SAFETY DATA SHEET

LIQUID HAND SOAP

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Product name : LIQUID HAND SOAP

Other means of identification : Not applicable

Recommended use : Skin-care

Restrictions on use : Reserved for industrial and professional use.

Product dilution information : Product is sold ready to use.

Company : Ecolab Inc.

370 N. Wabasha Street
St. Paul, Minnesota USA 55102
1-800-352-5326

Emergency health : 1-800-328-0026 (US/Canada), 1-651-222-5352 (outside US)

information

Issuing date : 03/28/2016

SECTION 2. HAZARDS IDENTIFICATION

GHS Classification
Eye irritation : Category 2A

GHS label elements

Hazard pictograms :

Signal Word : Warning

Hazard Statements : Causes serious eye irritation.

Precautionary Statements : Response:

IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. If eye
irritation persists: Get medical advice/ attention.

Other hazards : None known.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Pure substance/mixture : Mixture

Chemical name CAS-No. Concentration (%)

Sodium poly(oxyethylene) dodecyl ether sulfate 68585-34-2 1-5
sodium chloride 7647-14-5 1-5
glycerin 56-81-5 1-5
Alkylamidopropylbetaines 61789-40-0 1-5
sulfuric acid, mono-c10-16-alkyl esters, sodium 68585-47-7 1-5
salts
ethanol 64-17-5 1-5

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SECTION 4. FIRST AID MEASURES

In case of eye contact : Rinse with water.

In case of skin contact : Rinse with water.

If swallowed : Rinse mouth. Get medical attention if symptoms occur.

If inhaled : Get medical attention if symptoms occur.

Protection of first-aiders : No special precautions are necessary for first aid responders.

Notes to physician : Treat symptomatically.

Most important symptoms : See Section 11 for more detailed information on health effects and
and effects, both acute and symptoms.
delayed

SECTION 5. FIRE-FIGHTING MEASURES

Suitable extinguishing media : Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.

Unsuitable extinguishing : None known.

media

Specific hazards during fire : Not flammable or combustible.

fighting

Hazardous combustion : Decomposition products may include the following materials:

products Carbon oxides
Nitrogen oxides (NOx)
Sulfur oxides
Oxides of phosphorus

Special protective equipment : Use personal protective equipment.

for fire-fighters

Specific extinguishing : Fire residues and contaminated fire extinguishing water must be
methods disposed of in accordance with local regulations. In the event of fire
and/or explosion do not breathe fumes.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, : Ensure clean-up is conducted by trained personnel only. Refer to

protective equipment and protective measures listed in sections 7 and 8.
emergency procedures

Environmental precautions : Do not allow contact with soil, surface or ground water.

Methods and materials for : Stop leak if safe to do so. Contain spillage, and then collect with non-
containment and cleaning up combustible absorbent material, (e.g. sand, earth, diatomaceous
earth, vermiculite) and place in container for disposal according to
local / national regulations (see section 13). Flush away traces with
water. For large spills, dike spilled material or otherwise contain
material to ensure runoff does not reach a waterway.

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SECTION 7. HANDLING AND STORAGE

Advice on safe handling : No special handling advice required.

Conditions for safe storage : Keep out of reach of children. Store in suitable labeled containers.

Storage temperature : 0 °C to 50 °C

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Ingredients with workplace control parameters

Ingredients CAS-No. Form of Permissible Basis

exposure concentration
glycerin 56-81-5 TWA 10 mg/m3 ACGIH
TWA 5 mg/m3 OSHA Z1
(respirable
fraction)
ethanol 64-17-5 TWA 1,000 ppm NIOSH REL
1,900 mg/m3
TWA 1,000 ppm OSHA Z1
1,900 mg/m3

Engineering measures : Good general ventilation should be sufficient to control worker

exposure to airborne contaminants.

Personal protective equipment

Eye protection : No special protective equipment required.

Hand protection : No special protective equipment required.

Skin protection : No special protective equipment required.

Respiratory protection : No personal respiratory protective equipment normally required.

Hygiene measures : No specific measures identified.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : liquid
Color : clear, pink
Odor : Perfumes, fragrances
pH : 6.0 - 8.0, 100 %
Flash point : Not applicable, Does not sustain combustion.
Odor Threshold : No data available
Melting point/freezing point : No data available
Initial boiling point and : > 100 °C
boiling range
Evaporation rate : No data available
Flammability (solid, gas) : No data available

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Upper explosion limit : No data available

Lower explosion limit : No data available
Vapor pressure : No data available
Relative vapor density : No data available
Relative density : 1.025 - 1.045
Water solubility : soluble
Solubility in other solvents : No data available
Partition coefficient: n- : No data available
octanol/water
Autoignition temperature : No data available
Thermal decomposition : No data available
Viscosity, kinematic : 774.338 mm2/s (40 °C)

Explosive properties : No data available

Oxidizing properties : The substance or mixture is not classified as oxidizing.
Molecular weight : No data available
VOC : No data available

SECTION 10. STABILITY AND REACTIVITY

Chemical stability : Stable under normal conditions.

Possibility of hazardous : No dangerous reaction known under conditions of normal use.

reactions

Conditions to avoid : None known.

Incompatible materials : None known.

