Alsheet Alsheet: TM TM
Alsheet Alsheet: TM TM
Alsheet Alsheet: TM TM
com
ALSHEET
Steel
TM
Sheet
ALSHEETTM
2-6-1 Marunouchi, Chiyoda-ku,Tokyo 100-8071 Japan U034en_02_202004f
U034en_02_202004p
Tel: +81-3-6867-4111 © 2019, 2020 NIPPON STEEL CORPORATION
Introduction Manufacturing Process
Overall manufacturing Blast furnace
ALSHEET TM
is a cold-rolled steel that has been hot-dipped in an aluminum/silicon alloy. It process
Acid Pickling
offers the attractive surface of processed steel sheet that simultaneously affords some of Converter
the features of aluminum, such as resistance to corrosion, attractive appearance, coupled
Cold Rolling
with superior heat resistance and heat reflection, cold-rolled steel’s mechanical attributes Continuous Casting
and other physical characteristics.
Hot-dip
We have been manufacturing hot-dip aluminum-coated steel sheets under the name Hot Rolling
aluminum plating
“ALSHEETTM” since July 1961, and it has been widely adopted thanks to its superior
features, such as for vehicle mufflers (silencers), toasters, and gas cookers.
In recent years, there have been calls for the development of materials to succeed
Cooling equipment
stainless steel sheets to cope with exhaust gas restrictions, and inexpensive materials Post-Processing
in order to cut costs, and accordingly the demand for ALSHEETTM with improved heat Hot-dip Aluminum Plating The quality and shape of the aluminum-
resistance performance has grown in these fields as well. Process coated sheet are improved by the
skin pass and tension leveler, and
We have recently developed further improvements to our products in terms of heat <in order of process> post-processing is applied to the add
resistance, strength at high temperature, colorfastness, and corrosion resistance, and corrosion resistance and enhance paint
have extended our product lineup to meet the ever-diversifying needs of today’s market. Heat-processing furnace adhesion. Rustproofing oil is applied if
necessary.
Welder
Contents Pay-off reel Post-processing
Coating pot Skin pass mill
Manufacturing Process 1 Tension reel
Notice: While every effort has been made to ensure the accuracy of the information contained within this publication, the use of Heat resistant(˚C) 500~600 500~600 550 500
the information is at the reader’s risk and no warranty is implied or expressed by NIPPON STEEL CORPORATION with respect to
the use of the information contained herein. The information in this publication is subject to change or modification without notice.
Please contact the NIPPON STEEL CORPORATION office for the latest information. Changing color
300~350 300~350 550 500
Please refrain from unauthorized reproduction or copying of the contents of this publication.
The names of our products and services shown in this publication are trademarks or registered trademarks of NIPPON STEEL temperature(˚C)
CORPORATION, affiliated companies, or third parties granting rights to NIPPON STEEL CORPORATION or affiliated companies.
Other product or service names shown may be trademarks or registered trademarks of their respective owners.
1
Product Usage Examples
Water boiler
Cars
(mufflers,
(mufflers,
manifold covers,
manifold covers,
converter covers)
converter covers)
Hot plate
bake-wear
Motorbikes
(mufflers)
chen: Ou
it t
In the k
do :
Lawnmowers,
Lawnmowers,
Rice cookers portable generators
ors
(mufflers)
(mufflers)
Ovens, toasters,
home bakery
In d o ors:
Fan heater
2 3
Standards
1. Types 6. Mechanical Properties
• JIS G 3314-2018 (abstract) Hot-dip aluminum-coated steel sheets and bands • JIS G 3314-2018 (abstract) Hot-dip aluminum-coated steel sheets and bands
①In cases where the coating
Application Tensile test
Type designation is 120≦, the
Main use Aluminum coating designation Elongation (%) nominal thickness may
Tensile Nominal thickness (mm) be 26≦, if an agreement
SA1C Heat resistance (commercial) Code i s re a c h e d b e t w e e n t h e
strength
SA1D Heat resistance (drawing) delivering and accepting
(N/mm2) 0.30≦t<0.40 0.40≦t<0.60 0.60≦t<1.00 1.00≦
40, 60, 80, 100, 120 parties.
