Version: 1.

0
Revision Date: 10/30/2019

SAFETY DATA SHEET

1. Identification

Product identifier: TRIM-TEX 847 SPRAY ADHESIVE

Other means of identification

SDS number: RE1000037489

Recommended restrictions
Product Use: Adhesive
Restrictions on use: Not known.

Manufacturer/Importer/Distributor Information

Manufacturer

Company Name: TRIM-TEX INC

Address: 3700 WEST PRATT AVENUE
LINCOLNWOOD,IL 60712
Telephone: (847) 679-3000
Fax:

Emergency telephone number: 1-866-836-8855

2. Hazard(s) identification

Hazard Classification
Physical Hazards
Flammable aerosol Category 1
Health Hazards
Serious Eye Damage/Eye Irritation Category 2A
Skin sensitizer Category 1
Specific Target Organ Toxicity - Category 31.
Single Exposure

Target Organs
1. Narcotic effect.

Environmental Hazards
Acute hazards to the aquatic Category 3
environment

Label Elements

Hazard Symbol:

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Signal Word: Danger

Hazard Statement: Extremely flammable aerosol.

Causes serious eye irritation.
May cause an allergic skin reaction.
May cause drowsiness or dizziness.
Harmful to aquatic life.

Precautionary
Statements

Prevention: Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking. Do not spray on an open flame or other ignition
source. Do not pierce or burn, even after use. Wash thoroughly after
handling. Wear protective gloves/protective clothing/eye protection/face
protection. Avoid breathing dust/fume/gas/mist/vapors/spray. Contaminated
work clothing should not be allowed out of the workplace. Use only outdoors
or in a well-ventilated area. Avoid release to the environment.

Response: IF INHALED: Remove person to fresh air and keep comfortable for
breathing. IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. If eye
irritation persists: Get medical advice/attention. IF ON SKIN: Wash with
plenty of water If skin irritation or rash occurs: Get medical advice/attention.
Call a POISON CENTER/doctor if you feel unwell. Specific treatment (see
on this label). Wash contaminated clothing before reuse.

Storage: Protect from sunlight. Do not expose to temperatures exceeding

50°C/122°F. Store in a well-ventilated place. Keep container tightly closed.
Store locked up.

Disposal: Dispose of contents/container to an appropriate treatment and disposal

facility in accordance with applicable laws and regulations, and product
characteristics at time of disposal.

Hazard(s) not otherwise None.

classified (HNOC):

3. Composition/information on ingredients

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Mixtures

Chemical Identity CAS number Content in percent (%)*

2-Propanone 67-64-1 20 - <50%

Propane 74-98-6 10 - <20%
Acetic acid, methyl ester 79-20-9 5 - <10%
Methane, 1,1'-oxybis- 115-10-6 5 - 10%
Naphtha (petroleum), 64742-49-0 5 - <10%
hydrotreated light
Benzene, 1-chloro-4- 98-56-6 1 - <5%
(trifluoromethyl)-
Heptane 142-82-5 1 - <5%
Maleic Anhydride Modified 841251-34-1 0.1 - <1%
Liquid Polyisoprene
Cyclohexane, methyl- 108-87-2 0.1 - <1%
Methanol 67-56-1 0.1 - <1%
* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.

4. First-aid measures

Ingestion: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth.

Inhalation: Move to fresh air.

Skin Contact: If skin irritation occurs: Get medical advice/attention. Destroy or thoroughly
clean contaminated shoes. Immediately remove contaminated clothing and
shoes and wash skin with soap and plenty of water. If skin irritation or an
allergic skin reaction develops, get medical attention.

Eye contact: Immediately flush with plenty of water for at least 15 minutes. If easy to do,
remove contact lenses. Get medical attention.

Most important symptoms/effects, acute and delayed

Symptoms: No data available.

Hazards: No data available.

Indication of immediate medical attention and special treatment needed

Treatment: No data available.

5. Fire-fighting measures

General Fire Hazards: Use water spray to keep fire-exposed containers cool. Fight fire from a
protected location. Move containers from fire area if you can do so without
risk.

Suitable (and unsuitable) extinguishing media

Suitable extinguishing Use fire-extinguishing media appropriate for surrounding materials.

media:

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Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media:

Specific hazards arising from Vapors may travel considerable distance to a source of ignition and flash
the chemical: back.

Special protective equipment and precautions for firefighters

Special fire fighting No data available.

procedures:

Special protective equipment Firefighters must use standard protective equipment including flame
for fire-fighters: retardant coat, helmet with face shield, gloves, rubber boots, and in
enclosed spaces, SCBA.

6. Accidental release measures

Personal precautions, Ventilate closed spaces before entering them. ELIMINATE all ignition
protective equipment and sources (no smoking, flares, sparks or flames in immediate area). Keep
emergency procedures: upwind. See Section 8 of the SDS for Personal Protective Equipment. Do
not touch damaged containers or spilled material unless wearing
appropriate protective clothing. Keep unauthorized personnel away.

Methods and material for Absorb spill with vermiculite or other inert material, then place in a container
containment and cleaning for chemical waste.
up:

Notification Procedures: Dike for later disposal. Prevent entry into waterways, sewer, basements or
confined areas. Stop the flow of material, if this is without risk. ELIMINATE
all ignition sources (no smoking, flares, sparks or flames in immediate
area). Stop leak if you can do so without risk.