Hazardous decomposition : Decomposition products may include the following materials:

products Carbon oxides
Nitrogen oxides (NOx)
Sulfur oxides
Oxides of phosphorus

SECTION 11. TOXICOLOGICAL INFORMATION

Information on likely routes of : Inhalation, Eye contact, Skin contact

exposure

Potential Health Effects

Eyes : Causes serious eye irritation.

Skin : Health injuries are not known or expected under normal use.

Ingestion : Health injuries are not known or expected under normal use.

Inhalation : Health injuries are not known or expected under normal use.

Chronic Exposure : Health injuries are not known or expected under normal use.

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Experience with human exposure

Eye contact : Redness, Pain, Irritation

Skin contact : No symptoms known or expected.

Ingestion : No symptoms known or expected.

Inhalation : No symptoms known or expected.

Toxicity

Product
Acute oral toxicity : Acute toxicity estimate : > 5,000 mg/kg
Acute inhalation toxicity : No data available
Acute dermal toxicity : Acute toxicity estimate : > 5,000 mg/kg
Skin corrosion/irritation : No data available
Serious eye damage/eye : No data available
irritation
Respiratory or skin : No data available
sensitization
Carcinogenicity : No data available
Reproductive effects : No data available
Germ cell mutagenicity : No data available
Teratogenicity : No data available
STOT-single exposure : No data available
STOT-repeated exposure : No data available
Aspiration toxicity : No data available
Ingredients
Acute inhalation toxicity : ethanol
4 h LC50 Rat: 117 mg/l

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity
Environmental Effects : Harmful to aquatic life.

Product
Toxicity to fish : No data available
Toxicity to daphnia and other : No data available
aquatic invertebrates
Toxicity to algae : No data available
Ingredients
Toxicity to fish : Sodium poly(oxyethylene) dodecyl ether sulfate
96 h LC50 Fish: 28 mg/l

sodium chloride
96 h LC50 Fish: 5,840 mg/l

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glycerin
96 h LC50 Fish: 855 mg/l

Alkylamidopropylbetaines
96 h LC50 Fish: 2 mg/l

ethanol
96 h LC50 Pimephales promelas (fathead minnow): > 100 mg/l

Ingredients
Toxicity to daphnia and other : sulfuric acid, mono-c10-16-alkyl esters, sodium salts
aquatic invertebrates 48 h EC50 Daphnia: 1.37 mg/l

Persistence and degradability

No data available

Bioaccumulative potential
No data available

Mobility in soil
No data available

Other adverse effects

No data available

SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods : Do not contaminate ponds, waterways or ditches with chemical or

used container. Where possible recycling is preferred to disposal or
incineration. If recycling is not practicable, dispose of in compliance
with local regulations. Dispose of wastes in an approved waste
disposal facility.

Disposal considerations : Dispose of as unused product. Empty containers should be taken to

an approved waste handling site for recycling or disposal. Do not re-
use empty containers. Dispose of in accordance with local, state, and
federal regulations.

SECTION 14. TRANSPORT INFORMATION

The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are
in compliance with the selected mode of transport.

Land transport (DOT)

Not dangerous goods

Sea transport (IMDG/IMO)

Not dangerous goods

SECTION 15. REGULATORY INFORMATION

EPCRA - Emergency Planning and Community Right-to-Know

CERCLA Reportable Quantity

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This material does not contain any components with a CERCLA RQ.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.

SARA 311/312 Hazards : Acute Health Hazard

SARA 302 : No chemicals in this material are subject to the reporting requirements
of SARA Title III, Section 302.

SARA 313 : This material does not contain any chemical components with known
CAS numbers that exceed the threshold (De Minimis) reporting levels
established by SARA Title III, Section 313.

California Prop 65
This product does not contain any chemicals known to the State of California to cause cancer, birth, or
any other reproductive defects.

The ingredients of this product are reported in the following inventories:

1907/2006 (EU) :
not determined

Switzerland. New notified substances and declared preparations :

not determined

United States TSCA Inventory :

On TSCA Inventory

Canadian Domestic Substances List (DSL) :

All components of this product are on the Canadian DSL

Australia Inventory of Chemical Substances (AICS) :

On the inventory, or in compliance with the inventory

New Zealand. Inventory of Chemical Substances :

On the inventory, or in compliance with the inventory

Japan. ENCS - Existing and New Chemical Substances Inventory :

not determined

Japan. ISHL - Inventory of Chemical Substances (METI) :

not determined

Korea. Korean Existing Chemicals Inventory (KECI) :

On the inventory, or in compliance with the inventory

Philippines Inventory of Chemicals and Chemical Substances (PICCS) :

On the inventory, or in compliance with the inventory

China. Inventory of Existing Chemical Substances in China (IECSC) :

On the inventory, or in compliance with the inventory

SECTION 16. OTHER INFORMATION

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NFPA: HMIS III:

Flammability

HEALTH 2
0

Instability
Health

2 0 FLAMMABILITY 0
PHYSICAL HAZARD 0
0 = not significant, 1 =Slight,
Special hazard. 2 = Moderate, 3 = High
4 = Extreme, * = Chronic

Issuing date : 03/28/2016

Version : 1.1
Prepared by : Regulatory Affairs

REVISED INFORMATION: Significant changes to regulatory or health information for this revision is
indicated by a bar in the left-hand margin of the SDS.

The information provided in this Material Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to
be considered a warranty or quality specification. The information relates only to the specific material
designated and may not be valid for such material used in combination with any other materials or in
any process, unless specified in the text.

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