SA1E Heat resistance (deep drawing)
②In cases where the coating
SA1F Heat resistance (ultra-deep drawing) SA1C (270≦) — — — — designation is 120≦, the
SA1D 270≦ (28≦) ① 30≦ ② 32≦ 34≦ nominal thickness may be
2 8 ≦ f o r S A 1 D , 3 2≦ f o r
• NIPPON STEEL Product Standards SA1E 270≦ — 34≦ ② 36≦ 38≦ SA1E, and 33≦ for SA1F,
SA1F 270≦ — 35≦ ② 37≦ 39≦ if an agreement is reached
Application between the delivering and
Type
Main use Aluminum coating designation Note: Tensile test samples must conform to JIS 5. accepting parties.
NSA1C Heat resistance (commercial) ③In the case of SA1D, SA1E
Bending properties and SA1F, the internal spacing
NSA1D Heat resistance (drawing) of bends may be single-sheet
NSA1E Heat resistance (deep drawing) Internal spacing of bends product of nominal thickness,
Code Bending if an agreement is reached
NSA1F Heat resistance (ultra-deep drawing)
Nominal thickness (mm)
angle between the delivering and
040, 060, 080, 100, 120 <1.60 1.60≦
NSA1D-P Colorfastness at high temperature accepting parties.
NSA1D-PQ Colorfastness at high temperature II SA1C 180˚ Double-sheet product with nominal thickness Double-sheet product with nominal thickness
NSA440R High strength (TS=440 class) SA1D 180˚ Single-sheet nominal thickness Double-sheet product with nominal thickness ③
NSA590 High strength (TS=590 class) SA1E 180˚ Single-sheet nominal thickness Double-sheet product with nominal thickness ③
NSSQAS1500 Hot stamp 80, 160, etc. SA1F 180˚ Single-sheet nominal thickness Double-sheet product with nominal thickness ③
2. Aluminum coating mass (NIPPON STEEL Product Standards) • NIPPON STEEL Product Standards
Aluminum coating designation 040 060 080 100 120 160 ①In cases where the coating
Tensile test designation is 120≦, the
Minimum coating mass (both sides, triple-spot method) g/m2 40 60 80 100 120 160 Elongation (%) nominal thickness may
Minimum coating mass (both sides, Single-spot method) g/m2 30 45 60 75 90 — Code Tensile Nominal thickness (mm)
be 26≦, if an agreement
strength i s re a c h e d b e t w e e n t h e
delivering and accepting
(N/mm2) 0.30≦t<0.40 0.40≦t<0.60 0.60≦t<1.00 1.00≦ parties.
3. Surface treatment (NIPPON STEEL Product Standards) 4. Oil coating
④In cases where the coating
Type Main uses Code Remarks Code Type NSA1C (270≦) — — — — designation is 120≦, the
NSA1D (270≦) (28≦) ① 30≦ ④ 32≦ 34≦ nominal thickness may be
Untreated M — H High oil coating 28≦ for NSA1D, 32≦ for
Mainly domestic electrical appliances. Color remains N Normal oil coating NSA1E 270≦ — 34≦ ④ 36≦ 38≦ NSA1E, and 33≦ for NSA1F,
Chromate- Corrosion resistant QM if an agreement is reached
stable after heating. Recommended by FDA NSA1F 270≦ — 35≦ ④ 37≦ 39≦
free L Low oil coating between the delivering and
Enhance corrosion NSA1D-P 270≦ — 30≦ 32v 34≦
treatment QN Mainly automobiles X No oil coating accepting parties.
resistance
NSA1D-PQ 270≦ — 30≦ 32≦ 34≦ ⑤I n t h e c a s e o f N S A 1 D ,
N S A 1 E a n d N S A 1 F, t h e
NSA440R 440≦ — 25≦ 27≦ 28≦
5. Dimensional tolerance (NIPPON STEEL Product Standards) Width Tolerance
internal spacing of bends
NSA590 590≦ — — — 18≦ may be single-sheet product
Thickness tolerance (units: mm) of nominal thickness, if
NSSQAS1500 — — — — — an agreement is reached
Width
<1,000 1,000 ≦t≦1,250 Classification Tolerance between the delivering and
Thickness Note: Tensile test samples must conform to JIS 5.
accepting parties.