Environmental Precautions: Do not contaminate water sources or sewer. Prevent further leakage or
spillage if safe to do so. Avoid release to the environment.

7. Handling and storage

Precautions for safe handling: Avoid contact with eyes. Wash hands thoroughly after handling. Keep away
from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking. Do not spray on an open flame or other ignition source. Do not
pierce or burn, even after use. Avoid contact with eyes, skin, and clothing.

Conditions for safe storage, Pressurized container: protect from sunlight and do not expose to
including any temperatures exceeding 50°C. Do not pierce or burn, even after use.
incompatibilities: Aerosol Level 2

8. Exposure controls/personal protection

Control Parameters
Occupational Exposure Limits
Chemical Identity Type Exposure Limit Values Source

2-Propanone STEL 1,000 ppm 2,400 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000)
(1989)
PEL 1,000 ppm 2,400 mg/m3 US. OSHA Table Z-1 Limits for Air
Contaminants (29 CFR 1910.1000) (02 2006)
TWA 250 ppm US. ACGIH Threshold Limit Values (03 2015)

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TWA 750 ppm 1,800 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000)
(1989)
STEL 500 ppm US. ACGIH Threshold Limit Values (03 2015)
REL 250 ppm 590 mg/m3 US. NIOSH: Pocket Guide to Chemical
Hazards (2005)
Propane REL 1,000 ppm 1,800 mg/m3 US. NIOSH: Pocket Guide to Chemical
Hazards (2005)
PEL 1,000 ppm 1,800 mg/m3 US. OSHA Table Z-1 Limits for Air
Contaminants (29 CFR 1910.1000) (02 2006)
TWA 1,000 ppm 1,800 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000)
(1989)
Acetic acid, methyl ester REL 200 ppm 610 mg/m3 US. NIOSH: Pocket Guide to Chemical
Hazards (2005)
STEL 250 ppm 760 mg/m3 US. NIOSH: Pocket Guide to Chemical
Hazards (2005)
PEL 200 ppm 610 mg/m3 US. OSHA Table Z-1 Limits for Air
Contaminants (29 CFR 1910.1000) (02 2006)
STEL 250 ppm US. ACGIH Threshold Limit Values (2008)
TWA 200 ppm 610 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000)
(1989)
STEL 250 ppm 760 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000)
(1989)
TWA 200 ppm US. ACGIH Threshold Limit Values (2008)
Naphtha (petroleum), PEL 100 ppm 400 mg/m3 US. OSHA Table Z-1 Limits for Air
hydrotreated light Contaminants (29 CFR 1910.1000) (03 2016)
REL 100 ppm 400 mg/m3 US. NIOSH: Pocket Guide to Chemical
Hazards (2010)
TWA 100 ppm 400 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000)
(1989)
Heptane TWA 400 ppm 1,600 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000)
(1989)
REL 85 ppm 350 mg/m3 US. NIOSH: Pocket Guide to Chemical
Hazards (2005)
PEL 500 ppm 2,000 mg/m3 US. OSHA Table Z-1 Limits for Air
Contaminants (29 CFR 1910.1000) (02 2006)
STEL 500 ppm 2,000 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000)
(1989)
TWA 400 ppm US. ACGIH Threshold Limit Values (02 2012)
STEL 500 ppm US. ACGIH Threshold Limit Values (02 2012)
Ceil_Time 440 ppm 1,800 mg/m3 US. NIOSH: Pocket Guide to Chemical
Hazards (2005)
Cyclohexane, methyl- PEL 500 ppm 2,000 mg/m3 US. OSHA Table Z-1 Limits for Air
Contaminants (29 CFR 1910.1000) (02 2006)
TWA 400 ppm 1,600 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000)
(1989)
TWA 400 ppm US. ACGIH Threshold Limit Values (2008)
REL 400 ppm 1,600 mg/m3 US. NIOSH: Pocket Guide to Chemical
Hazards (2005)
Methanol REL 200 ppm 260 mg/m3 US. NIOSH: Pocket Guide to Chemical
Hazards (2005)
PEL 200 ppm 260 mg/m3 US. OSHA Table Z-1 Limits for Air
Contaminants (29 CFR 1910.1000) (02 2006)
TWA 200 ppm 260 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000)
(1989)
STEL 250 ppm 325 mg/m3 US. NIOSH: Pocket Guide to Chemical
Hazards (2005)
TWA 200 ppm US. ACGIH Threshold Limit Values (2008)
STEL 250 ppm US. ACGIH Threshold Limit Values (2008)
STEL 250 ppm 325 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000)
(1989)
Hexane TWA 50 ppm 180 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000)
(1989)
PEL 500 ppm 1,800 mg/m3 US. OSHA Table Z-1 Limits for Air
Contaminants (29 CFR 1910.1000) (02 2006)
REL 50 ppm 180 mg/m3 US. NIOSH: Pocket Guide to Chemical
Hazards (2005)
TWA 50 ppm US. ACGIH Threshold Limit Values (2008)
Cyclohexane TWA 100 ppm US. ACGIH Threshold Limit Values (2008)

