Solution-Stochiometry

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Generalities on the

aqueous solution &


Stoichiometry

Aqueous
Reactions
Concentration of aqueous solution

Aqueous
Reactions
Aqueous
Reactions
Aqueous
Reactions
1. (a)A solution is made by dissolving 13.5 g
of glucose (C6H12O6) in 0.100 kg of water.
What is the mass percentage of solute in this
solution?

(b)A 2.5 g sample of groundwater was found


to contain 5.4μg of Zn2+ What is the
concentration of Zn2+ in parts per million?
Aqueous
Reactions
2. a) Find the masses of sodium chloride and water
required to obtain 175 g of a 15% solution.

b) A commercial bleaching solution contains 3.62


mass % sodium hypochlorite, NaOCl. What is the
mass of NaOCl in a bottle containing 2500 g of
bleaching solution?

Aqueous
Reactions
3. A commercial bleach solution contains 3.62 mass
% NaOCl in water. Calculate (a) the molality and
(b)the mole fraction of NaOCl in the solution.

4. I2 is produced by the reaction of 0.4235 mol of


CuCl2 according to the following
equation: 2CuCl2+ 4KI→2CuI + 4KCl+I2 .
• How many molecules of I2 are produced?
• What mass of I2 is produced?

Aqueous
Reactions
5. Automotive air bags inflate when a sample of
sodium azide, NaN3, is very rapidly decomposed.
2NaN3(s)→2Na(s)+3N2(g)
What mass of sodium azide is required to produce
73.6 L of nitrogen gas with a density of 1.25 g/L?

Aqueous
Reactions
6.Silver is often extracted from ores as K[Ag(CN)2]
and then recovered by the reaction
2K[Ag(CN)2](aq)+Zn(s)→2Ag(s)+Zn(CN)2(aq)+2
KCN(aq)
(a) How many molecules of Zn(CN)2 are produced
by the reaction of 35.27 g of K[Ag(CN)2]?
(a) What mass of Zn(CN)2 is produced?

Aqueous
Reactions
7. Urea, CO(NH2)2, is manufactured on a large scale
for use in producing urea-formaldehyde plastics and
as a fertilizer. What is the maximum mass of urea
that can be manufactured from the CO2 produced by
combustion of 1.00×103 kg of carbon following the
below reaction?
C+O2​→CO2
NH3​+ CO2​→ CO(NH2​)2​ + H2​O

Aqueous
Reactions
8. In an accident, a solution containing 2.5 kg of
nitric acid was spilled. Two kilograms of
Na2CO3 was quickly spread on the area and CO2 was
released by the reaction. Was sufficient Na2CO3 used
to neutralize all of the acid? (in this reaction, water
and sodium nitrate are the other two products).
Na2​CO3 + HNO3​→NaNO3​+H2​O + CO2

Aqueous
Reactions
9. A compact car gets 37.5 miles per gallon on the
highway. If gasoline contains 84.2% carbon by mass
and has a density of 0.8205 g/mL, determine the
mass of carbon dioxide produced during a 500-mile
trip (3.785 liters per gallon).

Aqueous
Reactions

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