<0.40 ±0.06 ±0.06 Width −0, +7
0.40≦t<0.60 ±0.07 ±0.07 Bending properties
0.60≦t<0.80 ±0.09 ±0.09 Internal spacing of bends
Code Bending
0.80≦t<1.00 ±0.10 ±0.11 Nominal thickness (mm)
angle
1.00≦t<1.20 ±0.11 ±0.12 <1.60 1.60≦
1.20≦t<1.60 ±0.13 ±0.14
Notes:
NSA1C 180˚ Double-sheet product with nominal thickness Double-sheet product with nominal thickness
1.60≦t<2.00 ±0.15 ±0.16 1. Nominal thickness refers to the NSA1D 180˚ Single-sheet nominal thickness Double-sheet product with nominal thickness ⑤
thickness after coating
2.00≦t<2.30 ±0.17 ±0.18 2. Thickness shall be measured NSA1E 180˚ Single-sheet nominal thickness Double-sheet product with nominal thickness ⑤
±0.20 ±0.21 from an optimal spot at least
2.30≦ NSA1F 180˚ Single-sheet nominal thickness Double-sheet product with nominal thickness ⑤
50 mm inside the edge.
4 5
Quality Attributes
1.External appearance • Change in mass when heated (up to 600°C)
The coating mass on our ALSHEET products is controlled using the wiping method, resulting in an An example of the change in mass when continuously heating ALSHEET and cold-rolled
even surface with a beautiful finish. steel sheet in the air is shown below.
2.Heat resistance
The external appearance of ALSHEET at high temperature is much better than hot-dip galvanized steel 50
Cold-rolled steel sheet is damaged
sheet and cold-rolled steel sheet, and the surface does not discolor up to 300~350°C. after heating (at 600˚C) for 15 hours.
At higher temperature, the surface forms an Al-Fe alloy, of a different color, but this prevents the
(600˚C)
base metal from oxidizing, so its heat resistance is retained. ALSHEET
Mass (g/m2)
• Surface condition after heating〔As an example〕(35℃×200hours)
The surface color of ALSHEET does not change after heating at up to 350°C, and maintains
its beautiful appearance.
(500˚C)
ALSHEET
(g)
0 0
–10 –10
ALSHEET Hot-dip galvanized Electro-galvanized Cold-rolled
steel sheet steel sheet steel sheet –15 –15
–20 –20
• Oxidization resistance (600°C × 200 hours)
Flakes of oxidized metal do not form even after heating the ALSHEET at up to 600°C. –25 ALSHEET –25 ALSHEET
Electro-galvanized Electro-galvanized
steel sheet steel sheet
–30 –30
Stainless steel Stainless steel
–45 –45
3.Heat reflectivity
The heat reflectiveness of ALSHEET is outstanding, as its surface is very smooth, demonstrating
80% heat reflection at temperatures up to 450°C. Accordingly, it is well suited for use as a heat
shield panel in toasters and the top reflector for gas ovens and oil stoves that operate more
effectively with heat reflection.
• Heat reflectivity of various materials〔As an example〕 (unit:%)
Material NS Zinc chromate coat Electro-galvanized steel sheet
ALSHEET Hot-dip galvanized Electro-galvanized Cold-rolled ALSHEET (Electro-galvanized steel sheet) Aluminum coating designation Zero spangle material
Item Test condition
steel sheet steel sheet steel sheet
Heat reflec- 100˚C×24Hr 90 95 95 95
tion rate 400˚C×24Hr 80 30 20 20
6 7
4.Corrosion resistance 4-3. Cyclical wet/dry test (Corrosion resistance to exhaust gases)
ALSHEET affords better corrosion resistance than galvanized steel sheet under various conditions because As per the results of the corrosion resistance test to automotive exhaust gases using condensate simulated
microscopic and stable oxide or hydroxide films readily form in air or water, in the same way as aluminum. solution, ALSHEET demonstrates better corrosion resistance than electro-galvanized steel sheet and cold-
However, unlike galvanized steel sheet, this product does not designed to provide galvanic reactions (sacrificial rolled steel sheet.