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TWA 300 ppm 1,050 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000)
(1989)
REL 300 ppm 1,050 mg/m3 US. NIOSH: Pocket Guide to Chemical
Hazards (2005)
PEL 300 ppm 1,050 mg/m3 US. OSHA Table Z-1 Limits for Air
Contaminants (29 CFR 1910.1000) (02 2006)
Benzene, methyl- STEL 150 ppm 560 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000)
(1989)
REL 100 ppm 375 mg/m3 US. NIOSH: Pocket Guide to Chemical
Hazards (2005)
TWA 100 ppm 375 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000)
(1989)
Ceiling 300 ppm US. OSHA Table Z-2 (29 CFR 1910.1000) (02
2006)
TWA 20 ppm US. ACGIH Threshold Limit Values (2008)
TWA 200 ppm US. OSHA Table Z-2 (29 CFR 1910.1000) (02
2006)
MAX. 500 ppm US. OSHA Table Z-2 (29 CFR 1910.1000) (02
CONC 2006)
STEL 150 ppm 560 mg/m3 US. NIOSH: Pocket Guide to Chemical
Hazards (2005)
Benzene, ethyl- STEL 125 ppm 545 mg/m3 US. NIOSH: Pocket Guide to Chemical
Hazards (2005)
REL 100 ppm 435 mg/m3 US. NIOSH: Pocket Guide to Chemical
Hazards (2005)
PEL 100 ppm 435 mg/m3 US. OSHA Table Z-1 Limits for Air
Contaminants (29 CFR 1910.1000) (02 2006)
STEL 125 ppm 545 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000)
(1989)
TWA 100 ppm 435 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000)
(1989)
TWA 20 ppm US. ACGIH Threshold Limit Values (12 2010)
Phenol TWA 5 ppm US. ACGIH Threshold Limit Values (2008)
REL 5 ppm 19 mg/m3 US. NIOSH: Pocket Guide to Chemical
Hazards (2005)
Ceil_Time 15.6 ppm 60 mg/m3 US. NIOSH: Pocket Guide to Chemical
Hazards (2005)
PEL 5 ppm 19 mg/m3 US. OSHA Table Z-1 Limits for Air
Contaminants (29 CFR 1910.1000) (02 2006)
TWA 5 ppm 19 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000)
(1989)
Benzene, dimethyl- STEL 150 ppm 655 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000)
(1989)
TWA 100 ppm 435 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000)
(1989)
TWA 100 ppm US. ACGIH Threshold Limit Values (2008)
REL 100 ppm 435 mg/m3 US. NIOSH: Pocket Guide to Chemical
Hazards (2016)
PEL 100 ppm 435 mg/m3 US. OSHA Table Z-1 Limits for Air
Contaminants (29 CFR 1910.1000) (02 2006)
STEL 150 ppm US. ACGIH Threshold Limit Values (2008)
STEL 150 ppm 655 mg/m3 US. NIOSH: Pocket Guide to Chemical
Hazards (2016)
Benzene, ethenyl- TWA 20 ppm US. ACGIH Threshold Limit Values (2008)
STEL 40 ppm US. ACGIH Threshold Limit Values (2008)
REL 50 ppm 215 mg/m3 US. NIOSH: Pocket Guide to Chemical
Hazards (2005)
STEL 100 ppm 425 mg/m3 US. NIOSH: Pocket Guide to Chemical
Hazards (2005)
TWA 50 ppm 215 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000)
(1989)
STEL 100 ppm 425 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000)
(1989)
TWA 100 ppm US. OSHA Table Z-2 (29 CFR 1910.1000) (02
2006)
Ceiling 200 ppm US. OSHA Table Z-2 (29 CFR 1910.1000) (02
2006)
MAX. 600 ppm US. OSHA Table Z-2 (29 CFR 1910.1000) (02
CONC 2006)

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TWA 2 ppm US. ACGIH Notice of Intended Changes (NIC)

to Threshold Limit Values (03 2018)
Benzene REL 0.1 ppm US. NIOSH: Pocket Guide to Chemical
Hazards (2005)
TWA 1 ppm US. OSHA Table Z-1-A (29 CFR 1910.1000)
(1989)
Ceiling 25 ppm US. OSHA Table Z-2 (29 CFR 1910.1000) (02
2006)
TWA 0.5 ppm US. ACGIH Threshold Limit Values (2008)
STEL 2.5 ppm US. ACGIH Threshold Limit Values (2008)
STEL 5 ppm US. OSHA Specifically Regulated Substances
(29 CFR 1910.1001-1053) (02 2006)
OSHA_AC 0.5 ppm US. OSHA Specifically Regulated Substances
T (29 CFR 1910.1001-1053) (02 2006)
TWA 10 ppm US. OSHA Table Z-2 (29 CFR 1910.1000) (02
2006)
MAX. 50 ppm US. OSHA Table Z-2 (29 CFR 1910.1000) (02
CONC 2006)
STEL 5 ppm US. OSHA Table Z-1-A (29 CFR 1910.1000)
(1989)
TWA 1 ppm US. OSHA Specifically Regulated Substances
(29 CFR 1910.1001-1053) (02 2006)
STEL 1 ppm US. NIOSH: Pocket Guide to Chemical
Hazards (2005)

