Chemistry Notes
Chemistry Notes
Chemistry Notes
CHEMISTRY NOTES
by dhamira :)
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CHAPTER 2,F4: MATTER & THE ATOMIC STRUCTURE
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Matter -something occupies space&has mass
Particle Theory of matter
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id
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CHAPTER 3,F4: MOLE CONCEPT,FORMULA&EQUATION
p
Melting point -constant temperature that changes a solid to liquid at a specific pressure
Freezing point -constant temperature that changes a liquid to solid at a specific pressure
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What is isotopes atoms of the same element w same proton numbers but different nucleon number
Its uses
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CHAPTER 3,F4: MOLE CONCEPT,FORMULA&EQUATION
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3.1) RAM & RMM
Role of Carbon 12 -used as a standard atom
• can be handled easily
• solid at room temp
• can be found in almost all substances
Relative atomic mass Average mass of one atom/molecule of the element
(RAM) / Relative
1/12 x mass of 1 c-12 atom (*this eq =1
molecular mass (RMM) *kira atas je tkyah bahagi dgn bawah)
No of moles
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↑
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↑
CHAPTER 4,F4: PERIODIC TABLE OF ELEMENTS
F
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GROUP -the vertical column
-from 1 to 18
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-is determined by the no of valence electrons
PERIOD -the horizontal column
-from 1 to 7
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-is determined by the number of shells
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Physical properties -low melting &boiling point
-x conduct electricity in any state
-pungent smell&poisonous
-low density
Physical states in room -Flourine: pale yellow gas -bromine: reddish brown liquid
cond -chlorine: greenish yellow gas -iodine: purplish black solid
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-electronegativity increases
Changes of physical a) solid —> gas
state b) metal —> smei metal —> non-metal
Types of oxide formed i) Basic metal oxides (Na&Mg) ii) Amphoteric (Al)
& -form alkaline solution in water -can act as acid/base
-react w avid to produce salt&water -react w both to produce salt&water
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4.7) Transition elements (elements from group 3 -12)
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Physical properties -solid at room cond
-shiny surface
-high ductility & malleability
-high melting & boiling point
-high density
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-good conductor of heat & electricity
Special physical
characteristics
Application
- =
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CHAPTER 5,F4: CHEMICAL BOND
XX
XX Cl
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X
XX
XX
Lewis structure
What is covalent -formed thru sharing of electrons between non metal compounds
TYPES
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bond?
-single(1e shared),double(2e shared),triple(3e shared) covalent bond
Electron arrangement between hydrogen & chlorine (hydrogen chloride)
Lewis structure
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XX
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CHAPTER 5,F4: CHEMICAL BOND
EXAMPLE 2
• Our hair consists of protein molecules that can form hydrogen
bonds when the hair is dry.
• When the hair is wet, the protein molecules form hydrogen
bonds with water molecules.
I ↓I
• Formation of hydrogen bonds between protein molecules and
water molecules causes the hair to stick together.
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&
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CHAPTER 5,F4: CHEMICAL BOND
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What is dative bond? -type of covalent bond between 2 atoms where the electron pair is shared by
one atom only
-also known as coordinate bond
Examples Ammonium ion, NH4-
t
It
H"
* H
a)
b) Covalent compound c) Uses of ionic & covalent compounds in daily life
CHAPTER 6,F4: ACID BASE & SALT
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What is acid? Chemical substances that ionises in water to form H+/Hydroxonium ions,
H3O+
What is acidity of an acid? -no of moles of H+ formed when 1 mole of acid dissolves in water
Monoprotic Acid
-acid that ionises Diprotic Acid Triprotic Acid
in water to form -2 mole of H+ -3 mole of H+
1mole of H+
6.2) pH value
Acidic solution -pH value <7
-concentration of H+ increases, pH value decreases
-pH=-log [H+]
Alkaline solution -pH value > 7
-concentration of OH- increases, pH value increases
-pOH=-log[OH-]
pH scale -set of numbers to indicate the acidity or alkalinity of an aqueous solution
-pH+pOH = 14
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Acid & its physical CHEMICAL PROPERTIES
properties -acid+base —> salt+water
-acid+reactive metal —> salt+hydrogen gas
-acid+metal carbonate —> salt + water + CO2
PHYSICAL PROPERTIES
-sour taste
-corrosive
-pH value <7
-blue litmus paper turns red
PHYSICAL PROPERTIES
-biiter taste
-soapy feel
-pH value >7
-red litmus paper turns red
M= molarity before&after
V= initial & final volume
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CHAPTER 6,F4: ACID BASE & SALT
6.7) Neutralisation
What is neutralisation? Chemical reaction between an acid& an alkali to produce salt & water
What is the product of H+ + OH- —> H2O
neutralisation
Application of Agriculture Health Industry
neutralisation
-treat acid in stomach -soap&detergent
-pH of soil -prevent tooth decay product
-aquaponic -treat bee&wasp -treat acidic effluents
-nitrogenous fertiliser stings,jellyfish -treat acidic gases
stings&ant bites
• Protease enzyme
=function well in acidic medium stomach
=break down the protein into polypeptide
=pH of stomach is maintained between 1 and 2 by the presence of hydrochloric acid
• Gastric patients
=experience excess HCl in stomach
=milk of magnesia, Mg(OH), relieve pain as its alkaline properties can neutralise
excess HCl
• Plants
=grow best when the pH of the soil is close to 7
=extremely acidic soil is not suitable for crops
=quicklime, (CaO)or slaked lime, [Ca(OH)2] can be used to treat the acidic soil.