corrosion as a preventative measure), so care must be taken in how it is used. Its corrosion resistance under • Muffler test result examples
various conditions is presented below. (Chrysier' Spec 461H-83)
(With cold-rolled steel sheet data benchmarked as 100)
4-1. Saltwater spray test assessment Type
(%)
Corrosion rate
50 100 Muffler test method
• External appearance examples after saltwater spray test (after SST 168 hours) 1)Immerse test pieces in a mixed solution of
0.01N hydrogen bromide(HBr)– 0.05N
18%Cr Stainless steel 22.9% sulfuric acid(H2SO4)at 180°F(82°C)for
five seconds.
2)Remove and hang in the air to dry for an hour.
27.5% 3)Repeat processes 1) and 2)above twenty times.
13%Cr Stainless steel
4)Then heat in a furnace at atmospheric tempe-
rature of 1,000°F(538°C)for two hours.
5)Remove from furnace and allow to cool in air.
ALSHEET 80g/m2 30.1%(16μm)* 6)Repeat the above processes 1)to 5)
another 24 times.(Total 25 times)
7)Finally, remove any corrosion from the
Electro-galvanized 92.8%(80μm)* test pieces, weigh them, and calculate the
steel sheet 20/20 g/m2 corrosion rate by comparing the difference
with the sample weight before implementing
the test.
Cold-rolled steel sheet 100%(87μm)*
5.Chemical resistance
Aluminum is strongly resistant to mild acidity but weak against alkaline reagents, in contrast to zinc. Examples
ALSHEET Hot-dip galvanized steel sheet Electro-galvanized steel sheet Cold-rolled steel sheet
showing the weight loss due to corrosion caused by several chemicals are shown below.
(Chromate-free treatment) (Chromate-free treatment) (Chromate-free treatment)
(Unit: mg/dm2)
• External appearance examples after saltwater spray test (after heating at 300°C × 200 hours+SST168 hours) Hot-dip galvanized steel
Test type ALSHEET Cold-rolled steel sheet
sheet
16% SO2 gas test (96 hours) 130 2,825 1,510
18% NH3 gas test (192 hours) 10 180 25
20% HNO3 test (30 min.) 2 Original form is not retained. Original form is not retained.
1/10N NaCl + 0.3% H2O2 test 18 173 Red rust over entire surface
75 ALSHEET : pH 1.8~11.0
4-2. Example of resistance to gaseous sulfur oxides Hot-dip galvanized steel sheet
10
Corrosion loss (g/m2)
8 9
6.Weather resistance 8.Welding
ALSHEET forms a microscopic yet stable oxide film on the surface even in harsh environments, such as Appropriate conditions for ALSHEET’s resistance welding differ slightly from those for cold-rolled steel sheet
industrial areas, and affords outstanding resistance to weather. for both spot welding and seam welding.This is because aluminum itself is soft, flexible, and has good electrical
• Result examples for ALSHEET outdoor exposure test conductivity, so the amount of heat generated within layered sheets is less than with cold-rolled steel sheet.
Changes in weight of flat sheet as test piece 8-1.Spot welding
Heavy industry area Industrial area Urban area ● Mechanical test value examples per grade are shown below.
Increased ● Better welds can be achieved using electrodes with a smaller edge diameter.
● In terms of the electrode shape, better results can be achieved with a truncated cone type than radial type.
Changes in weight g/dm2
0
● Increase both the welding current and welding duration.
ALSHEET Drawing SA1D 196 314 42 44 - sufficient cooling with water from the top and bottom.
