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    Problem Sheet 3

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    ASHADEVI U
    This document contains calculations related to ideal gas law involving pressure, volume, temperature and moles of gases. It includes examples such as calculating the volume required to store 1 kgmole of methane at 50°C and 600 atm of pressure, calculating the volume of 15 kg of chlorine gas at 0.9 bar and 293K, and calculating the maximum temperature that 10 lbs of T2 gas can be heated to within a 30 cubic feet chamber.

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    Problem Sheet 3

    Uploaded by

    ASHADEVI U
    55 views3 pages
    This document contains calculations related to ideal gas law involving pressure, volume, temperature and moles of gases. It includes examples such as calculating the volume required to store 1 kgmole of methane at 50°C and 600 atm of pressure, calculating the volume of 15 kg of chlorine gas at 0.9 bar and 293K, and calculating the maximum temperature that 10 lbs of T2 gas can be heated to within a 30 cubic feet chamber.

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    This document contains calculations related to ideal gas law involving pressure, volume, temperature and moles of gases. It includes examples such as calculating the volume required to store 1 kgmole of methane at 50°C and 600 atm of pressure, calculating the volume of 15 kg of chlorine gas at 0.9 bar and 293K, and calculating the maximum temperature that 10 lbs of T2 gas can be heated to within a 30 cubic feet chamber.

    Copyright:

    © All Rights Reserved
    Download as PPTX, PDF, TXT or read online from Scribd
    Download as pptx, pdf, or txt
    55 views3 pages

    Problem Sheet 3

    Uploaded by

    ASHADEVI U
    This document contains calculations related to ideal gas law involving pressure, volume, temperature and moles of gases. It includes examples such as calculating the volume required to store 1 kgmole of methane at 50°C and 600 atm of pressure, calculating the volume of 15 kg of chlorine gas at 0.9 bar and 293K, and calculating the maximum temperature that 10 lbs of T2 gas can be heated to within a 30 cubic feet chamber.

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    © All Rights Reserved
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    CALCULATIONS OF PRESSURE, VOLUME AND TEMPERATURE USING IDEAL

    Its necessary to store 1 kgmole of methane at a temperature of


    50 o C and a pressure of 600 atm. What is the volume of the vessel
    that must be provided?
    Solution:
    n = 1 Kmol
    T = 50 o C = 323 K
    P= 600 atm
    V= nRT/P = (1* 0.082*323)/600
    = 0.044 m3

    Calculate the volume of 15 kg of chlorine at a pressure of 0.9 bar


    and 293 K assuming ideal gas law.
    Solution:
    W = 15 kg
    n = W/M =15/71 =0.211 kmol T = 293 K
    1 bar = 0.98 atm
    P= 0.9 bar= 0.88 atm
    V= nRT/P = (0.211* 0.082*293)/0.88
    = 5.76m3

    What is the value of gas constant R .

    What will be the % Na2O content of lye containing 80% caustic


    soda.
    Basis : 100 Kg of lye
    Weight of NaOH = 80 Kg

    2 NaOH Na 2 O + H2O
    2. kmol NaOH = 1 kmol of Na 2 O 80
    Kg of NaOH = 62 Kg of Na 2 O
    80 Kg of NaOH = (80*62)/80=62
    kg Weight of Na 2 O content of lye =
    62
    Kg
    Weight % of Na 2 O content of lye
    =(62/100)*100=62

    Define weight fraction and mole


    fraction .If 2.925 g of NaCl and
    19.1 g of sugar are dissolved in
    100 ml water .calculate the
    number
    of moles of NaCl and C12H22O11.

    Mass fraction (weight fraction) is the ratio of the mass of one


    component of a solution to the total mass of the solution.
    Mole fraction is a unit of concentration, defined to be equal
    to the
    number of moles of a component divided by the total number of
    moles of a solution:
    W NaCl=2.925 g
    nNacl=WNacl/M=2.925/58.5=0.05 mol
    Wsugar = 19.1 g
    n sugar = W sugar/M = 19.1/342 = 0.05 mol

    Calculate the molarity of solution prepared by dissolving 34.2 g of


    sucrose C12H22O11 in water to give 400 ml solution.
    Solution:
    W sucrose = 34.2 g
    V= 400 ml = 400*10 -3 litre
    Gm moles of sucrose = weight of sucrose/M= 34.2/342=0.1 mol
    Molarity = gm moles of sucrose/Volume of solution in litre
    = 0.1/ (400*10 -3 )
    =0.25

    Find the composition of air in weight percentage.


    Air composition Oxygen = 21 kmol Nitrogen = 79 kmol
    Weight Percentage
    Weight of oxygen = No of moles of oxygen * Molecular
    weight
    = 21 * 32 = 672 kg
    Weight of Air = No of moles of air * Molecular weight
    = 79 * 28 =2212 kg
    Weight percentage of air = weight of air/Total weight
    = (2212/2884)*100=76.69

    230g of NaCl is present in 1 litre solution at 25 o C .Density of


    solution is 1.148 g/cc .calculate the composition in weight
    percent.
    Solution:

    W NaCl =230 g
    V= 1 lit = 10 -3 m 3 T= 25 o C = 298 K
    ρ= 1.148 g/cc= 1.148*10^6 g/ m 3
    W soln= V soln * ρ= 10 -3 * 1.148*10^6 =1 1 4 8 g
    W soln = W NaCl +W H2O

    W H2O =W soln - W NaCl

    =1148- 230
    = 918 g
    Weight percentage of NaCl = W NaCl/ W soln =(230/1148 )*100=20
    Weight percentage of H2O =W H2O / W soln =(918/1148)*100 = 80

    Assuming the applicability of the ideal gas law. Calculate the maximum

    temperature to which 10 lb of T2, enclosed in 30 cu.ft. chamber.

    Solution:-

    Volume at S.C. = 0.307  359

    P2 V2 = 128.1 Cu.ft.
    T2  T 1 
    T1 V1

    = 273  150  30
    14.7
    128.1
    Temperature at 30 Cu.ft. = 652K (or) 379C

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