3
2 Y 2 Y 2 Y
2 2 2
2 2
1 w πR L 1 w 8πR L 1 w 27 2
= [ 2
] ⋅ + [ 2
] ⋅ + [ 2
] × πR L
2 πR Y 2 4πR Y 2 9πR Y
2 2 2 2
w L w L w L 11w L
⇒ E = + + =
2 2 2 2
2πR Y 4πR Y 6πR Y 12πR Y
3 Four wires of the same material are stretched by the same load. Which one of them will elongate most, if their dimensions are
as follows
Solution
ΔL =
FL
AY
Because, wires of the same material are stretched by the same load. So, F and Y will be constant.
∴ ΔL ∝
πr2
L
=
πr2
kL
Where R=
F
Y
=Constant
ΔL1 =
100k
−3 2
=
100k
−6
π×(1×10 ) π×10
=
100k
π
× 10 k
6
∴ ΔL2 =
200k
−3 2
=
200k
−6
π×(3×10 ) π×9×10
=
22.2
π
× 10 k
6
∴ ΔL3 =
300k
−3 2
=
100k
−6
π×(3×10 ) π×9×10
=
33.3
π
× 10 k
6
∴ ΔL4 =
400k
−3
=
400k
−6
π×(4×10 )2 π×16×10
=
25
π
× 10 k
6
4 Compute the bulk modulus of water if its volume changes from 100 litres to 99.5 litre under a pressure of 100 atmosphere.
Solution
5
(100×1.013×10 )
Δp
BW = −V = −100 ×
ΔV (99.5−100)
= 2.026 × 10 9
N/m
2
B A = Eθ = p
0
= 1.013 × 10 N/m
5 2
9
BW CA 2.026×10 4 1
= = = 2 × 10 ]
5 B
BA CW 1.013×10
i.e., bulk modulus of water is very large as compared to air. This means that air is about 20,000 times more compressive than water,
i.e., the average distance between air molecules is much larger than between water molecules.
5 A rod AD, consisting of three segments AB, BC and CD joined together, is hanging vertically from a fixed support at A. The
lengths of the segments are respectively 0.1 m, 0.2 m and 0.15 m. The cross - section of the rod is uniform 10 -4 m 2 . A weight of
10 kg is hung from D. Calculate the displacements of point D if Y AB = 2.5 x 10 10 N/m 2 , Y BC = 4 x 10 10 N/m 2 and Y CD = 1 x 10 10 N/m 2 .
(Neglect the weight of the rod.)
Solution
FL MgL
ΔL = =
AY YA
2.5×10 ×10
= 3.92 × 10
−6
m
10 −4
4×10 ×10
= 4.90 × 10 −6
m
1×10 ×10
= 14.7 × 10 −6
m
So displacement of B = ΔL1
= 3.92 × 10
−6
m
= 8.82 × 10
−6
m
= 23.5 × 10
−6
m
6 A man grows into a giant such that his linear dimensions increase by a factor of 9. Assuming that his density remains same, the
stress in the leg will change by a factor of:
Solution
Stress
F Mg
= =
A A
ρ(V olume) .g
=
A
3 3
ρ(9 x ) g
=
2
9 x2
= 9 times
7 Two liquids which do not react chemically are placed in a bent tube a shown in the figure. The heights of the liquids above their
surface of separation are
Solution
The pressure at the interface must be same, calculated via either tube. Since, both tube are open to the atmosphere, we must have
h1 ρ1 g = h2 ρ2 g
or h1 ρ1 = h2 ρ2
or hρ = constant
or h ∝
1
8 The Bulk moduli of Ethanol, Mercury and water are given as 0.9, 25 and 2.2 respectively in units of 10 9 Nm –2 . For a given value of
pressure, the fractional compression in volume is . which of the following statements about
ΔV
V
for these three liquids is
ΔV
correct ?
Solution
B =
P
ΔV
∴ (
ΔV
V
) =
P
( )
V
(∴
ΔV
V
) ∝
1
∴ Correct order
9 Two wires of equal length and cross-section are suspended as shown. Their Young's modulii are Y1 and Y respectively. The
2
Solution
K =
YA
or
Y (2A) Y1 A Y2 A
= +
l l l
or
Y1 +Y2
Y =
2
10 We have two (narrow) capillary tubes T and T . Their lengths are l and l and radii of the cross-section are r and r
1 2 1 2 1 2
respectively. The rate of water under a pressure difference P through tube T is 8 cm s . If l = 2l and r = r , what will be
1
3 −1
1 2 1 2
the rate of flow when the two tubes are connected in series and the pressure difference across the combination is same as before(= P
)
Solution
4
πPr 3 −1
V = = 8 cm s
8ηl
4 4
Pπr 2 πPr 2 16 3 −1 l
V1 = = = × 8 = cm s [∴ l1 = l = 2l2 or l2 = ]
l 3 8ηl 3 3 2
8η(l+ )
2
11 A 14.5 kg mass, fastened to one end of a steel wire of unstretched length 1 m is whirled in a vertical circle with an angular
frequency of 2 rev/s at the bottom of the circle. The cross- sectional area of the wire is 0.065 cm 2 . Calculate the elongation of
the wire when the mass is at the lowest point of its path.