Biological Limit Values

Chemical Identity Exposure Limit Values Source
2-Propanone (acetone: 25 mg/l (Urine) ACGIH BEL (03 2015)
Sampling time: End of shift.)
Methanol (methanol: 15 mg/l (Urine) ACGIH BEL (03 2013)
Sampling time: End of shift.)
Hexane (2,5-Hexanedion, 0.5 mg/l (Urine) ACGIH BEL (03 2018)
without hydrolysis: Sampling
time: End of shift.)
Benzene, methyl- (toluene: 0.03 mg/l (Urine) ACGIH BEL (03 2013)
Sampling time: End of shift.)
Benzene, methyl- (o-Cresol, 0.3 mg/g (Creatinine in urine) ACGIH BEL (03 2013)
with hydrolysis: Sampling
time: End of shift.)
Benzene, methyl- (toluene: 0.02 mg/l (Blood) ACGIH BEL (03 2013)
Sampling time: Prior to last
shift of work week.)
Benzene, ethyl- (Sum of 0.15 g/g (Creatinine in urine) ACGIH BEL (02 2014)
mandelic acid and
phenylglyoxylic acid:
Sampling time: End of shift.)
Phenol (Phenol with 250 mg/g (Creatinine in urine) ACGIH BEL (03 2013)
hydrolysis: Sampling time:
End of shift.)
Benzene, dimethyl- 1.5 g/g (Creatinine in urine) ACGIH BEL (03 2013)
(Methylhippuric acids:
Sampling time: End of shift.)
Benzene, ethenyl- (Mandelic 400 mg/g (Creatinine in urine) ACGIH BEL (03 2013)
acid plus phenylglyoxylic
acid: Sampling time: End of
shift.)
Benzene, ethenyl- (styrene: 40 µg/l (Urine) ACGIH BEL (03 2015)
Sampling time: End of shift.)
Benzene (S- 25 µg/g (Creatinine in urine) ACGIH BEL (03 2013)
Phenylmercapturic acid:
Sampling time: End of shift.)
Benzene (t,t-Muconic acid: 500 µg/g (Creatinine in urine) ACGIH BEL (03 2013)
Sampling time: End of shift.)

Appropriate Engineering No data available.

Controls

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Individual protection measures, such as personal protective equipment

General information: Provide easy access to water supply and eye wash facilities. Good general
ventilation (typically 10 air changes per hour) should be used. Ventilation
rates should be matched to conditions. If applicable, use process
enclosures, local exhaust ventilation, or other engineering controls to
maintain airborne levels below recommended exposure limits. If exposure
limits have not been established, maintain airborne levels to an acceptable
level. If exposure limits have not been established, maintain airborne levels
to an acceptable level.

Eye/face protection: Wear safety glasses with side shields (or goggles).

Skin Protection
Hand Protection: No data available.

Other: Wear suitable protective clothing. Wear chemical-resistant gloves, footwear,

and protective clothing appropriate for the risk of exposure. Contact health
and safety professional or manufacturer for specific information.

Respiratory Protection: In case of inadequate ventilation use suitable respirator. Seek advice from
local supervisor.

Hygiene measures: Observe good industrial hygiene practices. Avoid contact with eyes. When
using do not smoke. Contaminated work clothing should not be allowed out
of the workplace. Avoid contact with skin.

9. Physical and chemical properties

Appearance
Physical state: liquid
Form: Spray Aerosol
Color: No data available.
Odor: No data available.
Odor threshold: No data available.
pH: No data available.
Melting point/freezing point: No data available.
Initial boiling point and boiling range: No data available.
Flash Point: Estimated -104.4 °C
Evaporation rate: No data available.
Flammability (solid, gas): No data available.
Upper/lower limit on flammability or explosive limits
Flammability limit - upper (%): Estimated 12.1 %(V)
Flammability limit - lower (%): Estimated 2.4 %(V)
Explosive limit - upper (%): No data available.
Explosive limit - lower (%): No data available.
Vapor pressure: Estimated 4,137 - 5,516 hPa (20 °C)

Vapor density: No data available.

Density: Estimated 1.047 g/cm3
Relative density: No data available.
Solubility(ies)

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Solubility in water: No data available.

Solubility (other): No data available.
Partition coefficient (n-octanol/water): No data available.

Auto-ignition temperature: No data available.

Decomposition temperature: No data available.
Viscosity: No data available.

Other information
Minimum ignition temperature: Estimated 403.41 °C

10. Stability and reactivity

Reactivity: No data available.

Chemical Stability: Material is stable under normal conditions.

Possibility of hazardous No data available.

reactions:

Conditions to avoid: Avoid heat or contamination.

Incompatible Materials: No data available.

Hazardous Decomposition No data available.

Products:

11. Toxicological information

Information on likely routes of exposure

Inhalation: No data available.

Skin Contact: No data available.

Eye contact: No data available.

Ingestion: No data available.

Symptoms related to the physical, chemical and toxicological characteristics

Inhalation: No data available.

Skin Contact: No data available.

Eye contact: No data available.

Ingestion: No data available.

Information on toxicological effects

Acute toxicity (list all possible routes of exposure)

Oral
Product: Not classified for acute toxicity based on available data.
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Specified substance(s):
2-Propanone LD 50 (Rat): 5,800 mg/kg

Acetic acid, methyl ester LD 50 (Rat): 6,482 mg/kg

Naphtha (petroleum), LD 50 (Rat): > 5,000 mg/kg

hydrotreated light

Benzene, 1-chloro-4- LD 50 (Rat): > 2,000 mg/kg

(trifluoromethyl)-

Heptane LD 50 (Rat): > 5,000 mg/kg

Maleic Anhydride LD 50: > 2,000 mg/kg

Modified Liquid
Polyisoprene

Cyclohexane, methyl- LD Lo (Rabbit): 4,000 - 4,500 mg/kg

Methanol ATE: 100 mg/kg

LD 50 (Rat): > 1,187 - 2,769 mg/kg

Dermal
Product: ATEmix: 413,227.64 mg/kg

Inhalation
Product: ATEmix: 453.14 mg/l

Repeated dose toxicity

Product: No data available.