• Bacteria in the mouth produce lactic acid
=toothpaste is an alkaline can neutralise the acid.
•Bee sting
=acidic
=treated with alkaline calamine lotion or baking powder.
•Wasp sting
=alkaline
=can be treated with vinegar.
Titration -method use to determine volume of acid required to neutralise alkali & vice
versa quantitatively
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-involves a slow addition of a solution of known concentration (in the burette)
to a known volume of another solution of unknown concentration (in the
conical flask) until the reaction reaches the end point indicated through colour
change of the acid-base indicator
pH indicator
Indicator in acid in distilled water in alkali
litmus red purple blue
Solving numerical
M1V1 n(a) M=molarity (mol dm-3)
problems =
M2V2 n(b) V=volume (cm-3)
n=mole ratio of acid/alkali
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What is salt? -ionic compound form from metal ion or ammonium ion,NH4+ that replaces H+
in the end
Salt’s products • acid+alkali —> salt+water
• acid+reactive metal —> salt+hydrogen gas
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• acid+aqueous ammonia —> salt
Physical characteristics of -flat surface,straight sides&sharp corners
salt crystal -angles between adjacent faces are the same
-has geometrical shape
-high melting point
-geometrical shape varkes for different crystals
-geometrical shape is the same for similar crystals of different sizes
Examples&uses of salts -ammonium chloride/nitrate/
phosphate chemical fertilisers
-potassium chloride
-copper(II) sulphate
-mercury(I) chloride pesticides to kill insects,pests,grass&legs
-sodium chlorate(V)
hydrated calcium sulphate make plaster casts for supporting broken
bones
iron(II) sulphate heptahydrate iron supplements to treat anemia
-magenesium sulphate
heptahydrate(epsom salt)
-sodium sulphate laxatives to treat constipation
decahydrate(glauber salt)
-ingredients in antacids
sodium hydrogen carbonate
-neutralise excess acids in stomach
barium sulphate make intestinal organs seen clearly on x-
ray
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Chemical reactions
Fast reaction Slow reaction
-Combustion of cooking gas -Rusting
-Fireworks -Fermentation
-Ignition of matches -Photosynthesis
-Burning of papers -Decaying process
-Precipitation -Rock erosion
Rate of reaction -Meaning: Changes in the quantity of reactant or product per unit time
-Formula: Change in quantity of reactant or product/time taken for the
change to occur
-During the reaction:
a) Quantity of reactants decreases per unit time
b) Quantity of products increases per unit time
Average rate of reaction Average value for the rate of reaction that occurs in a particular time interval
Rate of reaction = Total volume of gas
Total time
Instantaneous rate of
reaction -
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CHAPTER 7,F4: RATE OF REACTION
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Factors
SIZE OF
REACTANTS CONCENTRATION TEMPERATURE PRESENCE OF
-the smaller the OF REACTANTS -the higher it is, CATALYST
size of -the higher it is,the the higher the -catalyst
reactants,the higher the rate of rate of reaction increases the rate
higher the rate reaction of reaction
of reaction
Characteristics of -specific
catalyst -changes the rate of reaction
-only small amount of catalyst required
-undergo physical changes
-no changes in chemical properties
-powdered catalyst is more effective
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-transition elements
7.3) Application of Factors that Affect the Rate of Reaction in Daily Life
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Concentration -rusting
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-corrosion in industrial area
Pressure -haber process
-pressure cooker
&
Temperature -cleaning
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-storage of food
Catalyst -fermentation
-production of ammonia solution
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-production of sulphuric acid
HABER PROCESS PRESSURE COOKER
CORROSION IN INDUSTRIAL
RUSTING increases the
AREA
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steam molecules
this pressure form ammonia
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near the
vapours of SO2 higher heat
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bes the water is
higher Kinetic
hv
Seaside contain higher Clions liquid for easier storage energy
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So dissolves in water
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faster
rusting becomes with metuls causes Corrosion
PRODUCTION OF AMMONIA
FERMENTATION PRODUCTION OF SULPHURIC ACID
CLEANING added to glucose I wn powder is added to
Zymase is
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Vanadium
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Speeds up
STORAGE FOOD
OF formation of ammonia
before Channelled to
gas is
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fridge acid
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CHAPTER 7,F4: RATE OF REACTION
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Based on collision theory -reactant particles must collide w e/o for a reaction to occur