Deep drawing SA1E 176 304 44 41 1.6 Recommended conditions for seam welding
Commercial SA1C
Materials used:
Sheet thickness: 0.80 mm
Coating mass: 80 g/m2
ALSHEET Drawing SA1D Test conditions:
Punch diameter: 60 mm
Punch shoulder diameter: 6.5 mm
Deep drawing SA1E Die diameter: 6.6 mm
Die shoulder diameter: 6.5 mm
Lubricant: Press working oil #620
Cold-rolled
Commercial SPCC
steel sheet
10 11
Size Availability
High temperature colorfast ALSHEET (NSA1D-P) 1.Commercial, Drawing, Deep Drawing 2.High Strength, Hot StampDrawing
High temperature colorfast ALSHEET does not change color when heated to temperatures up to 500 - 550°C
(670、2.3)
because an assaying restraining element is added to the base metal, which enables it to maintain the original (1350、2.3)
glossiness of aluminum at high temperature. 2.20
2.40 (610、2.3) (1219、2.3)
However, although alloying is restrained, if degreased at temperatures higher than 410°C, the color may (1600、2.0)
change due to degreasing. 2.20
2.00
Heating temperature
250℃ 350℃ 450℃ 500℃ 550℃ 2.00 1.80
Materials
(800、1.6) (1219、1.6)
High temperature colorfast ALSHEET(NSA1D-P) ◎ ◎ ◎ ◎ ◎ 1.80 1.60
(730、1.6) (1250、1.6)
(1240、1.6)
Thickness(mm)
Thickness(mm)
High temperature colorfast ALSHEET(Ⅱ)
(NSA1D-PQ) ◎ ◎ ◎ ◎ ● 1.60 1.40
Commercial: SA1C、NSA1C
Heat resistant ALSHEET(commercial) ◎ ◎ ● ● ● Drawing: SA1D、NSA1D
1.40
NSA1D-P 1.20
Hot-dip galvanized steel sheet ◎ △ ● ● ● (1600、1.1)
1.20 Deep drawing: SA1E、NSA1E (1530、1.0)
Electro-galvanized steel sheet ● ● ● ● ● 1.00
1.00 (1480、0.95)
• Examples of surface condition after heating (500°C × 200 hours) ◎ No change 0.80
NSSQAS1500 (1400、0.9)
△ Significant color change (670、0.8) (1580、0.8)
0.80
● Entire surface changes color NSA590
0.60 (1219、0.6)
0.60 (800、0.6)
(1240、0.6) (730、0.5) NSA440R (1250、0.5)
(610、0.35) 0.40
0.40
(1219、0.4)
(610、0.3) (1000、0.3) 0.20
0.20
600 800 1000 1200 600 800 1000 1200 1400 1600
Width(mm) Width(mm)
1.40
(1219、1.2)
1.20 (1250、1.199)
(610、1.199)
Thickness(mm)
1.00
0.80
0.70
0.60
0.50
0.40
Heat resistant High temperature High temperature colorfast 0.35
ALSHEET colorfast ALSHEET ALSHEET Ⅱ 0.30
0.27 (610、0.3) (1250、0.3)
12 13
Food Hygiene ALSHEET Pipe
① ALSHEET is composed of elements that are harmless to the human body, namely, Al, Si, “ALSHEET Pipe” is manufactured from “ALSHEET” using high frequency induction welding.
and Fe, and there are no concerns about contamination of metals, such as Pb and Cd, in the The strength of the steel is combined with the advantages of aluminum, so this pipe affords
manufacturing process, so it is well suited to use as a material for food-contact equipment, outstanding heat resistance and corrosion resistance. It is widely used for automobile exhaust
such as cookers. pipes subsequent to stainless steel.
② It is approved as material for use in food equipment by the Food & Drug Administration (FDA)
in the United States as well.
③ Chromate treatment is normally applied to the surface of aluminum coating to prevent 1. Characteristics
white rust, but this is not desirable for food-contact equipment. A chromate-free (QM) type
developed by us for use in domestic electrical appliances passed the elution test specified by
the FDA, and received a Recommendation Letter for items that come into contact with food.
(*) When oil is applied to materials, they must be degreased after processing. The surface is very smooth as is typical for aluminum, but about a 3-mm
width of the iron base appears through the bead cut in the case of high fre-
Appearance quency welding on the outer surface. A slight bead is raised along the weld
on the inner surface, but the protrusion can be controlled (0.2~0.5mm) by
pressure if required.