Specified substance(s):
2-Propanone NOAEL (Rat(Male), Oral, 13 Weeks): 10,000 ppm(m) Oral Experimental
result, Key study
Propane NOAEL (Rat(Female, Male), Inhalation, >= 28 d): 4,000 ppm(m) Inhalation
Experimental result, Key study
LOAEL (Rat(Female, Male), Inhalation, >= 28 d): 12,000 ppm(m) Inhalation
Experimental result, Key study
Acetic acid, methyl ester NOAEL (Rat(Female, Male), Inhalation, 28 d): 350 ppm(m) Inhalation
Experimental result, Key study
LOAEL (Rat(Female, Male), Inhalation, 28 d): 2,000 ppm(m) Inhalation
Experimental result, Key study
Methane, 1,1'-oxybis- NOAEL (Hamster(Female, Male), Inhalation, 28 d): 10,000 ppm(m)
Inhalation Experimental result, Supporting study
NOAEL (Rat(Female, Male), Inhalation, 2 yr): 2.5 %(m) Inhalation
Experimental result, Key study
NOAEL (Rat(Female, Male), Inhalation, 13 Weeks): 10,000 ppm(m)
Inhalation Experimental result, Supporting study
NOAEL (Rat(Female, Male), Inhalation, 4 Weeks): >= 10,000 ppm(m)
Inhalation Experimental result, Supporting study

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NOAEL (Hamster(Female, Male), Inhalation, 90 d): 10,000 ppm(m)

Inhalation Experimental result, Supporting study
Naphtha (petroleum), LOAEL (Rat(Female, Male), Oral, 13 Weeks): 1,250 mg/kg Oral Read-
hydrotreated light across based on grouping of substances (category approach), Key study
NOAEL (Rat(Female, Male), Dermal, 28 d): > 375 mg/kg Dermal
Experimental result, Supporting study
NOAEL (Rat(Female, Male), Inhalation): 10,000 mg/m3 Inhalation
Experimental result, Key study
Benzene, 1-chloro-4- NOAEL (Rat(Male), Oral, 90 - 92 d): 40 mg/kg Oral Experimental result, Key
(trifluoromethyl)- study
NOAEL (Rat(Male), Inhalation): 5.5 mg/m3 Inhalation Experimental result,
Key study
Heptane NOAEL (Rat(Male), Inhalation): 12,470 mg/m3 Inhalation Experimental
result, Key study
Cyclohexane, methyl- LOAEL (Rat(Female, Male), Oral, 28 d): 1,000 mg/kg Oral Experimental
result, Key study
NOAEL (Rat(Female, Male), Oral, 28 d): 250 mg/kg Oral Experimental
result, Key study
NOAEL (Rat(Female, Male), Inhalation): 1,600 mg/m3 Inhalation
Experimental result, Key study
Methanol LOAEL (Rat(Male), Inhalation, 1 - 6 Weeks): 13.3 mg/l Inhalation
Experimental result, Supporting study

Skin Corrosion/Irritation
Product: No data available.

Specified substance(s):
2-Propanone in vivo (Rabbit): Not irritant Experimental result, Supporting study

Acetic acid, methyl in vivo (Rabbit): Not irritant Experimental result, Key study
ester

Benzene, 1-chloro-4- in vivo (Rabbit): Not irritant (unspecified classification) Experimental result,
(trifluoromethyl)- Key study

Heptane in vivo (Rabbit): Irritating Read-across based on grouping of substances

(category approach), Key study

Methanol in vivo (Rabbit): Not irritant Experimental result, Key study

Serious Eye Damage/Eye Irritation

Product: No data available.
Specified substance(s):

2-Propanone Irritating.
Rabbit, 24 hrs: Minimum grade of severe eye irritant

Acetic acid, methyl Rabbit: Irritating

ester

Naphtha (petroleum), Rabbit, 24 - 72 hrs: Not irritating

hydrotreated light

Heptane Rabbit, 24 - 72 hrs: Not irritating

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Cyclohexane, methyl- Rabbit, 0.5 - 168 hrs: Not irritating

Respiratory or Skin Sensitization

Product: No data available.

Specified substance(s):
2-Propanone Skin sensitization:, in vivo (Guinea pig): Non sensitising
Naphtha (petroleum), Skin sensitization:, in vivo (Guinea pig): Non sensitising
hydrotreated light
Heptane Skin sensitization:, in vivo (Guinea pig): Non sensitising
Cyclohexane, methyl- Skin sensitization:, in vivo (Guinea pig): Non sensitising
Methanol Skin sensitization:, in vivo (Guinea pig): Non sensitising

Carcinogenicity
Product: No data available.
Specified substance(s):
Cyclohexane, methyl- May cause cancer.

