Chapter 1.2 - Basic Concepts of Thermodynamics

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CHAPTER 1b:

BASIC CONCEPTS OF
THERMODYNAMICS

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CONTENTS
 Thermodynamics and Energy
 Dimensions and Units
 Systems and Properties
 State, Processes and Cycles
 Temperature
 Pressure and Measuring Devices
 Problem Solving Technique
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LESSON OBJECTIVES

At the end of the lesson, you should be


able to:-
 Convert kPa / MPa to bar and vice versa
 Find absolute pressure for a given system
 Convert temperature from deg C to Kelvin
 Apply the 5-steps problem solving technique

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TEMPERATURE
 Measure of hotness and coldness
 Transfer of heat from higher to lower temp. until both bodies attain
the same temp. At that point, heat transfer stops and the two bodies
have reached thermal equilibrium

Zeroth Law of If two bodies are in thermal equilibrium with a


Thermodynamics third body, they are also in thermal equilibrium
with each other.

A (30oC) C (30oC) It is not necessary to bring those 2 bodies into contact,


we only need to see whether they are individually in
C (30oC) B (30oC) thermal equilibrium with a third body. Usually the third
body is a thermometer.

Adiabatic Process, Isothermal Process 4


TEMPERATURE (CONT’D)

T(K) = T(C) + 273.15 Rounded off to 273

T(R) = T(F) + 459.67 T(R) = 1.8T(K)

T(F ) = 1.8T(C) + 32 T(R) = T(F) = 1.8T(K)

T(K) = (T2C +273.15) - (T1C + 273.15)


= T2C - T1C
= TC

T
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SPECIFIC VOLUME

It is defined as :
1 V Unit: m3/kg
v 
 m

Or for a unit mole basis

V V .M Unit: m3/kmol
v   v.M
n m

Where M is the molecular weight in kg/kmol

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PRESSURE

 Defined as the normal force exerted by a


fluid per unit area:
Force F Unit: N/m2 or Pa
P 
Area A

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PRESSURE (CONT’D)
 Pressure discussed above is called absolute pressure. In thermo, absolute
pressure is always used unless otherwise stated.

 Pressure measuring device often indicate the difference between absolute


pressure in a system and that of the atmosphere.

 The magnitude of the difference is called:


 Gauge Pressure , when Pabs> Patm

Pgage  Pabs  Patm

 Vacuum Pressure, when Pabs< Patm

Pvac  Patm  Pabs

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EXAMPLES

1. A vacuum gage connected to a chamber reads 5.8 psi at a location


where the atmospheric pressure is 14.5 psi. Determine the absolute
pressure in the chamber.

Given that: Pvac  5.8 psi


Patm  14.5 psi
Therefore: Pabs  Patm  Pvac  14.5  5.8  8.7 psi

2. The absolute pressure inside a tank is 0.2 bar, and the surrounding
atmospheric pressure is 101 kPa. What reading would a pressure
gauge mounted in the tank wall give, in kPa? Is this a gauge of vacuum
reading?
Ans: 81 kPa (yes) 9
EXERCISES
1. A vacuum gage connected to a tank reads 30 kPa at a
location where the atmospheric pressure is 98 kPa. What
is the absolute pressure in the tank?
Ans: 68 kPa

2. A pressure gage connected to a valve stern of a truck


tire reads 240 kPa at a location where the atmospheric
pressure is 100 kPa. What is the absolute pressure in
the tire, in kPa?
Ans: 340 kPa

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PRESSURE MEASURING
DEVICES

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PRESSURE MEASURING
DEVICES

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PRESSURE MEASURING
DEVICES

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PRESSURE MEASURING
DEVICES
 Pressure measuring devices includes manometer and bourdon tube.

 Manometer • Measures small to moderate pressure difference


• Differential fluid column of height L corresponds to a pressure
difference between the system and the surrounding of the
manometer

P  Pabs  Patm   .g .h

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PRESSURE MEASURING
 Pressure - Pascal Law

P  Pabs  Patm   .g .h
APPLICATION

Pascal’s law: The pressure applied


to a confined fluid increases the
pressure throughout by the same
amount.

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EXAMPLE & EXERCISE
1. Determine the gauge pressure, in kPa, equivalent to a
manometer reading of 1 cm of water (density 1000 kg/m3).

Given that: h  0 .01 m ,   1000 kg / m 3

Therefore:  P   . g .h  (1000 ).( 9 .8).( 0 .01)  98 Pa

2. Determine the gauge pressure, in kPa, equivalent to a


manometer reading of 1 cm of mercury (density 13.59
times that of water).
Ans: 1333.18 N/m2

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PROBLEM-SOLVING
TECHNIQUE
• A five-step problem solution format
• To guide our thinking

KNOWN State what is known

FIND State what is to determined

Sketch, label with given data, identify closed


SCHEMATIC syst or CV

List simplifying assumptions and idealization


ASSUMPTIONS

ANALYSIS Use equations/relations to give results, check


units 18
EXAMPLE

A manometer is attached to a tank of gas in which the pressure is


greater than that of the surroundings. The manometer liquid is
mercury, with a density of 13.59 g/cm3. The difference in mercury
levels in the manometer is 2 cm. Atmospheric pressure is 98 kPa.
Calculate (in kPa), the gauge and absolute pressure of the gas.

Step 1: Known
h  2 cm  0.02m
Patm  98kPa
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3  13 . 59   10  3 3
 Hg  13 . 59 g / cm   kg   3
  (13 . 59 ). 10
 kg / m
 1000  m 

Step 2: Find
Pg , Pabs

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EXAMPLE (CONT’D)
Step 3: Sketch the system Step 4: State assumptions
Gas density is lower than density of
mercury

Step 5: Use equations

P  Pabs  Patm   .g .h

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Summary of Chapter 1

 Thermodynamics and energy  Processes and cycles


 Application areas of
thermodynamics  Temperature and the zeroth law
of thermodynamics
 Importance of dimensions and
units  Pressure
 Some SI and English units,
 The manometer and the
 Systems and control volumes atmospheric pressure
 Properties of a system
 Density and specific gravity
 Problem solving technique
 State and equilibrium
 The state postulate

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