Internal Energy: Iheatisthetrasterenegyincenes

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INTERNAL ENERGY

the random
molecular energy of a substance

I It
is U is called internal energy
increases
its the sum of the potential energy
if gas and kinetic energy
name inane
internal energy
SÉÉf systems object
are an much energy transfers
g through ie potato
f
900 100
yo
I W posativeexample AU intone
iHeatisthetrasterenegyincenes
of quantity of
a vicever
0th Lavoythermodynamic thermal energy between
and its surroundings The transfer
thermal Equilibrium the system
If Q is t therapy is going into the system
Q I4 If Q is teetersy is going out the system
i

isothermalconstanttemp

Work is the macroscopic transfer of energy


W is the work done by the system
If the system is doing work on the surroudizs Wt
If the surroundis is dong work on the system w
0th Law if two systems are at te sane temperature
there is no resultant heat flow thermal equilibrium Han

Pil JPY2 PV NRT tnv


are
undercurve

Fitr
4
113 ammonium

si
MPV
V2 Paz EI anat v
0.1132
g y
WORK DONE
A 313 Work done P
areaunder line
PAU
only you isobaric

Adiabatic Process no heat enters or leaves the


system 0 0
The rapid compression or expansion of a gas is
approximately adiabatic
put
IIistant
The adiabatic curve is from one isotherm
to another so it is steeper
first law TD Q OUtW 0 0
wax AU temperature decreased
EFFICIENCY Heat Engines
0setentggtnpd.ge
M
efficiency for
carnevers
ex
Etta
p
É Idea
Hotreservoir

Cop EYE
Second Law of
Thermodynamics An ideal engine would be reversible means

jjyjj.my
could run it backwards His i
joiner
th work to transfer hat from somethe lower
ay disorder in temp to something lusher temp
j

tempoforde teaptoisoroe
cannffyg.ee idealengine
they are very slow engines
AAAS Jk because the temp hey to

why is there a maximum possibility


no friction
internal enemy close to equilibrium
depends on the difference in hat
Entropy
a measure of how spread out
your energy i's
Energy is needed to be clumped tooth
energy
Entropy is an abstract definition
Clausius you cannot get heat to
go cold to hot without work

Kelvin you cannot take heat and


turn it into 1001 energy

Hot
I Et
Épw
f
dig waza
Q EYE

Do
Not Possible
Not Possible
Brett Break 2
retention
Brett Break 2
If a
quantity of heat plows from hot
to cold entropy Chee
sifts vial
As E E
Q 1520

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