IARC Monographs on the Evaluation of Carcinogenic Risks to Humans:

No carcinogenic components identified

US. National Toxicology Program (NTP) Report on Carcinogens:

No carcinogenic components identified

US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050):

No carcinogenic components identified

Germ Cell Mutagenicity

In vitro
Product: No data available.

In vivo
Product: No data available.

Reproductive toxicity
Product: No data available.

Specific Target Organ Toxicity - Single Exposure

Product: Inhalation - vapor: Narcotic effect. - Category 3 with narcotic effects.

Specific Target Organ Toxicity - Repeated Exposure

Product: No data available.
Specified substance(s):
Cyclohexane, methyl- Category 1

Target Organs
Specific Target Organ Toxicity - Single Exposure: Narcotic effect.

Aspiration Hazard
Product: No data available.

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Specified substance(s):
Naphtha (petroleum), May be fatal if swallowed and enters airways.
hydrotreated light
Heptane May be fatal if swallowed and enters airways.
Cyclohexane, methyl- May be fatal if swallowed and enters airways.

Other effects: No data available.

12. Ecological information

Ecotoxicity:

Acute hazards to the aquatic environment:

Fish
Product: No data available.

Specified substance(s):
2-Propanone LC 50 (Oncorhynchus mykiss, 96 h): 5,540 mg/l Experimental result, Key
study

Propane LC 50 (Various, 96 h): 147.54 mg/l QSAR QSAR, Key study

Acetic acid, methyl ester LC 50 (Fathead minnow (Pimephales promelas), 96 h): 295 - 348 mg/l
Mortality
LC 50 (Danio rerio, 48 h): 250 - 350 mg/l Experimental result, Key study

Methane, 1,1'-oxybis- LC 50 (Poecilia reticulata, 96 h): > 4.1 g/l Experimental result, Key study
NOAEL (Poecilia reticulata, 96 h): >= 4.1 g/l Experimental result, Key study
LC 50 (Various, 96 h): 1,783.04 mg/l QSAR QSAR, Supporting study

Naphtha (petroleum), LC 50 (96 h): 8.41 mg/l Experimental result, Key study
hydrotreated light

Benzene, 1-chloro-4- NOAEL (96 h): 2.2 mg/l Experimental result, Key study
(trifluoromethyl)- LC 50 (96 h): 3 mg/l Experimental result, Key study

Heptane LC 50 (Mozambique tilapia (Tilapia mossambica), 96 h): 375 mg/l Mortality

Cyclohexane, methyl- LC 50 (Oryzias latipes, 96 h): 2.07 mg/l Experimental result, Key study

Methanol EC 50 (Lepomis macrochirus, 96 h): 12,700 mg/l Experimental result, Key

study

Aquatic Invertebrates
Product: No data available.

Specified substance(s):
2-Propanone LC 50 (Daphnia pulex, 48 h): 8,800 mg/l Experimental result, Key study

Acetic acid, methyl ester EC 50 (Daphnia magna, 48 h): 1,026.7 mg/l Experimental result, Key study

Methane, 1,1'-oxybis- EC 50 (Daphnia magna, 48 h): > 4.4 g/l Experimental result, Key study
NOAEL (Daphnia magna, 48 h): >= 4.4 g/l Experimental result, Key study
LC 50 (Daphnia sp., 48 h): 755.549 mg/l QSAR QSAR, Supporting study
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Naphtha (petroleum), EC 50 (Daphnia magna, 48 h): 4.5 mg/l Experimental result, Key study
hydrotreated light

Benzene, 1-chloro-4- NOAEL (Daphnia magna, 48 h): 9.15 mg/l Experimental result, Key study
(trifluoromethyl)- EC 50 (Daphnia magna, 48 h): 18.84 mg/l Experimental result, Key study

Heptane EC 50 (Daphnia magna, 48 h): 1.5 mg/l Experimental result, Key study

Cyclohexane, methyl- EC 50 (Daphnia magna, 48 h): 0.326 mg/l Experimental result, Key study
ED 0 (Daphnia magna, 48 h): 0.037 mg/l Experimental result, Key study

Methanol EC 50 (Daphnia magna, 96 h): 18,260 mg/l Experimental result, Key study

Chronic hazards to the aquatic environment:

Fish
Product: No data available.

Specified substance(s):
Naphtha (petroleum), EC 50 (Daphnia magna): 10 mg/l Other, Key study
hydrotreated light NOAEL (Daphnia magna): 2.6 mg/l Other, Key study

Heptane NOAEL (Oncorhynchus mykiss): 1.284 mg/l QSAR QSAR, Key study

Methanol EC 50 (Oryzias latipes): 9,164 mg/l Experimental result, Supporting study

Aquatic Invertebrates
Product: No data available.

Specified substance(s):
2-Propanone LOAEL (Daphnia magna): 2,212 mg/l Experimental result, Key study
NOAEL (Daphnia magna): 2,212 mg/l Experimental result, Key study

Naphtha (petroleum), EC 50 (Daphnia magna): 10 mg/l Experimental result, Key study

hydrotreated light NOAEL (Daphnia magna): 2.6 mg/l Experimental result, Key study

Heptane NOAEL (Daphnia magna): 0.17 mg/l Read-across based on grouping of

substances (category approach), Key study
EC 50 (Daphnia magna): 0.23 mg/l Read-across based on grouping of
substances (category approach), Key study

Methanol NOAEL (Daphnia magna): 122 mg/l Experimental result, Supporting study

Toxicity to Aquatic Plants

Product: No data available.