Solution
= 2π × 2 rad/s
= 4π rad/s
= 6.5 × 10 -6 m 2
T - mg = mlω 2
or T = mg + mlω 2
= 14.5(9.8 + 16π 2 )
= 14.5 × 167.72 N
= 2431.94 N
Stress (T / A)
Young's modulus (Y) = =
Strain Δl/l
=
Tl
A⋅Δ l
Δl =
T⋅ l
A⋅Y
=
2431.94×1
−6 11
6.5×10 ×2×10
= 1.87 × 10 -3 m
= 1.87 mm
12 A rod of length 1.05 m having negligible mass is supported at its ends by two wires of steel (wire A) and aluminium (wire B) of
equal lengths as shown in figure. The cross-sectional areas of wires A and B are 1 mm 2 and 2 mm 2 respectively. At what point
along the rod should a mass m be suspended in order to produce equal stresses.
Solution
L et length of each wite be L and their area of cross-section be A l and A 2 respectively.
Given, A 1 = 1 mm 2 =1 x 10 -6 m 2
A 2 = 2 mm 2 = 2 x 10 -6 m 2
Y steel = 2 x 10 11 N-m 2
Y Al =7.O x 10 10 N-m 2
F1 F2
=
A1 A2
−6
F1 A1 1×10
or = =
F2 −6
A2 2×10
F1 1
or = ...(i)
F2 2
Let mass m be suspended at distance x from steel wire A. Taking moment of forces about the point of suspension of mass from the
rod, we get
F 1 x = F 2 (1.05 - x)
F1 (1.05−x)
or = ...(ii)
F2 x
1 (1.05−x)
=
2 x
x = 2.10 - 2x
or 3x = 2.10
or x = 0.70 m
[Take atmospheric pressure = 1.0 × 10 N m , density of water = 1000 kg m and g = 10 ms . Assume temperature to be constant
5 -2 -3 -2
Solution
In this question, we will have to assume that temperature is constant for enclosed air above water (or pV = constant) (∵ Boyle's
Law)
p = p 0 - ρgh ...(i)
CHEMISTRY
1 If the enthalphy of vaporization of water at its normal boiling point is 186.5 kJmol −1
, the entropy if its vaporization will be:
Solution
ΔH = 186.5 kJmol
−1
o
= 100 C = 100 + 273 = 373K
Entropy change,
−1
ΔH 186.5 kJ mol
ΔS = =
T 373K
−1 −1
= 0.5 kJ mol K
2 The heat atomisation of PH 3 (g) is 228 kcal per mol and that of P 2 H4 (g) is 335 kcal per mol. The energy of P − P bond is
Solution
Step1. P − H bond energy from bond dissociation energy of PH3 (g) containing 3 such P − H bonds
=
228
3
= 76 kcal/mol
3 He,N2 and O are expanded adiabatically and their expansion curves between P and V are plotted under similar conditions.
3
Solution
slope for
γ f or gas I
Ratio of slope = ;
γ f or gas II
4 For a reaction in which all reactants and products are liquids, which one of the following equations is most applicable?