-rate of reaction depends on the frequency of effective collisions
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-the higher it is, the higher the rate of reaction
To produce effective -reactant particles must hv energy =/> than the activation energy (Ea)
collision -Ea is the minimum energy required to break the chemical bonds between
reactants particles & form a new chemical bonds in the products
Activation energy -difference between reactants energy & energy at the peak of the curve in the
graph
Size of reactants -the smaller the size of reactants,the larger the TSA exposed
-the frequency of collisions between reactants particles is higher
- -the frequency of effective collisions between reactant particles is higher
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-rate of reaction is higher
Temperature of solution -the higher the temperature,the more kinetic energy of the reactant particles
-the frequency of collision between reactant particles is higher
-thee frequency of effective collision between reactant particles is higher
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-rate of reaction is higher
Concentration of -the higher the concentration of reactant particles,the higher the number of
reactants particles per unit volume
-the frequency of collision between reactant particles is higher
-the frequency of effective collision between reactant particles is higher
-
-rate of reaction is higher
Gas pressure -the higher the gas pressure, higher the number of gas particles per unit volume
-the frequency of collision between reactant particles is higher
-the frequency of effective collision between reactant particles is higher
-rate of reaction is higher
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Presence of catalyst -catalyst lower the Ea for the collision of reactant particle
-more reactant particles achieve the activation energy
-the frequency of collision between reactant particles is higher
-the frequency of effective collision between reactant particles is higher
-rate of reaction is higher
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reaction
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CHAPTER 8,F4: MANUFACTURED SUBSTANCES IN INDUSTRY
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Meaning of alloy Mixture of 2 or more elements whereits main elements is metal
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Strength & hardness Alloy > Pure metal
Comparison between
pure metal & alloy Pure metal Alloy
Diagram of the
arrangement
Size of atoms All atoms hv the same size Foreign atoms hv different sizes
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Arrangemen Arranged in orderly manner Orderly arrangement is disrupted
t of by foreign atoms
particles
Ability of When force is applied, layers When force is applied,it is
particles to of atoms easily slide over difficult for the layers of atom to
slide over each other to fill the empty slide over one another
space & form a new
structure
BRONZE BRASS
-90% copper -70% copper
-10% tin -30% zinc
-Medals,trophies,monuments -Musical instruments,keys
DURALUMIN
PEWTER
-93% aluminium
-95% tin
-3% copper
=
-3.5% antimony
-3% magnesium
1.5% copper
-1% manganese
-trophies,souvenirs
-body of aeroplanes,racing cars,bicycles
STAINLESS STEEL
STEEL
-73% iron
-98% iron
-18% chromium
-0.2-2% carbon
-8% nickel
-construction materials, railway
1% carbon
tracks
-cutlery,surgical instruments
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Types of glasses
FUSED SILICA GLASS
-made from silica,SiO2 w/o mix w chemical
-high melting point
-make telescope lens
BOROSILICATE GLASS
-made from SiO2,Na2Co3,CaCo3,boron oxide,B2O3 &
aluminium oxide, Al2O3
-resistant to heat
-low expansion coefficient
-make laboratory glasses
Type of ceramics
TRADITIONAL CERAMICS ADVANCED CERAMICS
-made from clay (kaolin) -made from inorganic compounds
Al2O3.2SiO2.2H2O (oxides&carbides)
-make bricks,pottery&crockery -hv higher heat resistance
-resistant to abrasion
-more chemically inert
-hv superconductivity properties
b) SILICAN NITRIDE
-high strength&fracture toughness at e) LITHIUM DISILICATE GLASS
high temperature(structural -biocompatibility!excellent
component for gas turbines) aesthetic properties,good
mechanical strength (used in
c) ALUMINIUM OXIDE dental treatment)
-chemically resitant&resistant to
wear(hip joint replacement)
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CHAPTER 8,F4: MANUFACTURED SUBSTANCES IN INDUSTRY
8.4) Composite materials & its importance
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Composite material A combination of 2 or more non-homogeneous substances
Example of REINFORCED
FIBRE GLASS OPTICAL FIBRE
composite CONCRETE -combination between
-combination of steel -combination between
materials silica glass fibres (SS)
bar/wire mesh (SS) & pastic (MS) & glass fibres
&cladding/plastic
concrete (MS) (SS) jacket(MS)
-high compression -high stretching strength
strength -flexible
-durable -high compression strength
-resistant to corrosion
-high stretching strength
-resistant to corrosion -use:transmit information in
-uses: construction of -heat&electrical insulator the form of light
bridges,dams&buildings -uses:helmets