2. Uses
Truck muffler
14 15
R120
3. Manufacturing Process 6. Quality Attributes 427∅×1.6
60˚
Tension roller 6-1. Heat resistance
• Appearance examples for 5-cycle test Bent pipe sample
ℓ=50mm
Pipe code 600 650 700 750 800
(℃ ) Humid conditions × 48 hours
Flat Bent Flat Bent Flat Bent Flat Bent Flat Bent
Uncoiler Share welder sheet pipe sheet pipe sheet pipe sheet pipe sheet pipe
Rotary loop Cooling
Heat resistant
◎
Internal ◎ ○
○
○
△
△
△
△∼×
×
in the air
ALSHEET External ◎ △ △∼× △∼× ×
1 cycle
Forming High frequency Bead • Examples of increase in oxidization after cycle heating test on straight pipe
Leveler Edge scarf roll welding (induction) cut Fairing roll
Traveling cutter
70 700˚C 180 800˚C
4. Specifications 60 100
Mechanical properties
Increased oxidization
50 50
Pipe code Coating mass designation for aluminum sheet YP TS EL
specifications
(N/mm2) (N/mm2) (%)
40 40
SA1D
AL80-TK 40, (60), 80, (100), (120) — 290≦ 35≦
NSA1D
30 30
5. Scope of Manufacturing 20 20
Thickness 10 10
(mm) 0.8 1.0 1.2 1.4 1.6 1.8 2.0 2.3
External diameter
(mm)
1 2 3 4 5 1 2 3 4 5 :Heat resistant
21.7 ALSHEET
22.2 Heating cycle Heating cycle
:YUS409D
25.4
27.2
31.8 △ △ △ △ △ △
6-2. Mechanical properties
34.0 △ △ △ △ △ △
35.0 △ △ △ △ △ △ Mechanical properties
38.1 ○ ○ ○ ○ ○ ○ Pipe designation Pipe size YP TS EL
40.0 ○ ○ ○ ○ ○ ○ (N/mm2) (N/mm2) (%)
42.7 ○ ○ ○ ○ ○ ○
45.0 ○ ○ ○ ○ ○ ○ AL80-TK 45∅×1.6 270 〜 310 300 〜 340 59 〜 70
47.6 ○ ○ ○ ○ ○ ○
48.6 ○ ○ ○ ○ ○ ○
50.8 ○ ○ ○ ○ ○ ○ 6-3. Dimensional tolerance
54.0 ○ ○ ○ ○ ○ ○
Please contact us regarding the dimensional tolerances in each case.
57.0 ○ ○ ○ ○ ○
57.2 ○ ○ ○ ○ ○
60.5 ○ ○ ○ ○ ○
65.0 ○ ○ ○ ○
68.9
70.0
75.0 ○ ○ ○ ○
76.3 : Please contact us
80.0 for details within
82.6 the blue frame
85.0
○ : Indicates internal
89.1 surface where bead
90.0 pressing is possible.
94.0
△ : Indicates internal
101.6 surface where bead
pressing is impossible.
16 17
Cautions for Use Order Guidelines
If inappropriately handled or used, ALSHEET cannot demonstrate its characteristic properties. When placing an order, please confirm the following matters in accordance with
Please pay attention to the following usage precautions. the purpose of the order.
18 19
Packaging and Labeling
The finished product is packaged and shipped as per normal procedure for steel to ensure that it is
Example of a Packaging Label
handled and stored with care prior to its use. The external layer of packaging consists of a packaging
label that contains details of the finished product that it is affixed to. Furthermore, the Package Card
is also included, which is the warranty for the product in question.
The Package Card is used when taking receipt of the product and confirming its condition. The
information contained on the Package Card and labels is detailed herein.
ALSHEET
SPECIFICATION COATING(G/M2)
V.C.I.
paper
Hoop
Lateral
skid Strap
Packing Longitudinal
label skid
Outer ring
Steel cover
[ Cut-length Sheet ] Hoop
Inside angle [ Coil ]
20 21