Persistence and Degradability

Biodegradation
Product: No data available.

Specified substance(s):
2-Propanone 90.9 % (28 d) Detected in water. Experimental result, Key study

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Propane 100 % (385.5 h) Detected in water. Experimental result, Key study

50 % (3.19 d) Detected in water. QSAR, Weight of Evidence study

Acetic acid, methyl ester 70 % Detected in water. Experimental result, Key study

Methane, 1,1'-oxybis- 5 % (28 d) Detected in water. Experimental result, Key study

7 % (4 Weeks) Detected in water. Experimental result, Supporting study
> 0 % (4 Weeks) Detected in water. Experimental result, Supporting study
8 % (4 Weeks) Detected in water. Experimental result, Supporting study

Naphtha (petroleum), 90.35 % (28 d) Detected in water. Experimental result, Supporting study
hydrotreated light

Benzene, 1-chloro-4- 3 % (28 d) Detected in water. Experimental result, Key study

(trifluoromethyl)-

Heptane 70 % Detected in water. Experimental result, Key study

Cyclohexane, methyl- > 0 % (28 d) Detected in water. Experimental result, Weight of Evidence
study
> 0 % (28 d) Detected in water. Experimental result, Weight of Evidence
study

Methanol 97 % Detected in water. Experimental result, Key study

BOD/COD Ratio
Product: No data available.

Bioaccumulative potential
Bioconcentration Factor (BCF)
Product: No data available.

Specified substance(s):
2-Propanone Haddock, adult, Bioconcentration Factor (BCF): 0.69 Aquatic sediment
Experimental result, Not specified

Naphtha (petroleum), Bioconcentration Factor (BCF): 10 - 2,500 Aquatic sediment Estimated by

hydrotreated light calculation, Key study

Benzene, 1-chloro-4- Bioconcentration Factor (BCF): 9 Aquatic sediment Estimated by calculation,

(trifluoromethyl)- Key study

Heptane Bioconcentration Factor (BCF): 552 Aquatic sediment Estimated by

calculation, Key study

Cyclohexane, methyl- Cyprinus carpio, Bioconcentration Factor (BCF): > 95 - < 321 Aquatic
sediment Experimental result, Key study

Methanol Leuciscus idus, Bioconcentration Factor (BCF): < 10 Aquatic sediment

Experimental result, Supporting study

Partition Coefficient n-octanol / water (log Kow)

Product: No data available.

Specified substance(s):

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Naphtha (petroleum), Log Kow: > 2.4 - < 5.7 23 °C Yes Experimental result, Key study
hydrotreated light Log Kow: 2.2 - 5.2 23 °C Yes Experimental result, Key study
Log Kow: 2.2 - 6.1 23 °C Yes Experimental result, Key study

Mobility in soil: No data available.

Known or predicted distribution to environmental compartments

2-Propanone No data available.
Propane No data available.
Acetic acid, methyl ester No data available.
Methane, 1,1'-oxybis- No data available.
Naphtha (petroleum), No data available.
hydrotreated light
Benzene, 1-chloro-4- No data available.
(trifluoromethyl)-
Heptane No data available.
Maleic Anhydride Modified No data available.
Liquid Polyisoprene
Cyclohexane, methyl- No data available.
Methanol No data available.

Other adverse effects: Harmful to aquatic organisms.

13. Disposal considerations

Disposal instructions: Discharge, treatment, or disposal may be subject to national, state, or local
laws.

Contaminated Packaging: No data available.

14. Transport information

DOT

UN Number: UN 1950
UN Proper Shipping Name: Aerosols, flammable
Transport Hazard Class(es)
Class: 2.1
Label(s): –
Packing Group: II
Marine Pollutant: No

Environmental Hazards: No
Marine Pollutant No

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Special precautions for user: Not regulated.

IMDG
UN Number: UN 1950
UN Proper Shipping Name: Aerosols, flammable
Transport Hazard Class(es)
Class: 2
Label(s): –
EmS No.:
Packing Group: –

Environmental Hazards: No
Marine Pollutant No

Special precautions for user: Not regulated.

IATA
UN Number: UN 1950
Proper Shipping Name: Aerosols, flammable
Transport Hazard Class(es):
Class: 2.1
Label(s): –
Packing Group: –

Environmental Hazards: No
Marine Pollutant No

Special precautions for user: Not regulated.

15. Regulatory information

US Federal Regulations

Restrictions on use: Not known.

TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)

US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Chemical Identity OSHA hazard(s)
Benzene Flammability
Cancer
Aspiration
Eye
Blood
Skin
respiratory tract irritation
Central nervous system

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CERCLA Hazardous Substance List (40 CFR 302.4):

Chemical Identity Reportable quantity
2-Propanone lbs. 5000
Propane lbs. 100
Methane, 1,1'-oxybis- lbs. 100
Acetic acid, methyl ester lbs. 100
Heptane lbs. 100
Cyclohexane, methyl- lbs. 100
Methanol lbs. 5000
Hexane lbs. 5000
Cyclohexane lbs. 1000
Benzene, methyl- lbs. 1000
Benzene, ethyl- lbs. 1000
Phenol lbs. 1000
Benzene, dimethyl- lbs. 100
Benzene, ethenyl- lbs. 1000
Benzene lbs. 10