Solution
Δn(g) = 0
ΔH = ΔE − Δng RT
ΔH = ΔE (∵ Δng = 0)
5 10 mole of an ideal gas is heated at constant pressure of one atmosphere from 27 o C to 127 o C. If C v, m = 21.686 + 10 -3 T, then ΔH
for the process is :
Solution
= 30 + 10 −3
T
ΔH = ∫ nCp, m dT
= 10 × ∫ (30 + 10
−3
T) ⋅ dT
−3
10 2 2
ΔH = 10[30 (T2 − T1 ) +( × [T − T ] × 10)]
2 2 1
6 One mole of a non-ideal gas undergoes a change of state (2.0 atm, 3, 0 L,95(K) → (4.0 atm, 5.0 L, 245 K) with a change in
internal energy, ΔU = 30.0 L atm is
Solution
ΔH = H2 − H1 = (E2 + P2 V2 ) − (E1 + P1 V1 ) = (E2 − E1 ) + P2 V2 − P1 V1
= 30 + 4 × 5 − 2 × 3 = 44 L atm
7 A piston is cleverly designed so that it extracts the maximum amount of work out of a chemical reaction, by matching P external to
the P internal at all times. This 8cm diameter piston initially holds back 1 mol of gas occupying 1 L, and comes to rest after being
pushed out a further 2 L at 25 o C .After exactly half of the work has been done, the piston has travelled out a total of
Solution
v i = 1 lit
v f = 1+2 = 3 lit
W = -n RT ln
3
1
= −2 ⋅ 303 RT log 3
−
W
2
= −
2⋅303 RT
2
log 3 = −2 ⋅ 303 RT log
V
2
log 3 = log V (V is new final volume)
log√3 = log V
∴ V = 1 ⋅ 732 L
V of cylinder = π r 2 h
732 cm
3
= 3 ⋅ 142 × (4)
2
× h
732
≈ 14 ⋅ 5 cm
50⋅24
8 Equal volumes of monoatomic and diatomic gases are taken at same temperature and pressure. The ratio of adiabatic
exponents of the gases will be-
Solution
Cp
γ1 = = 1.67
Cv
Cp
γ2 = = 1.40
Cv
1.67
∴ γ1 : γ2 = = 1.19 : 1
1.40
C6 H12 O6 + 6 O2 → 6 CO2 + 6 H2 O; ΔH = − 72 kcal/mol. How much energy will be released by the combustion of 1.6 g of
glucose (Molecular mass of glucose = 180 g/mol )?
Solution
C H O + 6O
6 12 → 6CO + 6H O; ΔH = -72 kcal
6 2 2 2
72×1.6
ΔH per 1.6 g = = 0.64 kcal
180
Which of the following figures given below shows adiabatic process;
10
Solution
Adiabatic slope are more steeper than isothermal. Slope of adiabatic process = γ× slope of isothermal process.
Heats of atomization of C, H, O are 717, 218, 249 KJmol -1 each. Fill your answer dividing by 100
Solution
ΔH
∘
f
= −62 ⋅ 0 = Σreac BE − Σproduct BE
Σproduct BE is heat of atomization of product into isolated gaseous atoms.
12 ΔC p for reaction be 2.0 + 0.2 T cal/deg. Its enthalpy of reaction at 10 K is -14.2 Kcal/mol. Its negative enthalpy of reaction at
100 K in Kcal/mol will be nearly
Solution
ΔH2 −ΔH1
By Krichoff's equation, = ΔC P
T2 − T1
T2 100 K
or Δ H2 −Δ H1 = ∫ Δ C p dT = ∫ (2 ⋅ 0 + 0 ⋅ 2 T)dT
T1 10 K
100 K
2 100 K
T 2
= [2 ⋅ 0 T +0 ⋅ 2 ] = [2 ⋅ 0T + 0 ⋅ 1T ]
2 10 K
10 K
= 2 × 90 + 0 ⋅ 1 × 110 × 90
= 1.17 Kcal/mol
= 1.17 Kcal/mol
∘ −1
Δf H for NaBr (s) = −360 ⋅ 1 kJ mol
Solution
Na (s) → Na (g);ΔHsub
∘
Na(s)
= +108 ⋅ 4 kJ
Na (g) ⟶ Na
+
(g)
+ 1e
−
; IENa(g) = +496 KJ
BDE(Br
)
1 2
Br2 (g) → Br (g); = 96 ⋅ 0 kJ
2 2
Br(g) + 1e
−
⟶ Br
−
(g)
; EAI(Br)
g
= −325 KJ
Na +
(g)
+ B r̄ (g) → NaBr (s) ; L.ENaBr(s) = Δlattice H
o
(NaBr)s
Na (s) +
1
2
Br2 (g) ⟶ NaBr (s) ; Δf H
o
NaBr(s)
= −360.1 KJ
i.e Δf H
o
(NaBr)
= ΔH
o
subNa(s)
+ IENa(g) +
B.D.E
2
(Br2 )
g
+ EAI
Br(g)
+ ΔLattice H
∘
NaBr(s)
L.ENaBr(s) = -735.5 kJ
MATHEMATICS
If sin x + cosec x + tan y + cot y = 4, where x ∈ (0, π/2] and y ∈ (0, then tan is a root of the equation
y
1
π
),
2 2
Solution
As α + α
1
≥ 2 if α > 0
Hence
π
sin x + cos ec x ≥ 2 ......(i) (f or x ∈ (0, ])
2
π
at y =
4
y
2 tan
tan y =
2
2
y
1−tan
2
y
2 tan
tan
π
4
=
2
2
1−tan
2
y y
2
1 − tan = 2 tan
2 2
y y
2
tan + 2 tan − 1 = 0
2 2
Solution
1
=
sin A
sin B
A+B A−B
2 cos( ) sin( )
2 2
=
A+B A−B
2 sin( ) cos( )
2 2
⇒
n−1
n+1
= tan (
A−B
2
) cot (
A+B
2
)
Solution
Since,
α+γ
∴ β =
2
α+γ α−γ
2cos( )sin( )
sinα−sinγ 2 2
=
cosγ−cosα α+γ α−γ
2sin( )( )
2 2
α+γ sinα−sinγ
cot( ) =
2 cosγ−cosα
sinα−sinγ
∴ = cotβ
cosγ−cosα
Solution
Given relation is
2
2
2 sin θ = (r − 1) + 2
R. H. S ∈ [2, ∞)
Now L. H. S = 2
⇒ sin θ = 1
⇒ θ =
π
2
,
5π
2
,
9π
2
(θ ∈ [0, 5π])
And R. H. S = 2
⇒ r
2
= 1
⇒ r = ± 1
2
, then tan x is
Solution
2 x x
1−tan 2 tan
⇒
2
2
x
+
2
2
x
=
1
1+tan 1+tan
2 2
Let tan
x
2
= t , then
2
1−t 2t 1
+ =
2 2
1+t 1+t 2
2 2±√7
⇒ 3t − 4t − 1 = 0 ⇒ t =
3
x 2+√7 x π x
⇒ t = tan = [∵ 0 < < , tan is positive]
2 3 2 2 2
x
2 tan
Now, tan x = 2
2
1−tan
2
2+√7
2( ) 3(2+√7)
3 1−2√7
= 2
= − ×
2+√7 1+2√7 1−2√7
1−( )
3
4+√7
⇒ tan x = − ( )
3
Solution
sin
π
16
⋅ sin
3π
16
⋅ sin
5π
16
⋅ sin
7π
16
=
1
2
[2 sin
5π
16
sin
3π
16
] ×
1
2
[2 sin
7π
16
sin
16
π
]
=
1
4
[(cos
π
8
− cos
π
2
) (cos
3π
8
− cos
π
2
)]
=
4×2
1
(cos
π
2
+ cos
π
4
)
[∵ cos
1 √2 π
= = = 0]
16 2
8 √2
If e then which of the following is correct ?
π
7
− π
2
< θ < ,
2
Solution
Given,
π
− π
e 2 < θ <
2
−π π
⇒ < log θ < cos
2 2
n
+ sin
3π
n
+ sin
5π
n
…. upto n terms is equal to
Solution
n−1
sin(α+( )β)
= 0
(∵ sin (
2 nβ nβ
= . sin ) = 0)
β 2 2
sin
2
9
cos 9°+sin 9°
cos 9°−sin 9°
can be equals to
Solution
tanx+tany
= tan(45° + 9°) (∵ tan (x + y) = )
1−tanx . tany
= tan 54°
Solution
sin (x+y) a+b
=
sin (x−y) a−b
sin (x+y)+sin (x−y) (a+b)+(a−b)
⇒ =
sin (x+y)−sin (x−y) (a+b)−(a−b)
2sin x cos y 2a
⇒ =
2 cos x sin y 2b
tan x a
⇒ =
tan y b
Solution
y = sin
−1
(sin8) − tan
−1
(tan10) + cos
−1
(cos 12)
−sec
−1
(sec 9) + cot
−1
(cot 6) − cosec
−1
(cosec 7)
y = 13π − 40
a = 13 and b = −40
a − b = 53
4
, then tan A tan B tan C =
Solution
then
π π
A = − θ C = + θ
4 4
Hence tan (
π
4
− θ) tan
π
4
tan (
π
4
+ θ)
=
1−tan θ
1+tan θ
. 1.
1+tan θ
1−tan θ
= 1
4
, then R
r
= K
4
find K
Solution
A B C 7
⇒ 1 + 4 sin sin sin =
2 2 2 4
A B C 3
4 sin sin sin =
2 2 2 4
R 3
=
r 4
m
] is,
(where [.] is the greatest integer function)
Solution
2 cos
2
θ + cos θ + 1 = 2 (cos
2
θ +
cos θ
2
+
1
2
)
2 {(cos θ +
1
4
) +
7
16
}
2
5 7 32
⇒ M = 2 (( ) + ) = 2( ) = 4
4 16 16
and m = 2 ( 7
16
) =
7
Hence, [ M
m
] = [
32
7
] = 4