Superfund Amendments and Reauthorization Act of 1986 (SARA)

Hazard categories
Fire Hazard
Immediate (Acute) Health Hazards
Flammable aerosol
Serious Eye Damage/Eye Irritation
Skin sensitizer
Specific Target Organ Toxicity - Single Exposure

SARA 302 Extremely Hazardous Substance

Reportable
Chemical Identity quantity Threshold Planning Quantity
2-Propanone
Acetic acid, methyl ester
Hexane
Phenol lbs. 1000 - -- -

SARA 304 Emergency Release Notification

Chemical Identity Reportable quantity
2-Propanone lbs. 5000
Propane lbs. 100
Methane, 1,1'-oxybis- lbs. 100
Acetic acid, methyl ester lbs. 100
Heptane lbs. 100
Cyclohexane, methyl- lbs. 100
Methanol lbs. 5000
Hexane lbs. 5000
Cyclohexane lbs. 1000
Benzene, methyl- lbs. 1000
Benzene, ethyl- lbs. 1000
Phenol lbs. 1000
Benzene, dimethyl- lbs. 100
Benzene, ethenyl- lbs. 1000
Benzene lbs. 10
Benzenamine, 2-methyl-
4-[2-(2-
methylphenyl)diazenyl]-

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SARA 311/312 Hazardous Chemical

Chemical Identity Threshold Planning Quantity
Phenol lbs
2-Propanone 10000 lbs
Propane 10000 lbs
Acetic acid, methyl ester 10000 lbs
Naphtha (petroleum), 10000 lbs
hydrotreated light
Benzene, 1-chloro-4- 10000 lbs
(trifluoromethyl)-
Heptane 10000 lbs
Maleic Anhydride Modified 10000 lbs
Liquid Polyisoprene
Cyclohexane, methyl- 10000 lbs
Methanol 10000 lbs
Hexane 10000 lbs
Cyclohexane 10000 lbs
Benzene, methyl- 10000 lbs
Benzene, ethyl- 10000 lbs
Benzene, dimethyl- 10000 lbs
Benzene, ethenyl- 10000 lbs
Benzene 10000 lbs
SARA 313 (TRI Reporting)
None present or none present in regulated quantities.

Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130):
Clean Water Act Section 311 Hazardous Substances (40 CFR 117.3)
US State Regulations

US. California Proposition 65

This product contains chemical(s) known to the State of California to cause cancer and/or to cause birth
defects or other reproductive harm.

Benzene, 1-chloro-4- Carcinogenic.

(trifluoromethyl)-
Methanol Developmental toxin. 03 2012
Hexane Male reproductive toxin. 12 2017
Benzene, methyl- Developmental toxin. 03 2008
Benzene, ethyl- Carcinogenic. 05 2011
Benzene, ethenyl- Carcinogenic. 04 2016
Benzene Developmental toxin. 03 2008
Benzene Carcinogenic. 05 2011
Benzene Male reproductive toxin. 03 2008
Benzenamine, 2-methyl-4- Carcinogenic. 05 2011
[2-(2-
methylphenyl)diazenyl]-

US. New Jersey Worker and Community Right-to-Know Act

Chemical Identity
2-Propanone
Propane
Methane, 1,1'-oxybis-
Acetic acid, methyl ester
Naphtha (petroleum), hydrotreated light
Benzene, 1-chloro-4-(trifluoromethyl)-
Heptane

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US. Massachusetts RTK - Substance List

Chemical Identity
Phenol
Benzene, ethenyl-

US. Pennsylvania RTK - Hazardous Substances

Chemical Identity
2-Propanone
Propane
Methane, 1,1'-oxybis-
Acetic acid, methyl ester
Naphtha (petroleum), hydrotreated light
Heptane

US. Rhode Island RTK

No ingredient regulated by RI Right-to-Know Law present.

International regulations

Montreal protocol
2-Propanone
Acetic acid, methyl ester

Stockholm convention
2-Propanone --
Acetic acid, methyl ester --

Rotterdam convention
2-Propanone --
Acetic acid, methyl ester --

Kyoto protocol

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Inventory Status:
Australia AICS: Not in compliance with the inventory.

Canada DSL Inventory List: On or in compliance with the inventory

EINECS, ELINCS or NLP: Not in compliance with the inventory.

Japan (ENCS) List: Not in compliance with the inventory.

Korea Existing Chemicals Inv. (KECI): Not in compliance with the inventory.

Canada NDSL Inventory: Not in compliance with the inventory.

Philippines PICCS: Not in compliance with the inventory.

US TSCA Inventory: On or in compliance with the inventory

New Zealand Inventory of Chemicals: Not in compliance with the inventory.

Japan ISHL Listing: Not in compliance with the inventory.

Japan Pharmacopoeia Listing: Not in compliance with the inventory.

Mexico INSQ: Not in compliance with the inventory.

Ontario Inventory: Not in compliance with the inventory.

Taiwan Chemical Substance Inventory: Not in compliance with the inventory.

China Inv. Existing Chemical Substances: On or in compliance with the inventory

16.Other information, including date of preparation or last revision

Issue Date: 10/30/2019

Revision Information: No data available.

Version #: 1.0

Further Information: No data available.

Disclaimer: This information is provided without warranty. The information is believed to

be correct. This information should be used to make an independent
determination of the methods to safeguard workers and the environment.

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